JP7466458B2 - ワイヤおよびケーブルコーティング用非発泡ポリオレフィン組成物 - Google Patents
ワイヤおよびケーブルコーティング用非発泡ポリオレフィン組成物 Download PDFInfo
- Publication number
- JP7466458B2 JP7466458B2 JP2020555216A JP2020555216A JP7466458B2 JP 7466458 B2 JP7466458 B2 JP 7466458B2 JP 2020555216 A JP2020555216 A JP 2020555216A JP 2020555216 A JP2020555216 A JP 2020555216A JP 7466458 B2 JP7466458 B2 JP 7466458B2
- Authority
- JP
- Japan
- Prior art keywords
- composition
- polymer
- ethylene
- silane
- moisture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims description 85
- 229920000098 polyolefin Polymers 0.000 title claims description 45
- 238000000576 coating method Methods 0.000 title description 7
- 239000003054 catalyst Substances 0.000 claims description 38
- 229920001169 thermoplastic Polymers 0.000 claims description 38
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 28
- 239000005977 Ethylene Substances 0.000 claims description 28
- -1 polyethylenes Polymers 0.000 claims description 28
- 238000009833 condensation Methods 0.000 claims description 19
- 230000005494 condensation Effects 0.000 claims description 19
- 239000000155 melt Substances 0.000 claims description 19
- 239000000654 additive Substances 0.000 claims description 16
- 229920000573 polyethylene Polymers 0.000 claims description 14
- 239000004698 Polyethylene Substances 0.000 claims description 8
- 239000002841 Lewis acid Substances 0.000 claims description 7
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical group CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 6
- 239000012975 dibutyltin dilaurate Substances 0.000 claims description 6
- 150000007517 lewis acids Chemical group 0.000 claims description 6
- 239000002879 Lewis base Substances 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 5
- 239000006229 carbon black Substances 0.000 claims description 5
- 150000007527 lewis bases Chemical class 0.000 claims description 5
- 239000004611 light stabiliser Substances 0.000 claims description 5
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 239000012963 UV stabilizer Substances 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 claims description 2
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 2
- 238000005187 foaming Methods 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 62
- 238000000034 method Methods 0.000 description 29
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 20
- 229920001577 copolymer Polymers 0.000 description 19
- 229910000077 silane Inorganic materials 0.000 description 19
- 150000001336 alkenes Chemical class 0.000 description 16
- 239000004711 α-olefin Substances 0.000 description 16
- 239000000945 filler Substances 0.000 description 15
- 239000000126 substance Substances 0.000 description 15
- 239000000463 material Substances 0.000 description 13
- 238000004132 cross linking Methods 0.000 description 12
- 229920000092 linear low density polyethylene Polymers 0.000 description 11
- 239000004707 linear low-density polyethylene Substances 0.000 description 11
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 11
- 150000004756 silanes Chemical class 0.000 description 11
- 238000001125 extrusion Methods 0.000 description 10
- 239000003999 initiator Substances 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 239000000178 monomer Substances 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 8
