JPH01221433A - Liquid composition for impregnating glass fiber - Google Patents
Liquid composition for impregnating glass fiberInfo
- Publication number
- JPH01221433A JPH01221433A JP63211090A JP21109088A JPH01221433A JP H01221433 A JPH01221433 A JP H01221433A JP 63211090 A JP63211090 A JP 63211090A JP 21109088 A JP21109088 A JP 21109088A JP H01221433 A JPH01221433 A JP H01221433A
- Authority
- JP
- Japan
- Prior art keywords
- glass fiber
- weight
- component
- solid content
- butadiene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003365 glass fiber Substances 0.000 title claims abstract description 50
- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 239000007788 liquid Substances 0.000 title claims abstract description 21
- 239000007787 solid Substances 0.000 claims abstract description 27
- 229920001897 terpolymer Polymers 0.000 claims abstract description 17
- 229920000126 latex Polymers 0.000 claims abstract description 16
- 239000004816 latex Substances 0.000 claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 11
- 229920001084 poly(chloroprene) Polymers 0.000 claims abstract description 10
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 229920002681 hypalon Polymers 0.000 claims description 10
- HKRUNOMQTBJMBK-UHFFFAOYSA-N 1,5-dihydroxycyclohexa-2,4-diene-1-carbaldehyde Chemical compound OC1=CC=CC(O)(C=O)C1 HKRUNOMQTBJMBK-UHFFFAOYSA-N 0.000 claims 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 16
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract description 14
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 abstract description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 8
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000460 chlorine Substances 0.000 abstract description 3
- 229910052801 chlorine Inorganic materials 0.000 abstract description 3
- 229910052717 sulfur Inorganic materials 0.000 abstract description 3
- 239000011593 sulfur Substances 0.000 abstract description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 2
- 230000008676 import Effects 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 description 20
- 239000005060 rubber Substances 0.000 description 20
- 239000003795 chemical substances by application Substances 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 6
- 235000011114 ammonium hydroxide Nutrition 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- -1 polyethylene Polymers 0.000 description 5
- 229920000459 Nitrile rubber Polymers 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- DGXAGETVRDOQFP-UHFFFAOYSA-N 2,6-dihydroxybenzaldehyde Chemical compound OC1=CC=CC(O)=C1C=O DGXAGETVRDOQFP-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000012756 surface treatment agent Substances 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- SEQDDYPDSLOBDC-UHFFFAOYSA-N Temazepam Chemical compound N=1C(O)C(=O)N(C)C2=CC=C(Cl)C=C2C=1C1=CC=CC=C1 SEQDDYPDSLOBDC-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- KVBYPTUGEKVEIJ-UHFFFAOYSA-N benzene-1,3-diol;formaldehyde Chemical compound O=C.OC1=CC=CC(O)=C1 KVBYPTUGEKVEIJ-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000004815 dispersion polymer Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- RCHKEJKUUXXBSM-UHFFFAOYSA-N n-benzyl-2-(3-formylindol-1-yl)acetamide Chemical compound C12=CC=CC=C2C(C=O)=CN1CC(=O)NCC1=CC=CC=C1 RCHKEJKUUXXBSM-UHFFFAOYSA-N 0.000 description 1
- 125000002560 nitrile group Chemical group 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- 238000013040 rubber vulcanization Methods 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明はガラス繊維含浸用液状組成物および該組成物に
由来する被膜を有するガラス繊維コードに関する。さら
に詳しくは、タイミングヘルドの如く、走行中に熱およ
び外力の両方を受ける製品に強化材として使用されるガ
ラス繊維コード等の含浸剤として好適な液状組成物およ
びそれに由来する被膜を有するガラス繊維コードに関す
る。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a liquid composition for impregnating glass fibers and a glass fiber cord having a coating derived from the composition. More specifically, a liquid composition suitable as an impregnating agent for glass fiber cord used as a reinforcing material in products such as timing healds that are subjected to both heat and external force during running, and a glass fiber cord having a coating derived therefrom. Regarding.
〈従来の技術〉
従来、タイミングヘルド用の芯線（強化材）としてのガ
ラス繊維コードは、タイミングヘルドの基材ゴム中に埋
設される前に、レヅルシンーボルマリンラテノクス（Ｒ
ＦＬ）処理が行なわれるのが普通である。<Prior art> Conventionally, glass fiber cords used as core wires (reinforcing materials) for timing helds are made of resin-bornumarin latex (R) before being embedded in the base rubber of timing healds.
FL) processing is normally performed.
特開昭５０−３１８４号公幸旧こは、レゾルシノールア
ルデヒト樹脂２〜１０重量部１、ブタシエン−スチレン
−ビニルピリシンターポリマ−２０〜６０重量部、カル
ボキシル化ブタジェンスチレン樹脂１５〜４０重量部お
よび非相溶性ワックス（例えばパラフィンワックス）３
〜３０重量部が含浸剤であるガラス繊維用含浸剤が開示
されている。JP-A-50-3184 discloses 2 to 10 parts by weight of resorcinol aldehyde resin, 20 to 60 parts by weight of butadiene-styrene-vinylpyric interpolymer, 15 to 40 parts by weight of carboxylated butadiene styrene resin, and Compatible wax (e.g. paraffin wax) 3
A glass fiber impregnating agent is disclosed in which the impregnating agent is 30 parts by weight.
特開昭５９−５３７８０号公報には、レゾルシンホルム
アルデヒＩ・樹脂水性液、スルホハロケン化ポリマー水
分散液および亜鉛化合物又はマグネシウム化合物を含有
する繊維の表面処理剤が開示されている。JP-A-59-53780 discloses a surface treatment agent for fibers containing an aqueous resorcinol-formaldehyde I/resin liquid, an aqueous sulfohaloxenated polymer dispersion, and a zinc compound or a magnesium compound.
特開昭５９−７３４５３号公報には、前記特開昭５９−
５３７８０号公報の前記表面処理剤で処理された補強用
ガラス繊維が開示されている。Japanese Unexamined Patent Publication No. 59-73453 contains the aforementioned
No. 53,780 discloses a reinforcing glass fiber treated with the above-mentioned surface treatment agent.
特開昭６１−２０７４４２号公沫には、クロロスルホン
化ポリエチレンの如きハロケン含有重合体のラテックス
とレゾルシン−ホルムアルデヒドの混合液で処理した繊
維と、ニトリル基含有高飽和炭化水素ゴム配合物とを加
硫接着する方法が開示されている。JP-A-61-207442 discloses a method in which fibers treated with a mixture of a latex of a halokene-containing polymer such as chlorosulfonated polyethylene and a resorcinol-formaldehyde mixture are combined with a highly saturated hydrocarbon rubber compound containing a nitrile group. A method of sulfur bonding is disclosed.
特公昭４７−３７５１３号公報には、基材ゴムとの接着
性、柔軟性、耐熱性あるいは耐水性等を向上させようと
して、ガラス１〜マーを含有する含浸剤ラテックスが開
示されている。Japanese Patent Publication No. 47-37513 discloses an impregnating latex containing glass 1 to mer in an attempt to improve adhesion to a base rubber, flexibility, heat resistance, water resistance, etc.
特開昭５３−７０１．９６号公報には、タイヤコードの
含浸剤として、ブタジェン−ハーフニスチル−メタクリ
ル酸ターポリマー、乳化性鉱物油類、シリカ誘導体類お
よびエステル類を配合してなるガラス繊維の含浸剤が開
示されている。JP-A-53-701.96 discloses impregnating glass fibers containing butadiene-halfnistil-methacrylic acid terpolymer, emulsifying mineral oils, silica derivatives, and esters as an impregnating agent for tire cords. Agents are disclosed.
さらに、特開昭５４−６９１９２号公ｆシには、タイヤ
コード含浸剤として、ビニルピリジンターポリマー、ポ
リブタジエンラテンクス、ワックスエマルジョンおよび
レゾルシノール−ホルムアルデヒド樹脂からなるガラス
繊維の含浸剤が開示されている。Further, JP-A-54-69192 discloses a glass fiber impregnating agent comprising a vinyl pyridine terpolymer, a polybutadiene latex, a wax emulsion, and a resorcinol-formaldehyde resin as a tire cord impregnating agent.
〈発明が解決しようとする問題点〉
本発明の目的は、新規な組成のガラス繊維含浸用組成物
を提供することにある。<Problems to be Solved by the Invention> An object of the present invention is to provide a composition for impregnating glass fibers with a novel composition.
本発明の他の目的は、クロルスルホン化ポリエチレンを
、含浸剤としてのゴム成分の一つして含有する、新規な
組成のガラス繊維含浸用組成物を提供することにある。Another object of the present invention is to provide a novel composition for impregnating glass fibers containing chlorosulfonated polyethylene as one of the rubber components as an impregnating agent.
本発明のさらに他の目的は、ガラス繊維コードを使用す
る製品に、優れた耐熱性、対屈曲疲労性および柔軟性を
付与することのできるガラス繊維コード含浸用組成物お
よび該組成物で処理されたガラス繊維コードを提供する
ことにある。Still another object of the present invention is a composition for impregnating a glass fiber cord, which can impart excellent heat resistance, resistance to bending fatigue, and flexibility to products using the glass fiber cord, and a composition treated with the composition. Our objective is to provide glass fiber cords with high quality.
本発明のさらに他の目的は、熱および外力の双方を一緒
に受ける製品、例えばベルトに使用して、長期間に亘り
該製品の強力を保持しつづけることのできるガラス繊維
含浸用組成物および該組成物で処理されたガラス繊維コ
ートを提供することにある。Still another object of the present invention is to provide a composition for impregnating glass fibers, which can be used in products that are subjected to both heat and external forces, such as belts, to maintain the strength of the products for a long period of time. An object of the present invention is to provide a glass fiber coat treated with a composition.
本発明のさらに他の目的および利点は以下の説明から明
かとなろう。Further objects and advantages of the invention will become apparent from the description below.
〈問題点を解決するための手段および利点〉本発明によ
れば、本発明の上記目的および利点は、
（Ａ）＋１１ レゾルシン−ボルムアルデヒド樹脂（
２）フタジエン−スチレン−ビニルピリジンターポリマ
ー、および
（３） クロルスルボン化ポリエチレンを含をしてな
り、そして
（Ｂ）上記（１）、 ＋２Ｌ および（３）の成分の固
形分合計量を基準として上記成分（１）は２〜１５重量
％であり
−に記成分（２）は１５〜８０重量％であり、そして
上記成分（３）は１５〜７０重量％である、ことを特徴
とするガラス繊維含浸用液状組成物によって達成される
。<Means and Advantages for Solving the Problems> According to the present invention, the above objects and advantages of the present invention are achieved by (A)+11 resorcin-bormaldehyde resin (
2) phthadiene-styrene-vinylpyridine terpolymer; and (3) chlorosulfonated polyethylene; A glass fiber characterized in that component (1) is 2 to 15% by weight, component (2) is 15 to 80% by weight, and component (3) is 15 to 70% by weight. This is achieved by a liquid composition for impregnation.
