JPH0529203B2 - - Google Patents
Info
- Publication number
- JPH0529203B2 JPH0529203B2 JP27125885A JP27125885A JPH0529203B2 JP H0529203 B2 JPH0529203 B2 JP H0529203B2 JP 27125885 A JP27125885 A JP 27125885A JP 27125885 A JP27125885 A JP 27125885A JP H0529203 B2 JPH0529203 B2 JP H0529203B2
- Authority
- JP
- Japan
- Prior art keywords
- shampoo
- hair
- composition
- lactylate
- phosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002453 shampoo Substances 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 24
- 150000003839 salts Chemical class 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 2
- -1 fatty acid ester Chemical class 0.000 description 15
- 208000001840 Dandruff Diseases 0.000 description 11
- 239000004094 surface-active agent Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 238000001035 drying Methods 0.000 description 8
- 239000006260 foam Substances 0.000 description 8
- 238000005406 washing Methods 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000010452 phosphate Substances 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- AEMRFAOFKBGASW-UHFFFAOYSA-M Glycolate Chemical compound OCC([O-])=O AEMRFAOFKBGASW-UHFFFAOYSA-M 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- JTXUVYOABGUBMX-UHFFFAOYSA-N didodecyl hydrogen phosphate Chemical compound CCCCCCCCCCCCOP(O)(=O)OCCCCCCCCCCCC JTXUVYOABGUBMX-UHFFFAOYSA-N 0.000 description 4
- CYFHLEMYBPQRGN-UHFFFAOYSA-N ditetradecyl hydrogen phosphate Chemical compound CCCCCCCCCCCCCCOP(O)(=O)OCCCCCCCCCCCCCC CYFHLEMYBPQRGN-UHFFFAOYSA-N 0.000 description 4
- AOHBGMDQHXJADT-UHFFFAOYSA-N 2-(2-dodecanoyloxypropanoyloxy)propanoic acid Chemical compound CCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C(O)=O AOHBGMDQHXJADT-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000003750 conditioning effect Effects 0.000 description 3
- TVACALAUIQMRDF-UHFFFAOYSA-N dodecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCOP(O)(O)=O TVACALAUIQMRDF-UHFFFAOYSA-N 0.000 description 3
- 239000002552 dosage form Substances 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- KRIXEEBVZRZHOS-UHFFFAOYSA-N tetradecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCOP(O)(O)=O KRIXEEBVZRZHOS-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- YVIGPQSYEAOLAD-UHFFFAOYSA-L disodium;dodecyl phosphate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOP([O-])([O-])=O YVIGPQSYEAOLAD-UHFFFAOYSA-L 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- HNYLJFVPFNLDRL-UHFFFAOYSA-N (2-hydroxyacetyl) 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(=O)CO HNYLJFVPFNLDRL-UHFFFAOYSA-N 0.000 description 1
- YFUSUXATWLGGNN-UHFFFAOYSA-N (2-hydroxyacetyl) dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC(=O)CO YFUSUXATWLGGNN-UHFFFAOYSA-N 0.000 description 1
- QSYXYZBUUZSDBF-UHFFFAOYSA-N (2-hydroxyacetyl) octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(=O)CO QSYXYZBUUZSDBF-UHFFFAOYSA-N 0.000 description 1
