JP6839291B2 - フォトポリマー組成物 - Google Patents
フォトポリマー組成物 Download PDFInfo
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- JP6839291B2 JP6839291B2 JP2019537738A JP2019537738A JP6839291B2 JP 6839291 B2 JP6839291 B2 JP 6839291B2 JP 2019537738 A JP2019537738 A JP 2019537738A JP 2019537738 A JP2019537738 A JP 2019537738A JP 6839291 B2 JP6839291 B2 JP 6839291B2
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- 239000000203 mixture Substances 0.000 title claims description 79
- 150000001875 compounds Chemical class 0.000 claims description 68
- 239000000178 monomer Substances 0.000 claims description 40
- -1 lactone compound Chemical class 0.000 claims description 34
- 229920005862 polyol Polymers 0.000 claims description 31
- 150000003077 polyols Chemical class 0.000 claims description 29
- 229920000642 polymer Polymers 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 26
- 150000001923 cyclic compounds Chemical class 0.000 claims description 25
- 239000011159 matrix material Substances 0.000 claims description 23
- 230000003287 optical effect Effects 0.000 claims description 22
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 19
- 150000002596 lactones Chemical class 0.000 claims description 17
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 14
- 239000012948 isocyanate Substances 0.000 claims description 10
- 239000002243 precursor Substances 0.000 claims description 9
- 230000000903 blocking effect Effects 0.000 claims description 8
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims description 7
- 125000000524 functional group Chemical group 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 230000005670 electromagnetic radiation Effects 0.000 claims description 5
- 239000005056 polyisocyanate Substances 0.000 claims description 5
- 230000000379 polymerizing effect Effects 0.000 claims description 5
- 229920000858 Cyclodextrin Polymers 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 230000000149 penetrating effect Effects 0.000 claims description 4
- PCHXZXKMYCGVFA-UHFFFAOYSA-N 1,3-diazetidine-2,4-dione Chemical compound O=C1NC(=O)N1 PCHXZXKMYCGVFA-UHFFFAOYSA-N 0.000 claims description 3
- 125000005702 oxyalkylene group Chemical group 0.000 claims description 3
- PJMDLNIAGSYXLA-UHFFFAOYSA-N 6-iminooxadiazine-4,5-dione Chemical group N=C1ON=NC(=O)C1=O PJMDLNIAGSYXLA-UHFFFAOYSA-N 0.000 claims description 2
- 229920001450 Alpha-Cyclodextrin Polymers 0.000 claims description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000001116 FEMA 4028 Substances 0.000 claims description 2
- 150000007945 N-acyl ureas Chemical class 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- ORILYTVJVMAKLC-UHFFFAOYSA-N adamantane Chemical group C1C(C2)CC3CC1CC2C3 ORILYTVJVMAKLC-UHFFFAOYSA-N 0.000 claims description 2
- HFHDHCJBZVLPGP-RWMJIURBSA-N alpha-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO HFHDHCJBZVLPGP-RWMJIURBSA-N 0.000 claims description 2
- 229940043377 alpha-cyclodextrin Drugs 0.000 claims description 2
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 2
- 235000011175 beta-cyclodextrine Nutrition 0.000 claims description 2
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- 239000004202 carbamide Substances 0.000 claims description 2
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- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical group O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 claims description 2
- GDSRMADSINPKSL-HSEONFRVSA-N gamma-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO GDSRMADSINPKSL-HSEONFRVSA-N 0.000 claims description 2
- 229940080345 gamma-cyclodextrin Drugs 0.000 claims description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 2
- HXSACZWWBYWLIS-UHFFFAOYSA-N oxadiazine-4,5,6-trione Chemical compound O=C1ON=NC(=O)C1=O HXSACZWWBYWLIS-UHFFFAOYSA-N 0.000 claims description 2
- 125000005581 pyrene group Chemical group 0.000 claims description 2
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical group O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims description 2
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 claims description 2
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- 239000000047 product Substances 0.000 description 11
- 239000003960 organic solvent Substances 0.000 description 10
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- 239000000975 dye Substances 0.000 description 8
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- 239000000463 material Substances 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000003505 polymerization initiator Substances 0.000 description 6
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 150000002009 diols Chemical class 0.000 description 5
- 229920005906 polyester polyol Polymers 0.000 description 5
- 150000005846 sugar alcohols Polymers 0.000 description 5
- 230000000007 visual effect Effects 0.000 description 5
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 230000002165 photosensitisation Effects 0.000 description 4
- 239000003504 photosensitizing agent Substances 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 3
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
- 230000001588 bifunctional effect Effects 0.000 description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
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- 229920005596 polymer binder Polymers 0.000 description 3
- 239000002491 polymer binding agent Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- OARRHUQTFTUEOS-UHFFFAOYSA-N safranin Chemical compound [Cl-].C=12C=C(N)C(C)=CC2=NC2=CC(C)=C(N)C=C2[N+]=1C1=CC=CC=C1 OARRHUQTFTUEOS-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 2
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- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 238000005160 1H NMR spectroscopy Methods 0.000 description 2
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 2
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 description 2
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- VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 2
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- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 description 2
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- 125000005442 diisocyanate group Chemical group 0.000 description 2
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
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- WMAVHUWINYPPKT-UHFFFAOYSA-M (e)-3-methyl-n-[(e)-(1-methyl-2-phenylindol-1-ium-3-ylidene)amino]-1,3-thiazol-2-imine;chloride Chemical compound [Cl-].C12=CC=CC=C2N(C)C(C=2C=CC=CC=2)=C1N=NC=1SC=C[N+]=1C WMAVHUWINYPPKT-UHFFFAOYSA-M 0.000 description 1
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- ZOMLUNRKXJYKPD-UHFFFAOYSA-N 1,3,3-trimethyl-2-[2-(2-methylindol-3-ylidene)ethylidene]indole;hydrochloride Chemical compound [Cl-].C1=CC=C2C(C)(C)C(/C=C/C=3C4=CC=CC=C4NC=3C)=[N+](C)C2=C1 ZOMLUNRKXJYKPD-UHFFFAOYSA-N 0.000 description 1
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- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
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- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 description 1
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Description
本出願は、2017年7月17日付の韓国特許出願第10−2017−0090560号に基づく優先権の利益を主張し、当該韓国特許出願の文献に開示されたすべての内容は本明細書の一部として含まれる。
さらに、本発明は、ホログラム記録媒体を含む光学素子を提供する。
また、本明細書では、前記フォトポリマー組成物から製造されたホログラム記録媒体が提供される。
また、本明細書では、電磁放射線によって、前記フォトポリマー組成物に含まれている光反応性単量体を選択的に重合させる段階を含む、ホログラフィック記録方法が提供される。
前記ポリロタキサン化合物に関する内容は上述した通りである。
下記表1に記載されているように、ポリロタキサンポリマー[A1000、Advanced Softmaterial INC]、光反応性単量体、safranin O(染料、シグマアルドリッチ社製品)、N−メチルジエタノールアミン(シグマアルドリッチ)、[4−メチルフェニル−(4−(2−メチルプロピル)フェニル)]ヨードニウムヘキサフルオロホスフェート(irgacure250)およびメチルイソブチルケトン(MIBK)を光を遮断した状態で混合し、Pasteミキサで約2分間撹拌して透明なコーティング液を得た。
(1)前記実施例および比較例それぞれで製造されたフォトポリマーコーティング面をslideガラスにラミネートし、記録時、レーザがガラス面を先に通過するように固定した。
(2)2つの干渉光(参照光および物体光)の干渉によりホログラフィックを記録し、透過型記録は2つのビームをサンプルの同一面に入射した。2つのビームの入射角に応じて回折効率は変化し、2つのビームの入射角が同一の場合、non−slantedとなる。non−slanted記録は、2つのビームの入射角が法線基準で同一であるので、回折格子はフィルムに垂直に生成される。
532nm波長のレーザを用いて透過型non−slanted方式で記録(2θ=45°)し、下記一般式1で回折効率(η)を計算した。
・MFA−75X:Needfill社製品のヘキサンジイソシアネートベースのポリイソシアネ−ト、NCO含有量=13.7%。
・ポリオール1:Polycaprolactone diol(2官能性ポリオール)、OH equivalent weight=625g/mol。
・ポリオール2:PEG−diol(polyethyleneglycol diol)、OH equivalent weight=150g/mol。
・ポリオール3:Needfill社の7341−X65製品、OH equivalent weight=567g/mol。
・HR6042:Miwon社製品の2官能性acrylate。
・DBTDL:aldrich社製品、ウレタン化触媒、ジブチルチンジラウレート。
・Irganox250:[4−methylphenyl−(4−(2−methylpropyl)phenyl)]iodonium hexafluorophosp。
Claims (12)
- ラクトン系化合物が結合した環状化合物;前記環状化合物を貫通する線状分子;および前記線状分子の両末端に配置されて前記環状化合物の離脱を防止する封鎖基;を含むポリロタキサン化合物を含むポリオールおよび2以上のイソシアネート基を含む化合物の間の反応生成物を含む高分子マトリックスまたはその前駆体;
光反応性単量体;および
光開始剤;を含む、フォトポリマー組成物であって、
前記光反応性単量体が、多官能(メタ)アクリレート単量体または単官能(メタ)アクリレート単量体を含む、フォトポリマー組成物。 - 前記ラクトン系化合物は、炭素数3〜12のラクトン系化合物または炭素数3〜12のラクトン系繰り返し単位を含むポリラクトン系化合物を含む、請求項1に記載のフォトポリマー組成物。
- 前記ラクトン系化合物は、直接結合、または炭素数1〜10の直鎖または分枝鎖のオキシアルキレン基を媒介として前記環状化合物に結合した、請求項1に記載のフォトポリマー組成物。
- 前記環状化合物は、α−シクロデキストリンおよびβ−シクロデキストリンおよびγ−シクロデキストリンからなる群より選択された1種以上を含み、
前記線状分子は、ポリオキシアルキレン系化合物またはポリラクトン系化合物であり、
前記封鎖基は、ジニトロフェニル基、シクロデキストリン基、アダマンタン基、トリリル基、フルオレセイン基およびピレン基からなる群より選択された1種以上の官能基を含む、請求項1に記載のフォトポリマー組成物。 - 前記ポリロタキサン化合物は、100,000〜800,000の重量平均分子量を有する、請求項1に記載のフォトポリマー組成物。
- 前記2以上のイソシアネート基を含む化合物は、脂肪族、環脂肪族、芳香族または芳香脂肪族のジ−イソシアネート、トリ−イソシアネートまたはポリ−イソシアネート;または
ウレタン、尿素、カルボジイミド、アシル尿素、イソシアヌレート、アロファネート、ビュレット、オキサジアジントリオン、ウレトジオンまたはイミノオキサジアジンジオン構造を有するジ−イソシアネートまたはトリイソシアネートのオリゴ−イソシアネートまたはポリ−イソシアネート;を含む、請求項1に記載のフォトポリマー組成物。 - 前記ポリロタキサン化合物を含むポリオールは、2〜20の炭素数を有する脂肪族芳香族ジオール、トリオールまたはポリオール;4〜30の炭素数を有する脂環族ジオール、トリオールまたはポリオール;および6〜30の炭素数を有する芳香族ジオール、トリオールまたはポリオール;からなる群より選択された1種以上をさらに含む、請求項1に記載のフォトポリマー組成物。
- 前記高分子マトリックスまたはその前駆体20〜80重量%;
前記光反応性単量体10〜70重量%;および
光開始剤0.1〜15重量%;を含む、請求項1に記載のフォトポリマー組成物。 - 前記フォトポリマー組成物は、光感応染料をさらに含む、請求項1に記載のフォトポリマー組成物。
- 請求項1に記載のフォトポリマー組成物から製造されたホログラム記録媒体。
- 請求項10に記載のホログラム記録媒体を含む光学素子。
- 電磁放射線によって、請求項1に記載のフォトポリマー組成物に含まれている光反応性単量体を選択的に重合させる段階を含む、ホログラフィック記録方法。
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