JP7420958B2 - 熱可塑性樹脂組成物、その製造方法及びそれを含む成形品 - Google Patents
熱可塑性樹脂組成物、その製造方法及びそれを含む成形品 Download PDFInfo
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- JP7420958B2 JP7420958B2 JP2022551739A JP2022551739A JP7420958B2 JP 7420958 B2 JP7420958 B2 JP 7420958B2 JP 2022551739 A JP2022551739 A JP 2022551739A JP 2022551739 A JP2022551739 A JP 2022551739A JP 7420958 B2 JP7420958 B2 JP 7420958B2
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Classifications
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- B29B7/40—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft
- B29B7/42—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft with screw or helix
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- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
- B29B7/48—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
- B29K2067/003—PET, i.e. poylethylene terephthalate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29K2083/00—Use of polymers having silicon, with or without sulfur, nitrogen, oxygen, or carbon only, in the main chain, as moulding material
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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Description
本出願は、2020年12月11日付の韓国特許出願第10-2020-0173178号及びこれに基づいて2021年12月09日付で再出願された韓国特許出願第10-2021-0175415号に基づく優先権の利益を主張し、当該韓国特許出願の文献に開示された全ての内容は本明細書の一部として組み込まれる。
前記(A)ポリカーボネート樹脂は、前記熱可塑性樹脂組成物の総100重量%中に30~60重量%含まれ、好ましくは33~55重量%、より好ましくは35~50重量%含まれてもよく、この場合に、他の物性の低下なしに、成形加工性及び機械的剛性がより優れるという利点がある。
前記(B)ポリオルガノシロキサン-ポリカーボネート樹脂(以下、「(B)樹脂」という)は、前記熱可塑性樹脂組成物の総100重量%中に25~50重量%含まれ、好ましくは25~45重量%、より好ましくは25~40重量%含まれてもよく、この場合に、機械的物性、成形加工性及び耐熱性に優れると同時に、広い温度及び湿度範囲で耐摩擦騒音特性に優れるという利点がある。
前記(C)ビニルシアン化合物-共役ジエンゴム-芳香族ビニル化合物共重合体(以下、「(C)共重合体」という)は、前記熱可塑性樹脂組成物の総100重量%中に10~20重量%含まれ、好ましくは12~20重量%、より好ましくは15~20重量%含まれてもよく、この範囲内で、機械的物性、成形加工性及び物性バランスに優れるという利点がある。前記(C)共重合体はまた、好ましい一例として13~18重量%、より好ましくは15~17重量%含まれてもよく、この範囲内で、成形加工性及び曲げ特性がより優れるという利点がある。
前記(D)ポリエステル樹脂は、前記熱可塑性樹脂組成物の総100重量%中に1~10重量%含まれ、好ましくは2~8重量%、より好ましくは3~7重量%含まれてもよく、この場合に、他の物性の低下なしに、成形加工性、及び、広い温度及び湿度範囲での耐摩擦騒音特性に優れるという利点がある。
前記(E)エポキシ基含有樹脂は、前記熱可塑性樹脂組成物の総100重量%中に2~5重量%含まれ、この範囲内で、他の物性の低下なしに、成形加工性及び耐摩擦騒音特性に優れるという利点がある。
