JPH01100102A - Acaricide comprising dimethylalkylbetaine as active ingredient - Google Patents
Acaricide comprising dimethylalkylbetaine as active ingredientInfo
- Publication number
- JPH01100102A JPH01100102A JP25562687A JP25562687A JPH01100102A JP H01100102 A JPH01100102 A JP H01100102A JP 25562687 A JP25562687 A JP 25562687A JP 25562687 A JP25562687 A JP 25562687A JP H01100102 A JPH01100102 A JP H01100102A
- Authority
- JP
- Japan
- Prior art keywords
- acaricide
- mites
- active ingredient
- dimethylalkylbetaine
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000642 acaricide Substances 0.000 title claims abstract description 25
- 239000004480 active ingredient Substances 0.000 title claims abstract description 14
- 230000000895 acaricidal effect Effects 0.000 title abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 18
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims description 4
- 229960003237 betaine Drugs 0.000 claims description 4
- 230000000717 retained effect Effects 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 2
- -1 polyethylene Polymers 0.000 abstract description 27
- 239000000123 paper Substances 0.000 abstract description 13
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- 239000004677 Nylon Substances 0.000 abstract description 5
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- 229920001778 nylon Polymers 0.000 abstract description 5
- 229920000573 polyethylene Polymers 0.000 abstract description 5
- 239000004743 Polypropylene Substances 0.000 abstract description 4
- 239000004745 nonwoven fabric Substances 0.000 abstract description 4
- 229920000728 polyester Polymers 0.000 abstract description 4
- 229920001155 polypropylene Polymers 0.000 abstract description 4
- 229920003002 synthetic resin Polymers 0.000 abstract description 4
- 239000000057 synthetic resin Substances 0.000 abstract description 4
- 231100000053 low toxicity Toxicity 0.000 abstract description 3
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- 239000010935 stainless steel Substances 0.000 abstract description 2
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- 241000238876 Acari Species 0.000 description 33
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- 238000012360 testing method Methods 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 11
- 239000000843 powder Substances 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 7
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- 238000010998 test method Methods 0.000 description 7
- XLOPRKKSAJMMEW-SFYZADRCSA-M (R,R)-chrysanthemate Chemical compound CC(C)=C[C@@H]1[C@@H](C([O-])=O)C1(C)C XLOPRKKSAJMMEW-SFYZADRCSA-M 0.000 description 6
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- 238000005507 spraying Methods 0.000 description 5
- 241000238710 Dermatophagoides Species 0.000 description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 241000238631 Hexapoda Species 0.000 description 4
- 235000019441 ethanol Nutrition 0.000 description 4
- 239000010903 husk Substances 0.000 description 4
- 239000005871 repellent Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
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- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
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- 239000010902 straw Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 240000008620 Fagopyrum esculentum Species 0.000 description 2
- 235000009419 Fagopyrum esculentum Nutrition 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 210000003746 feather Anatomy 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000012784 inorganic fiber Substances 0.000 description 2
- 239000003915 liquefied petroleum gas Substances 0.000 description 2
- GTCAXTIRRLKXRU-UHFFFAOYSA-N methyl carbamate Chemical compound COC(N)=O GTCAXTIRRLKXRU-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000002728 pyrethroid Substances 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
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- 235000009566 rice Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
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- 238000012546 transfer Methods 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- VEMKTZHHVJILDY-PMACEKPBSA-N (5-benzylfuran-3-yl)methyl (1r,3s)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-PMACEKPBSA-N 0.000 description 1
- LNJXZKBHJZAIKQ-UHFFFAOYSA-N 1,1,1,2-tetrachloro-3-(2,3,3,3-tetrachloropropoxy)propane Chemical compound ClC(Cl)(Cl)C(Cl)COCC(Cl)C(Cl)(Cl)Cl LNJXZKBHJZAIKQ-UHFFFAOYSA-N 0.000 description 1
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
- GNEPLYVYORHREW-UHFFFAOYSA-N 1,1,3,3,6-pentamethyl-7-nitro-2h-inden-5-amine Chemical compound CC1=C(N)C=C2C(C)(C)CC(C)(C)C2=C1[N+]([O-])=O GNEPLYVYORHREW-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- HEOKTYUDLCFFTF-UHFFFAOYSA-N 1,7-dimethylbicyclo[2.2.1]heptane-7-carbaldehyde Chemical compound CC12CCC(CC1)C2(C)C=O HEOKTYUDLCFFTF-UHFFFAOYSA-N 0.000 description 1
- NCDBYAPSWOPDRN-UHFFFAOYSA-N 2-[dichloro(fluoro)methyl]sulfanylisoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(SC(Cl)(Cl)F)C(=O)C2=C1 NCDBYAPSWOPDRN-UHFFFAOYSA-N 0.000 description 1
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000272814 Anser sp. Species 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 241001609213 Carassius carassius Species 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- 241000252233 Cyprinus carpio Species 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- PNVJTZOFSHSLTO-UHFFFAOYSA-N Fenthion Chemical compound COP(=S)(OC)OC1=CC=C(SC)C(C)=C1 PNVJTZOFSHSLTO-UHFFFAOYSA-N 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
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- 238000000354 decomposition reaction Methods 0.000 description 1
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
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- USPVNSDVCUTNJN-UHFFFAOYSA-N ethenyl cyclopropanecarboxylate Chemical compound C=COC(=O)C1CC1 USPVNSDVCUTNJN-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
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- 239000001963 growth medium Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
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- RPVDAUDBFGUPKL-UHFFFAOYSA-N propan-2-yl 2-(4-chlorophenyl)acetate Chemical compound CC(C)OC(=O)CC1=CC=C(Cl)C=C1 RPVDAUDBFGUPKL-UHFFFAOYSA-N 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明はジメチルアルキルベタインを含有することを特
徴とする殺ダニ剤及びダニ防除材に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to an acaricide and a mite control material containing dimethylalkyl betaine.
