JP6533469B2 - 選択的な雑草防除方法 - Google Patents
選択的な雑草防除方法 Download PDFInfo
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- JP6533469B2 JP6533469B2 JP2015555292A JP2015555292A JP6533469B2 JP 6533469 B2 JP6533469 B2 JP 6533469B2 JP 2015555292 A JP2015555292 A JP 2015555292A JP 2015555292 A JP2015555292 A JP 2015555292A JP 6533469 B2 JP6533469 B2 JP 6533469B2
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- YMXOXAPKZDWXLY-QWRGUYRKSA-N tribenuron methyl Chemical group COC(=O)[C@H]1CCCC[C@@H]1S(=O)(=O)NC(=O)N(C)C1=NC(C)=NC(OC)=N1 YMXOXAPKZDWXLY-QWRGUYRKSA-N 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 description 1
- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
- AKTQJCBOGPBERP-UHFFFAOYSA-N triflusulfuron Chemical compound FC(F)(F)COC1=NC(N(C)C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2C)C(O)=O)=N1 AKTQJCBOGPBERP-UHFFFAOYSA-N 0.000 description 1
- PIHCREFCPDWIPY-UHFFFAOYSA-N tris[2-(2,4-dichlorophenoxy)ethyl] phosphite Chemical compound ClC1=CC(Cl)=CC=C1OCCOP(OCCOC=1C(=CC(Cl)=CC=1)Cl)OCCOC1=CC=C(Cl)C=C1Cl PIHCREFCPDWIPY-UHFFFAOYSA-N 0.000 description 1
- KVEQCVKVIFQSGC-UHFFFAOYSA-N tritosulfuron Chemical compound FC(F)(F)C1=NC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(F)(F)F)=N1 KVEQCVKVIFQSGC-UHFFFAOYSA-N 0.000 description 1
- 208000029257 vision disease Diseases 0.000 description 1
- 230000004393 visual impairment Effects 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 241000228158 x Triticosecale Species 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Wood Science & Technology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pyridine Compounds (AREA)
- Catching Or Destruction (AREA)
- Physiology (AREA)
- Botany (AREA)
- Developmental Biology & Embryology (AREA)
Description
以下の用語は、本明細書で使用する場合、表示した意味を有する。
R1R2R3R4N+
(式中、R1、R2、R3、およびR4はそれぞれ独立して、水素またはC1〜C12アルキル、C3〜C12アルケニル、またはC3〜C12アルキニルを表し、これらはそれぞれ、1つまたは複数のヒドロキシ基、C1〜C4アルコキシ基、C1〜C4アルキルチオ基、またはフェニル基によって場合により置換されているが、但し、R1、R2、R3、およびR4は立体的に共存できる条件とする)が含まれる。さらに、R1、R2、R3、およびR4の任意の2つが一緒になって、1〜12個の炭素原子と最大2個の酸素原子または硫黄原子を含有する二官能性脂肪族部位を表すことができる。塩は、水酸化ナトリウムなどの金属水酸化物、アンモニア、トリメチルアミン、ジエタノールアミン、2−メチルチオプロピルアミン、ビスアリルアミン、2−ブトキシエチルアミン、モルホリン、シクロドデシルアミン、もしくはベンジルアミンなどのアミン、または水酸化テトラメチルアンモニウムもしくは水酸化コリンなどの水酸化テトラアルキルアンモニウムで処理することによって調製することができる。
