JP6441389B2 - 水素化熱分解生成物蒸気からの硫酸アンモニウムとしての硫化水素の除去 - Google Patents
水素化熱分解生成物蒸気からの硫酸アンモニウムとしての硫化水素の除去 Download PDFInfo
- Publication number
- JP6441389B2 JP6441389B2 JP2017003335A JP2017003335A JP6441389B2 JP 6441389 B2 JP6441389 B2 JP 6441389B2 JP 2017003335 A JP2017003335 A JP 2017003335A JP 2017003335 A JP2017003335 A JP 2017003335A JP 6441389 B2 JP6441389 B2 JP 6441389B2
- Authority
- JP
- Japan
- Prior art keywords
- phase
- product
- vapor
- aqueous phase
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000197 pyrolysis Methods 0.000 title claims 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title description 9
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 title description 6
- 229910052921 ammonium sulfate Inorganic materials 0.000 title description 6
- 235000011130 ammonium sulphate Nutrition 0.000 title description 6
- 229910000037 hydrogen sulfide Inorganic materials 0.000 title description 4
- 238000000034 method Methods 0.000 claims description 96
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 65
- 239000007788 liquid Substances 0.000 claims description 45
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 36
- 239000008346 aqueous phase Substances 0.000 claims description 32
- 229930195733 hydrocarbon Natural products 0.000 claims description 31
- 150000002430 hydrocarbons Chemical class 0.000 claims description 31
- 239000002028 Biomass Substances 0.000 claims description 25
- 238000006243 chemical reaction Methods 0.000 claims description 24
- 229910052739 hydrogen Inorganic materials 0.000 claims description 22
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 20
- 239000001257 hydrogen Substances 0.000 claims description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 17
- 229910021529 ammonia Inorganic materials 0.000 claims description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 17
- 239000001301 oxygen Substances 0.000 claims description 17
- 229910052760 oxygen Inorganic materials 0.000 claims description 17
- 229910052717 sulfur Inorganic materials 0.000 claims description 16
- 239000007789 gas Substances 0.000 claims description 14
- 239000004215 Carbon black (E152) Substances 0.000 claims description 13
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 13
- 239000011593 sulfur Substances 0.000 claims description 12
- 239000012808 vapor phase Substances 0.000 claims description 12
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 11
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- 239000012071 phase Substances 0.000 claims description 10
- 239000002594 sorbent Substances 0.000 claims description 7
- -1 diesel Substances 0.000 claims description 4
- 239000003502 gasoline Substances 0.000 claims description 3
- 239000003350 kerosene Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 2
- 238000000629 steam reforming Methods 0.000 claims description 2
- 239000012074 organic phase Substances 0.000 claims 7
- 238000001816 cooling Methods 0.000 claims 6
- 239000007791 liquid phase Substances 0.000 claims 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- 238000004090 dissolution Methods 0.000 claims 2
- 238000005755 formation reaction Methods 0.000 claims 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 230000003635 deoxygenating effect Effects 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 239000000047 product Substances 0.000 description 67