- 239000004416 thermosoftening plastic Substances 0.000 description 8
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 7
- 239000002585 base Substances 0.000 description 7
- 238000013329 compounding Methods 0.000 description 7
- 229920001684 low density polyethylene Polymers 0.000 description 7
- 239000004702 low-density polyethylene Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 6
- 239000004604 Blowing Agent Substances 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000001723 curing Methods 0.000 description 6
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 6
- 239000008188 pellet Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 5
- 239000004594 Masterbatch (MB) Substances 0.000 description 5
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 5
- 229920001903 high density polyethylene Polymers 0.000 description 5
- 239000004700 high-density polyethylene Substances 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 238000009413 insulation Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000013307 optical fiber Substances 0.000 description 4
- 230000001681 protective effect Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229920001187 thermosetting polymer Polymers 0.000 description 4
- 238000012056 up-stream process Methods 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 229920001400 block copolymer Polymers 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000013008 moisture curing Methods 0.000 description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- 229920005672 polyolefin resin Polymers 0.000 description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 239000004634 thermosetting polymer Substances 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 229920000034 Plastomer Polymers 0.000 description 2
- KVOZXXSUSRZIKD-UHFFFAOYSA-N Prop-2-enylcyclohexane Chemical compound C=CCC1CCCCC1 KVOZXXSUSRZIKD-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 241001422033 Thestylus Species 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 125000001769 aryl amino group Chemical group 0.000 description 2
- 239000013626 chemical specie Substances 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical group 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229920001179 medium density polyethylene Polymers 0.000 description 2
- 239000004701 medium-density polyethylene Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 230000003534 oscillatory effect Effects 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 238000000518 rheometry Methods 0.000 description 2
- 125000005372 silanol group Chemical group 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 229920002397 thermoplastic olefin Polymers 0.000 description 2
- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 description 1
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2,2'-azo-bis-isobutyronitrile Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 239000007848 Bronsted acid Substances 0.000 description 1
- OQGHDAKCDGEWNH-UHFFFAOYSA-M C[Sn](C)O Chemical compound C[Sn](C)O OQGHDAKCDGEWNH-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920010346 Very Low Density Polyethylene (VLDPE) Polymers 0.000 description 1
- 238000000333 X-ray scattering Methods 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 1