化合物Iの発芽後施用に対する、ヒマワリ(ヒマワリ(Helianthus annuus))、モロコシ(モロコシ(Sorghum vulgare))、イエローマスタード(シロガラシ(Sinapis alba))、スプリングユンセアキャノーラ(カラシナ(Brassica juncea))、ハルケール(ヤセイカンラン(Brassica oleracea))、ハルカブ(ブラッシカ・ラパ(Brassica rapa))、ハルルタバガ(セイヨウアブラナ(Brassica napus))、スプリングウインフレッド飼料ブラッシカ(ブラッシカ・ラパ×ヤセイカンラン(Brassica rapa x oleracea))、およびテンサイ(テンサイ(Beta vulgaris subsp. vulgaris var. altissima))の作物安全性を評価するため、様々な地域において、小規模区画研究実験を実施した。1ヘクタールあたり100リットル(L/ha)の水容量という最小施用をすべての実験に使用した。施用時における作物の段階分けは、子葉段階から分げつ中期まで(モロコシ)、または六葉期まで(アブラナ科(Brassicaceae)ファミリーの作物)の範囲とした。一般に、植物は、除草剤の施用時において、二葉から六葉期にあった。一部の例では、作物を標的とする障害は、穀作物における自生植物の観察される防除レベルに基づいて評価した。目視による障害の評点は、処理後の1〜27+週(WAT)の評点間隔で採取した。一般に、障害評点は、白化、成長阻害、成熟遅延、および異常生殖を含む、すべての植物毒性作用からなる。
5つの圃場試験からのデータにより、ユンセアキャノーラは、化合物Iに対して高い耐性レベルを示すことが示唆される。平均すると、ユンセアキャノーラに対する障害は、化合物Iの施用量が2.5、5および10gae/haにおいて、それぞれ7.5、11.3および5.5%を超えなかった。
3つの圃場試験からのデータにより、カブは、化合物Iに対して高い耐性レベルを示すことが示唆される。平均すると、カブに対する障害は、化合物Iの施用量が2.5、5および10gae/haにおいて、それぞれ2.5、5および7.5%を超えなかった。
3つの圃場試験からのデータにより、ルタバガは、化合物Iに対して高い耐性レベルを示すことが示唆される。平均すると、ルタバガに対する障害は、化合物Iの施用量が2.5、5および10gae/haにおいて、それぞれ6.3、10および15%を超えなかった。
3つの圃場試験からのデータにより、ケールは、化合物Iに対して高い耐性レベルを示すことが示唆される。平均すると、ケールに対する障害は、化合物Iの施用量が2.5、5および10gae/haにおいて、それぞれ2.5、1.3および3.8%を超えなかった。
実施した3つの圃場試験からのデータにより、ウインフレッド飼料ブラッシカは、化合物Iに対して高い耐性レベルを示すことが示唆される。平均すると、ウインフレッド飼料ブラッシカに対する障害は、化合物Iの施用量が2.5、5および10gae/haにおいて、それぞれ17.5、9.2および8.8%を超えなかった。
オーストラリアで実施した2つの圃場試験からのデータにより、ヒマワリは、化合物Iに対して高い耐性レベルを示すことが示唆される。平均すると、障害は、化合物Iの施用量が2.5、5および10gae/haにおいて、それぞれ6.7、13.3および15%を超えなかった。式(I)の化合物のTEA塩は、ヒマワリに対してメチルエステルよりもわずかに活性が低くなり得る。オーストラリアにおける、ハルヒマワリ(ヒマワリ(Helianthus annuus))に関する試験からのデータを表6にまとめる。式(I)の化合物のメチルエステルおよび式(I)の化合物のTEA塩は、表示施用量で試験した。施用は、B12〜B14の作物段階であった。
2つの圃場試験からのデータにより、モロコシは、化合物Iに対して高い耐性レベルを示すことが示唆される。平均すると、モロコシに対する障害は、化合物Iの施用量が2.5、5および10gae/haにおいて、それぞれ13.3、18.3および18.3%を超えなかった。式(I)の化合物のTEA塩は、モロコシに対してメチルエステルよりもわずかに活性が低くなり得る。ハルモロコシ(モロコシ(Sorghum vulgare))に関する試験からのデータを、表7にまとめる。式(I)の化合物のメチルエステルおよびTEA塩は、表示施用量で試験した。施用は、B17〜B22の作物段階であった。
1つの圃場試験からのデータにより、イエローマスタードは、化合物Iに対して高い耐性レベルを示すことが示唆される。平均すると、イエローマスタードに対する障害は、化合物Iの施用量が2.5、5および10gae/haにおいて、それぞれ8.5、14.3および25%を超えなかった。未処理の確認用処置物と比べて、イエローマスタードの収量は、施用量2.5〜10gae/haの化合物Iの施用により影響を受けなかった。データを表8にまとめる。式(I)の化合物のメチルエステルは、表示施用量で試験した。施用は、B14〜B15の作物段階であった。
ドイツおよびハンガリーで実施した5つの圃場試験からのデータにより、テンサイは、化合物Iに対してかなりの耐性レベルを示すことが示唆される。平均すると、テンサイに対する成長阻害は、化合物Iの施用量が0.5、1.0、2.0および3.0gae/haにおいて、それぞれ3.8、8.8、7.5および12.5%を超えなかった。
本発明は次の実施態様を含む。
(1)ヒマワリ、モロコシ、イエローマスタード、スプリングユンセアキャノーラ、ハルケール、ハルカブ、ハルルタバガ、スプリングウインフレッド飼料ブラッシカ、またはテンサイからなる群から選択される作物の存在下で望ましくない植生を選択的に発芽後防除する方法であって、除草有効量の4−アミノ−3−クロロ−6−(4−クロロ−2−フルオロ−3−メトキシフェニル)ピリジン−2−カルボン酸または農業上許容されるそのエステルもしくは塩を施用するステップを含む、方法。