- 230000003647 oxidation Effects 0.000 description 24
- 238000007254 oxidation reaction Methods 0.000 description 24
- 239000002023 wood Substances 0.000 description 16
- 240000008042 Zea mays Species 0.000 description 13
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 13
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 13
- 235000005822 corn Nutrition 0.000 description 13
- 239000010907 stover Substances 0.000 description 11
- 239000008213 purified water Substances 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 8
- 238000010586 diagram Methods 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000003337 fertilizer Substances 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- UYJXRRSPUVSSMN-UHFFFAOYSA-P ammonium sulfide Chemical compound [NH4+].[NH4+].[S-2] UYJXRRSPUVSSMN-UHFFFAOYSA-P 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000002689 soil Substances 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 150000004763 sulfides Chemical class 0.000 description 4
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 3
- 239000001273 butane Substances 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000003405 delayed action preparation Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000012787 harvest procedure Methods 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 235000008935 nutritious Nutrition 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002510 pyrogen Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/75—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/16—Hydrogen sulfides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/022—Preparation of aqueous ammonia solutions, i.e. ammonia water
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/026—Preparation of ammonia from inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/12—Separation of ammonia from gases and vapours
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/24—Sulfates of ammonium
- C01C1/245—Preparation from compounds containing nitrogen and sulfur
- C01C1/246—Preparation from compounds containing nitrogen and sulfur from sulfur-containing ammonium compounds
- C01C1/247—Preparation from compounds containing nitrogen and sulfur from sulfur-containing ammonium compounds by oxidation with free oxygen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/74—Treatment of water, waste water, or sewage by oxidation with air
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/002—Removal of contaminants
- C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
- C10K1/004—Sulfur containing contaminants, e.g. hydrogen sulfide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/70—Non-metallic catalysts, additives or dopants
- B01D2255/705—Ligands for metal-organic catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/304—Hydrogen sulfide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/08—Jet fuel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0966—Hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2200/00—Components of fuel compositions
- C10L2200/04—Organic compounds
- C10L2200/0461—Fractions defined by their origin
- C10L2200/0469—Renewables or materials of biological origin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Wood Science & Technology (AREA)
