JP7405617B2 - 糖溶液の処理 - Google Patents
糖溶液の処理 Download PDFInfo
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- JP7405617B2 JP7405617B2 JP2019557423A JP2019557423A JP7405617B2 JP 7405617 B2 JP7405617 B2 JP 7405617B2 JP 2019557423 A JP2019557423 A JP 2019557423A JP 2019557423 A JP2019557423 A JP 2019557423A JP 7405617 B2 JP7405617 B2 JP 7405617B2
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- 235000000346 sugar Nutrition 0.000 title claims description 27
- 239000011347 resin Substances 0.000 claims description 111
- 229920005989 resin Polymers 0.000 claims description 111
- 239000002245 particle Substances 0.000 claims description 93
- 229920000642 polymer Polymers 0.000 claims description 68
- 239000007864 aqueous solution Substances 0.000 claims description 58
- 238000000034 method Methods 0.000 claims description 35
- 229920002554 vinyl polymer Polymers 0.000 claims description 31
- 125000003277 amino group Chemical group 0.000 claims description 30
- 239000000178 monomer Substances 0.000 claims description 27
- 150000002772 monosaccharides Chemical class 0.000 claims description 15
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 14
- 239000007787 solid Substances 0.000 claims description 14
- 125000003118 aryl group Chemical group 0.000 claims description 10
- 125000004429 atom Chemical group 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 7
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 3
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 239000000243 solution Substances 0.000 description 17
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 14
- 239000000203 mixture Substances 0.000 description 14
- 235000019534 high fructose corn syrup Nutrition 0.000 description 10
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 10
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000008103 glucose Substances 0.000 description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 238000004042 decolorization Methods 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 229930091371 Fructose Natural products 0.000 description 5
- 239000005715 Fructose Substances 0.000 description 5
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 5
- 239000003463 adsorbent Substances 0.000 description 5
- 150000001721 carbon Chemical group 0.000 description 5
- 239000003361 porogen Substances 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000005727 Friedel-Crafts reaction Methods 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical group Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- CZMRCDWAGMRECN-UHFFFAOYSA-N Rohrzucker Natural products OCC1OC(CO)(OC2OC(CO)C(O)C(O)C2O)C(O)C1O CZMRCDWAGMRECN-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 238000005576 amination reaction Methods 0.000 description 4
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000010828 elution Methods 0.000 description 4
- 230000003204 osmotic effect Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- 238000005349 anion exchange Methods 0.000 description 3
- 239000011324 bead Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 125000003636 chemical group Chemical group 0.000 description 3
- 125000004970 halomethyl group Chemical group 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 125000001302 tertiary amino group Chemical group 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- 101710134784 Agnoprotein Proteins 0.000 description 2
- 235000016068 Berberis vulgaris Nutrition 0.000 description 2
- 241000335053 Beta vulgaris Species 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- 240000000111 Saccharum officinarum Species 0.000 description 2
- 235000007201 Saccharum officinarum Nutrition 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 238000005341 cation exchange Methods 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 150000002016 disaccharides Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920001542 oligosaccharide Polymers 0.000 description 2
- 150000002482 oligosaccharides Chemical class 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- OBQPKGCVMCIETH-UHFFFAOYSA-N 1-chloro-1-(1-chloroethoxy)ethane Chemical compound CC(Cl)OC(C)Cl OBQPKGCVMCIETH-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical class C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical class CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical class C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 239000003957 anion exchange resin Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical group ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 235000010633 broth Nutrition 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000012539 chromatography resin Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 125000006222 dimethylaminomethyl group Chemical group [H]C([H])([H])N(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- -1 ethylene, ethylene Chemical class 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000002386 heptoses Chemical class 0.000 description 1
- 150000002402 hexoses Chemical class 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 239000013461 intermediate chemical Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000002972 pentoses Chemical class 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229960004793 sucrose Drugs 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 150000003538 tetroses Chemical class 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 150000003641 trioses Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K1/00—Glucose; Glucose-containing syrups
- C13K1/06—Glucose; Glucose-containing syrups obtained by saccharification of starch or raw materials containing starch
- C13K1/08—Purifying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/12—Macromolecular compounds
- B01J41/14—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
- C13B20/00—Purification of sugar juices
- C13B20/14—Purification of sugar juices using ion-exchange materials
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
- C13B20/00—Purification of sugar juices
- C13B20/14—Purification of sugar juices using ion-exchange materials
- C13B20/146—Purification of sugar juices using ion-exchange materials using only anionic ion-exchange material
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K1/00—Glucose; Glucose-containing syrups
- C13K1/02—Glucose; Glucose-containing syrups obtained by saccharification of cellulosic materials
- C13K1/04—Purifying
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Description
水溶液は、水溶液の重量を基準として10重量%~50重量%の量の溶解している糖固体を含み、
溶解している糖固体は、溶解している糖固体の重量を基準として1重量%~99重量%の量の単糖を含有し、
水溶液は、100~10,000μS/cmのイオン導電率及び100~10,000国際色度の色成分を有し、
方法は、水溶液を樹脂粒子の集合体と接触させることを含み、
樹脂粒子は、1種以上のポリマーを含み、
ポリマーは、芳香環間にメチレン架橋基を含み、
ポリマーは、樹脂粒子に結合されているアミノ基を含み、
樹脂粒子は、樹脂粒子の集合体の重量を基準として53重量%~60重量%の水の保水能力を有する、方法である。
WRC(%)=100*(Wm-Wd)/Wm
によって与えられる。
TEC=10*(Va-Vblank)*Na/Vm
SBC=10*(Vb-Vblank)*Na/Vm
=樹脂1リットル当たりの四級アンモニウム基の当量
WBC=TEC-SBC=樹脂1リットル当たりのアミノ基の当量
ICU=1000*(420nmでの吸光度)/[(経路長)*(糖の濃度)]
糖の濃度=Brix/[100*(g/cm3)単位での密度]
である。上で計算したICUMSA価は、国際色度についてのICUとして報告される。
脱色=(CA-CB)/CA
式中、CAは、カラムに入る前のICUMSA色であり、CBは、カラムを出た後のICUMSA色である。脱色は、50BVで測定された。
脱色は、上述した通りに行った。結果は、次の通りである。「x」は、「測定せず」を意味する。
浸透安定性を試験した。結果は、次の通りである。
Claims (4)
- 水溶液を処理する方法であって、
前記水溶液は、前記水溶液の重量を基準として10重量%~50重量%の量の溶解している糖固体を含み、
前記溶解している糖固体は、前記溶解している糖固体の重量を基準として1重量%~99重量%の量の単糖を含有し、
前記水溶液は、100~10,000μS/cmのイオン導電率及び100~10,000国際色度の色成分を有し、
前記方法は、前記水溶液を樹脂粒子の集合体と接触させることを含み、
前記樹脂粒子は、1種以上のビニル芳香族ポリマーを含み、かつ、全てのビニル芳香族モノマーの重合した単位の総重量は、ポリマーの90重量%以上であり、
前記ポリマーは、芳香環間にメチレン架橋基を含み、かつ、前記メチレン架橋基は、前記樹脂粒子の総乾燥重量を基準として4重量%以下のメチレン架橋基の量で存在し、
前記ポリマーは、前記樹脂粒子に結合されているアミノ基を含み、かつ、前記樹脂粒子に結合されているアミノ基の総量は樹脂粒子の集合体1リットル当たり1.2~1.6当量であり、ここで、該アミノ基は、構造-NR 1 R 2 又は構造-N + HR 1 R 2 を有し、当該開放結合は、ポリマーの主鎖上の原子に直接又は間接的に連結しており、各R 1 及びR 2 は無置換のアルキル基であり、さらにR 1 とR 2 はいずれも、上記構造中の開放結合を介した該アミノ基の当該窒素原子を介する以外に、該ポリマーの主鎖の原子に直接又は間接的に結合することはなく、
前記ポリマーは、前記樹脂粒子の集合体1リットル当たり0.14~0.2当量の量の四級アンモニウム基を有し、
前記樹脂粒子は、前記樹脂粒子の集合体の重量を基準として53重量%~60重量%の水の保水能力を有し、かつ、
前記樹脂粒子は、窒素ガスを使用するブルナウアー-エメット-テラー(BET)法で測定された比表面積10m 2 /g~100m 2 /gを有することを特徴とする、方法。 - 前記樹脂粒子の集合体は、1.1未満の商(均等係数UC)D60/D10を有する、ここでD60は、当該樹脂粒子の60体積%がD60未満の直径を有し、当該樹脂粒子の40体積%がD60以上の直径を有し、かつ、D10は、当該樹脂粒子の10体積%がD10未満の直径を有し、当該樹脂粒子の90体積%がD10以上の直径を有する、請求項1に記載の方法。
- 前記樹脂粒子の集合体から前記水溶液を分離する後続の工程を更に含む、請求項1に記載の方法。
- 前記水溶液を前記樹脂粒子の集合体と接触させる工程は、前記水溶液を前記樹脂粒子の集合体の固定床に通すことによって行われる、請求項1に記載の方法。
Priority Applications (1)
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JP2022204019A JP2023038196A (ja) | 2017-04-28 | 2022-12-21 | 糖溶液の処理 |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201762491390P | 2017-04-28 | 2017-04-28 | |
US62/491,390 | 2017-04-28 | ||
PCT/US2018/029274 WO2018200617A1 (en) | 2017-04-28 | 2018-04-25 | Treatment of sugar solutions |
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JP2022204019A Division JP2023038196A (ja) | 2017-04-28 | 2022-12-21 | 糖溶液の処理 |
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JP2020518441A JP2020518441A (ja) | 2020-06-25 |
JP7405617B2 true JP7405617B2 (ja) | 2023-12-26 |
Family
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JP3112500B2 (ja) | 1991-06-04 | 2000-11-27 | 株式会社東芝 | 低音再生用スピーカ装置 |
WO2016144567A1 (en) | 2015-03-12 | 2016-09-15 | Dow Global Technologies Llc | Chromatographic separation of saccharides using polymeric macroporous alkylene-bridged resin |
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JPS5910800B2 (ja) * | 1974-04-25 | 1984-03-12 | 東京有機化学工業株式会社 | 糖液脱色用アニオン交換樹脂 |
WO1989008718A1 (en) * | 1988-03-17 | 1989-09-21 | The Dow Chemical Company | Process for decolorizing aqueous sugar solutions via adsorbent resins, and desorption of color bodies from the adsorbent resins |
US4950332A (en) * | 1988-03-17 | 1990-08-21 | The Dow Chemical Company | Process for decolorizing aqueous sugar solutions via adsorbent resins, and desorption of color bodies from the adsorbent resins |
US4871397A (en) * | 1988-05-09 | 1989-10-03 | The Dow Chemical Company | Process for decolorizing aqueous sugar solution |
JPH03112500A (ja) * | 1988-08-03 | 1991-05-14 | Dow Chem Co:The | 糖水溶液の脱色法 |
GB8905934D0 (en) * | 1989-03-15 | 1989-04-26 | Dow Europ Sa | A process for preparing adsorptive porous resin beads |
DE10056193A1 (de) | 2000-11-13 | 2002-05-29 | Bayer Ag | Zuckersaftentfärbung mittels monodisperser Anionenaustauscher |
CN105247078B (zh) * | 2013-05-28 | 2022-02-08 | 罗门哈斯公司 | 去除糖溶液中的杂质 |
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JP3112500B2 (ja) | 1991-06-04 | 2000-11-27 | 株式会社東芝 | 低音再生用スピーカ装置 |
WO2016144567A1 (en) | 2015-03-12 | 2016-09-15 | Dow Global Technologies Llc | Chromatographic separation of saccharides using polymeric macroporous alkylene-bridged resin |
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J.Sep.Sci.,2001,Vol.24,P.477-478 |
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CN110536970A (zh) | 2019-12-03 |
EP3615698A1 (en) | 2020-03-04 |
WO2018200617A1 (en) | 2018-11-01 |
JP2023038196A (ja) | 2023-03-16 |
EP3615698B1 (en) | 2024-04-03 |
CN110536970B (zh) | 2023-11-17 |
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