(2)前記4−アミノ−3−クロロ−6−(4−クロロ−2−フルオロ−3−メトキシフェニル)ピリジン−2−カルボン酸または農業上許容されるそのエステルもしくは塩が、最大10gae/haの施用量で施用される、上記(1)に記載の方法。
(2A)ヒマワリ、モロコシ、イエローマスタード、スプリングユンセアキャノーラ、ハルケール、ハルカブ、ハルルタバガ、スプリングウインフレッド飼料ブラッシカ、またはテンサイからなる群から選択される作物の存在下で望ましくない植生を選択的に発芽後防除する除草剤組成物であって、
該組成物は4−アミノ−3−クロロ−6−(4−クロロ−2−フルオロ−3−メトキシフェニル)ピリジン−2−カルボン酸または農業上許容されるそのエステルもしくは塩を含み、前記4−アミノ−3−クロロ−6−(4−クロロ−2−フルオロ−3−メトキシフェニル)ピリジン−2−カルボン酸または農業上許容されるそのエステルもしくは塩が、最大10gae/haの施用量で施用される、除草剤組成物。
(3)前記4−アミノ−3−クロロ−6−(4−クロロ−2−フルオロ−3−メトキシフェニル)ピリジン−2−カルボン酸または農業上許容されるそのエステルもしくは塩が、最大5gae/haの施用量で施用される、上記(1)に記載の方法、又は上記(2A)に記載の組成物。
(4)前記4−アミノ−3−クロロ−6−(4−クロロ−2−フルオロ−3−メトキシフェニル)ピリジン−2−カルボン酸または農業上許容されるそのエステルもしくは塩が、最大2.5gae/haの施用量で施用される、上記(1)に記載の方法、又は上記(2A)に記載の組成物。
(5)前記作物がヒマワリである、上記(1)から(4)のいずれかに記載の方法、又は上記(2A)に記載の組成物。
(6)前記作物がモロコシである、上記(1)から(4)のいずれかに記載の方法、又は上記(2A)に記載の組成物。
(7)前記作物がイエローマスタードである、上記(1)から(4)のいずれかに記載の方法、又は上記(2A)に記載の組成物。
(8)前記作物がスプリングユンセアキャノーラである、上記(1)から(4)のいずれかに記載の方法、又は上記(2A)に記載の組成物。
(9)前記作物がハルケールである、上記(1)から(4)のいずれかに記載の方法、又は上記(2A)に記載の組成物。
(10)前記作物がハルカブである、上記(1)から(4)のいずれかに記載の方法、又は上記(2A)に記載の組成物。
(11)前記作物がハルルタバガである、上記(1)から(4)のいずれかに記載の方法、又は上記(2A)に記載の組成物。
(12)前記作物がスプリングウインフレッド飼料ブラッシカである、上記(1)から(4)のいずれかに記載の方法、又は上記(2A)に記載の組成物。
(13)前記作物がテンサイである、上記(1)から(4)のいずれかに記載の方法、又は上記(2A)に記載の組成物。
(14)前記望ましくない植生が、アメリカヤエムグラ(シラホシムグラ(Galium aparine))、ハコベ(コハコベ(Stellaria media))、アカザ(ヒユ属種(Amaranthus spp.))、チシマオドリコソウ(タヌキジソ(Galeopsis tetrahit))、シロザ(シロザ(Chenopodium album))、カラクサケマン(カラクサケマン属種(Fumaria spp.))、ノミヨケソウ(イズハハコ属種(Conyza spp.))、アザミゲシ(アザミゲシ(Argemone mexicana))、フウロソウの種(フウロソウ属種(Geranium spp.))、ブタクサ(ブタクサ属種(Ambrosia spp.))、オランダフウロ(オランダフウロ(Erodium cicutarium))、ゼニアオイ(ゼニアオイ属種(Malva spp.))、自生アマ(アマ(Linum usitatissimum))、自生アルファルファ(ムラサキウマゴヤシ(Medicago sativa))、およびオドリコソウ(オドリコソウ属種(Lamium spp.))からなる群から選択される、上記(1)から(13)のいずれかに記載の方法、又は上記(2A)に記載の組成物。
Claims (11)
- イエローマスタード、スプリングユンセアキャノーラ、ハルケール、ハルカブ、ハルルタバガ、およびスプリングウインフレッド飼料ブラッシカからなる群から選択される作物の存在下で望ましくない植生を選択的に発芽後防除する除草剤組成物であって、
該組成物は4−アミノ−3−クロロ−6−(4−クロロ−2−フルオロ−3−メトキシフェニル)ピリジン−2−カルボン酸または農業上許容されるそのエステルもしくは塩を含み、前記4−アミノ−3−クロロ−6−(4−クロロ−2−フルオロ−3−メトキシフェニル)ピリジン−2−カルボン酸または農業上許容されるそのエステルもしくは塩が、最大10gae/haの施用量で施用される、除草剤組成物。 - 前記4−アミノ−3−クロロ−6−(4−クロロ−2−フルオロ−3−メトキシフェニル)ピリジン−2−カルボン酸または農業上許容されるそのエステルもしくは塩が、最大5gae/haの施用量で施用される、請求項1に記載の組成物。
- 前記4−アミノ−3−クロロ−6−(4−クロロ−2−フルオロ−3−メトキシフェニル)ピリジン−2−カルボン酸または農業上許容されるそのエステルもしくは塩が、最大2.5gae/haの施用量で施用される、請求項1に記載の組成物。
- 前記作物がイエローマスタードである、請求項1から3のいずれかに記載の組成物。
- 前記作物がスプリングユンセアキャノーラである、請求項1から3のいずれかに記載の組成物。
- 前記作物がハルケールである、請求項1から3のいずれかに記載の組成物。
- 前記作物がハルカブである、請求項1から3のいずれかに記載の組成物。
- 前記作物がハルルタバガである、請求項1から3のいずれかに記載の組成物。
