JPS6233106A - Mite controlling agent - Google Patents
Mite controlling agentInfo
- Publication number
- JPS6233106A JPS6233106A JP17386885A JP17386885A JPS6233106A JP S6233106 A JPS6233106 A JP S6233106A JP 17386885 A JP17386885 A JP 17386885A JP 17386885 A JP17386885 A JP 17386885A JP S6233106 A JPS6233106 A JP S6233106A
- Authority
- JP
- Japan
- Prior art keywords
- mite
- composition
- mites
- mite controlling
- controlling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 claims abstract description 38
- 239000000463 material Substances 0.000 claims abstract description 24
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims abstract description 12
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 claims abstract description 12
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229960000969 phenyl salicylate Drugs 0.000 claims abstract description 6
- 229960000956 coumarin Drugs 0.000 claims abstract description 5
- 235000001671 coumarin Nutrition 0.000 claims abstract description 5
- 239000000642 acaricide Substances 0.000 claims description 17
- 239000004480 active ingredient Substances 0.000 claims description 11
- XSAYZAUNJMRRIR-UHFFFAOYSA-N 2-acetylnaphthalene Chemical compound C1=CC=CC2=CC(C(=O)C)=CC=C21 XSAYZAUNJMRRIR-UHFFFAOYSA-N 0.000 claims description 5
- 241000238876 Acari Species 0.000 abstract description 32
- 239000003795 chemical substances by application Substances 0.000 abstract description 17
- 241001465754 Metazoa Species 0.000 abstract description 7
- 239000004745 nonwoven fabric Substances 0.000 abstract description 4
- 239000007921 spray Substances 0.000 abstract description 4
- 229920003002 synthetic resin Polymers 0.000 abstract description 4
- 239000000057 synthetic resin Substances 0.000 abstract description 4
- 239000003921 oil Substances 0.000 abstract description 3
- 235000013311 vegetables Nutrition 0.000 abstract description 3
- 229910052782 aluminium Inorganic materials 0.000 abstract description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004566 building material Substances 0.000 abstract description 2
- 239000000835 fiber Substances 0.000 abstract description 2
- 239000011888 foil Substances 0.000 abstract description 2
- 239000008187 granular material Substances 0.000 abstract description 2
- 150000002576 ketones Chemical class 0.000 abstract description 2
- 231100000053 low toxicity Toxicity 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract description 2
- 230000001276 controlling effect Effects 0.000 abstract 8
- 239000000470 constituent Substances 0.000 abstract 2
- 241000238713 Dermatophagoides farinae Species 0.000 abstract 1
- 241000261594 Tyrophagus longior Species 0.000 abstract 1
- 239000002671 adjuvant Substances 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 238000009472 formulation Methods 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- -1 propoxar and NAC Chemical compound 0.000 description 18
- 239000004744 fabric Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 10
- 239000000428 dust Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 239000005871 repellent Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 239000000077 insect repellent Substances 0.000 description 6
- 230000002940 repellent Effects 0.000 description 6
- 238000010998 test method Methods 0.000 description 6
- XLOPRKKSAJMMEW-SFYZADRCSA-M (R,R)-chrysanthemate Chemical compound CC(C)=C[C@@H]1[C@@H](C([O-])=O)C1(C)C XLOPRKKSAJMMEW-SFYZADRCSA-M 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- 239000000443 aerosol Substances 0.000 description 5
- 239000000123 paper Substances 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 235000013312 flour Nutrition 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 3
- 229940108410 resmethrin Drugs 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 239000004035 construction material Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- YMGUBTXCNDTFJI-UHFFFAOYSA-M cyclopropanecarboxylate Chemical compound [O-]C(=O)C1CC1 YMGUBTXCNDTFJI-UHFFFAOYSA-M 0.000 description 2
- YMGUBTXCNDTFJI-UHFFFAOYSA-N cyclopropanecarboxylic acid Chemical compound OC(=O)C1CC1 YMGUBTXCNDTFJI-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000012784 inorganic fiber Substances 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000003915 liquefied petroleum gas Substances 0.000 description 2
- GTCAXTIRRLKXRU-UHFFFAOYSA-N methyl carbamate Chemical compound COC(N)=O GTCAXTIRRLKXRU-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 239000002728 pyrethroid Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 description 1
- UTVKUFYOPJCDPE-UHFFFAOYSA-N 6-apt Chemical compound C1CCCC2=CC(CC(N)C)=CC=C21 UTVKUFYOPJCDPE-UHFFFAOYSA-N 0.000 description 1
- KYARBIJYVGJZLB-UHFFFAOYSA-N 7-amino-4-hydroxy-2-naphthalenesulfonic acid Chemical compound OC1=CC(S(O)(=O)=O)=CC2=CC(N)=CC=C21 KYARBIJYVGJZLB-UHFFFAOYSA-N 0.000 description 1
- FWEOQOXTVHGIFQ-UHFFFAOYSA-N 8-anilinonaphthalene-1-sulfonic acid Chemical compound C=12C(S(=O)(=O)O)=CC=CC2=CC=CC=1NC1=CC=CC=C1 FWEOQOXTVHGIFQ-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 241000345998 Calamus manan Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- 101710170963 Darlin Proteins 0.000 description 1
- 241000238710 Dermatophagoides Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- PNVJTZOFSHSLTO-UHFFFAOYSA-N Fenthion Chemical compound COP(=S)(OC)OC1=CC=C(SC)C(C)=C1 PNVJTZOFSHSLTO-UHFFFAOYSA-N 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- DDTBPAQBQHZRDW-UHFFFAOYSA-N cyclododecane Chemical compound C1CCCCCCCCCCC1 DDTBPAQBQHZRDW-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 description 1
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- USPVNSDVCUTNJN-UHFFFAOYSA-N ethenyl cyclopropanecarboxylate Chemical compound C=COC(=O)C1CC1 USPVNSDVCUTNJN-UHFFFAOYSA-N 0.000 description 1
- BNKAXGCRDYRABM-UHFFFAOYSA-N ethenyl dihydrogen phosphate Chemical compound OP(O)(=O)OC=C BNKAXGCRDYRABM-UHFFFAOYSA-N 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- NYNAFINLHQEHKU-UHFFFAOYSA-N methyl 1-(4-{[(2,4-diaminopteridin-6-yl)methyl]amino}benzoyl)piperidine-4-carboxylate Chemical compound C1CC(C(=O)OC)CCN1C(=O)C(C=C1)=CC=C1NCC1=CN=C(N=C(N)N=C2N)C2=N1 NYNAFINLHQEHKU-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- RPVDAUDBFGUPKL-UHFFFAOYSA-N propan-2-yl 2-(4-chlorophenyl)acetate Chemical compound CC(C)OC(=O)CC1=CC=C(Cl)C=C1 RPVDAUDBFGUPKL-UHFFFAOYSA-N 0.000 description 1
- 230000001007 puffing effect Effects 0.000 description 1
- 235000012950 rattan cane Nutrition 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 230000005068 transpiration Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は新規なダニ防除剤組成物及びダニ防除材に関す
る。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a novel mite control agent composition and a new mite control material.
