JPH0114643B2 - - Google Patents
Info
- Publication number
- JPH0114643B2 JPH0114643B2 JP57178168A JP17816882A JPH0114643B2 JP H0114643 B2 JPH0114643 B2 JP H0114643B2 JP 57178168 A JP57178168 A JP 57178168A JP 17816882 A JP17816882 A JP 17816882A JP H0114643 B2 JPH0114643 B2 JP H0114643B2
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- mol
- insulated wire
- resin
- diisocyanate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920005989 resin Polymers 0.000 claims description 61
- 239000011347 resin Substances 0.000 claims description 61
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 39
- 239000004962 Polyamide-imide Substances 0.000 claims description 29
- 238000006243 chemical reaction Methods 0.000 claims description 29
- 229920002312 polyamide-imide Polymers 0.000 claims description 29
- 150000003951 lactams Chemical class 0.000 claims description 24
- 230000002829 reductive effect Effects 0.000 claims description 21
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical group CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 19
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical group O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims description 18
- 150000002923 oximes Chemical class 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 15
- 239000011342 resin composition Substances 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 13
- 150000008064 anhydrides Chemical class 0.000 claims description 10
- 125000000524 functional group Chemical group 0.000 claims description 10
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical group C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 9
- 239000004020 conductor Substances 0.000 claims description 9
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical group OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 claims description 6
- WHIVNJATOVLWBW-SNAWJCMRSA-N methylethyl ketone oxime Chemical group CC\C(C)=N\O WHIVNJATOVLWBW-SNAWJCMRSA-N 0.000 claims description 4
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 4
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 125000004018 acid anhydride group Chemical group 0.000 claims description 2
- 150000003627 tricarboxylic acid derivatives Chemical class 0.000 claims 2
- 230000000903 blocking effect Effects 0.000 claims 1
- 239000002966 varnish Substances 0.000 description 29
- 239000000243 solution Substances 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 10
- 230000009257 reactivity Effects 0.000 description 10
- 239000002253 acid Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 230000000873 masking effect Effects 0.000 description 8
- -1 aromatic isocyanate Chemical class 0.000 description 7
- 239000012212 insulator Substances 0.000 description 7
- 150000007513 acids Chemical class 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 150000008065 acid anhydrides Chemical class 0.000 description 4
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229920006122 polyamide resin Polymers 0.000 description 4
- 239000005056 polyisocyanate Substances 0.000 description 4
- 229920001228 polyisocyanate Polymers 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 150000003628 tricarboxylic acids Chemical class 0.000 description 3
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- VQVIHDPBMFABCQ-UHFFFAOYSA-N 5-(1,3-dioxo-2-benzofuran-5-carbonyl)-2-benzofuran-1,3-dione Chemical compound C1=C2C(=O)OC(=O)C2=CC(C(C=2C=C3C(=O)OC(=O)C3=CC=2)=O)=C1 VQVIHDPBMFABCQ-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 244000028419 Styrax benzoin Species 0.000 description 2
- 235000000126 Styrax benzoin Nutrition 0.000 description 2
- 235000008411 Sumatra benzointree Nutrition 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- 229960002130 benzoin Drugs 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000002981 blocking agent Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- VEZUQRBDRNJBJY-UHFFFAOYSA-N cyclohexanone oxime Chemical compound ON=C1CCCCC1 VEZUQRBDRNJBJY-UHFFFAOYSA-N 0.000 description 2
- 238000007607 die coating method Methods 0.000 description 2
- 230000004069 differentiation Effects 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 235000019382 gum benzoic Nutrition 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- 238000005829 trimerization reaction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- FZENGILVLUJGJX-NSCUHMNNSA-N (E)-acetaldehyde oxime Chemical compound C\C=N\O FZENGILVLUJGJX-NSCUHMNNSA-N 0.000 description 1
- ODIGIKRIUKFKHP-UHFFFAOYSA-N (n-propan-2-yloxycarbonylanilino) acetate Chemical class CC(C)OC(=O)N(OC(C)=O)C1=CC=CC=C1 ODIGIKRIUKFKHP-UHFFFAOYSA-N 0.000 description 1
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
- LDXJRKWFNNFDSA-UHFFFAOYSA-N 2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]ethanone Chemical compound C1CN(CC2=NNN=C21)CC(=O)N3CCN(CC3)C4=CN=C(N=C4)NCC5=CC(=CC=C5)OC(F)(F)F LDXJRKWFNNFDSA-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- RLHGFJMGWQXPBW-UHFFFAOYSA-N 2-hydroxy-3-(1h-imidazol-5-ylmethyl)benzamide Chemical compound NC(=O)C1=CC=CC(CC=2NC=NC=2)=C1O RLHGFJMGWQXPBW-UHFFFAOYSA-N 0.000 description 1
- WMRCTEPOPAZMMN-UHFFFAOYSA-N 2-undecylpropanedioic acid Chemical compound CCCCCCCCCCCC(C(O)=O)C(O)=O WMRCTEPOPAZMMN-UHFFFAOYSA-N 0.000 description 1
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 1
- HENCHDCLZDQGIQ-UHFFFAOYSA-N 3-[3,5-bis(2-carboxyethyl)-2,4,6-trioxo-1,3,5-triazinan-1-yl]propanoic acid Chemical compound OC(=O)CCN1C(=O)N(CCC(O)=O)C(=O)N(CCC(O)=O)C1=O HENCHDCLZDQGIQ-UHFFFAOYSA-N 0.000 description 1
- UITKHKNFVCYWNG-UHFFFAOYSA-N 4-(3,4-dicarboxybenzoyl)phthalic acid Chemical compound C1=C(C(O)=O)C(C(=O)O)=CC=C1C(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 UITKHKNFVCYWNG-UHFFFAOYSA-N 0.000 description 1
- AIVVXPSKEVWKMY-UHFFFAOYSA-N 4-(3,4-dicarboxyphenoxy)phthalic acid Chemical compound C1=C(C(O)=O)C(C(=O)O)=CC=C1OC1=CC=C(C(O)=O)C(C(O)=O)=C1 AIVVXPSKEVWKMY-UHFFFAOYSA-N 0.000 description 1
- 239000004970 Chain extender Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- ZWXPDGCFMMFNRW-UHFFFAOYSA-N N-methylcaprolactam Chemical compound CN1CCCCCC1=O ZWXPDGCFMMFNRW-UHFFFAOYSA-N 0.000 description 1
- OMRDSWJXRLDPBB-UHFFFAOYSA-N N=C=O.N=C=O.C1CCCCC1 Chemical compound N=C=O.N=C=O.C1CCCCC1 OMRDSWJXRLDPBB-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- NBJODVYWAQLZOC-UHFFFAOYSA-L [dibutyl(octanoyloxy)stannyl] octanoate Chemical compound CCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCC NBJODVYWAQLZOC-UHFFFAOYSA-L 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- STZIXLPVKZUAMV-UHFFFAOYSA-N cyclopentane-1,1,2,2-tetracarboxylic acid Chemical compound OC(=O)C1(C(O)=O)CCCC1(C(O)=O)C(O)=O STZIXLPVKZUAMV-UHFFFAOYSA-N 0.000 description 1
- 230000009089 cytolysis Effects 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 238000006114 decarboxylation reaction Methods 0.000 description 1
- 125000006159 dianhydride group Chemical group 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- AIJZIRPGCQPZSL-UHFFFAOYSA-N ethylenetetracarboxylic acid Chemical compound OC(=O)C(C(O)=O)=C(C(O)=O)C(O)=O AIJZIRPGCQPZSL-UHFFFAOYSA-N 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- SQDFHQJTAWCFIB-UHFFFAOYSA-N n-methylidenehydroxylamine Chemical compound ON=C SQDFHQJTAWCFIB-UHFFFAOYSA-N 0.000 description 1
- OBKARQMATMRWQZ-UHFFFAOYSA-N naphthalene-1,2,5,6-tetracarboxylic acid Chemical compound OC(=O)C1=C(C(O)=O)C=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 OBKARQMATMRWQZ-UHFFFAOYSA-N 0.000 description 1
- DOBFTMLCEYUAQC-UHFFFAOYSA-N naphthalene-2,3,6,7-tetracarboxylic acid Chemical compound OC(=O)C1=C(C(O)=O)C=C2C=C(C(O)=O)C(C(=O)O)=CC2=C1 DOBFTMLCEYUAQC-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229920003055 poly(ester-imide) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- RTHVZRHBNXZKKB-UHFFFAOYSA-N pyrazine-2,3,5,6-tetracarboxylic acid Chemical compound OC(=O)C1=NC(C(O)=O)=C(C(O)=O)N=C1C(O)=O RTHVZRHBNXZKKB-UHFFFAOYSA-N 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 150000000000 tetracarboxylic acids Chemical class 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- LUEGQDUCMILDOJ-UHFFFAOYSA-N thiophene-2,3,4,5-tetracarboxylic acid Chemical compound OC(=O)C=1SC(C(O)=O)=C(C(O)=O)C=1C(O)=O LUEGQDUCMILDOJ-UHFFFAOYSA-N 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/303—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups H01B3/38 or H01B3/302
- H01B3/306—Polyimides or polyesterimides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00Â -Â C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/14—Polyamide-imides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/294—Coated or with bond, impregnation or core including metal or compound thereof [excluding glass, ceramic and asbestos]
- Y10T428/2942—Plural coatings
- Y10T428/2947—Synthetic resin or polymer in plural coatings, each of different type
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Insulating Materials (AREA)
- Insulated Conductors (AREA)
- Polyurethanes Or Polyureas (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Description
æ¬çºæã¯çµ¶çžé»ç·ã®è£œé æ³ã«é¢ããã
åŸæ¥æè¡ã«ãããŠãèç±é»ç·çšã¯ãã¹ã«çšãã
ããããªã¢ããã€ããæš¹èã¯åæ溶åªãšããŠïŒ®â
ã¡ãã«ãããªãã³ïŒNMPïŒãçšããŠåŸãããé
å ç²åºŠïŒæ¿åºŠïŒ0.5gïŒdlã溶åªïŒãžã¡ãã«ããªã«
ã ã¢ããã枬å®æž©åºŠïŒ30âïŒã0.4ãè¶ããåå
ã«é«ããããååéã®ãã®ãäž»ãšããŠçšããããŠ
ãããäžæ¹ãé»ç·çšã¯ãã¹ã®æº¶æ¶²ç²åºŠã¯ãã€ã¹å¡
è£ ã®å Žåãå¡è£ äœæ¥æ§ã®å¶çŽãã30ãã¢ãºïŒ30
âïŒä»è¿ã«èšå®ãããŠããããããã®æ¡ä»¶ãæºè¶³
ããäžèšããé«ååéã®ããªã¢ããã€ããæš¹èã®
æš¹èåã®å«æéã¯è¯æº¶åªã§ããNMPã䜿çšããŠ
ãããã30ééïŒ ãé«æš¹èååã®éçå€ãšãªã€ãŠ
ãããåŸã€ãŠããããé«ååéã®ããªã¢ããã€ã
ãæš¹èãé»ç·çšã¯ãã¹ã«çšããå Žåãé«äŸ¡ãª
NMPãå€éã«äœ¿çšããããåŸãã³ã¹ãäžåé¡ãš
ãªã€ãŠããã NMPã®äœ¿çšéãæžå°ãããé«æš¹èååããã
ãšã«ãã€ãŠã³ã¹ãäœæžãå³ãã²ãšã€ã®æ¹æ³ã¯æš¹è
ã®äœååéåã§ãããããããªããããžã€ãœã·ã¢
ããŒããšããªã«ã«ãã³é žç¡æ°Žç©ãšããåŸãããã
ãªã¢ããã€ããæš¹èã®éå ç²åºŠã0.4以äžã«äœå
åéåãããšãæš¹èã®æ«ç«¯å®èœåºæ¿åºŠãå¢å ãã
çµæãåŸãããã¯ãã¹ã¯çµæ¥ã«ãã挞次å¢ç²ãã
貯èµå®å®æ§ãèããäœäžããåé¡ãçãããçµæ¥
ã«ããå¢ç²ããå Žåã«ã¯ãäŸãã°é»ç·çšã¯ãã¹ãš
ããŠçšããå Žåãæåã«èšå®ããå¡è£ æ¡ä»¶ãå€æŽ
ããããå¢ç²ããã¯ãã¹ã溶å€ã§åžéããŠç²åºŠã
調ç¯ããªããã°ãªããªãçã®äžéœåãçãããŸ
ãã溶å€ãæ®çºãããŠåœ¢æããä¿è·å¡èã®è«žç¹æ§
ãå€åããããšãããã ãã®ãããªäžéœåã解æ¶ããããšãç®çãšã
ããæ«ç«¯å®èœåºãç¹å®ã®æŽ»æ§æ°ŽçŽ å«æååç©ã§å°
éïŒãã¹ã¯ïŒããé«æš¹èååãå¯èœã§ãã€ãŠå®å®
åãããããªã¢ããã€ããæš¹èã®è£œé æ³ã«ã€ããŠ
ã®ææ¡ãããã ãã®æ¹æ³ã¯äœååéåããããªã¢ããã€ããæš¹
èã®è²¯èµå®å®æ§ãèããæ¹è¯ãããã®ã§ãã€ã
ããéå ç²åºŠã0.3以äžã«äœååéåããé«åºŠã®
é«æš¹èååãå¯èœãªããªã¢ãã€ããæš¹èã«ã€ããŠ
ã¯ãæŽã«å³å¯ãªå®å®åæè¡ãèŠãããã®ã§ããã å³ã¡ããããäœååéé åã§ã¯å®å®åãããã
ãªã¢ããã€ããæš¹èãçŒä»ç¡¬åæã«ãããŠååãª
硬ååå¿æ§ã瀺ãããã«å®å®åæ¹æ³ã工倫ããå¿
èŠããããç¹ã«ãæ«ç«¯å®èœåºãéåžžã®çŒä»æž©åºŠç¯
å²ã§ç±çã«äžå¯éãªçµååºã«å°éããããããªæŽ»
æ§æ°ŽçŽ å«æååç©ãçšããå Žåã«ã¯ã貯èµå®å®æ§
ã«ã¯ãããããã®ã®ã硬ååå¿æ§ã¯èããé»å®³ã
ããã æ¬çºæã®ç®çã¯ãã®ãããªåé¡ç¹ã®ãªããæš¹è
åå«æéãé«ãããã€è²¯èµå®å®æ§ãšç¡¬ååå¿æ§ã«
ããããããªã¢ããã€ããæš¹èã®çµæç©ãé»æ°å°
äœã«çŽæ¥ãåã¯ä»ã®çµ¶çžç©ãä»ããŠå¡åžçŒä»ããŠ
ãªãèç±çµ¶çžé»ç·ã®è£œé æ³ãæäŸããããšã«ã
ãã æ¬çºæè ãã¯çæããããªã¢ããã€ããæš¹èã®
æ«ç«¯å®èœåºå°éå€ïŒãã¹ã¯å€ïŒã®çš®é¡ã䜿çšéã
æš¹èã®ååéçãå€ããŠãçš®ã ã®åææ¡ä»¶äžã§æš¹
èååå¿ãè¡ãªããåŸãããæš¹èã®æš¹èçµæãšå®
çšæ§èœãšã®é¢é£æ§ã詳现ã«æ€èšããçµæãæ¬çºæ
ã«è³ã€ãã æ¬çºæã¯å¡©åºæ§æº¶åªã®ååšäžã§ãè³éŠæãžã€ãœ
ã·ã¢ããŒãïŒïŒåã³ãã«ã«ãã³é žç¡æ°Žç©ïŒïŒ
ããã»ãŒçã¢ã«ã§æš¹èåå«æéã40ééïŒ ä»¥äžãš
ããŠåå¿ãããç³»ã«ãããŠãè³éŠæã€ãœã·ã¢ããŒ
ãïŒïŒïŒã¢ã«ã«å¯ŸããŠ0.1ã1.0ã¢ã«ã®ã©ã¯ã¿ã
ïŒïŒãšãäžèšã®åå¿åãåå¿äžåã¯åå¿åŸã«å
ããŠéå ç²åºŠã0.10ã0.27ãšããããªã¢ããã€ã
ãæš¹èã®çµæç©ãå°äœäžã«çŽæ¥ãŸãã¯ä»ã®çµ¶çžç©
ãä»ããŠå¡åžçŒä»ãã絶çžé»ç·ã®è£œé æ³ã«é¢ã
ãã ããã«ç¬¬ïŒã®çºæã¯ãå¡©åºæ§æº¶åªã®ååšäžã§ã
è³éŠæãžã€ãœã·ã¢ããŒãïŒïŒåã³ããªã«ã«ãã³
é žç¡æ°Žç©ïŒïŒããã»ãŒçã¢ã«ã§æš¹èåå«æéã
40ééïŒ ä»¥äžãšããŠåå¿ãããç³»ã«ãããŠãè³éŠ
æãžã€ãœã·ã¢ããŒãïŒïŒïŒã¢ã«ã«å¯ŸããŠ0.1ã
1.0ã¢ã«ã®ã©ã¯ã¿ã ïŒïŒããªãã³ã«è³éŠæãžã€ãœ
ã·ã¢ããŒãïŒïŒïŒã¢ã«ã«å¯ŸããŠ0.01ã0.5ã¢ã«
ã®ã¢ã«ã³ãŒã«ïŒïŒåã³ïŒåã¯ãªãã·ã ïŒïŒ
ããäžèšã®åå¿åãåå¿äžåã¯åå¿åŸã«å ããŠé
å ç²åºŠã0.10ã0.27ãšããããªã¢ããã€ããæš¹è
ã®çµæç©ãåºäœäžã«å¡ä»çŒä»ãã絶çžé»ç·ã®è£œé
æ³ã«é¢ããã 第ïŒã®çºæã«ããã硬ååå¿æ§ãé»å®³ãããã
ãããå®çšæ§èœãåŸãããã®æã奜ãŸãããã¹ã¯
å€ã®æ·»å æ¹æ³ã¯ããŸããã©ã¯ã¿ã ãåå¿åãåå¿
äžåã¯åå¿åŸã«å ããŠæ«ç«¯å®èœåºïŒäž»ã«ã€ãœã·ã¢
ããŒãåºïŒãå°éããåŸãã¢ã«ã³ãŒã«åã³ïŒåã¯
ãªãã·ã ãåå¿åŸã«å ããŠæ«ç«¯å®èœåºïŒäž»ã«é žç¡
æ°Žç©åºïŒãå°éããæ¹æ³ã§ãããåŸãããæš¹èã®
硬ååå¿æ§ã®ç¹ããã€ãœã·ã¢ããŒãåºã¯ã©ã¯ã¿ã
ã«ãã€ãŠå°éãããããšã奜ãŸããããŸããããª
ã«ã«ãã³é žç¡æ°Žç©ã«ã¢ã«ã³ãŒã«åã³ïŒåã¯ãªãã·
ã ãåå¿ãããã€ãã§ããã«è³éŠæãžã€ãœã·ã¢ã
ãŒããåå¿ãããåŸã«ãã©ã¯ã¿ã ãåå¿ãããã
ãšãã§ãããããªã«ã«ãã³é žç¡æ°Žç©ã«ã¢ã«ã³ãŒã«
åã³ïŒåã¯ãªãã·ã ãåå¿ãããã€ãã§è³éŠæãž
ã€ãœã·ã¢ããŒãããã³ã©ã¯ã¿ã ãå ããŠåæã«å
å¿ãããŠãããã æ¬çºæã«çšããããããªã¢ããã€ããæš¹èã®çµ
æç©ã¯æš¹èåå«æéãçŽ40ã55ééïŒ ãšé«ããé·
æã®è²¯èµå®å®æ§ã«ãããããšãã«èç±é»ç·çšã¯ã
ã¹ãšããŠé©ããŠããã æ¬çºæã«çšããããè³éŠæãžã€ãœã·ã¢ããŒããš
ããŠã¯ãäŸãã°ããªã¬ã³ãžã€ãœã·ã¢ããŒãããã·
ãªã¬ã³ãžã€ãœã·ã¢ããŒããïŒïŒ4â²âãžããšãã«ãš
ãŒãã«ãžã€ãœã·ã¢ããŒããããã¿ã¬ã³âïŒïŒïŒâ
ãžã€ãœã·ã¢ããŒããïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãž
ã€ãœã·ã¢ããŒããã€ãœããã³ãžã€ãœã·ã¢ããŒãã
ïŒïŒïŒâãããµã¡ãã¬ã³ãžã€ã¹ã·ã¢ããŒããã·ã¯
ããããµã³ãžã€ãœã·ã¢ããŒããªã©ããããèç±æ§
çãèæ ®ãããšïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãžã€ãœ
ã·ã¢ããŒãåã¯ããªã¬ã³ãžã€ãœã·ã¢ããŒããçšã
ãããšã奜ãŸãããå¿ èŠã«å¿ããŠãïŒïŒïŒâãã
ãµã¡ãã¬ã³ãžã€ãœã·ã¢ããŒããã€ãœããªãã³ãžã€
ãœã·ã¢ããŒãçã®èèªæãžã€ãœã·ã¢ããŒããèç°
åŒãžã€ãœã·ã¢ããŒãåã³ãããã®äžéåç©ãäžèš
ããè³éŠæãžã€ãœã·ã¢ããŒãã®äžéååå¿ã«ãã€
ãŠåŸãããã€ãœã·ã¢ãã¬ãŒãç°å«æããªã€ãœã·ã¢
ããŒããããªããšãã«ã¡ãã«ããªã€ãœã·ã¢ããŒ
ããäŸãã°ã¢ããªã³ãšããªã«ã ã¢ã«ããããšã®çž®
åç©ãããªã¹ã²ã³åãããã®ãªã©ã䜵çšããããš
ãã§ããããšãã«ãèç±æ§ã®æ¹è¯ã«å¹æã®ããã
ãªã¬ã³ãžã€ãœã·ã¢ããŒãåã¯ïŒïŒ4â²âãžããšãã«
ã¡ã¿ã³ãžã€ãœã·ã¢ããŒãã®äžéååå¿ã«ãã€ãŠåŸ
ãããã€ãœã·ã¢ãã¬ãŒãç°å«æããªã€ãœã·ã¢ããŒ
ãã奜ãŸããããã®äœ¿çšéã¯ã¯ãã¹ãèç±é»ç·çš
ã«äŸããå Žåãè³éŠæãžã€ãœã·ã¢ããŒãã®ïŒåœé
ã«å¯ŸããŠ0.03ã0.20åœéãšãšããã®ã奜ãŸããã ããªã«ã«ãã³é žç¡æ°Žç©ãšããŠã¯ãäŸãäžè¬åŒ(i)
åã³(ii)ã§ç€ºãããååç©ãçšããããã
ããããªã¢ããã€ããæš¹èã¯åæ溶åªãšããŠïŒ®â
ã¡ãã«ãããªãã³ïŒNMPïŒãçšããŠåŸãããé
å ç²åºŠïŒæ¿åºŠïŒ0.5gïŒdlã溶åªïŒãžã¡ãã«ããªã«
ã ã¢ããã枬å®æž©åºŠïŒ30âïŒã0.4ãè¶ããåå
ã«é«ããããååéã®ãã®ãäž»ãšããŠçšããããŠ
ãããäžæ¹ãé»ç·çšã¯ãã¹ã®æº¶æ¶²ç²åºŠã¯ãã€ã¹å¡
è£ ã®å Žåãå¡è£ äœæ¥æ§ã®å¶çŽãã30ãã¢ãºïŒ30
âïŒä»è¿ã«èšå®ãããŠããããããã®æ¡ä»¶ãæºè¶³
ããäžèšããé«ååéã®ããªã¢ããã€ããæš¹èã®
æš¹èåã®å«æéã¯è¯æº¶åªã§ããNMPã䜿çšããŠ
ãããã30ééïŒ ãé«æš¹èååã®éçå€ãšãªã€ãŠ
ãããåŸã€ãŠããããé«ååéã®ããªã¢ããã€ã
ãæš¹èãé»ç·çšã¯ãã¹ã«çšããå Žåãé«äŸ¡ãª
NMPãå€éã«äœ¿çšããããåŸãã³ã¹ãäžåé¡ãš
ãªã€ãŠããã NMPã®äœ¿çšéãæžå°ãããé«æš¹èååããã
ãšã«ãã€ãŠã³ã¹ãäœæžãå³ãã²ãšã€ã®æ¹æ³ã¯æš¹è
ã®äœååéåã§ãããããããªããããžã€ãœã·ã¢
ããŒããšããªã«ã«ãã³é žç¡æ°Žç©ãšããåŸãããã
ãªã¢ããã€ããæš¹èã®éå ç²åºŠã0.4以äžã«äœå
åéåãããšãæš¹èã®æ«ç«¯å®èœåºæ¿åºŠãå¢å ãã
çµæãåŸãããã¯ãã¹ã¯çµæ¥ã«ãã挞次å¢ç²ãã
貯èµå®å®æ§ãèããäœäžããåé¡ãçãããçµæ¥
ã«ããå¢ç²ããå Žåã«ã¯ãäŸãã°é»ç·çšã¯ãã¹ãš
ããŠçšããå Žåãæåã«èšå®ããå¡è£ æ¡ä»¶ãå€æŽ
ããããå¢ç²ããã¯ãã¹ã溶å€ã§åžéããŠç²åºŠã
調ç¯ããªããã°ãªããªãçã®äžéœåãçãããŸ
ãã溶å€ãæ®çºãããŠåœ¢æããä¿è·å¡èã®è«žç¹æ§
ãå€åããããšãããã ãã®ãããªäžéœåã解æ¶ããããšãç®çãšã
ããæ«ç«¯å®èœåºãç¹å®ã®æŽ»æ§æ°ŽçŽ å«æååç©ã§å°
éïŒãã¹ã¯ïŒããé«æš¹èååãå¯èœã§ãã€ãŠå®å®
åãããããªã¢ããã€ããæš¹èã®è£œé æ³ã«ã€ããŠ
ã®ææ¡ãããã ãã®æ¹æ³ã¯äœååéåããããªã¢ããã€ããæš¹
èã®è²¯èµå®å®æ§ãèããæ¹è¯ãããã®ã§ãã€ã
ããéå ç²åºŠã0.3以äžã«äœååéåããé«åºŠã®
é«æš¹èååãå¯èœãªããªã¢ãã€ããæš¹èã«ã€ããŠ
ã¯ãæŽã«å³å¯ãªå®å®åæè¡ãèŠãããã®ã§ããã å³ã¡ããããäœååéé åã§ã¯å®å®åãããã
ãªã¢ããã€ããæš¹èãçŒä»ç¡¬åæã«ãããŠååãª
硬ååå¿æ§ã瀺ãããã«å®å®åæ¹æ³ã工倫ããå¿
èŠããããç¹ã«ãæ«ç«¯å®èœåºãéåžžã®çŒä»æž©åºŠç¯
å²ã§ç±çã«äžå¯éãªçµååºã«å°éããããããªæŽ»
æ§æ°ŽçŽ å«æååç©ãçšããå Žåã«ã¯ã貯èµå®å®æ§
ã«ã¯ãããããã®ã®ã硬ååå¿æ§ã¯èããé»å®³ã
ããã æ¬çºæã®ç®çã¯ãã®ãããªåé¡ç¹ã®ãªããæš¹è
åå«æéãé«ãããã€è²¯èµå®å®æ§ãšç¡¬ååå¿æ§ã«
ããããããªã¢ããã€ããæš¹èã®çµæç©ãé»æ°å°
äœã«çŽæ¥ãåã¯ä»ã®çµ¶çžç©ãä»ããŠå¡åžçŒä»ããŠ
ãªãèç±çµ¶çžé»ç·ã®è£œé æ³ãæäŸããããšã«ã
ãã æ¬çºæè ãã¯çæããããªã¢ããã€ããæš¹èã®
æ«ç«¯å®èœåºå°éå€ïŒãã¹ã¯å€ïŒã®çš®é¡ã䜿çšéã
æš¹èã®ååéçãå€ããŠãçš®ã ã®åææ¡ä»¶äžã§æš¹
èååå¿ãè¡ãªããåŸãããæš¹èã®æš¹èçµæãšå®
çšæ§èœãšã®é¢é£æ§ã詳现ã«æ€èšããçµæãæ¬çºæ
ã«è³ã€ãã æ¬çºæã¯å¡©åºæ§æº¶åªã®ååšäžã§ãè³éŠæãžã€ãœ
ã·ã¢ããŒãïŒïŒåã³ãã«ã«ãã³é žç¡æ°Žç©ïŒïŒ
ããã»ãŒçã¢ã«ã§æš¹èåå«æéã40ééïŒ ä»¥äžãš
ããŠåå¿ãããç³»ã«ãããŠãè³éŠæã€ãœã·ã¢ããŒ
ãïŒïŒïŒã¢ã«ã«å¯ŸããŠ0.1ã1.0ã¢ã«ã®ã©ã¯ã¿ã
ïŒïŒãšãäžèšã®åå¿åãåå¿äžåã¯åå¿åŸã«å
ããŠéå ç²åºŠã0.10ã0.27ãšããããªã¢ããã€ã
ãæš¹èã®çµæç©ãå°äœäžã«çŽæ¥ãŸãã¯ä»ã®çµ¶çžç©
ãä»ããŠå¡åžçŒä»ãã絶çžé»ç·ã®è£œé æ³ã«é¢ã
ãã ããã«ç¬¬ïŒã®çºæã¯ãå¡©åºæ§æº¶åªã®ååšäžã§ã
è³éŠæãžã€ãœã·ã¢ããŒãïŒïŒåã³ããªã«ã«ãã³
é žç¡æ°Žç©ïŒïŒããã»ãŒçã¢ã«ã§æš¹èåå«æéã
40ééïŒ ä»¥äžãšããŠåå¿ãããç³»ã«ãããŠãè³éŠ
æãžã€ãœã·ã¢ããŒãïŒïŒïŒã¢ã«ã«å¯ŸããŠ0.1ã
1.0ã¢ã«ã®ã©ã¯ã¿ã ïŒïŒããªãã³ã«è³éŠæãžã€ãœ
ã·ã¢ããŒãïŒïŒïŒã¢ã«ã«å¯ŸããŠ0.01ã0.5ã¢ã«
ã®ã¢ã«ã³ãŒã«ïŒïŒåã³ïŒåã¯ãªãã·ã ïŒïŒ
ããäžèšã®åå¿åãåå¿äžåã¯åå¿åŸã«å ããŠé
å ç²åºŠã0.10ã0.27ãšããããªã¢ããã€ããæš¹è
ã®çµæç©ãåºäœäžã«å¡ä»çŒä»ãã絶çžé»ç·ã®è£œé
æ³ã«é¢ããã 第ïŒã®çºæã«ããã硬ååå¿æ§ãé»å®³ãããã
ãããå®çšæ§èœãåŸãããã®æã奜ãŸãããã¹ã¯
å€ã®æ·»å æ¹æ³ã¯ããŸããã©ã¯ã¿ã ãåå¿åãåå¿
äžåã¯åå¿åŸã«å ããŠæ«ç«¯å®èœåºïŒäž»ã«ã€ãœã·ã¢
ããŒãåºïŒãå°éããåŸãã¢ã«ã³ãŒã«åã³ïŒåã¯
ãªãã·ã ãåå¿åŸã«å ããŠæ«ç«¯å®èœåºïŒäž»ã«é žç¡
æ°Žç©åºïŒãå°éããæ¹æ³ã§ãããåŸãããæš¹èã®
硬ååå¿æ§ã®ç¹ããã€ãœã·ã¢ããŒãåºã¯ã©ã¯ã¿ã
ã«ãã€ãŠå°éãããããšã奜ãŸããããŸããããª
ã«ã«ãã³é žç¡æ°Žç©ã«ã¢ã«ã³ãŒã«åã³ïŒåã¯ãªãã·
ã ãåå¿ãããã€ãã§ããã«è³éŠæãžã€ãœã·ã¢ã
ãŒããåå¿ãããåŸã«ãã©ã¯ã¿ã ãåå¿ãããã
ãšãã§ãããããªã«ã«ãã³é žç¡æ°Žç©ã«ã¢ã«ã³ãŒã«
åã³ïŒåã¯ãªãã·ã ãåå¿ãããã€ãã§è³éŠæãž
ã€ãœã·ã¢ããŒãããã³ã©ã¯ã¿ã ãå ããŠåæã«å
å¿ãããŠãããã æ¬çºæã«çšããããããªã¢ããã€ããæš¹èã®çµ
æç©ã¯æš¹èåå«æéãçŽ40ã55ééïŒ ãšé«ããé·
æã®è²¯èµå®å®æ§ã«ãããããšãã«èç±é»ç·çšã¯ã
ã¹ãšããŠé©ããŠããã æ¬çºæã«çšããããè³éŠæãžã€ãœã·ã¢ããŒããš
ããŠã¯ãäŸãã°ããªã¬ã³ãžã€ãœã·ã¢ããŒãããã·
ãªã¬ã³ãžã€ãœã·ã¢ããŒããïŒïŒ4â²âãžããšãã«ãš
ãŒãã«ãžã€ãœã·ã¢ããŒããããã¿ã¬ã³âïŒïŒïŒâ
ãžã€ãœã·ã¢ããŒããïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãž
ã€ãœã·ã¢ããŒããã€ãœããã³ãžã€ãœã·ã¢ããŒãã
ïŒïŒïŒâãããµã¡ãã¬ã³ãžã€ã¹ã·ã¢ããŒããã·ã¯
ããããµã³ãžã€ãœã·ã¢ããŒããªã©ããããèç±æ§
çãèæ ®ãããšïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãžã€ãœ
ã·ã¢ããŒãåã¯ããªã¬ã³ãžã€ãœã·ã¢ããŒããçšã
ãããšã奜ãŸãããå¿ èŠã«å¿ããŠãïŒïŒïŒâãã
ãµã¡ãã¬ã³ãžã€ãœã·ã¢ããŒããã€ãœããªãã³ãžã€
ãœã·ã¢ããŒãçã®èèªæãžã€ãœã·ã¢ããŒããèç°
åŒãžã€ãœã·ã¢ããŒãåã³ãããã®äžéåç©ãäžèš
ããè³éŠæãžã€ãœã·ã¢ããŒãã®äžéååå¿ã«ãã€
ãŠåŸãããã€ãœã·ã¢ãã¬ãŒãç°å«æããªã€ãœã·ã¢
ããŒããããªããšãã«ã¡ãã«ããªã€ãœã·ã¢ããŒ
ããäŸãã°ã¢ããªã³ãšããªã«ã ã¢ã«ããããšã®çž®
åç©ãããªã¹ã²ã³åãããã®ãªã©ã䜵çšããããš
ãã§ããããšãã«ãèç±æ§ã®æ¹è¯ã«å¹æã®ããã
ãªã¬ã³ãžã€ãœã·ã¢ããŒãåã¯ïŒïŒ4â²âãžããšãã«
ã¡ã¿ã³ãžã€ãœã·ã¢ããŒãã®äžéååå¿ã«ãã€ãŠåŸ
ãããã€ãœã·ã¢ãã¬ãŒãç°å«æããªã€ãœã·ã¢ããŒ
ãã奜ãŸããããã®äœ¿çšéã¯ã¯ãã¹ãèç±é»ç·çš
ã«äŸããå Žåãè³éŠæãžã€ãœã·ã¢ããŒãã®ïŒåœé
ã«å¯ŸããŠ0.03ã0.20åœéãšãšããã®ã奜ãŸããã ããªã«ã«ãã³é žç¡æ°Žç©ãšããŠã¯ãäŸãäžè¬åŒ(i)
åã³(ii)ã§ç€ºãããååç©ãçšããããã
ãåŒã
ãåŒã
ïŒïŒžã¯âCH2âãâCOâãâSO2âãââ
çã§ããïŒèç±æ§ãã³ã¹ãé¢çãèæ ®ããã°ããª
ã¡ãªããé žç¡æ°Žç©ã奜ãŸããã å¿ èŠã«å¿ããŠãåèšããããªã«ã«ãã³é žç¡æ°Žç©
以å€ã®ããªã«ã«ãã³é žåã¯ãã®é žç¡æ°Žç©ã䜵çšã§
ããããããããªã«ã«ãã³é žãšããŠã¯ãäŸãã°ã
ãªã¡ãªããé žãããªã¡ã·ã³é žãããªã¹ïŒïŒâã«ã«
ããã·ãšãã«ïŒã€ãœã·ã¢ãã¬ãŒãããã¬ãã¿ã«
é žãã€ãœãã¿ã«é žãã³ãã¯é žãã¢ãžãã³é žãã»ã
ã·ã³é žãããã«ã³ãžã«ã«ãã³é žãªã©ãçšããã
ãã ããªã«ã«ãã³é žç¡æ°Žç©ãšããŠã¯ïŒïŒïŒïŒïŒïŒïŒ
âãã¿ã³ããã©ã«ã«ãã³é žãã·ã¯ããã³ã¿ã³ãã
ã©ã«ã«ãã³é žããã·ã¯ãâïŒïŒïŒïŒïŒïŒïŒâãªã¯
ãã³â(7)âïŒïŒïŒïŒïŒïŒïŒâããã©ã«ã«ãã³é žã
ãšãã¬ã³ããã©ã«ã«ãã³é žããã·ã¯ãâãïŒïŒ
ïŒïŒïŒãâãªã¯ãâ(7)âãšã³âïŒïŒïŒãïŒïŒïŒâ
ããã©ã«ã«ãã³é žçã®èèªæç³»ããã³èç°æç³»å
å¡©åºé žããããªã¡ãªããé žãïŒïŒ3â²ïŒïŒïŒ4â²âã
ã³ãŸããšãã³ããã©ã«ã«ãã³é žããã¹ïŒïŒïŒïŒâ
ãžã«ã«ããã·ããšãã«ïŒãšãŒãã«ãïŒïŒïŒïŒïŒïŒ
ïŒâããã¿ã¬ã³ããã©ã«ã«ãã³é žãïŒïŒïŒïŒïŒïŒ
ïŒâããã¿ã¬ã³ããã©ã«ã«ãã³é žããšãã¬ã³ã°ãª
ã³ãŒã«ãã¹ããªã¡ãªããŒããïŒïŒ2â²âãã¹ïŒïŒïŒ
ïŒâãã¹ã«ã«ããã·ããšãã«ïŒãããã³ãïŒïŒ
2â²ïŒïŒïŒ3â²âãžããšãã«ããã©ã«ã«ãã³é žãããª
ã¬ã³âïŒïŒïŒïŒïŒïŒ10âããã©ã«ã«ãã³é žãïŒïŒ
ïŒâãžã«ã«ããã·ããšãã«ã¹ã«ãã³çã®è³éŠæå
å¡©åºé žãããªããšã³âïŒïŒïŒïŒïŒïŒïŒâããã©ã«
ã«ãã³é žããã©ãžã³ããã©ã«ã«ãã³é žçã®è€çŽ ç°
åŒåå¡©åºé žãªã©ã®åå¡©åºé žäºç¡æ°Žç©ãªã©ãçšãã
ããã ãããããªã«ã«ãã³é žåã¯ãã®é žç¡æ°Žç©ã¯å¯ãš
ãæ§ã溶åªã«å¯Ÿãã溶解æ§ãæ圢å å·¥ã®äžã§ã®æº¶
åªæµãæ§ïŒå å·¥æ§ïŒã硬ååå¿æ§ãªã©ã®æš¹èç¹æ§
ã®æ¹è³ªã«çšããããšãã§ããããšãã«ã硬ååå¿
æ§ã®æ¹è¯ã«å¹æã®ããïŒïŒ3â²ïŒïŒïŒ4â²âãã³ãŸã
ãšãã³ããã©ã«ã«ãã³é žäºç¡æ°Žç©ã奜ãŸãããã
ã®äœ¿çšéã¯ããªã«ã«ãã³é žç¡æ°Žç©ïŒã¢ã«ã«å¯ŸããŠ
ïŒïŒ3â²ïŒïŒïŒ4â²âãã³ãŸããšãã³ããã©ã«ã«ãã³
é žäºç¡æ°Žç©0.03ã0.2ã¢ã«ã®ç¯å²ã奜ãŸããã è³éŠæãžã€ãœã·ã¢ããŒããšããªã«ã«ãã³é žç¡æ°Ž
ç©ã¯ã»ãŒçã¢ã«ã§åå¿ããããããã¯ã»ãŒçã¢ã«
ã§åå¿ãããå Žåã«ãçŒä»ç¡¬åã®éã«ååã«é«å
åéåããããªã¢ããã€ããæš¹èãåŸãããæè¯
ã®èç±æ§ãå¯ãšãæ§ã瀺ããäœããåå¿æº¶åªäžã«
äžçŽç©ãšããŠå«ãŸããå°éã®æ°Žãã€ãœã·ã¢ããŒã
åºãšåå¿ããããšãèããŠãžã€ãœã·ã¢ããŒãåå
ç©ãã¢ã«æ°ã«ãããŠè¥å¹²éå°ã«å ããããšã¯å·®æ¯
ããªããããã®éã¯ããªã«ã«ãã³é žç¡æ°Žç©ïŒã¢ã«
ã«å¯Ÿããè³éŠæãžã€ãœã·ã¢ããŒãååç©ïŒïŒïŒã¢
ã«ä»¥äžã§ãã€ãŠã¯ãªããªããããªã«ã«ãã³é žç¡æ°Ž
ç©ïŒã¢ã«ã«å¯ŸããŠè³éŠæãžã€ãœã·ã¢ããŒãã1.08
ã0.95ã¢ã«ãšããããšã奜ãŸããã å¡©åºæ§æº¶åªãšããŠã¯è³éŠæãžã€ãœã·ã¢ããŒãã«
察ããŠå®è³ªçã«äžæŽ»æ§ãªãã®ãçšãããããäŸã
ã°ãâã¡ãã«âïŒâãããªãã³ãïŒïŒ®âãžã¡
ãã«ããªã«ã ã¢ãããïŒïŒ®âãžã¡ãã«ã¢ã»ãã¢
ããããžã¡ãã«ã¹ã«ããã·ãããããµã¡ãã«ããª
ã¹ããªã³ã¢ãããâã¡ãã«âã«ããã©ã¯ã¿ã ãª
ã©ãçšãããããè³éŠæãžã€ãœã·ã¢ããŒããšããª
ã«ã«ãã³é žç¡æ°Žç©ãšã®åæ溶åªãšããŠã¯ïŒ®âã¡ã
ã«ãããªãã³ã奜ãŸããããŸããåå¿åŸã«çšãã
ããåžé溶åªãšããŠã¯ãžã¡ãã«ããªã«ã ã¢ããã
奜ãŸããããžã¡ãã«ããªã«ã ã¢ããã¯ã¯ãã¹ã®æº¶
液ç²åºŠãäžããå¹æããããé«æš¹èååã«å¯äžã
ãã æš¹èåå«æéã40ééïŒ æªæºã§ãããšãåæåŸ
éå°ã®æº¶åªãæ¿çž®ãªã©ã®ç¹éãªæäœã«ãã€ãŠé€å»
ããå¿ èŠããããçµæžçãªäžå©ãçãããã³ã¹
ããæ§èœãªã©ãèæ ®ãããš40ã80ééïŒ ã奜ãŸã
ããããã§ãæš¹èåå«æéãšã¯è³éŠæãžã€ãœã·ã¢
ããŒããšããªã«ã«ãã³é žç¡æ°Žç©ã®åã®åå¿ç³»äžã«
ãããæ¿åºŠãæããäœãã䜿çšããã©ã¯ã¿ã ãã¢
ã«ã³ãŒã«åã¯ãªãã·ã ã®éã¯ãã®èšç®ã«ã¯å ããª
ããã®ãšããã æ¬çºæã«äœ¿çšãããããªã¢ããã€ããæš¹èã®æ«
端å®èœåºå°éå€ïŒãã¹ã¯å€ïŒãšããŠçšããããã©
ã¯ã¿ã ãã¢ã«ã³ãŒã«åã³ãªãã·ã ãšããŠã¯ãäŸã
ã°ãïŒâãããªãã³ãεâã«ããã©ã¯ã¿ã ãã©ãŠ
ãªã«ã©ã¯ã¿ã çã®ã©ã¯ã¿ã ãã¡ã¿ããŒã«ããšã¿ã
ãŒã«ãïœâãã¿ããŒã«ãïœâãã¿ããŒã«ãã¡ãã«
ã»ããœã«ãããšãã«ã»ããœã«ããã¡ãã«ã«ã«ãã
ãŒã«ããã³ãžã«ã¢ã«ã³ãŒã«ãã·ã¯ããããµããŒ
ã«ãÏâãã€ããã»ããŒãã«ãªãã¢ã«ã³ãŒã«çã®
ççŽ æ°ãïŒã10ã®ã¢ã«ã³ãŒã«ãïŒâãã¿ãã³ãªã
ã·ã ããã«ã ã¢ã«ããã·ã ãã¢ã»ãã¢ã«ããã·
ã ãã·ã¯ããããµãã³ãªãã·ã çã®ãªãã·ã ãæ
ããããããããã®ãã¹ã¯å€ã¯ååå ã«ïŒåã®æŽ»
æ§æ°ŽçŽ ãå«æããŠãããã®ã奜ãŸããã掻æ§æ°ŽçŽ
ãïŒå以äžã§ãããšãæš¹èã®é䌞é·å€ãšãªããå
åéåã³æº¶æ¶²ç²åºŠã®ã³ã³ãããŒã«ãå°é£ãšãªãã
æŽã«ã¯èç±æ§ã®äœäžãèµ·ããããšãããã 第ïŒã®çºæã«ãããŠã¯ãã¯ãã¹ã®ç²åºŠå®å®åå¹
æãç±è§£é£ã®ãæããã³ã¹ãçã®èŠ³ç¹ãããã©ã¯
ã¿ã ãšããŠã¯Îµâã«ããã©ã¯ã¿ã ãã¢ã«ã³ãŒã«ãš
ããŠã¯ã¡ã¿ããŒã«ããªãã·ã ãšããŠã¯ïŒâãã¿ã
ã³ãªãã·ã ãçšããããšã奜ãŸããã ã©ã¯ã¿ã ã¯ç¡¬ååå¿æ§ãé»å®³ããããšãå°ãªã
ãšããç¹ã§å¥œãŸãããã貯èµå®å®æ§ã®å¹æã«åå
ã§ãªãå Žåãããããäžèšããã¢ã«ã³ãŒã«åã³ïŒ
åã¯ãªãã·ã ã䜿çšãã第ïŒã®çºæã«ãã€ãŠãã®
åé¡ã解決ããããšãã§ããã ã©ã¯ã¿ã ã®äœ¿çšéã¯ãè³éŠæãžã€ãœã·ã¢ããŒã
ïŒã¢ã«ã«å¯ŸããŠ0.1ã1.0ã¢ã«ãšãããã0.1ã¢ã«æª
æºã§ãããšè²¯èµå®å®æ§ãäžååãšãªãã 1.0ã¢ã«ãè¶ãããšã硬ååå¿æ§ã®é»å®³å¹æã¯
æ¯èŒçå°ãªãããããªãŒã®ã©ã¯ã¿ã ãå€éã«æ®ã
ãããã¯ãã¹ã®æš¹èåå«æéãäœäžããããã¹ã¯
å€ãšããŠã©ã¯ã¿ã ã®ã¿ã䜿çšããå Žåã¯0.3ã1.0
ã¢ã«ã®ç¯å²ã奜ãŸããããã¹ã¯å€ãšããŠã©ã¯ã¿ã
ãšã¢ã«ã³ãŒã«åã³ïŒåã¯ãªãã·ã ã®æ··åç³»ã䜿çš
ãã第ïŒã®çºæã«ãããŠã¯ã©ã¯ã¿ã ã®äœ¿çšéã¯
0.2ã0.8ã¢ã«ã®ç¯å²ã奜ãŸããã 第ïŒã®çºæã«ãããã¢ã«ã³ãŒã«åã³ïŒåã¯ãªã
ã·ã ã®äœ¿çšéã¯è³éŠæãžã€ãœã·ã¢ããŒãïŒã¢ã«ã«
察ããŠ0.01ã0.5ã¢ã«ãšãããã0.01ã¢ã«æªæºã§ã
ããšè²¯èµå®å®æ§ã«å¯Ÿããå¹æãäžååãšãªãã
0.5ã¢ã«ãè¶ãããšç¡¬ååå¿æ§ãèããæããã
çµæãçŒä»ãããå¡èã®å®çšæ§èœãäœäžããããš
ãã«å¥œãŸããã¯0.01ã0.3ã¢ã«ã®ç¯å²ãšãããã ã©ã¯ã¿ã ã第ïŒã®çºæã«ãããŠäœ¿çšãããã¢ã«
ã³ãŒã«åã³ïŒåã¯ãªãã·ã ã®æ·»å ã¯äžèšã®åå¿
åãåå¿äžåã¯åå¿åŸã«è¡ãªããããããªã¢ãã€
ããæš¹èã補é åŸãä»ã®æº¶åªã§åžéåŸã«å ããŠã
ããããããå šéãäžåºŠã«æ·»å ããŠãããã段é
çã«æ·»å ããŠããããéååå¿ãå¶åŸ¡ããæ¥æ¿ãª
è±çé žåå¿ã«ããçºæ³¡ãæå¶ããåæäžã®èŠ³ç¹ã
ãã©ã¯ã¿ã ã®äžéšåã¯å šéšãåå¿ååã¯åå¿äžã«
æ·»å ããããšã奜ãŸãããäœããã¢ã«ã³ãŒã«å
ã³ïŒåã¯ãªãã·ã ã¯ãéååå¿ãé»å®³ããå Žåã
ããããåå¿åŸãæ·»å ããã®ã奜ãŸãããã¢ã«ã³
ãŒã«åã³ïŒåã¯ãªãã·ã ãäžèšã®åå¿ååã¯åå¿
äžã«æ·»å ããŠåå¿ãããå Žåã¯ãè³éŠæãžã€ãœã·
ã¢ããŒãïŒã¢ã«ã«å¯ŸããŠã¢ã«ã³ãŒã«åã³ïŒåã¯ãª
ãã·ã ã0.25ã¢ã«æªæºãšãªãå²åã§çšããããšã
奜ãŸããã0.25ã¢ã«ä»¥äžã§ãããšãéååå¿åã¯
硬ååå¿ãé»å®³ããåŸåãããã åå¿æž©åºŠã¯ãã¹ã¯å€ãåå¿ååã¯åå¿äžã«æ·»å
ããå Žåã«ã¯80ã200âã§è¡ãªãããšã奜ãŸããã
網ç¶åãªã©ã®å¯åå¿ãæå¶ããããã«ã¯160â以
äžãšããã®ã奜ãŸããã130âååŸãæãé©ããŠ
ãããåå¿åŸã«æ·»å ããå Žåã«ã¯ã80ã160âã§
è¡ãªãããšã奜ãŸãããé«æš¹èåå«æéã§è¡ãªã
ã»ã©åå¿æž©åºŠã¯äœäžã§ãããäŸãã°ãæš¹èå«æé
ã60ééïŒ ã®å Žåã110âååŸãæãé©ããŠããã ãã¹ã¯å€ãåå¿åŸã«æ·»å ããæ¹æ³ã«ãããŠã¯ã
æ·»å åŸæŽã«ïŒã130âã§æ°æéåå¿ãããŠãæ«ç«¯
å®èœåºãå®å šã«å°éããå¿ èŠãããã90âååŸã
æãé©ããŠããã æ¬çºæã«çšããããªã¢ããã€ããæš¹èã®çµæç©
ã¯éå ç²åºŠã0.10ã0.27ãšãããã0.10æªæºã§ã
ããšã貯èµå®å®æ§åã¯èç±æ§ãå¯ãšãæ§ãªã©ã®å®
çšæ§èœãäžå åãšãªãã0.27ãè¶ãããšæš¹èåå«
æéãäœäžããæ¬çºæã®ç®çãéæã§ããªããª
ããéå ç²åºŠã®èª¿æŽã¯åå¿äžã«æº¶æ¶²ç²åºŠã枬å®ã
ãŠè¡ãªããããéå ç²åºŠã¯ãäžèšã®åå¿ã§åŸãã
ãæš¹è溶液ã®äžéšã«ïŒ®âã¡ãã«ãããªãã³ãå ã
ãŠ10ééïŒ ãšãã溶液15gããæ°ŽïŒäžã«å ããŠ
æš¹èãæ²æ®¿ãããã€ãã§æ²æ®¿ç©ã0.3mmHgã®æžå§
äžã§60âã§10æé也ç¥ããŠãåºåœ¢æš¹èãšãããã
ã®åºåœ¢æš¹èã0.5gïŒïœã®ãžã¡ãã«ãã«ã ã¢ãã
溶液ãšãã30âã§ãã€ãã³ããšã³ã¹ã±ç²åºŠèšïŒç²
床èšçªå·50ïŒãçšããŠæž¬å®ãããã æ¬çºæã«ãããããªã¢ããã€ããæš¹èã®çµæç©
ãã¯ãã¹ãšããå Žåã«ã¯äžèšããå¡©åºæ§ææ©æº¶åª
ã®ä»ã®å©æº¶å€ãšããŠãã·ã¬ã³ãNISSEKIHISOL
â100ã150ãã¡ãã«ã»ããœã«ãã¢ã»ããŒãããšã
ã«ã»ããœã«ãã¢ã»ããŒããγâãããã©ã¯ãã³ãª
ã©ã䜵çšããŠãããã æ¬çºæã«ãããŠçšããããããªã¢ããã€ããæš¹
èã®çµæç©ã«ãå¿ èŠã«å¿ããŠç¡¬åä¿é²è§Šåªåã¯ãŠ
ã¬ã¿ã³è§£é¢è§Šåªã䜵çšããããšãã§ãããäŸãã°
ããªãšãã«ã¢ãã³ãããªãšãã¬ã³ãžã¢ãã³ããžã¡
ãã«ã¢ããªã³ããžã¡ãã«ãšã¿ããŒã«ã¢ãã³ãïŒïŒ
ïŒâãžã¢ã¶âãã·ã¯ãïŒïŒïŒïŒïŒïŒïŒãŠã³ãã»ã³
âïŒïŒåã¯ãã®ææ©é žå¡©ïŒçã®ç¬¬äžçŽã¢ãã³é¡ã
ãžããã«ã¹ãºãžã©ãŠã¬ãŒãããžããã«ã¹ãºãžãªã¯
ããšãŒãçã®ææ©ã¹ãºååç©ãããã©ãããã·ã
ã¿ããŒããããã©ã€ãœããããã·ãã¿ããŒãåã¯
ãããã®ãã¬ãŒããã¢ã·ã¬ãŒãååç©çã®ææ©ã
ã¿ã³ååç©ãããªã¢ã«ãã«ãã¹ãã€ã³ãªã©ãçšã
ãããããšãã«ç¬¬äžçŽã¢ãã³é¡ã奜ãŸããããŸ
ããå¿ èŠã«å¿ããŠç¡¬åå€ãçé¢æŽ»æ§å€ãªã©ã®çš®ã
ã®æ·»å å€ã䜵çšããããšãã§ããã 硬åå€ãšããŠã¯äŸãã°ããšããã·æš¹èãã¢ãã
æš¹èãããšããŒã«ãã«ã ã¢ã«ãããæš¹èãæ°Žé žåº
åã³ïŒåã¯ã«ã«ããã·ã«åºãæããããªãšã¹ãã«
æš¹èãè³éŠæããªã€ãœã·ã¢ããŒãã®äžèšããåå
äžã«ïŒåã®æŽ»æ§æ°ŽçŽ ãå«æããååç©ã®ä»å ç©ãª
ã©ãçšããããã奜ãŸããã¯ãäžèšããè³éŠæãž
ã€ãœã·ã¢ããŒãåã¯ãã®äžéåç©ã®ååäžã«ïŒå
ã®æŽ»æ§æ°ŽçŽ ãæããååç©ã®ä»å ç©ããšãã«å¥œãŸ
ããã¯ïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãžã€ãœã·ã¢ããŒ
ã®Îµâã«ããã©ã¯ã¿ã ä»å ç©ãçšããããã ä»ã®æ·»å å€ãšããŠã¯ãã³ãŸã€ã³ã奜ãŸããçšã
ãããããã³ãŸã€ã³ã¯å¡èã®å¹³æ»æ§ãæ¹è¯ããã ãã®ããã«èª¿è£œãããã¯ãã¹ã¯ãäŸãã°ãã€ã¹
å¡èçšèç±é»ç·ã¯ãã¹ãšããŠäœ¿çšããå Žåã溶液
ç²åºŠã25ã35ãã¢ãºïŒ30âïŒã«èšå®ããæãçŽ40
ã55ééïŒ ã®é«æš¹èåå«æéãåŸãããšãã§ã
ãããŸããããšã«ãå¡è£ çšèç±é»ç·ã¯ãã¹ãšããŠ
䜿çšããå Žåã溶液ç²åºŠã0.6ã0.8ãã¢ãºïŒ30
âïŒã«èšå®ããæçŽ20ã35ééïŒ ã®é«æš¹èåå«æ
éãåŸãããšãã§ããããããã®ã¯ãã¹ã¯é·æã®
貯èµå®å®æ§ã«ããããŠãããšå ±ã«ãçŒãä»ããã
å¡èã¯è¯å¥œãªèç±æ§ãå¯ãšãæ§ã«å ããŠãèãã¬
ãªã³æ§ãèã¯ã¬ãŒãžã³ã°æ§ã«ããããŠããã ãã®ããã«ããŠåŸãããããªã¢ããã€ããæš¹è
ã®çµæç©ãé»æ°å°äœäžã«å¡åžçŒä»ããããšã«ãã€
ãŠèç±æ§ãèæ©èæ§ãèè¬åæ§çã«åªãã絶çžé»
ç·ãåŸãããšãã§ããããã®éãå°äœã®äžã«çŽæ¥
ããªã¢ããã€ããæš¹èã®çµæç©ãå¡åžçŒä»ãã
åŸãæŽã«ãã®äžã«ä»ã®çµ¶çžç©ãå¡åžçŒä»ããŠãã
ãããéã«å°äœã®äžã«ä»ã®çµ¶çžç©ãå¡åžçŒä»ãã
åŸããã®äžã«ããªã¢ããæš¹èã®çµæç©ãå¡åžçŒä»
ããŠãããããŸãããã®ãããªäºéæ§é ã«äžã«æŽ
ã«ããªã¢ããã€ããæš¹èãŸãã¯ä»ã®çµ¶çžç©ãä»»æ
ã®é åºã«å¡åžçŒä»ããŠå€å±€æ§é ã«ããŠããããä»
ã®çµ¶çžç©ãšããŠã¯å®è³ªçã«ç·ç¶ã®ç±å¯å¡æ§ããšã¹
ãã«ãåå²ç¶ã®ç±ç¡¬åæ§ããªãšã¹ãã«ãããªã¢ã
ããããªããã«ãã«ããŒã«ãããªãŠã¬ã¿ã³ãããª
ã€ãããããªã€ãããŸãŒã«ãããªã€ãããŸããã
ã³ãããªããã³ãã€ã³ãããªãšã¹ãã«ã€ãããã
ãªã¢ããã€ãããšã¹ãã«ããšããã·æš¹èåã³åçš®
èªå·±èçæ§ã¯ãã¹çããããããã å°äœã«ããªã¢ããã€ããæš¹èçµæç©åã¯ä»ã®çµ¶
çžç©ãå¡åžçŒä»ããæ¹æ³ã«ã€ããŠã¯ç¹ã«å¶éã¯ãª
ãã©ã®ãããªæ¹æ³ã§ãã€ãŠããããäŸãã°ãå°äœ
ããã¢ããã€ããæš¹èçµæç©åã¯ä»ã®çµ¶çžç©ã®äž
ãéããåŸãéå±è£œã®ãã€ã¹ãããã¯ããšã«ãã§
ããããŠåã¿ã調æŽããåŸãçã®äžãéããŠçŒä»
ããããšãæ°åç¹°ãè¿ãæ¹æ³ãäžæ¬çã§ããã 以äžãæ¬çºæãå®æœäŸåã³æ¯èŒäŸã«ãã€ãŠèª¬æ
ããã æ¯èŒäŸ ïŒ æž©åºŠèšããããŸãæ©ãç管å·åŽåšãã€ããïŒ
åã€å£ãã©ã¹ã³ã«ïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãžã€
ãœã·ã¢ããŒã452.5gãããªã¡ãªããé žç¡æ°Žç©
347.5gãâã¡ãã«ãããªãã³1485.7gãå ¥ãã
çªçŽ æ°æµäžã§ãããŸããªãã100âã§ïŒæéã15
âã§ïŒæéã120âã§ïŒæéåå¿ãããåŒãç¶ã
135âã«ææž©ããŠïŒæéåå¿ãé²ããïŒæš¹èåå«
æéã¯35ééïŒ ïŒããã·ã¬ã³381gãå ããŠåžéã
ããåŸãããããªã¢ããã€æš¹èã®ã¯ãã¹äžã®æš¹è
åå«æéïŒèšç®å€ïŒã¯30ééïŒ ãã¯ãã¹ã®åæç²
床ïŒïŒ¢åç²åºŠèšã30âïŒã¯31ãã¢ãºãããªã¢ãã
ã€ããæš¹èã®éå ç²åºŠïŒ0.5gïŒdlããžã¡ãã«ããª
ã«ã ã¢ããã30âïŒã¯0.42ã§ãã€ãããã®ã¯ãã¹
ã¯40âã§ïŒã±ææŸçœ®ããŠãç²åºŠå€åã¯å šãèŠãã
ãªãã€ãã å®æœäŸ ïŒ æž©åºŠèšããããŸãæ©ãç管å·åŽåšãã€ããïŒ
åã€å£ãã©ã¹ã³ã«ïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãžã€
ãœã·ã¢ããŒã452.5gãããªã¡ãªããé žç¡æ°Žç©
347.5gãεâã«ããã©ã¯ã¿ã 96.7gãâã¡ãã«
ãããªãã³533.3gãå ¥ããçªçŽ æ°æµäžã§ãããŸã
ãªãã100âã§ïŒæéã115âã§ïŒæéã125âã§
ïŒæéããã«135âã§åå¿ãé²ããçµç¹å€å®çšè©Š
æãšããŠæš¹èåå«æéã40ééïŒ ã«åžéãã溶液
ã®30âã®ã¬ãŒãããŒç²åºŠã25ç§ãšãªã€ããšããã§
100âã«å·åŽããâã¡ãã«ãããªãã³272.4gã
ãžã¡ãã«ããªã«ã ã¢ãã345.3gãã¡ã¿ããŒã«2.7g
ãå ããŠåžéãããåŒãç¶ã90âã§ïŒæéåå¿ã
ãããåŸãããæš¹èã®éå ç²åºŠã¯0.24ïŒ0.5gïŒdlã
ãžã¡ãã«ããªã«ã ã¢ããã30âïŒãåŸããããªã¢
ããæš¹èã®ã¯ãã¹äžã®æš¹èåå«æéïŒèšç®å€ïŒã¯
41ééïŒ ã§ããããã®ã¯ãã¹ã®åæç²åºŠã¯28ãã¢
ãºïŒ30âïŒã40âã§ïŒã±ææŸçœ®åŸã®ç²åºŠã¯29ãã¢
ãºïŒ30âïŒã§ããããããã貯èµå®å®æ§ã瀺ã
ãã å®æœäŸ ïŒ æž©åºŠèšããããŸãæ©ãç管å·åŽåšãã€ããïŒ
åã€å£ãã©ã¹ã³ã«ïŒïŒ4â²âãžããã«ã¡ã¿ã³ãžã€ãœ
ã·ã¢ããŒã456.4gãããªã¡ãªããé žç¡æ°Žç©
343.6gãâã¡ãã«ãããªãã³533.3gãεâã«ã
ãã©ã¯ã¿ã 48.4gãå ¥ããçªçŽ æ°æµäžã§ãããŸã
ãªãã100âã§ïŒæéã115âã§ïŒæéã125âã§
ïŒæéãããã«135âã§åå¿ãé²ããçµç¹å€å®çš
è©ŠæãšããŠæš¹èåå«æéã44ééïŒ ã«åžéãã溶
液ã®30âã®ã¬ãŒãããŒç²åºŠã29ç§ãšãªã€ããšãã
ã§100âã«å·åŽãããžã¡ãã«ããªã«ã ã¢ãã
484.9gãïŒâãã¿ãã³ãªãã·ã 18.6gãå ããŠåž
éãããåŒãç¶ã90âã§ïŒæéåå¿ããããåŸã
ããæš¹èã®éå ç²åºŠã¯0.21ïŒ0.5gïŒdlããžã¡ãã«ã
ãªã«ã ã¢ããã30âïŒãåŸãããããªã¢ããæš¹è
ã®ã¯ãã¹äžã®æš¹èåå«æéïŒèšç®å€ïŒã¯44ééïŒ
ã§ããããã®ã¯ãã¹ã®åæç²åºŠã¯34ãã¢ãºïŒ30
âïŒã40âã§ïŒã±ææŸçœ®åŸã®ç²åºŠã¯36ãã¢ãºïŒ30
âïŒã§ããããããã貯èµå®å®æ§ã瀺ããã å®æœäŸ ïŒ æž©åºŠèšããããŸãæ©ãç管å·åŽåšãã€ããïŒ
åã€å£ãã©ã¹ã³ã«ïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãžã€
ãœã·ã¢ããŒã452.5gãããªã¡ãªããé žç¡æ°Žç©
347.5gãεâã«ããã©ã¯ã¿ã 96.7gãâã¡ãã«
ãããªãã³533.3gãå ¥ãçªçŽ æ°æµäžã§ãããŸããª
ãã100âã§ïŒæéã115âã§ïŒæéã125âã§ïŒ
æéãããã«135âã§åå¿ãé²ããçµç¹å€å®çšè©Š
æãšããŠæš¹èåå«æéã45ééïŒ ã«åžéãã溶液
ã®30âã®ã¬ãŒãããŒç²åºŠã28ç§ãšãªã€ããšããã§
100âã«å·åŽãããžã¡ãã«ããªã«ã ã¢ãã444.4g
ãå ããŠåžéãããããã«ã¡ã¿ããŒã«13.7gãå
ã90âã§ïŒæéåå¿ããããæš¹èã®éå ç²åºŠã¯
0.21ïŒ0.5gïŒdlããžã¡ãã«ããªã«ã ã¢ããã30âïŒã
åŸãããããªã¢ããã€ããæš¹èã®ã¯ãã¹äžã®æš¹è
åå«æéïŒèšç®å€ïŒã¯45ééïŒ ã§ããããã®ã¯ã
ã¹ã®åæç²åºŠã¯30ãã¢ãºïŒ30âïŒã§ãã€ãããã®
ã¯ãã¹ã®40âã§ïŒã±ææŸçœ®åŸã®ç²åºŠã¯30ãã¢ãº
ïŒ30âïŒã§ããããããã貯èµå®å®æ§ã瀺ããã å®æœäŸïŒïŒïŒïŒïŒåã³æ¯èŒäŸïŒã§åŸãããã¯ã
ã¹ãçŽåŸïŒmmã®é ç·ã«å¡åžããçæž©260ïŒ360ïŒ
400âïŒå ¥å£ïŒäžå€®ïŒåºå£ïŒã«èšå®ããçé·4.5m
ã®æŽåçã®äžãç·é10mïŒåã®é床ã§ééãããŠ
çŒä»ããããšãïŒãïŒåç¹°ãè¿ããŠåŸããã絶çž
é»ç·ã®ç¹æ§ãè©äŸ¡ããããã®çµæãè¡šïŒã«ç€ºãã ãªããå®æœäŸïŒãïŒåã³æ¯èŒäŸïŒã¯å¡åžçŒä»å
æ°ãïŒåãšããå®æœäŸïŒã¯å®æœäŸïŒã§åŸãããã¯
ãã¹ãïŒåå¡åžçŒä»ããŠåŸããã絶çžé»ç·ã§ã
ãã
çã§ããïŒèç±æ§ãã³ã¹ãé¢çãèæ ®ããã°ããª
ã¡ãªããé žç¡æ°Žç©ã奜ãŸããã å¿ èŠã«å¿ããŠãåèšããããªã«ã«ãã³é žç¡æ°Žç©
以å€ã®ããªã«ã«ãã³é žåã¯ãã®é žç¡æ°Žç©ã䜵çšã§
ããããããããªã«ã«ãã³é žãšããŠã¯ãäŸãã°ã
ãªã¡ãªããé žãããªã¡ã·ã³é žãããªã¹ïŒïŒâã«ã«
ããã·ãšãã«ïŒã€ãœã·ã¢ãã¬ãŒãããã¬ãã¿ã«
é žãã€ãœãã¿ã«é žãã³ãã¯é žãã¢ãžãã³é žãã»ã
ã·ã³é žãããã«ã³ãžã«ã«ãã³é žãªã©ãçšããã
ãã ããªã«ã«ãã³é žç¡æ°Žç©ãšããŠã¯ïŒïŒïŒïŒïŒïŒïŒ
âãã¿ã³ããã©ã«ã«ãã³é žãã·ã¯ããã³ã¿ã³ãã
ã©ã«ã«ãã³é žããã·ã¯ãâïŒïŒïŒïŒïŒïŒïŒâãªã¯
ãã³â(7)âïŒïŒïŒïŒïŒïŒïŒâããã©ã«ã«ãã³é žã
ãšãã¬ã³ããã©ã«ã«ãã³é žããã·ã¯ãâãïŒïŒ
ïŒïŒïŒãâãªã¯ãâ(7)âãšã³âïŒïŒïŒãïŒïŒïŒâ
ããã©ã«ã«ãã³é žçã®èèªæç³»ããã³èç°æç³»å
å¡©åºé žããããªã¡ãªããé žãïŒïŒ3â²ïŒïŒïŒ4â²âã
ã³ãŸããšãã³ããã©ã«ã«ãã³é žããã¹ïŒïŒïŒïŒâ
ãžã«ã«ããã·ããšãã«ïŒãšãŒãã«ãïŒïŒïŒïŒïŒïŒ
ïŒâããã¿ã¬ã³ããã©ã«ã«ãã³é žãïŒïŒïŒïŒïŒïŒ
ïŒâããã¿ã¬ã³ããã©ã«ã«ãã³é žããšãã¬ã³ã°ãª
ã³ãŒã«ãã¹ããªã¡ãªããŒããïŒïŒ2â²âãã¹ïŒïŒïŒ
ïŒâãã¹ã«ã«ããã·ããšãã«ïŒãããã³ãïŒïŒ
2â²ïŒïŒïŒ3â²âãžããšãã«ããã©ã«ã«ãã³é žãããª
ã¬ã³âïŒïŒïŒïŒïŒïŒ10âããã©ã«ã«ãã³é žãïŒïŒ
ïŒâãžã«ã«ããã·ããšãã«ã¹ã«ãã³çã®è³éŠæå
å¡©åºé žãããªããšã³âïŒïŒïŒïŒïŒïŒïŒâããã©ã«
ã«ãã³é žããã©ãžã³ããã©ã«ã«ãã³é žçã®è€çŽ ç°
åŒåå¡©åºé žãªã©ã®åå¡©åºé žäºç¡æ°Žç©ãªã©ãçšãã
ããã ãããããªã«ã«ãã³é žåã¯ãã®é žç¡æ°Žç©ã¯å¯ãš
ãæ§ã溶åªã«å¯Ÿãã溶解æ§ãæ圢å å·¥ã®äžã§ã®æº¶
åªæµãæ§ïŒå å·¥æ§ïŒã硬ååå¿æ§ãªã©ã®æš¹èç¹æ§
ã®æ¹è³ªã«çšããããšãã§ããããšãã«ã硬ååå¿
æ§ã®æ¹è¯ã«å¹æã®ããïŒïŒ3â²ïŒïŒïŒ4â²âãã³ãŸã
ãšãã³ããã©ã«ã«ãã³é žäºç¡æ°Žç©ã奜ãŸãããã
ã®äœ¿çšéã¯ããªã«ã«ãã³é žç¡æ°Žç©ïŒã¢ã«ã«å¯ŸããŠ
ïŒïŒ3â²ïŒïŒïŒ4â²âãã³ãŸããšãã³ããã©ã«ã«ãã³
é žäºç¡æ°Žç©0.03ã0.2ã¢ã«ã®ç¯å²ã奜ãŸããã è³éŠæãžã€ãœã·ã¢ããŒããšããªã«ã«ãã³é žç¡æ°Ž
ç©ã¯ã»ãŒçã¢ã«ã§åå¿ããããããã¯ã»ãŒçã¢ã«
ã§åå¿ãããå Žåã«ãçŒä»ç¡¬åã®éã«ååã«é«å
åéåããããªã¢ããã€ããæš¹èãåŸãããæè¯
ã®èç±æ§ãå¯ãšãæ§ã瀺ããäœããåå¿æº¶åªäžã«
äžçŽç©ãšããŠå«ãŸããå°éã®æ°Žãã€ãœã·ã¢ããŒã
åºãšåå¿ããããšãèããŠãžã€ãœã·ã¢ããŒãåå
ç©ãã¢ã«æ°ã«ãããŠè¥å¹²éå°ã«å ããããšã¯å·®æ¯
ããªããããã®éã¯ããªã«ã«ãã³é žç¡æ°Žç©ïŒã¢ã«
ã«å¯Ÿããè³éŠæãžã€ãœã·ã¢ããŒãååç©ïŒïŒïŒã¢
ã«ä»¥äžã§ãã€ãŠã¯ãªããªããããªã«ã«ãã³é žç¡æ°Ž
ç©ïŒã¢ã«ã«å¯ŸããŠè³éŠæãžã€ãœã·ã¢ããŒãã1.08
ã0.95ã¢ã«ãšããããšã奜ãŸããã å¡©åºæ§æº¶åªãšããŠã¯è³éŠæãžã€ãœã·ã¢ããŒãã«
察ããŠå®è³ªçã«äžæŽ»æ§ãªãã®ãçšãããããäŸã
ã°ãâã¡ãã«âïŒâãããªãã³ãïŒïŒ®âãžã¡
ãã«ããªã«ã ã¢ãããïŒïŒ®âãžã¡ãã«ã¢ã»ãã¢
ããããžã¡ãã«ã¹ã«ããã·ãããããµã¡ãã«ããª
ã¹ããªã³ã¢ãããâã¡ãã«âã«ããã©ã¯ã¿ã ãª
ã©ãçšãããããè³éŠæãžã€ãœã·ã¢ããŒããšããª
ã«ã«ãã³é žç¡æ°Žç©ãšã®åæ溶åªãšããŠã¯ïŒ®âã¡ã
ã«ãããªãã³ã奜ãŸããããŸããåå¿åŸã«çšãã
ããåžé溶åªãšããŠã¯ãžã¡ãã«ããªã«ã ã¢ããã
奜ãŸããããžã¡ãã«ããªã«ã ã¢ããã¯ã¯ãã¹ã®æº¶
液ç²åºŠãäžããå¹æããããé«æš¹èååã«å¯äžã
ãã æš¹èåå«æéã40ééïŒ æªæºã§ãããšãåæåŸ
éå°ã®æº¶åªãæ¿çž®ãªã©ã®ç¹éãªæäœã«ãã€ãŠé€å»
ããå¿ èŠããããçµæžçãªäžå©ãçãããã³ã¹
ããæ§èœãªã©ãèæ ®ãããš40ã80ééïŒ ã奜ãŸã
ããããã§ãæš¹èåå«æéãšã¯è³éŠæãžã€ãœã·ã¢
ããŒããšããªã«ã«ãã³é žç¡æ°Žç©ã®åã®åå¿ç³»äžã«
ãããæ¿åºŠãæããäœãã䜿çšããã©ã¯ã¿ã ãã¢
ã«ã³ãŒã«åã¯ãªãã·ã ã®éã¯ãã®èšç®ã«ã¯å ããª
ããã®ãšããã æ¬çºæã«äœ¿çšãããããªã¢ããã€ããæš¹èã®æ«
端å®èœåºå°éå€ïŒãã¹ã¯å€ïŒãšããŠçšããããã©
ã¯ã¿ã ãã¢ã«ã³ãŒã«åã³ãªãã·ã ãšããŠã¯ãäŸã
ã°ãïŒâãããªãã³ãεâã«ããã©ã¯ã¿ã ãã©ãŠ
ãªã«ã©ã¯ã¿ã çã®ã©ã¯ã¿ã ãã¡ã¿ããŒã«ããšã¿ã
ãŒã«ãïœâãã¿ããŒã«ãïœâãã¿ããŒã«ãã¡ãã«
ã»ããœã«ãããšãã«ã»ããœã«ããã¡ãã«ã«ã«ãã
ãŒã«ããã³ãžã«ã¢ã«ã³ãŒã«ãã·ã¯ããããµããŒ
ã«ãÏâãã€ããã»ããŒãã«ãªãã¢ã«ã³ãŒã«çã®
ççŽ æ°ãïŒã10ã®ã¢ã«ã³ãŒã«ãïŒâãã¿ãã³ãªã
ã·ã ããã«ã ã¢ã«ããã·ã ãã¢ã»ãã¢ã«ããã·
ã ãã·ã¯ããããµãã³ãªãã·ã çã®ãªãã·ã ãæ
ããããããããã®ãã¹ã¯å€ã¯ååå ã«ïŒåã®æŽ»
æ§æ°ŽçŽ ãå«æããŠãããã®ã奜ãŸããã掻æ§æ°ŽçŽ
ãïŒå以äžã§ãããšãæš¹èã®é䌞é·å€ãšãªããå
åéåã³æº¶æ¶²ç²åºŠã®ã³ã³ãããŒã«ãå°é£ãšãªãã
æŽã«ã¯èç±æ§ã®äœäžãèµ·ããããšãããã 第ïŒã®çºæã«ãããŠã¯ãã¯ãã¹ã®ç²åºŠå®å®åå¹
æãç±è§£é£ã®ãæããã³ã¹ãçã®èŠ³ç¹ãããã©ã¯
ã¿ã ãšããŠã¯Îµâã«ããã©ã¯ã¿ã ãã¢ã«ã³ãŒã«ãš
ããŠã¯ã¡ã¿ããŒã«ããªãã·ã ãšããŠã¯ïŒâãã¿ã
ã³ãªãã·ã ãçšããããšã奜ãŸããã ã©ã¯ã¿ã ã¯ç¡¬ååå¿æ§ãé»å®³ããããšãå°ãªã
ãšããç¹ã§å¥œãŸãããã貯èµå®å®æ§ã®å¹æã«åå
ã§ãªãå Žåãããããäžèšããã¢ã«ã³ãŒã«åã³ïŒ
åã¯ãªãã·ã ã䜿çšãã第ïŒã®çºæã«ãã€ãŠãã®
åé¡ã解決ããããšãã§ããã ã©ã¯ã¿ã ã®äœ¿çšéã¯ãè³éŠæãžã€ãœã·ã¢ããŒã
ïŒã¢ã«ã«å¯ŸããŠ0.1ã1.0ã¢ã«ãšãããã0.1ã¢ã«æª
æºã§ãããšè²¯èµå®å®æ§ãäžååãšãªãã 1.0ã¢ã«ãè¶ãããšã硬ååå¿æ§ã®é»å®³å¹æã¯
æ¯èŒçå°ãªãããããªãŒã®ã©ã¯ã¿ã ãå€éã«æ®ã
ãããã¯ãã¹ã®æš¹èåå«æéãäœäžããããã¹ã¯
å€ãšããŠã©ã¯ã¿ã ã®ã¿ã䜿çšããå Žåã¯0.3ã1.0
ã¢ã«ã®ç¯å²ã奜ãŸããããã¹ã¯å€ãšããŠã©ã¯ã¿ã
ãšã¢ã«ã³ãŒã«åã³ïŒåã¯ãªãã·ã ã®æ··åç³»ã䜿çš
ãã第ïŒã®çºæã«ãããŠã¯ã©ã¯ã¿ã ã®äœ¿çšéã¯
0.2ã0.8ã¢ã«ã®ç¯å²ã奜ãŸããã 第ïŒã®çºæã«ãããã¢ã«ã³ãŒã«åã³ïŒåã¯ãªã
ã·ã ã®äœ¿çšéã¯è³éŠæãžã€ãœã·ã¢ããŒãïŒã¢ã«ã«
察ããŠ0.01ã0.5ã¢ã«ãšãããã0.01ã¢ã«æªæºã§ã
ããšè²¯èµå®å®æ§ã«å¯Ÿããå¹æãäžååãšãªãã
0.5ã¢ã«ãè¶ãããšç¡¬ååå¿æ§ãèããæããã
çµæãçŒä»ãããå¡èã®å®çšæ§èœãäœäžããããš
ãã«å¥œãŸããã¯0.01ã0.3ã¢ã«ã®ç¯å²ãšãããã ã©ã¯ã¿ã ã第ïŒã®çºæã«ãããŠäœ¿çšãããã¢ã«
ã³ãŒã«åã³ïŒåã¯ãªãã·ã ã®æ·»å ã¯äžèšã®åå¿
åãåå¿äžåã¯åå¿åŸã«è¡ãªããããããªã¢ãã€
ããæš¹èã補é åŸãä»ã®æº¶åªã§åžéåŸã«å ããŠã
ããããããå šéãäžåºŠã«æ·»å ããŠãããã段é
çã«æ·»å ããŠããããéååå¿ãå¶åŸ¡ããæ¥æ¿ãª
è±çé žåå¿ã«ããçºæ³¡ãæå¶ããåæäžã®èŠ³ç¹ã
ãã©ã¯ã¿ã ã®äžéšåã¯å šéšãåå¿ååã¯åå¿äžã«
æ·»å ããããšã奜ãŸãããäœããã¢ã«ã³ãŒã«å
ã³ïŒåã¯ãªãã·ã ã¯ãéååå¿ãé»å®³ããå Žåã
ããããåå¿åŸãæ·»å ããã®ã奜ãŸãããã¢ã«ã³
ãŒã«åã³ïŒåã¯ãªãã·ã ãäžèšã®åå¿ååã¯åå¿
äžã«æ·»å ããŠåå¿ãããå Žåã¯ãè³éŠæãžã€ãœã·
ã¢ããŒãïŒã¢ã«ã«å¯ŸããŠã¢ã«ã³ãŒã«åã³ïŒåã¯ãª
ãã·ã ã0.25ã¢ã«æªæºãšãªãå²åã§çšããããšã
奜ãŸããã0.25ã¢ã«ä»¥äžã§ãããšãéååå¿åã¯
硬ååå¿ãé»å®³ããåŸåãããã åå¿æž©åºŠã¯ãã¹ã¯å€ãåå¿ååã¯åå¿äžã«æ·»å
ããå Žåã«ã¯80ã200âã§è¡ãªãããšã奜ãŸããã
網ç¶åãªã©ã®å¯åå¿ãæå¶ããããã«ã¯160â以
äžãšããã®ã奜ãŸããã130âååŸãæãé©ããŠ
ãããåå¿åŸã«æ·»å ããå Žåã«ã¯ã80ã160âã§
è¡ãªãããšã奜ãŸãããé«æš¹èåå«æéã§è¡ãªã
ã»ã©åå¿æž©åºŠã¯äœäžã§ãããäŸãã°ãæš¹èå«æé
ã60ééïŒ ã®å Žåã110âååŸãæãé©ããŠããã ãã¹ã¯å€ãåå¿åŸã«æ·»å ããæ¹æ³ã«ãããŠã¯ã
æ·»å åŸæŽã«ïŒã130âã§æ°æéåå¿ãããŠãæ«ç«¯
å®èœåºãå®å šã«å°éããå¿ èŠãããã90âååŸã
æãé©ããŠããã æ¬çºæã«çšããããªã¢ããã€ããæš¹èã®çµæç©
ã¯éå ç²åºŠã0.10ã0.27ãšãããã0.10æªæºã§ã
ããšã貯èµå®å®æ§åã¯èç±æ§ãå¯ãšãæ§ãªã©ã®å®
çšæ§èœãäžå åãšãªãã0.27ãè¶ãããšæš¹èåå«
æéãäœäžããæ¬çºæã®ç®çãéæã§ããªããª
ããéå ç²åºŠã®èª¿æŽã¯åå¿äžã«æº¶æ¶²ç²åºŠã枬å®ã
ãŠè¡ãªããããéå ç²åºŠã¯ãäžèšã®åå¿ã§åŸãã
ãæš¹è溶液ã®äžéšã«ïŒ®âã¡ãã«ãããªãã³ãå ã
ãŠ10ééïŒ ãšãã溶液15gããæ°ŽïŒäžã«å ããŠ
æš¹èãæ²æ®¿ãããã€ãã§æ²æ®¿ç©ã0.3mmHgã®æžå§
äžã§60âã§10æé也ç¥ããŠãåºåœ¢æš¹èãšãããã
ã®åºåœ¢æš¹èã0.5gïŒïœã®ãžã¡ãã«ãã«ã ã¢ãã
溶液ãšãã30âã§ãã€ãã³ããšã³ã¹ã±ç²åºŠèšïŒç²
床èšçªå·50ïŒãçšããŠæž¬å®ãããã æ¬çºæã«ãããããªã¢ããã€ããæš¹èã®çµæç©
ãã¯ãã¹ãšããå Žåã«ã¯äžèšããå¡©åºæ§ææ©æº¶åª
ã®ä»ã®å©æº¶å€ãšããŠãã·ã¬ã³ãNISSEKIHISOL
â100ã150ãã¡ãã«ã»ããœã«ãã¢ã»ããŒãããšã
ã«ã»ããœã«ãã¢ã»ããŒããγâãããã©ã¯ãã³ãª
ã©ã䜵çšããŠãããã æ¬çºæã«ãããŠçšããããããªã¢ããã€ããæš¹
èã®çµæç©ã«ãå¿ èŠã«å¿ããŠç¡¬åä¿é²è§Šåªåã¯ãŠ
ã¬ã¿ã³è§£é¢è§Šåªã䜵çšããããšãã§ãããäŸãã°
ããªãšãã«ã¢ãã³ãããªãšãã¬ã³ãžã¢ãã³ããžã¡
ãã«ã¢ããªã³ããžã¡ãã«ãšã¿ããŒã«ã¢ãã³ãïŒïŒ
ïŒâãžã¢ã¶âãã·ã¯ãïŒïŒïŒïŒïŒïŒïŒãŠã³ãã»ã³
âïŒïŒåã¯ãã®ææ©é žå¡©ïŒçã®ç¬¬äžçŽã¢ãã³é¡ã
ãžããã«ã¹ãºãžã©ãŠã¬ãŒãããžããã«ã¹ãºãžãªã¯
ããšãŒãçã®ææ©ã¹ãºååç©ãããã©ãããã·ã
ã¿ããŒããããã©ã€ãœããããã·ãã¿ããŒãåã¯
ãããã®ãã¬ãŒããã¢ã·ã¬ãŒãååç©çã®ææ©ã
ã¿ã³ååç©ãããªã¢ã«ãã«ãã¹ãã€ã³ãªã©ãçšã
ãããããšãã«ç¬¬äžçŽã¢ãã³é¡ã奜ãŸããããŸ
ããå¿ èŠã«å¿ããŠç¡¬åå€ãçé¢æŽ»æ§å€ãªã©ã®çš®ã
ã®æ·»å å€ã䜵çšããããšãã§ããã 硬åå€ãšããŠã¯äŸãã°ããšããã·æš¹èãã¢ãã
æš¹èãããšããŒã«ãã«ã ã¢ã«ãããæš¹èãæ°Žé žåº
åã³ïŒåã¯ã«ã«ããã·ã«åºãæããããªãšã¹ãã«
æš¹èãè³éŠæããªã€ãœã·ã¢ããŒãã®äžèšããåå
äžã«ïŒåã®æŽ»æ§æ°ŽçŽ ãå«æããååç©ã®ä»å ç©ãª
ã©ãçšããããã奜ãŸããã¯ãäžèšããè³éŠæãž
ã€ãœã·ã¢ããŒãåã¯ãã®äžéåç©ã®ååäžã«ïŒå
ã®æŽ»æ§æ°ŽçŽ ãæããååç©ã®ä»å ç©ããšãã«å¥œãŸ
ããã¯ïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãžã€ãœã·ã¢ããŒ
ã®Îµâã«ããã©ã¯ã¿ã ä»å ç©ãçšããããã ä»ã®æ·»å å€ãšããŠã¯ãã³ãŸã€ã³ã奜ãŸããçšã
ãããããã³ãŸã€ã³ã¯å¡èã®å¹³æ»æ§ãæ¹è¯ããã ãã®ããã«èª¿è£œãããã¯ãã¹ã¯ãäŸãã°ãã€ã¹
å¡èçšèç±é»ç·ã¯ãã¹ãšããŠäœ¿çšããå Žåã溶液
ç²åºŠã25ã35ãã¢ãºïŒ30âïŒã«èšå®ããæãçŽ40
ã55ééïŒ ã®é«æš¹èåå«æéãåŸãããšãã§ã
ãããŸããããšã«ãå¡è£ çšèç±é»ç·ã¯ãã¹ãšããŠ
䜿çšããå Žåã溶液ç²åºŠã0.6ã0.8ãã¢ãºïŒ30
âïŒã«èšå®ããæçŽ20ã35ééïŒ ã®é«æš¹èåå«æ
éãåŸãããšãã§ããããããã®ã¯ãã¹ã¯é·æã®
貯èµå®å®æ§ã«ããããŠãããšå ±ã«ãçŒãä»ããã
å¡èã¯è¯å¥œãªèç±æ§ãå¯ãšãæ§ã«å ããŠãèãã¬
ãªã³æ§ãèã¯ã¬ãŒãžã³ã°æ§ã«ããããŠããã ãã®ããã«ããŠåŸãããããªã¢ããã€ããæš¹è
ã®çµæç©ãé»æ°å°äœäžã«å¡åžçŒä»ããããšã«ãã€
ãŠèç±æ§ãèæ©èæ§ãèè¬åæ§çã«åªãã絶çžé»
ç·ãåŸãããšãã§ããããã®éãå°äœã®äžã«çŽæ¥
ããªã¢ããã€ããæš¹èã®çµæç©ãå¡åžçŒä»ãã
åŸãæŽã«ãã®äžã«ä»ã®çµ¶çžç©ãå¡åžçŒä»ããŠãã
ãããéã«å°äœã®äžã«ä»ã®çµ¶çžç©ãå¡åžçŒä»ãã
åŸããã®äžã«ããªã¢ããæš¹èã®çµæç©ãå¡åžçŒä»
ããŠãããããŸãããã®ãããªäºéæ§é ã«äžã«æŽ
ã«ããªã¢ããã€ããæš¹èãŸãã¯ä»ã®çµ¶çžç©ãä»»æ
ã®é åºã«å¡åžçŒä»ããŠå€å±€æ§é ã«ããŠããããä»
ã®çµ¶çžç©ãšããŠã¯å®è³ªçã«ç·ç¶ã®ç±å¯å¡æ§ããšã¹
ãã«ãåå²ç¶ã®ç±ç¡¬åæ§ããªãšã¹ãã«ãããªã¢ã
ããããªããã«ãã«ããŒã«ãããªãŠã¬ã¿ã³ãããª
ã€ãããããªã€ãããŸãŒã«ãããªã€ãããŸããã
ã³ãããªããã³ãã€ã³ãããªãšã¹ãã«ã€ãããã
ãªã¢ããã€ãããšã¹ãã«ããšããã·æš¹èåã³åçš®
èªå·±èçæ§ã¯ãã¹çããããããã å°äœã«ããªã¢ããã€ããæš¹èçµæç©åã¯ä»ã®çµ¶
çžç©ãå¡åžçŒä»ããæ¹æ³ã«ã€ããŠã¯ç¹ã«å¶éã¯ãª
ãã©ã®ãããªæ¹æ³ã§ãã€ãŠããããäŸãã°ãå°äœ
ããã¢ããã€ããæš¹èçµæç©åã¯ä»ã®çµ¶çžç©ã®äž
ãéããåŸãéå±è£œã®ãã€ã¹ãããã¯ããšã«ãã§
ããããŠåã¿ã調æŽããåŸãçã®äžãéããŠçŒä»
ããããšãæ°åç¹°ãè¿ãæ¹æ³ãäžæ¬çã§ããã 以äžãæ¬çºæãå®æœäŸåã³æ¯èŒäŸã«ãã€ãŠèª¬æ
ããã æ¯èŒäŸ ïŒ æž©åºŠèšããããŸãæ©ãç管å·åŽåšãã€ããïŒ
åã€å£ãã©ã¹ã³ã«ïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãžã€
ãœã·ã¢ããŒã452.5gãããªã¡ãªããé žç¡æ°Žç©
347.5gãâã¡ãã«ãããªãã³1485.7gãå ¥ãã
çªçŽ æ°æµäžã§ãããŸããªãã100âã§ïŒæéã15
âã§ïŒæéã120âã§ïŒæéåå¿ãããåŒãç¶ã
135âã«ææž©ããŠïŒæéåå¿ãé²ããïŒæš¹èåå«
æéã¯35ééïŒ ïŒããã·ã¬ã³381gãå ããŠåžéã
ããåŸãããããªã¢ããã€æš¹èã®ã¯ãã¹äžã®æš¹è
åå«æéïŒèšç®å€ïŒã¯30ééïŒ ãã¯ãã¹ã®åæç²
床ïŒïŒ¢åç²åºŠèšã30âïŒã¯31ãã¢ãºãããªã¢ãã
ã€ããæš¹èã®éå ç²åºŠïŒ0.5gïŒdlããžã¡ãã«ããª
ã«ã ã¢ããã30âïŒã¯0.42ã§ãã€ãããã®ã¯ãã¹
ã¯40âã§ïŒã±ææŸçœ®ããŠãç²åºŠå€åã¯å šãèŠãã
ãªãã€ãã å®æœäŸ ïŒ æž©åºŠèšããããŸãæ©ãç管å·åŽåšãã€ããïŒ
åã€å£ãã©ã¹ã³ã«ïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãžã€
ãœã·ã¢ããŒã452.5gãããªã¡ãªããé žç¡æ°Žç©
347.5gãεâã«ããã©ã¯ã¿ã 96.7gãâã¡ãã«
ãããªãã³533.3gãå ¥ããçªçŽ æ°æµäžã§ãããŸã
ãªãã100âã§ïŒæéã115âã§ïŒæéã125âã§
ïŒæéããã«135âã§åå¿ãé²ããçµç¹å€å®çšè©Š
æãšããŠæš¹èåå«æéã40ééïŒ ã«åžéãã溶液
ã®30âã®ã¬ãŒãããŒç²åºŠã25ç§ãšãªã€ããšããã§
100âã«å·åŽããâã¡ãã«ãããªãã³272.4gã
ãžã¡ãã«ããªã«ã ã¢ãã345.3gãã¡ã¿ããŒã«2.7g
ãå ããŠåžéãããåŒãç¶ã90âã§ïŒæéåå¿ã
ãããåŸãããæš¹èã®éå ç²åºŠã¯0.24ïŒ0.5gïŒdlã
ãžã¡ãã«ããªã«ã ã¢ããã30âïŒãåŸããããªã¢
ããæš¹èã®ã¯ãã¹äžã®æš¹èåå«æéïŒèšç®å€ïŒã¯
41ééïŒ ã§ããããã®ã¯ãã¹ã®åæç²åºŠã¯28ãã¢
ãºïŒ30âïŒã40âã§ïŒã±ææŸçœ®åŸã®ç²åºŠã¯29ãã¢
ãºïŒ30âïŒã§ããããããã貯èµå®å®æ§ã瀺ã
ãã å®æœäŸ ïŒ æž©åºŠèšããããŸãæ©ãç管å·åŽåšãã€ããïŒ
åã€å£ãã©ã¹ã³ã«ïŒïŒ4â²âãžããã«ã¡ã¿ã³ãžã€ãœ
ã·ã¢ããŒã456.4gãããªã¡ãªããé žç¡æ°Žç©
343.6gãâã¡ãã«ãããªãã³533.3gãεâã«ã
ãã©ã¯ã¿ã 48.4gãå ¥ããçªçŽ æ°æµäžã§ãããŸã
ãªãã100âã§ïŒæéã115âã§ïŒæéã125âã§
ïŒæéãããã«135âã§åå¿ãé²ããçµç¹å€å®çš
è©ŠæãšããŠæš¹èåå«æéã44ééïŒ ã«åžéãã溶
液ã®30âã®ã¬ãŒãããŒç²åºŠã29ç§ãšãªã€ããšãã
ã§100âã«å·åŽãããžã¡ãã«ããªã«ã ã¢ãã
484.9gãïŒâãã¿ãã³ãªãã·ã 18.6gãå ããŠåž
éãããåŒãç¶ã90âã§ïŒæéåå¿ããããåŸã
ããæš¹èã®éå ç²åºŠã¯0.21ïŒ0.5gïŒdlããžã¡ãã«ã
ãªã«ã ã¢ããã30âïŒãåŸãããããªã¢ããæš¹è
ã®ã¯ãã¹äžã®æš¹èåå«æéïŒèšç®å€ïŒã¯44ééïŒ
ã§ããããã®ã¯ãã¹ã®åæç²åºŠã¯34ãã¢ãºïŒ30
âïŒã40âã§ïŒã±ææŸçœ®åŸã®ç²åºŠã¯36ãã¢ãºïŒ30
âïŒã§ããããããã貯èµå®å®æ§ã瀺ããã å®æœäŸ ïŒ æž©åºŠèšããããŸãæ©ãç管å·åŽåšãã€ããïŒ
åã€å£ãã©ã¹ã³ã«ïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãžã€
ãœã·ã¢ããŒã452.5gãããªã¡ãªããé žç¡æ°Žç©
347.5gãεâã«ããã©ã¯ã¿ã 96.7gãâã¡ãã«
ãããªãã³533.3gãå ¥ãçªçŽ æ°æµäžã§ãããŸããª
ãã100âã§ïŒæéã115âã§ïŒæéã125âã§ïŒ
æéãããã«135âã§åå¿ãé²ããçµç¹å€å®çšè©Š
æãšããŠæš¹èåå«æéã45ééïŒ ã«åžéãã溶液
ã®30âã®ã¬ãŒãããŒç²åºŠã28ç§ãšãªã€ããšããã§
100âã«å·åŽãããžã¡ãã«ããªã«ã ã¢ãã444.4g
ãå ããŠåžéãããããã«ã¡ã¿ããŒã«13.7gãå
ã90âã§ïŒæéåå¿ããããæš¹èã®éå ç²åºŠã¯
0.21ïŒ0.5gïŒdlããžã¡ãã«ããªã«ã ã¢ããã30âïŒã
åŸãããããªã¢ããã€ããæš¹èã®ã¯ãã¹äžã®æš¹è
åå«æéïŒèšç®å€ïŒã¯45ééïŒ ã§ããããã®ã¯ã
ã¹ã®åæç²åºŠã¯30ãã¢ãºïŒ30âïŒã§ãã€ãããã®
ã¯ãã¹ã®40âã§ïŒã±ææŸçœ®åŸã®ç²åºŠã¯30ãã¢ãº
ïŒ30âïŒã§ããããããã貯èµå®å®æ§ã瀺ããã å®æœäŸïŒïŒïŒïŒïŒåã³æ¯èŒäŸïŒã§åŸãããã¯ã
ã¹ãçŽåŸïŒmmã®é ç·ã«å¡åžããçæž©260ïŒ360ïŒ
400âïŒå ¥å£ïŒäžå€®ïŒåºå£ïŒã«èšå®ããçé·4.5m
ã®æŽåçã®äžãç·é10mïŒåã®é床ã§ééãããŠ
çŒä»ããããšãïŒãïŒåç¹°ãè¿ããŠåŸããã絶çž
é»ç·ã®ç¹æ§ãè©äŸ¡ããããã®çµæãè¡šïŒã«ç€ºãã ãªããå®æœäŸïŒãïŒåã³æ¯èŒäŸïŒã¯å¡åžçŒä»å
æ°ãïŒåãšããå®æœäŸïŒã¯å®æœäŸïŒã§åŸãããã¯
ãã¹ãïŒåå¡åžçŒä»ããŠåŸããã絶çžé»ç·ã§ã
ãã
ãè¡šã
è¡šïŒããæãããªããã«å®æœäŸïŒãå®æœäŸïŒã®
絶çžé»ç·ã¯æ¯èŒäŸïŒã§ç€ºããåŸæ¥åã®çµ¶çžé»ç·ãš
åæ§åªããèç±æ§ãèæ©èæ§ãå¯ãšãæ§ãæããŠ
ãããæš¹èåæ¿åºŠãå€§å¹ ã«é«ãåã ãã¯ãã¹ã®è£œ
é ã³ã¹ãã茞éã³ã¹ããå®è³ªçã«äœäžãããããš
ãã§ãããã®åã ã絶çžé»ç·ã®ã³ã¹ããäžããã
ãšãã§ããããŸããå®æœäŸïŒãšïŒåã³æ¯èŒäŸïŒã
æ¯èŒããŠãããããã«å¡åžçŒä»ãåæ°ãäœæžãã
ããšãã§ããçµæžæ§ã®åªããèç±æ§çµ¶çžé»ç·ãæ
äŸã§ããã
絶çžé»ç·ã¯æ¯èŒäŸïŒã§ç€ºããåŸæ¥åã®çµ¶çžé»ç·ãš
åæ§åªããèç±æ§ãèæ©èæ§ãå¯ãšãæ§ãæããŠ
ãããæš¹èåæ¿åºŠãå€§å¹ ã«é«ãåã ãã¯ãã¹ã®è£œ
é ã³ã¹ãã茞éã³ã¹ããå®è³ªçã«äœäžãããããš
ãã§ãããã®åã ã絶çžé»ç·ã®ã³ã¹ããäžããã
ãšãã§ããããŸããå®æœäŸïŒãšïŒåã³æ¯èŒäŸïŒã
æ¯èŒããŠãããããã«å¡åžçŒä»ãåæ°ãäœæžãã
ããšãã§ããçµæžæ§ã®åªããèç±æ§çµ¶çžé»ç·ãæ
äŸã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ å¡©åºæ§æº¶åªã®ååšäžã§ãè³éŠæãžã€ãœã·ã¢ã
ãŒãïŒïŒåã³ããªã«ã«ãã³é žç¡æ°Žç©ïŒïŒãã
ã»ãŒçã¢ã«ã§æš¹èåå«æéã40ééïŒ ä»¥äžãšããŠ
åå¿ãããç³»ã«ãããŠãè³éŠæãžã€ãœã·ã¢ããŒã
ïŒïŒïŒã¢ã«ã«å¯ŸããŠ0.1ã1.0ã¢ã«ã®ã©ã¯ã¿ã
ïŒïŒããäžèšã®åå¿åãåå¿äžåã¯åå¿åŸã«å
ããŠéå ç²åºŠã0.10ã0.27ãšããããªã¢ããã€ã
ãæš¹èã®çµæç©ãå°äœäžã«å¡ä»çŒä»ããããšãç¹
城ãšãã絶çžé»ç·ã®è£œé æ³ã ïŒ ããªã¢ããã€ããæš¹èãã©ã¯ã¿ã ãåå¿åã
åå¿äžåã¯åå¿åŸã«å ããŠæ«ç«¯å®èœåºïŒäž»ã«ã€ãœ
ã·ã¢ããŒãåºïŒãå°éããåŸãã¢ã«ã³ãŒã«åã³ïŒ
åã¯ãªãã·ã ãåå¿åŸã«å ããŠæ«ç«¯å®èœåºïŒäž»ã«
é žç¡æ°Žç©åºïŒãå°éãããŠåŸãããããªã¢ããã€
ããæš¹èã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çµ¶çž
é»ç·ã®è£œé æ³ã ïŒ è³éŠæãžã€ãœã·ã¢ããŒããïŒïŒ4â²âãžããšã
ã«ã¡ã¿ã³ãžã€ãœã·ã¢ããŒãåã¯ããªã¬ã³ãžã€ãœã·
ã¢ããŒãã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé åã¯ç¬¬ïŒé
èšèŒã®çµ¶çžé»ç·ã®è£œé æ³ã ïŒ ããªã«ã«ãã³é žç¡æ°Žç©ãããªã¡ãªããé žç¡æ°Ž
ç©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒé åã¯ç¬¬ïŒ
é èšèŒã®çµ¶çžé»ç·ã®è£œé æ³ã ïŒ å¡©åºæ§æº¶åªãâã¡ãã«ãããªãã³åã¯ãžã¡
ãã«ããªã«ã ã¢ããã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
é ã第ïŒé ã第ïŒé åã¯ç¬¬ïŒé èšèŒã®çµ¶çžé»ç·ã®
補é æ³ã ïŒ ã©ã¯ã¿ã ãεâã«ããã©ã¯ã¿ã ã§ããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒé ã第ïŒé ã第ïŒé åã¯ç¬¬
ïŒé èšèŒã®çµ¶çžé»ç·ã®è£œé æ³ã ïŒ å¡©åºæ§æº¶åªã®ååšäžã§ãè³éŠæãžã€ãœã·ã¢ã
ãŒãïŒïŒåã³ããªã«ã«ãã³é žç¡æ°Žç©ïŒïŒãã
ã»ãŒçã¢ã«ã§æš¹èåå«æéã40ééïŒ ä»¥äžãšããŠ
åå¿ãããç³»ã«ãããŠãè³éŠæãžã€ãœã·ã¢ããŒã
ïŒïŒïŒã¢ã«ã«å¯ŸããŠ0.1ã1.0ã¢ã«ã®ã©ã¯ã¿ã
ïŒïŒãªãã³ã«è³éŠæãžã€ãœã·ã¢ããŒãïŒïŒïŒ
ã¢ã«ã«å¯ŸããŠ0.01ã0.5ã¢ã«ã®ã¢ã«ã³ãŒã«ïŒïŒ
åã³ïŒåã¯ãªãã·ã ïŒïŒããäžèšã®åå¿åãå
å¿äžåã¯åå¿åŸã«å ããŠéå ç²åºŠã0.10ã0.27ãš
ããããªã¢ããã€ããæš¹èã®çµæç©ãå°äœäžã«å¡
åžçŒä»ããããšãç¹åŸŽãšãã絶çžç·ã®è£œé æ³ã ïŒ ã¢ã«ã³ãŒã«ãã¡ã¿ããŒã«ã§ããããªãã·ã ã
ïŒâãã¿ãã³ãªãã·ã ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
é èšèŒã®çµ¶çžé»ç·ã®è£œé æ³ã
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57178168A JPS5968108A (ja) | 1982-10-08 | 1982-10-08 | 絶çžé»ç·ã®è£œé æ³ |
US06/439,199 US4505980A (en) | 1982-10-08 | 1982-11-04 | Insulated wire |
DE19823249544 DE3249544C2 (de) | 1981-11-06 | 1982-11-05 | Isolierter Draht |
DE19823240934 DE3240934A1 (de) | 1981-11-06 | 1982-11-05 | Verfahren zur herstellung eines polyamid-imid-harzes |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57178168A JPS5968108A (ja) | 1982-10-08 | 1982-10-08 | 絶çžé»ç·ã®è£œé æ³ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5968108A JPS5968108A (ja) | 1984-04-18 |
JPH0114643B2 true JPH0114643B2 (ja) | 1989-03-13 |
Family
ID=16043799
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP57178168A Granted JPS5968108A (ja) | 1981-11-06 | 1982-10-08 | 絶çžé»ç·ã®è£œé æ³ |
Country Status (2)
Country | Link |
---|---|
US (1) | US4505980A (ja) |
JP (1) | JPS5968108A (ja) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2683416B2 (ja) * | 1989-05-17 | 1997-11-26 | äœåé»æ°å·¥æ¥æ ªåŒäŒç€Ÿ | 絶çžé»ç· |
DE3743780A1 (de) * | 1987-12-23 | 1989-07-06 | Bayer Ag | Verfahren zur verbesserung der haftfestigkeit von stromlos abgeschiedenen metallschichten auf polyimidoberflaechen |
US5219657A (en) * | 1988-10-04 | 1993-06-15 | Sumitomo Electric Industries Ltd. | Polyamideimide insulated wire |
US5206381A (en) * | 1989-08-07 | 1993-04-27 | Westinghouse Electric Corp. | Ultraviolet radiation curable polyamideimide oligomers |
US5281765A (en) * | 1992-05-27 | 1994-01-25 | Sumitomo Wiring Systems, Ltd. | Wiring assembly for equipment and a method for producing the same |
DE69613046T2 (de) * | 1995-06-29 | 2001-10-25 | Daiichi Denko Kk | Isolierter elektrischer Draht |
US5965263A (en) * | 1996-12-25 | 1999-10-12 | The Furukawa Electric Co., Ltd. | Insulated wire |
DE10041943A1 (de) * | 2000-08-25 | 2002-03-14 | Schenectady Int Inc | Polyamidimidharzlösung und ihre Verwendung zur Herstellung von Drahtlacken |
JP4057230B2 (ja) * | 2000-10-03 | 2008-03-05 | å€æ²³é»æ°å·¥æ¥æ ªåŒäŒç€Ÿ | 絶çžè¢«èŠé»æ°å°äœ |
FR2854900B1 (fr) * | 2003-05-16 | 2007-07-27 | Nexans | Composition pour couche adherente, conducteur electrique revetu d'une telle couche adherente et procede de fabrication d'un tel conducteur electrique |
JP4584014B2 (ja) * | 2005-04-25 | 2010-11-17 | æ¥ç«ãã°ãããã¯ã€ã€æ ªåŒäŒç€Ÿ | èéšåæŸé»æ§çµ¶çžå¡æã絶çžé»ç·ãåã³ãããã®è£œé æ¹æ³ |
JP4542463B2 (ja) * | 2005-04-25 | 2010-09-15 | æ¥ç«ãã°ãããã¯ã€ã€æ ªåŒäŒç€Ÿ | èéšåæŸé»æ§çµ¶çžå¡æã絶çžé»ç·ãåã³ãããã®è£œé æ¹æ³ |
JP5099577B2 (ja) * | 2006-07-04 | 2012-12-19 | äœåé»æ°å·¥æ¥æ ªåŒäŒç€Ÿ | èç±æ§æš¹èã¯ãã¹ãèç±æš¹èãã£ã«ã ãåã³èç±æš¹èè€åäœ |
KR20090031876A (ko) * | 2006-07-04 | 2009-03-30 | ì€ë¯ží 몚 ëŽí€ ê³ êµ ê°ë¶ìí€ê°ìŽì€ | ëŽìŽì± ìì§ ë°ëì, ëŽìŽ ìì§ íëŠ, ëŽìŽ ìì§ ë³µí©ì²Ž, ë° ì ì° ì ì |
DE102006052240A1 (de) * | 2006-11-03 | 2008-05-08 | Bayer Materialscience Ag | Lösungen blockierter Polyimide bzw. Polyamidimide |
JP4473916B2 (ja) * | 2008-01-09 | 2010-06-02 | æ¥ç«ãã°ãããã¯ã€ã€æ ªåŒäŒç€Ÿ | ããªã¢ããã€ããæš¹è絶çžå¡æåã³ãããçšãã絶çžé»ç· |
JP5397819B2 (ja) * | 2010-03-30 | 2014-01-22 | æ¥ç«éå±æ ªåŒäŒç€Ÿ | 絶çžå¡æããã³ãããçšãã絶çžé»ç· |
KR102358212B1 (ko) * | 2015-12-09 | 2022-02-04 | ëë ìŽ ì¹Žë¶ìí€ê°ìŽì€ | ìì§, ì¬ë¬ëŠ¬ ë° ê·žë€ì ì¬ì©í ì 잵첎ì ê·žì ì ì¡° ë°©ë² |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3528852A (en) * | 1965-10-27 | 1970-09-15 | Anaconda Wire & Cable Co | Dual-coated electrical conductor |
US3493413A (en) * | 1968-08-27 | 1970-02-03 | Anaconda Wire & Cable Co | Dual imide coated electrical conductor |
US4294952A (en) * | 1978-11-30 | 1981-10-13 | Hitachi Chemical Company, Ltd. | Polyamide-imide resin and its production |
JPS56106308A (en) * | 1980-01-24 | 1981-08-24 | Sumitomo Electric Industries | Insulated wire |
-
1982
- 1982-10-08 JP JP57178168A patent/JPS5968108A/ja active Granted
- 1982-11-04 US US06/439,199 patent/US4505980A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US4505980A (en) | 1985-03-19 |
JPS5968108A (ja) | 1984-04-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPH0114643B2 (ja) | ||
US4497944A (en) | Process for producing polyamide-imide resin | |
US4728697A (en) | Novel copolyamideimides, prepolymers therefor and method for their preparation | |
US7122244B2 (en) | Polyamide-imide resin solution and the use thereof for producing wire enamels | |
US20120318555A1 (en) | Polyamide-imide resin insulating coating material, insulated wire and coil | |
US4294952A (en) | Polyamide-imide resin and its production | |
US4447589A (en) | Method for preparing polyamide-imide resin | |
CA2261770A1 (en) | Wire enamels, comprising polyesterimides and/or polyamideimides with polyoxyalkylenediamines as molecular building blocks | |
US4740576A (en) | Preparation of polyamidoimide coatings having a long shelf life | |
DE3240934C2 (ja) | ||
CN109935392B (zh) | ç»çŒçµçº¿çšæž æŒãç»çŒçµçº¿ä»¥åçµæº | |
JPH0345728B2 (ja) | ||
US4379879A (en) | Heat resistant resin composition and insulating wire using the same which is a composition of an active hydrogen compound and the reaction product of a polyvalent isocyanate and a polyvalent carboxylic acid anhydride in an organic solvent | |
JPS6322217B2 (ja) | ||
JP2005179575A (ja) | ç±ç¡¬åæ§ããªã€ããæš¹èçµæç©ããã³ãã®ç¡¬åç© | |
EP1202292B1 (en) | Binder for a coating composition for electrical conductors | |
US4600729A (en) | Process for the preparation of aliphatic-aromatic poly-amide-imides in the absence of phenols | |
CA2359184A1 (en) | New coating binders with urea and/or hydantoin structures, a process for their production and their use | |
JPS6141086B2 (ja) | ||
US20140212665A1 (en) | Polyamide-imide coating material and insulated wire using the same | |
JPS5855168B2 (ja) | ããªã¢ããã€ããæš¹èçµæç©ããã³ãã®è£œé æ¹æ³ | |
JPS60243111A (ja) | èç±æ§æš¹èçµæç© | |
JPS6245644B2 (ja) | ||
JPH01182364A (ja) | èç±æ§æš¹èçµæç© | |
JP2943209B2 (ja) | 絶çžé»ç· |