- Biomedical Technology (AREA)
- General Health & Medical Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Industrial Gases (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Fertilizers (AREA)
- Processing Of Solid Wastes (AREA)
- Treating Waste Gases (AREA)
- Physical Water Treatments (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Catalysts (AREA)
- Gas Separation By Absorption (AREA)
Description
2H2S + O2→S2 + 2H2O
このプロセスは公知であり、石油製品の精製および改質に広く適用されてきた。しかし、このプロセスは複雑であり、多くの場合、複数の反応工程が関与する。さらに、このプロセスは、分子ベースで25%以上のH2Sを含有する流れに対して、最も効率的に適用することができる。H2Sだけでなくアンモニアも含有する流れがクラウスプラントで処理される場合、H2Sと共にアンモニアも酸化される。アンモニアは、水素化熱分解プロセスからの潜在的価値を有する反応生成物であることから、これは望ましいものではない。
すべての硫化化合物が硫酸塩化合物に変換されるために、こうして実質的に硫化化合物を含有しない生成物流が得られる。
1. 脱酸素化凝縮性炭化水素(ガソリン、ディーゼル、および灯油に対応する特性を有する)、
2. 非凝縮性炭化水素蒸気(メタン、エタン、プロパン、およびブタンなど)、
3. その他の非凝縮性蒸気(CO2、CO、および水素)
4. 水、ならびにアンモニア(NH3)および硫化水素(H2S)などの液体水に可溶性である種。
1. 脱酸素化凝縮性炭化水素(ガソリン、ディーゼル、および灯油に対応する特性を有する)、
2. 非凝縮性炭化水素蒸気(メタン、エタン、プロパン、およびブタンなど)、
3. その他の非凝縮性蒸気(CO2、CO、およびH2)
4. 水、ならびにアンモニア(NH3)および硫化水素(H2S)などの液体水に可溶性である種、
を含んでなる。
この木材の元素組成を、以下の表Aに示す。組成は、全体基準(供給原料中の水分および灰分を含む)、ならびに水分および灰分非含有(MAF)基準の両方で示す。表Aから分かるように、木材中には、少量であるが有意な量の窒素および硫黄が存在していた。
表Cから分かるように、コーンストーバー中には、木材供給原料の場合と同様に、少量であるが有意な量の窒素および硫黄が存在していた。この表から分かるように、コーンストーバーサンプルは、木材のサンプルよりも遥かに多い灰分および遥かに多い水分を含有していた。
Claims (25)
- バイオマスおよび水素を、1つ以上の反応器を備える水素化熱分解反応器中に導入する工程と、
前記バイオマスを十分に脱酸素化し、生成物蒸気を得る工程であって、
前記生成物蒸気は、全ての成分が気体状態となる温度において前記水素化熱分解反応器から、排出され、前記生成物蒸気が、脱酸素凝縮性炭化水素、非凝縮性ガスおよび水を含んでなる、工程と、
前記生成物蒸気を冷却し、液体有機相および生成物蒸気に含まれる水溶性化合物を少なくとも1種含む液体水性相に凝縮する工程であって、
前記水溶性化合物には、アンモニア(NH3)が含まれており、前記液体水性相に溶解している、冷却工程と、
前記液体水性相を、前記液体有機相から分離すると共に、前記液体水性相を処理し、前記液体水性相から、ガス相NH3生成物または水性NH4(OH)生成物を得る工程と、を含んでなることを特徴とする、水素化熱分解プロセス。 - 前記水素化熱分解反応器が、連続する複数の反応器を含んでなる、請求項1に記載のプロセス。
- NH3およびH2Sが、前記生成物蒸気に含まれる前記水溶性化合物であり、
前記生成物蒸気を冷却することにより、NH3およびH2Sを含む液体水性相を凝縮し、
前記溶解したNH3は、前記液体水性相におけるNH3とH2Sとの(NH4)2S形成反応の後に残存するよう、前記液体水性相に過剰量存在する、請求項1または2に記載のプロセス。 - 前記液体水性相を処理する工程が、前記液体水性相を、酸素と触媒反応させ、(NH4)2Sを(NH4)2SO4に実質的に酸化させることを含む、請求項3に記載のプロセス。
- 前記凝縮した有機相および水性相から、非凝縮性炭化水素およびH2Sを含む非凝縮性ガスを含んでなる冷却された蒸気相を分離する工程をさらに含む、請求項1〜4のいずれか一項に記載のプロセス。
- 前記冷却された蒸気相を処理し、実質的にH2Sを分離する工程をさらに含む、請求項5に記載のプロセス。
- 前記冷却された蒸気相の処理が、収着剤床または液体洗浄部と接触させることを含む、請求項6に記載のプロセス。
- 前記冷却された蒸気相の少なくとも一部を,蒸気改質器へ誘導し、水素を生成する工程をさらに含む、請求項5〜7のいずれか一項に記載のプロセス。
- 前記液体水性相の処理が、前記液体水性相をサワー水ストリッパーにさらし、ガス相NH3生成物を得る工程を含む、請求項1〜3、5〜8のいずれか一項に記載のプロセス。
- NH3およびH2Sが、前記生成物蒸気に含まれる前記水溶性化合物であり、
前記生成物蒸気を冷却することにより、NH3およびH2Sを含む液体水性相を凝縮し、
前記溶解したNH3は、前記液体水性相におけるNH3とH2Sとの(NH4)2S形成反応の後に残存するよう、前記液体水性相に過剰量存在し、
前記ガス相NH3生成物が、前記液体水性相を酸素と反応させ、(NH4)2Sを(NH4)2SO4に実質的に酸化させ、次いで、前記液体水性相をサワー水ストリッパーにさらすことにより得られる、請求項9に記載のプロセス。 - 前記液体水性相と酸素との反応が、触媒的に行われる、請求項10に記載のプロセス。
- 前記水性(NH4)OH生成物が、前記液体水性相を、酸素と反応させ、(NH4)2Sを(NH4)2SO4に実質的に酸化させることにより得られる、請求項1または2に記載のプロセス。
- 前記バイオマスが、前記液体水性相に寄与する水分を含む、請求項1〜12のいずれか一項に記載のプロセス。
- 前記脱酸素凝縮性炭化水素が、前記液体有機相において、実質的に回収され、ガソリン、ディーゼルおよび灯油に相当する特性を有する炭化水素を含んでなる、請求項1〜13のいずれか一項に記載のプロセス。
- 前記バイオマスが、窒素(N)化合物および硫黄(S)化合物を含んでなり、これらが、前記水素化熱分解反応器に導入された水素と反応し、前記生成物蒸気においてNH3およびH2Sを形成し、
前記生成物蒸気中において、NH3の量が、H2Sとの反応により、(NH4)2Sを形成するために消費される量より過剰である、請求項1〜14のいずれか一項に記載のプロセス。 - 前記生成物蒸気が、NH3およびH2Sを前記水溶性化合物として含み、 前記液体水性相が、NH3とH2Sとの反応により形成される(NH4)2Sを溶解するのに十分な量以上の水を含んでなる、請求項1〜15のいずれか一項に記載のプロセス。
- アンモニア生成物を調製する方法であって、
水素化熱分解反応器中において、バイオマスを処理し、固体チャー、ならびに水素、一酸化炭素、二酸化炭素、脱酸素凝縮性炭化水素および水蒸気を含み、全ての成分が気体状態となる温度において前記水素化熱分解反応器から排出される、加熱された生成物蒸気を得る工程と、