- 前記作物がスプリングウインフレッド飼料ブラッシカである、請求項1から3のいずれかに記載の組成物。
- 前記望ましくない植生が、アメリカヤエムグラ(シラホシムグラ(Galium aparine))、ハコベ(コハコベ(Stellaria media))、アカザ(ヒユ属種(Amaranthus spp.))、チシマオドリコソウ(タヌキジソ(Galeopsis tetrahit))、シロザ(シロザ(Chenopodium album))、カラクサケマン(カラクサケマン属種(Fumaria spp.))、ノミヨケソウ(イズハハコ属種(Conyza spp.))、アザミゲシ(アザミゲシ(Argemone mexicana))、フウロソウの種(フウロソウ属種(Geranium spp.))、ブタクサ(ブタクサ属種(Ambrosia spp.))、オランダフウロ(オランダフウロ(Erodium cicutarium))、ゼニアオイ(ゼニアオイ属種(Malva spp.))、自生アマ(アマ(Linum usitatissimum))、自生アルファルファ(ムラサキウマゴヤシ(Medicago sativa))、およびオドリコソウ(オドリコソウ属種(Lamium spp.))からなる群から選択される、請求項1から9のいずれかに記載の組成物。
- イエローマスタード、スプリングユンセアキャノーラ、ハルケール、ハルカブ、ハルルタバガ、およびスプリングウインフレッド飼料ブラッシカからなる群から選択される作物の存在下で望ましくない植生を選択的に発芽後防除する方法であって、除草有効量の4−アミノ−3−クロロ−6−(4−クロロ−2−フルオロ−3−メトキシフェニル)ピリジン−2−カルボン酸または農業上許容されるそのエステルもしくは塩を施用するステップを含み、前記4−アミノ−3−クロロ−6−(4−クロロ−2−フルオロ−3−メトキシフェニル)ピリジン−2−カルボン酸または農業上許容されるそのエステルもしくは塩が、最大10gae/haの施用量で施用される、方法。
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US (1) | US11109592B2 (ja) |
EP (1) | EP2947991B1 (ja) |
JP (2) | JP6533469B2 (ja) |
KR (1) | KR102192912B1 (ja) |
CN (2) | CN104936454A (ja) |
AR (1) | AR094573A1 (ja) |
AU (1) | AU2014209278B2 (ja) |
BR (1) | BR102014001858B8 (ja) |
CA (1) | CA2898488C (ja) |
CL (1) | CL2015002080A1 (ja) |
DK (1) | DK2947991T3 (ja) |
HU (1) | HUE044948T2 (ja) |
IL (1) | IL240018A0 (ja) |
LT (1) | LT2947991T (ja) |
MX (1) | MX352567B (ja) |
NZ (1) | NZ710012A (ja) |
PL (1) | PL2947991T3 (ja) |
RS (1) | RS58738B1 (ja) |
RU (1) | RU2677980C2 (ja) |
TR (1) | TR201904710T4 (ja) |
UA (1) | UA116795C2 (ja) |
UY (1) | UY35284A (ja) |
WO (1) | WO2014116894A1 (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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RU2657017C2 (ru) * | 2013-03-14 | 2018-06-08 | ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи | Контроль широколиственных культур с помощью 6-арилпиколинкарбоновых кислот, 2-арилпиримидинкарбоновых кислот или их солей или сложных эфиров |
WO2017214132A1 (en) * | 2016-06-10 | 2017-12-14 | Dow Agrosciences Llc | Safened herbicidal compositions containing halauxifen and methods of use thereof in brassica species |
CN108077074B (zh) * | 2017-12-05 | 2021-01-12 | 长沙学院 | 一种药用植物八仙草的组织培养方法 |
WO2023192088A1 (en) * | 2022-03-29 | 2023-10-05 | Corteva Agriscience Llc | A method of weed control in sugar beet |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
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CA2626103C (en) * | 2006-01-13 | 2013-07-30 | Dow Agrosciences Llc | 6-(poly-substituted aryl)-4-aminopicolinates and their use as herbicides |
RU2337545C1 (ru) * | 2007-04-18 | 2008-11-10 | Закрытое акционерное общество Фирма "Август" | Гербицидная композиция и способ борьбы с нежелательной растительностью |
BR122016022104B1 (pt) * | 2007-08-27 | 2019-03-19 | Dow Agrosciences Llc | Misturas herbicidas sinérgicas compreendendo certos ácidos carboxílicos de pirimidina ou piridina e certos herbicidas de cereal e arroz, composição herbicida, e métodos para controlar vegetação indesejável |
LT2740360T (lt) * | 2008-06-18 | 2018-03-12 | Basf Se | Trijų komponentų herbicidinės kompozicijos, apimančios aminopiralidiną ir imazamoksą |
CA2725376C (en) * | 2008-06-18 | 2016-09-06 | Basf Se | Herbicidal compositions comprising 4-amino-3,6-dichloropyridine-2-carboxylic acid |
EP2191719A1 (de) * | 2008-11-29 | 2010-06-02 | Bayer CropScience AG | Herbizid-Safener-Kombination |
EP2421832B1 (en) | 2009-02-27 | 2013-12-18 | Dow AgroSciences LLC | N-alkoxyamides of 6-(substituted phenyl)-4-aminopicolinates and 2-(substituted phenyl)-6-amino-4-pyrimidinecarboxylates and their use as selective herbicides for crops |
BRPI1011960A8 (pt) * | 2009-05-27 | 2016-05-03 | Bayer Cropscience Ag | Combinações herbicidas compreendendo tefuriltriona para uso em culturas de arroz |
EP2638804A1 (en) * | 2009-09-30 | 2013-09-18 | Basf Se | Low volatile amine salts of anionic pesticides |
RU2552042C2 (ru) | 2010-02-19 | 2015-06-10 | ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи | Гербицидная синергическая смесь, содержащая определенные пиридинкарбоновые кислоты и некоторые инсектициды (варианты), и гербицидная композиция на ее основе |
AU2011218123B2 (en) * | 2010-02-19 | 2015-02-12 | Corteva Agriscience Llc | Synergistic herbicide/fungicide composition containing a pyridine carboxylic acid and a fungicide |
CN102906096A (zh) * | 2010-03-23 | 2013-01-30 | 巴斯夫欧洲公司 | 具有除草作用的吡啶类 |
UA109797C2 (uk) * | 2010-11-05 | 2015-10-12 | Спосіб боротьби з бур'янами, що мають стійкість до гербіцидів на основі феноксіалканових кислот, за допомогою 4-аміно-3-хлор-6-(4-хлор-2-фтор-3-метоксифеніл)піридин-2-карбонової кислоти і її солей або складних ефірів | |
GB201109309D0 (en) * | 2011-06-02 | 2011-07-20 | Syngenta Ltd | Herbicidal compositions |
US20130005568A1 (en) * | 2011-06-30 | 2013-01-03 | E.I. Du Pont De Nemours And Company | Safened herbicidal mixtures |
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