JP7207617B1 - 2液硬化型接着性組成物、アンカーコート剤、接着剤、積層体、包装材 - Google Patents
2液硬化型接着性組成物、アンカーコート剤、接着剤、積層体、包装材 Download PDFInfo
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- JP7207617B1 JP7207617B1 JP2022547723A JP2022547723A JP7207617B1 JP 7207617 B1 JP7207617 B1 JP 7207617B1 JP 2022547723 A JP2022547723 A JP 2022547723A JP 2022547723 A JP2022547723 A JP 2022547723A JP 7207617 B1 JP7207617 B1 JP 7207617B1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/06—Polyurethanes from polyesters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/08—Polyurethanes from polyethers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/80—Packaging reuse or recycling, e.g. of multilayer packaging
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
Description
その一方で、ヒートシールにより袋を密閉する場合には、熱加工性に優れる無延伸のポリオレフィン類フィルムが必須であるが、無延伸ポリオレフィンフィルムには包装材料として不足している機能も多い。
本発明の2液硬化型接着性組成物は、ポリエステルポリオール(A1)と、ポリオール(A2)とを含むポリオール組成物(X)と、ポリイソシアネート化合物(C)を含むポリイソシアネート組成物(Y)とからなる。以下本発明の2液硬化型接着性組成物について詳述する。
本発明のポリオール組成物は、ポリエステルポリオール(A1)と、ポリオール(A2)とを必須成分として含む。以下本発明のポリオール組成物(X)について詳述する。
ポリエステルポリオール(A1)は、ポリエステルポリオール(A1)とキシレンジイソシアネートのトリメチロールプロパンアダクト体とを、[NCO]/[OH]が2±0.2で反応させたときの硬化塗膜の23℃0%RHにおける酸素透過率の3g/m2換算値が300cc/m2/day/atm以下である。[NCO]はXDI-TMPアダクト体が有するイソシアネート基のモル数であり、[OH]はポリエステルポリオール(A1)が有する水酸基のモル数である。酸素透過率はJIS-K7126(等圧法)に準じて測定する。なお以下ではキシレンジイソシアネートのトリメチロールプロパンアダクト体をXDI-TMPアダクト体ともいい、上記条件で測定したポリエステルポリオール(A1)の酸素透過率の3g/m2換算値をポリエステルポリオール(A1)の酸素透過率ともいう。
本発明に用いられるポリオール(A2)は、2以上の水酸基を有し、密度が1.2g/cm3以上であり、融点が20℃以上である化合物である。なおポリオール(A2)の密度は、20℃、1atmにおける値である。ポリエステルポリオール(A1)とポリオール(A2)とを併用することで、従来よりもガスバリア性に優れた無溶剤型接着剤とすることができる。ポリオール(A2)の密度の上限は特に限定されないが、一例として1.6g/cm3程度である。ポリオール(A2)の融点の上限は特に限定されないが、一例として120℃である。塗工適性の観点からは、80℃以下であることが好ましく、70℃以下であることがより好ましい。
ポリオール組成物(X)は、ガスバリア性を損なわない範囲でポリエステルポリオール(A1)、ポリオール(A2)以外の成分(B)を含んでいてもよい。成分(B)としては、無機充填剤(B1)、カップリング剤(B2)、酸無水物(B3)、酸素補足剤(B4)、リン酸類(B5)、粘着付与剤(B6)、ウレタン化触媒(B7)等が挙げられるがこれに限定されない。安定剤(酸化防止剤、熱安定剤、紫外線吸収剤等)、可塑剤、帯電防止剤、滑剤、ブロッキング防止剤、着色剤、結晶核剤、消泡剤、レベリング剤等を含んでいてもよい。
