JP6507490B2 - 炭酸飲料 - Google Patents
炭酸飲料 Download PDFInfo
- Publication number
- JP6507490B2 JP6507490B2 JP2014102098A JP2014102098A JP6507490B2 JP 6507490 B2 JP6507490 B2 JP 6507490B2 JP 2014102098 A JP2014102098 A JP 2014102098A JP 2014102098 A JP2014102098 A JP 2014102098A JP 6507490 B2 JP6507490 B2 JP 6507490B2
- Authority
- JP
- Japan
- Prior art keywords
- menthol
- carbonated beverage
- hexenol
- cis
- trans
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 title 1
- 235000014171 carbonated beverage Nutrition 0.000 claims description 66
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 claims description 52
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 47
- 229940041616 menthol Drugs 0.000 claims description 42
- 239000000284 extract Substances 0.000 claims description 33
- 206010013911 Dysgeusia Diseases 0.000 claims description 32
- 235000019658 bitter taste Nutrition 0.000 claims description 28
- ZCHHRLHTBGRGOT-SNAWJCMRSA-N (E)-hex-2-en-1-ol Chemical compound CCC\C=C\CO ZCHHRLHTBGRGOT-SNAWJCMRSA-N 0.000 claims description 26
- 244000269722 Thea sinensis Species 0.000 claims description 26
- MBDOYVRWFFCFHM-SNAWJCMRSA-N (2E)-hexenal Chemical compound CCC\C=C\C=O MBDOYVRWFFCFHM-SNAWJCMRSA-N 0.000 claims description 20
- 235000003599 food sweetener Nutrition 0.000 claims description 16
- 239000003765 sweetening agent Substances 0.000 claims description 16
- UFLHIIWVXFIJGU-ARJAWSKDSA-N (Z)-hex-3-en-1-ol Chemical compound CC\C=C/CCO UFLHIIWVXFIJGU-ARJAWSKDSA-N 0.000 claims description 15
- UFLHIIWVXFIJGU-UHFFFAOYSA-N hex-3-en-1-ol Natural products CCC=CCCO UFLHIIWVXFIJGU-UHFFFAOYSA-N 0.000 claims description 13
- HELXLJCILKEWJH-NCGAPWICSA-N rebaudioside A Chemical compound O([C@H]1[C@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O[C@]12C(=C)C[C@@]3(C1)CC[C@@H]1[C@@](C)(CCC[C@]1([C@@H]3CC2)C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HELXLJCILKEWJH-NCGAPWICSA-N 0.000 claims description 12
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 15
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- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 4
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- 239000001509 sodium citrate Substances 0.000 description 4
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 4
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- PJVXUVWGSCCGHT-ZPYZYFCMSA-N (2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanal;(3s,4r,5r)-1,3,4,5,6-pentahydroxyhexan-2-one Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O.OC[C@@H](O)[C@@H](O)[C@H](O)C(=O)CO PJVXUVWGSCCGHT-ZPYZYFCMSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
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- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 3
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- SDZQUCJFTUULJX-PLNGDYQASA-N (z)-hept-3-en-1-ol Chemical compound CCC\C=C/CCO SDZQUCJFTUULJX-PLNGDYQASA-N 0.000 description 2
- WBZFUFAFFUEMEI-UHFFFAOYSA-M Acesulfame k Chemical compound [K+].CC1=CC(=O)[N-]S(=O)(=O)O1 WBZFUFAFFUEMEI-UHFFFAOYSA-M 0.000 description 2
- 108010011485 Aspartame Proteins 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
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- 239000004386 Erythritol Substances 0.000 description 2
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
