JPH01177A - organic platinum ink - Google Patents
organic platinum inkInfo
- Publication number
- JPH01177A JPH01177A JP62-154769A JP15476987A JPH01177A JP H01177 A JPH01177 A JP H01177A JP 15476987 A JP15476987 A JP 15476987A JP H01177 A JPH01177 A JP H01177A
- Authority
- JP
- Japan
- Prior art keywords
- platinum
- tert
- organic
- ink
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 title claims description 65
- 229910052697 platinum Inorganic materials 0.000 title claims description 36
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 17
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 10
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 10
- 239000011230 binding agent Substances 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- -1 tert-amyl Chemical group 0.000 claims description 6
- 229920000180 alkyd Polymers 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 4
- 150000003505 terpenes Chemical class 0.000 claims description 4
- 235000007586 terpenes Nutrition 0.000 claims description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 239000000976 ink Substances 0.000 description 21
- 239000000919 ceramic Substances 0.000 description 5
- KIDPOJWGQRZHFM-UHFFFAOYSA-N platinum;hydrate Chemical compound O.[Pt] KIDPOJWGQRZHFM-UHFFFAOYSA-N 0.000 description 5
- 150000003058 platinum compounds Chemical class 0.000 description 4
- 238000007650 screen-printing Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910000510 noble metal Inorganic materials 0.000 description 3
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 2
- 241000723346 Cinnamomum camphora Species 0.000 description 2
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- 229930008380 camphor Natural products 0.000 description 2
- 229960000846 camphor Drugs 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- JZLWSRCQCPAUDP-UHFFFAOYSA-N 1,3,5-triazine-2,4,6-triamine;urea Chemical compound NC(N)=O.NC1=NC(N)=NC(N)=N1 JZLWSRCQCPAUDP-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- 235000007173 Abies balsamea Nutrition 0.000 description 1
- 239000004857 Balsam Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 244000018716 Impatiens biflora Species 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- 150000001621 bismuth Chemical class 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002343 gold Chemical class 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002940 palladium Chemical class 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 150000003283 rhodium Chemical class 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 150000003303 ruthenium Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、セラミック、ガラス製品の表面の装飾、電子
工業等に使用される有機白金インクに関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to an organic platinum ink used for surface decoration of ceramic and glass products, electronic industry, etc.
（従来技術とその問題点）
陶器等のセラミック製品やガラス製品の表面にインクを
使用して文字や図形を描いてその装飾効果を倍増させる
ことが従来から広く行われている。(Prior Art and its Problems) It has been widely practiced to double the decorative effect of ceramic products such as pottery and glass products by drawing letters and figures using ink on the surface of the products.
該文字や図形を描く際には単なるインクではなく、金や
銀等の貴金属光沢を有する有機貴金属インクを使用して
所謂金文字等を形成し、より高級な雰囲気を醸し出すこ
とも行われている。When drawing such letters and figures, instead of using simple ink, organic precious metal ink with the luster of precious metals such as gold and silver is used to form so-called gold letters, etc., to create a more luxurious atmosphere. .
これらの有機貴金属インクのうち、白金を貴金属として
含有するインクとして汎用されているものの白金源は、
「水白金」と呼ばれる、主成分が硫化バルサムと白金の
化合物であるが、該白金化合物の詳細は不明であり、量
産はされていない。Among these organic noble metal inks, the platinum source for the commonly used inks containing platinum as a noble metal is:
It is a compound called "water platinum" whose main components are balsam sulfide and platinum, but the details of the platinum compound are unknown and it is not mass-produced.
更に該水白金は低粘度であるため印刷性に乏しく筆や刷
毛による塗布は可能であるが通常のスクリーン印刷等に
は使用できないという欠点がある。Furthermore, since the water-platinum has a low viscosity, it has poor printability, and although it can be applied with a brush or a brush, it cannot be used for ordinary screen printing.
（発明の目的）
本発明は、有機白金インクの白金源として従来使用され
ていた水白金に換えて、より粘度が高く印刷性に優れた
白金化合物を使用して白金源を明確にして大量生産を可
能にするとともに、有機バインダを加えて印刷性をより
向上させた有機白金インクを提供することを目的とする
。(Objective of the invention) The present invention uses a platinum compound with higher viscosity and excellent printability in place of water platinum, which has been conventionally used as a platinum source for organic platinum ink, to clarify the platinum source and mass-produce it. The purpose of the present invention is to provide an organic platinum ink that further improves printability by adding an organic binder.
（問題点を解決するための手段）
本発明は、白金アルキルメルカプチド、少なくとも１種
類の樹脂酸の金属塩、有機バインダ及び溶剤を含有する
ことを特徴とする有機白金インクである。(Means for Solving the Problems) The present invention is an organic platinum ink characterized by containing platinum alkyl mercaptide, at least one metal salt of a resin acid, an organic binder, and a solvent.
以下本発明をより詳細に説明する。The present invention will be explained in more detail below.
本発明における白金アルキルメルカプチド、特に白金ｔ
ｅｒｔ−アルキルメルカプチドとは、例えば塩化白金酸
塩、は塩化白金酸塩の溶液にアルキルスルフィド及びｔ
ｅｒｔ−アルキルメルカプタンを加え反応させることに
より生成する白金化合物であり、該白金ｔｅｒｔ−アル
キルメルカプチドのｔｅｒｔ−アルキル基は、ｔｅｒｔ
−アミル、ｔｅｒｔ−ブチル、ｔｅｒｔ−オクチル、ｔ
ｅｒＬ−ドデシル、ｔｅｒｔ−テトラデシル、Ｌｅｒｔ
−ノニル及びｔｅｒｔ−ヘキサデシル等から選択される
。通常該白金化合物中の白金含有量は、約２０〜２５重
量％である。Platinum alkyl mercaptide in the present invention, especially platinum t
ert-alkyl mercaptide refers to, for example, chloroplatinate, a solution of chloroplatinate containing alkyl sulfide and tert-alkyl mercaptide.
It is a platinum compound produced by adding and reacting ert-alkyl mercaptan, and the tert-alkyl group of the platinum tert-alkyl mercaptide is tert-alkyl mercaptan.
-amyl, tert-butyl, tert-octyl, t
erL-dodecyl, tert-tetradecyl, Lert
-nonyl, tert-hexadecyl, and the like. Usually the platinum content in the platinum compound is about 20-25% by weight.
樹脂酸の金属塩は従来から汎用されている、金塩、銀塩
、パラジウム塩、ロジウム塩及びルテニウム塩等の貴金
属塩及び、ビスマス塩及びクロム塩等の卑金属塩を含み
、これらの樹脂酸の金属塩の１又は２種以上を使用する
。Metal salts of resin acids include noble metal salts such as gold salts, silver salts, palladium salts, rhodium salts, and ruthenium salts, and base metal salts such as bismuth salts and chromium salts, which have been widely used. One or more metal salts are used.
本発明における有機バインダとは、従来使用されている
ものの他、アルキド樹脂、尿素樹脂、ロジン誘導体及び
テルペン系樹脂等を使用することができる。使用できる
アルキド樹脂としては、アマニ油及びロジン変性アルキ
ド樹脂があり、尿素樹脂としてはｎ−ブチルエーテル型
ブチル化尿素樹脂等がある。父上記ロジン誘胤体樹脂と
は、天然ロジンを化学処理して該天然ロジンよりも粘度
を大きくした該天然ロジンから得られる物質の総称であ
り、例えばロジンのグリセリンエステル、ロジンのペン
タエリスリトールエステル、水素添加したロジンのメチ
ルエステル、マレイン酸変性したロジンエステル等が含
まれる。更にテルペン系樹脂としてテルペン重合体及び
α−ピネン重合体等を使用することができる。As the organic binder in the present invention, in addition to those conventionally used, alkyd resins, urea resins, rosin derivatives, terpene resins, etc. can be used. Examples of alkyd resins that can be used include linseed oil and rosin-modified alkyd resins, and examples of urea resins that can be used include n-butyl ether type butylated urea resins. The above-mentioned rosin derivative resin is a general term for substances obtained from natural rosin that has been chemically treated to have a higher viscosity than the natural rosin, such as rosin glycerin ester, rosin pentaerythritol ester, Includes hydrogenated rosin methyl ester, maleic acid-modified rosin ester, etc. Furthermore, terpene polymers, α-pinene polymers, etc. can be used as the terpene resin.
又本発明においては、上記白金アルキルメルカプチド、
上記樹脂酸の金属塩及び上記有機バインダの他に必須成
分として、これら成分の溶剤、例えばテルペンアルコー
ルを含む。該溶剤は上記物質を溶解しかつ該物質を含む
インクが陶器等に塗布された場合に比較的短時間で乾く
ような揮発性物質であることが好ましい。Further, in the present invention, the above platinum alkyl mercaptide,
In addition to the metal salt of the resin acid and the organic binder, a solvent for these components, such as a terpene alcohol, is included as an essential component. The solvent is preferably a volatile substance that dissolves the substance and dries in a relatively short time when an ink containing the substance is applied to ceramics or the like.
本発明における有機白金インクは、前記白金アルキルメ
ルカプチド、前記樹脂酸の金属塩、有機バインダ及び溶
剤の必須成分の他に、カンファーやアスファルト等の添
加物を含むことができる。The organic platinum ink in the present invention can contain additives such as camphor and asphalt in addition to the essential components of the platinum alkyl mercaptide, the metal salt of the resin acid, the organic binder, and the solvent.
以下本発明に係わる有機白金インクの実施例を記載する
が、該実施例は本発明を限定するものではない。Examples of organic platinum inks according to the present invention will be described below, but these examples are not intended to limit the present invention.
（実施例） 下記の成分を混合して有機白金インクとした。(Example) An organic platinum ink was prepared by mixing the following components.
白金ｔｅｒｔ−ドデシルメルカプチド ・・・７．０重量％ 樹脂酸ロジウム・・・０．０５重量％ 樹脂酸ビスマス・・・０．３重量％ 樹脂酸クロム・・・０．０５重量％ アルキド樹脂・・・１５重量％ 尿素メラミン樹脂・・・１０重量％ ロジン誘導体樹脂・・・５．０重量％ カンファー・・・６．５重量％ アスファルト・・・１．０重量％ 酢酸ベンジル・・・８．０重量％ テルペンアルコール・・・残部。Platinum tert-dodecyl mercaptide ...7.0% by weight Rhodium resin acid...0.05% by weight Bismuth resin acid...0.3% by weight Chromium resin acid...0.05% by weight Alkyd resin...15% by weight Urea melamine resin...10% by weight Rosin derivative resin...5.0% by weight Camphor...6.5% by weight Asphalt...1.0% by weight Benzyl acetate...8.0% by weight Terpene alcohol...remainder.
適度な粘性を有する該インクを陶器表面へ刷毛、スクリ
ーン印刷を用いて塗布し、５００〜９００℃で１０分〜
３０分加熱して焼成させた。The ink with appropriate viscosity is applied to the ceramic surface using a brush or screen printing, and heated at 500 to 900°C for 10 minutes.
It was heated and baked for 30 minutes.
一方白金ｔｅｒｔ−ドデシルメルカプチド７．０重量％
を水白金７．０重量％で置換した以外は上記した組成と
同一組成を有する有機白金インクを同様の条件で陶器上
に塗布した。On the other hand, platinum tert-dodecyl mercaptide 7.0% by weight
An organic platinum ink having the same composition as above was applied onto ceramics under the same conditions except that water was replaced with 7.0% by weight of platinum.
本実施例インクは、陶器表面のうち塗布された部分全体
に均一に付着し滑らかな表面を形成したが、水白金を使
用したインクではスクリーン印刷性に適さない。The ink of this example adhered uniformly to the entire coated portion of the pottery surface, forming a smooth surface, but the ink using water-platinum is not suitable for screen printing.