ポリオール組成物(X)がカップリング剤(B2)を含む場合、その配合量はポリオール組成物(X)全量の5質量%以下であることが好ましく、2質量%以上3質量%以下であることが好ましい。
ポリイソシアネート組成物(Y)は、イソシアネート化合物(C)を含む。イソシアネート化合物(C)としては、従来公知のものを特に制限なく用いることができ、テトラメチレンジイソシアネート、ヘキサメチレンジイソシアネート、トルエンジイソシアネート、ジフェニルメタンジイソシアネート、水素化ジフェニルメタンジイソシアネート、キシリレンジイソシアネート、水素化キシリレンジイソシアネート、イソホロンジイソシアネート或いはこれらのイソシアネート化合物の3量体、およびこれらのイソシアネート化合物の過剰量と、たとえばエチレングリコール、プロピレングリコール、メタキシリレンアルコール、1,3-ビスヒドロキシエチルベンゼン、1,4-ビスヒドロキシエチルベンゼン、トリメチロールプロパン、グリセロール、ペンタエリスリトール、エリスリトール、ソルビトール、エチレンジアミン、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、メタキシリレンジアミンなどの低分子活性水素化合物およびそのアルキレンオキシド付加物、ポリエステルポリオール類、ポリエーテルポリオール類、ポリアミド類の高分子活性水素化合物などと反応させて得られるアダクト体が挙げられる。
ポリイソシアネート組成物(Y)は、ガスバリア性を損なわない範囲でイソシアネート化合物(C)以外の成分(D)を含んでいてもよい。成分(D)としては、成分(B)と同様のものを用いることができる。また、ポリオール組成物(X)とポリイソシアネート組成物(Y)はそれぞれ同じ成分を含んでいてもよい。例えば、ポリオール組成物(X)とポリイソシアネート組成物(Y)がともにリン酸類を含んでいてもよい。
(2液硬化型接着剤)
本発明の2液硬化型接着剤は、上述したポリオール組成物(X)と、ポリイソシアネート組成物(Y)とを含み、ラミネート用途に好適である。本発明の接着剤はガスバリア性、塗工適性に優れ、また有機溶剤を含まないため溶剤排出の懸念がない。本発明の接着剤を用いることにより、金属や金属酸化物の蒸着層、金属箔等のバリア層を含まない場合であってもガスバリア性に優れた積層体を提供することができる。
本発明の積層体は、複数の基材(フィルム、紙など)を本発明の接着剤をノンソルベントラミネート法にて貼り合せて得られる。ラミネートされた積層体はガスバリア性に優れ、ガスバリア積層体として使用することができる。用いる基材に特に制限はなく、用途に応じて適宜選択することができる。例えば、食品包装用としては、ポリエチレンテレフタレート(PET)フィルム、ポリスチレンフィルム、ポリアミドフィルム、ポリアクリロニトリルフィルム、ポリエチレンフィルム(LLDPE:低密度ポリエチレンフィルム、HDPE:高密度ポリエチレンフィルム)やポリプロピレンフィルム(CPP:無延伸ポリプロピレンフィルム、OPP:二軸延伸ポリプロピレンフィルム)等のポリオレフィンフィルム、ポリビニルアルコールフィルム、エチレン-ビニルアルコール共重合体フィルム等が挙げられる。
(1)基材1/接着層1/シーラントフィルム
(2)基材1/接着層1/金属蒸着未延伸フィルム
(3)基材1/接着層1/金属蒸着延伸フィルム
(4)透明蒸着延伸フィルム/接着層1/シーラントフィルム
(5)基材1/接着層1/基材2/接着層2/シーラントフィルム
(6)基材1/接着層1/金属蒸着延伸フィルム/接着層2/シーラントフィルム
(7)基材1/接着層1/透明蒸着延伸フィルム/接着層2/シーラントフィルム
(8)基材1/接着層1/金属層/接着層2/シーラントフィルム
(9)基材1/接着層1/基材2/接着層2/金属層/接着層3/シーラントフィルム
(10)基材1/接着層1/金属層/接着層2/基材2/接着層3/シーラントフィルム
等が挙げられるがこれに限定されない。
(アンカーコート剤)
本発明のアンカーコート剤は、上述したポリオール組成物(X)と、ポリイソシアネート組成物(Y)とを含み、押出ラミネーションの接着補助剤として好適である。本発明のアンカーコート剤はガスバリア性、塗工適性に優れ、また有機溶剤を含まないため溶剤排出の懸念がない。本発明のアンカーコート剤を用いることにより、ガスバリア性に優れた基材を提供することができる。