- NBJODVYWAQLZOC-UHFFFAOYSA-L [dibutyl(octanoyloxy)stannyl] octanoate Chemical compound CCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCC NBJODVYWAQLZOC-UHFFFAOYSA-L 0.000 description 1
- RMKZLFMHXZAGTM-UHFFFAOYSA-N [dimethoxy(propyl)silyl]oxymethyl prop-2-enoate Chemical compound CCC[Si](OC)(OC)OCOC(=O)C=C RMKZLFMHXZAGTM-UHFFFAOYSA-N 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- PZGVVCOOWYSSGB-UHFFFAOYSA-L but-2-enedioate;dioctyltin(2+) Chemical compound CCCCCCCC[Sn]1(CCCCCCCC)OC(=O)C=CC(=O)O1 PZGVVCOOWYSSGB-UHFFFAOYSA-L 0.000 description 1
- 125000004369 butenyl group Chemical group C(=CCC)* 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- XXHCQZDUJDEPSX-KNCHESJLSA-L calcium;(1s,2r)-cyclohexane-1,2-dicarboxylate Chemical compound [Ca+2].[O-]C(=O)[C@H]1CCCC[C@H]1C([O-])=O XXHCQZDUJDEPSX-KNCHESJLSA-L 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- PNOXNTGLSKTMQO-UHFFFAOYSA-L diacetyloxytin Chemical compound CC(=O)O[Sn]OC(C)=O PNOXNTGLSKTMQO-UHFFFAOYSA-L 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229940069096 dodecene Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001941 electron spectroscopy Methods 0.000 description 1
- HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 description 1
- BXOUVIIITJXIKB-UHFFFAOYSA-N ethene;styrene Chemical compound C=C.C=CC1=CC=CC=C1 BXOUVIIITJXIKB-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical compound C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000012632 extractable Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 125000000555 isopropenyl group Chemical group [H]\C([H])=C(\*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 239000000088 plastic resin Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920006124 polyolefin elastomer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 229920006029 tetra-polymer Polymers 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- 210000002105 tongue Anatomy 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/309—Sulfur containing acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/064—VLDPE
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
- C08L2312/08—Crosslinking by silane
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Insulated Conductors (AREA)
Description
(A)55~94.99重量%の熱可塑性ポリマーと、
(B)5~44.99重量%の湿気硬化性ポリマーと、
(C)0.01~5重量%の湿気縮合触媒と、を含む、溶融ブレンド組成物である。
米国特許実務を目的として、いかなる参照される特許、特許出願、または刊行物の内容も、特に定義の開示(本開示に具体的に提供されるいかなる定義にも矛盾しない範囲で)、および当該技術分野における一般的知識に関して、それらの全体において参照により組み込まれる(または、その同等の米国版が参照によりそのように組み込まれる)。
加熱すると軟化する任意のポリマーは、本発明の実施に使用され得る熱可塑性ポリマーである。そのようなポリマーには、ポリオレフィン、ポリエステル、ポリアミド、ポリ塩化ビニル(PVC)、ポリスチレン、ポリテトラフルオロエチレン(PTFE)などが含まれる。
本発明の実施において使用される湿気硬化性ポリオレフィンは、シラン官能基を有するポリオレフィンである。シラン官能基は、共重合および/またはグラフト化によってポリオレフィンの中または上に導入することができる。
湿気縮合触媒、または単に架橋触媒には、ルイスおよびブレンステッド酸および塩基が含まれる。ルイス酸は、ルイス塩基からの電子対を受け入れることができる化学種である。ルイス塩基は、電子対をルイス酸に供与することができる化学種である。本発明の実施において使用され得るルイス酸には、ジブチルスズジラウレート(DBTDL)などのカルボン酸スズ、ジメチルヒドロキシスズオレエート、ジオクチルスズマレエート、ジ-n-ブチルスズマレエート、ジブチルスズジアセテート、ジブチルスズジオクトエート、酢酸第一スズ、オクタン酸第一スズ、ならびにナフテン酸鉛、カプリル酸亜鉛、およびナフテン酸コバルトなどの様々な他の有機金属化合物が含まれる。DBTDLは、好ましいルイス酸である。本発明の実施において使用され得るルイス塩基には、これらに限定されないが、第一級、第二級、および第三級アミンが含まれる。
本発明の組成物は、1つ以上の充填剤および/または添加剤を含むことができる。存在する充填剤の量は、好ましくは、湿気硬化性組成物の機械的および/または化学的特性の許容不能に大きな劣化を引き起こすであろう量を超えるべきではない。典型的には、存在する充填剤の量は、組成物の重量に基づいて、2~35、好ましくは5~20重量パーセント(重量%)である。代表的な充填剤には、カオリン粘土、水酸化マグネシウム、シリカ、炭酸カルシウム、およびカーボンブラックが挙げられる。充填剤は、難燃特性を有していても、または有していなくてもよい。充填剤が存在する場合の本発明の好ましい一実施形態では、充填剤は、充填剤がさもないとシラン硬化反応を妨げる可能性があるいかなる傾向も防止または遅延させる材料でコーティングされる。ステアリン酸は、そのような充填剤コーティングの例示である。充填剤および触媒は、あらゆる望ましくない相互作用および反応も回避するように選択され、この選択は、当該技術の範囲内で良好である。