- KHICUSAUSRBPJT-UHFFFAOYSA-N 2-(2-octadecanoyloxypropanoyloxy)propanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C(O)=O KHICUSAUSRBPJT-UHFFFAOYSA-N 0.000 description 1
- JVTIXNMXDLQEJE-UHFFFAOYSA-N 2-decanoyloxypropyl decanoate 2-octanoyloxypropyl octanoate Chemical compound C(CCCCCCC)(=O)OCC(C)OC(CCCCCCC)=O.C(=O)(CCCCCCCCC)OCC(C)OC(=O)CCCCCCCCC JVTIXNMXDLQEJE-UHFFFAOYSA-N 0.000 description 1
- AXDJCCTWPBKUKL-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-imino-3-methylcyclohexa-2,5-dien-1-ylidene)methyl]aniline;hydron;chloride Chemical compound Cl.C1=CC(=N)C(C)=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 AXDJCCTWPBKUKL-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- MGDNLGRMXPBCOR-UHFFFAOYSA-N bis(2-hydroxyethyl)azanium;dodecanoate Chemical compound OCCNCCO.CCCCCCCCCCCC(O)=O MGDNLGRMXPBCOR-UHFFFAOYSA-N 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 210000000736 corneocyte Anatomy 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 239000002702 enteric coating Substances 0.000 description 1
- 238000009505 enteric coating Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 229940071147 isostearoyl lactylate Drugs 0.000 description 1
- 210000002510 keratinocyte Anatomy 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940071209 stearoyl lactylate Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- QDSWHSQBAUPQGK-UHFFFAOYSA-K trisodium;dodecyl hydrogen phosphate;dodecyl phosphate Chemical compound [Na+].[Na+].[Na+].CCCCCCCCCCCCOP(O)([O-])=O.CCCCCCCCCCCCOP([O-])([O-])=O QDSWHSQBAUPQGK-UHFFFAOYSA-K 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
〔産業上の利用分野〕
本発明はシヤンプー組成物、更に詳細には、リ
ン酸エステル系界面活性剤及び特定の脂肪酸エス
テルを含有し、洗髪中の泡のなめらかさに優れ、
乾燥後の髪につやを与えることができ、更にフケ
の除去効果に優れたシヤンプー組成物に関する。
〔従来の技術及びその問題点〕
近時、陰イオン性界面活性剤の一種であるリン
酸エステル系界面活性剤は、皮膚に対する刺激性
が低く、極めて温和な界面活性剤であることが認
められ、洗浄剤組成物の一成分として利用されて
いる。
しかし、このリン酸エステル系界面活性剤は、
水ですすぎ時にカルシウム塩を生成し、これが毛
髪に付着し、洗髪後のすべりなどの感触を非常に
悪くすることを始めいくつかの難点があり、シヤ
ンプー組成物用の界面活性剤としては未だ満足の
ゆくものではなかつた。
この様な欠点を改善するため、従来、シヤンプ
ー基剤に油剤等のコンデイシヨニング剤を配合す
る方法がとられているが、コンデイシヨニング剤
添加によりシヤンプー本来の機能である泡立ち、
洗浄力が極端に悪くなり、著しく商品価値を損な
つてしまうという問題点があつた。
〔問題点を解決するための手段〕
本発明者らは、この様な従来のコンデイシヨニ
ング剤の欠点に注目し、洗髪時の感触が良好で、
乾燥後も毛髪のなめらかさに優れたコンデイシヨ
ニング剤について検討した結果、リン酸エステル
系界面活性剤に特定の脂肪酸エステルを併用配合
することにより、シヤンプー組成物の持つ洗浄力
を損わずに洗髪中の泡になめらかさ、クリーミー
さ等を付与し、乾燥後の髪につやを付与し、しか
も、フケの洗浄率を向上させることができること
を見出し、本発明を完成した。
すなわち本発明は、次の成分(A)及び(B)
(A) 次の一般式（）又は（）
（式中、R1、R2及びR3は各々炭素数８〜18の
飽和又は不飽和の炭化水素基を、Ｘ及びＹは各々
水素あるいはアルカリ金属、アンモニウム又は炭
素数２若しくは３のヒドロキシアルキル基を有す
るアルカノールアミンの塩であることを示し、
ｌ、ｍ及びｎは各々０〜10の数を示す）
で表わされるリン酸エステル系界面活性剤の１種
又は２種以上 ５〜50重量％
(B) 次の一般式（）
（式中、RCOは炭素数６〜22の脂肪酸の直鎖
又は分岐のアシル基を、ＡはCH3又は水素を、ｐ
は１〜３の整数を示す）
で表わされる化合物又はその塩 0.1〜５重量％
を含有するシヤンプー組成物を提供するものであ
る。
本発明の(A)成分であるリン酸エステル系界面活
性剤としては、エチレンオキサイドの付加モル数
が０〜３のものが好ましく、特にエチレンオキサ
イドが付加しておらず、炭素数12〜14のアルキル