前記加熱された生成物蒸気を冷却し、分離液体相として、有機相および水性相に凝縮させる工程であって、
前記水性相が、NH3の前記加熱された生成物蒸気から前記水性相への溶解によって形成されるNH4OHを含む、工程と、
前記分離液体相を分離し、ガス相NH3生成物または水性NH4OHのようなアンモニア生成物を前記水性相の処理から得る工程と、
を含むことを特徴とする、方法。 - 前記生成物蒸気が、NH3およびH2Sを含み、
前記加熱された生成物蒸気を冷却により、NH3とH2Sが前記加熱された生成物蒸気から水性相に溶解し、溶解したNH3の一部が、溶解したH2Sと反応することにより得られた(NH4)2Sを、前記水性相がさらに含む、請求項17に記載の方法。 - 前記水素化熱分解反応器が、連続する複数の反応器を含んでなる、請求項17または18に記載の方法。
- 前記アンモニア生成物が、前記水性相をサワー水ストリッパーにさらすことにより得られる前記ガス相NH3生成物である、請求項17〜19のいずれか一項に記載の方法。
- 前記液体相から、非凝縮性炭化水素を含む冷却された蒸気相を分離する工程と、 前記非凝縮性炭化水素の少なくとも一部を水蒸気改質し、前記水素化熱分解反応器において、前記バイオマスの処理に使用される水素を生成する工程と、を含む請求項17〜20のいずれか一項に記載の方法。
- バイオマス供給原料および水素を、1つ以上の反応器を備える水素化熱分解反応器中に導入する工程であって、
ケイ素が前記バイオマス中に存在する、工程と、
前記バイオマスを十分に脱酸素化し、気体状態であり、脱酸素凝縮性炭化水素、非凝縮性炭化水素および水を含んでなり、全ての成分が気体状態となる温度において前記水素化熱分解反応器から排出される、前記水素化熱分解反応器の生成物蒸気を得る工程と、 前記生成物蒸気を冷却し、凝縮性液体有機相、凝縮性液体水性相、および少なくともH2Sの一部を含む、冷却された蒸気相を得る工程と、
前記凝縮性液体有機相、前記凝縮性液体水性相および前記冷却された蒸気相を分離する工程と、
前記冷却された蒸気相を処理し、H2Sを実質的に除去し、少なくとも非凝縮性炭化水素の一部を含む、処理された蒸気相を得る工程と、
前記処理された蒸気相を、水蒸気改質機にさらし、改質された水素を前記非凝縮性炭化水素から生成する工程と、
を含むことを特徴とする、水素化熱分解プロセス。 - 前記水素化熱分解反応器が、連続する複数の反応器を含んでなる、請求項22に記載のプロセス。
- 前記冷却された蒸気相の処理工程が、前記冷却された蒸気相を、収着剤床または液体洗浄部と接触させることを含む、請求項22または23に記載のプロセス。
- 前記改質された水素の少なくとも一部を前記水素化熱分解反応器に再循環させる工程をさらに含む、請求項22〜24のいずれか一項に記載のプロセス。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/196,645 | 2011-08-02 | ||
US13/196,645 US8859831B2 (en) | 2011-08-02 | 2011-08-02 | Removal of hydrogen sulfide as ammonium sulfate from hydropyrolysis product vapors |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014523979A Division JP6077540B2 (ja) | 2011-08-02 | 2012-07-26 | 水素化熱分解生成物蒸気からの硫酸アンモニウムとしての硫化水素の除去 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2017122223A JP2017122223A (ja) | 2017-07-13 |
JP6441389B2 true JP6441389B2 (ja) | 2018-12-19 |
Family
ID=46690698
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014523979A Active JP6077540B2 (ja) | 2011-08-02 | 2012-07-26 | 水素化熱分解生成物蒸気からの硫酸アンモニウムとしての硫化水素の除去 |
JP2017003335A Active JP6441389B2 (ja) | 2011-08-02 | 2017-01-12 | 水素化熱分解生成物蒸気からの硫酸アンモニウムとしての硫化水素の除去 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014523979A Active JP6077540B2 (ja) | 2011-08-02 | 2012-07-26 | 水素化熱分解生成物蒸気からの硫酸アンモニウムとしての硫化水素の除去 |
Country Status (17)
Country | Link |
---|---|
US (2) | US8859831B2 (ja) |
EP (2) | EP2739571B1 (ja) |
JP (2) | JP6077540B2 (ja) |
KR (2) | KR101955177B1 (ja) |
CN (2) | CN105107346B (ja) |
AR (1) | AR087438A1 (ja) |
AU (2) | AU2012290464B2 (ja) |
BR (2) | BR122015017656B1 (ja) |
CA (1) | CA2843419C (ja) |
CL (1) | CL2014000261A1 (ja) |
MX (2) | MX362663B (ja) |
MY (2) | MY195613A (ja) |
RU (2) | RU2653841C2 (ja) |
SA (1) | SA112330748B1 (ja) |
UA (2) | UA121749C2 (ja) |
WO (1) | WO2013019558A1 (ja) |
ZA (2) | ZA201400959B (ja) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8859831B2 (en) * | 2011-08-02 | 2014-10-14 | Gas Technology Institute | Removal of hydrogen sulfide as ammonium sulfate from hydropyrolysis product vapors |
US9416321B2 (en) * | 2012-05-18 | 2016-08-16 | Uop Llc | Separation process with modified enhanced hot separator system |
US20140037507A1 (en) * | 2012-07-31 | 2014-02-06 | Hsiao-Lun WANG | Organic compound pyrolysis flashover energy-saving regeneration treatment system |
NL2013230B1 (en) * | 2014-07-21 | 2016-08-16 | Airpack Holding B V | Method for upgrading biogas and production of ammonium sulphate. |