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- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
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- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
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- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 description 2
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- VFLDPWHFBUODDF-FCXRPNKRSA-N curcumin Chemical compound C1=C(O)C(OC)=CC(\C=C\C(=O)CC(=O)\C=C\C=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-FCXRPNKRSA-N 0.000 description 2
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- GXANMBISFKBPEX-UHFFFAOYSA-N hex-3c-enal Natural products CCC=CCC=O GXANMBISFKBPEX-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Non-Alcoholic Beverages (AREA)
Description
しかし、メントールを炭酸飲料に配合すると、苦味の強さが顕著になりさらに特有の後味が残りやすくキレが悪いという課題がある。
しかし、これらの方法は炭酸飲料へメントールを添加した際の苦味や特有の後味には効果が十分ではなかった。
一方、近年、ストレス軽減や疲労回復成分として青葉の香りを有する香気成分(cis−3−ヘキセノール(青葉アルコール)、trans−2−ヘキセナール(青葉アルデヒド)などが知られており(非特許文献1)、いろいろな応用事例が報告されている(例えば、特許文献6、特許文献7参照)。しかし、これら先行文献には、本発明のメントールを含有する炭酸飲料へ甜茶抽出物を添加した際の甘味や特有の後味の低減効果は記載されていない。
(1)(a)3w/vppm以上のメントールと、(b)甜茶抽出物及び/または青葉の香りを有する香気成分を含有することを特徴とする炭酸飲料、
(2)メントールがl−メントールである(1)に記載の炭酸飲料、
(3)メントール1質量部に対し甜茶抽出物を2質量部以上含有する(1)又は(2)に記載の炭酸飲料、
(4)青葉の香りを有する香気成分がcis−3−ヘキセノール、trans−2−ヘキセナール、trans−2−ヘキセノール、及びcis−2−ヘキセノールの群から選ばれる少なくとも1種である、(1)〜(3)のいずれかに記載の炭酸飲料、
(5)メントール1質量部に対しcis−3−ヘキセノール、trans−2−ヘキセナール、trans−2−ヘキセノール、及びcis−2−ヘキセノールの群から選ばれる少なくとも1種を0.01質量部以上含有する(4)に記載の炭酸飲料、
(6)さらに、甘味料を含有する(1)〜(5)のいずれかに記載の炭酸飲料、
(7)甘味料が、異性化糖、砂糖、スクラロース及びステビア抽出物の群から選ばれる少なくとも1種である(6)に記載の炭酸飲料、
(8)pHが3.0〜5.0である(1)〜(7)の何れかに記載の炭酸飲料、
(9)3w/vppm以上のメントールを含有する炭酸飲料において、甜茶抽出物及び/または青葉の香りを有する香気成分を添加することで、メントールの苦味を抑制し、及び/又は後味のキレを改善する方法、
である。
また、本発明では、甜茶抽出物及び/または青葉の香りを有する香気成分の後味や苦味もメントールの苦味や後味によって相殺されるため、本発明の炭酸飲料の飲みやすさが損なわれることもない。
苦味が比較例に比べ「非常に強い」を3点、「強い」を2点、「やや強い」を1点、「同じ」を0点、「やや弱い」を−1点、「弱い」を−2点、「非常に弱い」を−3点とした7段階の評価で行った。パネル3名の平均点を下記表2に記載の基準に変換し示した。
後味のキレが比較例に比べ「非常に良い」を3点、「良い」を2点、「やや良い」を1点、「同じ」を0点、「やや悪い」を−1点、「悪い」を−2点、「非常に悪い」を−3点とした7段階の評価で行った。パネル3名の平均点を下記表3に記載の基準に変換し示した。
炭酸飲料の爽快感が、比較例に比べ「非常に強い」を3点、「強い」を2点、「やや強い」を1点、「同じ」を0点、「やや弱い」を−1点、「弱い」を−2点、「非常に弱い」を−3点とした7段階の評価で行った。パネル3名の平均点を下記表4に記載の基準に変換し示した。
また、比較例2〜6に示すように、甜茶と同じバラ科の植物であるバラの花びら抽出物では効果はなかった。また、青葉の香りを有する香気成分と似た構造の化合物であるcis−2−ペンテン-1-オール、cis−4−ヘプテン-1-オール、cis−3−ヘプテノール、1−ヘプタノール)も苦味を低減し、キレを改善する効果はなかった。
下記表11に記載の処方および次の方法に従い炭酸飲料を調製した。まず、全量(100ml)の45%程度の水に、クエン酸、クエン酸三ナトリウム、甜茶抽出物、cis−3−ヘキセノールを添加した後、40〜50℃に加温し、l−メントールを添加、溶解した後に、塩酸または水酸化ナトリウム水溶液でpHを調整し、全量の50%の濃度の飲料原液を調製した。最後にこの飲料原液に炭酸水を加えて全量とし、炭酸飲料を得た(実施例16〜22)。
Claims (8)
- (a)3w/vppm以上のメントールと、(b)甜茶抽出物、並びにcis−3−ヘキセノール、trans−2−ヘキセナール、trans−2−ヘキセノール、及びcis−2−ヘキセノールの群から選ばれる少なくとも1種である青葉の香りを有する香気成分を含有することを特徴とする炭酸飲料。
- メントールがl−メントールである請求項1に記載の炭酸飲料。
- メントール1質量部に対し甜茶抽出物を2質量部以上含有する請求項1又は2に記載の炭酸飲料。
- メントール1質量部に対し、cis−3−ヘキセノール、trans−2−ヘキセナール、trans−2−ヘキセノール、及びcis−2−ヘキセノールの群から選ばれる少なくとも1種である青葉の香りを有する香気成分を0.01質量部以上含有する請求項1又は2に記載の炭酸飲料。
- 甘味料を含有する請求項1〜4のいずれかに記載の炭酸飲料。
- 甘味料が、異性化糖、砂糖、スクラロース及びステビア抽出物の群から選ばれる少なくとも1種である請求項5に記載の炭酸飲料。
- pHが3.0〜5.0である請求項1〜6の何れかに記載の炭酸飲料。
- 3w/vppm以上のメントールを含有する炭酸飲料において、甜茶抽出物及び/または
cis−3−ヘキセノール、trans−2−ヘキセナール、trans−2−ヘキセノール、及びcis−2−ヘキセノールの群から選ばれる少なくとも1種である青葉の香りを有する香気成分を添加することで、メントールの苦味を抑制し、及び/又は後味のキレを改善する方法。
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