（発明の効果）
本発明の有機白金インクでは、従来の粘度が低く成分が
特定されなかった水白金の換わりに、粘度の高い白金ア
ルキルメルカプチドを使用し、かつ有機バインダを併用
して粘度を向上させているため、本発明の有機白金イン
クは特定成分を化学的に合成することにより大量生産が
可能になり、更にスクリーン印刷等の通常の印刷、及び
筆や刷毛等による塗布に対しても十分な粘度を有するイ
ンクとなり、装飾用、電子工業用の有機白金インクとし
ての性能が飛躍的に向上する。(Effects of the Invention) The organic platinum ink of the present invention uses platinum alkyl mercaptide, which has a high viscosity, in place of the conventional water platinum, which has a low viscosity and whose components have not been specified, and also uses an organic binder to reduce the viscosity. As a result, the organic platinum ink of the present invention can be mass-produced by chemically synthesizing specific components, and is also resistant to ordinary printing such as screen printing, and application with a brush or brush. The resulting ink has sufficient viscosity, and its performance as an organic platinum ink for decorative and electronic industries is dramatically improved.
出願人 田中貴金属工業株式会社Applicant: Tanaka Kikinzoku Kogyo Co., Ltd.
Claims (4)
樹脂酸の金属塩、有機バインダ及び溶剤を含有すること
を特徴とする有機白金インク。(1) An organic platinum ink containing platinum alkyl mercaptide, at least one metal salt of a resin acid, an organic binder, and a solvent.
キルメルカプチドである特許請求の範囲第１項に記載の
有機白金インク。(2) The organic platinum ink according to claim 1, wherein the platinum alkyl mercaptide is platinum tert-alkyl mercaptide.
−アルキル基が、ｔｅｒｔ−アミル、ｔｅｒｔ−ブチル
、ｔｅｒｔ−オクチル、ｔｅｒｔ−ドデシル、ｔｅｒｔ
−テトラデシル、ｔｅｒｔ−ノニル及びｔｅｒｔ−ヘキ
サデシルから成る群から選択される基である特許請求の
範囲第２項に記載の有機白金インク。(3) Platinum tert-alkyl mercaptide tert
- alkyl group is tert-amyl, tert-butyl, tert-octyl, tert-dodecyl, tert-
3. The organic platinum ink of claim 2, wherein the ink is a group selected from the group consisting of -tetradecyl, tert-nonyl and tert-hexadecyl.
ン誘導体及びテルペン系樹脂から成る群から選択される
バインダである特許請求の範囲第１項から第３項までの
いずれかに記載の有機白金インク。(4) The organic platinum ink according to any one of claims 1 to 3, wherein the organic binder is a binder selected from the group consisting of alkyd resins, urea resins, rosin derivatives, and terpene resins. .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15476987A JPH0765013B2 (en) | 1987-06-22 | 1987-06-22 | Organic platinum ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15476987A JPH0765013B2 (en) | 1987-06-22 | 1987-06-22 | Organic platinum ink |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPS64177A JPS64177A (en) | 1989-01-05 |
| JPH01177A true JPH01177A (en) | 1989-01-05 |
| JPH0765013B2 JPH0765013B2 (en) | 1995-07-12 |
Family
ID=15591490
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15476987A Expired - Lifetime JPH0765013B2 (en) | 1987-06-22 | 1987-06-22 | Organic platinum ink |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0765013B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2534930Y2 (en) * | 1989-06-22 | 1997-05-07 | エヌオーケー株式会社 | Actuator |
| CN108359316A (en) * | 2017-01-26 | 2018-08-03 | 上海贺利氏工业技术材料有限公司 | For using inkjet printing to generate the composition for ink of decorative layer on the surface of the substrate |
| JPWO2022209724A1 (en) * | 2021-03-31 | 2022-10-06 |
-
1987
- 1987-06-22 JP JP15476987A patent/JPH0765013B2/en not_active Expired - Lifetime
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