室内塵性のダニは屋内のいたるところで見出されその生
息域は畳、カーペットのみならずソファ−１ぬいぐるみ
、寝具類までにも及んでいる。Indoor dust mites are found everywhere indoors, and their habitat extends not only to tatami mats and carpets, but also to sofa-1 stuffed animals and bedding.
従来よりこのような室内塵性のダニに対する殺ダニ剤と
してはフェニトロチオン、フェンチオン、ＤＤＶＰ、ダ
イアジノン等のリン系化合物、プロポクサー、ＮＡＣ等
のカーバメイト系化合物、レスメトリン等のピレスロイ
ド系の化合物が知られている。Conventionally, known acaricides against indoor dust mites include phosphorus compounds such as fenitrothion, fenthion, DDVP, and diazinon, carbamate compounds such as propoxar and NAC, and pyrethroid compounds such as resmethrin. .
これら公知の殺ダニ剤は畳、カーペット用防虫紙に保持
させたり、そのまま散布、噴霧等して用いられているが
、リン系やカーバメイト系の殺ダニ剤は毒性が高くヒヨ
ウヒダニ類に対する効果が低いため、その適用範囲及び
適用量の限定を受けろ。また、ピレスロイド剤は高価で
遅効性であるため、その適用方法及び適用量の限定を受
ける 等種々の欠点を有している。These known acaricides are used by retaining them on insect repellent paper for tatami mats and carpets, or by spraying or spraying them directly, but phosphorus-based and carbamate-based acaricides are highly toxic and have low effectiveness against Dermatophagoides mites. Therefore, the scope and amount of application must be limited. In addition, pyrethroid agents are expensive and slow-acting, so they have various drawbacks, such as being limited in the method and amount of application.
そこで本発明者らは前記従来技術の問題点を解決すべく
鋭意研究を重ねた結果、帯電防止や柔軟性付与等の目的
で＆！維、化粧品関係に使用されろ両性界面活性剤であ
るジメチルアルキルベタインを有効成分とした場合、前
記した従来の殺ダニ剤の有する欠点がことごとく解消さ
れ、低毒性で人体に対する安全性にすぐれ、ヒヨウヒダ
ニ類等あらゆる種類のダニ類に効果のある殺ダニ剤を見
出し、本発明を完成するにいたった。Therefore, the inventors of the present invention have conducted extensive research to solve the problems of the prior art, and have found that &! When dimethylalkyl betaine, which is an amphoteric surfactant used in textiles and cosmetics, is used as an active ingredient, all of the drawbacks of the conventional acaricides mentioned above are eliminated, and it has low toxicity and excellent safety for the human body. They discovered a miticide that is effective against all kinds of mites, and completed the present invention.
Ｃ問題点を解決するための手段〕
すなわち本発明は
（υ一般式
％式％
（式中、ｎは８〜２４を表わす）
本発明において駆除の対象となるダニ類は、いずれの種
類でも対象をとなり得るが、特１こコナヒテウヒダニや
ヤケヒツウヒダニ等のヒヨウヒダニ類、ケナガコナダニ
やムギコナダニ等のコナダニ類、チリニクダニやイエニ
クダニ等のニクダニ類、ホコリダニ類、クワガタツメダ
ニやフトツメダニ等のツメダニ類、イエダニやトリサシ
ダニ等の動物寄生性ダニ類が挙げられろ。Means for Solving Problem C] That is, the present invention is based on (υ general formula % formula % (in the formula, n represents 8 to 24). Any type of mites to be exterminated in the present invention can be However, in particular, mites such as Dermatophagoides mites and Dermatophagoides mites, mites such as woolly mites and wheat mites, dust mites such as dust mites and dust mites, dust mites, mites such as stag mites and foot mites, and animals such as dust mites and common dust mites. List parasitic mites.
本発明の殺ダニ剤はそのまま用いることもできろが、通
常は液体担体及び固体担体に保持させ、必要に応じ塗膜
形成剤、乳化剤、分散剤、展着剤、湿潤剤、安定剤、噴
射剤、揮散調整剤等を添加して、油剤、乳剤、水溶液剤
、水和剤、噴霧剤、エアゾール剤、燻煙剤、塗布剤、粉
剤、粒剤等の形態で使用することができる。Although the acaricide of the present invention can be used as it is, it is usually held in a liquid carrier or a solid carrier, and if necessary, it can be treated with a film forming agent, an emulsifier, a dispersing agent, a spreading agent, a wetting agent, a stabilizer, or a spraying agent. It can be used in the form of oils, emulsions, aqueous solutions, wettable powders, sprays, aerosols, smokers, liniments, powders, granules, etc. by adding agents, volatilization regulators, etc.