熱可塑性ポリマー、湿気硬化性ポリマー、縮合触媒、ならびに最適な充填剤および添加剤の化合は、当業者に既知の標準的な手段によって実施することができる。化合機器の例は、BANBURY(商標)またはBOLLING(商標)内部ミキサーなどの内部バッチミキサーである。代替として、FARREL(商標)連続ミキサー、WERNER AND PFLEIDERER(商標)二軸スクリューミキサー、またはBUSS(商標)混練連続押出機などの、連続一軸もしくは二軸スクリューミキサーまたは押出機が使用され得る。使用するミキサーのタイプ、およびミキサーの動作条件は、粘度、体積抵抗率、押出表面平滑性などの組成物の特性に影響を与える。
一実施形態では、本発明の組成物は、既知の量および既知の方法によって(例えば、USP5,246,783および4,144,202に記載される機器および方法を用いて)、保護ジャケットまたは絶縁層としてケーブルに適用することができる。典型的には、組成物は、ケーブルコーティング用ダイを備える反応器-押出機内で調製され、組成物の構成成分が配合された後、ケーブルがダイから引き出される際に、組成物は、ケーブル上に押出される。硬化は、反応器-押出機中で開始することができる。
密度について測定される試料を、ASTM D1928に従って調製する。試料を、374°F(190℃)および30,000psiで3分間、次いで70°F(21℃)および30,000psiで1分間圧縮する。ASTM D792、方法Bを使用して、1時間以内の試料加圧で密度測定を行う。
DFH2065は、0.920g/cm3の密度および0.65g/10分のメルトインデックス(190℃/2.16kg)を有する粒状の線状低密度ポリエチレン(LLDPE)である。
組成物を、150℃のBRABENDER(商標)バッチミキサーで化合する。縮合触媒(ジブチルスズ、SI-LINK(商標)DFDB-5480NT)を、ブレンド前に乾燥させる。化合後、組成物を、BRABENDER(商標)3/4インチ直径、25:1 L/D押出機から1分当たり50回転(rpm)での動作で、1分当たり38フィートの巻取速度で押出する。押出機の温度プロファイルは、5つのゾーン全てで210℃である。押出されたストランドを、ペレット[サイズ?]に切断し、90℃の水浴で4時間硬化させ、次いで、対流式オーブンで、80℃で一晩乾燥させるか、または50℃および75%の相対湿度で、14日間湿度チャンバーで硬化させ、次いで、80℃で一晩乾燥させる。次いで、硬化および乾燥したペレットを、引張試験および伸長試験(1分当たり20インチの速度)のために4インチ×4インチの75ミルのプラークに溶融プレスする。動的振動剪断試験を、190℃で、毎秒100~0.1ラジアンの周波数掃引で行った。配合および試験結果を以下の表に報告する。
CE-1は、完全に架橋されたシステムであり、典型的な湿気硬化性シランコポリマーを表す。注釈2aのように、化合後に材料をペレット化し、次いで、硬化させた。この化合物は、CE-4での使用のために調製し、熱可塑性ではないため、それ自体では押出可能ではない。
(態様1)
溶融ブレンド組成物であって、前記組成物の重量に基づく重量パーセント(重量%)で、
(A)55~94.99重量%の熱可塑性ポリマーと、
(B)5~44.99重量%の湿気硬化性ポリマーと、
(C)0.01~5重量%の湿気縮合触媒と、を含む、溶融ブレンド組成物。
(態様2)
前記熱可塑性ポリマーが、ポリオレフィンである、態様1に記載の組成物。
(態様3)
前記熱可塑性ポリマーが、ポリエチレンである、態様1に記載の組成物。
(態様4)
前記湿気硬化性ポリマーが、シラン官能化ポリオレフィンである、態様1~3のいずれかに記載の組成物。
(態様5)
前記縮合触媒が、ルイス酸またはルイス塩基である、態様1~4のいずれかに記載の組成物。
(態様6)
前記縮合触媒が、ジブチルスズジラウレートである、態様1~5のいずれかに記載の組成物。
(態様7)
前記縮合触媒が、スルホン酸である、態様1~6のいずれかに記載の組成物。
(態様8)
態様1~7のいずれかに記載の架橋組成物。
(態様9)
態様1~8のいずれかに記載の組成物を含む、ワイヤまたはケーブルシース。
(態様10)
態様9に記載のシースを含む、ワイヤまたはケーブル。
Claims (11)
- 溶融ブレンド組成物であって、前記組成物の重量に基づく重量パーセント(重量%)で、
(A)55~94.99重量%の熱可塑性ポリマーであって、それぞれエチレンに由来する単位を少なくとも50モル%含む1種以上のポリエチレンである熱可塑性ポリマーと、
(B)5~44.99重量%のシラン官能化ポリオレフィンと、
(C)0.01~5重量%の湿気縮合触媒と、
(D)任意成分としてのカーボンブラックと、
(E)酸化防止剤、光安定剤、UV安定剤、粘着添加剤、加工助剤およびこれらの組み合わせからなる群より選ばれた任意成分としての添加剤と、
を含んでなり、前記(A)~(E)の合計量が100重量%になる非発泡組成物である、溶融ブレンド組成物。 - 前記縮合触媒が、ルイス酸またはルイス塩基である、請求項1に記載の組成物。
- 前記縮合触媒が、ジブチルスズジラウレートである、請求項1に記載の組成物。
- 前記縮合触媒が、スルホン酸である、請求項1に記載の組成物。
- 請求項1に記載の組成物の架橋体。
- 請求項1に記載の組成物を含む、ワイヤまたはケーブルシース。
- 請求項6に記載のシースを含む、ワイヤまたはケーブル。
- 前記熱可塑性ポリマーが、互いに異なる2種のポリエチレンを含む、請求項1に記載の組成物。
- 前記カーボンブラック(D)が存在する、請求項8に記載の組成物。
- 前記熱可塑性ポリマーが、互いに異なる3種のポリエチレンを含む、請求項9に記載の組成物。
- 前記添加剤(E)が存在し、かつ、該添加剤が酸化防止剤、光安定剤及び加工助剤を含む、請求項10に記載の組成物。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201862663390P | 2018-04-27 | 2018-04-27 | |
US62/663,390 | 2018-04-27 | ||
PCT/US2019/027001 WO2019209546A1 (en) | 2018-04-27 | 2019-04-11 | Non-foam polyolefin compositions for wire and cable coating |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2021521289A JP2021521289A (ja) | 2021-08-26 |
JP7466458B2 true JP7466458B2 (ja) | 2024-04-12 |
Family
ID=66484145
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2020555216A Active JP7466458B2 (ja) | 2018-04-27 | 2019-04-11 | ワイヤおよびケーブルコーティング用非発泡ポリオレフィン組成物 |
Country Status (8)
Country | Link |
---|---|
US (1) | US11767419B2 (ja) |
EP (1) | EP3784721B1 (ja) |
JP (1) | JP7466458B2 (ja) |
CN (1) | CN111971328B (ja) |
CA (1) | CA3097342A1 (ja) |
MX (1) | MX2020010196A (ja) |
RU (1) | RU2020134374A (ja) |
WO (1) | WO2019209546A1 (ja) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030050401A1 (en) | 2000-11-06 | 2003-03-13 | Peter Jackson | Crosslinked, predominantly polypropylene-based compositions |
JP2010150357A (ja) | 2008-12-25 | 2010-07-08 | Japan Polyethylene Corp | 中空成形用樹脂組成物及び成形品 |
JP2014009237A (ja) | 2012-06-27 | 2014-01-20 | Furukawa Electric Co Ltd:The | 耐熱性樹脂組成物、当該耐熱性樹脂組成物を有する配線材、ケーブル及び成形品 |
JP2014009238A (ja) | 2012-06-27 | 2014-01-20 | Furukawa Electric Co Ltd:The | 耐熱性樹脂組成物、当該耐熱性樹脂組成物を有する配線材、ケーブル及び成形品 |
JP2017521514A (ja) | 2014-06-27 | 2017-08-03 | ダウ グローバル テクノロジーズ エルエルシー | 安定化された水分硬化性ポリマー組成物 |
Family Cites Families (45)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE794718Q (fr) | 1968-12-20 | 1973-05-16 | Dow Corning Ltd | Procede de reticulation d'olefines |
US4144202A (en) | 1977-12-27 | 1979-03-13 | Union Carbide Corporation | Dielectric compositions comprising ethylene polymer stabilized against water treeing with epoxy containing organo silanes |
AT359142B (de) | 1978-09-15 | 1980-10-27 | Kabel Metallwerke Ghh | Verfahren zur kontinuierlichen herstellung von umhuellungen von langgestrecktem gut |
US4614764A (en) | 1985-03-06 | 1986-09-30 | Mobil Oil Corporation | Linear low density ethylene polymers blended with modified linear low density ethylene polymers |
US5073598A (en) | 1989-06-21 | 1991-12-17 | Mobil Oil Corporation | Method for improving the processing characteristics of polyethylene blends |
JPH03149242A (ja) | 1989-08-08 | 1991-06-25 | Union Carbide Chem & Plast Co Inc | 熱可塑性オレフィン |
US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
US5266627A (en) | 1991-02-25 | 1993-11-30 | Quantum Chemical Corporation | Hydrolyzable silane copolymer compositions resistant to premature crosslinking and process |
US5246783A (en) | 1991-08-15 | 1993-09-21 | Exxon Chemical Patents Inc. | Electrical devices comprising polymeric insulating or semiconducting members |
US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
US5783638A (en) | 1991-10-15 | 1998-07-21 | The Dow Chemical Company | Elastic substantially linear ethylene polymers |
FR2723880B1 (fr) | 1994-08-30 | 1997-01-03 | Bp Chemicals Snc | Procede pour modifier un polyethylene dans une extrudeuse |
US5977271A (en) | 1994-09-02 | 1999-11-02 | The Dow Chemical Company | Process for preparing thermoset interpolymers and foams |
US5869591A (en) | 1994-09-02 | 1999-02-09 | The Dow Chemical Company | Thermoset interpolymers and foams |
US5883144A (en) | 1994-09-19 | 1999-03-16 | Sentinel Products Corp. | Silane-grafted materials for solid and foam applications |
US5589519A (en) | 1994-09-30 | 1996-12-31 | Knaus; Dennis A. | Process of extruding lightly crosslinked polyolefin foam |
US5530072A (en) | 1995-04-19 | 1996-06-25 | Mobil Oil Corporation | Introduction of long chain branching into linear polyethylenes |
US5824718A (en) | 1995-04-20 | 1998-10-20 | The Dow Chemical Company | Silane-crosslinkable, substantially linear ethylene polymers and their uses |
US5795941A (en) | 1995-10-03 | 1998-08-18 | The Dow Chemical Company | Crosslinkable bimodal polyolefin compositions |
US5844009A (en) | 1996-04-26 | 1998-12-01 | Sentinel Products Corp. | Cross-linked low-density polymer foam |
