JP6820034B2 - Nanosilicon gallium heat insulating / explosion-proof glass and its manufacturing method - Google Patents
Nanosilicon gallium heat insulating / explosion-proof glass and its manufacturing method Download PDFInfo
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- JP6820034B2 JP6820034B2 JP2019548509A JP2019548509A JP6820034B2 JP 6820034 B2 JP6820034 B2 JP 6820034B2 JP 2019548509 A JP2019548509 A JP 2019548509A JP 2019548509 A JP2019548509 A JP 2019548509A JP 6820034 B2 JP6820034 B2 JP 6820034B2
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- 239000011521 glass Substances 0.000 title claims description 58
- 239000005543 nano-size silicon particle Substances 0.000 title claims description 29
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 title claims description 15
- 229910052733 gallium Inorganic materials 0.000 title claims description 15
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 45
- 238000000034 method Methods 0.000 claims description 19
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 15
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 15
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 13
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 13
- 229920005989 resin Polymers 0.000 claims description 13
- 239000011347 resin Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 8
- 238000005266 casting Methods 0.000 claims description 6
- 238000005520 cutting process Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 239000005341 toughened glass Substances 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 4
- 238000003786 synthesis reaction Methods 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000005728 strengthening Methods 0.000 claims description 3
- 230000002194 synthesizing effect Effects 0.000 claims description 3
- QZQVBEXLDFYHSR-UHFFFAOYSA-N gallium(III) oxide Inorganic materials O=[Ga]O[Ga]=O QZQVBEXLDFYHSR-UHFFFAOYSA-N 0.000 claims description 2
- 239000012258 stirred mixture Substances 0.000 claims description 2
- 239000006058 strengthened glass Substances 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 229910001195 gallium oxide Inorganic materials 0.000 claims 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 206010035148 Plague Diseases 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000005328 architectural glass Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000005344 low-emissivity glass Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/06—Joining glass to glass by processes other than fusing
- C03C27/10—Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Joining Of Glass To Other Materials (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Glass Compositions (AREA)
Description
本発明は建築の技術分野に関し、特に、ナノシリコンガリウム断熱・防爆ガラス及びその製造方法に関する。 The present invention relates to the technical field of construction, and more particularly to nanosilicon gallium heat insulating / explosion-proof glass and a method for producing the same.
住居への要求の高まりと建築レベルの進歩に伴って、住宅における各種ガラスの使用割合は明らかな上昇傾向にある。しかし、ガラスを透明性且つ断熱性・保温性とすることは、技術専門家らを悩ませ続ける重大な課題である。これまで、ガラスの断熱性問題を解決するためには、主として、断熱フィルム、熱反射フィルム及びＬＯＷ−Ｅガラスが使用されてきたが、これらの製品は透光性に劣る。また、現在最も使用されているＬＯＷ−Ｅガラスには、深刻な光害や防爆機能の欠如、及び価格の高騰といった問題が存在し、一般的には受け入れ難い。そこで、市場では、安全で、省エネ且つ低排出、価格が手頃で品質に優れた新世代の製品が早急に必要とされている。 The proportion of various types of glass used in homes is clearly on the rise with increasing demand for housing and advances in building levels. However, making glass transparent, heat-insulating, and heat-retaining is a serious issue that continues to plague technical experts. So far, heat insulating films, heat reflective films and LOW-E glasses have been mainly used to solve the problem of heat insulating properties of glass, but these products are inferior in translucency. In addition, the most used LOW-E glass at present has problems such as serious light pollution, lack of explosion-proof function, and soaring price, and is generally unacceptable. Therefore, there is an urgent need in the market for a new generation of safe, energy-saving, low-emission, affordable, and high-quality products.
上記の技術に存在する瑕疵に対し、本発明は、省エネ且つ低排出で価格が手頃なナノシリコンガリウム断熱・防爆ガラス及びその製造方法を提供する。 For the defects existing in the above technology, the present invention provides nanosilicon gallium heat insulating / explosion-proof glass which is energy-saving, low-emission, and affordable, and a method for manufacturing the same.
上記の目的を達成するために、本発明は、ナノシリコンガリウム断熱・防爆ガラスであって、２枚のガラスと１層の断熱フィルムを含み、前記断熱フィルムは２枚のガラスの間に挟持され、前記断熱フィルムは重量部換算で、ポリビニルブチラール樹脂８０〜９０重量部、ナノ二酸化ケイ素１〜２重量部、及びナノ酸化ガリウム（ＩＩＩ）０．５〜１重量部、を成分として含む。 In order to achieve the above object, the present invention is nanosilicon gallium heat insulating and explosion-proof glass, which includes two pieces of glass and one layer of heat insulating film, and the heat insulating film is sandwiched between the two pieces of glass. The heat insulating film contains 80 to 90 parts by weight of polyvinyl butyral resin, 1 to 2 parts by weight of nanosilicon dioxide, and 0.5 to 1 part by weight of nanogallium oxide (III) as components.
前記断熱フィルムは、更に、酢酸エチル、酢酸ブチル及びメチルエーテルを含み、重量部換算で、酢酸エチル、酢酸ブチル及びメチルエーテルは合計５〜１０重量部である。 The heat insulating film further contains ethyl acetate, butyl acetate and methyl ether, and the total amount of ethyl acetate, butyl acetate and methyl ether is 5 to 10 parts by weight in terms of parts by weight.
前記断熱フィルムはナノ酸化亜鉛を更に含み、重量部換算で、ナノ酸化亜鉛は１〜２重量部である。 The heat insulating film further contains nanozinc oxide, and the amount of nanozinc oxide is 1 to 2 parts by weight in terms of parts by weight.
前記断熱フィルムはナノエアロゲルを更に含み、重量部換算で、ナノエアロゲルは０．５〜１重量部である。 The heat insulating film further contains nano airgel, and the nano airgel is 0.5 to 1 part by weight in terms of weight.
重量部換算で、具体的に、ポリビニルブチラール樹脂８５重量部、ナノ二酸化ケイ素１．５重量部、ナノ酸化ガリウム（ＩＩＩ）０．５重量部、酢酸エチル２重量部、酢酸ブチル２重量部、メチルエーテル１重量部、ナノ酸化亜鉛１．５重量部、及びナノエアロゲル０．５重量部を含む。 In terms of parts by weight, specifically, 85 parts by weight of polyvinyl butyral resin, 1.5 parts by weight of nanosilicon dioxide, 0.5 parts by weight of nanogallium oxide (III), 2 parts by weight of ethyl acetate, 2 parts by weight of butyl acetate, methyl. It contains 1 part by weight of ether, 1.5 parts by weight of nanozinc oxide, and 0.5 part by weight of nanoaerogel.
本発明は、更に、合成ステップとして、ポリビニルブチラール樹脂、ナノ二酸化ケイ素、ナノ酸化ガリウム（ＩＩＩ）、酢酸エチル、酢酸ブチル、メチルエーテル、ナノ酸化亜鉛及びナノエアロゲルを溶融炉に投入して攪拌し、均一に混合する材料の準備・混合ステップと、均一に混合した混合物をキャスティング装置に送り込んでフィルム材を流延し、断熱フィルムをロール状に巻き取る断熱フィルムの製造ステップと、自動切断機を用いてガラスを切断し、切断したガラスをエッジ処理した後、自動洗浄・乾燥機にガラスを投入して洗浄するガラスの切断準備ステップと、ガラスを乾燥させた後、自動合わせラインに投入して断熱フィルムを貼り付け、断熱フィルムの表面を更に別のガラスで覆ってから、オートクレーブで加熱し、高圧をかけることで、フィルムと上下のガラスを溶融させ、しっかりと密着させるフィルム接着による完成品の合成ステップ、を含むナノシリコンガリウム断熱・防爆ガラスの製造方法を開示する。 Further, in the present invention, as a synthesis step, polyvinyl butyral resin, nanosilicon dioxide, nanogallium oxide (III), ethyl acetate, butyl acetate, methyl ether, nanozinc oxide and nanoairgel are put into a melting furnace and stirred. Using an automatic cutting machine, a step of preparing and mixing materials to be uniformly mixed, a step of manufacturing a heat insulating film in which the uniformly mixed mixture is sent to a casting device to spread the film material, and the heat insulating film is wound into a roll. The glass is cut, the cut glass is edge-treated, and then the glass is put into an automatic cleaning / drying machine to be cleaned. After attaching the film and covering the surface of the heat insulating film with another glass, heat it with an airgel and apply high pressure to melt the film and the upper and lower glass, and synthesize the finished product by film adhesion that firmly adheres. Disclose a method for manufacturing nanosilicon gallium heat-insulating and explosion-proof glass including steps.
材料の準備・混合プロセスにおける各原材料は、重量部換算で、それぞれ、ポリビニルブチラール樹脂８０〜９０重量部、ナノ二酸化ケイ素１〜２重量部、ナノ酸化ガリウム（ＩＩＩ）０．５〜１重量部、酢酸エチル２〜４重量部、酢酸ブチル２〜４重量部、メチルエーテル１〜２重量部、ナノ酸化亜鉛１〜３重量部、及びナノエアロゲル０．５〜１重量部である。 Each raw material in the material preparation / mixing process is 80 to 90 parts by weight of polyvinyl butyral resin, 1 to 2 parts by weight of nanosilicon dioxide, 0.5 to 1 part by weight of nanogallium oxide (III), respectively. 2 to 4 parts by weight of ethyl acetate, 2 to 4 parts by weight of butyl acetate, 1 to 2 parts by weight of methyl ether, 1 to 3 parts by weight of nanozinc oxide, and 0.5 to 1 part by weight of nanoaerogel.
材料の準備・混合プロセスでは、各原材料をそれぞれ溶融炉に投入して攪拌及び混合するが、具体的には、まず、ポリビニルブチラール樹脂を溶融炉に投入し、酢酸エチル、酢酸ブチル、メチルエーテルを加えて加熱及び攪拌した後、ナノ二酸化ケイ素を加えて攪拌し、ナノ酸化ガリウム（ＩＩＩ）を加えて攪拌してから、最後にナノエアロゲルを加えて攪拌する。 In the material preparation / mixing process, each raw material is put into a melting furnace and stirred and mixed. Specifically, first, polyvinyl butyral resin is put into a melting furnace, and ethyl acetate, butyl acetate, and methyl ether are added. After heating and stirring, nanosilicon dioxide is added and stirred, nanogallium oxide (III) is added and stirred, and finally nanoairgel is added and stirred.
断熱フィルムの製造プロセスでは、均一に攪拌した混合物を８０〜１２０度で加熱し、混合物を完全に溶融させてからキャスティング装置に送り込み、０．３〜１．２ＭＭのフィルム材に流延してから、断熱フィルムをロール状に巻き取る。 In the process of manufacturing a heat insulating film, a uniformly agitated mixture is heated at 80-120 degrees, the mixture is completely melted, then sent to a casting device and cast on a film material of 0.3-1.2 MM. , Wind the heat insulating film into a roll.
フィルム接着による完成品の合成プロセスでは、切断して準備したガラスについて更にガラス強化処理のプロセスを実施するが、具体的なプロセスとしては、きれいに洗浄したガラスを強化炉に投入して強化した後、ヒートソーク炉に強化後のガラスを投入して自爆させ、強化ガラスの応力を取り除いてから、ガラスを洗浄・乾燥した後に、自動合わせラインに投入してフィルム接着プロセスを実施する。 In the process of synthesizing the finished product by film bonding, the glass prepared by cutting is further subjected to the process of tempering the glass. As a specific process, the glass that has been thoroughly washed is put into a tempering furnace and strengthened, and then the glass is strengthened. After the tempered glass is put into a heat soak furnace and self-destructed to remove the stress of the tempered glass, the glass is washed and dried, and then put into an automatic alignment line to carry out a film bonding process.
本発明によれば、以下の有益な効果が得られる。 According to the present invention, the following beneficial effects can be obtained.
従来技術と比較して、本発明におけるナノシリコンガリウム断熱・防爆ガラスは、ナノ二酸化ケイ素とナノ酸化ガリウム（ＩＩＩ）を組み合わせて使用するため、製造されるガラスは、良好な透光性と断熱性及び保温性、紫外線遮断性、遮音性等の性能を備える。また、１平方メートルあたりの施工及び材料コストはＬＯＷ−Ｅガラス及び断熱フィルムの十分の一にすぎない。且つ、コーティング層は、良好な耐水性、高い表面硬度、強い付着力、良好な耐酸・耐アルカリ性、防カビ性、防湿性、耐温度差、耐摩耗性及び難燃性を備える。よって、自動車用ガラス、建築用ガラス、有機ガラスの透明性、断熱性・保温性及び省エネに幅広く応用可能であり、建築用フィルム等の同種の製品に代わる優良製品となる。 Compared with the prior art, the nanosilicon gallium adiabatic / explosion-proof glass in the present invention uses a combination of nanosilicon dioxide and nanogallium oxide (III), so that the produced glass has good translucency and adiabatic properties. It also has performance such as heat retention, UV blocking, and sound insulation. Also, the construction and material costs per square meter are only one tenth of LOW-E glass and heat insulating films. Moreover, the coating layer has good water resistance, high surface hardness, strong adhesive force, good acid / alkali resistance, mold resistance, moisture resistance, temperature difference, abrasion resistance and flame retardancy. Therefore, it can be widely applied to the transparency, heat insulation / heat retention, and energy saving of automobile glass, architectural glass, and organic glass, and it is an excellent product that replaces similar products such as architectural films.
本発明についてより明確に記載すべく、以下に、図面を組み合わせて本発明につき更に述べる。 In order to describe the present invention more clearly, the present invention will be further described below in combination with the drawings.
図１を参照して、本発明におけるナノシリコンガリウム断熱・防爆ガラスの製造方法は、以下の合成ステップを含む。 With reference to FIG. 1, the method for producing nanosilicon gallium adiabatic / explosion-proof glass in the present invention includes the following synthesis steps.
材料の準備・混合：まず、ポリビニルブチラール樹脂を溶融炉に投入し、酢酸エチル、酢酸ブチル、メチルエーテルを加えて加熱及び５分間攪拌する。続いて、ナノ二酸化ケイ素を加えて２分間攪拌し、ナノ酸化ガリウム（ＩＩＩ）を加えて２分間攪拌してから、最後にナノエアロゲルを加えて１０分間攪拌する。 Preparation and mixing of materials: First, the polyvinyl butyral resin is put into a melting furnace, ethyl acetate, butyl acetate and methyl ether are added, and the mixture is heated and stirred for 5 minutes. Subsequently, nanosilicon dioxide is added and stirred for 2 minutes, nanogallium oxide (III) is added and stirred for 2 minutes, and finally nanoairgel is added and stirred for 10 minutes.
断熱フィルムの製造：均一に攪拌した混合物を８０〜１２０度で加熱し、混合物を完全に溶融させてからキャスティング装置に送り込み、０．３〜１．２ＭＭのフィルム材に流延してから、断熱フィルムをロール状に巻き取る。 Manufacture of Insulation Film: A uniformly stirred mixture is heated at 80-120 degrees to completely melt the mixture before feeding it into a casting device, casting it on a film material of 0.3-1.2 MM and then insulating it. Wind the film into a roll.
ガラスの切断準備：自動切断機を用いてガラスを切断し、切断したガラスをエッジ処理した後、自動洗浄・乾燥機にガラスを投入して洗浄する。 Preparation for cutting glass: The glass is cut using an automatic cutting machine, the cut glass is edge-treated, and then the glass is put into an automatic washing / drying machine for cleaning.
ガラスの強化処理：きれいに洗浄したガラスを強化炉に投入して強化した後、ヒートソーク炉に強化後のガラスを投入して自爆させ、強化ガラスの応力を取り除く。次に、ガラスを洗浄・乾燥した後、自動合わせラインに投入してフィルム接着プロセスを実施する。 Glass strengthening treatment: After the cleanly washed glass is put into a tempered furnace and strengthened, the strengthened glass is put into a heat soak furnace and self-destructed to remove the stress of the tempered glass. Next, after the glass is washed and dried, it is put into an automatic alignment line to carry out a film bonding process.
フィルム接着による完成品の合成：ガラスを乾燥させた後、自動合わせラインに投入して断熱フィルムを貼り付け、断熱フィルムの表面を更に別のガラスで覆う。これをオートクレーブで加熱し、高圧をかけることで、フィルムと上下のガラスを溶融させ、しっかりと密着させる。 Synthesis of finished product by film bonding: After the glass is dried, it is put into an automatic alignment line to attach a heat insulating film, and the surface of the heat insulating film is covered with another glass. By heating this in an autoclave and applying high pressure, the film and the upper and lower glass are melted and firmly adhered.
本実施例では、材料の準備・混合プロセスにおける各原材料は、重量部換算で、それぞれ、ポリビニルブチラール樹脂８０〜９０重量部、ナノ二酸化ケイ素１〜２重量部、ナノ酸化ガリウム（ＩＩＩ）０．５〜１重量部、酢酸エチル２〜４重量部、酢酸ブチル２〜４重量部、メチルエーテル１〜２重量部、ナノ酸化亜鉛１〜３重量部、及びナノエアロゲル０．５〜１重量部である。 In this embodiment, each raw material in the material preparation / mixing process is 80 to 90 parts by weight of polyvinyl butyral resin, 1 to 2 parts by weight of nanosilicon dioxide, and 0.5 parts by weight of nanogallium oxide (III), respectively. ~ 1 part by weight, ethyl acetate 2-4 parts by weight, butyl acetate 2-4 parts by weight, methyl ether 1-2 parts by weight, nanozinc oxide 1-3 parts by weight, and nanoaerogel 0.5-1 part by weight. ..
各原材料は、以下の３つの割合で配合可能である。 Each raw material can be blended in the following three ratios.
１．ポリビニルブチラール樹脂８５重量部、ナノ二酸化ケイ素１．５重量部、ナノ酸化ガリウム（ＩＩＩ）０．５重量部、酢酸エチル２重量部、酢酸ブチル２重量部、メチルエーテル１重量部、ナノ酸化亜鉛１．５重量部、及びナノエアロゲル０．５重量部。 1. 1. 85 parts by weight of polyvinyl butyral resin, 1.5 parts by weight of nanosilicon dioxide, 0.5 parts by weight of nanogallium oxide (III), 2 parts by weight of ethyl acetate, 2 parts by weight of butyl acetate, 1 part by weight of methyl ether, 1 part by weight of nanozinc oxide .5 parts by weight and 0.5 parts by weight of nano airgel.
２．ポリビニルブチラール樹脂８０重量部、ナノ二酸化ケイ素１重量部、ナノ酸化ガリウム（ＩＩＩ）０．５重量部、酢酸エチル２重量部、酢酸ブチル２重量部、メチルエーテル１重量部、ナノ酸化亜鉛１重量部、及びナノエアロゲル０．５重量部。 2. 2. 80 parts by weight of polyvinyl butyral resin, 1 part by weight of nanosilicon dioxide, 0.5 part by weight of nanogallium oxide (III), 2 parts by weight of ethyl acetate, 2 parts by weight of butyl acetate, 1 part by weight of methyl ether, 1 part by weight of nanozinc oxide , And nano airgel 0.5 parts by weight.
３．ポリビニルブチラール樹脂９０重量部、ナノ二酸化ケイ素２重量部、ナノ酸化ガリウム（ＩＩＩ）１重量部、酢酸エチル４重量部、酢酸ブチル４重量部、メチルエーテル２重量部、ナノ酸化亜鉛３重量部、及びナノエアロゲル１重量部。 3. 3. 90 parts by weight of polyvinyl butyral resin, 2 parts by weight of nano-silicon dioxide, 1 part by weight of nano-gallium (III) oxide, 4 parts by weight of ethyl acetate, 4 parts by weight of butyl acetate, 2 parts by weight of methyl ether, 3 parts by weight of nano-zinc oxide, and 1 part by weight of nano airgel.
以上の開示は本発明におけるいくつかの具体的実施例にすぎず、本発明はこれらに限定されない。当業者が考え得るあらゆる変形は、いずれも本発明による保護の範囲に含まれる。 The above disclosure is only a few specific examples in the present invention, and the present invention is not limited thereto. Any modifications that can be considered by those skilled in the art are included in the scope of protection according to the present invention.
Claims (7)
ポリビニルブチラール樹脂８０〜９０重量部、
ナノ二酸化ケイ素１〜２重量部、及び
ナノ酸化ガリウム（ＩＩＩ）０．５〜１重量部、を成分として含むことを特徴とするナノシリコンガリウム断熱・防爆ガラス。 It contains two pieces of glass and one layer of heat insulating film, the heat insulating film is sandwiched between two pieces of glass, and the heat insulating film is converted into parts by weight.
80-90 parts by weight of polyvinyl butyral resin,
Nanosilicon gallium heat-insulating and explosion-proof glass, which comprises 1 to 2 parts by weight of nano-silicon dioxide and 0.5 to 1 part by weight of nano-gallium (III) oxide as components.
ポリビニルブチラール樹脂、ナノ二酸化ケイ素、ナノ酸化ガリウム（ＩＩＩ）、酢酸エチル、酢酸ブチル、メチルエーテル、ナノ酸化亜鉛及びナノエアロゲルを溶融炉に投入して攪拌し、均一に混合する材料の準備・混合ステップと、
均一に混合した混合物をキャスティング装置に送り込んでフィルム材を流延し、断熱フィルムをロール状に巻き取る断熱フィルムの製造ステップと、
自動切断機を用いてガラスを切断し、切断したガラスをエッジ処理した後、自動洗浄・乾燥機にガラスを投入して洗浄するガラスの切断準備ステップと、
ガラスを乾燥させた後、自動合わせラインに投入して断熱フィルムを貼り付け、断熱フィルムの表面を更に別のガラスで覆ってから、オートクレーブで加熱し、高圧をかけることで、フィルムと上下のガラスを溶融させ、しっかりと密着させるフィルム接着による完成品の合成ステップ、を含むことを特徴とするナノシリコンガリウム断熱・防爆ガラスの製造方法。 As a synthesis step
Polyvinyl butyral resin, nano-silicon dioxide, nano-gallium oxide (III), ethyl acetate, butyl acetate, methyl ether, nano-zinc oxide and nano-airgel are put into a melting furnace and stirred to prepare and mix materials uniformly. When,
A step of manufacturing a heat insulating film in which a uniformly mixed mixture is sent to a casting device, the film material is cast, and the heat insulating film is wound into a roll.
The glass is cut using an automatic cutting machine, the cut glass is edge-treated, and then the glass is put into an automatic washing / drying machine to be washed.
After drying the glass, put it in the automatic alignment line, attach the heat insulating film, cover the surface of the heat insulating film with another glass, heat it with an autoclave, and apply high pressure to the film and the upper and lower glass. A method for manufacturing nanosilicon gallium heat-insulating and explosion-proof glass, which comprises a step of synthesizing a finished product by film bonding, in which the glass is melted and firmly adhered.
きれいに洗浄したガラスを強化炉に投入して強化した後、ヒートソーク炉に強化後のガラスを投入して自爆させ、強化ガラスの応力を取り除いてから、ガラスを洗浄・乾燥した後に、自動合わせラインに投入してフィルム接着プロセスを実施することを特徴とする請求項４に記載のナノシリコンガリウム断熱・防爆ガラスの製造方法。 In the process of synthesizing the finished product by film bonding, a glass strengthening process is further carried out on the glass prepared by cutting. As a specific process,
After putting the thoroughly washed glass into the tempered glass and strengthening it, put the strengthened glass into the heat soak furnace and let it self-destruct to remove the stress of the tempered glass, then wash and dry the glass, and then put it on the automatic alignment line. The method for producing nanosilicon gallium heat-insulating / explosion-proof glass according to claim 4 , wherein the film is charged and the film bonding process is carried out.
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