前記熱可塑性樹脂組成物は、選択的に(F)衝撃補強剤を含むことができ、この場合に、他の物性の低下なしに、機械的物性がより優れるという利点がある。
本発明の熱可塑性樹脂組成物は、(A)ISO 1133に準拠して測定した流動指数(300℃、1.2kgの荷重)が25~35g/10minであるポリカーボネート樹脂30~60重量%と、(B)ポリオルガノシロキサン-ポリカーボネート樹脂25~50重量%と、(C)ビニルシアン化合物-共役ジエンゴム-芳香族ビニル化合物共重合体10~20重量%と、(D)ポリエステル樹脂1~10重量%と、(E)エポキシ基含有樹脂2~5重量%とを含むことを特徴とし、この場合に、機械的強度、成形加工性及び耐熱性に優れ、特に、広い温度及び湿度範囲で耐摩擦騒音特性に優れるという効果がある。
RPN 1以上3以下:良好(摩擦騒音の発生可能性が非常に低い)
RPN 4以上5以下:部分的に良好
RPN 6以上10以下:良くない
本発明の熱可塑性樹脂組成物は、(A)ISO 1133に準拠して測定した流動指数(300℃、1.2kgの荷重)が25~35g/10minであるポリカーボネート樹脂30~60重量%と、(B)ポリオルガノシロキサン-ポリカーボネート樹脂25~50重量%と、(C)ビニルシアン化合物-共役ジエンゴム-芳香族ビニル化合物共重合体10~20重量%と、(D)ポリエステル樹脂1~10重量%と、(E)エポキシ基含有樹脂2~5重量%とを含んで、200~300℃で混練及び押出するステップを含んで製造されることを特徴とする。この場合に、機械的物性、成形加工性、耐熱性及び耐摩擦騒音特性がいずれも優れるという効果がある。
本発明の成形品は、本記載の熱可塑性樹脂組成物を含むことを特徴とし、この場合に、機械的物性、成形加工性及び耐熱性と同時に、広い温度/湿度範囲で耐摩擦騒音特性が優れるという効果がある。
下記の実施例及び比較例で使用された物質は、次の通りである。
(A-2)ポリカーボネート樹脂:ISO 1133に準拠して測定した流動指数(300℃、1.2kgの荷重)が22g/10minであるビスフェノールA型PC樹脂(重量平均分子量10,000g/mol、固有粘度(25℃)0.9dl/g)
(B)ポリオルガノシロキサン-ポリカーボネート樹脂:ISO 1133に準拠して測定した流動指数(300℃、1.2kgの荷重)が0.8g/10minであり、ポリジメチルシロキサン単位を30重量%含むポリオルガノシロキサン-ポリカーボネート樹脂(重量平均分子量100,000g/mol)
(C)ビニルシアン化合物-共役ジエンゴム-芳香族ビニル化合物共重合体:平均粒径が1μmであるブタジエンゴム10重量%、アクリロニトリル28重量%及びスチレン62重量%を含むABS樹脂(重量平均分子量300,000g/mol)
(D)ポリエステル樹脂:固有粘度(25℃)1.2dl/gであるポリブチレンテレフタレート(重量平均分子量15,000g/mol)
(E)エポキシ基含有樹脂:グリシジルメタクリレート単位12重量%、及びビニルアセテート単位5重量%を含むエチレン系共重合体(重量平均分子量50,000g/mol)
(F)衝撃補強剤:ブタジエンゴム及びメタクリレートを含むコア-シェル構造のMMA-BD系衝撃補強剤(LG化学社のEM520)
(A-1)又は(A-2)のポリカーボネート樹脂、(B)ポリオルガノシロキサン-ポリカーボネート樹脂、(C)共重合体、(D)ポリエステル樹脂、(E)エポキシ基含有樹脂及び(F)衝撃補強剤を、下記の表1及び表2に示した含量でスーパーミキサー(super mixer)を用いて混合し、二軸押出機(twin-screw extruder、スクリュー直径26mm、L/D=40)で押出温度260℃及びスクリュー回転速度250rpmの押出条件で押出してペレット状に製造した。
前記実施例及び比較例で製造された試験片の物性を下記のような方法で測定し、その結果を下記表3及び表4に示した。
RPN 1以上3以下:良好(摩擦騒音の発生可能性が非常に低い)
RPN 4以上5以下:部分的に良好
RPN 6以上10以下:良くない
Claims (15)
- (A)ISO 1133に準拠して測定した流動指数(300℃、1.2kgの荷重)が25~35g/10minであるポリカーボネート樹脂30~60重量%と、
(B)ポリオルガノシロキサン-ポリカーボネート樹脂25~50重量%と、
(C)ビニルシアン化合物-共役ジエンゴム-芳香族ビニル化合物共重合体10~20重量%と、
(D)ポリエステル樹脂1~10重量%と、
(E)エポキシ基含有樹脂2~5重量%とを含み、
前記(B)樹脂と(D)樹脂は、重量比(B:D)が3:1~15:1である、
熱可塑性樹脂組成物。 - 前記熱可塑性樹脂組成物は、ISO 178に準拠して、23℃、試験片の厚さ4mm、間隔(span)64mm及び試験速度2mm/minの条件下で測定した曲げ強度が78MPa以上である、請求項1に記載の熱可塑性樹脂組成物。
- 前記熱可塑性樹脂組成物は、ISO 178に準拠して、23℃、試験片の厚さ4mm、間隔(span)64mm及び試験速度2mm/minの条件下で測定した曲げ弾性率が2,110MPa以上である、請求項1または2に記載の熱可塑性樹脂組成物。
- 前記熱可塑性樹脂組成物は、ISO 75に準拠して、1.8MPaの条件下で測定した熱変形温度(HDT)が95℃以上である、請求項1~3のいずれか一項に記載の熱可塑性樹脂組成物。
- 前記(A)ポリカーボネート樹脂は、線状ポリカーボネート樹脂、分岐状(branched)ポリカーボネート樹脂及びポリエステルカーボネート共重合体樹脂からなる群から選択された1種以上である、請求項1~4のいずれか一項に記載の熱可塑性樹脂組成物。
- 前記(A)ポリカーボネート樹脂は、重量平均分子量が10,000~30,000g/molである、請求項1~5のいずれか一項に記載の熱可塑性樹脂組成物。
- 前記(B)樹脂は、ポリオルガノシロキサン単位を25~45重量%含む、請求項1~6のいずれか一項に記載の熱可塑性樹脂組成物。
- 前記(B)樹脂は、ISO 1133に準拠して測定した流動指数(300℃、1.2kgの荷重)が0.5~4g/10minである、請求項1~7のいずれか一項に記載の熱可塑性樹脂組成物。
- 前記(C)共重合体は、平均粒径0.8~1.5μmの共役ジエンゴムが、前記(C)共重合体の総重量に対して3~12重量%含まれる、請求項1~8のいずれか一項に記載の熱可塑性樹脂組成物。
- 前記(B)樹脂と(C)共重合体は、重量比(B:C)が2:1~4:1である、請求項1~9のいずれか一項に記載の熱可塑性樹脂組成物。
- 前記(D)ポリエステル樹脂は、ポリエチレンアジペート(PEA)、ポリブチレンサクシネート(PBS)、ポリエチレンテレフタレート(PET)、ポリブチレンテレフタレート(PBT)、ポリトリメチレンテレフタレート(PTT)及びポリエチレンナフタレート(PEN)からなる群から選択される1種以上である、請求項1~10のいずれか一項に記載の熱可塑性樹脂組成物。
- 前記(D)ポリエステル樹脂は、25℃及びメチレンクロライド溶媒の条件下で測定した固有粘度が1.0~1.5dl/gである、請求項1~11のいずれか一項に記載の熱可塑性樹脂組成物。
- 前記熱可塑性樹脂組成物は、共役ジエンゴム40~60重量%及び(メタ)アクリレート系化合物40~60重量%を含んでなる衝撃補強剤を含む、請求項1~12のいずれか一項に記載の熱可塑性樹脂組成物。
- (A)ISO 1133に準拠して測定した流動指数(300℃、1.2kgの荷重)が25~35g/10minであるポリカーボネート樹脂30~60重量%と、(B)ポリオルガノシロキサン-ポリカーボネート樹脂25~50重量%と、(C)ビニルシアン化合物-共役ジエンゴム-芳香族ビニル化合物共重合体10~20重量%と、(D)ポリエステル樹脂1~10重量%と、(E)エポキシ基含有樹脂2~5重量%とを含んで、200~300℃で混練及び押出するステップを含む、熱可塑性樹脂組成物の製造方法。
- 請求項1~13のいずれか一項に記載の熱可塑性樹脂組成物を含む、成形品。
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US20150353732A1 (en) * | 2014-06-09 | 2015-12-10 | Sabic Global Technologies B.V. | Impact improved filled polycarbonate or polyester compositions |
KR101741174B1 (ko) * | 2015-12-23 | 2017-05-30 | 주식회사 삼양사 | 내화학성 및 충격 특성이 우수한 폴리카보네이트 수지 조성물 및 이를 포함하는 성형품 |
KR102138701B1 (ko) * | 2018-11-30 | 2020-07-29 | 주식회사 삼양사 | 내화학성, 기계적 물성 및 내광성이 우수한 고광택 폴리카보네이트 수지 조성물 및 이를 포함하는 성형품 |
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US20130190425A1 (en) | 2012-01-19 | 2013-07-25 | Yantao Zhu | Polycarbonate-polyester compositions, methods of manufacture, and articles thereof |
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