JPH01220899A - Wave absorber and manufacture thereof - Google Patents

Wave absorber and manufacture thereof

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Publication number
JPH01220899A
JPH01220899A JP4720488A JP4720488A JPH01220899A JP H01220899 A JPH01220899 A JP H01220899A JP 4720488 A JP4720488 A JP 4720488A JP 4720488 A JP4720488 A JP 4720488A JP H01220899 A JPH01220899 A JP H01220899A
Authority
JP
Japan
Prior art keywords
granular
electromagnetic
oxide magnetic
wave absorber
magnetic material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP4720488A
Other languages
Japanese (ja)
Other versions
JP2618674B2 (en
Inventor
Kenichi Noda
健一 野田
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Individual
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Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP63047204A priority Critical patent/JP2618674B2/en
Publication of JPH01220899A publication Critical patent/JPH01220899A/en
Application granted granted Critical
Publication of JP2618674B2 publication Critical patent/JP2618674B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PURPOSE:To increase the absorbing power of electromagnetic waves, and to thin the thickness of a wave absorber by dispersing granular spheres, on the surfaces of which electromagnetic absorption layers composed of an oxide magnetic material such as ferrite are formed, into a molding base material. CONSTITUTION:A wave absorber 1 is shaped by dispersing granular spheres (x), on the surfaces of which electromagnetic absorption layers (y) consisting of an oxide magnetic material are formed, into a molding base material 2. When the granular sphere (x) is manufactured, a film made up of the oxide magnetic material 4 is shaped onto the surface of a granular carrier 3, such as cow powdered bones, cellulose, etc., the granular carrier 3 is heated and baked, a binder in the material 4 is burnt, and the sintered ferrite layer (the electromagnetic absorption layer (y)) is formed, thus manufacturing the granular sphere (x), an internal layer (z) of which is brought to a coarse state through the dehydration, carbonization, etc., of the granular carrier. Electromagnetic waves alpha projected to the granular sphere (x) repeat reflection in the electromagnetic absorption layer (y) composed of the oxide magnetic material by the relationship of the incident angle of the electromagnetic waves, and generate dielectric loss, attenuate and dissipate while being brought to the state in which they are confined in the layer.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 本発明は、電波暗室の構築等に使用される電波吸収体及
び、その製造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a radio wave absorber used for constructing an anechoic chamber, and a method for manufacturing the same.

〈従来技術〉 電波吸収体は、入射さ゛れた電波を吸収し、消失させる
ものであり、広い帯域の周波数を吸収するW形電波吸収
体にあっては、電波暗室の様に、アンテナ等の特性を調
べるために、外部からの電波を遮断して無響空間を構成
するための構造材として利用される。また、特定の周波
数のみを吸収するN形電波吸収体にあっては、建物によ
るTV電波の反射防止等に利用され、いずれも広い用途
を有する。
<Prior art> A radio wave absorber absorbs and eliminates incident radio waves.W-shaped radio wave absorbers that absorb a wide range of frequencies are designed to absorb the characteristics of antennas, etc., like an anechoic chamber. It is used as a structural material to create an anechoic space by blocking radio waves from outside to investigate Furthermore, N-type radio wave absorbers that absorb only specific frequencies are used to prevent the reflection of TV radio waves from buildings, and both have a wide range of uses.

これらの電波吸収体は、入射された電波に、導電損また
は磁性損を生じさせて、光エネルギーを熱エネルギーに
変換することにより、前記吸収能を達成するのであって
、導電損を生じさせる電波吸収体としてカーボンを成形
基材に混合したものがあり、また誘電損を生じさせるも
のとしてフェライト等の粉末を成形基材に混合したもの
等がある。
These radio wave absorbers achieve the above-mentioned absorption ability by causing conduction loss or magnetic loss in the incident radio waves and converting optical energy into thermal energy. As an absorber, carbon is mixed into a molded base material, and as a material that causes dielectric loss, a powder such as ferrite is mixed into a molded base material.

ところが、これらの電波吸収体は成形基材に混合して所
定形状とするものであるが、いずれも十分な吸収能を達
成してるとは言えない、また、従来の構成では2電磁波
は、その電波吸収体の内部を透過する行程で、熱エネル
ギーに変換され、消耗するものであり、吸収体の厚さd
は、電磁波の波長λとの関係を有し、従来はd/λを性
能指数とし、所定の性能を達成するためには、厚さdを
かなり厚くする必要があるとされてきた0例えば、無損
失材の表面に、カーボンシート等の抵抗膜を配設した構
成にあっては、理論上λ/4の厚さを要し、周波数f 
= 100MHzの電磁波を適用する場合には、75c
mもの厚さが必要となる。
However, these radio wave absorbers are mixed into a molded base material and shaped into a predetermined shape, but none of them can be said to have achieved sufficient absorption ability, and in the conventional configuration, two electromagnetic waves are In the process of passing through the inside of the radio wave absorber, it is converted into thermal energy and consumed, and the thickness of the absorber d
has a relationship with the wavelength λ of electromagnetic waves, and conventionally, d/λ has been used as a figure of merit, and in order to achieve a certain performance, it has been thought that the thickness d needs to be considerably thick.For example, In a configuration in which a resistive film such as a carbon sheet is provided on the surface of a lossless material, a thickness of λ/4 is theoretically required, and the frequency f
= 75c when applying 100MHz electromagnetic waves
A thickness of m is required.

本発明は、効率の良い電波吸収体を提供することを目的
とするものである。
An object of the present invention is to provide an efficient radio wave absorber.

〈課題を解決するための手段〉 本願の第一の発明は、表面にフェライト等の酸化物磁性
材料からなる電磁吸収層yが形成されてなる粗球Xを成
形基材内に分散させたことを特徴とする電波吸収体であ
る。
<Means for Solving the Problems> The first invention of the present application is that rough spheres X each having an electromagnetic absorption layer y formed of an oxide magnetic material such as ferrite on the surface thereof are dispersed in a molded base material. It is a radio wave absorber characterized by:

また、第二の発明は、この粗球Xを軽量とするための製
造方法であって、牛骨粉、セルロース等の粒状担持体の
表面に酸化物磁性材料からなる被膜を形成し、これを加
熱して焼成することにより軽量粒球Xを形成し、該軽量
粒球Xを成形基材内に分散させたことを特徴とするもの
である。
The second invention is a manufacturing method for making the rough spheres X lightweight, which involves forming a film made of an oxide magnetic material on the surface of a granular carrier such as beef bone powder or cellulose, and heating the film. It is characterized in that lightweight granules X are formed by firing and then dispersed within a molded base material.

く作用〉 吸収材内に入射した電磁波は、第1図に示すように、そ
の入射角が球面に対して所定以上であるもの(α、β)
は、粗球Xに入射する。または、粗球X表面で反射した
もの(γ)も、その反射波は、吸収材内で他の粗球Xに
衝突し、結局いづれかの粗球X内に入射することとなる
。そして粗球Xに入射した電磁波(α)は、その入射角
の関係で、酸化物磁性材料から成る電磁吸収層y内で反
射を繰り返して、層内に閉じ込められた状態となりなが
ら、誘電損を生じて減衰し消失する。または該電磁吸収
層yを透過した電磁波(β)も、内層Z内に入射し、該
内層Zと電磁吸収層yとの境界面内で反射を繰り返し、
電磁吸収層yに再入射する等し、結局同様に減衰するこ
ととなる。
As shown in Figure 1, the electromagnetic waves that have entered the absorbing material have an angle of incidence greater than a predetermined angle with respect to the spherical surface (α, β).
is incident on the coarse sphere X. Alternatively, the reflected wave (γ) reflected from the surface of the rough sphere X collides with other rough spheres X within the absorbing material, and eventually enters into one of the rough spheres X. Due to the angle of incidence, the electromagnetic wave (α) incident on the rough sphere It arises, decays, and disappears. Alternatively, the electromagnetic wave (β) that has passed through the electromagnetic absorption layer y also enters the inner layer Z and is repeatedly reflected within the interface between the inner layer Z and the electromagnetic absorption layer y,
The light re-enters the electromagnetic absorption layer y, and ends up being attenuated in the same way.