本発明のガラス繊維含浸用液状組成物は、上記成分（］
、）、 （２１，および（３）の３成分を必須成分とし
て含有することを特徴とする。The liquid composition for impregnating glass fibers of the present invention has the above-mentioned components (]
, ), (21), and (3) as essential components.
本発明の液状組成物の好ましい態様では、ジカルボキシ
ル化ブタジエン−スチレン樹脂（４）またはクロロプレ
ンゴム（５）が上記成分（２）のターポリマーの一部に
替えて用いられる。In a preferred embodiment of the liquid composition of the present invention, dicarboxylated butadiene-styrene resin (4) or chloroprene rubber (5) is used in place of a part of the terpolymer of component (2).
成分（１１のレゾルシン−ホルマリン樹脂としては、レ
ゾルシノール対ホルマリンのモル比が１対１〜３のレゾ
ルシノールとポルマリンとの縮合反応によって生成され
るものが好ましく用いられる。例えばレゾール型樹脂あ
るいはノボラック型樹脂として知られているものが使用
でき、例えば固形分５〜１０重量％、例えば固形分８重
量％の水溶液として好適に使用される。As the resorcinol-formalin resin of component (11), one produced by a condensation reaction of resorcinol and pomarin with a molar ratio of resorcinol to formalin of 1:1 to 3 is preferably used. For example, as a resol type resin or a novolak type resin. Any known solution can be used, and is preferably used as an aqueous solution with a solid content of 5 to 10% by weight, for example, a solid content of 8% by weight.
成分（２）のブタジエンースチレンービニルピリジンタ
ーボリマーとしては、当業界の技術者に周知されている
多数のその種のターポリマー類を使用できる。例えばフ
ラジエフ２０〜８５重量％スチレン５〜７０重量％およ
びヒニルピリジン５〜３０重量％からなるターポリマー
、例えば約７０重量％のブタジェン、約１５重量％のス
チレンおよび約１５重量％のビニルピリシンからなるタ
ーポリマーが＄けられる。As component (2), the butadiene-styrene-vinylpyridine turbopolymer, a large number of such terpolymers known to those skilled in the art can be used. For example, a terpolymer consisting of 20-85% by weight Fradiev, 5-70% by weight styrene and 5-30% by weight hinylpyridine, for example a terpolymer consisting of about 70% butadiene, about 15% styrene and about 15% vinylpyridine. can be paid $.
代表的な適するブタジエン−スチレン−ビニルピリジン
ターポリマー類は“’ Ｎ１ｐｏ １２５１８ＦＳ”′
の商標名で日本ゼオン社から入手し得るターポリマーお
よび“’ ＪＳＲ０６５０”の商標名で日本合成ゴム社
から人手し得るターポリマーおよび” Ｐ、ｙｒａｔｅ
ｘ Ｊ −１９０４”の商標名で住友ノーガタック社か
ら入手し得るターポリマー等が挙げられる。成分（２）
のターポリマーは、例えば固形分約４０重量％のラテッ
クスとして好適に使用される。Representative suitable butadiene-styrene-vinylpyridine terpolymers are "'N1po 12518FS"'
Terpolymers available from Nippon Zeon Co., Ltd. under the trade name 'JSR0650' and terpolymers available from Nippon Synthetic Rubber Co., Ltd. under the trade name 'JSR0650'
Examples include terpolymers available from Sumitomo Naugatac under the trade name "x J-1904". Component (2)
The terpolymer is preferably used as a latex having a solids content of about 40% by weight, for example.
成分（３）のクロルスルポン化ポリエチレンは、ポリエ
チレンを二酸化イオウの存在下で塩素化することによっ
て製造されたもので、ポリエチレンの主鎖の水素原子の
一部がクロルスルボニル基（Ｃｎ ＳＯ□−）および塩
素で置換されたものである。Component (3), chlorosulfonated polyethylene, is produced by chlorinating polyethylene in the presence of sulfur dioxide, and some of the hydrogen atoms in the main chain of polyethylene are chlorosulfonyl groups (Cn SO□-). and those substituted with chlorine.
本発明で用いられるクロルスルポン化ポリエチレンとし
ては、例えば塩素含量２５〜４３重量％および硫黄含量
１．０〜１．５重量％のものが好ましい。The chlorsulfonated polyethylene used in the present invention preferably has a chlorine content of 25 to 43% by weight and a sulfur content of 1.0 to 1.5% by weight, for example.
成分（３）のクロルスルボン化ポリエチレンは、例えば
固形分３０〜６０重量％、例えは固形分４０重量％のラ
テックスとして好適に用いられる。代表的な適するクロ
ルスルボン化ポリエチレンは” Ｅｓｐｒｅｎｅ”の商
標名で住友化学工業社から入手し得る。The chlorosulfonated polyethylene of component (3) is preferably used as a latex with a solid content of 30 to 60% by weight, for example, a solid content of 40% by weight. A representative suitable chlorosulfonated polyethylene is available from Sumitomo Chemical Co., Ltd. under the trademark "Esprene."
本発明の好適な組成物において含有する成分（４）のジ
カルボキシル化ブタジエン−スチレン樹脂は、例えばマ
レイン酸の如きエチレン性不飽和ジカルボン酸の少量の
存在下で、ブタジェンとスチレンとを共重合せしめるこ
とによって製造させる。ジカルボキシル化ブタジエン−
スチレン樹脂としてば、例えばブタジェン２０〜８０重
量％、スチレン５〜７０重量％およびエチレン性不飽和
ジカルボン酸１〜１０重量％を含有するものが有利に用
いられる。The dicarboxylated butadiene-styrene resin of component (4) contained in the preferred composition of the present invention is prepared by copolymerizing butadiene and styrene in the presence of a small amount of an ethylenically unsaturated dicarboxylic acid such as maleic acid. Manufactured by Dicarboxylated butadiene
As the styrene resin, those containing, for example, 20 to 80% by weight of butadiene, 5 to 70% by weight of styrene, and 1 to 10% by weight of ethylenically unsaturated dicarboxylic acid are advantageously used.
成分（４）のジカルボキシル化ブタジエン−スチレン樹
脂は、例えば固形分３０〜６０重量％、例えば固形分４
０重量％のラテックスとして好適に用いられる。代表的
な適するジカルボキシル化ブタジエン−スチレン樹脂は
、“Ｎ１ｐｏｌ ２５７０Ｘ５″の商標名でロ本セオン
社から入手し得る。あるいは、” 、ＪＳｌｌ ０６６
８． ＪＳＲ０６９１あるいはＪＳＲ０６９７” の商
標名で日本合成ゴム社から入手し得る。The dicarboxylated butadiene-styrene resin of component (4) has a solid content of, for example, 30 to 60% by weight, for example, a solid content of 4%.
It is suitably used as 0% by weight latex. A representative suitable dicarboxylated butadiene-styrene resin is available from Lohon Seon under the trade name "N1pol 2570X5". Or”, JSll 066
8. It is available from Japan Synthetic Rubber Co. under the trade name JSR0691 or JSR0697.
同様に、本発明の好適な組成物が含有する成分（５）の
クロロプレンゴムとしては、当業者にＩ’ｌ知の多数の
その種のゴムのを使用できる。成分（５）のクロロプレ
ンゴムとしては、例えば固形分３０〜６０重量％、例え
ば固形分６０重量％のラテックスとして好適に用いられ
る。代表的な適するクロロプレンゴムとしては、“Ｎｅ
ｏｐｒｅｎｅ ６５０ ”の商標名で昭和ネオプレン社
から人手し得る。あるいは、Ｂａｙｐｒｅｎ Ｌａｔｅ
ｘ １１の商標名でＢａｙｅｒ社から入手し得る。Similarly, the chloroprene rubber of component (5) contained in the preferred compositions of the present invention can be any of a number of such rubbers known to those skilled in the art. The chloroprene rubber of component (5) is preferably used as a latex having a solid content of 30 to 60% by weight, for example, a solid content of 60% by weight. A typical suitable chloroprene rubber is “Ne”.
Available from Showa Neoprene Co., Ltd. under the trade name ``oprene 650''.Also, Bayprene Late
It is available from Bayer under the tradename X 11.
成分（２）〜（５）の上記の如きラテックスは、当業者
に周知の乳化剤を含有することができる。The latices as described above in components (2) to (5) may contain emulsifiers well known to those skilled in the art.
本発明のガラス繊維含浸用液状組成物は、上記（１１，
＋２１および（３）の成分を、これら３成分の固形分の
合計重量を基準として、成分（１）を２〜１５重量％、
成分（２）を１５〜８０重量％および成分（３）を１５
〜７０重量％で含有する。The liquid composition for impregnating glass fibers of the present invention is as described above (11,
+21 and (3), 2 to 15% by weight of component (1), based on the total weight of the solid content of these three components;
15 to 80% by weight of component (2) and 15% of component (3)
Contains up to 70% by weight.
上記重量割合の好ましい範囲は、成分（」）については
５〜１０重量％、成分（２）については３５〜６５重量
％および成分（３）については２０〜５０重量％である
。３成分の上記重量割合の確保は本発明の前記目的を達
成する上で重要である。Preferred ranges of the above weight proportions are 5 to 10% by weight for component (''), 35 to 65% by weight for component (2), and 20 to 50% by weight for component (3). Ensuring the above weight ratios of the three components is important in achieving the above object of the present invention.
成分（４）又は成分（５）を含有する本発明の好ましい
組成物は、成分（２）の上記重量範囲において、成分（
２）の重量割合の１０〜９０％を置換することができる
。A preferred composition of the present invention containing component (4) or component (5) contains component (2) in the above weight range.
10 to 90% of the weight proportion of 2) can be replaced.
本発明のガラス繊維含浸用液状組成物は、必要に応じ、
ｐＨを調整するため塩基例えばアンモニアを含有するこ
とができ、さらに必要により酸化防止剤等を含有するこ
とができる。The liquid composition for impregnating glass fibers of the present invention may contain, if necessary,
In order to adjust the pH, a base such as ammonia may be contained, and if necessary, an antioxidant or the like may be contained.