前記液体担体としては、水や例えばメチルアルコール、
エチルアルコール、イソプロピルアルコール等のアルコ
ール類、アセトン、メチルエチルケトン、シクロヘキサ
ノン等のケトン類、テトラヒドロフラン、ジオキサン、
ツメチルエーテル等のエーテル類、ヘキサン、ケロシン
、ノルマルパラフィン、ソルベントナフサ等の脂肪族炭
化水素類、ベンゼン、トルエン等の芳香族炭化水素類、
ジクロロメタン、ジクロロエタン等のハロゲン化炭化水
素類、酢酸エチル、酢酸ブチル等のエステル類、フロン
系溶剤（フロン１１３、フロン１１４ Ｂ２、フロン
２１゜フロンｌＯ等）を挙げることができる。固体担体
としては、例えばケイ酸、カオリン、活性炭、ベントナ
イト、ケイソウ土、タルク、クレー、炭酸カルシウム、
陶磁器粉等の鉱物性粉末、木粉、大豆粉、小麦粉、でん
粉等の植物質粉末、シクロデキストリン等の包接化合物
等を挙げることができる。The liquid carrier may be water, eg methyl alcohol,
Alcohols such as ethyl alcohol and isopropyl alcohol, ketones such as acetone, methyl ethyl ketone, and cyclohexanone, tetrahydrofuran, dioxane,
Ethers such as trimethyl ether, aliphatic hydrocarbons such as hexane, kerosene, normal paraffin, and solvent naphtha, aromatic hydrocarbons such as benzene and toluene,
Examples include halogenated hydrocarbons such as dichloromethane and dichloroethane, esters such as ethyl acetate and butyl acetate, and fluorocarbon solvents (Freon 113, Freon 114 B2, Freon 21° Freon 1O, etc.). Examples of solid carriers include silicic acid, kaolin, activated carbon, bentonite, diatomaceous earth, talc, clay, calcium carbonate,
Examples include mineral powders such as ceramic powder, vegetable powders such as wood flour, soybean flour, wheat flour, and starch, and clathrate compounds such as cyclodextrin.
尚、塗膜形成剤としては、セルロース誘導体、ビニル系
樹脂、アルキッド系樹脂、ユリア系樹脂、エポキシ系樹
脂、ポリエステル系樹脂、ウレタン系樹脂、シリコン系
樹脂、アクリル系樹脂、塩化ゴム、ポリビニルアルコー
ル等を、又乳化剤、分散剤、展着剤としては、石けん類
、ポリオキシエチレン脂肪アルコールエーテル、ポリオ
キシエチレンアルキルアリルエーテル、ポリオキシエチ
レン脂肪酸エステル、脂肪酸グリセリド、ソルビタン脂
肪酸エステル、高級アルコールの硫酸エステル、アルキ
ルアリルスルホン酸塩等の界面活性剤を、さらに噴射剤
としては、液化石油ガス、ジメチルエーテル、フルオロ
カーボン等を例示できる。又、揮散調整剤として、トリ
シクロデカン、シクロドデカン、２．４．６−ドリイソ
ブロビルー１．３．５−トリオキサン、トリメチレンノ
ルボルネン等の昇華性担体やバラジクロロベンゼン、ナ
フタリンπ樟脳等の昇華性防虫剤を用い、前記ダニ防除
組成物を昇華性固剤とすることもできるし、エムペンス
リン、ＤＤＶＰ等の揮散性防虫剤を組み合せ、揮散性ダ
ニ防除剤として使用することもできる。In addition, examples of coating film forming agents include cellulose derivatives, vinyl resins, alkyd resins, urea resins, epoxy resins, polyester resins, urethane resins, silicone resins, acrylic resins, chlorinated rubber, polyvinyl alcohol, etc. Also, as emulsifiers, dispersants, and spreading agents, soaps, polyoxyethylene fatty alcohol ethers, polyoxyethylene alkyl allyl ethers, polyoxyethylene fatty acid esters, fatty acid glycerides, sorbitan fatty acid esters, sulfuric esters of higher alcohols, Examples of surfactants such as alkylaryl sulfonates and propellants include liquefied petroleum gas, dimethyl ether, and fluorocarbons. In addition, as a volatilization control agent, sublimable carriers such as tricyclodecane, cyclododecane, 2.4.6-dolyisobrobyl-1.3.5-trioxane, trimethylene norbornene, and sublimation of baradichlorobenzene, naphthalene π camphor, etc. The mite control composition can be made into a sublimable solid agent using a sex insect repellent, or it can be used as a volatile mite control agent in combination with a volatile insect repellent such as empensurin or DDVP.