また、各粗球Xとの衝突と、その反射を繰り返すことに
より、電磁波の走行路が長くなる。この走行路は結局、
従来構成の吸収体の厚さdに相当することとなるから、
吸収体を厚くせずとも、十分な吸収能を達成できること
とを意味する。
Moreover, by repeating collision with each coarse ball X and its reflection, the travel path of the electromagnetic wave becomes longer. In the end, this route
Since it corresponds to the thickness d of the absorber of the conventional structure,
This means that sufficient absorption capacity can be achieved without increasing the thickness of the absorbent body.

さらにまた、前記粗球Xを製造するにあたって、牛骨粉
、セルロース等の粒状担持体の表面に酸化物磁性材料か
らなる被膜を形成し、これを加熱して焼成すると、粒状
相持体の脱水、炭化等により、内層Zが球状となり、該
粗球Xの重量の軽減化を図ることができる。このため、
該粗球を含有する吸収体の軽量化が達成される。
Furthermore, in producing the coarse spheres X, a film made of an oxide magnetic material is formed on the surface of a granular carrier such as bovine bone powder or cellulose, and when this is heated and fired, the granular carrier is dehydrated and carbonized. As a result, the inner layer Z becomes spherical, and the weight of the coarse spheres X can be reduced. For this reason,
The weight of the absorbent body containing the coarse spheres can be reduced.

〈実施例〉 第2図について本発明の一実施例を説明する。<Example> An embodiment of the invention will be described with reference to FIG.

本発明に係る電波吸収体lは、成形基材2内に、第1図
で既に示した酸化物磁性材料からなる電磁吸収層yが表
面に形成された直径3mm〜25a+mの粗球Xを分散
させてなるものである。
The radio wave absorber l according to the present invention has rough spheres X having a diameter of 3 mm to 25 a+m on whose surface an electromagnetic absorption layer y made of an oxide magnetic material already shown in FIG. 1 is dispersed in a molded base material 2. It is something that can be done.

前記粗球Xの製造方法の一例を第3図に従って説明する
An example of a method for manufacturing the coarse spheres X will be explained with reference to FIG. 3.

まず牛骨粉、セルロース等を糊、水等で練って粒状担持
体3を成形する(イ)。次に、フェライト粉にバインダ
ーを混入して粘度状にした材料4を貯留した槽5(ロ)
内に粒状担持体3を漬け、該粒状担持体3の表面に均一
に材料4を塗着形成する(ハ)、これを、炉6内で加熱
して、該担持体3を焼成して脱水炭化させ、かつ材料4
中のバインダーを焼失させて焼結フェライト層(酸化物
磁性材料からなる電磁吸収層y)を形成し、而して粗球
Xが製造される(二)。
First, beef bone powder, cellulose, etc. are kneaded with glue, water, etc. to form a granular carrier 3 (a). Next, a tank 5 (b) stores material 4 made by mixing ferrite powder with a binder to make it viscous.
The granular carrier 3 is soaked in the granular carrier 3, and the material 4 is uniformly coated on the surface of the granular carrier 3 (c). This is heated in the furnace 6 to bake the carrier 3 and dehydrate it. Carbonized and material 4
The binder inside is burnt off to form a sintered ferrite layer (electromagnetic absorption layer y made of oxide magnetic material), thus producing coarse spheres X (2).

かかる構成の粗球Xにあっては、内層2は相持体3の材
質により、前記焼成により内空状となるか、または空隙
率の高い球状となって、その軽量化が実現できる。
In the coarse spheres X having such a structure, the inner layer 2 becomes hollow or has a spherical shape with high porosity due to the firing, depending on the material of the supporting body 3, so that its weight can be reduced.

尚、内層2は内実状としても良(、この場合に電波吸収
能を有するカーボン、フェライト粉を混入した担持材に
よって構成することもできる。
The inner layer 2 may be formed as a solid material (in this case, the inner layer 2 may be made of a supporting material mixed with carbon or ferrite powder having radio wave absorbing ability).

この粗球Xを、砂利、砂、及び有機バインダーからなる
成形基材2内に分散混合し、板状等に成形し、その乾燥
凝固によって電波吸収体lが形成される。
The coarse spheres X are dispersed and mixed in a molding base material 2 made of gravel, sand, and an organic binder, molded into a plate shape, etc., and the radio wave absorber 1 is formed by drying and coagulating.

かかる構成にあって、電波吸収体1に入射した電磁波は
、各粗球Xに入射し、酸化物磁性材料層からなる電磁吸
収層y内で反射を繰り返して、層内に閉じ込められなが
ら、誘電損を生じて減衰消失するか、該材料層を透過し
て、内層Z内で反射を繰り返し、表層の電磁吸収層y内
に再入射する等の経路を経て、結局同様に消失すること
となる。
With such a configuration, the electromagnetic waves incident on the radio wave absorber 1 are incident on each coarse sphere X, are repeatedly reflected within the electromagnetic absorption layer y made of an oxide magnetic material layer, and are confined within the layer while dielectric Either it causes loss and attenuates and disappears, or it passes through the material layer, is repeatedly reflected within the inner layer Z, and re-enters the surface electromagnetic absorption layer y, and eventually disappears in the same way. .

また電波吸収体1の裏面には第2図のように、鉄板、銅
板または導電性ゴムシート等の導電板lOを裏打ちする
ことにより、電磁シールドがなされ得る。
Further, as shown in FIG. 2, the back surface of the radio wave absorber 1 can be provided with an electromagnetic shield by lining it with a conductive plate lO such as an iron plate, a copper plate, or a conductive rubber sheet.

前記成形基材2としては、合成樹脂材料、天然ゴム、合
成ゴム等も用いられ得る。
As the molded base material 2, synthetic resin materials, natural rubber, synthetic rubber, etc. may also be used.

前記粗球Xは、内層Zとなる担持材の表面に、ゴムフェ
ライトからなる電磁吸収体yを形成することにより構成
しても良い。該ゴムフェライトは、焼結フェライトとは
異なり、2G11z〜5GHzの周波数帯域の電磁波を
吸収し得る能力が知られており、この材料選定により、
次記する粗球Xの粒径の選定と共に、用途に応じた特性
を達成し得ることとなる。
The rough spheres X may be constructed by forming an electromagnetic absorber y made of rubber ferrite on the surface of a supporting material that becomes the inner layer Z. Unlike sintered ferrite, rubber ferrite is known to have the ability to absorb electromagnetic waves in the frequency band of 2G11z to 5GHz, and by selecting this material,
By selecting the particle size of the coarse spheres X as described below, it is possible to achieve characteristics according to the intended use.

前記粗球Xの直径により、吸収可能な電磁波の周波数が
変化することが認められる。このため、電波暗室、電波
つい立て等の材料として用いるために広い帯域の周波数
を吸収するもの(W形電波吸収体)を形成する場合には
、種々の径の粗球Xを成形基材2内に混合分散させれば
よい、また、特定の周波数のみを吸収するために用いる
もの(N形電波吸収体)を形成する場合には、所定の径
の粗球Xのみを混合分散させれば良い。すなわち1粒球
Xの径を選定することにより、適用可能な周波数帯域幅
を設定することができ、W形電波吸収体、N形電波吸収
体のいずれをも形成することができて、用途に応じた特
性を容易に生じさせることができる。
It is recognized that the frequency of electromagnetic waves that can be absorbed changes depending on the diameter of the rough sphere X. Therefore, when forming something that absorbs a wide range of frequencies (W-shaped radio wave absorber) for use as a material for radio anechoic chambers, radio wave stations, etc., coarse spheres X of various diameters are placed on the molded base material 2 Also, when forming something used to absorb only a specific frequency (N-type radio wave absorber), it is sufficient to mix and disperse only the coarse spheres X with a predetermined diameter. good. In other words, by selecting the diameter of a single sphere Accordingly, the corresponding characteristics can be easily generated.

また前記構成にあって、成形基材2の一成分としてカー
ボン、フェライト等の粉末を混入すると、電波は、各粉
末との衝突により、誘電損または誘電損を生じて、その
減衰がさらに効率的になされることとなる。
Furthermore, in the above structure, if powders such as carbon or ferrite are mixed as a component of the molding base material 2, the radio waves will collide with each powder, causing dielectric loss or dielectric loss, and the attenuation will be made more efficient. It will be done.

〈発明の効果〉 本発明は、上述の様に、成形基材2内に、電磁吸収層y
が表層に形成された粗球Xを分散して。
<Effects of the Invention> As described above, the present invention provides an electromagnetic absorption layer y in the molded base material 2.
disperses the coarse spheres X formed on the surface layer.

電波吸収体lを構成したものであるから、電磁波は、粗
球X内に入射し、その電磁吸収層y内で、反射を繰り返
して減衰するとともに、その行路を長くすることができ
る。このため、電磁波の吸収能が飛躍的に向上し、電波
吸収体1の薄厚化を実現できる。また粗球Xの径を選定
したり、または複数の径の粗球Xを混在させる等により
、用途に応じた特性を生じさせることができ、高層建物
の側壁に使用して、テレビ電波の反射による受信障害を
防ぐ等、その利用分野が拡大する。
Since the radio wave absorber 1 is configured, the electromagnetic wave enters the coarse sphere X, is repeatedly reflected within the electromagnetic absorption layer y, and is attenuated, and its path can be lengthened. Therefore, the ability to absorb electromagnetic waves is dramatically improved, and the thickness of the radio wave absorber 1 can be reduced. In addition, by selecting the diameter of the rough spheres X or mixing coarse spheres The fields of its use will expand, such as preventing reception interference due to

また、粒状担持体の表面に酸化物磁性材料からなる被膜
を形成し、これを加熱して焼成した粗球は軽量となり、
前記粗球を備えた吸収体にあって、その軽量化を図るこ
とができる6 等の優れた効果がある。
In addition, by forming a coating made of oxide magnetic material on the surface of the granular carrier and heating and firing it, the coarse spheres become lightweight.
The absorbent body equipped with the coarse spheres has the following excellent effects, such as being able to reduce its weight.

【図面の簡単な説明】[Brief explanation of the drawing]

添付図面は本発明の実施例を示し、第1図は粗球Xの作
用を示す説明図、第2図は電波吸収体の一例を示す縦断
側面図、第3図は軽量粒球Xの製造工程を示す説明図で
ある。 l・・・電波液吸収体 2・・・成形基材 3・・・粒状担持体 lO・・・導電板 X・・・粗球 y・・・電磁吸収層 Z−・・内層葛1
8 富20 昂30 ↓ 手続補正書 昭和63年9月19日 2、発明の名称 電波吸収体及び、その製造方法 3、補正をする者 事件との関係  出願人 住所 名古屋市瑞穂区関取町4番地 氏名  野  1) 健  − 4、代理人 〒460 住所 名古屋市中区千代田3丁目11番11号ノ ロ、補正の対象  明細書 7、補正の内容 明細書第7頁第1O行と第11行との間に次の文「 ま
た成形基材2としては1発泡ウレタン樹脂等の発泡プラ
スチック材料を用いても良い。 この材料にあっては、電波吸収体lの軽量化を実現でき
ると共に、前記導電板10を一方の型板に代用して成形
することにより、接着剤を要することなく該導電板10
との接合が可能となる利点がある。」 以上
The attached drawings show embodiments of the present invention; FIG. 1 is an explanatory diagram showing the action of the coarse spheres X, FIG. 2 is a vertical side view showing an example of a radio wave absorber, and FIG. It is an explanatory diagram showing a process. l... Radio wave liquid absorber 2... Molded base material 3... Granular support lO... Conductive plate X... Rough sphere y... Electromagnetic absorption layer Z-... Inner layer kudzu 1
8 Tomi 20 Kou 30 ↓ Procedural amendment September 19, 1988 2. Name of the invention: Radio wave absorber and its manufacturing method 3. Person making the amendment Relationship with the case Applicant address: 4, Sekitori-cho, Mizuho-ku, Nagoya City Name No 1) Ken - 4, Agent 460 Address Noro 3-11-11 Chiyoda, Naka-ku, Nagoya Subject of amendment Specification 7, Contents of amendment Page 7 Lines 1O and 11 In between, there is the following sentence: "Also, a foamed plastic material such as foamed urethane resin may be used as the molding base material 2. With this material, the weight of the radio wave absorber l can be reduced, and the conductive plate By molding the conductive plate 10 by replacing it with one of the templates, the conductive plate 10 can be formed without using an adhesive.
This has the advantage that it can be bonded to "that's all

