JP6742996B2 - チタン合金 - Google Patents
チタン合金 Download PDFInfo
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- JP6742996B2 JP6742996B2 JP2017521288A JP2017521288A JP6742996B2 JP 6742996 B2 JP6742996 B2 JP 6742996B2 JP 2017521288 A JP2017521288 A JP 2017521288A JP 2017521288 A JP2017521288 A JP 2017521288A JP 6742996 B2 JP6742996 B2 JP 6742996B2
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- JP
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- Prior art keywords
- titanium alloy
- alloy according
- titanium
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- additionally
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 229910001069 Ti alloy Inorganic materials 0.000 title claims description 47
- 239000010936 titanium Substances 0.000 claims description 32
- 229910045601 alloy Inorganic materials 0.000 claims description 29
- 239000000956 alloy Substances 0.000 claims description 29
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 23
- 229910052719 titanium Inorganic materials 0.000 claims description 19
- 239000010931 gold Substances 0.000 claims description 14
- 239000007943 implant Substances 0.000 claims description 13
- 239000010955 niobium Substances 0.000 claims description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 8
- 229910052737 gold Inorganic materials 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 238000005275 alloying Methods 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 239000011651 chromium Substances 0.000 claims description 7
- 229910052758 niobium Inorganic materials 0.000 claims description 7
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 239000011733 molybdenum Substances 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 claims description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 230000003044 adaptive effect Effects 0.000 claims 1
- 239000002994 raw material Substances 0.000 claims 1
- 239000000463 material Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 210000000988 bone and bone Anatomy 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 238000001595 flow curve Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 241000894007 species Species 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- 229910001040 Beta-titanium Inorganic materials 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 229910001092 metal group alloy Inorganic materials 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910000967 As alloy Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 210000001124 body fluid Anatomy 0.000 description 2
- 239000010839 body fluid Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- ZNKMCMOJCDFGFT-UHFFFAOYSA-N gold titanium Chemical compound [Ti].[Au] ZNKMCMOJCDFGFT-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 229910001258 titanium gold Inorganic materials 0.000 description 2
- 208000024827 Alzheimer disease Diseases 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 229910011212 Ti—Fe Inorganic materials 0.000 description 1
- 229910003077 Ti−O Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000002048 anodisation reaction Methods 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 210000001624 hip Anatomy 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229910001456 vanadium ion Inorganic materials 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L27/00—Materials for grafts or prostheses or for coating grafts or prostheses
- A61L27/02—Inorganic materials
- A61L27/04—Metals or alloys
