JP7486418B2 - フィロシリケートで含浸されたメラミン-ホルムアルデヒドフォーム - Google Patents
フィロシリケートで含浸されたメラミン-ホルムアルデヒドフォーム Download PDFInfo
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- JP7486418B2 JP7486418B2 JP2020514931A JP2020514931A JP7486418B2 JP 7486418 B2 JP7486418 B2 JP 7486418B2 JP 2020514931 A JP2020514931 A JP 2020514931A JP 2020514931 A JP2020514931 A JP 2020514931A JP 7486418 B2 JP7486418 B2 JP 7486418B2
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- Prior art keywords
- foam
- melamine
- formaldehyde
- weight
- polyurethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000006260 foam Substances 0.000 title claims description 146
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 title claims description 56
- 229910052615 phyllosilicate Inorganic materials 0.000 title claims description 38
- 229920000877 Melamine resin Polymers 0.000 title claims description 13
- 229920003009 polyurethane dispersion Polymers 0.000 claims description 35
- 239000000203 mixture Substances 0.000 claims description 32
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 18
- 239000006185 dispersion Substances 0.000 claims description 17
- 239000004814 polyurethane Substances 0.000 claims description 17
- 229920002635 polyurethane Polymers 0.000 claims description 15
- 238000005470 impregnation Methods 0.000 claims description 13
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 12
- 239000011888 foil Substances 0.000 claims description 12
- 239000004744 fabric Substances 0.000 claims description 10
- 150000001718 carbodiimides Chemical class 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 239000011148 porous material Substances 0.000 claims description 9
- NNOZGCICXAYKLW-UHFFFAOYSA-N 1,2-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC=C1C(C)(C)N=C=O NNOZGCICXAYKLW-UHFFFAOYSA-N 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 5
- 239000003365 glass fiber Substances 0.000 claims description 5
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 2
- 239000011707 mineral Substances 0.000 claims 2
- 238000012360 testing method Methods 0.000 description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 23
- 239000000853 adhesive Substances 0.000 description 17
- 230000001070 adhesive effect Effects 0.000 description 15
- 239000002270 dispersing agent Substances 0.000 description 14
- 239000003063 flame retardant Substances 0.000 description 13
- 229910052782 aluminium Inorganic materials 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 10
- 229920005832 Basotect® Polymers 0.000 description 9
- 239000011230 binding agent Substances 0.000 description 9
- 239000011256 inorganic filler Substances 0.000 description 9
- 229910003475 inorganic filler Inorganic materials 0.000 description 9