一般家庭の室内塵中には必ずと言ってよい程ダニが生息
しているが、近年、住宅、生活様式の変化に伴いグーの
多発生が見られるようになった。Dust mites are almost always present in the indoor dust of ordinary households, but in recent years, as housing and lifestyles have changed, the occurrence of goo has increased.
従来よりこのような室内塵性のダニに対するダニ防除剤
としては、例えばフェニトロチオン、フヱンチオン、Ｄ
ＤＶＰ、ダイアジノン等のリン系化合物、プロポクサー
、ＮＡＣ等のカーバメイト系化合物、レスメトリンフォ
ルテ専のピレスロイド系の化合物が知られている。Conventional mite control agents against indoor dust mites include, for example, fenitrothion, fenthion, and D.
Phosphorus compounds such as DVP and diazinon, carbamate compounds such as propoxar and NAC, and pyrethroid compounds exclusive to resmethrin forte are known.
これら公知のダニ防除剤は、畳、カーペット、防虫紙に
保持させたり、そのまま散布、噴霧等して用いられてい
るが、次のような短所を有している。すなわち、リン系
のダニ防除剤は、毒性が高く、悪臭を有し、と曹つヒダ
ニ類に対する効果が低いという短所を有し、カーバメイ
ト系のダニ防除剤は、毒性が高く、ヒ胃つヒダニ頻に対
する効果が低いという短所を有し、ピレスロイド系のダ
ニ防除剤は、高価であり、ケナガコナダニに対する効果
が低いという短所を有しており、又これらのダニ防除剤
を組み合わせて使用する場合等に使いづらいというよう
な種々の間懸点を含んでいる。These known mite control agents are used by keeping them on tatami mats, carpets, and insect repellent paper, or by scattering or spraying them as they are, but they have the following disadvantages. In other words, phosphorus-based mite repellents are highly toxic, have a bad odor, and are less effective against stomach mites, while carbamate-based mite repellents are highly toxic and have a bad odor, and are less effective against stomach mites. Pyrethroid-based mite control agents are expensive and have low effectiveness against woolly mites, and when these mite control agents are used in combination, It contains various issues such as difficulty in use.
Ｃ問題点を解決するための手段〕
そこで本発明者は、毒性が低く、幅広いダニ防除領域を
持つ、安価なダニ防除剤を提供するため種々研究を重ね
た結果、サリチル酸フェニル（以下ＰＳという）、安息
香酸フェニル（以下ＰＢという）％ジフェニルアミン（
以下ＤＡといつ）。Means for Solving Problem C] Therefore, the present inventor has conducted various studies to provide an inexpensive tick control agent that has low toxicity and has a wide range of tick control areas, and has developed phenyl salicylate (hereinafter referred to as PS). , phenyl benzoate (hereinafter referred to as PB)% diphenylamine (
(hereinafter referred to as DA).
メチルβ−ナフチルケトン（以下ＭＮＫという）、クマ
リン（以下ＣＭという）、が上記要件を満たすことを見
い出した。すなわち本発明はサリチル酸フェニル、安息
香酸フェ二〜、ジフェニルアミン、メチルβ−ナフチル
ケトン、クマリンから選択される少なくとも一種を有効
成分として含有することを特徴とするダニ防除剤組成物
、及び該組成物を基材に保持させたことを特徴とするダ
ニ防除材に係る。It has been found that methyl β-naphthyl ketone (hereinafter referred to as MNK) and coumarin (hereinafter referred to as CM) satisfy the above requirements. That is, the present invention provides a mite control agent composition containing as an active ingredient at least one selected from phenyl salicylate, phenyl benzoate, diphenylamine, methyl β-naphthyl ketone, and coumarin, and the composition. The present invention relates to a mite-controlling material that is held on a base material.
本発明のダニ防除剤組成物は、その有効成分としてサリ
チ／Ｉ／酸フェニル、安息香酸フェニル、ジフェニルア
ミン、メチルβ−ナフチルケトン、クマリンの少なくと
も一種を含有することにより、極めて優れたダニ防除効
果を示す。その対象となるダニ類は、いずれの種類でも
対象をとなり得るが、特にコナヒ替つヒダニやヤケヒー
ラダニ等のし曹つヒダエ類、ケナガコナダニやムギコナ
ダニ等のコナダニ類、チリニクダニやイエニクダニ等の
ニクダニ類、ホコリダニ類、クワガタイメダニやフトツ
メダニ等のツメダニ類、イエダニやトリサシダニ等の動
物寄生性ダニ類が挙げられる。The mite control agent composition of the present invention has an extremely excellent mite control effect by containing at least one of salicium/I/phenyl acid, phenyl benzoate, diphenylamine, methyl β-naphthyl ketone, and coumarin as its active ingredient. show. The target mites can be any type of mites, but in particular, the mites include the mites, such as the mites, the mites, the mites, the mites, the mites, the mites, the mites, and the mites. mites, mites such as the stag mite and the foot mite, and animal parasitic mites such as the house dust mite and the common dust mite.
本発明のダニ防除剤組成物は、上記有効成分を含有する
組成物をそのまま用いることもできるが、通常は液体担
体及び固体担体にその有効成分を含有する組成物を保持
させ、必要に応じ塗膜形成剤。For the mite control composition of the present invention, the composition containing the above-mentioned active ingredient can be used as it is, but usually the composition containing the active ingredient is held in a liquid carrier or a solid carrier, and then applied as necessary. Film forming agent.
乳化剤、分散剤、展着剤、湿潤剤、安定剤、噴射剤、揮
散調整剤等を添加して、油剤、乳剤、水利剤、噴霧剤、
エアゾール剤、燻煙剤、ｆ！！布剤、粉剤、粒剤等の形
態で使用することができる。By adding emulsifiers, dispersants, spreading agents, wetting agents, stabilizers, propellants, volatilization regulators, etc., oil agents, emulsions, irrigation agents, sprays, etc.
Aerosols, smoke agents, f! ! It can be used in the form of cloth, powder, granules, etc.
前記液体担体としては、水や例えばメチルアルコ−Ａ／
、エチルアルコール、イソプロピルアルコール等のアル
コール類、アセトン、メチルエチルケトン、シクロヘキ
サノン等のケトン類、テトラヒドロフラン、ジオキサン
、ジメチＶエーテル等の３−−ｆｋ類、ヘキサン、ケロ
シン、ノルマルバフフィン、ソルベントナフサ等の脂肪
族法化水素類、ベンゼン、トルエン等の芳香族炭化水素
類、ジクロロメタン、ジクロロエタン等のハロゲン化炭
化水素類、酢酸エチル、酢酸ブチル等のエステ化類等を
挙げることができる。固体担体としては、例えばケイ酸
、カオリン、活性炭、ベントナイト、ケイソウ土、タル
ク、クレー、次階カルシウム、゛陶磁器粉専の鉱物性粉
末、木粉、大豆粉、小麦粉、でん粉等の植物質粉末、シ
クロデキストリン等の包接化合物等を挙げることができ
る。The liquid carrier may be water or, for example, methyl alcohol-A/
, alcohols such as ethyl alcohol and isopropyl alcohol, ketones such as acetone, methyl ethyl ketone, and cyclohexanone, 3-fk compounds such as tetrahydrofuran, dioxane, and dimethyV ether, and aliphatics such as hexane, kerosene, normal buffine, and solvent naphtha. Examples include hydrocarbons, aromatic hydrocarbons such as benzene and toluene, halogenated hydrocarbons such as dichloromethane and dichloroethane, and esterified hydrocarbons such as ethyl acetate and butyl acetate. Solid carriers include, for example, silicic acid, kaolin, activated carbon, bentonite, diatomaceous earth, talc, clay, calcium, mineral powder specialized for ceramic powder, vegetable powder such as wood flour, soybean flour, wheat flour, starch, etc. Examples include clathrate compounds such as cyclodextrin.
尚、塗膜形成剤としては、セルロース誘導体、ビニル系
樹脂、アルキッド系樹脂、エリア糸ａ脂、エポキシ系樹
脂、ポリエステル爪樹脂、ウレタン系樹脂、シリコン系
樹脂、アクリル系樹脂、塩化ゴム、ポリビニルアＶコー
ル等を、又乳化剤、分散剤、展着剤としては１石けん類
、ポリオキシエチレン脂肪アルコールエーテル、ポリオ
キシエチレンアルキ〃アリＶエーテル、ポリオキシエチ
レン脂肪酸エステル、脂肪酸グリセリド、ソルビタンＪ
ｌｌ 肪ａエステル、高級アルコールの硫酸エステル、
アルキルアＩＪＡ／７−ルホン酸塩等の界面活性剤を、
さらに噴射剤としては、液化石油ガス、ジメチルエーテ
ｖ１フルオロカーボン等を例示できる。In addition, as coating film forming agents, cellulose derivatives, vinyl resins, alkyd resins, area thread a resin, epoxy resins, polyester nail resins, urethane resins, silicone resins, acrylic resins, chlorinated rubber, and polyvinyl resins are used. V-col, etc., and as emulsifiers, dispersants, and spreading agents, soaps, polyoxyethylene fatty alcohol ether, polyoxyethylene alkylene V ether, polyoxyethylene fatty acid ester, fatty acid glyceride, Sorbitan J
ll fatty a ester, higher alcohol sulfate ester,
A surfactant such as Alkylua IJA/7-sulfonate,
Furthermore, examples of the propellant include liquefied petroleum gas, dimethyl ether v1 fluorocarbon, and the like.
又、揮散調整剤として、トリシクロデカン、シクロドデ
カン、２．４６−ドリイソブロビルーＬ１５−トリオキ
サン、トリメチレンノルボルネン等の昇華性担体やパラ
ジクロロベンゼン、ナフタリン、樟脳等の昇華性防虫剤
を用い、前記ダニ防除組成物を昇華性固剤とすることも
できるし、エムペンスリン、ＤＤＶＰ等の揮散性防虫剤
を組み合せ、揮散性ダニ防除剤として使用することもで
きる。Further, as a volatilization regulator, a sublimable carrier such as tricyclodecane, cyclododecane, 2,46-dolyisobrobyl-L15-trioxane, trimethylene norbornene, or a sublimable insect repellent such as paradichlorobenzene, naphthalene, camphor, etc. is used, and the above-mentioned The mite control composition can be made into a sublimable solid agent, or it can be used in combination with a volatile insect repellent such as empensurin or DDVP as a volatile mite control agent.
さらに本発明のダニ防除剤組成物には、各種の防虫剤、
協力剤、害虫忌避剤、ネズミ忌避剤、酸化防止剤１分解
防止剤、殺菌剤、防黴剤、香料。Furthermore, the mite control agent composition of the present invention includes various insect repellents,
Synergist, pest repellent, rat repellent, antioxidant 1 decomposition inhibitor, bactericide, fungicide, fragrance.
着色料等を配合することもできる。配合可能な防虫剤と
しては、従来より害虫駆除に用いられる各種薬剤がいず
れも使用できる。代表ｒ１的薬剤としては、３−アリル
−２−メチルシクロベンター２−エン−４−オン−１−
イ／Ｉ／ｄｌ−シス／トランスークリサンテマート、３
−アリル−２−メチルシクロペンタ−２−エン−４−オ
ン−１−イルｄ−ｔｙス／）フンスークリサンテマート
、ｄ−３−アリｐｖ−２−メチルシクロベンター２−エ
ン−４−オン−１−イア１／ｄ−）フンスークリサンテ
マート、３−アリル−２−メチルシクロペンタ−２−工
ン−４−オン−１−イル ｄ−）フンスークリサンテマ
ート、Ｎ−（３・４・５・６−テトフヒドロフタリミド
）−メチＮ ｄ／−シス／トランスークリサンテマー
ト、５−ベンジル−３−フリＶメチル ｄ−シス／トラ
ンスークリサンテマート（以下ＡＡという）、５−（２
−プロバギＡ／）−３−フリ〜メチルクリサンテマート
、３−フェノキシベンジ／ｌ／２・２−ジメチル−３−
（２’・２′−シクロロンビニルシクロプロパンカルボ
キシレート、３−フェノキシベンジル ｄ−シス／トラ
ンスークリサンテマート、ａ−シアノフェノキシベンジ
Ｖ イソプロピル−４−クロロフェニルアセテート、ｄ
−３−アリル−２−メチルシクロペンタ−２−工ン−４
−オン−１−イル ｄ−）フンスークリサンテマー）、
（Ｓ）−α−シアノ−３−フェノキシベンジル（ＩＲ・
シス）−３−（２・２−ジクロロビニル）−２・２−’
）ｊ’Ｐルシクロプロパンカルボキシレート、（Ｒ，Ｓ
）−α−シアノ−３−フェノキシベンジＡ／（ＩＲＩＩ
ｓ）−シス／トランス−３−（２・２−ジクロロビニル
）−２１２−ジメチＶシクロプロパンカルボキシレート
、α−シアノ−３−フェノキシベンジル ｄ−シス／ト
ランスークリサンテマート、ｌ−エチニ／ｌ／−２−メ
チルー２−ペンテニル シス／トランスークリサンデマ
ート、ｌ−エチニル−２−メチ／Ｌ／−２−ペンテニル
２・２−ジメチｐｖ−３−（２−メチル−１−’プロ
ベニ／Ｌ／）シクロプロパン−１−カルボキシレート、
ｌ−エチニル−２−メチル−２−ペンチェｔｖ”ｌ・２
・３・３−テトヲメチＶシクロプロバンカＶポキシレー
ト、ｌ−エチ＝／Ｌ／−２−メチルー２−ペンテニル
２・２−ジメチル−ツー（２・２−ジクロロビ＝Ａ／）
シクロプロパン−１−カルボキシレート、Ｏｅ〇−ジメ
チｖｏ−（２・２−ジクロロ）ビニルホスフェート、０
−イソプロボキシフェニＭメチルカーバメート、０・Ｏ
−ジメチｔｖＯ−（３−メチ１％／ ’−４−二トロフ
ェニ／Ｌ／）チオノフォスフェート、０・０−ジエチｔ
ｖ ０−２−イソプロピシー４−メチル−ピリミジｖ
−（６）−チオフォスフェート（以下ＡＢという）％
０・０−ジメチル ５−（１−２−シカＶボエトキシ
エチ／Ｌ／）−ジチオフオスフェート、インポルニルチ
オシアネート（以下ＡＣという）等を例示できる。Coloring agents and the like can also be added. As the insect repellent that can be blended, any of the various chemicals conventionally used for exterminating pests can be used. Representative r1 drugs include 3-allyl-2-methylcyclobenter-2-en-4-one-1-
I/I/dl-cis/trans-chrysanthemate, 3
-allyl-2-methylcyclopent-2-en-4-one-1-yl d-tys/)funsucrysanthemate, d-3-allypv-2-methylcyclopent-2-en-4-one -1-ia 1/d-) Funsu chrysanthemate, 3-allyl-2-methylcyclopent-2-en-4-one-1-yl d-) Funsu chrysanthemate, N-(3.4・5,6-tetophhydrophthalimide)-methyN d/-cis/trans-chrysanthemate, 5-benzyl-3-furyVmethyl d-cis/trans-chrysanthemate (hereinafter referred to as AA), 5- (2
-Probagi A/)-3-furi-methylchrysanthemate, 3-phenoxybendi/l/2.2-dimethyl-3-
(2',2'-cyclolon vinyl cyclopropanecarboxylate, 3-phenoxybenzyl d-cis/trans-chrysanthemate, a-cyanophenoxybenzyl V isopropyl-4-chlorophenylacetate, d
-3-allyl-2-methylcyclopent-2-en-4
-on-1-yl d-)funsu chrysanthemer),
(S)-α-cyano-3-phenoxybenzyl (IR・
cis)-3-(2,2-dichlorovinyl)-2,2-'
)j'P cyclopropane carboxylate, (R,S
)-α-cyano-3-phenoxybendiA/(IRII
s)-cis/trans-3-(2,2-dichlorovinyl)-212-dimethyV cyclopropanecarboxylate, α-cyano-3-phenoxybenzyl d-cis/trans-chrysanthemate, l-ethini/l /-2-methyl-2-pentenyl cis/trans-chrysandemate, l-ethynyl-2-methy/L/-2-pentenyl 2,2-dimethypv-3-(2-methyl-1-'proveni/L /) cyclopropane-1-carboxylate,
l-ethynyl-2-methyl-2-penche tv”l・2