基を有するものが好ましい。(A)成分の好ましい具
体例としては、モノ−又はジラウリルリン酸ナト
リウム、モノ−又はジラウリルリン酸カリウム、
モノ−又はジラウリルリン酸ジエタノールアミ
ン、モノ−又はジラウリルリン酸トリエタノール
アミン、モノ−又はジミリスチルリン酸ナトリウ
ム、モノ−又はジミリスチルリン酸カリウム、モ
ノ−又はジミリスチルリン酸ジエタノールアミ
ン、モノ−又はジミリスチルリン酸トリエタノー
ルアミン等が挙げられる。この(A)成分は、使用に
当り上記式（）と（）で表わされる化合物
を、その重量比で10：０〜５：５、特に10：０〜
７：３の割合で混合することが好ましい。
また、本発明の(B)成分としては、前記式（）
で表わされる脂肪酸ラクチレート及び脂肪酸グリ
コレートが使用される。（）式中、RCOの炭素
数が12〜18のものが好ましく、その具体例として
は、ラウロイルラクチレート、イソラウロイルラ
クチレート、ミリストイルラクチレート、イソミ
リストイルラクチレート、オレロイルラクチレー
ト、イソオレロイルラクチレート、ステアロイル
ラクチレート、イソステアロイルラクチレート、
ラウロイルグリコレート、イソラウロイルグリコ
レート、ミリストイルグリコレート、イソミリス
トイルグリコレート、オレロイルグリコレート、
イソオレロイルグリコレート、ステアロイルグリ
コレート、イソステアロイルグリコレート等が挙
げられる。塩としては、例えばアンモニウム塩、
アルカリ金属塩、アミン塩等が挙げられる。
本発明のシヤンプー組成物において、(A)成分は
全組成中に５〜50重量％（以下、％で示す）、特
に好ましくは10〜40％、また(B)成分は全組成中に
0.1〜５％、特に好ましくは0.1〜３％となるよう
に配合される。これらの範囲外では、本発明効果
を十分発揮することはできない。
本発明のシヤンプー組成物には上記成分の他に
公知のシヤンプー組成物の配合成分として用いら
れるプロピレングリコール、グリセリン等の溶解
剤、エタノール、無機塩、高級アルコール、ヒド
ロキシメチルセルロース、ヒドロキシエチルセル
ロース、ヒドロキシプロピルセルロース、メチル
セルロース等の粘度調整剤、その他香料、色素、
柴外線吸収剤、酸化防止剤、抗フケ剤、殺菌剤、
防腐剤等を必要に応じ、配合することができる。
残部は水であり、通常50〜90重量％使用される。
本発明のシヤンプー組成物は、その剤型につい
て特に制限はなく、従来公知の剤型、例えば液体
シヤンプー、ペーストシヤンプー等の剤型とする
ことができる。そして、本発明のシヤンプー組成
物は、上記剤型に応じ公知方法に従つて、(A)成分
と(B)成分を配合し、更に必要により上記各種任意
成分を添加配合することにより調製される。
〔発明の効果〕
本発明のシヤンプー組成物は、洗髪中の泡のな
めらかさ、クリーミーさに優れ、乾燥後の髪につ
やを付与することができ、更にフケの除去効果を
有し、しかも洗浄力に優れたものである。
〔実施例〕
実施例 １
第１表に示す組成物の液体シヤンプーを調製
し、その性質を下記方法により評価した。結果を
第１表に示す。
(1) 泡の感触の評価方法
30ｇの人毛を40℃の水で湿らせ20ｇの水を含
ませる。次いで、シヤンプー組成物１ｇを使用
して洗髪し、泡の感触を女性パネラー20名の官
能評価により判定する。洗髪の際の指の通り具
合を「泡のすべり」として、更に液の外観を
「クリーミー性」の観点から評価する。
(2) 仕上がりの感触及びつやの評価方法
30ｇの人毛を40℃の水で湿らせ20ｇの水を含
ませる。次いでシヤンプー組成物１ｇを使用し
て洗髪後、流水で水洗した人毛を絞り、ドライ
ヤーで乾燥後の感触（すべり）及びつやを女性
パネラー20名の官能評価により判定する。
(3) 洗浄力の測定方法
人工油性汚垢布を３％シヤンプー水溶液中に
浸し、ターゴトメーターにて40℃で10分間撹拌
した後、流水下ですすぎ、洗浄前後の汚染布の
460nmにおける反射率を色彩計にて測定し、洗
浄率を算出した。
[Industrial Application Field] The present invention provides a shampoo composition, more specifically, a shampoo composition containing a phosphoric acid ester surfactant and a specific fatty acid ester, which has excellent lather smoothness during hair washing,
This invention relates to a shampoo composition capable of imparting shine to hair after drying and further having an excellent dandruff removal effect. [Prior art and its problems] Recently, it has been recognized that phosphate ester surfactants, which are a type of anionic surfactant, are extremely mild surfactants with low irritation to the skin. , is used as a component of cleaning compositions. However, this phosphate ester surfactant
There are several drawbacks, including the generation of calcium salts when rinsing with water, which adhere to the hair and make the hair feel slippery after washing, so it is still unsatisfactory as a surfactant for shampoo compositions. It wasn't something I could go by. In order to improve these drawbacks, a conventional method has been to add a conditioning agent such as an oil to the shampoo base.