本発明の積層体は、フィルムに予め40℃~100℃程度に加熱しておいた本発明のアンカーコート剤をラミネーターにより塗布し、エージング処理を行った後に、押出し機により溶融させたポリマー材料をラミネートすることにより得られる(押出しラミネーション法)。フィルムとしては、積層体1に用いるフィルムと同様のものを用いることができる。溶融させるポリマー材料としては、低密度ポリエチレン樹脂や直線状低密度ポリエチレン樹脂、エチレン-酢酸ビニル共重合体樹脂等のポリオレフィン系樹脂が好ましい。
本発明の積層体1、2は、食品や医薬品などの保護を目的とする多層包装材料として使用することができる。多層包装材料として使用する場合には、内容物や使用環境、使用形態に応じてその層構成は変化し得る。
<ポリエステルポリオール(A1)の合成>
(ポリエステルポリオール(A1-1))
攪拌機、窒素ガス導入管、スナイダー管、コンデンサーを備えたポリエステル反応容器に、エチレングリコール79.10部、無水フタル酸74.06部、アジピン酸73.07部及びチタニウムテトライソプロポキシド0.01部を仕込み、精留管上部温度が100℃を超えないように徐々に加熱して内温を220℃に保持した。酸価が1mgKOH/g以下になったところでエステル化反応を終了し、数平均分子量800の(A1-1)を得た。水酸基価は143.2mgKOH/g、酸素透過率は148.7cc/m2/day/atm以下であった。
攪拌機、窒素ガス導入管、スナイダー管、コンデンサーを備えたポリエステル反応容器に、エチレングリコール27.02部、1,3,5-トリス(2-ヒドロキシエチル)イソシアヌル酸110.4部、無水フタル酸62.60部を仕込み、精留管上部温度が100℃を超えないように徐々に加熱して内温を220℃に保持した。酸価が1mgKOH/g以下になったところでエステル化反応を終了し、数平均分子量450のポリエステルポリオール(A1-2)を得た。水酸基価は371.2mgKOH/g、酸素透過率は102.3cc/m2/day/atm以下であった。
攪拌機、窒素ガス導入管、スナイダー管、コンデンサーを備えたポリエステル反応容器に、エチレングリコール33.88部、1,3,5-トリス(2-ヒドロキシエチル)イソシアヌル酸98.86部、無水フタル酸67.26部を仕込み、精留管上部温度が100℃を超えないように徐々に加熱して内温を220℃に保持した。酸価が1mgKOH/g以下になったところでエステル化反応を終了し、数平均分子量420のポリエステルポリオール(A1-3)を得た。水酸基価は378.3mgKOH/g、酸素透過率は103.7cc/m2/day/atm以下であった。
攪拌機、窒素ガス導入管、スナイダー管、冷却コンデンサー、滴下漏斗を備えた反応容器にひまし油73.98部、ポリプロピレングリコール(分子量約4000)51.02部を入れて70℃に加熱しながら撹拌し、ミリオネートMN(4,4’-ジフェニルメタンジイソシアネートと2,4’-ジフェニルメタンジイソシアネートとの混合物)2.55部を、滴下漏斗を用いて滴下し、更に4時間撹拌し、ポリオール(AH1)を得た。水酸基価は115.0mgKOH/g、酸素透過率は300cc/m2/day/atmを超えるものであった。
(ウレタンプレポリマー(C2-1))
攪拌機、窒素ガス導入管、スナイダー管、コンデンサーを備えたポリエステル反応容器に、エチレングリコール92.00部、無水フタル酸118.50部、アジピン酸29.23部及びチタニウムテトライソプロポキシド0.01部を仕込み、精留管上部温度が100℃を超えないように徐々に加熱して内温を220℃に保持した。酸価が1mgKOH/g以下になったところでエステル化反応を終了し、数平均分子量500のポリエステルポリオール(c1-1)を得た。ポリエステルポリオール(c1-1)の酸素透過率は131.8cc/m2/day/atm以下であった。
攪拌機、窒素ガス導入管、スナイダー管、コンデンサーを備えたポリエステル反応容器に、エチレングリコール100.12部、無水フタル酸148.12部、及びチタニウムテトライソプロポキシド0.02部を仕込み、精留管上部温度が100℃を超えないように徐々に加熱して内温を220℃に保持した。酸価が1mgKOH/g以下になったところでエステル化反応を終了し、数平均分子量400のポリエステルポリオール(c1-2)を得た。ポリエステルポリオール(c1-2)の酸素透過率は104.6cc/m2/day/atm以下であった。
攪拌機、窒素ガス導入管、スナイダー管、冷却コンデンサー、滴下漏斗を備えた反応容器にキシリレンジイソシアネート114.91部を入れて70℃に加熱しながら撹拌し、ポリエステルポリオール(c1-2)を92.93部、滴下漏斗を用いて2時間かけて滴下し、更に4時間撹拌し、ウレタンプレポリマー(C2-3)を得た。JIS-K1603に従い測定したNCO%は15.3%であった。
攪拌機、窒素ガス導入管、スナイダー管、コンデンサーを備えたポリエステル反応容器に、エチレングリコール58.84部、1,3,5-トリス(2-ヒドロキシエチル)イソシアヌル酸57.88部、無水フタル酸83.30部を仕込み、精留管上部温度が100℃を超えないように徐々に加熱して内温を220℃に保持した。酸価が1mgKOH/g以下になったところでエステル化反応を終了し、数平均分子量380のポリエステルポリオール(c1-3)を得た。ポリエステルポリオール(c1-3)の酸素透過率は103.8cc/m2/day/atm以下であった。
攪拌機、窒素ガス導入管、スナイダー管、コンデンサーを備えたポリエステル反応容器に、エチレングリコール73.60部、1,3,5-トリス(2-ヒドロキシエチル)イソシアヌル酸25.06部、無水フタル酸101.36部を仕込み、精留管上部温度が100℃を超えないように徐々に加熱して内温を220℃に保持した。酸価が1mgKOH/g以下になったところでエステル化反応を終了し、数平均分子量360のポリエステルポリオール(c1-4)を得た。ポリエステルポリオール(c1-4)の酸素透過率は105.5cc/m2/day/atm以下であった。
攪拌機、窒素ガス導入管、スナイダー管、冷却コンデンサー、滴下漏斗を備えた反応容器にミリオネートMN(4,4’-ジフェニルメタンジイソシアネートと2,4’-ジフェニルメタンジイソシアネートとの混合物)114.00部を入れて70℃に加熱しながら撹拌し、ポリプロピレングリコール(分子量約400)28.16部、ポリプロピレングリコール(分子量約1000)58.44部を、滴下漏斗を用いて2時間かけて滴下し、更に4時間撹拌し、ウレタンプレポリマー(CH2)を得た。JIS-K1603に従い測定したNCO%は13.5%であった。なお、ウレタンプレポリマー(CH2)の合成に用いたポリプロピレングリコールはいずれも酸素透過率が300cc/m2/day/atmを超えるものであった。
合成したポリエステルポリオール(A1)、ポリオール(A2)を表1-4に占める比率で配合し、ポリエステルポリオール(A1)、ポリオール(A2)の総量に対して100ppmになるようにリン酸を添加しポリオール組成物(X)を調整した。また、イソシアネート化合物(C1)、ウレタンプレポリマー(C2)を、表1-4に示す比率で配合してポリイソシアネート組成物(Y)を調整した。ポリオール組成物(X)、ポリオール組成物(Y)を表1-4に示す比率で配合して実施例、比較例の接着剤を得た。なお表中におけるポリオール(A2)はイソソルビドであり、XDIはキシリレンジイソシアネートであり、MDIはミリオネートMN(4,4’-ジフェニルメタンジイソシアネートと2,4’-ジフェニルメタンジイソシアネートとの混合物)である。
実施例、比較例の接着剤を約70℃に加熱し、無溶剤用テストコーターを用いて、膜厚20μmのOPPフィルム(東洋紡(株)製「P2161」)塗膜量3.0g/m2となるように塗布し、次いで膜厚30μmのCPPフィルム(東洋紡(株)製「P1128」)と接着剤の塗布面とを貼り合わせた。50℃で4日間エージングを行い、実施例、比較例の積層体を得た。
(接着強度)
25℃の雰囲気下で引張試験機を用い、剥離速度を300mm/minに設定し、180°の剥離方法でOPPフィルムとCPPフィルム間の接着強度(N/15mm)を測定した。結果を表1-4にまとめた。
得られた積層体を10cm×10cmのサイズに調整し、OX-TRAN2/21(モコン社製:酸素透過率測定装置)を用い、JIS-K7126(等圧法)に準じ、23℃0%RHの雰囲気下で酸素透過率を測定した。なおRHとは、湿度を表す。実際に塗布された接着剤の塗膜量は一律ではないため、酸素透過率の実測値(cc/m2/day/atm)を、接着剤の塗布量が3g/m2であった場合に換算し、結果を表1-4にまとめた。
Claims (7)
- ポリエステルポリオール(A1)と、ポリオール(A2)とを含むポリオール組成物(X)と、ポリイソシアネート化合物(C)を含むポリイソシアネート組成物(Y)と、を含み、
前記ポリエステルポリオール(A1)は、前記ポリエステルポリオール(A1)とキシレンジイソシアネートのトリメチロールプロパンアダクト体とを、NCO/OHが2±0.2で反応させたときの硬化塗膜の23℃0%RHにおける酸素透過率の3g/m2換算値が300cc/m2/day/atm以下であり、