・3,3-tetromethane V cycloprobanca V poxylate, l-ethyl/L/-2-methyl-2-pentenyl
2,2-dimethyl-two (2,2-dichlorobi=A/)
Cyclopropane-1-carboxylate, Oe〇-dimethyvo-(2,2-dichloro)vinyl phosphate, 0
-IsoproboxyphenyM methyl carbamate, 0.0
-dimethytvO-(3-methy1%/'-4-nitropheny/L/)thionophosphate, 0.0-diethyt
v 0-2-isopropyl-4-methyl-pyrimidi v
-(6)-thiophosphate (hereinafter referred to as AB)%
Examples include 0.0-dimethyl 5-(1-2-cicaVboethoxyethyl/L/)-dithiophosphate and impolyl thiocyanate (hereinafter referred to as AC).
本発明のダニ防除剤組成物中の有効成分量は、その剤型
、適用方法、及び適用場所等に応じて適宜に決定すれは
よいが、水利剤や乳剤の形態で用いる場合は、有効成分
組成物を０１〜５０重量％、油剤やエアゾーシ剤の形態
で用いる場合は、有効成分組成物をＯ１〜３０！ｉｆ％
とするのが好ましく、その適用量は、処理すべき面積１
ｍ当りに有効成分組成物を約ｚＯη以上、適用空間１ｍ
当りに有効成分組成物を約２ダ以上存在させるのが望ま
しい。The amount of the active ingredient in the mite control agent composition of the present invention may be appropriately determined depending on its dosage form, application method, application location, etc., but when used in the form of an aquarium or emulsion, When using the composition in the form of an oil or aerosol, the active ingredient composition is O1 to 30% by weight. if%
It is preferable that the amount of application is 1
Approximately zOη or more of the active ingredient composition per meter, application space 1m
It is desirable to have about 2 or more active ingredient compositions present per serving.
本発明はまた、上記ダニ防除剤組成物を基材に保持させ
てなるダニ防除材をも提供するものである。まダニ防除
材は、その基材の特性を利用してダニ防除性を有するフ
ィルム、シート、建築・構築材料等として用いられる。The present invention also provides a mite-controlling material in which the above-mentioned mite-controlling agent composition is retained on a base material. Tite control materials are used as films, sheets, building and construction materials, etc. that have tick control properties by utilizing the characteristics of their base materials.
ここで基材としては例えばポリエチレン、ポリプロピレ
ン、ナイロン、ポリ塩化ビニル、ポリ塊化ビニリダン、
ポリエステル等の合成樹脂シート、動植物質又は無機質
繊維体シート（紙、布、不織布、皮革等）、これら合成
樹脂と無機質繊維又は粉体との混合シート又は混紡布、
上記合成樹脂と動植物繊維との混紡布又は不織布、アル
ミニウム、ステンレス、亜鉛等の金属の箔又はフィルム
及び上記各種シートの積層シートを例示できる。さらに
上記基材としては、建築・構築材料とする天然木材例え
ばキリ、ペンシルシダ、クス等やブツスチック例え＋ｆ
ｆｉ 化ビニルＩｌ脂、ｊｔ！素化ポリエチレン、ポ
リエチレン、ポリプロピレン等の成型物をも有効１こ利
用できる。これら基材への本発明のダニ防除＄ｔｍ成物
の保持手段は、特に制限はなく、例えば塗布、含浸％滴
下、混練等により行い得る。保持量も特に制限はなく適
宜に決定できるが、通常上記基材への含浸による場合は
、飽和含浸量適の量とするのが好ましい。Here, examples of the base material include polyethylene, polypropylene, nylon, polyvinyl chloride, poly agglomerated vinylidan,
Synthetic resin sheets such as polyester, animal/vegetable or inorganic fiber sheets (paper, cloth, non-woven fabric, leather, etc.), mixed sheets or blended fabrics of these synthetic resins and inorganic fibers or powder,
Examples include blended fabrics or nonwoven fabrics of the synthetic resins and animal and plant fibers, foils or films of metals such as aluminum, stainless steel, and zinc, and laminated sheets of the various sheets listed above. Furthermore, the above-mentioned base materials include natural wood used as architectural and construction materials, such as awl, pencil fern, oak, etc.
fi vinyl chloride l fat, jt! Molded products of hydrogenated polyethylene, polyethylene, polypropylene, etc. can also be effectively used. The means for holding the mite-controlling $tm composition of the present invention on these substrates is not particularly limited, and may be carried out, for example, by coating, dripping at an impregnating percentage, kneading, or the like. The retained amount is not particularly limited and can be determined as appropriate; however, in the case of impregnating the above-mentioned base material, it is preferable to set the amount to an appropriate amount for saturation impregnation.