There was a problem in that the cleaning power became extremely poor and the product value was significantly reduced. [Means for Solving the Problems] The present inventors focused on the shortcomings of such conventional conditioning agents, and developed a hair conditioner that provides a good feel when washing hair,
As a result of investigating a conditioning agent that leaves hair smooth even after drying, we found that by combining a phosphate ester surfactant with a specific fatty acid ester, the shampoo composition's cleansing power was not impaired. The present invention was completed based on the discovery that it is possible to impart smoothness, creaminess, etc. to foam during hair washing, to impart shine to hair after drying, and to improve the dandruff cleaning rate. That is, the present invention comprises the following components (A) and (B) (A) the following general formula () or () (In the formula, R 1 , R 2 and R 3 each represent a saturated or unsaturated hydrocarbon group having 8 to 18 carbon atoms, and X and Y each represent hydrogen, an alkali metal, ammonium, or a hydroxyalkyl group having 2 or 3 carbon atoms. Indicates that it is a salt of an alkanolamine having a group,
(l, m and n each represent a number from 0 to 10) 5 to 50% by weight of one or more phosphate ester surfactants represented by (B) the following general formula () (In the formula, RCO is a linear or branched acyl group of a fatty acid having 6 to 22 carbon atoms, A is CH 3 or hydrogen, p
represents an integer of 1 to 3) or a salt thereof in an amount of 0.1 to 5% by weight. As the phosphoric acid ester surfactant which is component (A) of the present invention, one having an added mole of ethylene oxide of 0 to 3 is preferable, and especially one having no added ethylene oxide and having a carbon number of 12 to 14. Those having an alkyl group are preferred. Preferred specific examples of component (A) include sodium mono- or dilauryl phosphate, potassium mono- or dilauryl phosphate,
Diethanolamine mono- or dilauryl phosphate, triethanolamine mono- or dilauryl phosphate, sodium mono- or dimyristyl phosphate, potassium mono- or dimyristyl phosphate, diethanolamine mono- or dimyristyl phosphate, mono- or dimyristyl phosphate Examples include triethanolamine. When used, component (A) contains the compounds represented by the above formulas () and () in a weight ratio of 10:0 to 5:5, particularly 10:0 to 5:5.
Preferably, they are mixed in a ratio of 7:3. In addition, as the component (B) of the present invention, the above formula ()
Fatty acid lactylates and fatty acid glycolates represented by are used. In the formula (), RCO preferably has 12 to 18 carbon atoms, and specific examples include lauroyl lactylate, isolauroyl lactylate, myristoyl lactylate, isomyristoyl lactylate, oleloyl lactylate, isooleloyl lactylate, stearoyl lactylate, isostearoyl lactylate,
lauroyl glycolate, isolauroyl glycolate, myristoyl glycolate, isomyristoyl glycolate, oleloyl glycolate,
Examples include isooleloyl glycolate, stearoyl glycolate, isostearoyl glycolate, and the like. Examples of salts include ammonium salts,
Examples include alkali metal salts and amine salts. In the shampoo composition of the present invention, component (A) is 5 to 50% by weight (hereinafter expressed as %) in the total composition, particularly preferably 10 to 40%, and component (B) is in the total composition.
It is blended in an amount of 0.1 to 5%, particularly preferably 0.1 to 3%. Outside these ranges, the effects of the present invention cannot be fully exhibited. In addition to the above-mentioned ingredients, the shampoo composition of the present invention also includes dissolving agents such as propylene glycol and glycerin, which are used as ingredients in known shampoo compositions, ethanol, inorganic salts, higher alcohols, hydroxymethyl cellulose, hydroxyethyl cellulose, and hydroxypropyl cellulose. , viscosity modifiers such as methylcellulose, other fragrances, pigments,
Shibagai ray absorber, antioxidant, anti-dandruff agent, bactericide,
Preservatives and the like can be added as necessary.
The balance is water, usually used at 50-90% by weight. The shampoo composition of the present invention is not particularly limited in its dosage form, and can be in any conventionally known dosage form, such as liquid shampoo or paste shampoo. The shampoo composition of the present invention is prepared by blending the components (A) and (B) according to the known method according to the above-mentioned dosage form, and further adding and blending the above-mentioned various optional components as necessary. . [Effects of the Invention] The shampoo composition of the present invention has excellent foam smoothness and creaminess during hair washing, can add shine to hair after drying, has a dandruff removal effect, and is easy to clean. It has excellent power. [Examples] Example 1 A liquid shampoo of the composition shown in Table 1 was prepared, and its properties were evaluated by the following method. The results are shown in Table 1. (1) Method for evaluating the feel of foam Moisten 30g of human hair with 40℃ water and add 20g of water. Next, hair is washed using 1 g of the shampoo composition, and the feel of the foam is evaluated by sensory evaluation by 20 female panelists. The way the hair runs through your fingers during hair washing is evaluated as ``slippage of the foam,'' and the appearance of the liquid is evaluated in terms of ``creaminess.'' (2) How to evaluate the feel and gloss of the finished product: Moisten 30g of human hair with 40℃ water and add 20g of water. Next, after washing the hair using 1 g of the shampoo composition, the washed human hair was wrung out under running water, and after drying with a hair dryer, the feel (slipness) and gloss were judged by sensory evaluation by 20 female panelists. (3) Method for measuring cleaning power Soak an artificial oil-based stained cloth in a 3% shampoo aqueous solution, stir for 10 minutes at 40℃ using a tergotometer, rinse under running water, and measure the soiled cloth before and after washing.
The reflectance at 460 nm was measured using a colorimeter, and the cleaning rate was calculated.
【表】【table】
【表】【table】
【表】
第１表より明らかな如く、リン酸エステル系界
面活性剤と脂肪酸ラクチレートまたは脂肪酸グリ
コレートを併用配合することにより、泡のなめら
かさに優れ、乾燥後の髪につやを与えることがで
き、しかも洗浄力の優れたシヤンプー剤が得られ
る。
実施例 ２
第２表に示す組成の液体シヤンプーを調製し、
そのフケ除去効果を下記方法により試験した。結
果を第３表に示す。[Table] As is clear from Table 1, by combining a phosphate ester surfactant with fatty acid lactylate or fatty acid glycolate, it is possible to create a smooth foam and add shine to the hair after drying. Moreover, a shampoo agent with excellent detergency can be obtained. Example 2 A liquid shampoo having the composition shown in Table 2 was prepared,
The dandruff removal effect was tested by the following method. The results are shown in Table 3.
【表】【table】
【表】
フケの除去効果の測定方法：
女性パネラー10名について測定を行つた。
頭皮へあてたカツプに、10％シヤンプー液を２
ml注入し、30秒後、フケ分散液に、フクシン／ク
リスタルバイオレツト混合液を数滴加え、血球計
算板にて角質細胞数を計数し、フケの除去率とし
た。
女性パネラー１名につき、本発明品、比較品各
３ケ所の角質細胞数を測定した。[Table] Method for measuring dandruff removal effect: Measurement was performed on 10 female panelists. Apply two drops of 10% shampoo to the cup applied to the scalp.
ml was injected, and 30 seconds later, several drops of the fuchsin/crystal violet mixture were added to the dandruff dispersion, and the number of corneocytes was counted using a hemocytometer, which was determined as the dandruff removal rate. For each female panelist, the number of keratinocytes was measured at three locations each for the present invention product and the comparative product.
【表】
第３表より明らかな如く、リン酸エステル系界
面活性剤とラクチレートを併用配合することによ
り、フケの除去効果に優れたシヤンプー剤が得ら
れる。
実施例 ３
ペーストシヤンプー
（組成）
モノ／ジ（７／３）ラウリルリン酸ナトリウム
20％
ラウロイルラクチレート（ナトリウム塩、−
＝２） ２％
カーボポール941（カルボキシビニルポリマー）
0.5％
NaCl １％
香 料 0.3％
水 残部
上記の配合組成物により、極めて泡のなめらか
さに優れ、乾燥後の髪につやを与えることがで
き、かつフケの除去効果に優れたシヤンプー剤が
得られた。
実施例 ４
液体シヤンプー
（組成）
ポリオキシエチレン（＝２）モノ／ジ
（７／３）ラウリルリン酸ナトリウム 18％
ラウロイルラクチレート（ナトリウム塩、＝
２） ３％
ラウリン酸ジエタノールアミン ５％
香 料 0.3％
水 残部
上記の配合組成物により、極めて、泡のなめら
かさに優れ、乾燥後の髪につやを与えることがで
き、かつフケの除去効果に優れたシヤンプー剤が
得られた。[Table] As is clear from Table 3, by combining a phosphate ester surfactant and lactylate, a shampoo agent with excellent dandruff removal effect can be obtained. Example 3 Paste shampoo (composition) Mono/di(7/3) sodium lauryl phosphate
20% lauroyl lactylate (sodium salt, -
=2) 2% Carbopol 941 (carboxyvinyl polymer)
0.5% NaCl 1% Fragrance 0.3% Water Balance The above composition provides a shampoo that has an extremely smooth foam, can add shine to hair after drying, and has an excellent dandruff removal effect. It was done. Example 4 Liquid shampoo (composition) Polyoxyethylene (=2) mono/di(7/3) sodium lauryl phosphate 18% Lauroyl lactylate (sodium salt, =
2) 3% Diethanolamine Laurate 5% Fragrance 0.3% Water Balance The above blended composition produces extremely smooth foam, can add shine to hair after drying, and has an excellent dandruff removal effect. A shampoo was obtained.
１ 粉粒状の低融点物質を核として造粒された粒
状物に微粉状の腸溶性コーテイング基剤を付着さ
せた粒状物。
1. A granular material in which a finely powdered enteric coating base is attached to a granular material granulated using a powdery low melting point substance as a core.
Claims (1)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27125885A JPS62132811A (en) | 1985-12-02 | 1985-12-02 | Shampoo composition |
| US06/931,810 US4758376A (en) | 1985-11-28 | 1986-11-18 | Phosphate surfactant based detergent compositions |
| EP86116008A EP0224796B1 (en) | 1985-11-28 | 1986-11-18 | Detergent composition |
| DE8686116008T DE3682035D1 (en) | 1985-11-28 | 1986-11-18 | CLEANING SUPPLIES. |
| AT86116008T ATE68520T1 (en) | 1985-11-28 | 1986-11-18 | CLEANING SUPPLIES. |
| ES198686116008T ES2026844T3 (en) | 1985-11-28 | 1986-11-18 | A DETERGENT COMPOSITION. |
| MYPI86000151A MY101124A (en) | 1985-11-28 | 1986-11-27 | Detergent composition |
| SG143/93A SG14393G (en) | 1985-11-28 | 1993-02-09 | Detergent composition |
| HK418/93A HK41893A (en) | 1985-11-28 | 1993-04-29 | Detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27125885A JPS62132811A (en) | 1985-12-02 | 1985-12-02 | Shampoo composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62132811A JPS62132811A (en) | 1987-06-16 |
| JPH0529203B2 true JPH0529203B2 (en) | 1993-04-28 |
Family
ID=17497563
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP27125885A Granted JPS62132811A (en) | 1985-11-28 | 1985-12-02 | Shampoo composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62132811A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8828013D0 (en) * | 1988-12-01 | 1989-01-05 | Unilever Plc | Topical composition |
| GB8828014D0 (en) * | 1988-12-01 | 1989-01-05 | Unilever Plc | Topical composition |
| GB8828017D0 (en) * | 1988-12-01 | 1989-01-05 | Unilever Plc | Topical composition |
| GB8828020D0 (en) * | 1988-12-01 | 1989-01-05 | Unilever Plc | Topical composition |
| GB9000704D0 (en) * | 1990-01-12 | 1990-03-14 | Unilever Plc | Topical composition |
-
1985
- 1985-12-02 JP JP27125885A patent/JPS62132811A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62132811A (en) | 1987-06-16 |
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