本発明のガラス繊維含浸用液状組成物は、通常固形分含
量１５〜３０重量％の水性ラテックスとして好適に使用
することができる。本発明のガラス繊維含浸用組成物は
、その中にガラス繊維ストランドを浸漬し、過剰分を除
去し、ついて必要により乾燥することによって、ガラス
繊維ストランドに施される。その際、ガラス繊維スｌ〜
ランドには、ガラス繊維の紡糸時に施される集束剤が施
されでいても、いなくてもいずれでもよい。ガラス繊維
ストランドば次いて所望の本数を集めて、通常撚りが施
されてカラス繊維コードが得られる。The liquid composition for impregnating glass fibers of the present invention can be suitably used as an aqueous latex having a solid content of usually 15 to 30% by weight. The glass fiber impregnating composition of the present invention is applied to a glass fiber strand by dipping the glass fiber strand therein, removing excess, and optionally drying. At that time, glass fiber
The land may or may not be coated with a sizing agent applied during spinning of glass fibers. The glass fiber strands are then collected in the desired number and usually twisted to obtain a glass fiber cord.
このガラス繊維コードは未加硫のゴム基材中に、それ自
体公知の方法で埋め込まれ、加圧下で加熱加硫される。This glass fiber cord is embedded in an unvulcanized rubber base material by a method known per se, and heated and vulcanized under pressure.
上記方法において、本発明の液状３、■酸物は、ガラス
繊維コードに対し、固形分含量で通常１０〜３０重量％
に相当する量で施され、ガラス繊維コードに該液状組成
物の被膜を与える。In the above method, the liquid acid of the present invention (3) usually has a solid content of 10 to 30% by weight based on the glass fiber cord.
of the liquid composition to provide a coating of the liquid composition on the glass fiber cord.
該液状組成物の被膜はゴム基材中に埋設される前に通常
熱処理を受は固体被膜を与える。固体被膜はガラス繊維
に対し固形分換算で１０〜３０重量％を占めることが好
ましい。The coating of the liquid composition is usually subjected to a heat treatment to provide a solid coating before being embedded in the rubber substrate. The solid coating preferably accounts for 10 to 30% by weight of the glass fibers in terms of solid content.
本発明の含浸用液状組成物をほどこされたガラス繊維コ
ードは種々のゴム、特にクロロプレンゴム、水素化ニト
リルゴム、クロロスルポン化ポリエチレン等に対して優
れた接着性を示す。The glass fiber cord coated with the liquid impregnating composition of the present invention exhibits excellent adhesion to various rubbers, particularly chloroprene rubber, hydrogenated nitrile rubber, chlorosulfonated polyethylene, and the like.
自動車エンジン付近の温度上昇に伴い、近年自動車のタ
イミングヘルド用のゴＪ、としては、従来から用いられ
てきたクロロプレンのほか、クロロスルホン化ポリエチ
レンや水素化ニトリルゴムの様な耐熱性のゴムが使用さ
れるようになってきた。As temperatures near automobile engines rise, in recent years heat-resistant rubbers such as chlorosulfonated polyethylene and hydrogenated nitrile rubber have been used for timing helds in automobiles, in addition to the conventional chloroprene. It has started to be done.
本発明の含浸用液状組成物は、このような耐熱性のゴム
に対する接着性も十分である点で特徴的である。本発明
の含浸剤組成物を施されたガラス繊維コードは、水素化
ニトリルゴムまたはクロロスルホン化ポリエチレンゴム
に埋設する前に、接着性を更に高めるために好ましくは
更にハロゲン含有ポリマー、イソシアネート化合物を含
む処理液で処理される。また得られたゴム製品は耐熱性
、対屈曲疲労性及び柔軟性に優れる。それ故、本発明の
含浸用組成物は熱および外力の双方を一緒に受ける例え
ばタイミングヘルドに使用されるガラス繊維コード用の
含浸用組成物としてきわめて好適に使用することができ
る。The impregnating liquid composition of the present invention is characterized in that it also has sufficient adhesion to such heat-resistant rubber. The glass fiber cord coated with the impregnating agent composition of the present invention preferably further contains a halogen-containing polymer and an isocyanate compound to further improve adhesion before being embedded in hydrogenated nitrile rubber or chlorosulfonated polyethylene rubber. Processed with processing liquid. Furthermore, the obtained rubber product has excellent heat resistance, resistance to bending fatigue, and flexibility. Therefore, the impregnating composition of the present invention can be very suitably used as an impregnating composition for glass fiber cords used in timing healds, which are subjected to both heat and external force.
以下実施例により本発明をさらに詳細に説明する。The present invention will be explained in more detail with reference to Examples below.
〈実施例〉
実施例１
（１） 直径９μｍの無アルカリガラスのフィラメン
トを紡糸し、ごれを集束剤により集束して３３７テノク
スのガラスストランドを得、これを３本合糸させ下記組
成、
２５％アンモニア水 １重量部水
４重量部からなる含浸剤中
を浸漬して通過させ、次いで過剰の含浸剤を、ガラスコ
ードに対し固形分が約２０重量％となるまで抜取り、さ
らに約２５０°Ｃの温度で２分間熱処理して含浸剤処理
ガラス繊維束を得た。<Example> Example 1 (1) A filament of alkali-free glass with a diameter of 9 μm was spun, and the dirt was bundled with a binding agent to obtain a glass strand of 337 tenox, and three of these were combined to give the following composition: 25 % ammonia water 1 part by weight water
It was dipped and passed through an impregnating agent consisting of 4 parts by weight, and then the excess impregnating agent was removed until the solid content was about 20% by weight with respect to the glass cord, and it was further heat-treated at a temperature of about 250°C for 2 minutes. A glass fiber bundle treated with an impregnating agent was obtained.