- 238000009413 insulation Methods 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 239000000654 additive Substances 0.000 description 8
- RASZIXQTZOARSV-BDPUVYQTSA-N astacin Chemical compound CC=1C(=O)C(=O)CC(C)(C)C=1/C=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(C)C=CC=C(C)C=CC1=C(C)C(=O)C(=O)CC1(C)C RASZIXQTZOARSV-BDPUVYQTSA-N 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical group [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 8
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 7
- 239000004604 Blowing Agent Substances 0.000 description 7
- 238000010276 construction Methods 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- 125000000129 anionic group Chemical group 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000007906 compression Methods 0.000 description 6
- 230000006835 compression Effects 0.000 description 6
- 150000002009 diols Chemical class 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 150000004756 silanes Chemical class 0.000 description 5
- 229910052623 talc Inorganic materials 0.000 description 5
- 102000034498 Astacin Human genes 0.000 description 4
- 108090000658 Astacin Proteins 0.000 description 4
- FMKGDHLSXFDSOU-BDPUVYQTSA-N Dienon-Astacin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)C(=O)C(=CC1(C)C)O)C=CC=C(/C)C=CC2=C(C)C(=O)C(=CC2(C)C)O FMKGDHLSXFDSOU-BDPUVYQTSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000004115 Sodium Silicate Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 235000003676 astacin Nutrition 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 235000019353 potassium silicate Nutrition 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 229910052911 sodium silicate Inorganic materials 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000000454 talc Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 239000004640 Melamine resin Substances 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000005030 aluminium foil Substances 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229920002050 silicone resin Polymers 0.000 description 3
- -1 siloxanes Chemical class 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 2
- 229920005789 ACRONAL® acrylic binder Polymers 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 239000002313 adhesive film Substances 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229920003180 amino resin Polymers 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 229910052622 kaolinite Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000002557 mineral fiber Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- HXLAEGYMDGUSBD-UHFFFAOYSA-N 3-[diethoxy(methyl)silyl]propan-1-amine Chemical compound CCO[Si](C)(OCC)CCCN HXLAEGYMDGUSBD-UHFFFAOYSA-N 0.000 description 1
