JP6967971B2 - 界面活性剤で安定化されたシクロヘキサンジオキシドオキシム製剤 - Google Patents
界面活性剤で安定化されたシクロヘキサンジオキシドオキシム製剤 Download PDFInfo
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- 150000001555 benzenes Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- FWFSEYBSWVRWGL-UHFFFAOYSA-N cyclohex-2-enone Chemical compound O=C1CCCC=C1 FWFSEYBSWVRWGL-UHFFFAOYSA-N 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 235000018927 edible plant Nutrition 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 235000004426 flaxseed Nutrition 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 235000008216 herbs Nutrition 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000011785 micronutrient Substances 0.000 description 1
- 235000013369 micronutrients Nutrition 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 235000010460 mustard Nutrition 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- XGNHRRHYGMFKAQ-OWOJBTEDSA-N o-[(e)-3-chloroprop-2-enyl]hydroxylamine Chemical compound NOC\C=C\Cl XGNHRRHYGMFKAQ-OWOJBTEDSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- 239000003880 polar aprotic solvent Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- KIWATKANDHUUOB-UHFFFAOYSA-N propan-2-yl 2-hydroxypropanoate Chemical compound CC(C)OC(=O)C(C)O KIWATKANDHUUOB-UHFFFAOYSA-N 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
- 239000013225 prussian blue Substances 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- DVQHRBFGRZHMSR-UHFFFAOYSA-N sodium methyl 2,2-dimethyl-4,6-dioxo-5-(N-prop-2-enoxy-C-propylcarbonimidoyl)cyclohexane-1-carboxylate Chemical compound [Na+].C=CCON=C(CCC)[C-]1C(=O)CC(C)(C)C(C(=O)OC)C1=O DVQHRBFGRZHMSR-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000006076 specific stabilizer Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000012430 stability testing Methods 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical at least one of the bonds to hetero atoms is to nitrogen
- A01N35/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical at least one of the bonds to hetero atoms is to nitrogen containing a carbon-to-nitrogen double bond
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/18—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with sulfur as the ring hetero atom
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Description
製剤A−1
クレトジム70%汎用製品(MUP) 51.4%
Aerosol OT−100(乳化剤) 10.0%
Solvesso150 ND(溶媒) 38.6%
製剤A−2
クレトジム70%汎用製品(MUP) 51.4%
Genapol XM 060(乳化剤) 10.0%
Solvesso150 ND(溶媒) 38.6%
以下の表中の概要に従って界面活性剤を変更した以外は同様に他の製剤を調製した。
試験方法
安定化クレトジム製剤の安定性の評価
実施例1
実施例2
表2は、様々な比のノニオン性界面活性剤及びイオン性界面活性剤を含有する製剤、並びに水道水水性媒体中で1時間目及び4時間目におけるエマルション安定性を示す。結果は、ノニオン性界面活性剤のイオン性界面活性剤に対する比が7:3であるとき最良のエマルション性能が得られたことを示す。
実施例3
実施例4
実施例5
実施例6
Claims (30)
- 20重量%〜50重量%のシクロヘキサンジオンオキシム系除草剤、又はその農業的に許容可能な塩と、
安定化シクロヘキサンジオンオキシム系除草剤を提供するのに有効な量の1以上の安定化界面活性剤と、
非極性溶媒である希釈剤と、を含み、
前記安定化界面活性剤が、14個〜22個の炭素原子を有するアルカンスルホネート、アルコールエトキシレート、トリスチリルフェノールエトキシレート、又はこれらの混合物であり、
前記非極性溶媒が、脂肪族炭化水素、芳香族炭化水素、及びアルキルエステルからなる群から選択され、
エポキシ化油脂肪酸及び脂肪酸のエポキシ化エステルを少なくとも含まないことを特徴とする組成物。 - 1以上の補助剤を更に含む請求項1に記載の組成物。
- 前記非極性溶媒が、芳香族炭化水素である請求項1に記載の組成物。
- 前記芳香族炭化水素が、ベンゼン、トルエン、キシレン、置換若しくは非置換ナフタレン、モノアルキル化芳香族、ポリアルキル化芳香族、又はこれらの混合物である請求項3に記載の組成物。
- 前記非極性溶媒が、アルキルエステルである請求項1に記載の組成物。
- 前記アルキルエステルが、メチルエステルである請求項5に記載の組成物。
- 前記アルキルエステルが、植物油のメチルエステルである請求項6に記載の組成物。
- 前記植物油が、キャノーラ、亜麻仁、ベニバナ、ダイズ、又はヒマワリ油である請求項7に記載の組成物。
- 前記1以上の補助剤が、作物油を含む請求項2に記載の組成物。
- 前記アルカンスルホネートが、ジオクチルスルホコハク酸ナトリウムである請求項1に記載の組成物。
- 20重量%〜40重量%の前記シクロヘキサンジオンオキシム系除草剤、又はその農業的に許容可能な塩を含む請求項1に記載の組成物。
- 200g/L〜400g/Lの前記シクロヘキサンジオンオキシム系除草剤、又はその農業的に許容可能な塩を含む請求項1に記載の組成物。
- 0.1重量%〜30重量%の前記安定化界面活性剤を含む請求項1に記載の組成物。
- 0.1重量%〜15重量%の前記安定化界面活性剤を含む請求項1に記載の組成物。
- 1重量%〜99重量%の前記非極性溶媒を含む請求項1に記載の組成物。
- 10重量%〜80重量%の前記非極性溶媒を含む請求項1に記載の組成物。
- 前記シクロヘキサンジオンオキシム系除草剤、又はその農業的に許容可能な塩が、メチル(E)−(RS)−3−[1−(アロキシイミノ)ブチル]−4−ヒドロキシ−6,6−ジメチル−2−オキソシクロヘキサ−3−エンカルボキシレート)、5−(3−ブチリル−2,4,6−トリメチルフェニル)−2−(1−エトキシイミノプロピル)−3−ヒドロキシシクロヘキサ−2−エノン)、(2−{1−[2−(4−クロロフェノキシ)プロポキシイミノ]ブチル}−3−ヒドロキシ−5−チアン−3−イルシクロヘキサ−2−エノン)、(±)−2−[(E)−1−[(E)−3−クロロアリルオキシイミノ]プロピル]−5−[2−(エチルチオ)プロピル]−3−ヒドロキシシクロヘキサ−2−エノン)、(±)−2−[1−(エトキシイミノ)ブチル]−3−ヒドロキシ−5−チアン−3−イルシクロヘキサ−2−エノン)、(±)−(EZ)−2−(1−エトキシイミノブチル)−5−[2−(エチルチオ)プロピル]−3−ヒドロキシシクロヘキサ−2−エノン)、(EZ)−(RS)−2−{1−[(2E)−3−クロロアリルオキシ−イミノ]プロピル}−3−ヒドロキシ−5−ペルヒドロピラン−4−イルシクロ−ヘキサ−2−エン−1−オン)、2−[1−(エトキシイミノ)プロピル]−3−ヒドロキシ−5−メシチルシクロヘキサ−2−エノン)、及び2−[1−[[2−(4−クロロフェノキシ)プロポキシ]イミノ]ブチル]−3−ヒドロキシ−5−(テトラヒドロ−2H−チオピラン−3−イル)−2−シクロヘキセン−1−オンからなる群から選択される請求項1から16のいずれかに記載の組成物。
- 前記シクロヘキサンジオンオキシム系除草剤、又はその農業的に許容可能な塩が、(±)−2−[(E)−1−[(E)−3−クロロアリルオキシイミノ]プロピル]−5−[2−(エチルチオ)プロピル]−3−ヒドロキシシクロヘキサ−2−エノン)又はその塩を含む請求項1から17のいずれかに記載の組成物。
- マイクロエマルションを含む乳化性濃縮物、水和剤(wettable powder)、顆粒、ペレット、粉塵、油噴霧物、エアゾール、懸濁液濃縮物、又はカプセルを含む請求項1から17のいずれかに記載の組成物。
- 雑草を管理する方法であって、
20重量%〜50重量%のシクロヘキサンジオンオキシム系除草剤、又はその農業的に許容可能な塩と、
14個〜22個の炭素原子を有するアルカンスルホネート、アルコールエトキシレート、トリスチリルフェノールエトキシレート、又はこれらの混合物である有効量の安定化界面活性剤と、
脂肪族炭化水素、芳香族炭化水素、及びアルキルエステルからなる群から選択される非極性溶媒である希釈剤と、を含み、
少なくともエポキシ化油脂肪酸及び脂肪酸のエポキシ化エステルを含まない組成物を、雑草、作物、又は生息地域に施用することを含むことを特徴とする方法。 - 前記組成物が、1以上の補助剤を更に含む請求項20に記載の方法。
- 前記シクロヘキサンジオンオキシム系除草剤、又はその農業的に許容可能な塩が、メチル(E)−(RS)−3−[1−(アロキシイミノ)ブチル]−4−ヒドロキシ−6,6−ジメチル−2−オキソシクロヘキサ−3−エンカルボキシレート)、5−(3−ブチリル−2,4,6−トリメチルフェニル)−2−(1−エトキシイミノプロピル)−3−ヒドロキシシクロヘキサ−2−エノン)、(2−{1−[2−(4−クロロフェノキシ)プロポキシイミノ]ブチル}−3−ヒドロキシ−5−チアン−3−イルシクロヘキサ−2−エノン)、(±)−2−[(E)−1−[(E)−3−クロロアリルオキシイミノ]プロピル]−5−[2−(エチルチオ)プロピル]−3−ヒドロキシシクロヘキサ−2−エノン)、(±)−2−[1−(エトキシイミノ)ブチル]−3−ヒドロキシ−5−チアン−3−イルシクロヘキサ−2−エノン)、(±)−(EZ)−2−(1−エトキシイミノブチル)−5−[2−(エチルチオ)プロピル]−3−ヒドロキシシクロヘキサ−2−エノン)、(EZ)−(RS)−2−{1−[(2E)−3−クロロアリルオキシ−イミノ]プロピル}−3−ヒドロキシ−5−ペルヒドロピラン−4−イルシクロ−ヘキサ−2−エン−1−オン)、2−[1−(エトキシイミノ)プロピル]−3−ヒドロキシ−5−メシチルシクロヘキサ−2−エノン)、及び2−[1−[[2−(4−クロロフェノキシ)プロポキシ]イミノ]ブチル]−3−ヒドロキシ−5−(テトラヒドロ−2H−チオピラン−3−イル)−2−シクロヘキセン−1−オンからなる群から選択される請求項20に記載の方法。
- 前記シクロヘキサンジオンオキシム系除草剤、又はその農業的に許容可能な塩が、(±)−2−[(E)−1−[(E)−3−クロロアリルオキシイミノ]プロピル]−5−[2−(エチルチオ)プロピル]−3−ヒドロキシシクロヘキサ−2−エノン)又はその塩を含む請求項20に記載の方法。
- 前記雑草が、イネ科植物である請求項20に記載の方法。
- 前記イネ科植物が、オオムギ、イヌビエ、ギョウギシバ、メリケンニクキビ、スズメノチャヒキ、トウモロコシ、メヒシバ、タツノツメガヤ、オオクサキビ、オニウシノケグサ、ホソノゲムギ、エノコログサ、ネコジャラシ、オヒシバ、モロコシ、ツノアイアシ、コヒメビエ、オニメヒシバ、スズメガヤ、エンバク、カモガヤ、多年草、シバムギ、ペルシアンライグラス、キビ、雑草イネ,セイバンモロコシ根茎、ライムギ、ドクムギ、セイバンモロコシ実生、モロコシ、キタメヒシバ、ホソナルコビエ、アゼガヤ、オヒジワ、自生オオムギ、自生エンバク、自生トウモロコシ、自生カナリーシード、自生コムギ、コムギ、カラスムギ、野生キビ、ハナクサキビ、ナルコビエ、キダチノネズミガヤ、及びキンエノコロからなる群から選択される請求項24に記載の方法。
- 前記組成物が、出芽後処理として施用される請求項20に記載の方法。
- 前記組成物が、雑草管理の必要があるか又は望ましくない雑草のリスクがある作物に施用される請求項20に記載の方法。
- 前記作物が、キャノーラ、アマ、エンドウ、レンズマメ、豆類、linola(登録商標)、カラシ、ヒヨコマメ、ヒマワリ、ジャガイモ、アルファルファ実生、タマネギ、及びダイズのいずれかである請求項27に記載の方法。
- 20重量%〜50重量%のシクロヘキサンジオンオキシム系除草剤を1以上の安定化界面活性剤及び希釈剤と混合して、安定化組成物を作製することを含むことを特徴とする安定化除草剤組成物を作製する方法であって、
前記安定化界面活性剤が、14個〜22個の炭素原子を有するアルカンスルホネート、アルコールエトキシレート、トリスチリルフェノールエトキシレート、又はこれらの混合物であり、
前記希釈剤が、脂肪族炭化水素、芳香族炭化水素、及びアルキルエステルからなる群から選択される非極性溶媒であり、
エポキシ化油脂肪酸及び脂肪酸のエポキシ化エステルを少なくとも含まない安定化除草剤組成物を作製する方法。 - a)1以上の安定化界面活性剤、
b)1以上の補助剤、及び
c)20重量%〜50重量%のシクロヘキサンジオンオキシム系除草剤
を任意の順序で希釈剤に添加して、安定化組成物を作製することを含み、
前記安定化界面活性剤が、14個〜22個の炭素原子を有するアルカンスルホネート、アルコールエトキシレート、トリスチリルフェノールエトキシレート、又はこれらの混合物であり、
前記希釈剤が、脂肪族炭化水素、芳香族炭化水素、及びアルキルエステルからなる群から選択される非極性溶媒であり、
エポキシ化油脂肪酸及び脂肪酸のエポキシ化エステルを少なくとも含まないことを特徴とする、安定化除草剤組成物を作製する方法。
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