次にこのガラス繊維束に１インチ当り２．１回のＺ方向
（Ｓ方向）の下撚りを与えた。Next, this glass fiber bundle was twisted 2.1 times per inch in the Z direction (S direction).
（２） この下撚りを与えたガラス繊維束を１３本合
わせて１インチ当り２．１回のＳ方向（Ｚ方向）の上撚
りを加え、ＥＣＧ １５０３／１３２．ＩＳ （Ｚ）の
コードを得た。このコートを１２０ ａｍの長さに切断
し、表−１の配合の未加硫クロロプレンゴムシートの上
に２０木平行に並べ（全幅２５１ｍ）、これを上下方向
から、１５０°Ｃで２５分間、プレスして加硫した。(2) A total of 13 of these pre-twisted glass fiber bundles are given 2.1 twists per inch in the S direction (Z direction) to form ECG 1503/132. I got the code for IS (Z). This coat was cut into lengths of 120 am, placed in parallel on unvulcanized chloroprene rubber sheets with the composition shown in Table 1 (total width 251 m), and heated from above and below at 150°C for 25 minutes. It was pressed and vulcanized.
表＝１ ゴム配合
加硫後、コートの尖端部とゴムの尖端部とを強固に把持
し、互いに反対方向に引っ張って、コードをゴムから引
き剥して接着性を調べ、次の基準によって判定した。Table = 1 After rubber compounding and vulcanization, the tip of the coat and the tip of the rubber were firmly grasped and pulled in opposite directions, and the cord was peeled off from the rubber to examine adhesion, and the adhesion was judged according to the following criteria. .
◎、ゴム破壊、 ０１３７４以上ゴム破壊、△；
１／２以上ゴム破壊、×；ゴム破壊せず、接着力は、◎
が最大で、順次○、△および×と低下する。◎, rubber destruction, 01374 or more rubber destruction, △;
1/2 or more rubber destroyed, ×; Rubber not destroyed, adhesive strength: ◎
is the maximum, and decreases sequentially to ◯, △, and ×.
また、ナイロ帆布を円筒ドラ１、上に巻き付け、その上
に該処理コードを５Ｑ）Ｈり晶とＺ撚り品を交互にスビ
ニンクし、さらに表−１のゴム配合物の未加硫シートを
積層して、上記条件で加硫した。In addition, a nylon canvas was wrapped around the cylindrical drum 1, and the treated cord was applied to the 5Q) H crystal and Z twisted products alternately, and an unvulcanized sheet of the rubber compound shown in Table 1 was further laminated. Then, vulcanization was performed under the above conditions.
次に該円筒状物をインチ幅にカットしタイミングベルト
を製造した。該タイミングヘルドを、直径ｌＱｃｍのプ
リー２個の間に装着して８０°Ｃの雰囲気中で３００時
間走行させた後、ヘルドをコードに沿って切断し、切断
面のコードの状態を電子顕微鏡で観察し、次の基準によ
って含浸剤（ＲＦＬ）の状態を判定した。Next, the cylindrical product was cut into inch width pieces to produce timing belts. The timing heald was installed between two pulleys with a diameter of 1Q cm and run for 300 hours in an atmosphere of 80°C.The heald was then cut along the cord and the state of the cord at the cut surface was examined using an electron microscope. Observation was made and the condition of the impregnating agent (RFL) was determined according to the following criteria.
◎：未走行と変わらず、
○、ＲＦＬが硬くなり、凝集破壊を始めた状態、△；凝
集破壊が進行し石状に砕ける、
×；さらに凝集破壊が進行し砂状になる、また、走行後
のヘルドの強力保持率を下記のようにして調べた。◎: Same as when not running. ○: RFL becomes hard and has started cohesive failure. △: Cohesive failure progresses and breaks into stone-like pieces. ×: Cohesive failure progresses further and becomes sand-like. The strong retention rate of the later heald was investigated as follows.
即ち、上下クランプにプリーを備えた引っ張り試験機に
本タイミングヘルドを装着して引っ張り、タイミングヘ
ルド破断時の強力を測定した。次に以下の算出式を用い
てタイミングヘルド走行試験後の強力保持率を求めた。That is, the timing heald was attached to a tensile testing machine equipped with pulleys on the upper and lower clamps, and the timing heald was pulled to measure the strength at which the timing held broke. Next, the strength retention rate after the timing held running test was determined using the following calculation formula.
結果を表−３に示す。The results are shown in Table-3.
実施例２
２５％アンモニア水 １重量部水
４重量部からなる含浸剤を
用いて、実施例］と同様にして処理を行なった。結果を
表−３に示す。Example 2 25% ammonia water 1 part by weight water
The treatment was carried out in the same manner as in Example, using 4 parts by weight of an impregnating agent. The results are shown in Table-3.
実施例３
２５％アンモニア水 １重量部水
４重量部からなる含浸剤を
用いて、実施例１と同様にして処理を行なった。結果を
表−３に示す。Example 3 25% ammonia water 1 part by weight water
The treatment was carried out in the same manner as in Example 1 using 4 parts by weight of an impregnating agent. The results are shown in Table-3.
実施例４
２５％アンモニア水 １重量部水
９重量部からなる含浸剤を
用いて、実施例１と同様にして処理を行なった。結果を
表−３に示す。Example 4 25% ammonia water 1 part by weight water
The treatment was carried out in the same manner as in Example 1 using 9 parts by weight of impregnating agent. The results are shown in Table-3.
実施例５
実施例２で得たＥＣＧ １５０３／１３２． Ｉ Ｓ
（Ｚ ）のコートに下記組成の処理液を、不揮発分の付
着量が２．５〜３．５重量％となるように塗布し、有機
溶剤を蒸発、除去して二次被覆層を備えた硝子繊維コー
ドをえた。Example 5 ECG obtained in Example 2 1503/132. IS
A treatment solution with the following composition was applied to the coating of (Z) so that the amount of nonvolatile matter attached was 2.5 to 3.5% by weight, and the organic solvent was evaporated and removed to form a secondary coating layer. I got a glass fiber cord.
Ｐ−ジニトロソヘンセン ２．２５ ｆｆｌｆｉ
ｔ部カーボンブランク ３．０ 重量
部キシレン ５１．０ 重量部
トリクロロエチレン ３４．０ 重量部こ
の硝子繊維コードを用いて、表−２のゴム配合の未加硫
の水素化ニトリルゴムシー１−を用いる他は実施例１と
同様にして試験した。ただしタイミングベルト走行試験
の雰囲気温度は１２０ ’Ｃで実施した。結果を表〜３
に示す。P-dinitrosohensen 2.25 fflfi
t part Carbon blank 3.0 parts by weight Xylene 51.0 parts by weight Trichlorethylene 34.0 parts by weight Using this glass fiber cord, unvulcanized hydrogenated nitrile rubber sheet 1- with the rubber compound shown in Table 2 was used. was tested in the same manner as in Example 1. However, the timing belt running test was conducted at an ambient temperature of 120'C. Table of results ~ 3
Shown below.
表−２
比較例１
２５％アンモニア水 １重量部水
４重量部からなる含浸剤を
用いて、実施例１と同様にして処理を行なった。結果を
表−３に示す。Table-2 Comparative Example 1 25% ammonia water 1 part by weight water
The treatment was carried out in the same manner as in Example 1 using 4 parts by weight of an impregnating agent. The results are shown in Table-3.
比較例２
２５％アンモニア水 １重量部水
４重量部からなる含浸剤を
用いて、実施例１と同様にして処理を行なった。結果を
表−３に示す。Comparative Example 2 25% ammonia water 1 part by weight water
The treatment was carried out in the same manner as in Example 1 using 4 parts by weight of an impregnating agent. The results are shown in Table-3.
比較例３
比較例１で得たガラス繊維コート用いる他は実施例５と
全く同様に実施した。結果を表−３に示す。Comparative Example 3 The same procedure as in Example 5 was carried out except that the glass fiber coat obtained in Comparative Example 1 was used. The results are shown in Table-3.
表−３ 特許出願人 日本硝子繊維株式会社Table-3 Patent applicant: Nippon Glass Fiber Co., Ltd.
Claims (1)
リマー （３）クロルスルホン化ポリエチレン を含有してなり、そして （Ｂ）上記（１）、（２）、および（３）の成分の固形
分合計量を基準として上記成分（１）は２〜１５重量％
であり 上記成分（２）は１５〜８０重量％であり、そして 上記成分（３）は１５〜７０重量％である ことを特徴とするガラス繊維含浸用液状組成物。 ２、ジカルボキシル化ブタジエン−スチレン樹脂（４）
を、上記成分（２）のターポリマーの一部に替えて用い
る請求項１記載の組成物。 ３、上記成分（２）の使用量の１０〜９０％を、ジカル
ボキシル化ブタジエン−スチレン樹脂（４）に替えて用
いる請求項１記載の組成物。 ４、クロロプレンゴム（５）を上記成分（２）のターポ
リマーの一部に替えて用いる請求項１記載の組成物。 ５、上記成分（２）の使用量の１０〜９０％をクロロプ
レンゴム（５）に替えて用いる請求項１記載の組成物。 ６、固型分含量が１５〜３０重量％の水性ラテックスで
ある請求項１記載の組成物。 ７、請求項１記載の液状組成物の皮膜を有するガラス繊
維コード。 ８、請求項１記載の液状組成物に由来する固体被膜を有
するガラス繊維コード。 ９、固体被膜を、固形分換算で、ガラス繊維に対し１０
〜３０重量％の量で有する請求項８記載のガラス繊維コ
ード。[Scope of Claims] 1. (A) (1) resorcinol-formaldehyde resin (2) butadiene-styrene-vinylpyridine-terpolymer (3) chlorosulfonated polyethylene, and (B) the above (1) ), (2), and (3) The above component (1) is 2 to 15% by weight based on the total solid content of components (2) and (3).
A liquid composition for impregnating glass fibers, wherein the component (2) is 15 to 80% by weight, and the component (3) is 15 to 70% by weight. 2. Dicarboxylated butadiene-styrene resin (4)
The composition according to claim 1, wherein is used in place of a part of the terpolymer of component (2). 3. The composition according to claim 1, wherein 10 to 90% of the amount of component (2) used is used in place of dicarboxylated butadiene-styrene resin (4). 4. The composition according to claim 1, wherein chloroprene rubber (5) is used in place of a part of the terpolymer of component (2). 5. The composition according to claim 1, wherein 10 to 90% of the amount of component (2) used is used in place of chloroprene rubber (5). 6. The composition according to claim 1, which is an aqueous latex having a solids content of 15 to 30% by weight. 7. A glass fiber cord having a coating of the liquid composition according to claim 1. 8. A glass fiber cord having a solid coating derived from the liquid composition according to claim 1. 9. The solid coating has a solid content of 10% compared to glass fiber.
9. The glass fiber cord of claim 8 having an amount of ˜30% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63211090A JPH01221433A (en) | 1987-09-07 | 1988-08-25 | Liquid composition for impregnating glass fiber |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62-222006 | 1987-09-07 | ||
| JP22200687 | 1987-09-07 | ||
| JP63211090A JPH01221433A (en) | 1987-09-07 | 1988-08-25 | Liquid composition for impregnating glass fiber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01221433A true JPH01221433A (en) | 1989-09-04 |
| JPH0456053B2 JPH0456053B2 (en) | 1992-09-07 |
Family
ID=26518430
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63211090A Granted JPH01221433A (en) | 1987-09-07 | 1988-08-25 | Liquid composition for impregnating glass fiber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01221433A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20000026308A (en) * | 1998-10-20 | 2000-05-15 | 구광시 | Adhesive composition for rubber reinforced fiber and dipped cord for reinforcing rubber and dipped cord cloth |
| US6262154B1 (en) | 1996-07-09 | 2001-07-17 | Nippon Sheet Glass Co., Ltd. | Treatment for rubber-reinforcing fibers, reinforcing fibers, and reinforced rubbers |
| US6664325B1 (en) | 1999-01-14 | 2003-12-16 | Nippon Sheet Glass Co., Ltd. | Fiber processing agent, reinforcing fiber processed by the fiber processing agent and rubber product reinforced by the reinforcing fiber |
| US6790901B2 (en) | 2000-02-15 | 2004-09-14 | Nippon Sheet Glass Co., Ltd. | Fiber-treating agent, glass fiber and rubber product both made with the fiber treating agent |
| US6929857B2 (en) | 2001-03-12 | 2005-08-16 | Honda Giken Kogyo Kabushiki Kaisha | Fiber for reinforcing rubber products |
| US7030182B2 (en) | 2002-03-14 | 2006-04-18 | Nippon Sheet Glass Company, Limited | Rubber-reinforcing glass fiber treatment agent, rubber-reinforcing cord using the fiber treatment agent, and rubber product |
| JP2007197553A (en) * | 2006-01-26 | 2007-08-09 | Central Glass Co Ltd | Coating liquid for glass fiber and rubber-reinforcing glass fiber using the same |
| JP2012066967A (en) * | 2010-09-24 | 2012-04-05 | Central Glass Co Ltd | Coating solution for covering glass fiber and rubber-reinforcing glass fiber using the same |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005009010A (en) * | 2003-06-18 | 2005-01-13 | Asahi Fiber Glass Co Ltd | Reinforcing fiber for rubber product |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS503184A (en) * | 1973-04-24 | 1975-01-14 | ||
| JPS5469192A (en) * | 1977-11-02 | 1979-06-02 | Owens Corning Fiberglass Corp | Impregnant of tire cord |
| JPS5973453A (en) * | 1982-10-20 | 1984-04-25 | Sumitomo Chem Co Ltd | Surface-treated reinforcing glass fiber |
| JPS61207442A (en) * | 1985-03-12 | 1986-09-13 | Nippon Zeon Co Ltd | Bonding between rubber compound and fiber |
-
1988
- 1988-08-25 JP JP63211090A patent/JPH01221433A/en active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS503184A (en) * | 1973-04-24 | 1975-01-14 | ||
| JPS5469192A (en) * | 1977-11-02 | 1979-06-02 | Owens Corning Fiberglass Corp | Impregnant of tire cord |
| JPS5973453A (en) * | 1982-10-20 | 1984-04-25 | Sumitomo Chem Co Ltd | Surface-treated reinforcing glass fiber |
| JPS61207442A (en) * | 1985-03-12 | 1986-09-13 | Nippon Zeon Co Ltd | Bonding between rubber compound and fiber |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6262154B1 (en) | 1996-07-09 | 2001-07-17 | Nippon Sheet Glass Co., Ltd. | Treatment for rubber-reinforcing fibers, reinforcing fibers, and reinforced rubbers |
| KR20000026308A (en) * | 1998-10-20 | 2000-05-15 | 구광시 | Adhesive composition for rubber reinforced fiber and dipped cord for reinforcing rubber and dipped cord cloth |
| US6664325B1 (en) | 1999-01-14 | 2003-12-16 | Nippon Sheet Glass Co., Ltd. | Fiber processing agent, reinforcing fiber processed by the fiber processing agent and rubber product reinforced by the reinforcing fiber |
| US6790901B2 (en) | 2000-02-15 | 2004-09-14 | Nippon Sheet Glass Co., Ltd. | Fiber-treating agent, glass fiber and rubber product both made with the fiber treating agent |
| US6929857B2 (en) | 2001-03-12 | 2005-08-16 | Honda Giken Kogyo Kabushiki Kaisha | Fiber for reinforcing rubber products |
| US7030182B2 (en) | 2002-03-14 | 2006-04-18 | Nippon Sheet Glass Company, Limited | Rubber-reinforcing glass fiber treatment agent, rubber-reinforcing cord using the fiber treatment agent, and rubber product |
| JP2007197553A (en) * | 2006-01-26 | 2007-08-09 | Central Glass Co Ltd | Coating liquid for glass fiber and rubber-reinforcing glass fiber using the same |
| JP2012066967A (en) * | 2010-09-24 | 2012-04-05 | Central Glass Co Ltd | Coating solution for covering glass fiber and rubber-reinforcing glass fiber using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0456053B2 (en) | 1992-09-07 |
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