JPH01102016A - Hair treating agent composition - Google Patents
Hair treating agent compositionInfo
- Publication number
- JPH01102016A JPH01102016A JP26148487A JP26148487A JPH01102016A JP H01102016 A JPH01102016 A JP H01102016A JP 26148487 A JP26148487 A JP 26148487A JP 26148487 A JP26148487 A JP 26148487A JP H01102016 A JPH01102016 A JP H01102016A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- alkyl
- formulas
- quaternary ammonium
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 18
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims abstract description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 125000001453 quaternary ammonium group Chemical group 0.000 claims 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 10
- -1 polyoxyethylene Polymers 0.000 abstract description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 230000002209 hydrophobic effect Effects 0.000 abstract description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract description 3
- 125000005843 halogen group Chemical group 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract 1
- 210000000744 eyelid Anatomy 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 230000007794 irritation Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000006210 lotion Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 3
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000003676 hair preparation Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 2
- 206010057385 Eyelid irritation Diseases 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 206010044625 Trichorrhexis Diseases 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- CAYHVMBQBLYQMT-UHFFFAOYSA-N 2-decyltetradecan-1-ol Chemical compound CCCCCCCCCCCCC(CO)CCCCCCCCCC CAYHVMBQBLYQMT-UHFFFAOYSA-N 0.000 description 1
- XULHFMYCBKQGEE-UHFFFAOYSA-N 2-hexyl-1-Decanol Chemical compound CCCCCCCCC(CO)CCCCCC XULHFMYCBKQGEE-UHFFFAOYSA-N 0.000 description 1
- YJHSJERLYWNLQL-UHFFFAOYSA-N 2-hydroxyethyl(dimethyl)azanium;chloride Chemical compound Cl.CN(C)CCO YJHSJERLYWNLQL-UHFFFAOYSA-N 0.000 description 1
- JYZLSYFPFQTNNO-UHFFFAOYSA-N 2-octyldecan-1-ol Chemical compound CCCCCCCCC(CO)CCCCCCCC JYZLSYFPFQTNNO-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 206010015946 Eye irritation Diseases 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005526 alkyl sulfate group Chemical group 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000003766 combability Effects 0.000 description 1
- 210000000795 conjunctiva Anatomy 0.000 description 1
- 210000004087 cornea Anatomy 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 231100000013 eye irritation Toxicity 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 230000003700 hair damage Effects 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 210000000554 iris Anatomy 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- PIUVNPNBPWVVKZ-UHFFFAOYSA-N octadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC PIUVNPNBPWVVKZ-UHFFFAOYSA-N 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000012487 rinsing solution Substances 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】 毛髪処理剤組成物に関する。[Detailed description of the invention] The present invention relates to a hair treatment composition.
[従来の技術]
通常、毛髪は頭皮から分泌される皮脂や、ヘアクリーム
、ヘアオイル等の動植物油脂等によりおおわれているが
石鹸や合成洗剤等で洗髪するとそれらの油脂成分は必要
以上に除去されてしまう。[Prior Art] Normally, hair is covered with sebum secreted from the scalp and animal and vegetable oils such as hair creams and hair oils, but when hair is washed with soap or synthetic detergents, these oils and fats are removed more than necessary. Put it away.
そのため洗髪後の毛髪は滑かざが失われパサパサした硬
い感触となり、櫛通りが悪くなって裂毛や枝毛が生じや
すくなってしまう。まして昨今のようにおしやれ意識の
向上からパーマの利用、ヘアカラー、ブリーチの利用が
通常化してきている中では、毛髪の損傷が進み上記現象
は助長される。As a result, the hair after washing loses its smoothness and feels dry and hard, making it difficult to comb and causing split ends and split ends. Furthermore, as the use of perms, hair coloring, and bleaching are becoming more common as people become more conscious about their appearance, hair damage progresses and the above phenomenon is exacerbated.
このよう、な不都合を解消するために洗髪後の処理剤と
して各種の毛髪化粧料が開発され使用されている。これ
ら毛髪化粧料は第四級アンモニウム塩を主成分とするも
のであり、第四級アンモニウム塩には、水難溶性のもの
と水易溶性のものどがある。従ってそれに対応して毛髪
化粧料には、「すすぐタイプのもの」と「すすがないタ
イプ」のものとがあって、それぞれの使用形態を典なら
しめている。In order to overcome these inconveniences, various hair cosmetics have been developed and used as post-washing treatment agents. These hair cosmetics mainly contain quaternary ammonium salts, and quaternary ammonium salts include those that are poorly soluble in water and those that are easily soluble in water. Accordingly, there are two types of hair cosmetics: ``rinsing type'' and ``non-rinsing type'', each with its own standard usage format.
水易溶性のものは透明な状態を得やすいが上述した効果
、即ち毛髪に対する滑かざ、パサパサした硬い感触、櫛
通りの改善の点で効果に乏しい。Easily water-soluble products tend to provide a transparent state, but are poor in the above-mentioned effects, ie, improving the smoothness of the hair, the dry and hard feel, and the improvement of combability.
一方、水難溶性のものは透明な状態にするために、HL
Bの高い活性剤が配合されてきた。しかしながら、HL
Bの高い活性剤の影響により水難溶性の第四級アンモニ
ウム塩の毛髪への吸着が阻害され、洗髪後等の毛髪のき
しみや、もつれの防止、優れた仕上り感といった第四級
アンモニウム塩がもつ本来の効果が、発揮されていなか
ったのが実状である。On the other hand, for poorly water-soluble substances, HL is used to make them transparent.
Activators with high B have been formulated. However, H.L.
Due to the effect of the active agent with a high B content, the adsorption of poorly water-soluble quaternary ammonium salts to the hair is inhibited, and the effects of quaternary ammonium salts include prevention of hair squeaks and tangles after washing, and excellent finish feel. The reality is that the intended effects were not being achieved.
また、第四級アンモニウム塩単独の溶液は、極めて強い
眼瞼刺激性を示し、アニオン性界面活性剤やノニオン性
界面活性剤等と比べると顕著であって美容上、健康上大
きな問題であり、その刺激緩和は強く望まれているとこ
ろである。In addition, solutions containing only quaternary ammonium salts exhibit extremely strong eyelid irritation, which is more pronounced than anionic surfactants or nonionic surfactants, and is a major cosmetic and health problem. Stimulus relief is strongly desired.
[発明が解決しようとする問題点1
本発明者らは、上記事情に鑑み鋭意研究をかきねた結果
、特定のシリコーン化合物と、第四級アンモニウム塩及
びエタノールとを組合せることにより、「すすぐタイプ
」および「すすがないタイプ」のいずれのタイプに適用
しても、透明で、眼19やJ激性の低い、使用性(滑か
き及び光沢を毛髪に付与)に優れた毛髪処理剤組成物が
得られることを見い出し本発明を完成するに至った。[Problem to be Solved by the Invention 1] In view of the above circumstances, the present inventors have made extensive research and have found that by combining a specific silicone compound, a quaternary ammonium salt, and ethanol, a "rinsing solution" can be achieved. A hair treatment agent composition that is transparent, has low eye irritation and is easy to use (gives smoothness and shine to hair), regardless of whether it is applied to either the ``type'' or the ``no-rinse type''. The present inventors have discovered that a product can be obtained and have completed the present invention.
F問題点を解決するための手段]
すなわち、本発明は、(I)ポリオキシアルキレン変性
オルガノポリシロキサンの一種又は二捕取」−と、(I
I)第四級アンモニウム塩0.2〜10重量%と、(I
ll)エタノールとを含有し、(I)/(TI)の重量
比が371〜10/1であることを特徴とする毛髪処理
剤組成物である。Means for Solving Problem F] That is, the present invention provides (I) one or two trapping polyoxyalkylene-modified organopolysiloxanes;
I) 0.2 to 10% by weight of a quaternary ammonium salt;
ll) ethanol, and the weight ratio of (I)/(TI) is 371 to 10/1.
以下、本発明の構成について詳述する。Hereinafter, the configuration of the present invention will be explained in detail.
本発明に用いられるポリオキシアルキレン変性オルガノ
ポリシロキサンは、下記一般式[A]乃至[D]で表さ
れる化合物である。The polyoxyalkylene-modified organopolysiloxane used in the present invention is a compound represented by the following general formulas [A] to [D].
本発明に用いられるポリオキシアルキレン変性オルガノ
ポリシロキサンの平均分子量は3000以上を有するも
のが好ましく、更に好ましくは5000以上である。ま
た、ポリオキシアルキレン変性オルガノポリシロキサン
分子中にポリオキシアルキレン基を2〜80重量%含有
するものが好ましく、効果発現の面から更に好ましくは
、11〜40重量%である。The polyoxyalkylene-modified organopolysiloxane used in the present invention preferably has an average molecular weight of 3,000 or more, more preferably 5,000 or more. Further, it is preferable that the polyoxyalkylene-modified organopolysiloxane molecule contains 2 to 80% by weight of polyoxyalkylene groups, and more preferably 11 to 40% by weight from the viewpoint of effect expression.
本発明に用いられる第四級アンモニウム塩は、下記一般
式で表される化合物である。The quaternary ammonium salt used in the present invention is a compound represented by the following general formula.
(式中Rt、R2、R3及びR4はアルキル基、ヒドロ
キシアルキル基、ポリオキシエチレン基、ベンジル基で
あり、そのうちの1個又は2個は炭素数12〜18の長
鎖アルキル基、残りは炭素数1〜3のアルキル基、ヒド
ロキシアルキル基、ポリオキシエチレン基又はベンジル
基のいずれかである。(In the formula, Rt, R2, R3, and R4 are an alkyl group, a hydroxyalkyl group, a polyoxyethylene group, or a benzyl group, one or two of which are long-chain alkyl groups with 12 to 18 carbon atoms, and the rest are carbon atoms.) It is any one of number 1 to 3 alkyl groups, hydroxyalkyl groups, polyoxyethylene groups, or benzyl groups.
モしてXは、ハロゲン原子又はアルキル基の炭素数が1
又は2のアルキル硫酸基を示す。)本発明に゛用いられ
る第四級アンモニウム塩を例示すると、アルキルトリメ
チルアンモニウムクロライド、ジアルキルジメチルアン
モニウムクロライド、ジアルキルメチルビス(2−ヒド
ロキシエチル)アンモニウムクロライド、ジアルキルメ
チル(2−ヒドロキシエチル)アンモニウムクロライド
、アルキルジメチル(2−ヒドロキシエチル)アンモニ
ウムクロライド、アルキルペンタエトキシ化アンモニウ
ムクロライド、ジアルキルポリエトキシ化アンモニウム
クロライド等が挙げられる。これらの中でも、パルミチ
ルトリメチルアンモニウムクロライド、牛脂アルキルト
リメチルアンモニウムクロライド、ステアリルトリメチ
ルアンモニウムクロライド等のアルキルトリメチルアン
モニウムクロライドが特に好ましい。本発明の第四級ア
ンモニウム塩は、上記のものの一種又は二種以上が用い
られる。and X is a halogen atom or an alkyl group having 1 carbon number
or 2 alkyl sulfate group. ) Examples of quaternary ammonium salts used in the present invention include alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, dialkylmethylbis(2-hydroxyethyl)ammonium chloride, dialkylmethyl(2-hydroxyethyl)ammonium chloride, and alkyltrimethylammonium chloride. Examples include dimethyl (2-hydroxyethyl) ammonium chloride, alkylpentaethoxylated ammonium chloride, dialkyl polyethoxylated ammonium chloride, and the like. Among these, alkyltrimethylammonium chlorides such as palmityltrimethylammonium chloride, tallow alkyltrimethylammonium chloride, and stearyltrimethylammonium chloride are particularly preferred. As the quaternary ammonium salt of the present invention, one or more of the above salts may be used.
本発明の第四級アンモニウム塩の配合量は、毛髪処理剤
組成物全量中、0.2〜10重量%である。The amount of the quaternary ammonium salt of the present invention is 0.2 to 10% by weight based on the total amount of the hair treatment composition.
0.2重量%未満では、本発明の効果を満足きせること
かできず、10重量%を越えると毛髪にべたつとが生じ
、好ましくない。If it is less than 0.2% by weight, the effect of the present invention cannot be achieved, and if it exceeds 10% by weight, the hair will become sticky, which is not preferable.
本発明の毛髪処理剤組成物においては、上述のポリオキ
シアルキレン変性オルガノポリシロキサンと、第四級ア
ンモニウム塩との重量比は、371〜10ハの範囲にあ
る必要があり、特に好ましくは371〜8/1である。In the hair treatment composition of the present invention, the weight ratio of the polyoxyalkylene-modified organopolysiloxane and the quaternary ammonium salt must be in the range of 371 to 10, particularly preferably 371 to 10. It is 8/1.
371未満か又は10/1を越える場合には、本発明の
効果を得ることができない。If it is less than 371 or more than 10/1, the effects of the present invention cannot be obtained.
本発明に用いられるエタノールの配合量は、ポリオキシ
アルキレン変性オルガノポリシロキサン及び第四級アン
モニウム塩を溶解しうる量である。The amount of ethanol used in the present invention is an amount that can dissolve the polyoxyalkylene-modified organopolysiloxane and the quaternary ammonium salt.
本発明の毛髪処理剤組成物は、透明であるが、さらにこ
の組成物に水を添加したものも透明であり、有用である
。また、本発明の毛髪処理剤組成物には、上記した成分
の他に、疎水性シリコーン、分枝高級アルコール、液状
炭化水素、液状エステル油分等の油性物質を配合すると
、効果の面で特に好ましい。The hair treatment composition of the present invention is transparent, but a composition obtained by adding water to this composition is also transparent and useful. Furthermore, in addition to the above-mentioned components, it is particularly preferable to incorporate oily substances such as hydrophobic silicones, branched higher alcohols, liquid hydrocarbons, and liquid ester oils into the hair treatment composition of the present invention in terms of effects. .
疎水性シリコーンとしては、メチルポリシロキサン、メ
チルフェニルポリシロキサン、脂肪酸変性ポリシロキサ
ン、脂肪族アルコール変性ポリシロキサン等が挙げられ
る。分枝高級アルコールとしては、2−オクチルドデカ
ノール、2−デシルテトラデカノール、2−オクチルデ
カノール、2−へキシルデカノール、2−へブチルウン
デカノール等が挙げられる。Examples of the hydrophobic silicone include methylpolysiloxane, methylphenylpolysiloxane, fatty acid-modified polysiloxane, and aliphatic alcohol-modified polysiloxane. Examples of the branched higher alcohol include 2-octyldodecanol, 2-decyltetradecanol, 2-octyldecanol, 2-hexyldecanol, and 2-hebutylundecanol.
液状炭化水素としては、流動パラフィン、スクワラン等
が挙げられる。Examples of liquid hydrocarbons include liquid paraffin and squalane.
液状エステル油分としては、イソプロピルミリステート
、セチル−2−エチルヘキサノエート、ステアリル−2
−エチルヘキサノエート、リンゴ酸ジイソステアリルア
ルコールエステル、シカプリン酸ネオペンチルグリコー
ル、ジー2−エチルヘキサン酸エチレングリコール、1
2−ヒドロキシステアリン酸コレステリル、シカプリン
酸ネオペンチル □、〈グリコール等が挙げられる。Liquid ester oils include isopropyl myristate, cetyl-2-ethylhexanoate, stearyl-2
-Ethylhexanoate, diisostearyl malate alcohol ester, neopentyl glycol capriate, ethylene glycol di-2-ethylhexanoate, 1
Examples include cholesteryl 2-hydroxystearate, neopentyl capriate, and glycol.
これら、油性物質を配合する場合の好ましい配合比とし
ては、ポリオキシアルキレン変性オルガノボリシロキ1
ナンと第四級アンモニウム塩との総重量に対して174
〜1/10である。When blending these oil-based substances, the preferred blending ratio is polyoxyalkylene-modified organoborisiloxane 1
174 based on the total weight of Nan and quaternary ammonium salt
~1/10.
本発明の毛髪処理剤組成物には、ざらに必要に応じて保
湿剤、香料、防腐剤等を配合することができる。なお、
これらは本発明の目的を損なわない質的、量的条件下で
使用されなければならない。The hair treatment composition of the present invention may contain a humectant, a fragrance, a preservative, etc., as necessary. In addition,
These must be used under qualitative and quantitative conditions that do not impair the purpose of the invention.
本発明の毛髪処理剤組成物は、ヘアリンス剤、プレヘア
リンス剤、スプレー型又はデイスペンサー型のヘアコン
ディショナー、ヘアローラ3ン等の各種用途に利用でき
る。The hair treatment composition of the present invention can be used in various applications such as hair rinses, pre-hair rinses, spray-type or dispenser-type hair conditioners, and hair rollers.
[発明の効果]
本発明は、ポリオキシアルキレン変性オルガノポリシロ
キサンと、第四級アンモニウム塩と、エタノールとを特
定比率で配合することにより、透明性、使用性に優れ、
しかも刺激のない毛髪処理剤組成物を提供するものであ
る。[Effects of the Invention] The present invention has excellent transparency and usability by blending a polyoxyalkylene-modified organopolysiloxane, a quaternary ammonium salt, and ethanol in a specific ratio.
Moreover, it provides a hair treatment composition that does not cause irritation.
[実施例]
次に実施例及び比較例をあげて、本発明を具体的に説明
する。本発明はこれにより限定されるものではない。配
合量は重量%である。[Example] Next, the present invention will be specifically explained with reference to Examples and Comparative Examples. The present invention is not limited thereby. The blending amount is in weight%.
実施例に先立ち評価法を以下に示す。Prior to Examples, evaluation methods are shown below.
盈凱並 以下の基準で肉眼で判定を行なった。Eikai parallel Judgment was made visually according to the following criteria.
O・・・透明
Δ・・・少しかすむ
X・・・不透明又は沈澱あり
t ) 1 ′
シャンプー処理された毛束(5g、 20cm)に試料
0.5gを直接塗布し、手で均一に伸ばした後、25℃
、65%R)lの雰囲気で乾燥させ、−昼夜放置後の毛
束の状態について、20名のパネラ−により評価した。0...Transparent Δ...Slightly hazy After that, 25℃
, 65% R)l, and the condition of the hair bundles after being left to stand day and night was evaluated by 20 panelists.
評価基準は、1.0重量%のステアリルトリメチルアン
モニウムクロライド、3重量%のセチルアルコール、1
0重量%のプロピレングリコール及び水(残部)からな
る試料と比較し、下記の6段階で評価した。The evaluation criteria were: 1.0% by weight stearyltrimethylammonium chloride, 3% by weight cetyl alcohol, 1% by weight
It was compared with a sample consisting of 0% by weight of propylene glycol and water (the remainder) and evaluated on the following 6 scales.
0:非常に優れている。0: Very good.
O:やや優れている。O: Slightly excellent.
△:同等。△: Equivalent.
X:やや劣っている。X: Slightly inferior.
×X:劣っている。×X: Inferior.
贋U肱車H1社」k形−
家兎の目の結膜のうに試料を滴下し、その後、一定時間
毎に角膜、虹彩、結膜に生じた反応を判定し、その最大
値を動物数で平均して眼瞼刺激とした。K-type - A sample is dropped into the conjunctival sac of a rabbit's eye, and the reactions that occur in the cornea, iris, and conjunctiva are determined at regular intervals, and the maximum value is averaged over the number of animals. It was used as eyelid irritation.
実施例1〜18、比較例1〜5
表−1,2に示す組成物を調製し、透明性、使用性及び
刺激性について調べた。なお、ポリオキシアルキレン変
性オルガノポリシロキサンの詳細については表−3に示
す。Examples 1 to 18, Comparative Examples 1 to 5 The compositions shown in Tables 1 and 2 were prepared and examined for transparency, usability, and irritation. The details of the polyoxyalkylene-modified organopolysiloxane are shown in Table 3.
(以下余白)
表−1,2から明らかなように本発明の組成物は、透明
性、なめらかざ及びつやに優れ、しかもほとんど刺激性
がないことがわかる。(The following is a blank space) As is clear from Tables 1 and 2, the composition of the present invention has excellent transparency, smooth texture, and gloss, and has almost no irritation.
実施例19 ヘアトリートメントローション(1)ポ
リオキシアルキレン変性
オルガノポリシロキサン 2.0
[一般式A POE基20重量%
分子量6000 ]
(2)シバルミチルジメチル
アンモニウムクロライド 0.4(3)エタノ
ール 40.0(4)プロピ
レングリコール 6.0(5)ジメチル
ポリシロキサン(6cps) 0.2(6)色素
適量(7)香料
適量(8)精製水
残部製法
(3)に(IL(2)を溶解し、ざらにこれに(5)と
(7)を添加溶解する[A部]。Example 19 Hair treatment lotion (1) Polyoxyalkylene-modified organopolysiloxane 2.0 [General formula A POE group 20% by weight, molecular weight 6000] (2) Civalmityldimethylammonium chloride 0.4 (3) Ethanol 40.0 ( 4) Propylene glycol 6.0 (5) Dimethylpolysiloxane (6 cps) 0.2 (6) Pigment Appropriate amount (7) Fragrance
Appropriate amount (8) Purified water
The remainder is prepared by dissolving IL (2) in method (3), and roughly adding and dissolving (5) and (7) [Part A].
(4) 、(6)を(8)に溶解する[B部]。(4) Dissolve (6) in (8) [Part B].
[B部]を[A部]に撹拌添加してヘアトリートメント
ローションを得る。[Part B] is stirred and added to [Part A] to obtain a hair treatment lotion.
実施例20 ヘアトリートメントローション(i)ポ
リオキシアルキレン変性
オルガノポリシロキサン 1.2
[一般式A POE基30重量%
分子量20000 ]
(2)ステアリルトリメチル
アンモニウムクロライド 0.2(3)エタノ
ール 30.0(4)ジプロピ
レングリコール 2.0(5)カチオニッ
クボリペプタイド 0.6(6)スク、フラン
0.1(7)イソプロピルミ
リステート 0.1(8)色素
適量(9)香料
適量(10)精製水
残部製法
(3)に(IL(2)を溶解し、ざらにこれに(6)、
(7)と(9)を添加溶解する[A部]。Example 20 Hair treatment lotion (i) Polyoxyalkylene-modified organopolysiloxane 1.2 [General formula A POE group 30% by weight Molecular weight 20000] (2) Stearyltrimethylammonium chloride 0.2 (3) Ethanol 30.0 (4) ) Dipropylene glycol 2.0 (5) Cationic voripeptide 0.6 (6) Suku, Furan
0.1(7) Isopropyl myristate 0.1(8) Pigment
Appropriate amount (9) Fragrance
Appropriate amount (10) Purified water
For the remaining part (dissolve IL (2) in method (3), add it to (6),
Add and dissolve (7) and (9) [Part A].
(4) 、(5) 、(8)を(10)に溶解する[B
部]。Dissolve (4), (5), and (8) in (10) [B
Department].
[8部1を[A部]に撹拌添加してヘアトリートメント
ローションを得る。[Part 8 1 is stirred and added to [Part A] to obtain a hair treatment lotion.
実施例19.20は、透明性、なめらかき及びつやに優
れ、しかもほとんど刺激性がなかった。Examples 19 and 20 had excellent transparency, smoothness, and gloss, and had almost no irritation.
特許出願人 株式会社 資生堂Patent applicant: Shiseido Co., Ltd.
Claims (1)
より選ばれたポリオキシアルキレン変性オルガノポリシ
ロキサンの一種又は二種以上と、 (II)第四級アンモニウム塩0.2〜10重量%と、 (III)エタノールとを含有し、( I )/(II)の重量
比が3/1〜10/1であることを特徴とする毛髪処理
剤組成物。 ▲数式、化学式、表等があります▼[A] ▲数式、化学式、表等があります▼[B] ▲数式、化学式、表等があります▼[C] ▲数式、化学式、表等があります▼[D] (式中、Rは炭素数1乃至3のアルキル基、又はフェニ
ル基、R′は水素、又は炭素数1乃至12のアルキル基
、pは1乃至5の整数、mは5乃至100の整数、nお
よびxは1乃至50の整数、tおよびyは0乃至50の
整数である。)[Scope of Claims] (I) one or more polyoxyalkylene-modified organopolysiloxanes selected from compounds represented by the following general formulas [A] to [D]; (II) quaternary ammonium A hair treatment composition comprising 0.2 to 10% by weight of a salt and (III) ethanol, the weight ratio of (I)/(II) being 3/1 to 10/1. ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [A] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [B] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [C] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [ D] (wherein, R is an alkyl group having 1 to 3 carbon atoms or a phenyl group, R' is hydrogen or an alkyl group having 1 to 12 carbon atoms, p is an integer of 1 to 5, and m is an integer of 5 to 100. (Integers, n and x are integers from 1 to 50, and t and y are integers from 0 to 50.)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62261484A JPH0764709B2 (en) | 1987-10-16 | 1987-10-16 | Hair treatment composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62261484A JPH0764709B2 (en) | 1987-10-16 | 1987-10-16 | Hair treatment composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH01102016A true JPH01102016A (en) | 1989-04-19 |
JPH0764709B2 JPH0764709B2 (en) | 1995-07-12 |
Family
ID=17362547
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62261484A Expired - Lifetime JPH0764709B2 (en) | 1987-10-16 | 1987-10-16 | Hair treatment composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0764709B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007161207A (en) * | 2005-12-16 | 2007-06-28 | Aisin Seiki Co Ltd | Clip mounting structure for vehicular molding |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55108811A (en) * | 1979-02-10 | 1980-08-21 | Lion Corp | Hair-treating composition |
JPS55136214A (en) * | 1979-04-09 | 1980-10-23 | Lion Corp | Hair conditioner composition |
JPS584709A (en) * | 1981-06-30 | 1983-01-11 | Lion Corp | Brushing composition |
JPS5826811A (en) * | 1981-08-10 | 1983-02-17 | Lion Corp | Hair treatment composition |
JPS60126209A (en) * | 1983-12-09 | 1985-07-05 | Lion Corp | Cosmetic |
JPS6229406A (en) * | 1985-07-31 | 1987-02-07 | Mazda Motor Corp | Rear suspension device for automobile |
JPS63183520A (en) * | 1986-09-18 | 1988-07-28 | Kao Corp | Emulsion type hair cosmetic |
-
1987
- 1987-10-16 JP JP62261484A patent/JPH0764709B2/en not_active Expired - Lifetime
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55108811A (en) * | 1979-02-10 | 1980-08-21 | Lion Corp | Hair-treating composition |
JPS55136214A (en) * | 1979-04-09 | 1980-10-23 | Lion Corp | Hair conditioner composition |
JPS584709A (en) * | 1981-06-30 | 1983-01-11 | Lion Corp | Brushing composition |
JPS5826811A (en) * | 1981-08-10 | 1983-02-17 | Lion Corp | Hair treatment composition |
JPS60126209A (en) * | 1983-12-09 | 1985-07-05 | Lion Corp | Cosmetic |
JPS6229406A (en) * | 1985-07-31 | 1987-02-07 | Mazda Motor Corp | Rear suspension device for automobile |
JPS63183520A (en) * | 1986-09-18 | 1988-07-28 | Kao Corp | Emulsion type hair cosmetic |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007161207A (en) * | 2005-12-16 | 2007-06-28 | Aisin Seiki Co Ltd | Clip mounting structure for vehicular molding |
Also Published As
Publication number | Publication date |
---|---|
JPH0764709B2 (en) | 1995-07-12 |
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