さら番ζ本発明の殺ダニ剤は、各種の防虫剤、協力剤、
害虫忌避剤、ネズミ忌避剤、酸化防止剤、分解防止剤、
殺菌剤、防黴剤、香料、着色料等を配合することもでき
る。配合可能な防虫剤としては、３−アリル−２−メチ
ルシクロペンター２−エン−４−オン−１−イル ｄｉ
−シス／トランスークリサンテマート、３−アリル−２
−メチルシクロペンタ−２−エン−４−オン−１−イル
ｄ−シス／トランス−クリサンナマー）、ｄ−３−ア
リル−２−メチルシクロペンタ−２−エン−４−オンー
１−イル ｄ−トランスークリサンテマート、３−アリ
ル−２−メチルシクロペンタ−２−エン−４−オンー１
−イル ｄ−トランスークリサンテマート、Ｎ−（３・
４・５・６−チトラヒドロフタリミド）−メチル ｄｌ
−シス／トランスークリサンテマート、５−ベンジル−
３−フリルメチル ｄ−シス／トランスークリサンテマ
ート、 ５− （２−プロパギル）−３−フリルメチル
クリサンテマート、３−フェノキシベンジル ２・２−
ジメチル−３−（２’・２′−ジクロロ）ビニルシクロ
プロパンカルボキシレート、３−フェノキシベンジル
ｄ−シス／トランスークリサンテマート、α−シアノフ
ェノキシペンジル イソプロピル−４−クロロフェニル
アセテート、ｄ−３−アリル−２−メチルシクロペンタ
−２−エン−４−オン−１−イル ｄ−）ランスークリ
サンテマート、（Ｓ）−α−シアノ−３−フェノキシベ
ンジル（ＩＲ拳シス）−３−（２−２−ジクロロビニル
）−２・２−ジメチルシクロプロパンカルボキシレート
、（Ｒ，Ｓ）−α−シアノ−３−フェノキシベンジル
（ＩＲ−１ｓ）−シス／トランス−３−（２・２−ジク
ロロビニル）−２・２−ジメチルシクロプロパンカルボ
キシレート、α−シアノ−３−フェノキシベンジル ｄ
−シス／トランスークリサンテマート、１−エチニル−
２−メチル−２−ペンテニル シス／トランスークリサ
ンテマート、１−エチニル−２−メチル−２−ペンテニ
ル ２懐２−ジメチル−３−（２−メチル−１−プロペ
ニル）シクロプロパン−１−カルボキシレート、ｌ−エ
チニル−２−メチル−２−ペンテニル２・２・３・３−
テトラメチルシクロプロパンカルボキシレート、ｌ−エ
チニル−２−メチル−２−ペンテニル ２・２−ジメチ
ル−３−（２・２−ジクロロビニル）シクロプロパン−
１−カルボキシレート、０・０−ジメチル 〇−（２・
２−ジクロロ）ビニル本スフエート、〇−インプａボキ
シフェニルメテルカーバメート、０・Ｏ−ジメチル ０
−（３−メチル−４−二トロフェニル）チオノフォスフ
ェート、０・〇−ジエチル ０−２−イソプロピル−４
−メチル−ピリミジル−（６）−チオフォスフェート、
０・０−ジメチル ５−（ｉ・２−ジカルボエトキシエ
チル）−ジチオフォスフェート、ペンリルヘンゾエート
等を又、協力剤としては、６−（プロピルビペロニル）
−ブチルカルビチルエーテル、Ｎ−（２−エチルヘキシ
ル）−１−イソプロピル−４−メチルビシクロ（２，２
，２）オクト−５−エン−２，３−ジカルボキシイミド
、イソボルニルチオシアノアセテート、オクタクロロジ
プロピルエーテル等を、さらに殺菌剤、防黴剤としては
Ｎ−（フルオロジクロロメチルチオ）−フタルイミド、
Ｎ、Ｎ−ジメチル−）スルファミド、２，４．４’ −
トリクロロ−２′−ヒドロキシジフェニルエーテル、０
−フェニルフェノール、Ｐ−クロロ−ｍ−キシレノール
、４−クロロフェニル−３′−ヨードプロパルギルホル
マール等が例示できる。Saraban ζ The acaricide of the present invention can be used for various insect repellents, synergists,
Pest repellent, rat repellent, antioxidant, decomposition inhibitor,
Bactericidal agents, antifungal agents, fragrances, colorants, etc. can also be added. As an insect repellent that can be blended, 3-allyl-2-methylcyclopent-2-en-4-one-1-yl di
-cis/trans-chrysanthemate, 3-allyl-2
-Methylcyclopent-2-en-4-on-1-yl d-cis/trans-chrysannamer), d-3-allyl-2-methylcyclopent-2-en-4-on-1-yl d-tran Sucrysanthemate, 3-allyl-2-methylcyclopent-2-en-4-one-1
-yl d-transucrysanthemate, N-(3.
4,5,6-titrahydrophthalimido)-methyl dl
-cis/trans-chrysanthemate, 5-benzyl-
3-Furylmethyl d-cis/trans-chrysanthemate, 5-(2-propargyl)-3-furylmethylchrysanthemate, 3-phenoxybenzyl 2,2-
Dimethyl-3-(2',2'-dichloro)vinylcyclopropanecarboxylate, 3-phenoxybenzyl
d-cis/trans-chrysanthemate, α-cyanophenoxypenzyl isopropyl-4-chlorophenylacetate, d-3-allyl-2-methylcyclopent-2-en-4-one-1-yl d-) Ran Sucrysanthemate, (S)-α-cyano-3-phenoxybenzyl (IR-cis)-3-(2-2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate, (R,S)- α-cyano-3-phenoxybenzyl
(IR-1s)-cis/trans-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate, α-cyano-3-phenoxybenzyl d
-cis/trans-chrysanthemate, 1-ethynyl-
2-Methyl-2-pentenyl cis/trans-chrysanthemate, 1-ethynyl-2-methyl-2-pentenyl 2-dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate , l-ethynyl-2-methyl-2-pentenyl 2,2,3,3-
Tetramethylcyclopropanecarboxylate, l-ethynyl-2-methyl-2-pentenyl 2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropane-
1-carboxylate, 0.0-dimethyl 〇-(2.
2-dichloro)vinyl sulfate, 〇-impa boxyphenyl methyl carbamate, 0.O-dimethyl 0
-(3-methyl-4-nitrophenyl)thionophosphate, 0.0-diethyl 0-2-isopropyl-4
-methyl-pyrimidyl-(6)-thiophosphate,
0,0-dimethyl 5-(i,2-dicarboethoxyethyl)-dithiophosphate, penlylhenzoate, etc., and as a synergist, 6-(propylbiperonyl)
-butyl carbityl ether, N-(2-ethylhexyl)-1-isopropyl-4-methylbicyclo(2,2
, 2) Oct-5-ene-2,3-dicarboximide, isobornylthiocyanoacetate, octachlorodipropyl ether, etc., and N-(fluorodichloromethylthio)-phthalimide as a fungicide and fungicide. ,
N,N-dimethyl-)sulfamide, 2,4.4'-
Trichloro-2'-hydroxydiphenyl ether, 0
Examples include -phenylphenol, P-chloro-m-xylenol, and 4-chlorophenyl-3'-iodopropargyl formal.
本発明の殺ダニ剤中の有効成分量は、その剤型、適用方
法、及び適用場所等蕃と応じて適宜に決定すればよいが
、水溶液剤、′水和剤、乳剤や塗布剤、粉剤、粒剤等の
形態で用いろ場合は、有効成分を０．１〜３５重量％、
噴霧剤、燻煙剤、油剤やエアゾール剤の形態で用いる場
合は、有効成分を０．１〜ｌＯ重量％とするのが好まし
く、その適用量は、処理すべき面積１ｍ当りに有効成分
を約１（１９以上、適用空間１ｍ当りに有効成分を約１
岬以上存在させるのが望ましい。The amount of active ingredient in the acaricide of the present invention may be appropriately determined depending on the dosage form, application method, application location, etc.; When used in the form of granules, etc., the active ingredient is 0.1 to 35% by weight,
When used in the form of a spray, smoke, oil, or aerosol, the active ingredient is preferably 0.1 to 10% by weight, and the amount of application is approximately 0.1 to 10% by weight of the active ingredient per 1 m of area to be treated. 1 (more than 19, approximately 1 active ingredient per 1 m of application space)
It is desirable to have a cape or more.
本発明はまた、上記殺ダニ剤を基材に保持させてなるダ
ニ防除材をも提供するものである。該ダニ防除材は、そ
の基材の特性を利用してダニ防除性を有するフィルム、
シート、クツシラン、寝具類用充填材、建築・構築材料
等として用いられる。ここで基材としては例えばポリエ
チレン、ポリプロピレン、ナイロン、ポリ塩化ビニル、
ポリ塩化ビニリデン、ポリエステル等の合成樹脂シート
、動植物質又は無機質繊維体シート（紙、布、不織布、
皮革等）、これら合成樹脂と無機質繊維又は粉体との混
合シート又は混紡布、上記合成樹脂と動植物繊維との混
紡布又は不織布、アルミニウム、ステンレス、亜鉛等の
金属の箔又はフィルム及び上記各種シートの積層シート
を例示できる。又、クツション、寝具類用充填材として
は天然綿（綿、真綿等）、合成繊維綿（ポリエステル綿
、ナイロン綿、アクリル綿等）羽毛その他の動物毛、ソ
バ殻、籾殻、穀類ワラ、発泡プラスチック（発泡ポリエ
チレン、発泡ウレタン等）等を例示できろ。The present invention also provides a tick-controlling material in which the above-mentioned acaricide is retained in a base material. The mite-controlling material is a film that has mite-controlling properties by utilizing the characteristics of the base material.
It is used as a filler for sheets, bedding, building materials, etc. Examples of base materials here include polyethylene, polypropylene, nylon, polyvinyl chloride,
Synthetic resin sheets such as polyvinylidene chloride and polyester, animal and plant material or inorganic fiber sheets (paper, cloth, non-woven fabric,
leather, etc.), mixed sheets or blended fabrics of these synthetic resins and inorganic fibers or powders, blended fabrics or nonwoven fabrics of the above synthetic resins and animal and plant fibers, foils or films of metals such as aluminum, stainless steel, and zinc, and the various sheets mentioned above. An example is a laminated sheet. In addition, fillers for cushions and bedding include natural cotton (cotton, cotton cotton, etc.), synthetic fiber cotton (polyester cotton, nylon cotton, acrylic cotton, etc.), feathers and other animal hair, buckwheat husks, rice husks, cereal straw, and foamed plastics. (Polyethylene foam, urethane foam, etc.) Can you give examples?
さらに上記基材としては建築・構築材料とする天然木材
例えばキリ、ペンシルシダ、クス等やプラスチック例え
は塩化ビニル樹脂、塩素化ポリエチレン、ポリエチレン
、ポリプロピレン等の成型物をも有効ｌこ利用できる。Furthermore, as the base material, natural wood used as building and construction materials, such as awn, pencil fern, oak, etc., and molded plastics, such as vinyl chloride resin, chlorinated polyethylene, polyethylene, polypropylene, etc., can also be effectively used.
これら基材への本発明のダニ防除剤の保持手段は、特に
制限はなく、例えば塗布、含浸、滴下、劃り混練等によ
り行い得る。保持量も特に制限はなく適宜に決定できる
が、通常上記基材への含浸ｌこよる場合は、飽和含浸１
迄の量とするのが好ましい。The means for retaining the mite control agent of the present invention on these substrates is not particularly limited, and may be carried out, for example, by coating, impregnating, dropping, kneading, etc. The retention amount is not particularly limited and can be determined as appropriate; however, if the above-mentioned base material is impregnated with 1.
It is preferable to set the amount up to.
本発明のダニ防除材の好ましい一実施形態としては、ダ
ニ防除カーペットを例示できろ。該ダニ防除カーペット
は、例えばパイル、第一基布、バッキング剤及び第二基
布より成る通常のカーペットを作成後、必要に応じて塗
膜形成剤を配合した液剤形態を有する本発明の殺ダニ剤
を噴霧塗布するか、上記カーペットの作成に先立ち、パ
イル、第−基布及び第二基布のいずれか少なくとも１種
に本発明の殺ダニ剤を処理しこれらを用いてカーペット
を作成することにより得られろ、上記の如くして作成さ
れろダニ防除カーペットは、カーペット面積１扉当りに
有効成分を約０．１〜１０ｇ保持させろことが望ましい
。A preferred embodiment of the tick-control material of the present invention is a tick-control carpet. The mite-killing carpet is prepared by, for example, preparing a normal carpet consisting of a pile, a first base fabric, a backing agent, and a second base fabric, and then applying the mite-killing carpet of the present invention in the form of a liquid containing a coating film forming agent as needed. Either by spraying the acaricide, or by treating at least one of the pile, the first base fabric, and the second base fabric with the acaricide of the present invention prior to creating the carpet, and using these to create a carpet. It is desirable that the mite-repellent carpet obtained by or prepared as described above retains about 0.1 to 10 g of the active ingredient per carpet area.
又、他の実施形態としてはダニ防除布団及び枕を例示で
きる。該ダニ防除布団及び枕は、天然綿、合成繊維綿、
羽毛その他の動物毛、ソバ殻、籾殻、穀類ワラ、発泡プ
ラスチック等の充填材に、本発明の殺ダニ剤を噴霧塗布
することにより得られる。上記の如くして作成されるダ
ニ防除布団及び枕は充填材重量１ ｋｑに対して、約０
゜１〜ｌｏｔの有効成分を保持させればよい。Moreover, as other embodiments, a tick-proof futon and a pillow can be exemplified. The dust mite control futon and pillow are made of natural cotton, synthetic fiber cotton,
It can be obtained by spraying the acaricide of the present invention onto fillers such as feathers and other animal hair, buckwheat husks, rice husks, cereal straw, and foamed plastics. The dust mite-repellent futon and pillow produced as described above contain about 0
It is sufficient to retain 1 to 1 lot of the active ingredient.
本発明の殺ダニ剤及びダニ防除材は、その有効成分とし
て前記一般式で示される１ジメ÷ルアルた効果を発揮す
る。The miticide and mite control material of the present invention exhibit the same effect as the 1 dimer divided by the above general formula as an active ingredient.
以下、本発明を実施例を挙げてさらに詳しく説明する。 Hereinafter, the present invention will be explained in more detail with reference to Examples.
実施例Ｌ コナヒヨウヒダニに対する効力不織布（ポリ
プロピレン製、厚み２３０μ）を５×５ＣＭの大きさに
切断して所定の濃度となるよう供試化合物のアセトン溶
液を含浸させろ。Example L Efficacy against Dermatophagoides sinensis A nonwoven fabric (made of polypropylene, thickness 230 μm) was cut into a size of 5×5 CM and impregnated with an acetone solution of the test compound to a predetermined concentration.
溶媒除去後この含浸布を約３００頭の供試ダニとともに
ポリエチレン袋（６×６ｃ！ｇ）に入れ四方を密着させ
る。４８時間後に実体顕微鏡下で主孔の判定をした。結
果は下式のアボット補正による死出率（へ）で求め表１
に示した。After removing the solvent, this impregnated cloth and about 300 test mites were placed in a polyethylene bag (6 x 6 c!g) and tightly sealed on all sides. After 48 hours, the main pores were determined under a stereomicroscope. The results are calculated using the death rate (to) using the Abbott correction using the formula below.Table 1
It was shown to.
補正死出率（％）＝エニー’Ｘ’Ｈ１゜Ｘ；無処理区の
生存虫の百分率
ｙ；処理区の 〃
表１
本発明の殺ダニ剤はレスメトリンよりも高い効果を示し
た。Corrected mortality rate (%) = Any 'X'H1°X; Percentage of surviving insects y in untreated area;
実施例２
カーペットの防虫化を目的として下記表２の仕様ＮＩＩ
Ａ〜■でカーペット形態の本発明のダニ防除材を作製し
た。Example 2 Specification NII shown in Table 2 below for the purpose of making carpet insect repellent
The mite control material of the present invention in the form of a carpet was prepared in A to ■.
表２
上記で得られたダニ防除カーペットサンプル庵Ａ〜Ｉに
つき、以下の試験を行った。Table 2 The following tests were conducted on the mite control carpet samples A to I obtained above.
〈試験法〉
カーペットサンプルＮｈＡ〜■および薬剤無処理カーぺ
、ト（各々２０Ｘ２０３＞上の中央部に、コナヒ冒つヒ
ダニ約１万頭を含むダニ培地を置き、これをコンテナ（
４１Ｘ３１Ｘ２２ＣＭ）底部に入れた後、２５℃、６４
％ＲＨの条件下で２日間保存後、吸引筒接続部に２００
ｒｎｅｓｈ ナイロンゴウス２枚を挟んだ掃除機で
カーペット表面又は裏面のダニを吸い取った。次１こ、
ナイロンゴウスを掃除機よりはずし、ダーリング液１０
０ ｍｌを入れた３ ０ Ｏｙｔｌ容ビ容素−カー内ニ
を払い落とし、攪拌後遠沈管に移しｌ ０００ ｒｐｍ
で遠心分離して、上滑部を口紙を置いたブフナー漏斗番
こ移し、吸引口過する。この口紙上の生存ダニ類をカウ
ントし、結果は次式より死去率（％）として求めた。<Test method> Place a mite culture medium containing about 10,000 mites infecting Konahi in the center of the carpet samples NhA~■ and drug-free carpet (each 20 x 203)
41X31X22CM) After putting it in the bottom, 25℃, 64
After storing for 2 days under the condition of %RH, 200
Dust mites were removed from the surface or back of the carpet using a vacuum cleaner with two pieces of nylon gas sandwiched between them. Next one,
Remove the nylon goose from the vacuum cleaner and add Darling liquid 10
Shake off the contents of the 30 Oytl bi-liquid car containing 0 ml, stir, and transfer to a centrifuge tube at 1000 rpm.
