JPH01203036A - Emulsion composition and emulsion cosmetic - Google Patents

Emulsion composition and emulsion cosmetic

Info

Publication number
JPH01203036A
JPH01203036A JP63028543A JP2854388A JPH01203036A JP H01203036 A JPH01203036 A JP H01203036A JP 63028543 A JP63028543 A JP 63028543A JP 2854388 A JP2854388 A JP 2854388A JP H01203036 A JPH01203036 A JP H01203036A
Authority
JP
Japan
Prior art keywords
oil
composition
emulsion composition
polyhydric alcohol
emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP63028543A
Other languages
Japanese (ja)
Other versions
JP2652395B2 (en
Inventor
Shinji Tobe
信治 戸辺
Takashi Ikeda
隆 池田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shiseido Co Ltd
Original Assignee
Shiseido Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shiseido Co Ltd filed Critical Shiseido Co Ltd
Priority to JP63028543A priority Critical patent/JP2652395B2/en
Publication of JPH01203036A publication Critical patent/JPH01203036A/en
Application granted granted Critical
Publication of JP2652395B2 publication Critical patent/JP2652395B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/062—Oil-in-water emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin

Abstract

PURPOSE:To increase mechanical strength by projecting light to monomolecular cumulative film which consists of an organic compound containing a specific hydrophilic group and a hydrophobic group, both formed on a hydrophilic substrate in the same molecule and thereby chemically binding the layers. CONSTITUTION:An emulsified composition is prepared by blending at least, one or two kinds of surfactant selected based on alkylglycosid which is expressed by formula I (R is a straight-chain or branched saturated alkyl group with 8-24 carbon atoms and an unsaturated alkenyl group, X is an integer of 1-15), polyhydric alcohol with at least 3, hydroxyl groups in a molecule and an oil component. Oil-in-water type emulsion composition is prepared by blending the above-mentioned emulsion composition to a water composition. The preferable dose of alkylglycosid of the formula I to be blended to the emulsion composition is 0.1-10wt.%, and the blending weight of polyhydric alcohol is 1-1,000 times that of alkylglycosid.

Description

【発明の詳細な説明】 ［産業上の利用分野］ 本発明は乳化組成物及び乳化化粧料、特に乳化剤として
アルキルグリコシドを用いたものに間するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to emulsified compositions and emulsified cosmetics, particularly those using alkyl glycosides as emulsifiers.

［従来の技術］ 一般に化粧料などに用いられている界面活性剤は、陰イ
オン性、陽イオン性などのイオン性界面活性剤、両性界
面活性剤、非イオン性界面活性剤などに分類される。[Prior art] Surfactants generally used in cosmetics are classified into ionic surfactants such as anionic and cationic surfactants, amphoteric surfactants, nonionic surfactants, etc. .

これらの中で、皮膚刺激性は非イオン性界面活性剤が最
も低いといわれており、化粧料あるいは医薬品基剤に多
用されているが、それでも人によっては皮膚に対して刺
激を感じるなどの問題を生じる場合もある。Among these, nonionic surfactants are said to have the lowest skin irritation and are often used in cosmetics and pharmaceutical bases, but they still cause problems such as irritation to the skin for some people. may occur.

従って、最近ではエチレンオキシド鎖を用いていない非
イオン性界面活性剤の開発が切望されている。Therefore, there has recently been a strong desire to develop nonionic surfactants that do not use ethylene oxide chains.

従来、このような非イオン性界面活性剤として、ショ糖
脂肪酸エステルを用いた報告例もある（特開昭５６−５
５３０６号）。Conventionally, there have been reports using sucrose fatty acid esters as such nonionic surfactants (Japanese Patent Laid-Open No. 56-5
No. 5306).

［発明が解決しようとする課題］ ／　　　　−、ｊ３ しかしながら、前述したショ糖脂肪酸エステルを用いた
例でも、当該ショ糖脂肪酸エステルに加えて他の非イオ
ン性界面活性剤を併用しないと安定性の良好な乳化組成
物が得られないという問題点があった。[Problem to be solved by the invention] / -, j3 However, even in the example using the sucrose fatty acid ester described above, the stability cannot be improved unless other nonionic surfactants are used in addition to the sucrose fatty acid ester. There was a problem that a good emulsified composition could not be obtained.

