JPH01180815A - Cleaning agent composition - Google Patents
Cleaning agent compositionInfo
- Publication number
- JPH01180815A JPH01180815A JP283688A JP283688A JPH01180815A JP H01180815 A JPH01180815 A JP H01180815A JP 283688 A JP283688 A JP 283688A JP 283688 A JP283688 A JP 283688A JP H01180815 A JPH01180815 A JP H01180815A
- Authority
- JP
- Japan
- Prior art keywords
- alkanolamine
- ammonium ion
- phosphoric acid
- formula
- cleaning agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 22
- 239000012459 cleaning agent Substances 0.000 title abstract description 5
- -1 phosphoric acid compound Chemical class 0.000 claims abstract description 26
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 14
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 10
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 5
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 4
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 3
- 238000004140 cleaning Methods 0.000 claims description 10
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 238000004040 coloring Methods 0.000 abstract description 6
- 238000005187 foaming Methods 0.000 abstract description 6
- 150000002148 esters Chemical class 0.000 abstract description 3
- 239000002738 chelating agent Substances 0.000 abstract description 2
- 150000002430 hydrocarbons Chemical group 0.000 abstract description 2
- 150000002500 ions Chemical class 0.000 abstract description 2
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 13
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- 229910019142 PO4 Inorganic materials 0.000 description 7
- 150000005690 diesters Chemical class 0.000 description 7
- 239000010452 phosphate Substances 0.000 description 7
- TVACALAUIQMRDF-UHFFFAOYSA-N dodecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCOP(O)(O)=O TVACALAUIQMRDF-UHFFFAOYSA-N 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 238000002845 discoloration Methods 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 239000002453 shampoo Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- FKKAGFLIPSSCHT-UHFFFAOYSA-N 1-dodecoxydodecane;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC FKKAGFLIPSSCHT-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000001815 facial effect Effects 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- UHGIMQLJWRAPLT-UHFFFAOYSA-N octadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCCCOP(O)(O)=O UHGIMQLJWRAPLT-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- WFFZELZOEWLYNK-XPWSMXQVSA-N bis[(e)-octadec-9-enyl] hydrogen phosphate Chemical compound CCCCCCCC\C=C\CCCCCCCCOP(O)(=O)OCCCCCCCC\C=C\CCCCCCCC WFFZELZOEWLYNK-XPWSMXQVSA-N 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Polymers OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- JTXUVYOABGUBMX-UHFFFAOYSA-N didodecyl hydrogen phosphate Chemical compound CCCCCCCCCCCCOP(O)(=O)OCCCCCCCCCCCC JTXUVYOABGUBMX-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- ZUVCYFMOHFTGDM-UHFFFAOYSA-N hexadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCOP(O)(O)=O ZUVCYFMOHFTGDM-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- KRIXEEBVZRZHOS-UHFFFAOYSA-N tetradecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCOP(O)(O)=O KRIXEEBVZRZHOS-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明はシャンプー、洗顔料などの洗浄剤組成物に関す
る。更に詳しくは本発明は、アンモニウムイオンあるい
はアルカノールアミンを対イオンとするリン酸エステル
系界面活性剤を配合し、毛髪、皮膚に温和で、しかも経
口により着色を生ずることのない洗浄剤組成物に関する
。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to cleaning compositions such as shampoos and facial cleansers. More specifically, the present invention relates to a detergent composition containing a phosphate ester surfactant having ammonium ion or alkanolamine as a counter ion, which is mild to hair and skin and does not cause coloring when administered orally.
従来の技術とその問題点
リン酸エステル系界面活性剤は、一般に皮膚に対しマイ
ルドな性質を示し、洗浄剤組成物中に配合すると肌に温
和でつっばり感がなく、しっとり感のある仕上がりを与
えることが知られている。Conventional technology and its problems Phosphate ester surfactants generally exhibit mild properties on the skin, and when incorporated into cleaning compositions, they give a mild, non-tacky, and moist finish to the skin. known to give.
特に、リン酸エステルをトリエタノールアミン等でアル
カノールアミンとすることにより優れた起泡力および水
溶性を示す。In particular, excellent foaming power and water solubility are exhibited by converting the phosphoric acid ester into an alkanolamine using triethanolamine or the like.
しかしながら、＋１ン酸工ステル系界面活性剤をアルカ
ノールアミノ塩にすると経日で激しい変色（褐変）がみ
られる。However, when the alkanol amino salt of the +1-phosphoric ester surfactant is converted into an alkanol amino salt, severe discoloration (browning) is observed over time.
本発明者等は、このように優れた風合、起泡力を有する
リン酸エステル−アルカノールアミン塩系界面活性剤を
用い、しかも経口での着色がない洗浄剤組成物を得るべ
く鋭意研究した。その結果、特定のキレート剤を一定量
以上配合することにより経口での変色が効果的に防止で
きることを見い出し本発明を完成するに至った。The present inventors conducted extensive research in order to obtain a cleaning composition that uses a phosphate ester-alkanolamine salt surfactant that has such excellent texture and foaming power and that does not cause oral coloring. . As a result, they discovered that oral discoloration can be effectively prevented by incorporating a certain amount or more of a specific chelating agent, and have completed the present invention.
問題点を解決するためへ下段
本発明は、
（１）（ａ）下式
％式％
〔式中、Ｍ４、Ｍ２、Ｍ３及びＭ４は各々別個に水素原
子、アルカリ金属、アンモニウムイオンまたはアルカノ
ールアミンを意味する〕
で表されるリン酸化合物０．００１〜２０重量％、並び
に
（ｂ）下式・
Ｒ・−ｏ−（ＡＯ）、、−７−ＯＸ （ＩＩ）Ｙ
および
〔式中、Ｒ１、Ｒ２及びＲ８は各々炭素数８〜１８の飽
和又は不飽和の炭化水素基、Ｘはアンモニウムイオンま
たはアルカノールアミン、Ｙは水素原子、アンモニウム
イオンまたはアルカノールアミン、ＡＯは炭素数２また
は３のアルキレンオキシド、Ｑ、 ｍ、及びｎは各々０
〜２０の整数を示す〕で表されるリン酸エステルの混合
物からなる界面活性剤１〜３０重量％
を配合したことを特徴とする洗浄剤組成物を提供するも
のである。In order to solve the problems, the present invention has the following features: (1) (a) The following formula % [In the formula, M4, M2, M3 and M4 each independently represent a hydrogen atom, an alkali metal, an ammonium ion or an alkanolamine. 0.001 to 20% by weight of a phosphoric acid compound represented by the following formula: R2 and R8 are each a saturated or unsaturated hydrocarbon group having 8 to 18 carbon atoms, X is an ammonium ion or alkanolamine, Y is a hydrogen atom, ammonium ion or alkanolamine, AO is an alkylene oxide having 2 or 3 carbon atoms, Q, m, and n are each 0
The present invention provides a cleaning composition characterized in that it contains 1 to 30% by weight of a surfactant consisting of a mixture of phosphoric acid esters represented by the following integer from 1 to 20.
本発明洗浄剤に配合される式Ｉのリン酸化合物としては
、例えば１−ヒドロキシエタノ−１，１−ジホスホン酸
およびそのカリウムまた・よナト、・ノウムなどのアル
カリ金属との塩、もしくはｊルモニウム、あるいはモノ
エタノールアミ、／、；、てタノールアミン、トリエタ
ノールアミンなどのアルカノールアミンとの塩があげら
れる。Examples of the phosphoric acid compound of formula I that can be incorporated into the cleaning agent of the present invention include 1-hydroxyethano-1,1-diphosphonic acid and its salts with alkali metals such as potassium, yonato, and noum; , or salts with alkanolamines such as monoethanolamine, /, tanolamine, and triethanolamine.
かかるリン酸化合物の配合最は洗浄剤組成物中０００１
〜２０重量％、好ましくは０．０５〜１０重患％である
。０００１％より配合Ｉが少ないと変色の防止に効果が
なく、逆に２０％以上配合しても変色防止の効果がほぼ
平衡に達しコスト面から好ましくない。また高温で変質
したリン酸化合物が経口により析出あるいは異臭を発す
る。The composition of such a phosphoric acid compound is 0001 in a cleaning composition.
-20% by weight, preferably 0.05-10% by weight. If the amount of Blend I is less than 0,001%, it will not be effective in preventing discoloration, and conversely, if it is blended in an amount of 20% or more, the effect of preventing discoloration will almost reach equilibrium, which is not preferable from a cost standpoint. In addition, phosphoric acid compounds that are altered at high temperatures precipitate or emit a strange odor when taken orally.
前記式（ＩＩ）および（ＩＩ［）のポリオキシエチレン
アルキルリン酸エステル塩としては、例えばポリオキン
エチレン（１）ラウリルリン酸 モノまたはジエステル
、ポリオキシエチレン（２）ラウリルリン酸 モノまた
はジエステル、ポリオキシエチレン（２０）ミリスチル
リン酸 モノまたはジエステル、ポリオキシエチレン（
１３）パルミチルリン酸 モノまたはジエステル、ポリ
オキシエチレン（４）ステアリルリン酸 モノまたはジ
エステル、ポリオキシエチレン（１０）オレイルリン酸
モノまたはジエステルなどのアンモニアもしくはモノ
エタノールアミン、ジェタノールアミン、トリエタノー
ルアミンなどのアルカノールアミンとの塩等が挙げられ
る。Examples of the polyoxyethylene alkyl phosphate ester salts of formulas (II) and (II[) include polyoxyethylene (1) lauryl phosphate mono- or diester, polyoxyethylene (2) lauryl phosphate mono- or diester, and polyoxyethylene (2) lauryl phosphate mono- or diester. Oxyethylene (20) myristyl phosphate mono or diester, polyoxyethylene (
13) Palmityl phosphoric acid mono or diester, polyoxyethylene (4) stearyl phosphoric acid mono or diester, polyoxyethylene (10) oleyl phosphoric acid mono or diester etc. Ammonia or alkanols such as monoethanolamine, jetanolamine, triethanolamine etc. Examples include salts with amines.
また、前記式（ＩＩ）および（ＩＩＩ）のアルキルリン
酸エステル塩（Ｌｍ、ｎが０のもの）としては、例えば
、モノまたはジラウリルリン酸、モノまたはシミリスチ
ルリン酸、モノまたはシバルミチルリン酸、モノまたは
ンステアリルリン酸、モノまたはジオレイルリン酸など
のアンモニアもしくはモノエタノールアミン、ジェタノ
ールアミン、トリエタノールアミンなどのアルカノール
アミンとの塩等が挙げられる。Further, the alkyl phosphate ester salts (Lm, n is 0) of the formulas (II) and (III) include, for example, mono- or dilauryl phosphoric acid, mono- or cimilistyl phosphoric acid, mono- or civalmityl phosphoric acid, Examples include salts of mono- or stearyl phosphoric acid, mono- or dioleyl phosphoric acid, etc. with ammonia or alkanolamines such as monoethanolamine, jetanolamine, triethanolamine, etc.
これらボＩ゛・・ ・エチレンアルキルリン酸エステル
塩、およびアルキルリン酸エステル塩は、通常混合物と
して入手され、モノ／ジ（式■／式■）比が１００１０
〜５０１５０のものが洗浄力に優れ、好ましい。These bodies... Ethylene alkyl phosphate salts and alkyl phosphate salts are usually obtained as a mixture, and have a mono/di (formula ■/formula ■) ratio of 10010.
-50150 has excellent detergency and is preferable.
これらポリオキシエチレンアルキルリン酸エステル塩お
よびアルキルリン酸エステル塩は、組成物全体に対して
１〜３０重量％、好ましくは５〜２０重量％配合される
。配合量り月重量％より少ないと皮膚へのしっとり感賦
与などのリン酸エステル特有の効果が発現せず、一方、
３０重量％を越えると低温時にゲル化を生ずるなどの問
題を生ずる。These polyoxyethylene alkyl phosphate ester salts and alkyl phosphate ester salts are blended in an amount of 1 to 30% by weight, preferably 5 to 20% by weight, based on the entire composition. If the amount is less than 1% by weight, the effects peculiar to phosphate esters, such as imparting moist sensation to the skin, will not be exhibited; on the other hand,
If it exceeds 30% by weight, problems such as gelation at low temperatures will occur.
本発明の洗浄剤組成物には、使用目的により他の界面活
性剤、湿油剤、紫外線吸収剤、酸化防止剤、防腐剤、色
素、香料、増粘剤等を配合することができる。また、本
発明組成物は常法により配合、製造できる。The cleaning composition of the present invention may contain other surfactants, humectants, ultraviolet absorbers, antioxidants, preservatives, pigments, fragrances, thickeners, etc. depending on the purpose of use. Further, the composition of the present invention can be blended and manufactured by conventional methods.
実施例
以下に本発明を実施例により更に詳細に説明するが、本
発明はこれらの実施例に限定されるものではない。EXAMPLES The present invention will be explained in more detail with reference to Examples below, but the present invention is not limited to these Examples.
（１）評価法
〔起泡性、しっとり感〕
専門パネラ−５０名により洗浄剤組成物２０％水溶液で
手洗い試験を行い、その時の泡立ち、しっとり感をっぎ
の基準で評価し、平均値を求めた。(1) Evaluation method [foaming property, moist feeling] A hand washing test was conducted by 50 expert panelists using a 20% aqueous solution of the cleaning composition, and the foaming and moist feeling at that time were evaluated using the GG criteria, and the average value was calculated. Ta.
（起泡性）
４・・・非常に良い
３・・・ 良い
２・・・ 普通
ｌ・・・ 悪い
（しっとり感）
２ ・しっとり感有
１・・ややしっとり感有
０ ・感じられない
一７＝
〔着色度および臭気〕
洗浄剤組成物を４５℃で３ケ月放置後、着色度と異臭を
０°Ｃに保持した試料と比較して次の基準により評価し
た。(Foaming properties) 4... Very good 3... Good 2... Average l... Bad (moist feeling) 2 - Moist feeling 1... Slightly moist feeling 0 - Not felt - 7 = [Coloration degree and odor] After the cleaning composition was left at 45°C for 3 months, the coloration degree and off-odor were evaluated in comparison with a sample maintained at 0°C according to the following criteria.
（着色度）
○１着色が全く認められない
△ 僅かに着色が認められた
×、激しい着色が認められた
（臭 気）
○ 臭気なし
△ 僅かに異臭有
×、激しい異臭有
〔低温安定性〕
０°Ｃに３ケ月放置し、洗浄剤組成物を次の基準で評価
した。(Degree of coloration) ○1 No coloration observed △ Slight coloration ×, intense coloration observed (odor) ○ No odor △ Slightly off-odor ×, strong off-odor [Low temperature stability] After being left at 0°C for 3 months, the cleaning composition was evaluated based on the following criteria.
○ 流動性有
へ やや流動性に劣る、又は僅かに
結晶の析出
× 流動性なし、又は結晶の析出
実施例１〜１２および比較例１〜５
〜８−
第１表に示す各成分を常法により配合し、シャンプーを
得た。○ Fluidity Slightly poor fluidity or slight crystal precipitation × No fluidity or crystal precipitation Examples 1 to 12 and Comparative Examples 1 to 5 to 8 A shampoo was obtained.
第１表から明らかなごとく、リン酸エステルのアンモニ
ウム塩、トリエタノールアミン塩のみを用いた洗浄剤は
着色が生じる。これに対して１−ヒドロキノエタン−１
，１−ジホスホン酸、またはその塩を０００１〜２重量
％配合することにより着色が防止される。かかる配合憑
がこの範囲より多いと、僅かな結晶の析出や異臭が生ず
る。As is clear from Table 1, the cleaning agent using only the ammonium salt and triethanolamine salt of phosphoric acid ester causes coloring. In contrast, 1-hydroquinoethane-1
, 1-diphosphonic acid, or a salt thereof in an amount of 0001 to 2% by weight prevents coloring. If the content exceeds this range, slight crystal precipitation and off-odor may occur.
なお、リン酸エステル−トリエタノールアミン塩は２種
以上を組み合わせても良い。Note that two or more types of phosphoric acid ester-triethanolamine salts may be used in combination.
実施例１３（ボディーシャンプー）
成 分 配合世（重傷％）ラウ
リルリン酸・ＴＥＡ １５．０ＰＯＥ（
２）ラウリルリン酸・ＴＥＡ ３ ０ＰＯＥ
（３）ラウリルエーテルスルフェート・ＴＥＡ
２ ．０ヤシ油アルキルジメチ
ルベタイン ２０プロピレングリコール
ｌＯ０１−ヒドロキンエタン−１，１−ジホス
ホン酸 ０３パラベン
０１色素 微量香料
ｏ３水
残部
実施例１４（ヘアーシャンプー）
リン酸・ＴＥＡ １５．０ポリオ
キシエヂレン（３）ラウリル
エーテルザルフェート・ＴＥＡ ５．０ヤン浦
脂肪酸ジエタノールアミド ３．０アロエキス
ｏ１ヒドロキンエチルセル
ロース ｏ２プロピレングワコ〜ル
５゜１−ヒドロキンエタン−１゜
１−ジホスホン酸・４Ｎａ Ｏ，５パ
ラベン ０．１色素
微量ｄ、Ｑ−メントー
ル ０２香料
０．１水
残部
実施例１５（洗顔料）
成 分 配合虫（重量％）ラウ
リルリン酸・ＴＥＡ １０．０ステアリン
酸・ＴＥＡ １．８．０ミリスチン酸
・ＴＥＡ ２．０セタノール
５０パラフインワツクス
０５１−ヒドロキシエタン１．１−ン
ポスポン酸 ０５オリーブ油
１．０パラベン
０３香料 ０３水
残部
実施例１３〜１５はいずれも着色防止効果が認められた
。Example 13 (Body Shampoo) Ingredients Blend (serious injury %) Lauryl phosphoric acid/TEA 15.0POE (
2) Lauryl phosphate/TEA 30POE
(3) Lauryl ether sulfate/TEA
2. 0 Coconut oil alkyl dimethyl betaine 20 Propylene glycol
lO01-Hydroquinethane-1,1-diphosphonic acid 03 Paraben
01 Pigment Trace fragrance
o3 water
Remainder Example 14 (hair shampoo) Phosphoric acid/TEA 15.0 Polyoxyethylene (3) Lauryl ether sulfate/TEA 5.0 Yangura fatty acid diethanolamide 3.0 Allo extract
o1 Hydroquine ethylcellulose o2 Propylene wacol
5゜1-hydroquinethane-1゜1-diphosphonic acid, 4Na O, 5 paraben 0.1 dye
Trace amount d, Q-menthol 02 fragrance
0.1 water
Remainder Example 15 (facial cleanser) Ingredients (wt%) lauryl phosphoric acid/TEA 10.0 stearic acid/TEA 1.8.0 myristic acid/TEA 2.0 cetanol
50 paraffin wax
051-Hydroxyethane1.1-posponic acid 05Olive oil
1.0 paraben
03 Fragrance 03 Water
In all of the remaining Examples 13 to 15, the effect of preventing coloring was observed.
特許出願人 ザンスター株式会社Patent applicant: Zanstar Co., Ltd.
Claims (1)
に水素原子、アルカリ金属、アンモニウムイオンまたは
アルカノールアミンを意味する〕 で表されるリン酸化合物０．００１〜２．０重量％、並
びに （ｂ）下式： ▲数式、化学式、表等があります▼（II） および ▲数式、化学式、表等があります▼（III） 〔式中、Ｒ＿１、Ｒ＿２及びＲ＿３は各々炭素数８〜１
８の飽和又は不飽和の炭化水素基、Ｘはアンモニウムイ
オンまたはアルカノールアミン、Ｙは水素原子、アンモ
ニウムイオンまたはアルカノールアミン、ＡＯは炭素数
２または３のアルキレンオキシド、ｌ、ｍ、及びｎは各
々０〜２０の整数を示す〕で表されるリン酸エステルの
混合物からなる界面活性剤１〜３０重量％ を配合したことを特徴とする洗浄剤組成物。(1) (a) The following formula: ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (I) [In the formula, M_1, M_2, M_3 and M_4 each independently represent a hydrogen atom, an alkali metal, an ammonium ion, or an alkanolamine. ] 0.001 to 2.0% by weight of a phosphoric acid compound represented by, and (b) the following formula: ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (II) and ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (III) [In the formula, R_1, R_2 and R_3 each have 8 to 1 carbon atoms
8 saturated or unsaturated hydrocarbon group, X is ammonium ion or alkanolamine, Y is hydrogen atom, ammonium ion or alkanolamine, AO is alkylene oxide having 2 or 3 carbon atoms, l, m, and n are each 0 A cleaning composition characterized in that it contains 1 to 30% by weight of a surfactant consisting of a mixture of phosphoric acid esters represented by [indicating an integer from 20 to 20].
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP283688A JPH01180815A (en) | 1988-01-08 | 1988-01-08 | Cleaning agent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP283688A JPH01180815A (en) | 1988-01-08 | 1988-01-08 | Cleaning agent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01180815A true JPH01180815A (en) | 1989-07-18 |
Family
ID=11540500
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP283688A Pending JPH01180815A (en) | 1988-01-08 | 1988-01-08 | Cleaning agent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01180815A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10604452B2 (en) | 2004-11-12 | 2020-03-31 | General Electric Company | Article having a dispersion of ultrafine titanium boride particles in a titanium-base matrix |
-
1988
- 1988-01-08 JP JP283688A patent/JPH01180815A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10604452B2 (en) | 2004-11-12 | 2020-03-31 | General Electric Company | Article having a dispersion of ultrafine titanium boride particles in a titanium-base matrix |
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