JP6901570B2 - 単層カーボンナノチューブ用途のための分解可能なs−テトラジン系ポリマー - Google Patents
単層カーボンナノチューブ用途のための分解可能なs−テトラジン系ポリマー Download PDFInfo
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Description
が挙げられる(しかし、これらに限定されない)。
示差走査熱量測定(DSC)曲線は、s−テトラジンポリマーが約250℃で熱分解し得ることを示している。
s−テトラジン系ポリマーとSWCNTとの間の相互作用は非常に強いが、SWCNT構造を破壊するのに十分なほど強くはない。ポリフルオレン類(PFDD)のような他のポリマーは、PFDD分散液をs−テトラジンポリマー溶液で処理することによって容易に置換することができる。
上記のように、s−テトラジン系ポリマーは、光照射または加熱によって分解することがある。分解後、得られた小分子は、溶液中で洗い流すか、レーザー照射下で蒸発させるか、または固体状態であれば真空下で加熱することができる。このように、クリーンなSWCNTネットワークを得ることができ、それは、薄膜トランジスタ(TFT)またはセンサーなどの電気デバイス用途にとって望ましい。これについては、図4を参照して以下さらに説明する。
PBDTFT/SWCNT分散液を使用して電子デバイスを製造することができる。
一般に、PFDD/SWCNTからのTFTは、より高い電流と移動度とを有しているが、SEMの画像は、PBDTFTz/SWCNTのものと非常に似ているチューブ密度を示している(図7aおよび7b参照)。ポリマー/SWCNTの重量比は4:1であるが、SWCNTの濃度は25.5mg/Lである。画像の右下隅にあるスケールバーは1μmである。
ポリマーの除去は、トランジスタ性能における適度の利得をもたらすが、露出したナノチューブ表面は、分子の化学的検知を含む、いくつかの用途にとって望ましいプラットフォームを提供する。本明細書に記載の新規な化学と裸の高純度sc−SWCNT薄膜を産生するその能力は、種々のデバイス、特に、整列SWCNT、光起電力デバイスおよび光電子デバイスに基づく高性能トランジスタとppb検知が可能であり、環境用途にも健康管理用途にも適用できる最重要なセンサーとの最適化性能を可能にし得る。
その各々の全体の内容は、この参照により組み入れられる:
P.Avouris、Acc.Chem.Res.、2002年、35巻、1026頁。
Q.Cao、J.A.Rogers、Adv.Mater.、2009年、21巻、29頁。
L.Hu、D.S.Hecht、G.Gruner、Chem.Rev.、2010年、110巻、5790頁。
R.V.Noorden、Nature、2011年、469巻、14頁。
C.Wang、K.Takei、T.Takahashi、A.Javey、Chem.Soc.Rev.、2013年、42巻、2592頁。
M.F.L.De Volder、S.H.Tawfick、R.H.Baughman、A.J.Hart、Science、2013年、339巻、535頁。
Q.Zhang、J.−Q.Huang、W.−Z.Qian、Y.−Y.Zhang、F.Wei、Small、2013年、9巻、1237頁。
L.−M.Peng、Z.Zhang、S.Wang、Mater.Today、2014年、17巻、434頁。
H.Zhang、B.Wu、W.Hu、Y.Liu、Chem.Soc.Rev.、2011年、40巻、1324頁。
F.Lu、M.J.Meziani、L.Cao、Y.−P.Sun、Langmuir、2011年、27巻、4339頁。
Y.Wu、X.Lin、M.Zhang、J.Nanomaterials、2013年、627215頁。
A.D.Franklin、Nature、498巻、443頁。
D.−M.Sun、C.Liu、W.C.Ren、H.−M.Cheng、Small、2013年、9巻、1188頁。
Y.Che、H.Chen、H.Gui、J.Liu、B.Liu、C.Zhou、Semicond.Sci.Technol.、2014年、29巻、073001頁。
G.S.Tulevski、A.D.Franklin、D.Frank、J.M.Lobez、Q.Cao、H.Park、A.Afzali、S.−J.Han、J.B.Hannon、W.Haensch、ACS Nano、2014年、8巻、8730頁。
T.Fujigaya、N.Nakashima、Sci.Technol.Adv.Mater.、2015年、16巻、024802頁。
H.Wang、Z.Bao、Nano Today、2015年、10巻、737頁。
Z.Li、J.Ding、P.Finnie、J.Lefebvre、F.Cheng、C.T.Kingston、P.R.L.Malenfant、Nano Res.、2015年、8巻、2179頁。
G.J.Brady、Y.Joo、S.S.Roy、P.Gopalan、M.S.Arnold、Appl.Phys.Lett.、2014年、104巻、083107頁。
Z.Li、J.Ding、J.Lefebvre、P.R.L.Malenfant、Org.Electron.、2015年、26巻、15頁。
C.M.Homenick、R.James、G.P.Lopinski、J.Dunford、J.Sun、H.Park、Y.Jung、G.Cho、P.R.L.Malenfant、ACS Appl.Mater.Interfaces、2016年、8巻、27900頁。
C.Cao、J.B.Andrews、A.D.Franklin、Adv.Electron.Mater.、2017年、3巻、1700057頁。
F.Lemasson、J.Tittmann、F.Hennrich、N.Sturzl、S.Malik、M.M.Kappes、M.Mayor、Chem.Commun.、2011年、47巻、7428頁。
T.Umeyama、K.Kawabata、N.Tezuka、Y.Matano、Y.Miyato、K.Matsushige、M.Tsujimoto、S.Isoda、M.Takano、H.Imahori、Chem.Commun.、2010年、46巻、5969頁。
Z.Zhang、Y.Che、R.A.Smaldone、M.Xu、B.R.Bunes、J.S.Moore、L.Zang、J.Am.Chem.Soc.、2010年、132巻、14113頁。
W.Z.Wang、W.F.Li、X.Y.Pan、C.M.Li、L.−J.Li、Y.G.Mu、J.A.Rogers、M.B.Chan−Park、Adv.Funct.Mater.、2011年、21巻、1643頁。
Q.Ji、J.Han、X.Yu、S.Qiu、H.Jin、D.Zhang、Q.Li、Carbon、2016年、105巻、448頁。
I.Pochorovski、H.Wang、J.I.Feldblyum、X.Zhang、A.L.Antaris、Z.Bao、J.Am.Chem.Soc.、2015年、137巻、4328頁。
F.Toshimitsu、N.Nakashima、Sci.Rep.、2015年、5巻、18066頁、doi:10.1038/srep18066。
A.Llanes−Pallas、K.Yoosaf、H.Traboulsi、J.Mohanraj、T.Seldrum、J.Dumont、A.Minoia、R.Lazzaroni、N.Armaroli、D.Bonifazi、J.Am.Chem.Soc.、2011年、133巻、15412頁。
T.Lei、X.Chen、G.Pitner、H.−S.P.Wong、Z.Bao、J.Am.Chem.Soc.、2016年、138巻、802頁。
F.Toshimitsu、N.Nakashima、Nat.Commun.、2014年、5巻、5041頁、doi:10.1038/ncomms6041。
Y.Joo、G.J.Brady、M.J.Shea、M.B.Oviedo、C.Kanimozhi、S.K.Schmitt、B.M.Wong、M.S.Arnold、P.Gopalan、ACS Nano、2015年、9巻、10203頁。
Z.Li、J.Ding、Macromol.Chem.Phys.、2011年、212巻、2260頁。
Z.Li、J.Ding、N.Song、J.Lu、Y.Tao、J.Am.Chem.Soc.、2010年、132巻、13160頁。
Z.Li、J.Ding、N.Song、X.Du、J.Zhou、J.Lu、Y.Tao、Chem.Mater.、2011年、23巻、1977頁。
W.Gomulya、G.D.Costanzo、E.J.F.de Carvalho、S.Z.Bisri、V.Derenskyi、M.Fritsch、N.Frohlich、S.Allard、P.Gordiichuk、A.Herrmann、S.J.Marrink、M.C.dosSantos、U.Scherf、M.A.Loi、Adv.Mater.、2013年、25巻、2948頁。
J.Ding、Z.Li、J.Lefebvre、F.Cheng、G.Dubey、S.Zou、P.Finnie、A.Hrdina、L.Scoles、G.P.Lopinski、C.T.Kinsgton、B.Simard、P.R.L.Malenfant、Nanoscale、2014年、6巻、2328頁。
http://raymor.com/our−products/isosol−s100/(2016年8月アクセス)。
S.D.Stranks、C.−K.Yong、J.A.Alexander−Webber、C.Weisspfennig、M.B.Johnston、L.M.Herz、R.J.Nicholas、ACS Nano、2012年、6巻、6058頁。
S.D.Stranks、S.N.Habisreutinger、B.Dirks、R.J.Nicholas、Adv.Mater.、2013年、25巻、4365頁。
S.D.Stranks、A.M.R.Baker、J.A.Alexander−Webber、B.Dirks、R.J.Nicholas.、Small、2013年、9巻、2245頁。
T.Takenobu、T.Takano、M.Shiraishi、Y.Murakami、M.Ata、H.Kataura、Y.Achiba、Y.Iwasa、Nat.Mater.、2003年、2巻、683頁。
Y.Joo、G.J.Brady、M.S.Arnold、R.Gopalan、Langmuir、2014年、30巻、3460頁。
M.L.Geier、K.Moudgil、S.Barlow、S.R.Marder、M.C.Hersam、Nano Lett.、2016年、16巻、4329頁。
M.J.Shea、R.D.Mehlenbacher、M.T.Zanni、M.S.Arnold、J.Phys.Chem.Lett.、2014年、5巻、3742頁。
Q.Cao、S.−J.Han、G.S.Tulevski、A.D.Franklin、W.Haensch、ACS Nano、2012年、6巻、6471頁。
J.M.Lobez、T.M.Swager、Angew.Chem.Int.Ed.、2010年、49巻、95頁。
A.Chortos、I.Pochorovski、P.Lin、G.Pitner、X.Yan、T.Z.Gao、J.W.F.To、T.Lei、J.W.Will III、H.−S.P.Wong、Z.Bao、ACS Nano、2017年、DOI:10.1021/acsnano.7b01076。
G.J.Brady、A.J.Way、N.S.Safron、H.T.Evensen、P.Gopalan、M.S.Arnold、Sci.Adv.、2016年、2巻、e1601240頁。
R.Ihly、K.S.Mistry、A.J.Ferguson、T.T.Clikeman、B.W.Larson、O.Reid、O.V.Boltalina、S.H.Strauss、G.Rumbles、J.L.Blackburn、Nat.Chem.、2016年、8巻、603頁。
M.L.Moser、G.Li、M、Chen、E.Bekyarova、M.E.Itkis、R.C.Haddon、Nano Lett.、2016年、16巻、5386頁。
B.Norton−Bake、R.Ihly、I.E.Gould、A.D.Avery、Z.R.Owczarczyk、A.J.Ferguson、J.L.Blackburn、ACS Energy Lett.、2016年、1巻、1212頁。
J.E.EllisおよびA.Star、ChemPlusChem、2016年、81巻、1248−1265頁。
J.F.Fennell、Jr.、S.F.Lui、J.M.Azzarelli、J.G.Weis、S.Rochat、K.A.Mirca、J.B.Ravnsboek、およびT.M.Swager、Angew.Chem.Int.Ed.、2016年、55巻、1266−1281頁。
T.Zhang、S.Mubeen、N.V.MyungおよびM.A Deshusses、Nanotechnology、19巻(2008年)、332001頁(14頁)。
J.Kong、N.R.Franklin、C.Zhou、M.G.Chapline、S.Peng、K.Cho、H.Dai、Science、2000年、287巻、622頁。
C.M.Aguirre、P.L.Levesque、M.Paillet、F.Lapointe、B.C.St−Antoine、P.Desjardins、R.Martel、Adv.Mater.、2009年、21巻、3087頁。
F.Rigoni、S.Tognolini、P.Borghetti、G.Drera、S.Pagliara、A.Goldoni、L.Sangaletti、Analyst、2013年、138巻、7392頁。
G.Chen、T.M.Paronyan、E.M.Pigos、A.R.Harutyunyan、Sci.Rep.、2012年、2巻、343頁、DOI:10.1038/srep00343。
X.Wang、G.Li、R.Liu、H.Ding、T.Zhang、J.Mater.Chem.、2012年、22巻、21824頁。
P.Qi、O.Vermesh、M.Grecu、A.Javey、Q.Wang、H.Dai、NanoLett.、2003年、3巻、347頁。
M.Rother、M.Brohmann、S.Yang、S.B.Grimm、S.P.Schiessl、A.Graf、J.Zaumseil、Adv.Electron.Mater.、2017年、1700080頁。
J.Lefebvre、J.Ding、Mater.Today Comm.、2017年、10巻、72頁。
M.Meyyappan、Small、2016年、12巻、16号、2118−2129頁。
http://raymor.com/our−products/isosol−s100/(2016年8月アクセス)。
Claims (25)
- 共役ポリマーで抽出された半導体単層カーボンナノチューブ(sc−SWCNT)を精製するための方法であって、
sc−SWCNTと会合した共役ポリマーを含む処理済sc−SWCNT分散液中で共役ポリマーをs−テトラジン系ポリマーと交換する工程を含む方法。 - 光照射または熱処理によって前記s−テトラジン系ポリマーを分解する工程、続いて分解生成物を除去する工程をさらに含む、請求項1に記載の方法。
- 前記分解生成物が、すすぎまたは蒸発によって除去される、請求項2に記載の方法。
- 前記共役ポリマーが、ポリフルオレンを含む、請求項1に記載の方法。
- 前記共役ポリマーが、ポリチオフェンを含む、請求項1に記載の方法。
- 前記共役ポリマーが、ポリ(9,9−ジ−n−ドデシルフルオレン)(PFDD)である、請求項1に記載の方法。
- 前記sc−SWCNTに対する前記共役ポリマーの重量比が、最大値2を有する、請求項1に記載の方法。
- 前記sc−SWCNTに対する前記s−テトラジン系ポリマーの重量比が、最大値4を有する、請求項1に記載の方法。
- 前記sc−SWCNTに対する前記s−テトラジン系ポリマーの重量比が、1から4の間である、請求項1に記載の方法。
- 薄膜トランジスタの製造のための請求項1に記載の方法。
- 薄膜トランジスタおよび化学センサーからなる群から選択される電子デバイスの製造のための、半導体単層カーボンナノチューブ(sc−SWCNT)と会合したs−テトラジン系ポリマーを含む分散液の使用。
- 前記半導体単層カーボンナノチューブ(sc−SWCNT)と会合したs−テトラジン系ポリマーが、sc−SWCNTと会合した共役ポリマーを前記分散液中で前記s−テトラジン系ポリマーと交換することによって製造される、請求項16に記載の使用。
- 前記電子デバイスが、4pptから100ppbまで、3pptから1ppbまで、4ppbから100ppmまで、または3ppbから1ppmまでの範囲内の1つ以上の化学物質の量を検出することができる化学センサーである、請求項16から18のいずれか一項に記載の使用。
- 前記電子デバイスが、気相中または液相中の1つ以上の化学物質を検出することができる化学センサーである、請求項16に記載の使用。
- 前記1つ以上の化学物質が、アンモニアガスまたは二酸化窒素ガス(NO 2 )である、請求項20に記載の使用。
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