US10392566B2 (en) | 2015-04-27 | 2019-08-27 | Gas Technology Institute | Co-processing for control of hydropyrolysis processes and products thereof |
AU2016360766B2 (en) * | 2015-11-23 | 2019-08-22 | Shell Internationale Research Maatschappij B.V. | Conversion of biomass into a liquid hydrocarbon material |
CN108291152B (zh) * | 2015-11-23 | 2021-01-08 | 国际壳牌研究有限公司 | 生物质向液态烃物质的转化 |
US10264578B2 (en) * | 2017-01-31 | 2019-04-16 | Qualcomm Incorporated | Listen before transmit (LBT) communication channel for vehicle-to-vehicle communications |
US10246330B2 (en) | 2017-04-13 | 2019-04-02 | Marsulex Environmental Technologies Corporation | Systems and processes for removing hydrogen sulfide from gas streams |
US11383995B2 (en) * | 2018-03-28 | 2022-07-12 | Heartland Water Technology, Inc. | Apparatus and method for treating hydrogen sulfide and ammonia in wastewater streams |
CN109502556B (zh) * | 2018-11-28 | 2022-01-14 | 昆明理工大学 | 一种载硫磺后催化剂回收单质硫并再生的方法及*** |
CN112442383B (zh) * | 2020-11-13 | 2022-03-04 | 新奥科技发展有限公司 | 一种煤的预处理方法 |
US11967745B2 (en) * | 2022-04-27 | 2024-04-23 | Saudi Arabian Oil Company | Co-production of hydrogen, carbon, and electricity with carbon dioxide capture |
Family Cites Families (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1021254A (en) | 1974-10-22 | 1977-11-22 | Ortloff Corporation (The) | Natural gas processing |
US4336125A (en) * | 1979-07-20 | 1982-06-22 | Institute Of Gas Technology | Production of synthetic hydrocarbon fuels from peat |
US4415431A (en) | 1982-07-14 | 1983-11-15 | Cities Service Company | Integrated oxygasification and hydropyrolysis process for producing liquid and gaseous hydrocarbons |
US4690807A (en) * | 1985-08-15 | 1987-09-01 | General Electric Environmental Services, Inc. | Process for the simultaneous absorption of sulfur oxides and production of ammonium sulfate |
US4765873A (en) * | 1985-12-06 | 1988-08-23 | The Dow Chemical Company | Continuous process for the removal of hydrogen sulfide from a gaseous stream |
CN1018928B (zh) * | 1986-05-20 | 1992-11-04 | 煤气技术研究所 | 硫化床中含碳固体粒子气化时除去硫化合物的方法 |
US4749555A (en) | 1986-10-02 | 1988-06-07 | Shell Oil Company | Process for the selective removal of hydrogen sulphide and carbonyl sulfide from light hydrocarbon gases containing carbon dioxide |
US5427762A (en) * | 1987-05-27 | 1995-06-27 | Hydrocarb Corporation | Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol |
US4854249A (en) | 1987-08-03 | 1989-08-08 | Institute Of Gas Technology | Two stage combustion |
US4908122A (en) | 1989-05-08 | 1990-03-13 | Uop | Process for sweetening a sour hydrocarbon fraction |
US4913802A (en) | 1989-05-08 | 1990-04-03 | Uop | Process for sweetening a sour hydrocarbon fraction |
US5207927A (en) * | 1992-03-18 | 1993-05-04 | Uop | Treatment of an aqueous stream containing water-soluble inorganic sulfide compounds |
US5470486A (en) | 1994-06-20 | 1995-11-28 | Uop | Conversion of water-soluble inorganic sulfide compounds in an aqueous stream |
US5536385A (en) | 1995-03-03 | 1996-07-16 | Envirocorp Services & Technology, Inc. | Production and purification of contaminated effluent streams containing ammonium sulfate and ammonia |
CA2226023A1 (en) * | 1997-01-08 | 1998-07-08 | Colt Engineering Corporation | Process for scrubbing ammonia and hydrogen sulfide from a fluid acid stream |