- JCQKQWAONVEFJC-UHFFFAOYSA-N 3-hydroxy-2,2-bis(hydroxymethyl)propanal Chemical compound OCC(CO)(CO)C=O JCQKQWAONVEFJC-UHFFFAOYSA-N 0.000 description 1
- RWLDCNACDPTRMY-UHFFFAOYSA-N 3-triethoxysilyl-n-(3-triethoxysilylpropyl)propan-1-amine Chemical compound CCO[Si](OCC)(OCC)CCCNCCC[Si](OCC)(OCC)OCC RWLDCNACDPTRMY-UHFFFAOYSA-N 0.000 description 1
- SWDDLRSGGCWDPH-UHFFFAOYSA-N 4-triethoxysilylbutan-1-amine Chemical compound CCO[Si](OCC)(OCC)CCCCN SWDDLRSGGCWDPH-UHFFFAOYSA-N 0.000 description 1
- RBVMDQYCJXEJCJ-UHFFFAOYSA-N 4-trimethoxysilylbutan-1-amine Chemical compound CO[Si](OC)(OC)CCCCN RBVMDQYCJXEJCJ-UHFFFAOYSA-N 0.000 description 1
- FEIQOMCWGDNMHM-UHFFFAOYSA-N 5-phenylpenta-2,4-dienoic acid Chemical compound OC(=O)C=CC=CC1=CC=CC=C1 FEIQOMCWGDNMHM-UHFFFAOYSA-N 0.000 description 1
- 229920005824 ACRODUR® 950 L Polymers 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229920005837 Basotect® UL Polymers 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- 239000006244 Medium Thermal Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical group [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 229920004482 WACKER® Polymers 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- OLBVUFHMDRJKTK-UHFFFAOYSA-N [N].[O] Chemical compound [N].[O] OLBVUFHMDRJKTK-UHFFFAOYSA-N 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 229920003015 aliphatic polyurethane dispersion Polymers 0.000 description 1
- 229910001583 allophane Inorganic materials 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- VPKDCDLSJZCGKE-UHFFFAOYSA-N carbodiimide group Chemical group N=C=N VPKDCDLSJZCGKE-UHFFFAOYSA-N 0.000 description 1
- 150000003857 carboxamides Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000002666 chemical blowing agent Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 238000007706 flame test Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000010191 image analysis Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000003137 locomotive effect Effects 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 238000000399 optical microscopy Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000008194 pharmaceutical composition Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- ZWLUXSQADUDCSB-UHFFFAOYSA-N phthalaldehyde Chemical compound O=CC1=CC=CC=C1C=O ZWLUXSQADUDCSB-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- JMHCCAYJTTWMCX-QWPJCUCISA-M sodium;(2s)-2-amino-3-[4-(4-hydroxy-3,5-diiodophenoxy)-3,5-diiodophenyl]propanoate;pentahydrate Chemical compound O.O.O.O.O.[Na+].IC1=CC(C[C@H](N)C([O-])=O)=CC(I)=C1OC1=CC(I)=C(O)C(I)=C1 JMHCCAYJTTWMCX-QWPJCUCISA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- NVBFHJWHLNUMCV-UHFFFAOYSA-N sulfamide Chemical class NS(N)(=O)=O NVBFHJWHLNUMCV-UHFFFAOYSA-N 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Description
(a) アミノシランで表面修飾された少なくとも1種の粒子状フィロシリケートを、アニオン的に及び/又は非イオン的に安定化された少なくとも1種のポリウレタン分散体と混合する工程と、
(b) 工程(a)からの混合物をフォームに適用する工程と、
(c) 任意に、次に混合物をフォームの細孔中に導入するようにフォームを圧縮する(compressing)工程と、
(d) フォームを乾燥させる工程と
を含む、当該メラミン/ホルムアルデヒドフォームを製造する方法によって達成される。
(X-(CH2)n)k-Si-(O-CmH2m+1)4-k
(式中、
XはNH2-であり、
nは2~10、好ましくは3~4の整数であり、
mは1~5、好ましくは1~2の整数であり、
kは1~3、好ましくは1の整数である)
のものである。
a)ジイソシアネートであって、
a1)式-N=C=N-のカルボジイミド構造単位、及び任意に、
a2)式-N=C=N-の構造単位を含まないもの
を含有するジイソシアネート、
b)ジオールであって、
b1)ジオール(b)の総量に基づいて、その10~100モル%が500~5000g/molの分子量を有し、
b2)ジオール(b)の総量に基づいて、その0~90モル%が60~500g/molの分子量を有する
ジオール、
c)モノマー(a)及び(b)と異なり、少なくとも1つのイソシアネート基、又はポリウレタンを水中に分散可能にする少なくとも1つの親水性基又は潜在的に親水性の基をさらに有する少なくとも1つのイソシアネート反応性基を有するモノマー、
d)任意に、モノマー(a)~(c)と異なり、アルコール性ヒドロキシル基、第1級又は第2級アミノ基、又はイソシアネート基である反応性基を有するさらなる多官能化合物、及び
e)任意に、モノマー(a)~(d)と異なり、アルコール性ヒドロキシル基、第1級又は第2級アミノ基、又はイソシアネート基である反応性基を有する単官能化合物
から製造することができる。
酸、分散剤及び発泡剤を用いて、メラミン/ホルムアルデヒド予備縮合物及び溶媒を発泡剤の沸点より高い温度で発泡して、その後に乾燥させることが可能である。
(1)製造されるフォームのメラミン/ホルムアルデヒド予備縮合物、及び任意にさらに添加される成分を含む懸濁液を製造する工程と、
(2)工程(1)からの懸濁液を発泡剤の沸点より高い温度に加熱することにより、予備縮合物を発泡させる工程と、
(3)工程(2)から得られたフォームを乾燥させる工程と
を含む。
(a)アミノシランで表面修飾された少なくとも1種の粒子状フィロシリケートを、アニオン的に及び/又は非イオン的に安定化された少なくとも1種のポリウレタン分散体、及び任意に分散剤及び疎水剤/疎油剤と混合する工程と、
(b)工程(a)からの混合物をフォームに適用する工程と、
(c)任意に、次に混合物をフォームの細孔中に導入するようにフォームを圧縮する工程と、
(d) フォームを乾燥させる工程と
を含む方法により製造を行う。
不燃性試験IMO 2010 FTPコードパート1
この燃焼試験を使用して、決議MSC.307(88))に従って造船業部門における使用のための材料の不燃性を実証する。DIN EN ISO 1182に従って、電気加熱炉で円筒形の試験試料(H=50mm、φ45mm)を750℃に加熱することにより試験を行った。炉温度の平均温度差及び試験試料の表面温度の平均温度差が30℃以下である場合、この試験試料を「不燃性」に分類する。質量の平均損失は50質量%を超えてはならず、観察した平均点火時間は10秒未満であった。
粒子状フィロシリケートのメラミン/ホルムアルデヒドフォームとの接着を評価するために、メラミン/ホルムアルデヒドフォームから45mmの直径及び50mmの高さを有する円筒形の試験試料を製造した。フィロシリケートをフォーム構造に適用して乾燥した後、フォームを壊さずに、円筒形の試験試料を手動で暗い固体ベース上に押し込んだ。硬質表面上の粉末状コーティングは、フォームからのフィラー(フィロシリケート)の分離の証拠となる。
DIN EN 13162標準は、EN 1609に従って短時間の部分的な浸漬後の吸水率WPを定義する。結果は、1.0kg/m2の吸水率を超えてはならない。EN 1609に従う滴下法(drip method)において、本発明の疎水化フォームの試験試料の初期質量m0を決定した。その後、試験試料を空の水容器に入れ、水を添加したときにも部分的に浸ったままになるように秤量した。その後、試験試料の下側が水位より10mm低くなるまで、注意深く水を添加した。24時間後、試験試料を取り出した。10分間滴下した後、試験試料を再秤量し、質量m24を決定した。m24とm0の差を平方メートルでの試験試料の底面面積APに除することにより、平方メートル当たりのキログラムでの吸水率WPを計算した。
DIN EN 12667「建築材料と製品の熱性能、保護されたホットプレート及び熱流量計法の平均値による熱抵抗の決定、高及び中程度の熱抵抗の製品」に従って、熱伝導率を測定した。
酸素指数(LOI=限界酸素指数)は、特にプラスチックの燃焼挙動を説明するためのパラメーターである。それは、垂直に置かれた試験試料の燃焼が試験条件下で持続する酸素-窒素混合物の最小酸素濃度である。その酸素指数が低いほど、物質はより容易に燃焼する。
通常の製造手順:
WO 2012/059493に記載しているようにメラミン/ホルムアルデヒドフォームを製造し、WO 2009/021963に従って比較例Aを製造した。対応するフォームは、例えばBASF SEから商品名Basotect(登録商標)で購入できる。
フィロシリケート、分散剤、ポリウレタン分散体及び水からなる分散液中にメラミン/ホルムアルデヒドフォームの平坦ブランクを浸漬することにより、含浸を行った。フォームブランクを分散液中に複数回圧縮した後、フォームブランクを分散液から取り出し、その後に、130℃で一定の質量になるまで約4時間乾燥させた。
a) LOI:20.2%
b) LOI:27.0%
c) LOI:30.4%。
Claims (13)
- 連続気泡フォーム構造を有するメラミン/ホルムアルデヒドフォームであって、
フォーム構造に適用された状態の含浸物を有し、該含浸物は、アミノシランで表面修飾された少なくとも1種の粒子状フィロシリケート及びアニオン的に及び/又は非イオン的に安定化された少なくとも1種のポリウレタン分散体を含み、且つ