Centrifuge the mixture, transfer the top slide to a Buchner funnel with a paper cap, and pass through the suction port. The living mites on this paper were counted, and the result was determined as a mortality rate (%) using the following formula.
補正死生率（％） ＝ −Ｘ １００
Ｘ；薬剤無処理カーペット区の生存ダニ数ｙ；ダニ防除
カーペット区の生存ダニ数上記の試験を３回繰返し、結
果をその平均値で表３に示す。Corrected mortality rate (%) = -X 100
上記表３の如く、各サンプルは十分なダニ防除性を示し
た。As shown in Table 3 above, each sample showed sufficient mite control properties.
実施例３
下記の供試化合物サンプルの指Ａ、Ｇ各々１゜ｆに、香
料を微量、エチルアルコール２０ｇｔ’を加え、さら番
こ蒸溜水を加えて全体を１５０ ｍｌとし、これと液化
石油ガス及びジメチルエーテル混合物（１：ｌ容積比）
の１５０−とをエアゾール用耐圧缶（内容４００ｍ？）
に充填して噴射装置に取付け、密封してエアゾール剤の
形態として本発明の殺ダニ剤を得た。Example 3 Add a small amount of fragrance and 20gt' of ethyl alcohol to 1°F each of finger A and G of the test compound sample below, add Sarabanko distilled water to make a total of 150 ml, and mix this with liquefied petroleum gas. and dimethyl ether mixture (1:l volume ratio)
150- and pressure-resistant aerosol cans (content 400m?)
The acaricide of the present invention was obtained in the form of an aerosol by filling it in a container, attaching it to an injection device, and sealing it.
このようにして得た各エアゾールを用い、実施例りと同
様にしてダニ防除効果を試験した。Using each aerosol thus obtained, the mite control effect was tested in the same manner as in the example.
く試験法〉
上質紙（３０Ｘ３０３）に各エアゾールを３秒間、でき
るだけ均一番こなるようにスプレーし、常温下１日保存
後、５×５１の大きさのシートに切り抜き、以下実施例
りの試験方法に準じてダニ防除効果を試験した。Test method> Spray each aerosol on high-quality paper (30 x 303) for 3 seconds in as uniform a pattern as possible, store it at room temperature for 1 day, then cut it into a 5 x 51 sheet and perform the test as described in the example below. The mite control effect was tested according to the method.
上記の試験を３回繰返し、結果をその平均値で表４に示
す。The above test was repeated three times, and the results are shown in Table 4 as the average value.
表４
上記表４の如く、各サンプルは十分なダニ防除性を示し
た。Table 4 As shown in Table 4 above, each sample showed sufficient mite control properties.
実施例（
下記表５の供試化合物混入サンプルのＰｉＡ、Ｇを布団
綿に供試化合物が１１７に９綿となるように噴霧後乾燥
し、本発明のダニ防除材を得た。Example (PiA and G of the test compound-containing samples shown in Table 5 below were sprayed on futon cotton so that the test compound was 117 to 9 cotton, and then dried to obtain the mite control material of the present invention.
上記で得られた防ダニ加工布団綿サンプル座Ａ〜Ｇにつ
いて以下の試験を行なった。The following tests were conducted on the mite-proofed futon cotton samples A to G obtained above.
く試験法〉
布団綿サンプルｈＡ〜Ｇまでの各々１ｆをサンプル管（
３０ｇ／）にとり、これに約５００頭のコナヒヨウヒダ
ニを入れ蓋をして２５℃下に設置する。４８時間後にサ
ンプル管より綿を取り出し熱追い出し法により生ダニを
回収し次式により防虫率（％）を求めた。Test method> Place 1f of each of the futon cotton samples hA to G in sample tubes (
30g/), put about 500 Dermatophagoids mites in it, cover it with a lid, and set it at 25°C. After 48 hours, the cotton was taken out from the sample tube, live mites were collected by the heat expulsion method, and the insect control rate (%) was determined using the following formula.
防虫率Ｃ％＞ ＝＝ ｘ−ニエ×１００Ｘ；無処理区の
回収ダニの百分率
ｙ；処理区の回収ダニの百分率
その結果、いずれのサンプルもほぼ１００％の防虫率を
得ることができ、十分なダニ防除性を示した。Insect control rate C%> == x-nie x 100 It showed excellent mite control properties.
実施例５゜
実施例３で用いた本発明の供試化合物を、それぞれ酸化
ケイ素の同重量と充分攪拌混合授粉状化して、粉末形態
の本発明の殺ダニ剤を得た。Example 5 The test compounds of the present invention used in Example 3 were mixed and pollinated with the same weight of silicon oxide with sufficient stirring to obtain the acaricide of the present invention in powder form.
このようにして得た粉末剤を下記試験法により、ダニ防
除効果を試験した。The dust mite control effect of the thus obtained powder was tested using the following test method.
く試験法〉
約２ ｃｓ長番と切ったワラを加熱殺虫後、その５ｔを
１ＯＯ−三角フラスコに入れ、次に各粉末剤００５ｆを
投入し混合して、２５℃、８５〜９０％ＲＨの条件下で
ｌＥ＋保存する。この三角フラスコに約４００頭のケナ
ガコナダニを投入し、同条件下で２日保存後、熱追い出
し法により生存ダニを追い出し、その数をカウントし、
死生率を実施例２の試験法に準じて算出した。Test method> After killing insects by heating approximately 2 cs long and cut straw, put 5 tons of it into a 1OO Erlenmeyer flask, then add each powder 005f, mix, and heat at 25°C and 85-90% RH. Store under lE+ conditions. Approximately 400 woolly mites were placed in this Erlenmeyer flask, and after storing them for 2 days under the same conditions, the surviving mites were expelled using the heat expulsion method, and their number was counted.
The mortality rate was calculated according to the test method of Example 2.
そ°の結果、いずれの粉末剤モはぼ１００％の死生率を
得ろことができ、十分なダニ防除性を示した。As a result, all of the powder formulations were able to obtain a mortality rate of approximately 100%, indicating sufficient mite control properties.
実施例６
掃除機用紙パックに下記表６に示した供試化合物Ａ、Ｉ
のアセトン溶液を含浸後乾燥し本発明のダニ防除材を得
た。Example 6 Test compounds A and I shown in Table 6 below were placed in a vacuum cleaner paper pack.
The material was impregnated with an acetone solution and dried to obtain the mite control material of the present invention.
表６
上記で得られたダニ防除用紙バックサンプル庵Ａ〜■に
ついて以下の試験を行なった。Table 6 The following tests were conducted on the mite control paper bag samples A to Iori obtained above.
（試験法〉
紙パツクサンプルＮＩＩＡ〜Ｉおよび無処理の紙パツク
を市販の電気掃除機（吸込仕事率１６ ＧＷ）に装着し
た後、室内塵の代替として綿状ポリエステル短繊維２０
Ｆをよくほぐしながら吸引させた後、紙パツクを取り出
し、３欝ｌの水をスプレーした。さらにフナと、ウヒダ
ニ約１０００頭を含むダニ飼育用培地約２００岬を紙パ
ツク中に入れた後、再び掃除機内に該紙パツクを装着し
２５℃７５％ＲＨ下に２週間設置した。その後、紙パツ
ク中のダニを飽和食塩水浮遊法により回収し生死を判定
して死出率（％）を求めた。(Test method) After installing paper pack samples NIIA-I and untreated paper packs into a commercially available vacuum cleaner (suction power 16 GW), cotton-like polyester staple fibers 20% were used as a substitute for indoor dust.
After loosening the F well and suctioning it, the paper pack was taken out and 3 liters of water was sprayed on it. Furthermore, about 200 capes of a mite breeding medium containing crucian carp and about 1,000 carp mites were placed in the paper pack, and the paper pack was placed inside the vacuum cleaner again and placed at 25° C. and 75% RH for two weeks. Thereafter, the mites in the paper pack were collected by the saturated saline suspension method, and the mortality rate (%) was determined by determining whether they were alive or dead.
上記の試験、を３回繰返し、結果をその平均型で表７に
示す。The above test was repeated three times, and the average results are shown in Table 7.
上記表７の如く各サンプルは十分なダニ防除性を示した
。As shown in Table 7 above, each sample showed sufficient mite control properties.
本発明の殺ダニ剤は低毒性で人体に対して安全であるの
で、畳、カーペット等の敷物類、ソファ−、タンス等の
家具類、ふとん、ベツド等の寝具類、ぬいぐるみ等の玩
具類等人が頼繁に接触するようなところでも安心して使
用することができ、その対象となるダニ類は、いずれの
種類でも対象となり得るが、特にコナヒ曹つヒダ二やヤ
ケヒ曹つヒダニ等のと、ウヒダニ類に有効である等の効
果を有する。The acaricide of the present invention has low toxicity and is safe for the human body, so it can be used on rugs such as tatami mats and carpets, furniture such as sofas and chests of drawers, bedding such as futons and beds, and toys such as stuffed animals. It can be used safely even in places where people come into close contact with it, and it can target any type of mites, but it is especially suitable for mites such as Konahi mites and Yakehi mites. , it has effects such as being effective against spiny mites.
（以上） 特許出願人 アース製薬株式会社(that's all) Patent applicant Earth Pharmaceutical Co., Ltd.
Claims (2)
含有することを特徴とする殺ダニ剤。(1) A miticide characterized by containing dimethylalkyl betaine as an active ingredient represented by the general formula ▲ Numerical formula, chemical formula, table, etc. ▼ (in the formula, n represents 8 to 24).
含有する殺ダニ剤を基材に保持させたことを特徴とする
ダニ防除材。(2) A miticide containing dimethylalkyl betaine as an active ingredient represented by the general formula ▲ Numerical formula, chemical formula, table, etc. ▼ (in the formula, n represents 8 to 24) is retained on the base material. A tick control material featuring:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25562687A JP2572994B2 (en) | 1987-10-12 | 1987-10-12 | Acaricide containing dimethylalkyl betaine as an active ingredient |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25562687A JP2572994B2 (en) | 1987-10-12 | 1987-10-12 | Acaricide containing dimethylalkyl betaine as an active ingredient |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01100102A true JPH01100102A (en) | 1989-04-18 |
| JP2572994B2 JP2572994B2 (en) | 1997-01-16 |
Family
ID=17281364
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP25562687A Expired - Fee Related JP2572994B2 (en) | 1987-10-12 | 1987-10-12 | Acaricide containing dimethylalkyl betaine as an active ingredient |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2572994B2 (en) |
-
1987
- 1987-10-12 JP JP25562687A patent/JP2572994B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2572994B2 (en) | 1997-01-16 |
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