Claims (1)

【特許請求の範囲】 1)表面に酸化物磁性材料からなる電磁吸収層が形成さ
れてなる粒球を成形基材内に分散させたことを特徴とす
る電波吸収体。 2)粒状担持体の表面に酸化物磁性材料からなる被膜を
形成し、これを加熱して焼成することにより軽量粒球を
形成し、該軽量粒球を成形基材内に分散させたことを特
徴とする電波吸収体の製造方法。
[Scope of Claims] 1) A radio wave absorber characterized in that particles having an electromagnetic absorption layer made of an oxide magnetic material formed on the surface thereof are dispersed in a molded base material. 2) A film made of an oxide magnetic material is formed on the surface of a granular support, and this is heated and fired to form lightweight granules, and the lightweight granules are dispersed within a molding base material. A method for producing a characteristic radio wave absorber.
JP63047204A 1988-02-29 1988-02-29 Manufacturing method of radio wave absorber Expired - Fee Related JP2618674B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03165599A (en) * 1989-11-24 1991-07-17 Kenichi Noda Radio wave absorbent material, manufacture thereof, and radio wave absorbing board formed thereof
EP0479438A2 (en) * 1990-10-02 1992-04-08 Minnesota Mining And Manufacturing Company Electromagnetic radiation absorbing material employing doubly layered particles
US5389434A (en) * 1990-10-02 1995-02-14 Minnesota Mining And Manufacturing Company Electromagnetic radiation absorbing material employing doubly layered particles
JP2007036081A (en) * 2005-07-29 2007-02-08 Ritsuken Gen Microwave-absorbing film structure and its manufacturing method
JP2007142369A (en) * 2005-10-17 2007-06-07 Noc:Kk Electromagnetic wave absorbing material and electromagnetic wave absorbing powder
US8138959B2 (en) * 2006-10-19 2012-03-20 Hitachi Metals, Ltd. Radio wave absorption material and radio wave absorber
CN103785362A (en) * 2014-02-13 2014-05-14 中国科学院化学研究所 Magnetic porous cellulose sphere adsorbent and preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS49121999A (en) * 1973-04-02 1974-11-21
JPS60130698U (en) * 1984-02-13 1985-09-02 塚本 健吉 Ferra for radio wave absorbing material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS49121999A (en) * 1973-04-02 1974-11-21
JPS60130698U (en) * 1984-02-13 1985-09-02 塚本 健吉 Ferra for radio wave absorbing material

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03165599A (en) * 1989-11-24 1991-07-17 Kenichi Noda Radio wave absorbent material, manufacture thereof, and radio wave absorbing board formed thereof
EP0479438A2 (en) * 1990-10-02 1992-04-08 Minnesota Mining And Manufacturing Company Electromagnetic radiation absorbing material employing doubly layered particles
US5389434A (en) * 1990-10-02 1995-02-14 Minnesota Mining And Manufacturing Company Electromagnetic radiation absorbing material employing doubly layered particles
JP2007036081A (en) * 2005-07-29 2007-02-08 Ritsuken Gen Microwave-absorbing film structure and its manufacturing method
JP2007142369A (en) * 2005-10-17 2007-06-07 Noc:Kk Electromagnetic wave absorbing material and electromagnetic wave absorbing powder
JP4620645B2 (en) * 2005-10-17 2011-01-26 株式会社 エヌ・オー・シー Manufacturing method of electromagnetic wave absorber
US8138959B2 (en) * 2006-10-19 2012-03-20 Hitachi Metals, Ltd. Radio wave absorption material and radio wave absorber
CN103785362A (en) * 2014-02-13 2014-05-14 中国科学院化学研究所 Magnetic porous cellulose sphere adsorbent and preparation method and application thereof

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