発■旦且狛 本発明は前期従来技術の課題に鑑みなされたものであり
、その目的は乳化安定性が良好でしかも使用性に優れて
いる乳化組成物及び乳化化粧料を提供することにある。The present invention was made in view of the problems of the prior art, and its purpose is to provide emulsified compositions and emulsified cosmetics that have good emulsion stability and are easy to use. .

［課題を解決するための手段］ 本発明者らは、前期目的を達成するため鋭意検討した結
果、アルキルグリコシドを乳化剤として用いると、前述
したような皮膚刺激性が低く、少量の使用でも乳化安定
性が良好でかつ使用性に優れた乳化組成物が得られるこ
とを見いだし、本発明を完成するに至った。[Means for Solving the Problems] As a result of intensive studies to achieve the above object, the present inventors found that when alkyl glycosides are used as emulsifiers, the skin irritation described above is low and emulsions are stable even when used in small amounts. It was discovered that an emulsified composition with good properties and excellent usability can be obtained, and the present invention was completed.

すなわち、本発明にかかる乳化組成物は、下記一般式（
Ｉ）で表されるアルキルグリコシドから選ばれる一種ま
たは二種以上の界面活性剤と、分子内に３個以上の水酸
基を有する多価アルコールと、油相成分と、を含む。That is, the emulsified composition according to the present invention has the following general formula (
It contains one or more surfactants selected from the alkyl glycosides represented by I), a polyhydric alcohol having three or more hydroxyl groups in the molecule, and an oil phase component.

（式中Ｒは、炭素数８〜２４の直鎖及び／または分岐の
飽和アルキル基または不飽和アルケニル基を、Ｘは１〜
１５の整数を表す。） そして、この乳化組成物は、透明もしくは半透明の粘稠
液体またはゲルである。(In the formula, R is a linear and/or branched saturated alkyl group or unsaturated alkenyl group having 8 to 24 carbon atoms, and X is 1 to 24 carbon atoms.
Represents an integer of 15. ) This emulsified composition is a transparent or translucent viscous liquid or gel.

また、前記乳化組成物と水相成分からなる水中油型乳化
組成物は、乳白色の微粒粒子のエマルジョンである。Further, the oil-in-water emulsion composition comprising the emulsion composition and an aqueous phase component is an emulsion of milky white fine particles.

以下、本発明について詳述する。The present invention will be explained in detail below.

本発明に用いる非イオン性界面活性剤であるアルキルグ
リコシドは、前記一般式（Ｉ）で示される炭素数８〜２
４の直鎖及び／または分岐の飽和アルキル基または不飽
和アルケニル基（Ｒ）を有するものであり、それらは単
独でも、あるいは混合物としても用いられる。The alkyl glycoside which is the nonionic surfactant used in the present invention has 8 to 2 carbon atoms represented by the general formula (I).
It has 4 linear and/or branched saturated alkyl groups or unsaturated alkenyl groups (R), and they can be used alone or as a mixture.

アルキルグリコシドの配合量は、前記請求項１記載の乳
化組成物全量中の０．　１〜１０重量％（以下％と略す
）、好ましくは乳化安定性、べた付きなどの使用性を考
慮して０．５〜５％である。The amount of the alkyl glycoside to be blended is 0.0000000000000000000 in the total amount of the emulsified composition according to claim 1. It is 1 to 10% by weight (hereinafter abbreviated as %), preferably 0.5 to 5% in consideration of usability such as emulsion stability and stickiness.

本発明に用いられる、分子内に３個以上の水酸基を有す
る多価アルコールとしては、グリセリン、ジグリセリン
、トリグリセリン、テトラグリセリン、ペンタグリセリ
ン、ヘキサグリセリン等のポリグリセリン、トリメチロ
ールエタン、トリメチロールプロパン、エリスリトール
、ペンタエリスリトール、グルコース、ソルビタン、ソ
ルビトール、マルチトール、シュクロース、ラフィノー
ス、トレハロース等であり、一種または二種以上を組み
合わせて用いる。特に好ましいのはグリセリン、ジグリ
セリン、トリグリセリン、ソルビトール、マルチトール
である。Examples of the polyhydric alcohol having three or more hydroxyl groups in the molecule used in the present invention include polyglycerin such as glycerin, diglycerin, triglycerin, tetraglycerin, pentaglycerin, and hexaglycerin, trimethylolethane, and trimethylolpropane. , erythritol, pentaerythritol, glucose, sorbitan, sorbitol, maltitol, sucrose, raffinose, trehalose, etc., and they are used alone or in combination of two or more. Particularly preferred are glycerin, diglycerin, triglycerin, sorbitol, and maltitol.