本発明のダニ防除材の好ましい一実施起様としては、ダ
ニ防除カーペットを例示できる。該ダニ防除カーペット
は、例えばバイ／Ｍ％第一基布、パフキング剤及び第二
基布より成る通常のカーペットを作成後その表面及び（
又は）裏面に、液剤形態を有する本発明のダニ防除剤組
成物を噴ｌｉ籟布するか、上記カーペットの作成ｔこ先
立ち、バイ〃、第−基布及び第二基布のいずれか少なく
とも一種をこ本発明のダニ防除剤組成物を混練し、これ
らを用いてカーペットを作成するか、あるいはバッキン
グ剤に本発明のダニ防除剤を混入し、これを用いてプレ
コート方式又はジュードパツク方式に従いカーペットを
作成することトこより得られる。A preferred example of the mite-controlling material of the present invention is a mite-controlling carpet. The mite-repellent carpet can be prepared by, for example, preparing a normal carpet consisting of a Bi/M% first base fabric, a puffing agent, and a second base fabric, and then treating the surface and (
or) Spray the mite control agent composition of the present invention in liquid form on the back surface of the carpet, or, prior to the production of the carpet, apply at least one of the base fabric, the first base fabric, and the second base fabric. The mite control agent composition of the present invention is kneaded and used to make a carpet, or the backing agent is mixed with the mite control agent of the present invention and used to prepare a carpet according to a pre-coat method or a jude pack method. This can be achieved by creating.
上記において、プレコート方式とは第一基布ｔこバイル
を固定化するため１こあらかじめバッキング剤を塗布処
理し、後にこの処理部にさらにバッキング剤を塗布処理
し、第二基布を接着させる方法という。またジ、−トバ
クク方式とは、パイルを織り込んだ第一基布ｔこバッキ
ング剤を塗布処理し。In the above, the pre-coat method is a method in which a backing agent is applied in advance to one piece of the first base fabric in order to fix the bulk, and then a backing agent is further applied to this treated area and the second base fabric is bonded. That's what it means. In addition, the Ji-Tobaku method involves applying a backing agent to the first base fabric into which pile is woven.
第二基布を接着させる方法をいう。上記の如（して作成
されるダニ防除カーペットは、通常好ましくはカーペッ
ト面積１ｍ画りに有効成分組成物を約０５〜２００ｇ保
持させるのがよい。Refers to the method of adhering the second base fabric. The mite-repellent carpet prepared as described above usually preferably retains about 05 to 200 g of the active ingredient composition per meter of carpet area.
以上に述べた如く本発明のダニ防除剤組成物ｔよ％ 、
％ −ヘラ）、床、 ＩＩ”’Ｆ、マツトレス、ソファ
−１布団や枕等の寝具類、押入れ、収納具類、倉庫等に
載置、散布、噴霧、塗布、煙霧、加熱蒸散等の方法によ
り直接処理したり、又該組成物を基材に保持させたダニ
防除材を上記の場所ｔこ設置すれば、優れたダニ防除効
果を示す。As mentioned above, the mite control agent composition of the present invention is
% - spatula), floor, II'''F, pine tress, sofa-1 bedding such as futons and pillows, closets, storage equipment, placing in warehouses, etc. Methods such as scattering, spraying, coating, fumes, heating transpiration, etc. Excellent mite control effects can be obtained by directly treating the mites with a mite-controlling material or by placing a mite-controlling material containing the composition on a base material in the above-mentioned locations.
Ｃ＊施例〕 以下、本発明の実施例を挙げてさらに詳しく説明する。C*Example] Hereinafter, the present invention will be explained in more detail with reference to Examples.
１１ｉ例１ コナと習つヒダニに対する効力黒上質紙
（５×５α）に、所定の濃度となるよう供試組成物のア
セトン溶液を含浸させる。溶媒除去後この含浸紙を約３
００頭の供試ダニとともｔこポリエチレン袋（６ｘ ６
ａｐｔ ）に入れ四方を密着させる。４８時間後に実
体顕微鏡下で生死の判定をした。結果は、下式のアボッ
ト補正による死去率（％）で求め表１に示した。11i Example 1 Efficacy against Kona and Dermatophagoides Black high-quality paper (5 x 5α) is impregnated with an acetone solution of the test composition to a predetermined concentration. After removing the solvent, this impregnated paper was
A polyethylene bag (6 x 6
apt) and press the four sides tightly together. After 48 hours, the animals were judged to be alive or dead under a stereomicroscope. The results are shown in Table 1 by calculating the mortality rate (%) by Abbott correction using the following formula.
補正死去率Ｃ％）＝ ｘｌＯＯ
Ｘ：無処理区の生存虫の百分率
ｙ：処理区の生存虫の百分率
表 １
コナヒ１ウダニに対し、レスメトリンフォルテが有効で
あることが知られているが、本発明のダニ防り剤１ｍｍ
動物、レスメトリンフォルテよりも高い効力を示した。Corrected mortality rate C%) = xlOO , 1mm of the tick repellent of the present invention
showed higher efficacy than resmethrin forte in animals.