DE19731062C2 (de) * | 1997-07-19 | 2001-07-12 | Lurgi Lentjes Bischoff Gmbh | Verfahren zur Entfernung von sauren Gasen aus Rauchgasen, insbesondere aus Kraftwerksabgasen und Abgasen von Müllverbrennungsanlagen |
US6017501A (en) * | 1997-12-26 | 2000-01-25 | Marathon Oil Company | Disposal of hydrogen sulfide gas by conversion to sulfate ions in an aqueous solution |
NL1011490C2 (nl) | 1999-03-08 | 2000-09-12 | Paques Bio Syst Bv | Werkwijze voor het ontzwavelen van gassen. |
US6797154B2 (en) * | 2001-12-17 | 2004-09-28 | Chevron U.S.A. Inc. | Hydrocracking process for the production of high quality distillates from heavy gas oils |
US20080031809A1 (en) * | 2006-07-18 | 2008-02-07 | Norbeck Joseph M | Controlling the synthesis gas composition of a steam methane reformer |
RU2261891C1 (ru) * | 2004-05-31 | 2005-10-10 | Институт химии и химической технологии СО РАН (ИХХТ СО РАН) | Способ получения жидких углеводородных смесей из твердого углеродсодержащего сырья |
EP1852493A1 (en) * | 2006-05-05 | 2007-11-07 | BIOeCON International Holding N.V. | Hydrothermal treatment of carbon-based energy carrier material |
US7258848B1 (en) | 2006-07-31 | 2007-08-21 | E. I. Du Pont De Nemours And Company | Process for scrubbing ammonia from acid gases comprising ammonia and hydrogen sulfide |
US7960520B2 (en) | 2007-06-15 | 2011-06-14 | Uop Llc | Conversion of lignocellulosic biomass to chemicals and fuels |
US8217210B2 (en) * | 2007-08-27 | 2012-07-10 | Purdue Research Foundation | Integrated gasification—pyrolysis process |
US8217211B2 (en) * | 2007-08-27 | 2012-07-10 | Purdue Research Foundation | Process for producing liquid hydrocarbon by pyrolysis of biomass in presence of hydrogen from a carbon-free energy source |
JP2009093779A (ja) | 2007-09-19 | 2009-04-30 | Sony Corp | コンテンツ再生装置及びコンテンツ再生方法 |
US8353980B2 (en) * | 2008-12-05 | 2013-01-15 | Marsulex Environmental Technologies Corporation | Flue gas scrubbing apparatus and process |
US8915981B2 (en) * | 2009-04-07 | 2014-12-23 | Gas Technology Institute | Method for producing methane from biomass |
US8492600B2 (en) * | 2009-04-07 | 2013-07-23 | Gas Technology Institute | Hydropyrolysis of biomass for producing high quality fuels |
US20100251600A1 (en) * | 2009-04-07 | 2010-10-07 | Gas Technology Institute | Hydropyrolysis of biomass for producing high quality liquid fuels |
US8063258B2 (en) * | 2009-05-22 | 2011-11-22 | Kior Inc. | Catalytic hydropyrolysis of organophillic biomass |
EP2494006A4 (en) | 2009-10-27 | 2014-01-22 | Ignite Energy Resources Ltd | METHOD FOR PRODUCING HYDROCARBON PRODUCTS FROM BIO OILS AND / OR CARBON OILS |
US8383871B1 (en) * | 2010-09-03 | 2013-02-26 | Brian G. Sellars | Method of hydrogasification of biomass to methane with low depositable tars |
US8859831B2 (en) * | 2011-08-02 | 2014-10-14 | Gas Technology Institute | Removal of hydrogen sulfide as ammonium sulfate from hydropyrolysis product vapors |
-
2011
- 2011-08-02 US US13/196,645 patent/US8859831B2/en active Active
-
2012
- 2012-07-26 MY MYPI2020002472A patent/MY195613A/en unknown
- 2012-07-26 KR KR1020147005634A patent/KR101955177B1/ko active Application Filing
- 2012-07-26 AU AU2012290464A patent/AU2012290464B2/en active Active
- 2012-07-26 CA CA2843419A patent/CA2843419C/en active Active
- 2012-07-26 MX MX2014001200A patent/MX362663B/es active IP Right Grant
- 2012-07-26 JP JP2014523979A patent/JP6077540B2/ja active Active
- 2012-07-26 RU RU2014107841A patent/RU2653841C2/ru not_active IP Right Cessation
- 2012-07-26 CN CN201510554096.0A patent/CN105107346B/zh active Active
- 2012-07-26 EP EP12748300.6A patent/EP2739571B1/en active Active
- 2012-07-26 BR BR122015017656-5A patent/BR122015017656B1/pt active IP Right Grant
- 2012-07-26 EP EP22150181.0A patent/EP4005981A1/en active Pending
- 2012-07-26 KR KR1020197005683A patent/KR102092527B1/ko active IP Right Grant
- 2012-07-26 UA UAA201610071A patent/UA121749C2/uk unknown
- 2012-07-26 UA UAA201402083A patent/UA113740C2/uk unknown
- 2012-07-26 MY MYPI2014700228A patent/MY178021A/en unknown
- 2012-07-26 RU RU2018114265A patent/RU2018114265A/ru not_active Application Discontinuation
- 2012-07-26 CN CN201280048542.5A patent/CN103842299B/zh active Active
- 2012-07-26 WO PCT/US2012/048345 patent/WO2013019558A1/en active Application Filing
- 2012-07-26 BR BR112014002376-0A patent/BR112014002376B1/pt active IP Right Grant
- 2012-08-01 SA SA112330748A patent/SA112330748B1/ar unknown
- 2012-08-02 AR ARP120102830A patent/AR087438A1/es active IP Right Grant
-
2014
- 2014-01-29 MX MX2019001085A patent/MX2019001085A/es active IP Right Grant
- 2014-01-31 CL CL2014000261A patent/CL2014000261A1/es unknown
- 2014-02-07 ZA ZA2014/00959A patent/ZA201400959B/en unknown
- 2014-10-13 US US14/512,841 patent/US9593282B2/en active Active
-
2015
- 2015-02-25 ZA ZA2015/01289A patent/ZA201501289B/en unknown
-
2017
- 2017-01-12 JP JP2017003335A patent/JP6441389B2/ja active Active
- 2017-02-16 AU AU2017201034A patent/AU2017201034B2/en active Active
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6441389B2 (ja) | 水素化熱分解生成物蒸気からの硫酸アンモニウムとしての硫化水素の除去 | |
JP2014529635A5 (ja) | ||
CN102159527B (zh) | 用于将固体转化为燃料的***以及方法 | |
EA012530B1 (ru) | Способ получения этанола из сырья, содержащего углеводороды | |
AU2010224320A1 (en) | Process for conversion of waste fluid streams from chemical processing plants to beneficiary agriculture products | |
WO2020160998A1 (en) | A process for cleaning biogas while producing a sulfur-containing fertilizer | |
US20070292337A1 (en) | Method for Hydrogen Sulphide and/or Mercaptans Decomposition | |
NZ716910B2 (en) | Hydropyrolysis process | |
NZ620809B2 (en) | Removal of hydrogen sulfide as ammonium sulfate from hydropyrolysis product vapors | |
WO2020132546A1 (en) | Methods and systems to decarbonize natural gas using sulfur to produce hydrogen and polymers | |
US1160375A (en) | Process of removing sulfureted hydrogen from gases. | |
WO2019132209A1 (ko) | 황화수소를 포함하는 산성가스 정제방법 및 그 장치 | |
CN115244156B (zh) | 成本有效的具有气体再循环的脱氧工艺 | |
CN105722959A (zh) | 烷烃转化成有机硒和有机碲 | |
CN103359690A (zh) | 获取硫的方法和装置 | |
JPH11302667A (ja) | ガス化方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20180126 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180206 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20180507 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180704 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180717 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20181015 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20181026 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20181121 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6441389 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |