JPH01159635A - Silver halide photographic sensitive material - Google Patents
Silver halide photographic sensitive materialInfo
- Publication number
- JPH01159635A JPH01159635A JP31792487A JP31792487A JPH01159635A JP H01159635 A JPH01159635 A JP H01159635A JP 31792487 A JP31792487 A JP 31792487A JP 31792487 A JP31792487 A JP 31792487A JP H01159635 A JPH01159635 A JP H01159635A
- Authority
- JP
- Japan
- Prior art keywords
- silver halide
- layer
- compounds
- nucleus
- silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 Silver halide Chemical class 0.000 title claims abstract description 59
- 239000000463 material Substances 0.000 title claims abstract description 42
- 229910052709 silver Inorganic materials 0.000 title claims abstract description 30
- 239000004332 silver Substances 0.000 title claims abstract description 30
- 238000001035 drying Methods 0.000 claims abstract description 8
- 238000000576 coating method Methods 0.000 abstract description 16
- 239000011248 coating agent Substances 0.000 abstract description 15
- 239000002245 particle Substances 0.000 abstract description 11
- 239000003112 inhibitor Substances 0.000 abstract description 3
- 229920002307 Dextran Polymers 0.000 abstract 4
- 239000000839 emulsion Substances 0.000 description 28
- 239000000975 dye Substances 0.000 description 21
- 239000010410 layer Substances 0.000 description 21
- 150000001875 compounds Chemical class 0.000 description 18
- 238000000034 method Methods 0.000 description 13
- 108010010803 Gelatin Proteins 0.000 description 9
- 206010070834 Sensitisation Diseases 0.000 description 9
- 229920000159 gelatin Polymers 0.000 description 9
- 239000008273 gelatin Substances 0.000 description 9
- 235000019322 gelatine Nutrition 0.000 description 9
- 235000011852 gelatine desserts Nutrition 0.000 description 9
- 230000008313 sensitization Effects 0.000 description 9
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 8
- 239000011230 binding agent Substances 0.000 description 8
- 239000004094 surface-active agent Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 229920003171 Poly (ethylene oxide) Chemical class 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- 239000011241 protective layer Substances 0.000 description 6
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
- 238000011161 development Methods 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 4
- 239000006224 matting agent Substances 0.000 description 4
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 4
- HWDDJFFLFNQAFQ-UHFFFAOYSA-M potassium;4-ethenylbenzenesulfonate Chemical compound [K+].[O-]S(=O)(=O)C1=CC=C(C=C)C=C1 HWDDJFFLFNQAFQ-UHFFFAOYSA-M 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 230000001235 sensitizing effect Effects 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910000510 noble metal Inorganic materials 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- ZVNPWFOVUDMGRP-UHFFFAOYSA-N 4-methylaminophenol sulfate Chemical compound OS(O)(=O)=O.CNC1=CC=C(O)C=C1.CNC1=CC=C(O)C=C1 ZVNPWFOVUDMGRP-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- HOLVRJRSWZOAJU-UHFFFAOYSA-N [Ag].ICl Chemical compound [Ag].ICl HOLVRJRSWZOAJU-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000009499 grossing Methods 0.000 description 2
- 150000002366 halogen compounds Chemical class 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 150000002484 inorganic compounds Chemical class 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000002916 oxazoles Chemical class 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical class O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- 150000003557 thiazoles Chemical class 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- NCNYEGJDGNOYJX-NSCUHMNNSA-N (e)-2,3-dibromo-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Br)=C(/Br)C=O NCNYEGJDGNOYJX-NSCUHMNNSA-N 0.000 description 1
- LUMLZKVIXLWTCI-NSCUHMNNSA-N (e)-2,3-dichloro-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Cl)=C(/Cl)C=O LUMLZKVIXLWTCI-NSCUHMNNSA-N 0.000 description 1
- AIGNCQCMONAWOL-UHFFFAOYSA-N 1,3-benzoselenazole Chemical class C1=CC=C2[se]C=NC2=C1 AIGNCQCMONAWOL-UHFFFAOYSA-N 0.000 description 1
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical class C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 1
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical class C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical class C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- ODIRBFFBCSTPTO-UHFFFAOYSA-N 1,3-selenazole Chemical class C1=C[se]C=N1 ODIRBFFBCSTPTO-UHFFFAOYSA-N 0.000 description 1
- OYTMCDCWKVWQET-UHFFFAOYSA-N 1-ethenylsulfonyl-2-(2-ethenylsulfonylethoxy)ethane Chemical compound C=CS(=O)(=O)CCOCCS(=O)(=O)C=C OYTMCDCWKVWQET-UHFFFAOYSA-N 0.000 description 1
- JAAIPIWKKXCNOC-UHFFFAOYSA-N 1h-tetrazol-1-ium-5-thiolate Chemical class SC1=NN=NN1 JAAIPIWKKXCNOC-UHFFFAOYSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- KTSDQEHXNNLUEA-UHFFFAOYSA-N 2-ethenylsulfonylacetamide Chemical compound NC(=O)CS(=O)(=O)C=C KTSDQEHXNNLUEA-UHFFFAOYSA-N 0.000 description 1
- UGWULZWUXSCWPX-UHFFFAOYSA-N 2-sulfanylideneimidazolidin-4-one Chemical class O=C1CNC(=S)N1 UGWULZWUXSCWPX-UHFFFAOYSA-N 0.000 description 1
- IBLIZVNATHGWMW-UHFFFAOYSA-N 3,4-dimethyl-1,2-oxazole perchloric acid Chemical compound Cl(=O)(=O)(=O)O.CC=1C(=NOC1)C IBLIZVNATHGWMW-UHFFFAOYSA-N 0.000 description 1
- SAPGIBGZGRMCFZ-UHFFFAOYSA-N 3-[(2,5-dioxopyrrol-3-yl)methyl]pyrrole-2,5-dione Chemical compound O=C1NC(=O)C(CC=2C(NC(=O)C=2)=O)=C1 SAPGIBGZGRMCFZ-UHFFFAOYSA-N 0.000 description 1
- OWIRCRREDNEXTA-UHFFFAOYSA-N 3-nitro-1h-indazole Chemical class C1=CC=C2C([N+](=O)[O-])=NNC2=C1 OWIRCRREDNEXTA-UHFFFAOYSA-N 0.000 description 1
- XRZDIHADHZSFBB-UHFFFAOYSA-N 3-oxo-n,3-diphenylpropanamide Chemical compound C=1C=CC=CC=1NC(=O)CC(=O)C1=CC=CC=C1 XRZDIHADHZSFBB-UHFFFAOYSA-N 0.000 description 1
- OCVLSHAVSIYKLI-UHFFFAOYSA-N 3h-1,3-thiazole-2-thione Chemical class SC1=NC=CS1 OCVLSHAVSIYKLI-UHFFFAOYSA-N 0.000 description 1
- NYYSPVRERVXMLJ-UHFFFAOYSA-N 4,4-difluorocyclohexan-1-one Chemical compound FC1(F)CCC(=O)CC1 NYYSPVRERVXMLJ-UHFFFAOYSA-N 0.000 description 1
- GIQKIFWTIQDQMM-UHFFFAOYSA-N 5h-1,3-oxazole-2-thione Chemical compound S=C1OCC=N1 GIQKIFWTIQDQMM-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical class C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000257465 Echinoidea Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 241000192130 Leuconostoc mesenteroides Species 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 102000010410 Nogo Proteins Human genes 0.000 description 1
- 108010077641 Nogo Proteins Proteins 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
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- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
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- 239000003638 chemical reducing agent Substances 0.000 description 1
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- AKCUHGBLDXXTOM-UHFFFAOYSA-N hydroxy-oxo-phenyl-sulfanylidene-$l^{6}-sulfane Chemical class SS(=O)(=O)C1=CC=CC=C1 AKCUHGBLDXXTOM-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine group Chemical group N1=CCC2=CC=CC=C12 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 150000002475 indoles Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- CBEQRNSPHCCXSH-UHFFFAOYSA-N iodine monobromide Chemical compound IBr CBEQRNSPHCCXSH-UHFFFAOYSA-N 0.000 description 1
- 150000002503 iridium Chemical class 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- PKDBSOOYVOEUQR-UHFFFAOYSA-N mucobromic acid Natural products OC1OC(=O)C(Br)=C1Br PKDBSOOYVOEUQR-UHFFFAOYSA-N 0.000 description 1
- ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 description 1
- 150000004780 naphthols Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910001120 nichrome Inorganic materials 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002829 nitrogen Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002918 oxazolines Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 1
- 229950005308 oxymethurea Drugs 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- WHMDPDGBKYUEMW-UHFFFAOYSA-N pyridine-2-thiol Chemical class SC1=CC=CC=N1 WHMDPDGBKYUEMW-UHFFFAOYSA-N 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- GGWBHVILAJZWKJ-KJEVSKRMSA-N ranitidine hydrochloride Chemical compound [H+].[Cl-].[O-][N+](=O)\C=C(/NC)NCCSCC1=CC=C(CN(C)C)O1 GGWBHVILAJZWKJ-KJEVSKRMSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical class O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 1
- 150000003283 rhodium Chemical class 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 235000017709 saponins Nutrition 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- HMNUYYJYMOXWTN-UHFFFAOYSA-J strontium;barium(2+);disulfate Chemical compound [Sr+2].[Ba+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O HMNUYYJYMOXWTN-UHFFFAOYSA-J 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 125000004964 sulfoalkyl group Chemical group 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 150000003536 tetrazoles Chemical class 0.000 description 1
- 150000003475 thallium Chemical class 0.000 description 1
- JJJPTTANZGDADF-UHFFFAOYSA-N thiadiazole-4-thiol Chemical class SC1=CSN=N1 JJJPTTANZGDADF-UHFFFAOYSA-N 0.000 description 1
- 150000003549 thiazolines Chemical class 0.000 description 1
- 125000005323 thioketone group Chemical group 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Abstract
Description
【発明の詳細な説明】
１０発明の背景
（技術分野）
本発明はハロゲン化銀写真感光材料に関し、特に塗布乾
燥時のカブリ発生を防止するととも°に高湿度での接着
を防止した写真感光材料に関する。Detailed Description of the Invention 10. Background of the Invention (Technical Field) The present invention relates to a silver halide photographic light-sensitive material, and particularly to a photographic light-sensitive material which prevents fogging during coating and drying and also prevents adhesion at high humidity. Regarding.
（先行技術とその問題点）
塗布乾燥時にトリメチロールプロパンなどのポリオール
化合物、ハイドロキノン、カテコール、レゾルシンなど
のポリヒドロキシベンゼン化合物を含有させてハロゲン
化銀写真感光材料のカブリの発生を防止することが知ら
れている。しかじながらこｎらの化合物を金回させると
感光材料金高湿に保つと接着をしてしまうという欠点が
あることが見出さｔＮ＊。(Prior art and its problems) It is known that fogging of silver halide photographic light-sensitive materials can be prevented by containing polyol compounds such as trimethylolpropane, polyhydroxybenzene compounds such as hydroquinone, catechol, and resorcinol during coating and drying. It is being However, it has been discovered that when these compounds are mixed with gold, they tend to adhere to the photosensitive material when kept at high humidity.
■０発明の目的
本発明の目的は塗布時のカブリを防止させると同時に高
湿での接着を発生させないハロゲン化銀写真感光材料を
提供することにある。(2) Object of the Invention The object of the invention is to provide a silver halide photographic material which prevents fogging during coating and at the same time does not cause adhesion at high humidity.
■０発明の開示 このような目的は下記の本発明によって達成される。■Disclosure of 0 inventions These objects are achieved by the invention described below.
すなわち、支持体上に少なくとも１層のハロゲン化銀粒
子を含む層ｔ−肩し、かつ感光材料中にテキストランと
乾燥カブリ防止剤の両方を含むことを特徴とするハロゲ
ン化銀写真感光材料である。That is, a silver halide photographic light-sensitive material is characterized in that it has at least one layer containing silver halide grains on a support and contains both a text run and a drying antifoggant in the light-sensitive material. be.
■０発明の具体的構成 以下、本発明の具体的構成について詳細に説明する。■Specific structure of 0 invention Hereinafter, a specific configuration of the present invention will be explained in detail.
本発明において感光材料中に添加するテキストランは、
特開昭１．／−１，９０１，１号に記載さｎている工う
にロイコノストックメゼンテロイデス等のテキストラン
生産菌、またはこｎらの菌の培養液より分離したテキス
トランシュクラーゼを蔗糖液に作用して得らｎるネイテ
ィブテキストランを酸、アルカリ、酵素による部分分解
重合法によって分子ｉｋを低下させたものである。本発
明に用いられるテキストランの重量平均分子量はｉｏ、
。In the present invention, the text run added to the photosensitive material is
Japanese Patent Publication No. 1. Textlan-producing bacteria such as Leuconostoc mesenteroides, the sea urchin described in No. 1,901, No. The resulting native text run is reduced in molecular ik by partial decomposition polymerization using acids, alkalis, and enzymes. The weight average molecular weight of the text run used in the present invention is io,
.
ＯＯから３００．０００．好ましくは２０ 、０００か
らａｏｏ 、ｏｏｏである。300.000 from OO. Preferably it is from 20,000 to aoo, ooo.
またテキストランの添加量は感光材料中の全バインダー
の！〜ＳＯＺｇ％とりわけ、７６〜＋０重量優になるよ
うにするのが好ましい。Also, the amount of Textran added is the total amount of binder in the photosensitive material! ~SOZg% Particularly preferably 76~+0% by weight.
本発明においてテキストランを含有せしめる層はどの層
でも良いが、好ましくはノ・ロゲン化銀粒子を含む層で
あることが好ましい。また好箇しくに支持体の上の下塗
り層に隣接した層には諮加しないことが良い。In the present invention, the layer containing text runs may be any layer, but preferably it is a layer containing silver halogenide grains. Also, it is preferable not to apply it to a layer adjacent to the undercoat layer on the support.
テキストランをハロゲン化銀乳剤層に加える場合、加え
る時期はいつでも良い。When adding a text run to a silver halide emulsion layer, it can be added at any time.
テキストランは粉末として加えても良いが、５〜３０％
水浴液として用いるのが便利である。Textran may be added as a powder, but at a concentration of 5-30%.
It is convenient to use as a water bath solution.
本発明において感光材料中に添加する乾燥カブリ防止剤
とは塗布乾燥時に発生するカブリを防止する化合物であ
り、下記の現像液で２００（：１２分間現像し九ときの
カブリ値を０．０２以上下げる効果を持つものである。In the present invention, the drying antifoggant added to the photosensitive material is a compound that prevents fogging that occurs during coating and drying. It has the effect of lowering
具体的にはトリメチロールブロノξン、エチレングリコ
ール、グリセリン、ｉ、ｚ−ベンタンジオール、ｌ、≠
−ブタンジオール、／、６−ヘキサンジオールなどのポ
リオール化合物、）・イドロキノン、カテコール、レゾ
ルシンなどのポリヒドロキシベンゼン化合物などがある
。Specifically, trimethylolbronoξone, ethylene glycol, glycerin, i,z-bentanediol, l,≠
Examples include polyol compounds such as -butanediol and 6-hexanediol, and polyhydroxybenzene compounds such as hydroquinone, catechol, and resorcinol.
現像液
メトール ２ノ亜硫酸ナ
トリウム ／ ００９ハイドロキノン
よ１ボラツクス・１ＩＨ
２０２？ ・
水をＤ口えて ／１本発明
における乾燥カブリ防止剤の使用量とじては、乳剤層中
のハロゲン化銀１モル当Ｂｏ、ｊ〜６０？、特にコ〜ｉ
ｏｔであることが好ましい。Developer Metol 2 Sodium Sulfite / 009 Hydroquinone Yo1 Volax / 1IH
202? - Add water /1 The amount of the drying antifoggant used in the present invention is Bo per mole of silver halide in the emulsion layer: ~60? , especially Ko~i
It is preferable that it is ot.
本発明の写真感光材料に用いらｎる写真乳剤中のハロゲ
ン化銀粒子に、立方体、八面体、菱ｌコ面体、／参面体
の工うな規則的（ｒｅｇｕｌａｒ）な結晶体を肩するも
のでも工く、また球状、板状などのような変則的（ｉｒ
ｒｅｇｕｌａｒ）な結晶形をもつもの、あるいはこれら
の結晶形の複合形をもつものでもよい。又、リサーチ・
ディスクロージャー（Ｒｅｓｅａｒｒ、ｈ Ｄｉｓｃｌ
ｏｓｕｒｅ）２Ｊｊ巻第２０〜！１頁（／りｒ３年）月
）に記載のアスペクト比１以上の平板状粒子であっても
工い。The silver halide grains in the photographic emulsion used in the photographic light-sensitive material of the present invention may include regular crystal bodies such as cubic, octahedral, rhombohedral, and tanhedral. It can also be irregular (irregular), such as spherical or plate-shaped.
It may have a regular crystal form or a composite form of these crystal forms. Also, research
Disclosure (Researr, h Discl.
osure) 2Jj Volume 20~! Even tabular grains with an aspect ratio of 1 or more as described on page 1 (/r3 years) may be used.
また、エピタキシャル構造を有するものでもよいし、粒
子の内部と表面とが異なった組成（例えはハロゲン組成
）からなる多層構造からなる粒子であってもよい。Further, the particles may have an epitaxial structure, or may have a multilayer structure in which the inside and the surface of the particle have different compositions (for example, halogen composition).
また粒子の平均サイズはＯ，Ｓμ以上であることが好ま
しい。さらに好ましくは平均サイズ０゜７μ以上ｊ、Ｏ
μ以下である。Further, it is preferable that the average size of the particles is O, Sμ or more. More preferably, the average size is 0°7μ or more.
It is less than μ.
また、粒子サイズ分布は、広くても狭くてもよい。後者
のものはいわゆる単分散乳剤として知らしておシ、分散
係数としては２０％以下、より好ましくはｌよチ以下が
よい。（ここで分散係数は標準偏差を平均粒子サイズで
割ったもの）こｎらの写真乳剤ハハ・グラフキデ
（Ｐ、Ｇｌａｆｋｉｄｅｓ）著ンハー・工・フイジーク
・ホトグラフィック（Ｃｈｉｍｉｅ ｅｔ ｉ’ｈ
ｙａｉｑｕｅＰｈｏｔｏｇｒａｐｈｉｑｕｅ） （ポ
ール＋モントル（Ｐａｕｌ Ｍｏｎｔｅｌ）社刊、１７
６７年）ジー。Also, the particle size distribution may be broad or narrow. The latter is known as a so-called monodisperse emulsion and has a dispersion coefficient of 20% or less, more preferably 10% or less. (Here, the dispersion coefficient is the standard deviation divided by the average grain size.) These photographic emulsions by Chimie et i'h Glafkides, Chimie et i'h
yaiquePhotographique) (Paul + Montel), 17
1967) Gee.
エフ・トウフィン、（（Ｊ、Ｆ、Ｄｕｆｆｉｎ）著フォ
トグラフィック・エマルジョン・ケミストリー（Ｐｈｏ
ｔｏｇｒａｐｈｉｃ Ｅｍｕｌｓｉｏｎ Ｃｂｅｒｎｉ
ｓｔｒｙ）（ザ・フオーカ／Ｌ／−プレス（Ｔｈｅ Ｆ
ｏｃａｌ Ｐｒｅｓｓ）刊、１９４４年）、ブイ・エ
ル・ゼリクマン（Ｖ、Ｌ、Ｚｅｌｉｋｍａｎン ら著メ
イキング・アンド・コーティング・フォトグラフィック
・エマルジョン（Ｍａｋｉｎｇａｎｄ Ｃｏａｔｉｎｇ
ＰｈｏｔｏｇｒａｐｈｉｃＥｍｕｌｓｉｏｎ） （
ザ・フォーカル・プレス（Ｔ ｈ ｅＦｏｃａｌ Ｐ
ｒｅｓｓ）刊、１９４弘年ンなどに記載さした方法を用
いて調製することができる。すなわち、＃ｌ性法、中性
法、アンモニア法等のいすｎでもよく、また可溶性銀塩
と可溶性ノ＼ロゲン塩を反応させる形式としては片側混
合法、同時混合法、そｎらの組合せなどのいずれを用い
てもよい。Photographic Emulsion Chemistry (Pho) by F. Duffin
tographic Emulsion Cberni
stry) (The Fooka/L/-Press (The F
Making and Coating Photographic Emulsions by V. L. Zelikman et al.
Photographic Emulsion) (
The Focal Press
It can be prepared using the method described in 194 Kounen, published by (Res.). In other words, methods such as #l-neutral method, neutral method, ammonia method, etc. may be used, and methods for reacting soluble silver salts with soluble nitrogen salts include one-sided mixing method, simultaneous mixing method, and combinations thereof. Either of these may be used.
これらの写真乳剤は塩化銀゛、臭化銀、沃化銀、沃臭化
銀、塩沃臭化銀、塩沃化銀、塩臭化銀、塩沃化銀のいず
汁の組合せでもよい。These photographic emulsions may be a combination of silver chloride, silver bromide, silver iodide, silver iodobromide, silver chloroiodobromide, silver chloroiodide, silver chlorobromide, and silver chloroiodide. .
父、本発明の感光材料の塗布録音は／−２０ｆ／ＴｒＬ
２、特に２〜ｌＯｔ／ｒｒＬ２でおることが好ましい。Father, the coating recording of the photosensitive material of the present invention is /-20f/TrL
2, particularly preferably 2 to 10t/rrL2.
ハロゲン化銀粒子形成または物理熟成の段階においてカ
ド賽つム塩、亜鉛塩、鉛塩、タリウム塩、イリジウム塩
、またはその錯塩、ロジウム塩またはその錯塩、鉄塩ま
７ｔはその錯塩などを共存させてもよい。At the stage of silver halide grain formation or physical ripening, cadmium salts, zinc salts, lead salts, thallium salts, iridium salts, or complex salts thereof, rhodium salts or complex salts thereof, iron salts, or complex salts thereof are allowed to coexist. You can.
本発明のハロゲン化銀写真感光材料の乳剤層及びその他
の層のバインダーとしてテキストラン以外ＫＵゼラチン
、カゼインなどの蛋白質：カルボキシメチルセルロース
、ヒドロキシエチルセルロース等のセルロース化合物：
寒天、でんぷん誘導体等の糖誘導体：合成親水性コロイ
ド例えＦｉポリビニルアルコール、ポＩＪ−Ｎ−ビニル
ピロリドン、ポリアクリル酸共重合体、ポリアクリルア
ミドまたはこれらの誘導体および部分加水分解物樽を使
用することも出来る。As a binder for the emulsion layer and other layers of the silver halide photographic light-sensitive material of the present invention, proteins other than Textran such as KU gelatin and casein; Cellulose compounds such as carboxymethyl cellulose and hydroxyethyl cellulose:
Sugar derivatives such as agar, starch derivatives: synthetic hydrophilic colloids such as polyvinyl alcohol, polyacrylic acid copolymers, polyacrylamide or derivatives thereof and partial hydrolysates can also be used I can do it.
ここに言うゼラチンはいわゆる石灰処理ゼラチン、酸処
理ゼラチンおよび酵素処理ゼラチンを指す。特に好まし
いゼラチンは特開昭６２−ｔ７ヂよ２号に開示さｎてい
る高分子量取分含有ゼラチンである。Gelatin referred to herein refers to so-called lime-processed gelatin, acid-processed gelatin and enzyme-processed gelatin. A particularly preferred gelatin is a high molecular weight fraction-containing gelatin disclosed in JP-A-62-T7-2.
又、本発明の写真感光材料は、写真構成層中に米国特許
第３．≠ｌ／、ｐＨ号、同３．弘ｉｉ。Further, the photographic light-sensitive material of the present invention has U.S. Patent No. 3. ≠l/, pH number, same 3. Hiro ii.
７７２号、特公昭４Ａｊ−よＪＪ／号等に記載のアルキ
ルアクリレート系ラテックスを含むことが出来る。772, Japanese Patent Publication No. 4Aj-YoJJ/, etc., may be included.
本発明の感光性ハロゲン化銀乳剤層に用いられる乳剤は
化学増感することが好ましい。The emulsion used in the photosensitive silver halide emulsion layer of the present invention is preferably chemically sensitized.
化学増感のためには、前記グラフキデ
（Ｇｌａｆｋｉｄｅｓ）１７ｔはゼリクマｙ（ＺｅＬｉ
ｋｍａｎ）らの著Ｖｔりるイハエッチ−７リーザー（Ｊ
ｉ、Ｆｒ１ｅｓｅｒ編デ・グルンドラーゲン・デル・フ
ォトグラフィジエン・プロツエセ・ｄト・ジルベルハロ
ゲニーテン（Ｄｉｅ Ｇｒｕｎｄｌａｇｅｎ ｄｅｒ
Ｐｈｏｔｏｇｒａｐｈｉｓｒ：ｈｅｎ Ｐｒｏｚｅｓ
ｓｅ ｍ１ｔＳ・ｉＩｂｅｒｈａｌｏｇｅｎｉｄｅｎ
）アカデｉツシエ・フエラーグスゲゼルシャフト（Ａｋ
ａｄｅｍｉｓｃｈｅＶｅｒｌａｇｓｇｅｓｅｌｌｓｃｈ
ａｆｔ） 、（、／ ５’ ｔ ｒ ）に記載の方法を
用いることができる。For chemical sensitization, the Glafkides 17t were mixed with ZeLi
Kman) et al.'s Vt Ruruihaetch-7 Reaser (J
i, Fr1eser ed.
Photographer: hen Prozes
se m1tS・iIberhalogeniden
) Akadeitushie Felleragsgesellschaft (Ak
ademischeVerlagsgesellsch
aft), (,/5' tr) can be used.
すなわち、銀イオンと反応し得る硫黄を含む化合物や活
性ゼラチンを用いる硫黄増感法、還元性物質を用いる還
元増感法、金その他の貴金属化合物を用いる貴金属増感
法などを単独または組合せて用いることができる。硫黄
増感剤としては、チ：ｔ５Ａ酸塩、チオ尿素類、チアゾ
ール類、ローダニン類、その他の化合物を用いることが
できる。還元増感剤としては第−丁ず塩、アｄン類、ヒ
ドラジン誘導体、ホルムアミジンスルフィン酸、シラン
化合物などを用いることができる。貴金属増感のために
は全錯塩のほか、白金、イリジウム、パラジウム等の周
期律舜■族の金属の錯塩を用いることができる。That is, a sulfur sensitization method using a compound containing sulfur that can react with silver ions or active gelatin, a reduction sensitization method using a reducing substance, a noble metal sensitization method using gold or other noble metal compounds, etc. are used alone or in combination. be able to. As the sulfur sensitizer, thi:t5A acid salts, thioureas, thiazoles, rhodanines, and other compounds can be used. Examples of reduction sensitizers that can be used include tertiary salts, adnes, hydrazine derivatives, formamidine sulfinic acid, and silane compounds. For noble metal sensitization, in addition to total complex salts, complex salts of metals in the Shun group of the periodic system, such as platinum, iridium, and palladium, can be used.
不発明の感光材料にに安定剤として種々の化合物を官有
させることができる。すなわちアゾール類たとえはベン
ゾチアゾリウム塩、ニトロインダゾール類、トリアゾー
ル類、べ／シトリアゾール類、ペンズイばダゾール類（
特にニトロ−ま次はハロゲン置換体）：へテロ環メルカ
プト化合物類たとえはメルカプトチアゾール類、メルカ
プトベンゾチアゾール類、メルカプトベンズイミダゾー
ル類、メルカプトチアジアゾール類、メルカプトテトラ
ゾール類（特にｌ−）二ニルー！−メルカプトテトラゾ
ール）、メルカプトピリジン類；カルボキシル基やスル
ホン基などの水溶性基を肩する上記のへテロ環メルカプ
ト化合物類；チオケト化合物たとえばオキサゾリンチオ
ン；アザインデン類たとえはテトラアザインデン類：（
特に弘−ヒドロキシ置換（／、Ｊ、Ｊａ、７）テトラア
ザインデン類）：ベンゼンチオスルホン酸類：ベンゼン
ソルフイン酸：などのような安定剤として知らｎた多く
の化合物を加えることができる。Various compounds can be incorporated into the uninvented photographic material as stabilizers. That is, examples of azoles include benzothiazolium salts, nitroindazoles, triazoles, be/citriazoles, and penzibadazoles (
Heterocyclic mercapto compounds such as mercaptothiazoles, mercaptobenzothiazoles, mercaptobenzimidazoles, mercaptothiadiazoles, mercaptotetrazoles (particularly nitro- or halogen-substituted) (particularly l-) di-niru! -mercaptotetrazole), mercaptopyridines; the above-mentioned heterocyclic mercapto compounds bearing a water-soluble group such as a carboxyl group or a sulfone group; thioketo compounds such as oxazolinthione; azaindenes such as tetraazaindenes: (
In particular, many compounds known as stabilizers can be added, such as hydroxy-substituted (/, J, Ja, 7) tetraazaindenes), benzenethiosulfonic acids, benzenesulfinic acids, and the like.
本発明の感光材′料の写真乳剤層ま１９：、は他の構成
層には塗布助剤、帯電防止、スベリ注改良、乳化分散お
よび写真特注改良（たとえは現像促進、硬調比、増感）
など種々の目的で界面活性剤を含んでもよい。The photographic emulsion layer (19) of the light-sensitive material of the present invention contains coating aids, antistatic agents, slip injection improvement, emulsification dispersion, and photographic customization improvements (such as development acceleration, high contrast ratio, sensitization, etc.). )
Surfactants may be included for various purposes such as.
たとえばサポニン（ステロイド系）、アルキレンオキサ
イド誘導体（例えはポリエチレングリコール、ポリエチ
レングリコール／ポリプロピレングリコール縮金物、ポ
リエチレングリコールアルキルエーテル類またはポリエ
チレングリコールアルキルアリールエーテル類、ポリエ
チレングリコールエステル類、ポリエチレングリコール
ソルビタンエステル類、ポリアルキレングリコールアル
キルアミドまたはアばド類、シリコーンのポリエチレン
オキサイド付加物類）、グリシドールＢ導体（ｊｔとえ
はアルケニルコハク酸ポリグリセリド、アルキルフェノ
ールポリグリセリド）、多価アルコールの脂肪酸エステ
刈ｉ糖のアルキルエステル類などの非イオン注界面活性
剤：アルキルヵルボン酸塩、アルキルスルフォン酸塩、
アルキルベンゼンスルフォン酸塩、アルキルナフタレン
スルフォン酸塩、アルキル硫酸エステル類、アルキルリ
ン酸エステル類、Ｎ−アシル−Ｎ−アルキルタウリン酸
、スルホコハク酸エステル類、スルホアルキルポリオキ
シエチレンアルキルフェニルエーテル類、ポリオキシエ
チレンアルキルリン酸エステル類などの工うなカルボキ
シ基、スルホ基、ホスホ基、硫酸エステル基、燐酸エス
テル差等のａｌ注基金含むアニオン界面活性剤ニアばノ
酸類、アミンアルキルスルホン酸類、アばノアルキル硫
酸まｆｃｈ燐酸燐酸エステルアルキルベタイン類、アミ
ンオキシド類などの両件界面活性剤：アルキルアミン塩
類、脂肪族おるいは芳香族第弘級アンモニウム塩類、ピ
リジニウム、イばダゾリウムなどのμ級アンモニウム塩
類、および脂肪族または複素環を含むホスホニウムまた
はスルホニウム塩類などのカチオン界面活性剤を用いる
ことができる。For example, saponins (steroids), alkylene oxide derivatives (such as polyethylene glycol, polyethylene glycol/polypropylene glycol condensates, polyethylene glycol alkyl ethers or polyethylene glycol alkylaryl ethers, polyethylene glycol esters, polyethylene glycol sorbitan esters, polyalkylene Glycol alkylamides or amide compounds, polyethylene oxide adducts of silicone), glycidol B conductors (for example, alkenylsuccinic acid polyglycerides, alkylphenol polyglycerides), alkyl esters of fatty acid esters and sugars of polyhydric alcohols Non-ionic surfactants such as: alkyl carboxylates, alkyl sulfonates,
Alkylbenzene sulfonate, alkylnaphthalene sulfonate, alkyl sulfate, alkyl phosphate, N-acyl-N-alkyl tauric acid, sulfosuccinate, sulfoalkyl polyoxyethylene alkylphenyl ether, polyoxyethylene Anionic surfactants such as alkyl phosphate esters, carboxy groups, sulfo groups, phospho groups, sulfate ester groups, phosphoric acid esters, etc. Niabano acids, amine alkyl sulfonic acids, abanoalkyl sulfates, etc. Both surfactants such as fch phosphoric acid phosphate ester alkyl betaines and amine oxides: alkyl amine salts, aliphatic or aromatic bronchial ammonium salts, μ-class ammonium salts such as pyridinium and ibadazolium, and fats. Cationic surfactants such as phosphonium or sulfonium salts containing groups or heterocycles can be used.
こ扛らの界面活性剤の内ポリオキシエチレン系界面活性
剤及び含フッ素界面活性剤が特に好ましく用いられる。Among these surfactants, polyoxyethylene surfactants and fluorine-containing surfactants are particularly preferably used.
本発明のポリオキシエチレン系界面活性剤は、使用する
写真感光材料の種類、形態又は塗布方式等にニジその使
用量は異なるが、一般には、その変用ｔは写真感光材料
のＡ ｇ ｉモル当夛ｔ、ｏｒ１１９以上でよく、特に
６０〜以上が好ましい。The amount of the polyoxyethylene surfactant of the present invention used varies depending on the type, form, coating method, etc. of the photographic material used, but in general, the modified amount is A g imole of the photographic material. It may be 119 or more, particularly preferably 60 or more.
本発明のポリオキシエチレン系界面活性剤は写真感光材
料の感光性乳剤層に添加するのが好ましいが、非感光性
の層に添加してもよい。The polyoxyethylene surfactant of the present invention is preferably added to a light-sensitive emulsion layer of a photographic light-sensitive material, but it may also be added to a non-light-sensitive layer.
硬化剤とじてに例えは特開昭ｊｊ−／弘２！コ≠に記載
さｎている様な耐拡散性を有した高分子硬化剤、でも良
いし以下に示す工うな低分子硬化剤でも良い。代表的な
例としてはムコクロル酸、ムコブロム酸、ホルムアルデ
ヒド、ジメチロール尿素、トリメチロールメラばン、グ
リオキザール、２．３−ジヒドロキシ−よ−メチル−７
，≠−ジオキサン、グルタルアルデヒドの如きアルデヒ
ド系化合物ニジビニルスルホン、メチレンビスマレイミ
ド、！−アセチルー／、Ｊ−ジアクリロイル−へキサヒ
ドロ−８−トリアジン、ｉ、３．ｚ−トリアクリロイル
−へキサヒドロ−ｓ −トＩＪアジン、’ ＋ ３＋
’ −トリビニルスルホニル−へキサヒドロ−ｓ −ト
リアジン、ビス（ビニルスルホニルエチル）エーテル、
ｌ、３−ビス（ビニルスルホニル）−一一プロ、Ｒノー
ル、／、！−ビス（ビニルスルホニルアセチルアミド）
プロパンの如き活性ビニル系化合物：２．≠−ジクロロ
ー６−ヒドロキシー８−トリアジ・ナトリウム塩、コ、
弘−シクロロ−６−メドキシーＳ−１！Ｊアジン、コ。An example of a hardening agent is JP-A-Shojj-/Hiroshi 2! It may be a polymer curing agent with diffusion resistance as described in ≠, or it may be a low molecular curing agent such as the one shown below. Typical examples include mucochloric acid, mucobromic acid, formaldehyde, dimethylolurea, trimethylolmelaban, glyoxal, 2,3-dihydroxy-y-methyl-7
,≠-dioxane, aldehyde compounds such as glutaraldehyde, divinyl sulfone, methylene bismaleimide,! -acetyl/, J-diacryloyl-hexahydro-8-triazine, i, 3. z-Triacryloyl-hexahydro-s-IJ azine,' + 3+
'-trivinylsulfonyl-hexahydro-s-triazine, bis(vinylsulfonylethyl) ether,
l,3-bis(vinylsulfonyl)-11pro,R-nor,/,! -Bis(vinylsulfonylacetylamide)
Active vinyl compounds such as propane: 2. ≠-dichloro-6-hydroxy-8-triazid sodium salt,
Hiro-cyclo-6-medoxy S-1! J Azin, Co.
弘−ジクロロ−６−（≠−スルホアニリノ）−３−トリ
アジン・ナトリウム塩、２．＋Ｌ−ジクロロ−６−（コ
ースルホエチルアｄ）） −ｓ −）リアジン、Ｎ、Ｎ
′−ビス（２−クロロエチルカルバばル）ピはラジンの
如籾活性ハロゲン系化合物：ビス（２，ｊ−二ポ午ンプ
ロビル）メチルプロピルアンモニウム−ｐ−トルエンス
ルホン酸塩の如きエポキシ系化合物；λ、ｕ、Ａ−トリ
エチレンイεノーＳ−）リアジンの如さエチレンイミン
系化合物：／、Ｊ−ジ（メタンスルホンオキシ）エタン
の如きメタルスルホン酸エステル系化合物；ジシクロへ
キシルカルボシイばドの如きカルボジイミド系化合物：
２．！−ジメチルイソオキサゾール・過塩素酸塩の如き
インオキサゾール系化合物ニクロム間くん、酢酸クロム
の如き無機系化合物を挙げることができる。Hiro-dichloro-6-(≠-sulfoanilino)-3-triazine sodium salt, 2. +L-dichloro-6-(cosulfoethyl d)) -s-) riazine, N,N
'-Bis(2-chloroethylcarbabal)p is an active halogen compound such as radin: an epoxy compound such as bis(2,j-dipropylammonium)methylpropylammonium-p-toluenesulfonate; Ethyleneimine compounds such as λ, u, A-triethylene ε no S-) riazine; metal sulfonic acid ester compounds such as /, J-di(methanesulfonoxy)ethane; carbodiimide compounds such as dicyclohexylcarboside Compound:
2. ! Examples include inoxazole compounds such as dimethyl isoxazole perchlorate, and inorganic compounds such as nichrome and chromium acetate.
こｎらの化合物の中で特に好ましいのは、ビニルスルホ
ン基を肩する化合物及び活性ハロゲン化合物である。Particularly preferred among these compounds are compounds bearing a vinyl sulfone group and active halogen compounds.
本発明の写真乳剤は、メチン色素類その他によって分光
増感さｎる。用いらｎる色素には、シアニン色素、メロ
シアニン色素、複合シアニン色素、複合メロンアニン色
素、ホロポーラ−シアニン色素、ヘミシアニン色素、ス
チリル色素、およびヘミオキソノール色素が包含さｎる
。特に石川な色素はシアニン色素、メロシアニン色素お
よび複合メロンアニン色素に属する色素である。これら
の色素類には塩基注異節環核としてシアニン色素類に通
常利用さｎる核のいずｎをも適用できる。すなわち、ビ
ロリン核、オキサゾリン核、チアゾリン核、ビロール核
、オキサゾール核、チアゾール核、セレナゾール核、イ
ずダゾール核、テトラゾール核、ピリジン核など：こｎ
らの核に脂環式炭化水素環が融合した核：お工びこれら
の核に芳香族炭化水素環が融合し九核：すなわち、イン
ドレニン核、ベンズインドレニン核、インドール核、ベ
ンズオキサゾール核、ナフトオキサゾール核、ベンゾチ
アゾール核、ナフトチアゾール核、ベンゾセレナゾール
核、ベンズイミダゾール核、キノリン核などが適用でき
る。これらの核に炭素原子上に置換されていてもよい。The photographic emulsions of this invention are spectrally sensitized with methine dyes and others. Dyes that can be used include cyanine dyes, merocyanine dyes, complex cyanine dyes, complex melonanine dyes, holopolar cyanine dyes, hemicyanine dyes, styryl dyes, and hemioxonol dyes. In particular, Ishikawa pigments are pigments belonging to cyanine pigments, merocyanine pigments, and complex melonanine pigments. For these dyes, any of the nuclei commonly used for cyanine dyes can be used as the base annular ring nucleus. Namely, viroline nucleus, oxazoline nucleus, thiazoline nucleus, virol nucleus, oxazole nucleus, thiazole nucleus, selenazole nucleus, izudazole nucleus, tetrazole nucleus, pyridine nucleus, etc.
A nucleus in which an alicyclic hydrocarbon ring is fused to these nuclei: 9 nuclei in which an aromatic hydrocarbon ring is fused to these nuclei: indolenine nucleus, benzindolenine nucleus, indole nucleus, benzoxazole nucleus, naphtho An oxazole nucleus, a benzothiazole nucleus, a naphthothiazole nucleus, a benzoselenazole nucleus, a benzimidazole nucleus, a quinoline nucleus, etc. are applicable. These nuclei may be substituted on carbon atoms.
メロシアニン色素または複合メロシアニン色素にはケト
メチレン構造を有する核として、ピラゾリン−！−オン
核、チオヒダントイン核、コーチオオキサゾリジンーコ
、弘−ジオン核、チアゾリジン−２，弘−ジオン核、ロ
ーダニン核、チオバルビッール除核などのｊ−ｊ員異節
環核を適用することができる。Merocyanine dyes or composite merocyanine dyes contain pyrazoline-! as a core having a ketomethylene structure. j-j member heteroartic ring nuclei such as -one nucleus, thiohydantoin nucleus, corchioxazolidine nucleus, Hiro-dione nucleus, thiazolidine-2, Hiro-dione nucleus, rhodanine nucleus, and thiobarbyl enucleation can be applied. .
本発明に於ける増感色素の使用量としては、銀モル当ｐ
／Ｘ／（１６〜Ｊｘ１０−３モルであルコとが好ましい
。The amount of sensitizing dye used in the present invention is p per mole of silver.
/X/(16 to Jx10-3 mol, preferably with alcohol.
本発明において増感色素は塗布する前でのとこの時点で
添加しても良いが、化学増感が終了する前までに添加す
るのが好ましい。In the present invention, the sensitizing dye may be added at this point before coating, but it is preferably added before the chemical sensitization is completed.
本発明の写真乳剤にに色像形成カプラー、すなわち芳香
族アばン（通常第一級アばン）現像主薬の酸化生成物と
反応して色素ｔ−ｑ成する化合物（以下カプラーと略記
する）を含んでもよい。カプラーは分子中にバラスト基
とよばｎる疎水基を有する非拡散性のものが望ましい。The photographic emulsion of the present invention contains a color image-forming coupler, that is, a compound that reacts with the oxidation product of an aromatic aban (usually a primary aban) developing agent to form a dye t-q (hereinafter abbreviated as coupler). ) may also be included. The coupler is preferably a non-diffusible coupler having a hydrophobic group called a ballast group in its molecule.
カプラーは銀イオンに対し参当量性あるいは２当量性の
どちらでもよい。また色補正の効果をもつカラードカプ
ラー、あるいは現像にともなって現像抑制剤を放出する
カプラー（いわゆるＤＩＲカプラー）を含んでも工い。The coupler may be either equivalent or bi-equivalent to the silver ion. It may also contain a colored coupler that has a color correction effect or a coupler that releases a development inhibitor during development (so-called DIR coupler).
カプラーはカップリング反応の生底物が無色であるよう
なカプラーでもよい。The coupler may be such that the raw material of the coupling reaction is colorless.
黄色発色カプラーとしては公知の開鎖ケトメチレン系カ
プラーを用いることができる。こしらのうちベンゾイル
アセトアニリド系及びピバロイルアセトアニリド系化合
物に有利である。As the yellow coloring coupler, a known open-chain ketomethylene coupler can be used. Among these, benzoylacetanilide-based and pivaloylacetanilide-based compounds are advantageous.
マゼンタカプラーとしてはピラゾロン化合物、インダシ
ロン系化合物、シアノアセチル化合物などを用いること
ができ、特にピラゾロン系化合物に有利である。As the magenta coupler, pyrazolone compounds, indacylon compounds, cyanoacetyl compounds, etc. can be used, and pyrazolone compounds are particularly advantageous.
シアンカプラーとしてはフェノール系化合物、ナフトー
ル系化合物などを用いることができる。As the cyan coupler, phenolic compounds, naphthol compounds, etc. can be used.
本発明のハロゲン化銀写真感光材料の保護層は、親水性
コロイドからなる層であシ、使用される親水性コロイド
としては前述したものが用いられる。The protective layer of the silver halide photographic light-sensitive material of the present invention is a layer consisting of a hydrophilic colloid, and the hydrophilic colloid used is one described above.
また、保護層は、単層であっても重層となっていても工
い。In addition, the protective layer may be a single layer or a multilayer.
本発明のハロゲン化銀写真感光材料の乳剤層又は保護層
中に、好ましくは、保護層中にはマット剤及び／又は平
滑剤などを添加しても工い。マット剤の例としては適当
な粒径（粒径０．Ｊ〜ｊμのものまたは、保護層の厚味
の２倍以上、特に弘倍以上のものが好ましい）のポリメ
チルメタアクリレートなどのごとき水分散性ビニル重合
体のごときＭ様化合物又はハロゲン化銀、硫酸ストロン
チュームバリウムなどのごとき無機化合物などが好まし
く用いられる。平滑剤はマット剤と類似した接着故障防
止に役立つ他、特に映画用フィルムの撮影時もしくに映
写時のカメラ適合性に関係する摩擦特注の改良に有効で
あシ、具体的な例としては流動パラフィン、高級脂肪酸
のエステル類などのごときワックス類、ポリフッ素化炭
化水素類もしくはその訪導体、ポリアルキルポリシロキ
サン、ポリアルキルポリシロキサン、ポリアルキルアリ
ールポリシロキサン、もしくはそれらのアルキレンオキ
サイド付カロ誘導体のごときシリコーン類などが好まし
く用いられる。A matting agent and/or a smoothing agent may preferably be added to the emulsion layer or protective layer of the silver halide photographic material of the present invention. An example of a matting agent is water such as polymethyl methacrylate with an appropriate particle size (preferably a particle size of 0.J to Jμ or a particle size of at least twice the thickness of the protective layer, particularly at least 10 times the thickness of the protective layer). M-like compounds such as dispersible vinyl polymers or inorganic compounds such as silver halide, barium strontium sulfate, etc. are preferably used. Smoothing agents help prevent adhesion failure similar to matting agents, and are particularly effective in improving friction customization related to camera compatibility during filming or projection of motion picture films.Specific examples include: Liquid paraffin, waxes such as esters of higher fatty acids, polyfluorinated hydrocarbons or their derivatives, polyalkylpolysiloxanes, polyalkylpolysiloxanes, polyalkylarylpolysiloxanes, or their alkylene oxide-attached derivatives. Silicones such as the like are preferably used.
本発明のハロゲン化銀写真感光材料には、他に、必要に
応じて中間層、フィルター層、などを設けることができ
る。The silver halide photographic material of the present invention may also be provided with an intermediate layer, a filter layer, etc., if necessary.
本発明のハロゲン化銀写真感光材料としては、具体的に
はｘｉＷ＆光材料、リス感光材料、黒白撮影感光材料、
カラーネガ感光材料、カラー反転感光材料、カラー印画
紙などを挙げることができる。Specifically, the silver halide photographic materials of the present invention include xiW & optical materials, lithographic materials, black and white photographic materials,
Examples include color negative photosensitive materials, color reversal photosensitive materials, and color photographic paper.
好１しくに黒白撮影感光材料が良い。Preferably, a black and white photosensitive material is used.
本発明の写真感光材料には、その他必要に応じて種々の
添ＶＯ剤を用いることができる。例えば、現像促進剤、
螢光増白剤、色カブリ防止剤、紫外線吸収剤、などであ
る。具体的には、リサーチ・ディスクロージャー（ＲＥ
ＳＥＡＪに）ｉ ＤＩＳＣＬＯ８ＵＲＥ）／７４号第２
ｌｒ〜３０頁（ＲＤ−／７６＄Ｊ、１９７１年）に記載
さｎ九ものを用いることができる。In the photographic material of the present invention, various other VO agents may be used as necessary. For example, development accelerator,
These include fluorescent whitening agents, color antifoggants, and ultraviolet absorbers. Specifically, research disclosure (RE)
SEAJ) i DISCLO8URE)/74 No. 2
1r~30 (RD-/76$J, 1971) can be used.
又、本発明の感光材料の現像処理に関してもＲＤ−／７
６≠３の第２ｒ〜３０頁の記載を参考にすることかで色
る。Also, regarding the development processing of the photosensitive material of the present invention, RD-/7
It depends on whether you refer to the description on pages 2r to 30 of 6≠3.
又、本発明の感光材料を処理する定着液としては富士写
真フィルム■製のフジフィックス、スーツ〈−フジフィ
ックス、富士ＤＰフィックス、スーパーフジフィックス
ＤＰ、米国コダック社製のＦ−乙、ＫＯＤＡＫ Ｆｉｘ
ｅｒ、小西六社製のコニフィックス、コニフィックスラ
ピント、その他オリフィックス、マイフィックス、ニジ
フィックス、８産うビットフィクサーＦ、日量ラビット
フィクサーＰ、ノ鵞ンフィックスＦ％／ぐンフィックス
Ｐ１マイロールＦ、オリエンタルＱＦなどがある。Examples of fixing solutions for processing the light-sensitive material of the present invention include Fuji Fix, Suit <-Fuji Fix, Fuji DP Fix, Super Fuji Fix DP, manufactured by Fuji Photo Film ■, F-Otsu, and KODAK Fix manufactured by Kodak Company, USA.
er, Conifix manufactured by Konishi Rokusha, Conifix Rapinto, other orifices, My Fix, Niji Fix, 8-year-old Bit Fixer F, Daily Rabbit Fixer P, Nogo Fix F%/Gun Fix P1 My There are Roll F, Oriental QF, etc.
本発明の感光材料に用いらｎる代表的支持体はセルロー
ズナイトレートフィルム、セルローズアセテートフィル
ム、ポリビニルアセタールフィルム、ポリスチレンフィ
ルム、ポリエチレンテレフタレートフィルム及び他のポ
リエステル並びにガラス、紙、金属、木等がおばら牡る
。Typical supports used in the photosensitive material of the present invention include cellulose nitrate film, cellulose acetate film, polyvinyl acetal film, polystyrene film, polyethylene terephthalate film and other polyesters, as well as glass, paper, metal, wood, etc. oyster
（実施例）
以下に実施例を挙げて本発明を例証するが、本発明はこ
ｎに限定されるものでない。(Example) The present invention will be illustrated below with reference to Examples, but the present invention is not limited thereto.
（実施例１）
ｆｉｌ 感光性ハロゲン化銀乳剤の調製臭化カリウム
および沃化カリウムと硝酸銀をゼラチ／水浴液に激しく
攪拌しながら添加し、平均粒径０．６μの厚板状の沃臭
化銀（平均ヨード含有率６モルチ）を調製した。その後
通常の沈澱法にニジ水洗し、その後塩化金酸およびチオ
硫酸ナトリウムを用い沈金・硫黄増感法に工）化学増感
を行ない感光性沃臭化銀乳剤Ａｔ−得友。(Example 1) Preparation of fil Photosensitive Silver Halide Emulsion Potassium bromide and potassium iodide and silver nitrate were added to the gelatin/water bath with vigorous stirring to form a slab-like iodobromide emulsion with an average grain size of 0.6μ. Silver (average iodine content 6 molty) was prepared. Thereafter, the conventional precipitation method was followed by washing with water, followed by chemical sensitization using chloroauric acid and sodium thiosulfate using a precipitation/sulfur sensitization method to obtain a photosensitive silver iodobromide emulsion.
感光性沃臭化銀乳剤Ａと同様に但し調製温度と沃化カリ
ウムの量を調節してノ・ログン化銀乳剤Ｂ（平均ヨード
含有率ｉｏ％、平均粒径ｉ、ｏμの厚板状沃臭化銀〕を
ｖＩ４裂した。A plate-shaped silver iodobromide emulsion B (average iodine content io%, average grain size i, oμ silver bromide] was cleaved into vI4.
＋２１ Ｉｎ！布試料の作製
トリアセチルセルロース支持体上に下記層構成を設けて
試料／〜１３を作成した。+21 In! Preparation of fabric samples Samples/-13 were prepared by providing the following layer structure on a triacetyl cellulose support.
（最下層ン
バインダー：ゼラチン−／ １．Ａｔ／ｍ２塗布助
剤 ：ポリｐ−スチレンスル
ホン酸カリウム塩
／Ｊ 、ｏ■／ｍ２
（定着促進剤）
バインダー：ゼラチン−／ ／ＳＦ／７ＦＬ２
定着促進剤： ０．ｌｔｆ／／ｍ２−ｔ
染料
２’Ａｍ９／ｍ２
染料
／ ｊ ｒｎ９／ ７ＦＬ ２
（中間層）
バインダー：ゼラチン−７０，弘？ ／ ｍ ２塗布助
剤 ：ポリｐ−スチレンスル
ホン酸カリウム塩
３、Ｊｒｒｒｇ／ＴｒＬ２
（乳剤層−ｌ）
塗布銀量 ：乳剤Ａ Ｉ、１９７ｍ２バイン
ダー：ゼラチンーコ ２１／ｍ２増感色素 ：Ｄ
ｙｅ−／ ２．ｌｑ／Ａｇｌ？添加剤： Ｃ１ｇ）１
ａ５０＋ＣＨ４Ｃ）１２０←Ｈｒ、ｒダ／Ａｇ／Ｐ
塗布助剤 ：ポリｐ−スチレンスルホン酸カリウム塩
ｊ （７ｍ９ ／ ｍ ２硬 膜 剤：／、！−
ビス（ビニルスルホニルアセドアイド）エタン
ヂＯ■／□２
（乳剤層−２）
塗布銀量 ：乳剤Ｂ ≠１／ｍ２バインダ
ー：ゼラチンーλ ６．Ｉｆ／ｍ２増感色素 ：Ｄｙ
ｅ−／ ２．／ｑ／Ａｇ／Ｌ？添加剤： Ｃ１３ｌ−
１３５０＋Ｃ）１２ｃ）１２０→−Ｈ２Ｏ
ｚ、ｒ■／Ａｇ／Ｓ’
塗布助剤 ：ポリｐ−スチレンスルホン酸カリウム塩
／７０Ｔｎ９／ｍ２
λ、 ／ ｍ９／ｋｇ ／ ｒ
（表面保護層）
バインダー：ゼラチン−３ｏ、７１／ｍ２界面活性剤：
！Ｏ■／ｍ”
ｃ３ｔ＋７
ＣｇＦ１７ＳＯ２Ｎ（ＣＨ２ＣＨｚＯ） ４ （ｃ）ｔ
２ ） ＋８０ａＮａ≠、！ｍ９／ｍ２
３Ｈ７
ＣＢＦ１７８０２Ｎ（−Ｃ）ｉ２Ｃ）ｉ２０）−Ｈｊ
、 ０ ”９／ ｍ ”丁べ多剤 ： ）ｉ３１ｃ１５
ｃＯＯｃ五６Ｈ３３’ｆｉ７ｍ９／ｍ２
マット剤 ：ポリメチルメタクリレ
ート微粒子（平均粒子
サイＸ Ｊａ）０．ｌＪｍｔｐ／７ＦＬ２（３）セン
シトメトリー
ｃｎらの試料を２ｚ０Ｃｂｚｃ４Ｒｎｏ温ａ度で塗布後
７日間保存した。(Bottom layer binder: Gelatin-/1.At/m2 Coating aid: Poly p-styrene sulfonic acid potassium salt/J, o/m2 (Fixing accelerator) Binder: Gelatin-//SF/7FL2
Fixation accelerator: 0. ltf//m2-t Dye 2'Am9/m2 Dye/j rn9/ 7FL 2 (Intermediate layer) Binder: Gelatin-70, Hiro? / m2 Coating aid: Poly p-styrene sulfonic acid potassium salt 3, Jrrrg/TrL2 (emulsion layer-l) Coating silver amount: Emulsion A I, 197 m2 Binder: Gelatinco 21/m2 Sensitizing dye: D
ye-/ 2. lq/Agl? Additive: C1g)1
a50+CH4C) 120←Hr, rda/Ag/P Coating aid: Poly p-styrene sulfonic acid potassium salt
j (7m9/m2 hardener:/,!-
Bis(vinylsulfonylacedoide)ethane O■/□2 (Emulsion layer-2) Coated silver amount: Emulsion B ≠1/m2 Binder: Gelatin-λ 6. If/m2 sensitizing dye: Dy
e-/2. /q/Ag/L? Additive: C13l-
1350+C) 12c) 120→-H2O z, r■/Ag/S' Coating aid: Poly p-styrene sulfonic acid potassium salt
/70Tn9/m2 λ, /m9/kg/r (Surface protective layer) Binder: Gelatin-3o, 71/m2 Surfactant: ! O■/m” c3t+7 CgF17SO2N(CH2CHzO) 4 (c)t
2) +80aNa≠,! m9/m2 3H7 CBF17802N(-C)i2C)i20)-Hj
, 0 "9/m" Chobe multi-drug: ) i31c15
cOOc56H33'fi7m9/m2 Matting agent: Polymethyl methacrylate fine particles (average particle size X Ja) 0. lJmtp/7FL2 (3) Sensitometry The sample of cn et al. was stored at 2z0Cbzc4Rno temperature a degree for 7 days after application.
（イ）カブリの測定
各々の試料を下記の現像液で２０°ＣＩ２分間現像し、
定着、水洗しカブリを測定し念。(b) Measurement of fog Develop each sample with the following developer for 2 minutes at 20°C.
Fix, wash with water, and measure fog to be sure.
現像液
メトール ２７亜硫酸ナ
トリウム １ｏｏｙハイドロキノン
！１ボラソクス・ｚｏ）ｉ
２０ コ２水を加えて
／ｌカブリ（ΔＤ）はタイプ試料／との
カブリの差として示す。Developer Metol 27 Sodium Sulfite 1ooy Hydroquinone
! 1 borasox・zo)i
20 Add 2 water
/l fog (ΔD) is shown as the difference in fog from type sample /.
（ロ）高湿時の接着
各々の試料ｔ２ｊ ０ＣＩＯチの条件で２時間調湿した
後、各々乳剤面側と乳剤面と反対の側をくっつけた形で
重ねる。重ね合わせ次試料の上に／片≠儂の正方形のカ
ラス板を置き、その上に重さｔｏｏｔを乗せた後≠０’
（：１日放置して接着し九跡を評価し友。(b) Adhesion at high humidity Each sample t2j After conditioning the humidity for 2 hours under the conditions of 0CIO, stack each sample with the emulsion side and the side opposite to the emulsion side stuck together. After stacking, place a square glass plate with / piece ≠ mine on top of the sample, and after placing the weight toot on it ≠ 0'
(: Leave it for a day, glue it and evaluate the nine traces.
実用許容レベル：Ｏ
実用許容外 ：Ｘ
ゼラチンｌ〜３の高分子ｔｇ分
（特開昭４２−４７９！λ号による高分子量取分〕化合
物−ｌ
トリメチロールプロノξン
化合物−２
ハイドロキノン
テキストラン
平均分子量 ｉｔ万
第１表かられかるように本発明の構成の試料はカブリが
低くなおかつ高湿時の接着が良い試料であることがわか
る。Practical permissible level: O Practical permissible: As can be seen from Table 1, the sample with the structure of the present invention has low fog and good adhesion at high humidity.
Claims (1)
を有し、かつ感光材料中にテキストランと乾燥カブリ防
止剤の両方を含むことを特徴とするハロゲン化銀写真感
光材料。A silver halide photographic material comprising at least one layer containing silver halide grains on a support, and containing both a text run and a drying antifoggant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31792487A JPH01159635A (en) | 1987-12-16 | 1987-12-16 | Silver halide photographic sensitive material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31792487A JPH01159635A (en) | 1987-12-16 | 1987-12-16 | Silver halide photographic sensitive material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01159635A true JPH01159635A (en) | 1989-06-22 |
Family
ID=18093558
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP31792487A Pending JPH01159635A (en) | 1987-12-16 | 1987-12-16 | Silver halide photographic sensitive material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01159635A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0768570A1 (en) * | 1995-10-09 | 1997-04-16 | Konica Corporation | Image forming method |
| JP2009012240A (en) * | 2007-07-03 | 2009-01-22 | Seiko Epson Corp | Lid body, recorder |
-
1987
- 1987-12-16 JP JP31792487A patent/JPH01159635A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0768570A1 (en) * | 1995-10-09 | 1997-04-16 | Konica Corporation | Image forming method |
| US5723265A (en) * | 1995-10-09 | 1998-03-03 | Konica Corporation | Image forming method |
| JP2009012240A (en) * | 2007-07-03 | 2009-01-22 | Seiko Epson Corp | Lid body, recorder |
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