分子内に３個以上の水酸基を有する多価アルコールの配
合量は、アルキルグリコシドに対し重潰比で１〜１００
０倍の範囲である。多価アルコールの配合量がアルキル
グリコシドに対しｌ未満であるとアルキルグリコシドの
溶解性が悪くなり、１０００を越えると乳化安定性が悪
くなる。The blending amount of the polyhydric alcohol having three or more hydroxyl groups in the molecule is 1 to 100 in weight ratio to the alkyl glycoside.
It is in the range of 0 times. If the amount of polyhydric alcohol is less than 1 to alkyl glycoside, the solubility of the alkyl glycoside will be poor, and if it exceeds 1,000, emulsion stability will be poor.

本発明に用いられる油相成分としては、流動パラフィン
、スクワラン、ワセリン、マイクロクリスタリンワック
スなどの炭化水素類、イソプロピルミリステート、セチ
ル−２−エチルヘキサノエート、グリセリル−トリー２
−エチルヘキサノエート、ビタミンＥアセテート、ビタ
ミンＡパルミテート、ビタミンＣステアレート、ビタミ
ンＣサルフェート等のエステル油類、ミツ蝋、鯨蝋等の
ロウ類、アボカド油、ツバキ油、マカデミアナツツ油、
アーモンド油、米ヌカ油、オリーブ油、ヒマシ油、ナタ
ネ油、サフラワー油、トウモロコシ油、小麦胚芽油、大
豆油、綿実油、茶実油、ホホバ油等の植物性油類、ター
ドル油、ミンク油、卵黄油等の動物性油類、セタノール
、ステアリルアルコール、オレイルアルコール、オクチ
ルドデカノール、ベヘニルアルコールなどの高級アルコ
ール類、ラウリン酸、ミリスチン酸、パルミチン酸、ス
テアリン酸、オレイン酸、リノール酸、リルイン酸、リ
シノール酸、イソステアリン酸などの高級脂肪酸類、ジ
メチルシリコーン、メチルフェニルシリコーン、環状シ
リコーン等のシリコーン油類、その他のシリコーン樹脂
、高分子量シリコーンなどの、通常化粧料、医薬品基剤
に用いられる油分であって、これらの中から一種または
二種以上を組み合わせて用いる。なお、このような油相
成分に対してアルキルグリコシドと分子内に３個以上の
水酸基を有する多価アルコールとの合計量は、乳化安定
性を図る上から、２０％以上となるように調製すること
が好ましい。The oil phase components used in the present invention include hydrocarbons such as liquid paraffin, squalane, petrolatum, and microcrystalline wax, isopropyl myristate, cetyl-2-ethylhexanoate, and glyceryl tri-2
- Ester oils such as ethylhexanoate, vitamin E acetate, vitamin A palmitate, vitamin C stearate, vitamin C sulfate, waxes such as beeswax and spermaceti, avocado oil, camellia oil, macadamia nut oil,
Vegetable oils such as almond oil, rice bran oil, olive oil, castor oil, rapeseed oil, safflower oil, corn oil, wheat germ oil, soybean oil, cottonseed oil, teaseed oil, jojoba oil, turdle oil, mink oil, Animal oils such as egg yolk oil, higher alcohols such as cetanol, stearyl alcohol, oleyl alcohol, octyldodecanol, behenyl alcohol, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, liluic acid, ricinol Oils normally used in cosmetics and pharmaceutical bases, such as acids, higher fatty acids such as isostearic acid, silicone oils such as dimethyl silicone, methylphenyl silicone, and cyclic silicone, other silicone resins, and high molecular weight silicones. , one or a combination of two or more of these may be used. In addition, the total amount of alkyl glycoside and polyhydric alcohol having 3 or more hydroxyl groups in the molecule is adjusted to be 20% or more with respect to such oil phase components in order to ensure emulsion stability. It is preferable.

本発明にかかる乳化組成物には、前記必須成分の他に使
用目的により陰イオン性、陽イオン性などのイオン性界
面活性剤、両性活性剤、非イオン性活性剤、レシチン、
カゼインナトリウム、サポニン等の合成または天然界面
活性剤、薬剤、紫外線吸収剤、防腐剤、酸化防止剤、ア
ルコール、色素、香料などを添加してもよい。In addition to the above-mentioned essential components, the emulsified composition according to the present invention may include ionic surfactants such as anionic and cationic surfactants, amphoteric surfactants, nonionic surfactants, lecithin,
Synthetic or natural surfactants such as sodium caseinate and saponin, drugs, ultraviolet absorbers, preservatives, antioxidants, alcohols, pigments, fragrances, and the like may be added.

このようにして得られた乳化組成物は、均一な透明もし
くは半透明の粘稠液体またはゲルであり、サンケアゼリ
ー、美容ゼリー、マツサージゼリー、薬用ゼリーなどの
乳化化粧料に使用することができる。The emulsified composition thus obtained is a uniform transparent or translucent viscous liquid or gel, and can be used in emulsified cosmetics such as sun care jelly, beauty jelly, pine surgery jelly, and medicated jelly.

また、請求項２に記載された水中油型乳化組成物を得る
には前述した乳化組成物と水相成分（水）とを混合すれ
ばよい。Moreover, in order to obtain the oil-in-water emulsion composition described in claim 2, the above-mentioned emulsion composition and an aqueous phase component (water) may be mixed.

水には保湿剤、薬剤、防腐剤、高分子物質、顔料、分散
剤、金属イオン封鎖剤、低級アルコール、生薬抽出物、
ムコ多糖類、アミノ酸、色素など、通常化粧料、医薬品
基剤に用いられる成分を溶解、分散して用いてもよい。Water includes humectants, drugs, preservatives, polymer substances, pigments, dispersants, sequestering agents, lower alcohols, crude drug extracts,
Ingredients commonly used in cosmetics and pharmaceutical bases, such as mucopolysaccharides, amino acids, and pigments, may be dissolved or dispersed.

前記乳化組成物と水との量的関係については極めて広範
囲に選択できるが、乳化組成物０．５〜８０％に対して
水相成分９９．５％〜２０％である。The quantitative relationship between the emulsified composition and water can be selected from a very wide range, but the aqueous phase component should be 99.5% to 20% with respect to 0.5 to 80% of the emulsified composition.

ここに得られた水中油型乳化組成物は、均一な微細粒子
を分散した乳白色の粘稠または低粘性の液体であり、乳
液、クリーム、ファンデーション、アクネクリーム等に
使用することができる。The oil-in-water emulsion composition obtained here is a milky white viscous or low-viscosity liquid in which uniform fine particles are dispersed, and can be used in milky lotions, creams, foundations, acne creams, etc.

［実施例］ 以下、本発明を実施例及び比較例によってさらに詳細に
説明する。[Examples] Hereinafter, the present invention will be explained in more detail by Examples and Comparative Examples.

なお、本発明はこれにより限定されるものではない。Note that the present invention is not limited to this.

＋＋ 第１表 調整法 多価アルコールにアルキルグリコシドな室温下で均一に
溶解した後、ホモミキサー処理しなから油相成分を徐々
に添加する。++ Table 1 Preparation method After uniformly dissolving the alkyl glycoside in polyhydric alcohol at room temperature, the oil phase components are gradually added without homomixer treatment.

比較結果 前記第１表に示すように、各実施例と比較例を比べるこ
とにより、各実施例の乳化組成物の乳化安定性がきわめ
てよいことが理解される。Comparison Results As shown in Table 1 above, by comparing each Example and Comparative Example, it can be seen that the emulsion stability of the emulsion composition of each Example is extremely good.

第２表 調整法 精製水に所定量の乳化組成物を攪拌しながら徐々に添加
する。Table 2 Preparation method A predetermined amount of the emulsion composition is gradually added to purified water while stirring.

比較結果 前記第２表より、実施例１の乳化組成物と精製水の割合
は、乳化組成物が１０％以上できわめて良好であること
が理解される。Comparison Results From Table 2 above, it is understood that the ratio of the emulsified composition and purified water of Example 1 is very good when the emulsified composition is 10% or more.

