JP6744215B2 - 迅速な泡つぶれを有する洗浄組成物 - Google Patents
迅速な泡つぶれを有する洗浄組成物 Download PDFInfo
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- JP6744215B2 JP6744215B2 JP2016534678A JP2016534678A JP6744215B2 JP 6744215 B2 JP6744215 B2 JP 6744215B2 JP 2016534678 A JP2016534678 A JP 2016534678A JP 2016534678 A JP2016534678 A JP 2016534678A JP 6744215 B2 JP6744215 B2 JP 6744215B2
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- cleaning composition
- surfactant
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- 239000000203 mixture Substances 0.000 title claims description 84
- 238000004140 cleaning Methods 0.000 title claims description 78
- 239000006260 foam Substances 0.000 title description 14
- 150000001875 compounds Chemical class 0.000 claims description 99
- -1 2-ethylhexyl group Chemical group 0.000 claims description 40
- 239000004094 surface-active agent Substances 0.000 claims description 39
- 125000002947 alkylene group Chemical group 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- MMXKVMNBHPAILY-UHFFFAOYSA-N ethyl laurate Chemical compound CCCCCCCCCCCC(=O)OCC MMXKVMNBHPAILY-UHFFFAOYSA-N 0.000 claims description 10
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 7
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 6
- RGXWDWUGBIJHDO-UHFFFAOYSA-N ethyl decanoate Chemical compound CCCCCCCCCC(=O)OCC RGXWDWUGBIJHDO-UHFFFAOYSA-N 0.000 claims description 6
- 150000003505 terpenes Chemical class 0.000 claims description 6
- 235000007586 terpenes Nutrition 0.000 claims description 6
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- YYZUSRORWSJGET-UHFFFAOYSA-N ethyl octanoate Chemical compound CCCCCCCC(=O)OCC YYZUSRORWSJGET-UHFFFAOYSA-N 0.000 claims description 5
- 239000007859 condensation product Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- ZRNCNTSXSYXHOW-UHFFFAOYSA-N butyl decanoate Chemical compound CCCCCCCCCC(=O)OCCCC ZRNCNTSXSYXHOW-UHFFFAOYSA-N 0.000 claims description 3
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
- 239000006265 aqueous foam Substances 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 description 20
- 150000003839 salts Chemical class 0.000 description 11
- 239000000126 substance Substances 0.000 description 10
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 10
- 239000002253 acid Substances 0.000 description 9
- 150000001412 amines Chemical class 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 239000002736 nonionic surfactant Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 5
- 238000005187 foaming Methods 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 4
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 4
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- KCQUJORJVXQRST-UHFFFAOYSA-N acetic acid;ethane-1,2-diamine Chemical compound CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.NCCN KCQUJORJVXQRST-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000012459 cleaning agent Substances 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 229930182478 glucoside Natural products 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 3
- YEYKMVJDLWJFOA-UHFFFAOYSA-N 2-propoxyethanol Chemical compound CCCOCCO YEYKMVJDLWJFOA-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 2
- 125000006528 (C2-C6) alkyl group Chemical group 0.000 description 2
- GZMAAYIALGURDQ-UHFFFAOYSA-N 2-(2-hexoxyethoxy)ethanol Chemical compound CCCCCCOCCOCCO GZMAAYIALGURDQ-UHFFFAOYSA-N 0.000 description 2
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 2
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- ZTVCAEHRNBOTLI-UHFFFAOYSA-L Glycine, N-(carboxymethyl)-N-(2-hydroxyethyl)-, disodium salt Chemical compound [Na+].[Na+].OCCN(CC([O-])=O)CC([O-])=O ZTVCAEHRNBOTLI-UHFFFAOYSA-L 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000004676 glycans Polymers 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000004530 micro-emulsion Substances 0.000 description 2
- 229930003658 monoterpene Natural products 0.000 description 2
- 150000002773 monoterpene derivatives Chemical class 0.000 description 2
- 235000002577 monoterpenes Nutrition 0.000 description 2
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- IBOBFGGLRNWLIL-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)[O-] IBOBFGGLRNWLIL-UHFFFAOYSA-N 0.000 description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 2
- 229960003330 pentetic acid Drugs 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 150000004804 polysaccharides Polymers 0.000 description 2
- NDVASEGYNIMXJL-UHFFFAOYSA-N sabinene Chemical compound C=C1CCC2(C(C)C)C1C2 NDVASEGYNIMXJL-UHFFFAOYSA-N 0.000 description 2
- 229930004725 sesquiterpene Natural products 0.000 description 2
- 150000004354 sesquiterpene derivatives Chemical class 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- FVEFRICMTUKAML-UHFFFAOYSA-M sodium tetradecyl sulfate Chemical compound [Na+].CCCCC(CC)CCC(CC(C)C)OS([O-])(=O)=O FVEFRICMTUKAML-UHFFFAOYSA-M 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000002888 zwitterionic surfactant Substances 0.000 description 2
- NPNUFJAVOOONJE-ZIAGYGMSSA-N β-(E)-Caryophyllene Chemical compound C1CC(C)=CCCC(=C)[C@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-ZIAGYGMSSA-N 0.000 description 2
- NDVASEGYNIMXJL-NXEZZACHSA-N (+)-sabinene Natural products C=C1CC[C@@]2(C(C)C)[C@@H]1C2 NDVASEGYNIMXJL-NXEZZACHSA-N 0.000 description 1
- QEBNYNLSCGVZOH-NFAWXSAZSA-N (+)-valencene Chemical compound C1C[C@@H](C(C)=C)C[C@@]2(C)[C@H](C)CCC=C21 QEBNYNLSCGVZOH-NFAWXSAZSA-N 0.000 description 1
- ITYNGVSTWVVPIC-DHGKCCLASA-N (-)-allo-Aromadendrene Chemical compound C([C@@H]1[C@H]2C1(C)C)CC(=C)[C@@H]1[C@H]2[C@H](C)CC1 ITYNGVSTWVVPIC-DHGKCCLASA-N 0.000 description 1
- 239000001890 (2R)-8,8,8a-trimethyl-2-prop-1-en-2-yl-1,2,3,4,6,7-hexahydronaphthalene Substances 0.000 description 1
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 description 1
- 125000006710 (C2-C12) alkenyl group Chemical group 0.000 description 1
- 125000006711 (C2-C12) alkynyl group Chemical group 0.000 description 1
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- QCTZUSWOKFCWNB-QXMHVHEDSA-N (z)-n,n-dimethyloctadec-9-en-1-amine oxide Chemical compound CCCCCCCC\C=C/CCCCCCCC[N+](C)(C)[O-] QCTZUSWOKFCWNB-QXMHVHEDSA-N 0.000 description 1
- LAVARTIQQDZFNT-UHFFFAOYSA-N 1-(1-methoxypropan-2-yloxy)propan-2-yl acetate Chemical compound COCC(C)OCC(C)OC(C)=O LAVARTIQQDZFNT-UHFFFAOYSA-N 0.000 description 1
- 239000005968 1-Decanol Substances 0.000 description 1
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 1
- QGJDXUIYIUGQGO-UHFFFAOYSA-N 1-[2-[(2-methylpropan-2-yl)oxycarbonylamino]propanoyl]pyrrolidine-2-carboxylic acid Chemical compound CC(C)(C)OC(=O)NC(C)C(=O)N1CCCC1C(O)=O QGJDXUIYIUGQGO-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- FENFUOGYJVOCRY-UHFFFAOYSA-N 1-propoxypropan-2-ol Chemical compound CCCOCC(C)O FENFUOGYJVOCRY-UHFFFAOYSA-N 0.000 description 1
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- WMDZKDKPYCNCDZ-UHFFFAOYSA-N 2-(2-butoxypropoxy)propan-1-ol Chemical compound CCCCOC(C)COC(C)CO WMDZKDKPYCNCDZ-UHFFFAOYSA-N 0.000 description 1
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 description 1
- LCVQGUBLIVKPAI-UHFFFAOYSA-N 2-(2-phenoxypropoxy)propan-1-ol Chemical compound OCC(C)OCC(C)OC1=CC=CC=C1 LCVQGUBLIVKPAI-UHFFFAOYSA-N 0.000 description 1
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 description 1
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 description 1
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 description 1
- DENWXVJCXRNUNB-UHFFFAOYSA-N 2-[dodecyl-[2-(2-hydroxyethoxy)ethyl]amino]ethanol Chemical compound CCCCCCCCCCCCN(CCO)CCOCCO DENWXVJCXRNUNB-UHFFFAOYSA-N 0.000 description 1
- NIFPWUCDSCRTCA-UHFFFAOYSA-N 2-decyl-n,n-dimethyltetradecan-1-amine oxide Chemical compound CCCCCCCCCCCCC(C[N+](C)(C)[O-])CCCCCCCCCC NIFPWUCDSCRTCA-UHFFFAOYSA-N 0.000 description 1
- LLCXFSRLSYMSPW-UHFFFAOYSA-N 2-ethylhexan-1-ol;2-methyloxirane;oxirane Chemical compound C1CO1.CC1CO1.CCCCC(CC)CO LLCXFSRLSYMSPW-UHFFFAOYSA-N 0.000 description 1
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical class CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 1
- TUBRCQBRKJXJEA-UHFFFAOYSA-N 3-[hexadecyl(dimethyl)azaniumyl]propane-1-sulfonate Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CCCS([O-])(=O)=O TUBRCQBRKJXJEA-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- NVEQFIOZRFFVFW-UHFFFAOYSA-N 9-epi-beta-caryophyllene oxide Natural products C=C1CCC2OC2(C)CCC2C(C)(C)CC21 NVEQFIOZRFFVFW-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
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- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
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- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
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- FEFAREAYTNHYNP-UHFFFAOYSA-K tripotassium;[bis[[hydroxy(oxido)phosphoryl]methyl]-oxidoazaniumyl]methyl-hydroxyphosphinate Chemical compound [K+].[K+].[K+].OP([O-])(=O)C[N+]([O-])(CP(O)([O-])=O)CP(O)([O-])=O FEFAREAYTNHYNP-UHFFFAOYSA-K 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/188—Terpenes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2037—Terpenes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
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Description
消費者は、硬表面洗浄剤の泡立ちを、その洗浄剤の効率及び有効性と関連するものとして連想する。したがって、洗浄力または有効性を示すために、洗浄剤が初めに泡立つことが望ましい。泡立ちは、スプレー散布器により提供されるもの等の撹拌により増強され得る。また、洗浄剤の機能を知らせ、望ましいすすぎ特性を示すために、泡が迅速につぶれることも望ましい。米国特許第2013/269727 A1号は、泡立ち洗浄剤ではなく、特許請求された組成物中に存在しない非イオン性界面活性剤のリン酸エステル等の結合剤を必要とする、アスファルトからゴムを除去するための溶剤系洗浄剤に関する。国際公開第02/04589 A1号は、下部水相/上部油相を有する2相洗浄産物に関する。国際公開第2006/004721 A1号は、垂直に貼り付き、3〜50%の一次溶媒を含有する、すなわち、C6〜22飽和もしくは不飽和のカルボン酸の特定のC1〜4アルキルエステルが、アニオン性界面活性剤、短鎖共界面活性剤、及び増粘剤を含有する、古い塗料を除去するためのマイクロエマルション組成物に関する。米国特許第5877133 A号は、C11〜C13脂肪酸の低級(C1〜C4)アルキルエステル、非イオン性界面活性剤、及びエチレングリコールエーテル、一価アルコール、多価アルコール、または任意の組み合わせから選択される結合剤に関する。国際公開第2006/007371 A1号は、1部に酸化剤を有し、使用時に混合される2部構成の洗浄組成物に関する。米国特許第2011/190187 A1号は、有機残渣剥離剤、3%超のグリコール、7%超の芳香族アルコールに関する。
10MPa0.5≦δD≦22MPa0.5、0≦δP≦10MPa0.5、及び0≦δH≦14MPa0.5のハンセン溶解度パラメータを有する第2の化合物の使用が、望ましい結果を提供することが発見された。第1の化合物は、12MPa0.5≦δD≦18MPa0.5、0≦δP≦12MPa0.5、及び0≦δH≦9MPa0.5、具体的には、15MPa0.5≦δD≦17MPa0.5、0≦δP≦4MPa0.5、及び0≦δH≦5MPa0.5のハンセン溶解度パラメータを有してもよい。
R3−(OCnH2n)zOX (2)
式中、R3は、置換もしくは非置換C1〜C12脂肪族基、置換もしくは非置換C6〜C12アリール基、式−C(=O)C6H5の基、または式−C(=O)CH3の基であり、nは2〜4であり、zは1〜4であり、Xは、−H、−CH3、−C(=O)CH3、または−C(=O)C6H5である、化合物を含む。
R3−(OCnH2n)zOX(2)
式中、R3は、置換もしくは非置換C1〜C12脂肪族基、置換もしくは非置換C6〜C12アリール基、式−C(=O)C6H5の基、または式−C(=O)CH3の基であり、nは2〜4であり、zは1〜4であり、Xは、−H、−CH3、−C(=O)CH3、または−C(=O)C6H5である、化合物を含んでもよく、かつ/または(10)R3は、非置換C2〜C6アルキル基であり、nは2〜4であり、zは1〜3であってもよく、かつ/または(11)第1の化合物及び第2の化合物はそれぞれ独立して、80〜750ダルトンの分子量を有してもよく、かつ/または(12)界面活性剤、第1の化合物、及び第2の化合物はそれぞれ独立して、洗浄組成物の総重量に基づいて、0.1〜10重量パーセントの量で含まれてもよい。
それぞれの実施例(E)及び比較例(C)において、洗浄剤は、初めに、水をガラス製の瓶に入れて計量し、撹拌棒を加え、次いで、500回転毎分(rpm)で撹拌しながら、界面活性剤を添加し、続いて、存在する場合、水と不混和性化合物及び水と混和性化合物を添加することにより、表4〜10に提供される量(g)を用いて調製された。10分間撹拌した後、存在する場合、残りの成分を撹拌しながら添加した。
TRITON(商標)CG50、TRITON(商標)CG425、TRITON(商標)CG600、TRITON(商標)CG650、TRITON(商標)DF16、TRITON(商標)CF10、TRITON(商標)LF20、及びTRITON(商標)X45は、the Dow Chemical Companyから入手した。
Minfoam(商標)1x及びMinfoam(商標)2xは、the Dow Chemical Companyから入手した。
Tergitol(商標)15−S−9は、the Dow Chemical Companyから入手した。
EcoSsense(商標)3000は、the Dow Chemical Companyから入手した。
Versenex(商標)80は、40%のジエチレントリアミン五酢酸五ナトリウム水溶液であり、the Dow Chemical Companyから受け取った状態で使用した。
過酸化水素は、35%の水溶液である。
PEG/PPG−17/6コポリマーの製品UCON(商標)75−H−450は、the Dow Chemical Companyから入手した。
UCON(商標)OSP−32は、the Dow Chemical Companyから入手した。
撹拌した後、撹拌棒を取り出し、ガラス製の瓶に蓋をかぶせた。次いで、ガラス製の瓶を10秒間激しく振とうした。泡立ちからつぶれまでの時間を測定して、表3に従って泡つぶれの等級を得た。
消費者特殊製品協会(CSPA)の方法DC−17に従って光沢試験(消費者特殊製品協会(Washington D.C)から入手可能である)を用いて硬表面洗浄の評価を行った。タイルは、CSPAの方法DC−17に従って、乳汁、ラード、オリーブ油、バンディ粘土、及びカーボンブラックを用いて染色した。次に、2ミリリットル(mL)の表11及び12に提供される製剤を、光沢機を用いて染色したタイルに塗布し、タイルの表面をスポンジで10回拭き取り、5つの完全なサイクルを得た。洗浄したタイルを1が不良であり、10が清浄である、1〜10の尺度に評価した。
[1] 水性洗浄組成物であって、
界面活性剤と、
水と不混和性であり、
10MPa 0.5 ≦δ D ≦22MPa 0.5 、0≦δ P ≦14MPa 0.5 、及び0≦δ H ≦14MPa 0.5 のハンセン溶解度パラメータを有する第1の化合物と、
水と混和性であり、10MPa 0.5 ≦δ D ≦22MPa 0.5 、0≦δ P ≦10MPa 0.5 、及び0≦δ H ≦14MPa 0.5 のハンセン溶解度パラメータを有する第2の化合物と、を含み、
前記界面活性剤、前記第1の化合物、及び前記第2の化合物がそれぞれ独立して、前記洗浄組成物の総重量に基づいて、0.01〜30重量パーセントの量で含まれる、前記水性洗浄組成物。
[2] 前記界面活性剤が、置換もしくは非置換C6〜C22脂肪族アルコールの非イオン性C2〜C4アルキレンオキシド縮合物、置換もしくは非置換C6〜C12アルキルフェノールのC2〜C4アルキレンオキシド縮合物、アルキルサッカライド、アミンオキシド、アルキルジフェニルオキシドジスルホネート、またはそれらの組み合わせである、上記態様1に記載の前記洗浄組成物。
[3] 前記界面活性剤が、非置換C6〜C22脂肪族アルコールのC2〜C4アルキレンオキシド縮合物であり、前記脂肪族アルコール1モル当たり2〜9モルのアルキレンオキシド基を含む、上記態様1または2に記載の前記洗浄組成物。
[4] 前記アルキレンオキシドが、エチレンオキシド、プロピレンオキシド、またはそれらの組み合わせである、上記態様1〜3のいずれかに記載の前記洗浄組成物。
[5] 前記界面活性剤が、8〜14の親水性−親油性バランスを有する、上記態様1〜4のいずれかに記載の前記洗浄組成物。
[6] 前記第1の化合物が、15MPa 0.5 ≦δ D ≦17MPa 0.5 、0≦δ P ≦4MPa 0.5 、及び0≦δ H ≦5MPa 0.5 のハンセン溶解度パラメータを有し、
前記第2の化合物が、14MPa 0.5 ≦δ D ≦17MPa 0.5 、1≦δ P ≦7MPa 0.5 、及び7≦δ H ≦12MPa 0.5 のハンセン溶解度パラメータを有する、上記態様1〜5のいずれかに記載の前記洗浄組成物。
[7] 但し、前記第2の化合物が、7.1未満のδ P 及び12.1未満のδ H を有するものとする、上記態様1〜6のいずれかに記載の前記洗浄組成物。
[8] 前記第1の化合物が、置換または非置換テルペンであるか、
式1の化合物であって、
それらの組み合わせである、上記態様1〜7のいずれかに記載の前記洗浄組成物。
[9] R 2 が、非置換C2〜C4アルキル基である、上記態様1〜8のいずれかに記載の前記洗浄組成物。
[10] 前記第2の化合物が、
式2の化合物であって、
R 3 −(OC n H 2n ) z OX (2)
式中、
R 3 が、置換もしくは非置換C1〜C12脂肪族基、置換もしくは非置換C6〜12アリール基、式−C(=O)C 6 H 5 の基、または式−C(=O)CH 3 の基であり、
nが2〜12であり、
zが1〜4であり、
Xが、−H、−CH 3 、−C(=O)CH 3 、または−C(=O)C 6 H 5 である、化合物を含む、上記態様1〜9のいずれかに記載の前記洗浄組成物。
[11] 前記第2の化合物が、
式2の化合物であって、
R 3 −(OC n H 2n ) z OX (2)
式中、
R 3 が、置換もしくは非置換C1〜C12脂肪族基、置換もしくは非置換C6〜C12アリール基、式−C(=O)C 6 H 5 の基、または式−C(=O)CH 3 の基であり、
nが2〜4であり、
zが1〜4であり、
Xが、−H、−CH 3 、−C(=O)CH 3 、または−C(=O)C 6 H 5 である、化合物を含む、上記態様1〜10のいずれかに記載の前記洗浄組成物。
[12] R 3 が、非置換C2〜C6アルキル基であり、nが2〜4であり、zが1〜3である、上記態様1〜11のいずれかに記載の前記洗浄組成物。
[13] 前記第1の化合物及び前記第2の化合物がそれぞれ独立して、80〜750ダルトンの分子量を有する、上記態様1〜12のいずれかに記載の前記洗浄組成物。
[14] 前記界面活性剤、前記第1の化合物、及び前記第2の化合物がそれぞれ独立して、前記洗浄組成物の総重量に基づいて、0.1〜10重量パーセントの量で含まれる、上記態様1〜13のいずれかに記載の前記洗浄組成物。
[15] 水性洗浄組成物を製造する方法であって、
界面活性剤と、
水と不混和性であり、10MPa 0.5 ≦δ D ≦22MPa 0.5 、0≦δ P ≦14MPa 0.5 、及び0≦δ H ≦14MPa 0.5 のハンセン溶解度パラメータを有する第1の化合物と、
水と混和性であり、10MPa 0.5 ≦δ D ≦22MPa 0.5 、0≦δ P ≦10MPa 0.5 、及び0≦δ H ≦14MPa 0.5 のハンセン溶解度パラメータを有する第2の化合物と、を組み合わせて、前記洗浄組成物を製造することを含む、前記方法。
[16] 表面を洗浄する方法であって、前記表面を、上記態様1に記載の前記洗浄組成物と接触させることと、前記表面から汚れ及び前記洗浄組成物を除去することと、を含む、前記方法。
Claims (9)
- 水性泡立ち洗浄組成物であって、
2−エチルへキシル基を有するアルコールの、該アルコール1モル当たり2〜9モルのエチレンオキシド及びプロピレンオキシドの縮合産物であり、8.5〜13.5の親水性−親油性バランスを有する非イオン性アルコキシル化界面活性剤と、
オクタン酸エチル、オクタン酸ブチル、デカン酸エチル、デカン酸ブチル、ラウリン酸エチル、またはこれらの組み合わせを含む第1の化合物と、
水に混和性であり、14MPa0.5≦δD≦17MPa0.5、1≦δP≦7MPa0.5、及び7≦δH≦12MPa0.5のハンセン溶解度パラメータを有する第2の化合物と、を含み、
前記界面活性剤、前記第1の化合物、及び前記第2の化合物がそれぞれ独立して、前記洗浄組成物の総重量に基づいて、0.2〜8重量パーセントの量で含まれる、前記水性泡立ち洗浄組成物。 - 前記界面活性剤が、9〜13の親水性−親油性バランスを有する、請求項1に記載の前記洗浄組成物。
- 置換または非置換テルペンをさらに含む、請求項1または2に記載の前記洗浄組成物。
- 前記第2の化合物が、
式2の化合物であって、
R3−(OCnH2n)zOX (2)
式中、
R3が、置換もしくは非置換C1〜C12脂肪族基、置換もしくは非置換C6〜12アリール基、式−C(=O)C6H5の基、または式−C(=O)CH3の基であり、
nが2〜12であり、
zが1〜4であり、
Xが、−H、−CH3、−C(=O)CH3、または−C(=O)C6H5である、化合物を含む、請求項1〜3のいずれかに記載の前記洗浄組成物。 - R3が非置換のC2〜C6アルキル基であり、nが2〜4であり、そしてzが1〜3である、請求項4に記載の前記洗浄組成物。
- 第1の化合物及び第2の化合物が各々独立に80〜750ダルトンの分子量を有する、請求項1〜5のいずれかに記載の前記洗浄組成物。
- 前記界面活性剤、前記第1の化合物、及び前記第2の化合物がそれぞれ独立して、前記洗浄組成物の総重量に基づいて、0.6〜4重量パーセントの量で含まれる、請求項1〜6のいずれかに記載の前記洗浄組成物。
- 水性洗浄組成物を製造する方法であって、
アルコール1モル当たり1〜15モルのアルキレンオキシドを含む脂肪族または芳香族アルコールのアルキレンオキシド縮合産物である非イオン性アルコキシル化界面活性剤であって、前記アルキレンオキシドが、エチレンオキシド、プロピレンオキシド、またはそれらの組み合わせである、非イオン性アルコキシル化界面活性剤と、
オクタン酸エチル、オクタン酸ブチル、デカン酸エチル、デカン酸ブチル、ラウリン酸エチル、またはこれらの組み合わせを含む第1の化合物と、
水混和性であり、14MPa0.5≦δD≦17MPa0.5、1≦δP≦7MPa0.5、及び7≦δH≦12MPa0.5のハンセン溶解度パラメータを有する第2の化合物と、を組み合わせて、前記洗浄組成物を製造することを含む、前記方法。 - 表面を洗浄する方法であって、前記表面を、請求項1に記載の前記洗浄組成物と接触させて泡を形成することと、前記表面から汚れ及び前記洗浄組成物を除去することと、を含む、前記方法。
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- 2014-11-21 US US15/038,548 patent/US10138443B2/en active Active
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- 2014-11-21 EP EP14808796.8A patent/EP3077492A1/en not_active Ceased
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2020
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US10138443B2 (en) | 2018-11-27 |
JP2020128557A (ja) | 2020-08-27 |
AU2014357506B2 (en) | 2018-06-14 |
BR112016011742A2 (pt) | 2017-08-08 |
EP3077492A1 (en) | 2016-10-12 |
AU2014357506A1 (en) | 2016-07-14 |
JP6940652B2 (ja) | 2021-09-29 |
WO2015084610A1 (en) | 2015-06-11 |
JP2016540855A (ja) | 2016-12-28 |
CN105765046A (zh) | 2016-07-13 |
US20160298059A1 (en) | 2016-10-13 |
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