前記ポリオール(A2)は、2以上の水酸基を有し、密度が1.2g/cm3以上であり、融点が20℃以上である2液無溶剤型接着性組成物。 - 前記ポリイソシアネート化合物(C)が、ポリエステルポリオール(c1)とポリイソシアネートとの反応生成物であるウレタンプレポリマー(C2)を含み、
前記ポリエステルポリオール(c1)は、前記ポリエステルポリオール(c1)とキシレンジイソシアネートのトリメチロールプロパンアダクト体とを、NCO/OHが2±0.2で反応させたときの硬化塗膜の23℃0%RHにおける酸素透過率の3g/m2換算値が300cc/m2/day/atm以下である、請求項1に記載の2液無溶剤型接着性組成物。 - 前記ポリオール(A2)の配合量は、前記ポリエステルポリオール(A1)とポリオール(A2)との総量の5質量%以上90質量%以下である請求項1または2のいずれか一項に記載の2液無溶剤型接着性組成物。
- 請求項1乃至3のいずれか一項に記載のポリオール組成物(X)と、
ポリイソシアネート組成物(Y)と、を含む2液硬化型接着剤。 - 請求項1乃至3のいずれか一項に記載のポリオール組成物(X)と、
ポリイソシアネート組成物(Y)と、を有するアンカーコート剤。 - 基材と、請求項1~3のいずれか一項に記載の2液無溶剤型接着性組成物の硬化塗膜とを有する積層体。
- 請求項6に記載の積層体を含む包装材。
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013018904A (ja) * | 2011-07-13 | 2013-01-31 | Dic Corp | 酸素バリア性接着剤用樹脂組成物、接着剤、及び積層体 |
JP2013237154A (ja) * | 2012-05-11 | 2013-11-28 | Dic Corp | 多層フィルム、及びスタンディングパウチ |
JP2014159548A (ja) * | 2013-01-22 | 2014-09-04 | Toyo Ink Sc Holdings Co Ltd | 接着剤組成物、並びに積層体およびその製造方法 |
WO2017104639A1 (ja) * | 2015-12-17 | 2017-06-22 | Dic株式会社 | ガスバリア性接着剤、フィルム、及びガスバリア性フィルム |
WO2020129668A1 (ja) * | 2018-12-20 | 2020-06-25 | Dic株式会社 | 2液型接着剤、2液型接着剤用ポリイソシアネート組成物、積層体、包装材 |
WO2020262006A1 (ja) * | 2019-06-25 | 2020-12-30 | Dic株式会社 | ガスバリア性積層体、包装材 |
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---|---|---|---|---|
JP2013018904A (ja) * | 2011-07-13 | 2013-01-31 | Dic Corp | 酸素バリア性接着剤用樹脂組成物、接着剤、及び積層体 |
JP2013237154A (ja) * | 2012-05-11 | 2013-11-28 | Dic Corp | 多層フィルム、及びスタンディングパウチ |
JP2014159548A (ja) * | 2013-01-22 | 2014-09-04 | Toyo Ink Sc Holdings Co Ltd | 接着剤組成物、並びに積層体およびその製造方法 |
WO2017104639A1 (ja) * | 2015-12-17 | 2017-06-22 | Dic株式会社 | ガスバリア性接着剤、フィルム、及びガスバリア性フィルム |
WO2020129668A1 (ja) * | 2018-12-20 | 2020-06-25 | Dic株式会社 | 2液型接着剤、2液型接着剤用ポリイソシアネート組成物、積層体、包装材 |
WO2020262006A1 (ja) * | 2019-06-25 | 2020-12-30 | Dic株式会社 | ガスバリア性積層体、包装材 |
Cited By (1)
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JP7332075B1 (ja) * | 2021-11-11 | 2023-08-23 | Dic株式会社 | 接着剤、積層体、包装材 |
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