JP7355728B2 - 燃料添加剤を生成する方法 - Google Patents
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Description
Claims (20)
- 燃料添加剤を生成する方法であって、
少なくともイソブチレン及びブタジエンを含む供給ストリームを、メチルターシャリーブチルエーテルユニットに通過させ、少なくともブタジエンを含む第1のプロセスストリーム及びメチルターシャリーブチルエーテル生成物を生成する工程、
前記第1のプロセスストリームを、選択的水素化ユニットに通過させ、1-ブテン、2-ブテン及びn-ブテンのうちの少なくとも1つを含む第2のプロセスストリームを生成する工程、
前記第2のプロセスストリームを異性化ユニットに通過させ、少なくとも2-ブテンを含む第3のプロセスストリームを生成する工程、および
前記第3のプロセスストリームを水和ユニットに通過させ、アルコール燃料添加剤と、イソブタン、n-ブタン及びイソブチレンのうちの少なくとも1つを含むリサイクルストリームと、を生成する工程
を含む、方法。 - 供給ストリーム源は接触分解プロセスおよび/またはオレフィン生成プロセスの生成物を含む、請求項1に記載の方法。
- 前記供給ストリームは、イソブチレン、1,3-ブタジエン及び1,2-ブタジエンを含み、さらに、エチルアセチレン、ビニルアセチレン、cis-2-ブテン、trans-2-ブテン、1-ブテン、イソブタン、n-ブタン、または前記の少なくとも1つを含む組み合わせを含む、請求項1又は2に記載の方法。
- 前記供給ストリーム中に存在するイソブチレンの99.99%以下が、前記メチルターシャリーブチルエーテルユニット内でメチルターシャリーブチルエーテルに変換される、請求項1~3のいずれか1項に記載の方法。
- 前記メチルターシャリーブチルエーテルユニットから前記メチルターシャリーブチルエーテル生成物を引き出す工程をさらに含む、請求項4に記載の方法。
- 前記第1のプロセスストリーム中に存在するブタジエンの90%以上が、前記選択的水素化ユニット内で、1-ブテン、2-ブテン、n-ブタン、または前記の少なくとも1つを含む組み合わせに変換される、請求項1~5のいずれか1項に記載の方法。
- 前記選択的水素化ユニットは第1の反応器内の第1の触媒および第2の反応器内の第2の触媒を含む、請求項1~6のいずれか1項に記載の方法。
- 前記選択的水素化ユニットに通過させる前に、水素を前記第1のプロセスストリームに添加する工程をさらに含む、請求項1~7のいずれか1項に記載の方法。
- 前記第2のプロセスストリーム中に存在する1-ブテンの90%以上が前記異性化ユニット内で2-ブテンに変換される、請求項1~8のいずれか1項に記載の方法。
- 前記第3のプロセスストリームは、前記水和ユニットを通過する前に、0.1重量%以下のブタジエンを含む、請求項1~9のいずれか1項に記載の方法。
- 前記第3のプロセスストリームは、前記水和ユニットを通過する前に、0.01重量%以上、好ましくは、0.25重量%から50重量%の1-ブテンおよび/または2-ブテンを含む、請求項1~10のいずれか1項に記載の方法。
- 前記水和ユニットは、振動バッフル反応器、固定床反応器、メンブレン一体化反応器、または前記の少なくとも1つを含む組み合わせを含む、請求項1~11のいずれか1項に記載の方法。
- 前記第3のプロセスストリーム中に存在するブテンの99.9重量%未満、好ましくは75重量%以上が、前記水和ユニット内でブタノールに変換される、請求項1~12のいずれか1項に記載の方法。
- 前記燃料添加剤を前記水和ユニットから引き出す工程をさらに含む、請求項1~13のいずれか1項に記載の方法。
- 前記燃料添加剤は、2-ブタノール、tert-ブチルアルコール、または前記の少なくとも1つを含む組み合わせを含む、請求項14に記載の方法。
- 前記燃料添加剤は、1.0重量%以上、好ましくは0.1から25重量%、より好ましくは1から20重量%のトリメチルペンタンを含む、請求項14に記載の方法。
- 前記燃料添加剤のオクタン価は、アンチノック指数によれば、80超、好ましくは82超、より好ましくは85超、より好ましくは87超、さらにいっそう好ましくは90超である、請求項14に記載の方法。
- 前記燃料添加剤のリード蒸気圧は65キロパスカル以下である、請求項14に記載の方法。
- 前記異性化ユニットの底部ストリームをメタセシスユニットに通過させ、プロピレン生成物を前記メタセシスユニットから引き出す工程をさらに含む、請求項1~18のいずれか1項に記載の方法。
- 燃料添加剤を生成する方法であって、
C4炭化水素を含む第1の供給ストリームを接触分解ユニットに通過させ、第2の供給ストリームを生成する工程であって、前記第1の供給ストリームはエチルアセチレン、ビニルアセチレン、1,3-ブタジエン、1,2-ブタジエン、イソブチレン、cis-2-ブテン、trans-2-ブテン、1-ブテン、イソブタン、n-ブタン、または前記の少なくとも1つを含む組み合わせを含み、前記第2の供給ストリームは少なくともイソブチレン、ブタジエンを含む工程、
前記第2の供給ストリームをメチルターシャリーブチルエーテルユニットに通過させ、第1のプロセスストリームおよびメチルターシャリーブチルエーテル生成物を生成し、前記メチルターシャリーブチルエーテル生成物を前記メチルターシャリーブチルエーテルユニットから引き出す工程であって、前記供給ストリーム中に存在するイソブチレンの99.99%未満が、前記メチルターシャリーブチルエーテルユニット内でメチルターシャリーブチルエーテルに変換される工程、
前記第1のプロセスストリームを水素化ユニットに通過させ、第2のプロセスストリームを生成する工程であって、前記第1のプロセスストリーム中に存在するブタジエンの90%以上が、前記水素化ユニット内で2-ブテン、1-ブテンおよびn-ブタンに変換される工程、
前記第2のプロセスストリームを異性化ユニットに通過させ、第3のプロセスストリームを生成する工程であって、前記第2のプロセスストリーム中に存在する1-ブテンの99.99%以下が前記異性化ユニット内で2-ブテンに変換される工程、
前記第3のプロセスストリームを水和ユニットに通過させる工程であって、前記第3のプロセスストリームは、前記水和ユニットを通過する前に0.1重量%以下のブタジエンを含む工程、
燃料添加剤生成物を前記水和ユニットから引き出す工程であって、前記燃料添加剤生成物は0.1重量%超のトリメチルペンタンを含む工程、
ラフィネートストリームを前記水和ユニットから引き出し、前記ラフィネートストリームを前記接触分解ユニットにリサイクルする工程、および
前記異性化ユニットの底部ストリームをメタセシスユニットに通過させ、プロピレン生成物を前記メタセシスユニットから引き出す工程
を含む、方法。
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CN111801404A (zh) | 2018-03-19 | 2020-10-20 | 沙特基础工业全球技术有限公司 | 生产燃料添加剂的方法 |
US11248181B2 (en) | 2018-04-19 | 2022-02-15 | Sabic Global Technologies B.V. | Method of producing a fuel additive |
WO2019217050A1 (en) | 2018-05-07 | 2019-11-14 | Sabic Global Technologies B.V. | Method of producing a fuel additive |
EP3790854A1 (en) | 2018-05-07 | 2021-03-17 | SABIC Global Technologies B.V. | Method of producing a fuel additive |
US11697626B2 (en) | 2018-05-18 | 2023-07-11 | Sabic Global Technologies B.V. | Method of producing a fuel additive with a hydration unit |
WO2020058825A1 (en) | 2018-09-18 | 2020-03-26 | Sabic Global Technologies B.V. | Systems and processes for efficient production of one or more fuel additives |
WO2020104967A1 (en) | 2018-11-20 | 2020-05-28 | Sabic Global Technologies B.V. | Process and system for producing ethylene and at least one of butanol and an alkyl tert-butyl ether |
US20220185750A1 (en) * | 2019-03-08 | 2022-06-16 | Sabic Global Technologies B.V. | Method of producing a fuel additive |
US11236031B2 (en) | 2020-02-12 | 2022-02-01 | Saudi Arabian Oil Company | Integrated process for the production of isononanol and gasoline and diesel blending components |
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JP2017508725A (ja) | 2014-02-11 | 2017-03-30 | サウジ アラビアン オイル カンパニー | 燃料混合成分としての混合ブタノールおよびジイソブテンの生成方法 |
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