裏血溺ｌ　美容ゼリー スクワラン　　　　　　　　　　　３０．０％ホホバ油
　　　　　　　　　　　　２０．０ビタミンＥアセテー
ト　　　　　　　０．　５香料　　　　　　　　　　　
　　　適量色素　　　　　　　　　　　　　　適量アル
キルグリコシド　　　　　　　　２．０（Ｒは炭素数１
２の直鎖アルキル基　ｘ＝１）グリセリン　　　　　　
　　　　２０．０マルチトール（７０％液）　　　　　
２７．３ヒアルロン酸ナトリウム　　　　　　０．２以
上のように配合した美容ゼリーを使用した結果、本来の
機能を損なうことがなく、また乳化安定性もきわめて良
好であった。Ura-ketsudori Beauty Jelly Squalane 30.0% Jojoba Oil 20.0 Vitamin E Acetate 0. 5 fragrances
Appropriate amount of dye Appropriate amount of alkyl glycoside 2.0 (R is 1 carbon number
2 straight chain alkyl group x=1) glycerin
20.0 Maltitol (70% liquid)
27.3 Sodium Hyaluronate As a result of using the cosmetic jelly formulated as above, the original function was not impaired and the emulsion stability was also extremely good.

そして、パネル試験の結果によっても、何等肌に異常な
刺激を感じる者がなかった。Also, according to the results of the panel test, no one felt any abnormal irritation to their skin.

爽血止１　サンケアクリーム 流動パラフィン　　　　　　　　　２０．０％スクワラ
ン　　　　　　　　　　　１０．０ワセリン　　　　　
　　　　　　　　　５・　０ビタミンＥアセテート　　
　　　　　０．５香料　　　　　　　　　　　　　　　
適量２−エチルへキシル−ｐ− ジメチルアミノベンゾエート　　　２．０４−ｔ−ブチ
ル−４２− メトキシジベンゾイルメタン　　　２．０アルキルグリ
コシド　　　　　　　　３．０（Ｒは炭素数１６の直鎖
アルキル基、ｘ＝８）精製水　　　　　　　　　　　　
　５５．２７カルボキシメチルセルロース　　　　０．
２二酸化チタン　　　　　　　　　　　２・　０（最大
粒径０．　１μ以下で、 平均粒径１０〜４０ｍμ） 分散剤　　　　　　　　　　　　　　適量以上のように
配合したサンケアクリームを使用した結果でも、本来の
機能を損なうことがなく、また乳化安定性もきわめて良
好であった。Refreshing Blood Stop 1 Sun Care Cream Liquid Paraffin 20.0% Squalane 10.0 Vaseline
5.0 vitamin E acetate
0.5 fragrance
Appropriate amount 2-ethylhexyl-p-dimethylaminobenzoate 2.04-t-butyl-42-methoxydibenzoylmethane 2.0 Alkyl glycoside 3.0 (R is a straight chain alkyl group with 16 carbon atoms, x = 8) purified water
55.27 Carboxymethylcellulose 0.
Titanium dioxide 2.0 (maximum particle size 0.1μ or less, average particle size 10-40mμ) Dispersant Even if a sun care cream is used in an appropriate amount or more, it does not impair its original function, and The emulsion stability was also very good.

そして、パネル試験の結果によっても何等肌に異常な刺
激を感しる者がなかった。Also, according to the results of the panel test, no one felt any abnormal irritation to their skin.

爽胤且且　ファンデーション 流動パラフィン　　　　　　　　　２０．０％セチル−
２−エチル ヘキサノニー）　　　　　　　　　　１０．０ワセリン
　　　　　　　　　　　　　２．０香料　　　　　　　
　　　　　　　適量アルキルグリコシド　　　　　　　
　４．０（Ｒは炭素数１２の直鎖アルキル基、ｘ＝６）
バラオキシ安息香酸メチル　　　　　０．２酸化チタン
　　　　　　　　　　　１５．０カオリン　　　　　　
　　　　　　　５．０タルク　　　　　　　　　　　　
　　　３．０着色顔料　　　　　　　　　　　　　　ｉ
、　　。Sotan and Foundation Liquid Paraffin 20.0% Cetyl-
2-ethylhexanony) 10.0 Vaseline 2.0 Fragrance
Appropriate amount of alkyl glycoside
4.0 (R is a straight chain alkyl group having 12 carbon atoms, x=6)
Methyl roseoxybenzoate 0.2 titanium oxide 15.0 kaolin
5.0 talc
3.0 colored pigment i
, .