UA46901C2 (uk) | 1997-05-15 | 2002-06-17 | Піреллі Каві Е Сістемі С.П.А. | Силовий передавальний кабель, спосіб надання ударостійкості кабелю (варіанти) та спінений полімерний матеріал для нього |
US6496629B2 (en) | 1999-05-28 | 2002-12-17 | Tycom (Us) Inc. | Undersea telecommunications cable |
CA2290318C (en) | 1999-11-24 | 2009-02-03 | Shaw Industries Limited | Crosslinked compositions containing silane-grafted polyolefins and polypropylene |
US6545094B2 (en) | 2001-03-09 | 2003-04-08 | The Dow Chemical Company | Blends of ethylenic polymers with improved modulus and melt strength and articles fabricated from these blends |
CA2440427C (en) | 2001-03-12 | 2010-11-30 | General Cable Technologies Corporation | Methods of making compositions comprising thermoplastic and curable polymers and articles made from such methods |
US6714707B2 (en) | 2002-01-24 | 2004-03-30 | Alcatel | Optical cable housing an optical unit surrounded by a plurality of gel layers |
DE60317204T2 (de) * | 2002-07-31 | 2008-08-07 | Exxonmobil Chemical Patents Inc., Baytown | Silanvernetztes polyethylen |
US7504347B2 (en) | 2004-03-17 | 2009-03-17 | Dow Global Technologies Inc. | Fibers made from copolymers of propylene/α-olefins |
US7582716B2 (en) | 2004-03-17 | 2009-09-01 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for blown films with high hot tack |
US7355089B2 (en) | 2004-03-17 | 2008-04-08 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
US7524911B2 (en) | 2004-03-17 | 2009-04-28 | Dow Global Technologies Inc. | Adhesive and marking compositions made from interpolymers of ethylene/α-olefins |
US7579408B2 (en) | 2004-03-17 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic vulcanizate comprising interpolymers of ethylene/α-olefins |
US7514517B2 (en) | 2004-03-17 | 2009-04-07 | Dow Global Technologies Inc. | Anti-blocking compositions comprising interpolymers of ethylene/α-olefins |
US7892466B2 (en) | 2004-08-19 | 2011-02-22 | Univation Technologies, Llc | Oxygen tailoring of polyethylene resins |
EP1905045B1 (en) | 2005-07-15 | 2016-05-04 | Prysmian S.p.A. | Cable having expanded, strippable jacket |
WO2007032885A2 (en) * | 2005-09-13 | 2007-03-22 | Dow Global Technologies Inc. | Distannoxane catalysts for silane crosslinking and condensation reactions |
US20100227966A1 (en) | 2009-03-06 | 2010-09-09 | Shawcor Ltd. | Moisture-crosslinked polyolefin compositions |
WO2013043796A2 (en) | 2011-09-23 | 2013-03-28 | Exxonmobil Chemical Patents Inc. | Modified polyethylene compositions |
EP2910595A1 (en) * | 2014-02-21 | 2015-08-26 | Borealis AG | Polymer Blends |
RU2699143C1 (ru) | 2014-08-28 | 2019-09-03 | Дау Глоубл Текнолоджиз Ллк | Вспененные композиции модифицированного пероксидом линейного полиэтилена низкой плотности и способы получения вспененных композиций из него |
JP6287919B2 (ja) * | 2015-03-24 | 2018-03-07 | 株式会社オートネットワーク技術研究所 | 電線被覆材組成物、絶縁電線及びワイヤーハーネス |
BR112018006725B1 (pt) * | 2015-10-29 | 2022-04-19 | Dow Global Technologies Llc | Composição polimérica reticulável e condutor revestido |
EP3182418A1 (en) | 2015-12-18 | 2017-06-21 | Borealis AG | A cable jacket composition, cable jacket and a cable, e.g. a power cable or a communication cable |
PL3182422T3 (pl) | 2015-12-18 | 2020-01-31 | Borealis Ag | Sposób wytwarzania kabla energetycznego i kabel energetyczny otrzymywany według sposobu |
EP3252094A1 (en) | 2016-05-31 | 2017-12-06 | Borealis AG | Foamable ethylene polymer |