- A61L27/06—Titanium or titanium alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/16—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
- C22F1/18—High-melting or refractory metals or alloys based thereon
- C22F1/183—High-melting or refractory metals or alloys based thereon of titanium or alloys based thereon
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Animal Behavior & Ethology (AREA)
- Medicinal Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Transplantation (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dermatology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials For Medical Uses (AREA)
Description
a)0.2から1.5%の酸素(O)、
b)0.1から1.5%の鉄(Fe)、
c)0.01から2%の炭素(C)、
d)残りのチタン(Ti)。
以下、本願の出願当初の特許請求の範囲に記載した発明を付記する。
[1] 合金元素としてのアルミニウム(Al)、バナジウム(V)、コバルト(Co)、クロム(Cr)、ニッケル(Ni)、および錫(Sn)を排除したうえで、合金成分に含まれている、または製造中に取り込まれた不可避的な微量の不純物のほかに少なくとも次の合金成分
a)0.2から1.5%の酸素(O)、
b)0.1から1.5%の鉄(Fe)、
c)0.01から2%の炭素(C)、
d)残りのチタン(Ti)
を重量%で有している、特に生体適合的なインプラントに使用するためのチタン合金。
[2] 0.4%の酸素(O)を有することを特徴とする、[1]に記載のチタン合金。
[3] 0.5%の鉄(Fe)を有することを特徴とする、[1]または[2]に記載のチタン合金。
[4] 0.08%の炭素(C)を有することを特徴とする、[1]から[3]のいずれか1項に記載のチタン合金。
[5] 1%未満の金(Au)を追加的に有することを特徴とする、[1]から[4]のいずれか1項に記載のチタン合金。
[6] 0.1%の金(Au)を有することを特徴とする、[5]に記載のチタン合金。
[7] 1%未満のニオブ(Nb)を追加的に有することを特徴とする、[1]から[6]のいずれか1項に記載のチタン合金。
[8] 0.1%のニオブ(Nb)を有することを特徴とする、[7]に記載のチタン合金。
[9] 1%未満のモリブデン(Mo)を追加的に有することを特徴とする、[1]から[8]のいずれか1項に記載のチタン合金。
[10] 0.1%のモリブデン(Mo)を有することを特徴とする、[9]に記載のチタン合金。
[11] 1%未満のジルコニウム(Zr)を追加的に有することを特徴とする、[1]から[10]のいずれか1項に記載のチタン合金。
[12] 0.1%のジルコニウム(Zr)を有することを特徴とする、[11]に記載のチタン合金。
[13] 1.5%未満、特に0.4%未満の窒素(N)を追加的に有することを特徴とする、[1]から[12]のいずれか1項に記載のチタン合金。
[14] 0.2%の窒素(N)を有することを特徴とする、[13]に記載のチタン合金。
[15] 0.5%未満のケイ素(Si)を追加的に有することを特徴とする、[1]から[14]のいずれか1項に記載のチタン合金。
[16] 0.05%のケイ素(Si)を有することを特徴とする、[15]に記載のチタン合金。
[17] 0.2%未満の水素(H)を追加的に有することを特徴とする、[1]から[16]のいずれか1項に記載のチタン合金。
[18] [1]から[17]のいずれか1項に記載の合金で少なくとも部分的に構成されるインプラント、特に人工補綴用のインプラント。
Claims (17)
- 合金元素としてのアルミニウム(Al)、バナジウム(V)、コバルト(Co)、クロム(Cr)、ニッケル(Ni)、および錫(Sn)を排除したうえで、合金成分に含まれている、または製造中に取り込まれた不可避的な微量の不純物のほかに次の合金成分(以下、重量%)
a)0.2から1.5%の酸素(O)、
b)0.1から1.5%の鉄(Fe)、
c)0.01から2%の炭素(C)、
d)残りのチタン(Ti)と、
追加的な1%未満の金(Au)と、からなることを特徴とする生体適合的なインプラントに使用するためのチタン合金。 - 0.4%の酸素(O)を有することを特徴とする、請求項1に記載のチタン合金。
- 0.5%の鉄(Fe)を有することを特徴とする、請求項1または2に記載のチタン合金。
- 0.08%の炭素(C)を有することを特徴とする、請求項1から3のいずれか1項に記載のチタン合金。
- 0.1%の金(Au)を有することを特徴とする、請求項1に記載のチタン合金。
- 1%未満のニオブ(Nb)を追加的に有することを特徴とする、請求項1から5のいずれか1項に記載のチタン合金。
- 0.1%のニオブ(Nb)を有することを特徴とする、請求項6に記載のチタン合金。
- 1%未満のモリブデン(Mo)を追加的に有することを特徴とする、請求項1から7のいずれか1項に記載のチタン合金。
- 0.1%のモリブデン(Mo)を有することを特徴とする、請求項8に記載のチタン合金。
- 1%未満のジルコニウム(Zr)を追加的に有することを特徴とする、請求項1から9のいずれか1項に記載のチタン合金。
- 0.1%のジルコニウム(Zr)を有することを特徴とする、請求項10に記載のチタン合金。
- 1.5%未満、特に0.4%未満の窒素(N)を追加的に有することを特徴とする、請求項1から11のいずれか1項に記載のチタン合金。
- 0.2%の窒素(N)を有することを特徴とする、請求項12に記載のチタン合金。
- 0.5%未満のケイ素(Si)を追加的に有することを特徴とする、請求項1から13のいずれか1項に記載のチタン合金。
- 0.05%のケイ素(Si)を有することを特徴とする、請求項14に記載のチタン合金。
- 0.2%未満の水素(H)を追加的に有することを特徴とする、請求項1から15のいずれか1項に記載のチタン合金。
- 請求項1から16のいずれか1項に記載の合金で少なくとも部分的に構成されるインプラント。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102014010032.4A DE102014010032B4 (de) | 2014-07-08 | 2014-07-08 | Titanlegierung |
DE102014010032.4 | 2014-07-08 | ||
PCT/DE2015/100252 WO2016004918A1 (de) | 2014-07-08 | 2015-06-22 | Titanlegierung |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2017526822A JP2017526822A (ja) | 2017-09-14 |
JP6742996B2 true JP6742996B2 (ja) | 2020-08-19 |
Family
ID=53800789
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2017521288A Expired - Fee Related JP6742996B2 (ja) | 2014-07-08 | 2015-06-22 | チタン合金 |
Country Status (6)
Country | Link |
---|---|
US (1) | US10767244B2 (ja) |
EP (1) | EP3167088B1 (ja) |
JP (1) | JP6742996B2 (ja) |
DE (1) | DE102014010032B4 (ja) |
RU (1) | RU2722300C2 (ja) |
WO (1) | WO2016004918A1 (ja) |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS52115713A (en) * | 1976-03-25 | 1977-09-28 | Sumitomo Metal Ind Ltd | High tensile titanium having excellent hydrogen brittleness resistance |
JPH01252747A (ja) * | 1987-12-23 | 1989-10-09 | Nippon Steel Corp | 延性の優れた高強度チタン材及びその製造方法 |
ZA9010217B (en) * | 1989-12-21 | 1991-10-30 | Smith & Nephew Richards Inc | Biocompatible low modulus titanium alloy for medical implants |
JP3408683B2 (ja) * | 1995-12-01 | 2003-05-19 | 株式会社インジェックス | 歯科用器具 |
JPH1136029A (ja) * | 1997-05-21 | 1999-02-09 | Sumitomo Metal Ind Ltd | 高強度チタン合金鋳造品 |
JP2000096165A (ja) * | 1998-09-25 | 2000-04-04 | Sumitomo Metal Ind Ltd | 抗菌性および耐生物付着性に優れたTi合金およびその製造方法 |
DE19858889B4 (de) | 1998-12-19 | 2008-08-07 | Wolter, Dietmar, Prof. Dr.Med. | Fixationssystem für Knochen |
WO2001019268A1 (de) * | 1999-09-14 | 2001-03-22 | Dietmar Wolter | Fixationssystem für knochen |
JP4065644B2 (ja) * | 2000-03-16 | 2008-03-26 | 新日本製鐵株式会社 | 耐衝撃特性に優れた耐衝撃用冷間加工硬化チタン成品及びその製造方法 |
JP2004269982A (ja) * | 2003-03-10 | 2004-09-30 | Daido Steel Co Ltd | 高強度低合金チタン合金とその製造方法 |
KR100714244B1 (ko) * | 2004-04-26 | 2007-05-02 | 한국기계연구원 | 생체용 골유도성 금속 임플란트 및 그 제조방법 |
ATE479783T1 (de) * | 2005-05-23 | 2010-09-15 | Thyssenkrupp Vdm Gmbh | Titan-legierung |
US8337750B2 (en) * | 2005-09-13 | 2012-12-25 | Ati Properties, Inc. | Titanium alloys including increased oxygen content and exhibiting improved mechanical properties |
US7799711B2 (en) | 2007-08-31 | 2010-09-21 | Corning Incorporated | Photomachinable glass compositions having tunable photosensitivity |
JP4666271B2 (ja) * | 2009-02-13 | 2011-04-06 | 住友金属工業株式会社 | チタン板 |
JP5491882B2 (ja) * | 2010-01-27 | 2014-05-14 | 株式会社神戸製鋼所 | 冷間圧延性に優れた高強度チタン板 |
EP2468912A1 (en) * | 2010-12-22 | 2012-06-27 | Sandvik Intellectual Property AB | Nano-twinned titanium material and method of producing the same |
FR2982618B1 (fr) | 2011-11-10 | 2014-08-01 | Institut Nat Des Sciences Appliquees De Rennes Insa De Rennes | Procede de fabrication d'un alliage a base de titane pour dispositifs biomedicaux |
JP5988899B2 (ja) * | 2012-07-05 | 2016-09-07 | 株式会社神戸製鋼所 | チタン板およびチタン板の製造方法 |
US20140271336A1 (en) * | 2013-03-15 | 2014-09-18 | Crs Holdings Inc. | Nanostructured Titanium Alloy And Method For Thermomechanically Processing The Same |
-
2014
- 2014-07-08 DE DE102014010032.4A patent/DE102014010032B4/de active Active
-
2015
- 2015-06-22 JP JP2017521288A patent/JP6742996B2/ja not_active Expired - Fee Related
- 2015-06-22 US US15/324,192 patent/US10767244B2/en active Active
- 2015-06-22 RU RU2017103374A patent/RU2722300C2/ru active
- 2015-06-22 WO PCT/DE2015/100252 patent/WO2016004918A1/de active Application Filing
- 2015-06-22 EP EP15748161.5A patent/EP3167088B1/de active Active
Also Published As
Publication number | Publication date |
---|---|
EP3167088B1 (de) | 2020-01-29 |
JP2017526822A (ja) | 2017-09-14 |
US10767244B2 (en) | 2020-09-08 |
DE102014010032B4 (de) | 2017-03-02 |
DE102014010032A1 (de) | 2016-01-14 |
RU2017103374A (ru) | 2018-08-02 |
EP3167088A1 (de) | 2017-05-17 |
RU2017103374A3 (ja) | 2019-02-22 |
RU2722300C2 (ru) | 2020-05-28 |
US20170314099A1 (en) | 2017-11-02 |
WO2016004918A1 (de) | 2016-01-14 |
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