JP6637046B2 - 錆防止コーティング中の酸化αオレフィン - Google Patents
錆防止コーティング中の酸化αオレフィン Download PDFInfo
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- JP6637046B2 JP6637046B2 JP2017531670A JP2017531670A JP6637046B2 JP 6637046 B2 JP6637046 B2 JP 6637046B2 JP 2017531670 A JP2017531670 A JP 2017531670A JP 2017531670 A JP2017531670 A JP 2017531670A JP 6637046 B2 JP6637046 B2 JP 6637046B2
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- 239000002585 base Substances 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- RUGLKMZEADWYCJ-KVVVOXFISA-N calcium;(z)-octadec-9-enoic acid Chemical compound [Ca].CCCCCCCC\C=C/CCCCCCCC(O)=O RUGLKMZEADWYCJ-KVVVOXFISA-N 0.000 description 1
- CKJFPVNRRHVMKZ-UHFFFAOYSA-L calcium;naphthalene-1-sulfonate Chemical compound [Ca+2].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1.C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 CKJFPVNRRHVMKZ-UHFFFAOYSA-L 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000012668 chain scission Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical class OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 238000006471 dimerization reaction Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 229940116333 ethyl lactate Drugs 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002462 imidazolines Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910000398 iron phosphate Inorganic materials 0.000 description 1
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
- 229940035429 isobutyl alcohol Drugs 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- SWVGZFQJXVPIKM-UHFFFAOYSA-N n,n-bis(methylamino)propan-1-amine Chemical compound CCCN(NC)NC SWVGZFQJXVPIKM-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052755 nonmetal Chemical class 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- BNJOQKFENDDGSC-UHFFFAOYSA-N octadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCC(O)=O BNJOQKFENDDGSC-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000010690 paraffinic oil Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000003017 phosphorus Chemical class 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000010689 synthetic lubricating oil Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 150000004867 thiadiazoles Chemical class 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- 125000005457 triglyceride group Chemical group 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/086—Organic or non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Lubricants (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Description
良好なフィルム完全性(integrity)、良好な塩水噴霧性能(salt-spray performance)、および早期不具合(premature failure)がほとんどないことの少なくとも1つを含む非常に良好な錆抑制性能を提供する、コーティング組成物用のワックスが得られることが望ましい。
AO1 − 主にC26〜C28種を有するアルファオレフィン
AO2 − 主にC20〜C24種を有するアルファオレフィン
酸化AO − 25〜35の酸価まで酸化されている、AO1と同じかまたは類似したアルファオレフィン
酸化AOメチルエステル − メタノールで17〜25の酸価(エステル化後)までエステル化されている酸化AO
酸化AOブチルエステル − n−ブタノールで10〜20の酸価(エステル化後)までエステル化されている酸化AO
スルホン酸Ba − 42〜49%希釈油(油フリー基準で報告される量)を含む過塩基性アルカリールバリウムスルホネート
スルホン酸Ca 1 − 40%希釈油(油フリー基準で報告される量)を含む中性アルキルナフタレンスルホン酸カルシウム
スルホン酸Ca 2 − 57%希釈油(油フリー基準で報告される量)を含む中性アルキルベンゼンスルホン酸カルシウム
スルホン酸Ca 3 − 56%希釈油(油フリー基準で報告される量)を含む中性アルキルベンゼンスルホン酸カルシウム
スルホン酸Ca 4 − 50%希釈油(油フリー基準で報告される量)を含む中性アルキルベンゼンスルホン酸カルシウム
オレイン酸 − 商用グレード
エステルコポリマー1 − エステル官能基および約21個の炭素の側鎖を含有する市販の炭化水素可溶性ポリマー流動点降下剤、Mw約43,000。挙げられている量は、約10〜60%の希釈油を含むと考えられる。
エステルコポリマー2 − 芳香族モノマーおよびエステルモノマーを含有する炭化水素可溶性コポリマーであって、そのエステルが10〜36個の炭素を有するアルコールから調製される、炭化水素可溶性コポリマー;Mn約10,000〜40,000。挙げられている量は約30%の希釈油を含む。
希釈剤 − 石油ナフサ
石油ワックス,ブチルエステル−酸化石油ワックスから
一実施形態において、例えば、以下の項目が提供される。
(項目1)
(a)約16〜約40個の炭素原子を有する酸化αオレフィンであって、前記酸化αオレフィンが、1つもしくは複数のカルボン酸基、または、前記カルボン酸の1つもしくは複数のC1〜C28アルキルエステル、例えばメチルまたはブチルエステルを含み、前記αオレフィンが、任意のエステル化の前に測定して約10〜約120の酸価まで酸化されている、酸化αオレフィン;
(b)約10〜約36個の炭素原子の少なくとも1つの分枝を有し、および約5000〜約300,000の数平均分子量を有する炭化水素可溶性エステル含有ポリマー;
(c)少なくとも10個の炭素原子を有するカルボン酸;
(d)アルキルアリールスルホン酸の塩であって、そのアルキル基が炭化水素油中での前記塩の溶解性を提供するのに十分な長さである、アルキルアリールスルホン酸の塩;
(e)前記塩を溶解させるのに十分な量の油;および
(f)任意選択で、揮発性希釈剤
を含むコーティング組成物。
(項目2)
(a)前記酸化αオレフィンの量が約15〜約40重量パーセントであり、(b)前記炭化水素可溶性エステル含有ポリマーの量が約0.1〜約10重量パーセントであり、(c)前記カルボン酸の量が約1〜約8重量パーセントであり、(d)前記アルカリールスルホン酸の前記塩の量が約3〜約30重量パーセントであり、そして(e)前記油の量が約2〜約80重量パーセントで存在する炭化水素油であり、前記パーセンテージが任意の揮発性希釈剤の量を含まない、項目1に記載のコーティング組成物。
(項目3)
前記炭化水素油の量が約2〜約30重量パーセントである、項目2に記載のコーティング組成物。
(項目4)
(a)前記酸化αオレフィンの量が約0.3〜約22重量パーセントであり、(b)前記炭化水素可溶性エステル含有ポリマーの量が約0.002〜約8重量パーセントであり、(c)前記カルボン酸の量が約0.02〜約10重量パーセントであり、(d)前記アルカリールスルホン酸の前記塩の量が約0.06〜約20重量パーセントであり、(e)前記油の量が約70〜約98重量パーセントで存在する炭化水素油であり、前記パーセンテージが任意の揮発性希釈剤の量を含まない、項目1に記載のコーティング組成物。
(項目5)
(a)前記酸化αオレフィンが、エステル化前に、約10〜約100または約30〜約85の酸価まで酸化されている、項目1〜5のいずれか一項に記載のコーティング組成物。
(項目6)
(b)前記炭化水素可溶性エステル含有ポリマーが、アルファオレフィン−無水マレイン酸エステルコポリマー、スチレン−無水マレイン酸エステルコポリマー、フマル酸−酢酸ビニルエステルコポリマーまたはその混合物を含む、項目1〜5のいずれかに記載のコーティング組成物。
(項目7)
(c)前記カルボン酸が二酸またはポリ酸を含む、項目1〜6のいずれかに記載のコーティング組成物。
(項目8)
(c)前記カルボン酸が、隣接炭素原子上に2つのカルボン酸基を有する二酸またはポリ酸を含み、前記二酸またはポリ酸が少なくとも14個の炭素原子を有する、項目1〜6のいずれかに記載のコーティング組成物。
(項目9)
(d)前記アルキルアリールスルホン酸の前記塩が金属塩である、項目1〜8のいずれかに記載のコーティング組成物。
(項目10)
前記金属塩が、カルシウム塩 バリウム塩またはナトリウム塩、特にカルシウム塩である、項目9に記載のコーティング組成物。
(項目11)
(d)前記アルキルアリールスルホン酸の前記塩が、9もしくは12〜約200個の炭素原子または約18〜約100個の炭素原子のアルキル基を含有する、項目1〜10のいずれかに記載のコーティング組成物。
(項目12)
(e)前記油が炭化水素油である、項目1〜11のいずれかに記載のコーティング組成物。
(項目13)
約10または約16〜約40個の炭素原子の非酸化αオレフィンをさらに含む、項目1〜8のいずれかに記載のコーティング組成物。
(項目14)
前記非酸化αオレフィンと前記酸化αオレフィンの重量比が約0.3:1〜約2:1である、項目9に記載のコーティング組成物。
(項目15)
前記非酸化αオレフィンの量が、約0.2〜約40重量パーセントまたは約10〜約40重量パーセントまたは約0.2〜約20重量パーセントである、項目13または項目14に記載のコーティング組成物。
(項目16)
酸化オレフィン以外に酸化石油ワックスをさらに含む、項目1〜15のいずれかに記載のコーティング組成物。
(項目17)
約18〜約75個の炭素原子の炭化水素ワックス、または8〜約24個の炭素原子の脂肪酸の1つもしくは複数をベースとしたトリグリセリド、またはその混合物をさらに含む、項目1〜15のいずれか一項に記載のコーティング組成物。
(項目18)
前記炭化水素ワックス、またはトリグリセリド、またはその混合物の量が、約0.2〜約20重量パーセントまたは約10〜約20重量パーセントまたは約0.2〜約10重量パーセントである、項目16に記載のコーティング組成物。
(項目19)
前記揮発性希釈剤が存在する、項目1〜17のいずれか一項に記載のコーティング組成物。
(項目20)
前記揮発性希釈剤が炭化水素溶媒を含む、項目18に記載のコーティング組成物。
(項目21)
前記揮発性希釈剤の量が前記組成物の約60〜約98重量パーセントであり、他の成分(a)〜(e)の総量が約2〜約40重量パーセントである、項目18または項目19に記載のコーティング組成物。
(項目22)
項目1〜20のいずれか一項に記載の組成物でコーティングされた表面。
(項目23)
前記表面が鉄金属を含む、項目21に記載の表面。
(項目24)
表面に腐食保護を提供する方法であって、前記表面に、項目1〜16のいずれか一項に記載のコーティング組成物を塗布するステップを含む、方法。
(項目25)
前記表面が鉄金属を含む、項目23に記載の方法。
(項目26)
前記コーティング組成物が揮発性希釈剤を含み、前記方法が、前記揮発性希釈剤を蒸発させるステップをさらに含む、項目23または項目24に記載の方法。
(項目27)
項目1〜17のいずれか一項に記載の成分を含むフィルム。
Claims (15)
- (a)約16〜約40個の炭素原子を有する酸化αオレフィンであって、前記酸化αオレフィンが、1つもしくは複数のカルボン酸基、または、前記カルボン酸の1つもしくは複数のC1〜C28アルキルエステル、例えばメチルまたはブチルエステルを含み、前記αオレフィンが、任意のエステル化の前に測定して約10〜約120の酸価まで酸化されている、酸化αオレフィン;
(b)約10〜約36個の炭素原子の少なくとも1つの分枝を有し、および約5000〜約300,000の数平均分子量を有する炭化水素可溶性エステル含有ポリマー;
(c)少なくとも10個の炭素原子を有するカルボン酸;
(d)アルキルアリールスルホン酸の塩であって、そのアルキル基が炭化水素油中での前記塩の溶解性を提供するのに十分な長さである、アルキルアリールスルホン酸の塩;
(e)前記塩を溶解させるのに十分な量の油;および
(f)任意選択で、揮発性希釈剤
を含むコーティング組成物。 - (a)前記酸化αオレフィンの量が約15〜約40重量パーセントであり、(b)前記炭化水素可溶性エステル含有ポリマーの量が約0.1〜約10重量パーセントであり、(c)前記カルボン酸の量が約1〜約8重量パーセントであり、(d)前記アルカリールスルホン酸の前記塩の量が約3〜約30重量パーセントであり、そして(e)前記油の量が約2〜約80重量パーセントで存在する炭化水素油であり、前記パーセンテージが任意の揮発性希釈剤の量を含まない、請求項1に記載のコーティング組成物。
- (a)前記酸化αオレフィンが、エステル化前に、約10〜約100または約30〜約85の酸価まで酸化されている、請求項1に記載のコーティング組成物。
- (b)前記炭化水素可溶性エステル含有ポリマーが、アルファオレフィン−無水マレイン酸エステルコポリマー、スチレン−無水マレイン酸エステルコポリマー、フマル酸−酢酸ビニルエステルコポリマーまたはその混合物を含む、請求項1に記載のコーティング組成物。
- (c)前記カルボン酸が二酸またはポリ酸を含む、請求項1に記載のコーティング組成物。
- (d)前記アルキルアリールスルホン酸の前記塩が金属塩である、請求項1に記載のコーティング組成物。
- (d)前記アルキルアリールスルホン酸の前記塩が、9もしくは12〜約200個の炭素原子または約18〜約100個の炭素原子のアルキル基を含有する、請求項1に記載のコーティング組成物。
- (e)前記油が炭化水素油である、請求項1に記載のコーティング組成物。
- 約10または約16〜約40個の炭素原子の非酸化αオレフィンをさらに含む、請求項1に記載のコーティング組成物。
- 酸化オレフィン以外に酸化石油ワックスをさらに含む、請求項1に記載のコーティング組成物。
- 約18〜約75個の炭素原子の炭化水素ワックス、または8〜約24個の炭素原子の脂肪酸の1つもしくは複数をベースとしたトリグリセリド、またはその混合物をさらに含む、請求項1に記載のコーティング組成物。
- 前記揮発性希釈剤が存在する、請求項1に記載のコーティング組成物。
- 請求項1に記載の組成物でコーティングされた表面。
- 表面に腐食保護を提供する方法であって、前記表面に、請求項1に記載のコーティング組成物を塗布するステップを含む、方法。
- 請求項1に記載の成分を含むフィルム。
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