実施例２ ケナガコナダニに対する効力実施例りと同様
の手順で行ない２４時間後に生死の判定をした。結果は
、５１！施例りと同じくアボット補正による死去率（％
）で求め表２に一示した。Example 2 Efficacy against woolly mites The same procedure as in Example was followed, and 24 hours later, whether the animals were alive or dead was determined. The result is 51! As with the example, the mortality rate (%) is adjusted by Abbott.
) and are shown in Table 2.
ケナガコナダニに対し、本発明のダニ防除剤組成物は、
レスメトリンフォルテよりモ高い効力を示した。The mite control agent composition of the present invention against woolly mites,
It showed higher efficacy than resmethrin forte.
９！施例３
カーペットの防虫化を目的として：下記表３の豐
仕様ｍＡ−Ｊでカーペット形態の本発明のダニ防除材を
作成した。9! Example 3 For the purpose of making a carpet insect repellent: A mite repellent material of the present invention in the form of a carpet was prepared according to the rattan specification mA-J shown in Table 3 below.
上記で得られたダニ防除カーペットサンプル煮Ａ−Ｊｒ
ｃつき、以下の試験を行った。Mite control carpet sample boiled A-Jr obtained above
The following tests were conducted with c.
〈試験法〉
カーペットサンプルＡ Ａ ＝ Ｊおよび薬剤無処理カ
ーペット（各々２０Ｘ２０Ｑｌ）上の中央部に、コナヒ
ツウヒダニ約１万頭を含むダニ培地を置き、こレヲコン
テナ（’ ４１ Ｘ ３１ Ｘ ２２ ａ ）ＫｆＢＡ
＋：入れた後、２５Ｃ１６４％Ｒ１の条件下で２日間保
存後、吸引筒接続１部に２ ＣＩ Ｏｍｅｓｈ ナイ
ロンゴウス２枚を挾んだ掃除機でカーペット表面又は裏
面のダニを吸い取った。次ｔこ、ナイロンゴウスな掃除
機よりはずし、ダーリンダ液１００ ｍｌを入れた３
００ ｍｌｌヒビ−カー内ダニを払い落とし、攪拌後遠
沈管に移し１１０００ｒｐ で遠心分離して、上清部
を口紙を置いたプフナー漏斗に移し、吸引口過する。こ
の口紙上の生存ダニ類をカウントし、結果は次式より死
去率（％）として求めた。<Test method> A mite culture medium containing approximately 10,000 mites was placed in the center of the carpet sample A A = J and the chemical-free carpet (each 20 x 20 Ql), and this container (' 41 x 31 x 22 a) KfBA
+: After storing the carpet under 25C164%R1 conditions for 2 days, dust mites on the surface or back of the carpet were sucked off using a vacuum cleaner with two pieces of 2 CI Omesh nylon gas sandwiched between one part of the suction cylinder connection. Next, I removed it from the nylon vacuum cleaner and added 100 ml of Darlin liquid.
Dust mites in the 00 ml beaker were shaken off, stirred, transferred to a centrifuge tube, centrifuged at 11,000 rpm, and the supernatant was transferred to a Puchner funnel with a spout and filtered through the suction spout. The living mites on this paper were counted, and the result was determined as a mortality rate (%) using the following formula.
Ｘ：薬剤無処理カーペット区の生存ダニ数ｙ：ダニ防除
カーペット区の生存ダニ数上記の試験を３回繰返し、結
果をその平均値で表４に示す。X: Number of surviving mites in the chemical-free carpet area y: Number of surviving mites in the mite-controlled carpet area The above test was repeated three times, and the results are shown in Table 4 as the average value.
表４
上記表４の如く、各サンプ〃は十分なダニ防除性を示し
た。Table 4 As shown in Table 4 above, each sample showed sufficient mite control properties.
実施例４
下記表の供試組成物サンプルの／ｉ Ａ −Ｒ６４１５
ｇＣ１香料を微ゑ、ヱ＋Ａ／セロソルブ２０ｄ６“を加
え、さらに無臭灯油な加えて全体をＩＦＩＯ声ｌとし、
これと液化石油ガス及びジメチルエーテル混合物（１：
１容積比）の１５０ ｍｌとをエアゾール用耐圧缶（内
容４００ｍ／）Ｋ−充填して噴射装置に取付け、密封し
てエアゾール剤の形態として本発明のダニ防除材を得た
。Example 4 /i A-R6415 of the test composition sample in the table below
Add a slight amount of gC1 fragrance, 20d6 of E+A/Cellosolve, and add odorless kerosene to make the whole thing IFIO.
This and a mixture of liquefied petroleum gas and dimethyl ether (1:
1 volume ratio) was filled into an aerosol pressure-resistant can (content: 400 m/kg), attached to an injection device, and sealed to obtain the mite control material of the present invention in the form of an aerosol.
このようにして得た各エアシー〃を用い、実施例りと同
様ケこしてダニ防除効果を試験した。Using each air sea obtained in this way, the mite control effect was tested in the same manner as in the example.
〈試験法〉
上質紙（３０Ｘ３０ｃＭ）に各エアゾールを３秒間、で
きるｔごけ均−ｔこなるようにスプレーし、常温下１日
保存後、５部５ｃｍの大きさのフートｔこ切り抜き、以
下実施例りの試験方法ｔこ準じてダニ防除効果を試験し
た。<Test method> Spray each aerosol on high-quality paper (30 x 30 cM) for 3 seconds so as to spread evenly, and after storing it at room temperature for 1 day, cut out 5 pieces of 5 cm foot pieces, as shown below. The mite control effect was tested according to the test method in Example.