分散剤　　　　　　　　　　　　　適量グリセリン　　
　　　　　　　　　８．０Ｍ製水　　　　　　　　　　
　　　３３．８以上のように配合したファンデーション
によっても、本来の機能を損なうことがなく、また乳化
安定性もきわめて良好であった。Dispersant: Appropriate amount of glycerin
8.0M water
Even with the foundation formulated as above in 33.8, the original function was not impaired and the emulsion stability was also extremely good.

そして、パネル試験の結果によっても何等肌に異常な刺
激を感じる者がなかった。Also, according to the results of the panel test, no one felt any abnormal irritation to their skin.

［発明の効果］ 本発明は以上のように構成されているので、次のような
効果を奏する。[Effects of the Invention] Since the present invention is configured as described above, the following effects are achieved.

請求項１に記載の乳化組成物によれば、アルキルグリコ
シドと多価アルコールを含むので、乳化安定性及び使用
性が良好な乳化組成物を得ることができる。According to the emulsion composition according to claim 1, since the emulsion composition contains an alkyl glycoside and a polyhydric alcohol, an emulsion composition having good emulsion stability and usability can be obtained.

請求項２に記載の水中油型乳化組成物によれば、請求項
１に記載の乳化組成物を用いて水中油型としているので
、同様に乳化安定性が良好で使用性が良好な水中油型乳
化組成物を得ることができる。According to the oil-in-water emulsion composition according to claim 2, since the emulsion composition according to claim 1 is used to form an oil-in-water type, the oil-in-water emulsion composition also has good emulsion stability and good usability. A type emulsion composition can be obtained.

請求項３に記載の乳化化粧料によれば、請求項１に記載
の乳化組成物を用いているので、安定性がよく、しかも
皮膚刺激性を少なくすることができる。According to the emulsified cosmetic according to claim 3, since the emulsified composition according to claim 1 is used, it has good stability and can reduce skin irritation.

請求項４に記載の水中油型乳化化粧料によれば、請求項
１記載の乳化組成物を用いているので、安定性がよく、
しかも皮膚刺激性の少ない水中油型化粧料を得ることが
できる。According to the oil-in-water emulsified cosmetic according to claim 4, since the emulsified composition according to claim 1 is used, it has good stability;
Furthermore, an oil-in-water cosmetic with less skin irritation can be obtained.

Claims (4)

【特許請求の範囲】[Claims] （１）下記一般式（ I ）で表されるアルキルグリコシ
ドから選ばれる一種または二種以上の界面活性剤と、分
子内に３個以上の水酸基を有する多価アルコールと、油
相成分と、を含むことを特徴とする乳化組成物。 一般式（ I ） ▲数式、化学式、表等があります▼ （式中Ｒは、炭素数８〜２４の直鎖及び／または分岐の
飽和アルキル基または不飽和アルケニル基を、ｘは１〜
１５の整数を表す。）(1) One or more surfactants selected from alkyl glycosides represented by the following general formula (I), a polyhydric alcohol having three or more hydroxyl groups in the molecule, and an oil phase component. An emulsified composition comprising: General formula (I) ▲ Numerical formulas, chemical formulas, tables, etc.
Represents an integer of 15. ) （２）請求項（１）記載の乳化組成物と、水相成分と、
を含むことを特徴とする水中油型乳化組成物。(2) the emulsified composition according to claim (1), and an aqueous phase component;
An oil-in-water emulsion composition comprising: （３）下記一般式（ I ）で表されるアルキルグリコシ
ドから選ばれる一種または二種以上の界面活性剤と、分
子内に３個以上の水酸基を有する多価アルコールと、油
相成分と、を含むことを特徴とする乳化化粧料。 一般式（ I ） ▲数式、化学式、表等があります▼ （式中Ｒは、炭素数８〜２４の直鎖及び／または分岐の
飽和アルキル基または不飽和アルケニル基を、ｘは１〜
１５の整数を表す。）(3) One or more surfactants selected from alkyl glycosides represented by the following general formula (I), a polyhydric alcohol having three or more hydroxyl groups in the molecule, and an oil phase component. An emulsified cosmetic comprising: General formula (I) ▲ Numerical formulas, chemical formulas, tables, etc.
Represents an integer of 15. ) （４）下記一般式（ I ）で表されるアルキルグリコシ
ドから選ばれる一種または二種以上の界面活性剤と、分
子内に３個以上の水酸基を有する多価アルコールと、油
相成分と、水相成分とを含むことを特徴とする水中油型
乳化化粧料。 一般式（ I ） ▲数式、化学式、表等があります▼ （式中Ｒは、炭素数８〜２４の直鎖及び／または分岐の
飽和アルキル基または不飽和アルケニル基を、ｘは１〜
１５の整数を表す。）(4) One or more surfactants selected from alkyl glycosides represented by the following general formula (I), a polyhydric alcohol having three or more hydroxyl groups in the molecule, an oil phase component, and water. An oil-in-water emulsion cosmetic comprising a phase component. General formula (I) ▲ Numerical formulas, chemical formulas, tables, etc.
Represents an integer of 15. )
JP63028543A 1988-02-09 1988-02-09 Emulsion composition and emulsified cosmetic Expired - Fee Related JP2652395B2 (en)

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0368440A (en) * 1989-08-04 1991-03-25 Huels Ag Emulsifier for producing polysiloxane oil- or polysiloxane-paraffin oil-aqueous emulsion having storing stability
JPH06502117A (en) * 1990-10-17 1994-03-10 ソシエテ　デクスプルワタシヨン　ドゥ　プロデュイ　プール　レ　インドゥストリエ　シミッケ　−　エス．エ．ペ．ペ．イ．セ． Use of compositions based on fatty alcohols for producing emulsions, methods for producing emulsions and emulsions obtained by this method
US5494938A (en) * 1990-01-25 1996-02-27 Henkel Kommanditgesellschaft Auf Aktien Oil-in-water emulsions
JPH08245366A (en) * 1995-03-16 1996-09-24 Nonogawa Shoji Kk Cosmetic
JPH09500825A (en) * 1993-07-27 1997-01-28 インペリアル・ケミカル・インダストリーズ・ピーエルシー Surfactant composition
US5885563A (en) * 1997-04-24 1999-03-23 U.S. Philips Corporation Shaving liquid
EP0870494A3 (en) * 1997-04-08 2000-01-05 Beiersdorf Aktiengesellschaft Cosmetic and dermatological washing composition containing acrylate copolymers, alkylglucosides and alcohols
JP2001181193A (en) * 1999-12-22 2001-07-03 Masao Saito Anti-inflammatory cream
JP2002541170A (en) * 1999-04-10 2002-12-03 コグニス・ドイチュラント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング・ウント・コムパニー・コマンディットゲゼルシャフト Sunscreen preparations containing alkyl and / or alkenyl oligoglycoside esters of hydroxycarboxylates
KR20030071270A (en) * 2002-02-28 2003-09-03 학교법인 한양학원 Method and System for Recognizing Iris using Iris Characteristic
JP2005514340A (en) * 2001-10-25 2005-05-19 ソシエテ・デクスプロワタシオン・デ・プロデュイ・プール・レ・アンデュストリー・シミック・セピック Use of alkyl polyglycosides as emulsifiers for the preparation of oil-in-water emulsions containing inorganic fillers or pigments, and oil-in-water emulsions containing such alkyl polyglycosides
US7544674B2 (en) 2002-10-25 2009-06-09 Galderma S.A. Topical skin care composition
JP2009249383A (en) * 2008-04-02 2009-10-29 Lvmh Recherche Use of alkyl glycoside or alkyl glycoside mixture having antiaging property as activation agent in cosmetic composition and method for cosmetic care by using the composition
WO2015047188A1 (en) * 2013-09-30 2015-04-02 Enza Biotech Ab Surfactant composition
JP2016172700A (en) * 2015-03-17 2016-09-29 ポーラ化成工業株式会社 Emulsion composition
JP2021116232A (en) * 2020-01-22 2021-08-10 ポーラ化成工業株式会社 Oil-in-water emulsion composition

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JPS591405A (en) * 1982-06-28 1984-01-06 Shiseido Co Ltd Emulsifiable composition
JPS59141510A (en) * 1983-01-31 1984-08-14 Shiseido Co Ltd Emulsified composition

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0368440A (en) * 1989-08-04 1991-03-25 Huels Ag Emulsifier for producing polysiloxane oil- or polysiloxane-paraffin oil-aqueous emulsion having storing stability
US5494938A (en) * 1990-01-25 1996-02-27 Henkel Kommanditgesellschaft Auf Aktien Oil-in-water emulsions
JPH06502117A (en) * 1990-10-17 1994-03-10 ソシエテ　デクスプルワタシヨン　ドゥ　プロデュイ　プール　レ　インドゥストリエ　シミッケ　−　エス．エ．ペ．ペ．イ．セ． Use of compositions based on fatty alcohols for producing emulsions, methods for producing emulsions and emulsions obtained by this method
US5958431A (en) * 1990-10-17 1999-09-28 Societe D'exploitation De Produits Pour Les Industries Chimique S.E.P.P.I.C. Use of fatty alcohol based compositions for preparing emulsions; method of preparing emulsions and emulsions so obtained
JPH09500825A (en) * 1993-07-27 1997-01-28 インペリアル・ケミカル・インダストリーズ・ピーエルシー Surfactant composition
JPH08245366A (en) * 1995-03-16 1996-09-24 Nonogawa Shoji Kk Cosmetic
EP0870494A3 (en) * 1997-04-08 2000-01-05 Beiersdorf Aktiengesellschaft Cosmetic and dermatological washing composition containing acrylate copolymers, alkylglucosides and alcohols
US5885563A (en) * 1997-04-24 1999-03-23 U.S. Philips Corporation Shaving liquid
JP2002541170A (en) * 1999-04-10 2002-12-03 コグニス・ドイチュラント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング・ウント・コムパニー・コマンディットゲゼルシャフト Sunscreen preparations containing alkyl and / or alkenyl oligoglycoside esters of hydroxycarboxylates
JP2001181193A (en) * 1999-12-22 2001-07-03 Masao Saito Anti-inflammatory cream
JP2005514340A (en) * 2001-10-25 2005-05-19 ソシエテ・デクスプロワタシオン・デ・プロデュイ・プール・レ・アンデュストリー・シミック・セピック Use of alkyl polyglycosides as emulsifiers for the preparation of oil-in-water emulsions containing inorganic fillers or pigments, and oil-in-water emulsions containing such alkyl polyglycosides
KR20030071270A (en) * 2002-02-28 2003-09-03 학교법인 한양학원 Method and System for Recognizing Iris using Iris Characteristic
US7939516B2 (en) 2002-10-25 2011-05-10 Galderma S.A. Topical skin care composition
US9333172B2 (en) 2002-10-25 2016-05-10 Galderma S.A. Topical skin care composition
US7544674B2 (en) 2002-10-25 2009-06-09 Galderma S.A. Topical skin care composition
US8247395B2 (en) 2002-10-25 2012-08-21 Galderma S.A. Topical skin care composition
US8653053B2 (en) 2002-10-25 2014-02-18 Galderma S.A. Topical skin care composition
JP2009249383A (en) * 2008-04-02 2009-10-29 Lvmh Recherche Use of alkyl glycoside or alkyl glycoside mixture having antiaging property as activation agent in cosmetic composition and method for cosmetic care by using the composition
CN105705623A (en) * 2013-09-30 2016-06-22 安莎生物技术有限公司 Surfactant composition
WO2015047188A1 (en) * 2013-09-30 2015-04-02 Enza Biotech Ab Surfactant composition
JP2016535811A (en) * 2013-09-30 2016-11-17 エンサ バイオテック アクチエボラグＥｎｚａ Ｂｉｏｔｅｃｈ Ａｂ Surfactant composition
US10188736B2 (en) 2013-09-30 2019-01-29 Enza Biotech Ab Surfactant composition
CN105705623B (en) * 2013-09-30 2020-02-21 安莎生物技术有限公司 Surfactant composition
JP2020041146A (en) * 2013-09-30 2020-03-19 エンサ バイオテック アクチエボラグＥｎｚａ Ｂｉｏｔｅｃｈ Ａｂ Surfactant composition
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