前記含浸物により適用された物質は、乾燥されている、ことを特徴とするメラミン/ホルムアルデヒドフォーム。 - 前記アミノシランで表面修飾された少なくとも1種の粒子状フィロシリケートが、100質量部の含浸されていないメラミン/ホルムアルデヒドフォームに基づいて、50~350質量部の量で前記フォーム構造に適用されている、請求項1に記載のフォーム。
- 前記アニオン的に及び/又は非イオン的に安定化された少なくとも1種のポリウレタン分散体が、前記含浸物の乾燥質量に基づいて、0.5質量%~10質量%の量で使用される、請求項1又は2に記載のフォーム。
- 前記含浸されていないメラミン/ホルムアルデヒドフォームが5~12g/lの範囲の密度を有する、請求項1から3のいずれか一項に記載のフォーム。
- 前記含浸されたメラミン/ホルムアルデヒドフォームの密度が、前記含浸されていないメラミン/ホルムアルデヒドフォームの密度より少なくとも3g/l高い、請求項1から4のいずれか一項に記載のフォーム。
- 前記メラミン/ホルムアルデヒドフォームが、5:1~1.3:1の範囲のホルムアルデヒドとメラミンのモル比を有する、請求項1から5のいずれか一項に記載のフォーム。
- 前記アニオン的に及び/又は非イオン的に安定化された少なくとも1種のポリウレタン分散体が、式-N=C=N-のカルボジイミド構造単位を含むポリウレタンの水性分散体である、請求項1から6のいずれか一項に記載のフォーム。
- 前記式-N=C=N-のカルボジイミド構造単位が、テトラメチルキシリレンジイソシアネート(TMXDI)を介して前記ポリウレタン中に導入される、請求項7に記載のフォーム。
- 式-N=C=N-のカルボジイミド構造単位の含有量が、前記ポリウレタンに基づいて5~150mmol/kgである、請求項7又は8に記載のフォーム。
- その外表面が、ガラス繊維不織布、鉱物繊維不織布、炭素繊維不織布、炭素繊維織物、ガラス繊維織物、鉱物繊維織物、又は金属ホイルで少なくとも部分的にラミネートされている、請求項1から9のいずれか一項に記載のフォーム。
- 請求項1から9のいずれか一項に記載のメラミン/ホルムアルデヒドフォームを製造する方法であって、以下の工程:
(a) アミノシランで表面修飾された少なくとも1種の粒子状フィロシリケートを、アニオン的に及び/又は非イオン的に安定化された少なくとも1種のポリウレタン分散体と混合する工程と、
(b) 工程(a)からの混合物を前記フォームに適用する工程と、
(d) 前記フォームを乾燥させる工程と
を含む、方法。 - 工程(b)と工程(d)の間に、以下の工程:
(c) 次に前記混合物を前記フォームの細孔中に導入するように前記フォームを圧縮する工程、
を含む、請求項11に記載の方法。 - 40~200℃の範囲の温度で工程d)を行う、請求項11に記載の方法。
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PCT/EP2018/073333 WO2019052825A1 (de) | 2017-09-12 | 2018-08-30 | Mit schichtsilikat imprägnierter melamin/formaldehyd-schaumstoff |
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JP2011506150A (ja) | 2007-12-19 | 2011-03-03 | ビーエーエスエフ ソシエタス・ヨーロピア | 発泡可能な反応性樹脂を含む支持材の成形体 |
JP2013544927A (ja) | 2010-11-05 | 2013-12-19 | ビーエーエスエフ ソシエタス・ヨーロピア | 無機充填剤を有するメラミン樹脂フォーム材料 |
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DE2915457A1 (de) | 1979-04-17 | 1980-10-30 | Basf Ag | Elastischer schaumstoff auf basis eines melamin/formaldehyd-kondensationsproduktes |
US4511678A (en) | 1979-04-17 | 1985-04-16 | Basf Aktiengesellschaft | Resilient foam based on a melamine-formaldehyde condensate |
DE3175603D1 (en) | 1981-08-06 | 1987-01-02 | Toyo Rubber Chemical Ind Co | Method for manufacturing low density rubber foamed body |
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JP2009522438A (ja) | 2006-01-12 | 2009-06-11 | ザ プロクター アンド ギャンブル カンパニー | 修飾された連続気泡発泡体を含む洗浄用具 |
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KR102592784B1 (ko) | 2023-10-23 |
WO2019052825A1 (de) | 2019-03-21 |
KR20200053564A (ko) | 2020-05-18 |
EP3681941B1 (de) | 2021-10-06 |
ES2902798T3 (es) | 2022-03-29 |
EP3681941A1 (de) | 2020-07-22 |
JP2020533462A (ja) | 2020-11-19 |
CN111094415A (zh) | 2020-05-01 |
US20200270415A1 (en) | 2020-08-27 |
US11236212B2 (en) | 2022-02-01 |
CN111094415B (zh) | 2022-12-27 |
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