上記の試験を３回繰返し、結果をその平均値で表５に示
す。The above test was repeated three times and the results are shown in Table 5 as the average value.
表５
上記表５の如（、各サンプルは十分なダニ防除性を示し
た。Table 5 As shown in Table 5 above, each sample showed sufficient mite control properties.
実施例５
下記ｗ２６の供試組成物混入サンプＶのＡＡ−Ｇを、不
織布（ポリエチレン−パルプ製、厚さ３００μ、面積１
ｍ）に供試組成物が１ｇとなるように含浸後乾燥し、シ
ート状形態の本発明ダニ防除材を一得た。Example 5 AA-G of sample V mixed with the following w26 test composition was coated with a nonwoven fabric (made of polyethylene pulp, thickness 300μ, area 1
m) was impregnated with 1 g of the test composition and dried to obtain a sheet-shaped mite control material of the present invention.
このシートを５×５１に切断し実施例１と同様にしてダ
ニ防除効果を試験した。This sheet was cut into 5 x 51 pieces and tested for mite control effect in the same manner as in Example 1.
表６
その結果、いずれのサンプルもほぼ１００％の死生率を
得ることができ、十分なダニ防除性を示した。Table 6 As a result, almost 100% mortality rate was obtained for all samples, indicating sufficient mite control properties.
実施例６
実施例５で用いた本発明の供試組成物を、それぞれ酸化
ケイ素の同重量と充分攪拌混合後粉状化して、粉末形因
の本発明のダニ防除材を得た。Example 6 The test compositions of the present invention used in Example 5 were mixed with the same weight of silicon oxide with sufficient stirring and then pulverized to obtain the mite control material of the present invention in powder form.
このようにして得た粉末剤を下記試験法によりダニ防除
効果を試験した。The dust mite control effect of the thus obtained powder was tested using the following test method.
〈試験方法〉
約２ｏＩＩ！！ｃに切ったワラを加熱殺虫後、その５ｇ
を１００ ｍｌ三角フラスコに入れ１次に各粉末剤００
５ｇを投入し混合して２５℃、８５〜９０％ＲＨの条件
下で１日保存する。この三角フラスコをこ約４００頭の
ケナガコナダニを投入し、同条件下で２８−保存後、熱
追い出し法により生存ダニを追い出し、その数をカウン
トし、死生率を実施例３の試験法に準じて算出した。<Test method> Approximately 2oII! ! 5g of straw cut into C pieces after heating and killing insects
Pour into a 100 ml Erlenmeyer flask and add 00 ml of each powder.
5g of the mixture was added, mixed, and stored for one day at 25°C and 85-90% RH. Approximately 400 woolly mites were placed in this Erlenmeyer flask, and after storage under the same conditions for 28 hours, living mites were expelled by heat expulsion method, the number was counted, and the mortality rate was determined according to the test method of Example 3. Calculated.
Claims (1)
ルアミン、メチルβ−ナフチルケトン、クマリンから選
択される少なくとも一種を有効成分として含有すること
を特徴とするダニ防除剤組成物。 ２、サリチル酸フェニル、安息香酸フェニル、ジフェニ
ルアミン、メチルβ−ナフチルケトン、クマリンから選
択される少なくとも一種を有効成分として含有するダニ
防除剤組成物を基材に保持させたことを特徴とするダニ
防除材。[Scope of Claims] 1. A mite control agent composition containing as an active ingredient at least one selected from phenyl salicylate, phenyl benzoate, diphenylamine, methyl β-naphthyl ketone, and coumarin. 2. A mite control material comprising a base material holding a mite control agent composition containing as an active ingredient at least one selected from phenyl salicylate, phenyl benzoate, diphenylamine, methyl β-naphthyl ketone, and coumarin. .
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17386885A JPS6233106A (en) | 1985-08-06 | 1985-08-06 | Mite controlling agent |
| EP86900243A EP0233288B1 (en) | 1985-08-06 | 1985-12-06 | Acaricide |
| DE8686900243T DE3586542T2 (en) | 1985-08-06 | 1985-12-06 | ACARICIDES. |
| US07/041,071 US4800196A (en) | 1985-08-06 | 1985-12-06 | Phenyl salicylate and benzyl salicylate as acaricidal agents |
| PCT/JP1985/000675 WO1987000728A1 (en) | 1985-08-06 | 1985-12-06 | Acaricide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17386885A JPS6233106A (en) | 1985-08-06 | 1985-08-06 | Mite controlling agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6233106A true JPS6233106A (en) | 1987-02-13 |
| JPH058682B2 JPH058682B2 (en) | 1993-02-02 |
Family
ID=15968621
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17386885A Granted JPS6233106A (en) | 1985-08-06 | 1985-08-06 | Mite controlling agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6233106A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5180586A (en) * | 1989-10-19 | 1993-01-19 | Takasago International Corporation | Acaricidal composition |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6157501A (en) * | 1984-08-20 | 1986-03-24 | ウエルナー・ウント・メルツ・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング | Acarecede |
-
1985
- 1985-08-06 JP JP17386885A patent/JPS6233106A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6157501A (en) * | 1984-08-20 | 1986-03-24 | ウエルナー・ウント・メルツ・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング | Acarecede |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5180586A (en) * | 1989-10-19 | 1993-01-19 | Takasago International Corporation | Acaricidal composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH058682B2 (en) | 1993-02-02 |
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