-
2019
- 2019-04-11 EP EP19723550.0A patent/EP3784721B1/en active Active
- 2019-04-11 CA CA3097342A patent/CA3097342A1/en active Pending
- 2019-04-11 RU RU2020134374A patent/RU2020134374A/ru unknown
- 2019-04-11 MX MX2020010196A patent/MX2020010196A/es unknown
- 2019-04-11 CN CN201980023469.8A patent/CN111971328B/zh active Active
- 2019-04-11 JP JP2020555216A patent/JP7466458B2/ja active Active
- 2019-04-11 US US17/049,643 patent/US11767419B2/en active Active
- 2019-04-11 WO PCT/US2019/027001 patent/WO2019209546A1/en active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030050401A1 (en) | 2000-11-06 | 2003-03-13 | Peter Jackson | Crosslinked, predominantly polypropylene-based compositions |
JP2010150357A (ja) | 2008-12-25 | 2010-07-08 | Japan Polyethylene Corp | 中空成形用樹脂組成物及び成形品 |
JP2014009237A (ja) | 2012-06-27 | 2014-01-20 | Furukawa Electric Co Ltd:The | 耐熱性樹脂組成物、当該耐熱性樹脂組成物を有する配線材、ケーブル及び成形品 |
JP2014009238A (ja) | 2012-06-27 | 2014-01-20 | Furukawa Electric Co Ltd:The | 耐熱性樹脂組成物、当該耐熱性樹脂組成物を有する配線材、ケーブル及び成形品 |
JP2017521514A (ja) | 2014-06-27 | 2017-08-03 | ダウ グローバル テクノロジーズ エルエルシー | 安定化された水分硬化性ポリマー組成物 |
Also Published As
Publication number | Publication date |
---|---|
US20210238397A1 (en) | 2021-08-05 |
KR20210005002A (ko) | 2021-01-13 |
CN111971328B (zh) | 2024-03-12 |
CA3097342A1 (en) | 2019-10-31 |
RU2020134374A (ru) | 2022-04-20 |
WO2019209546A1 (en) | 2019-10-31 |
EP3784721A1 (en) | 2021-03-03 |
CN111971328A (zh) | 2020-11-20 |
EP3784721B1 (en) | 2023-09-27 |
MX2020010196A (es) | 2020-10-20 |
JP2021521289A (ja) | 2021-08-26 |
US11767419B2 (en) | 2023-09-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2478042B1 (en) | Crosslinked, melt-shaped articles and compositions for producing same | |
CA2861113C (en) | Thermoplastic, semiconductive compositions | |
JP2010531918A (ja) | 柔軟性が増大したケーブルの絶縁のためのポリオレフィンエラストマー及びシランコポリマーの架橋可能なブレンド配合物 | |
KR20180008487A (ko) | 폴리올레핀의 실란 가교결합을 위한 경화 조절 첨가제로서 하이드록실-말단화된 pdms | |
JP5331900B2 (ja) | エチレン−ビニルシランコポリマーの湿分硬化用触媒系 | |
CN111936567B (zh) | 电线和电缆涂料用发泡聚烯烃组合物 | |
JP7466458B2 (ja) | ワイヤおよびケーブルコーティング用非発泡ポリオレフィン組成物 | |
KR102681959B1 (ko) | 와이어 및 케이블 코팅용 비 발포 폴리올레핀 조성물 | |
JP2022514957A (ja) | ワイヤおよびケーブルコーティング用固体架橋ポリオレフィン組成物 | |
BR112020020688B1 (pt) | Composição misturada por fusão, composição reticulada, bainha de fio ou cabo e fio ou cabo | |
BR112020020688A2 (pt) | Composições de poliolefina não espumantes para revestimento de fios e cabos | |
WO2023049127A1 (en) | Halogen free flame retardant polymeric compositions |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
RD03 | Notification of appointment of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7423 Effective date: 20201023 |
|
RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20210205 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20220328 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20230323 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20230404 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20230704 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20231010 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20240105 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20240326 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20240402 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 7466458 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |