JP6356138B2 - 毛髪処理剤用キット及び毛髪処理方法 - Google Patents
毛髪処理剤用キット及び毛髪処理方法 Download PDFInfo
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- JP6356138B2 JP6356138B2 JP2015541568A JP2015541568A JP6356138B2 JP 6356138 B2 JP6356138 B2 JP 6356138B2 JP 2015541568 A JP2015541568 A JP 2015541568A JP 2015541568 A JP2015541568 A JP 2015541568A JP 6356138 B2 JP6356138 B2 JP 6356138B2
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- hair treatment
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- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- AZJPTIGZZTZIDR-UHFFFAOYSA-L rose bengal Chemical compound [K+].[K+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 AZJPTIGZZTZIDR-UHFFFAOYSA-L 0.000 description 1
- 229940109850 royal jelly Drugs 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 239000004248 saffron Substances 0.000 description 1
- 235000013974 saffron Nutrition 0.000 description 1
- 235000002020 sage Nutrition 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 229940058287 salicylic acid derivative anticestodals Drugs 0.000 description 1
- 150000003872 salicylic acid derivatives Chemical class 0.000 description 1
- SJOXEWUZWQYCGL-UHFFFAOYSA-N salicylic acid menthyl ester Natural products CC(C)C1CCC(C)CC1OC(=O)C1=CC=CC=C1O SJOXEWUZWQYCGL-UHFFFAOYSA-N 0.000 description 1
- 108700004121 sarkosyl Proteins 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000001026 semi permanent hair color Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 239000012176 shellac wax Substances 0.000 description 1
- SQVRNKJHWKZAKO-OQPLDHBCSA-N sialic acid Chemical compound CC(=O)N[C@@H]1[C@@H](O)C[C@@](O)(C(O)=O)OC1[C@H](O)[C@H](O)CO SQVRNKJHWKZAKO-OQPLDHBCSA-N 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229940080237 sodium caseinate Drugs 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- KMPHTYSTEHXSTL-UHFFFAOYSA-M sodium;2-hydroxypropanoate;2-hydroxypropanoic acid Chemical compound [Na+].CC(O)C(O)=O.CC(O)C([O-])=O KMPHTYSTEHXSTL-UHFFFAOYSA-M 0.000 description 1
- ZNOZEKFDBJRBMI-UHFFFAOYSA-M sodium;4-(2-ethylhexoxy)-4-oxo-3-sulfobutanoate Chemical compound [Na+].CCCCC(CC)COC(=O)C(S(O)(=O)=O)CC([O-])=O ZNOZEKFDBJRBMI-UHFFFAOYSA-M 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- UQZIYBXSHAGNOE-XNSRJBNMSA-N stachyose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO[C@@H]3[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O3)O)O2)O)O1 UQZIYBXSHAGNOE-XNSRJBNMSA-N 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 229910052917 strontium silicate Inorganic materials 0.000 description 1
- QSQXISIULMTHLV-UHFFFAOYSA-N strontium;dioxido(oxo)silane Chemical compound [Sr+2].[O-][Si]([O-])=O QSQXISIULMTHLV-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 239000001027 temporary hair color Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- BORJONZPSTVSFP-UHFFFAOYSA-N tetradecyl 2-hydroxypropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)O BORJONZPSTVSFP-UHFFFAOYSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
- KWXLCDNSEHTOCB-UHFFFAOYSA-J tetrasodium;1,1-diphosphonatoethanol Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P(=O)([O-])C(O)(C)P([O-])([O-])=O KWXLCDNSEHTOCB-UHFFFAOYSA-J 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- SHWIJIJNPFXOFS-UHFFFAOYSA-N thiotaurine Chemical compound NCCS(O)(=O)=S SHWIJIJNPFXOFS-UHFFFAOYSA-N 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- 229940098465 tincture Drugs 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- GYDJEQRTZSCIOI-LJGSYFOKSA-N tranexamic acid Chemical compound NC[C@H]1CC[C@H](C(O)=O)CC1 GYDJEQRTZSCIOI-LJGSYFOKSA-N 0.000 description 1
- 229960000401 tranexamic acid Drugs 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229940118594 trimethylolpropane triisostearate Drugs 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- 229960005066 trisodium edetate Drugs 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- LNRUEZIDUKQGRH-YZUCMPLFSA-N umbelliferose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 LNRUEZIDUKQGRH-YZUCMPLFSA-N 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 229960001722 verapamil Drugs 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000010374 vitamin B1 Nutrition 0.000 description 1
- 239000011691 vitamin B1 Substances 0.000 description 1
- 235000019164 vitamin B2 Nutrition 0.000 description 1
- 239000011716 vitamin B2 Substances 0.000 description 1
- 235000019158 vitamin B6 Nutrition 0.000 description 1
- 239000011726 vitamin B6 Substances 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 239000009538 yokuinin Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 229940105125 zinc myristate Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- GBFLQPIIIRJQLU-UHFFFAOYSA-L zinc;tetradecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O GBFLQPIIIRJQLU-UHFFFAOYSA-L 0.000 description 1
- OJYLAHXKWMRDGS-UHFFFAOYSA-N zingerone Chemical compound COC1=CC(CCC(C)=O)=CC=C1O OJYLAHXKWMRDGS-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
- FYGDTMLNYKFZSV-BYLHFPJWSA-N β-1,4-galactotrioside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@H](CO)O[C@@H](O[C@@H]2[C@@H](O[C@@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-BYLHFPJWSA-N 0.000 description 1
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
- 229930007845 β-thujaplicin Natural products 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/04—Preparations for permanent waving or straightening the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
- A61K2800/882—Mixing prior to application
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Description
特許文献1には、単体のマグネシウムと水素分子とを反応させ、粉末状のマグネシウム基水素化物を製造する方法が開示されている。前記粉末状のマグネシウム基水素化物は、予め水素を吸蔵しており、水と反応させることにより、効率的に水素が発生する。
特許文献2には、微粒子化した水素化マグネシウムを含有させ、水と反応させることにより、水素が発生する粉末浴用化粧料が開示されている。しかしながら、この粉末浴用化粧料は、使用時に十分な水素を発生させるために大量の水が必要であり、また、粉末浴用化粧料の反応に使用する水は、お湯である必要がある。
水溶液が酸性を示す物質を含有するB剤と、
水を含有するC剤と、
からなる毛髪処理剤用キットを提供する。
本発明に係る毛髪処理剤用キットを用いて得られる毛髪処理剤としては、例えば、パーマ剤又は染毛剤が挙げられる。
本発明に係る毛髪処理剤用キットは、前記A剤と、前記B剤と、を予め混合しておいてもよい。
また、前記B剤と、前記C剤と、を予め混合しておいてもよい。
本発明に係る毛髪処理剤用キットは、前記A剤、前記B剤、及び前記C剤を、使用時に混合して毛髪処理剤を得ることができる。
本発明に係る毛髪処理剤用キットの前記B剤に含有させることができる前記水溶液が酸性を示す物質としては、例えば、クエン酸、塩化マグネシウム、過酸化水素等を挙げることができる。
水溶液が酸性を示す物質を含有するB剤を毛髪に接触させる接触工程(II)と、
水を含有するC剤を毛髪に接触させる接触工程(III)と、
を、同時又は順不同で行う毛髪処理方法を提供する。
本発明に係る毛髪処理方法では、前記接触工程(I)〜(III)を経た後に、毛髪を加熱する加熱工程(IV)を更に行うこともできる。
本発明に係る化粧料用キット及び毛髪処理剤用キットは、大別して、(1)水素化マグネシウムを含有するA剤、(2)水溶液が酸性を示す物質を含有するB剤、(3)水を含有するC剤、からなる。そして、これらA剤、B剤及びC剤を、混合することにより化粧料又は毛髪処理剤が得られる。
水素化マグネシウムを生成する反応式は下記式(1)で表される。
上記問題点を解決するため、B剤中に水溶液が酸性を示す物質を含有させ、反応溶液を酸性とすることで、上記式(2)の反応が常温においても効率的に水素を発生させることが可能となる。
前記染毛料としては、例えば、ヘアマニキュア、カラーシャンプー、カラーリンス等の半永久染毛料、カラースプレー、カラースティック等、一時的に染毛してシャンプー等で洗い流せる一時染毛料等が挙げられる。
A剤は、水素化マグネシウムを含有する。
本発明に用いられるA剤中の水素化マグネシウムは、その入手方法に特に制限はないが、例えば、特許第4083786号公報や、特許第4425990号公報に開示されている方法によって、効率的に製造することが可能である。
また、特許第4425990号公報に開示されているように、粉体原料のかわりに、マグネシウムを主成分とする薄片を複数集積して圧縮した圧縮物を作成し、これを水素ガス雰囲気中で水素ガスとを反応させてもよい。この方法によれば、マグネシウムを主成分とする薄片から製造するので、粉塵爆発を起こす可能性がある粉体原料から製造する方法に比べ、より安全に、水素化率の高い水素化マグネシウムを効率的に製造することができる。
前記吸湿用成分としては、水分を吸収する作用を有するものを含有すればよく、例えば、シリカ、硫酸ナトリウム、硫酸マグネシウム、硫酸銅、塩化カルシウム、塩化マグネシウム、アルミナ、五酸化二リン、珪藻土、ゼオライト等が挙げられる。
なお、平均粒径とは、水素化マグネシウムの粒度分布を測定して得られた50wt%径である。50wt%径とは、50%累積度数の粒径である。つまり、粒径が小さい水素化マグネシウム粒子から順に累積し、その累積値が50%に達したときの粒径である。
B剤は、水溶液が酸性を示す物質を含有する。
本発明に用いられるB剤中の水溶液が酸性を示す物質は、一般的に化粧料や毛髪処理剤等に用いられ、少量では人体に影響のない物質であり、水溶液とした時に酸性を示す物質であれば、公知の物質を1種又は2種以上自由に選択して用いることができる。
C剤は、水を含有する。
本発明に用いられるC剤中の水は、一般的に化粧料や毛髪処理剤等に用いられ、入手が容易な水である。また、単一成分であっても、混合成分であってもよい。
前記水は、原水、水道水、蒸留水、精製水、純水、脱イオン水、淡水、硬水、軟水等が挙げられる。
さらに、本発明に係る化粧料用キット及び毛髪処理剤キットの各剤は、公知方法により調製でき、通常用いられる成分で本発明の効果を妨げない範囲において、例えば、保湿剤、界面活性剤(アニオン界面活性剤、カチオン界面活性剤、両性界面活性剤、非イオン界面活性剤等)、油分(炭化水素油、合成エステル油、シリコーン油、液体油脂、固体油脂、ロウ類等)、高級脂肪酸、高級アルコール、粉末成分、水溶性高分子(天然、半合成、合成)、増粘剤、紫外線吸収剤、金属イオン封鎖剤、低級アルコール、糖類(単糖、オリゴ糖、多糖)、有機アミン、pH調製剤、ビタミン類、酸化防止剤、酸化防止助剤、その他の配合可能成分等を、必要に応じて適宜配合することができる。ただし、これらの例示に限定されるものでない。
本発明に係る毛髪処理方法は、少なくとも、接触工程(I)〜(III)を、同時又は順不同で行う方法である。また、必要に応じて、加熱工程(IV)を更に行うこともできる。以下、各工程について、詳細に説明する。なお、各工程で用いるA剤、B剤、及びC剤の詳細は、前述した化粧料用キット及び毛髪処理剤用キットで用いられるA剤、B剤、及びC剤と同一であるため、ここでは説明を割愛する。
接触工程(I)は、水素化マグネシウムを含有するA剤を毛髪に接触させる工程である。
接触工程(II)は、水溶液が酸性を示す物質を含有するB剤を毛髪に接触させる工程である。
接触工程(III)は、水を含有するC剤を毛髪に接触させる工程である。
加熱工程(IV)は、前記接触工程(I)〜(III)を経た後に、毛髪を加熱する工程である。通常、前記接触工程(I)〜(III)を行い、所定時間の放置工程を経て、その後、毛髪から毛髪処理剤をシャンプー等で除去した後に、この加熱工程(IV)を行う。加熱工程(IV)は、本発明において必須の工程ではないが、後述する通り、毛髪中の水分をより向上させるためには、加熱工程(IV)を行うことが好ましい。
以下、本発明に係る毛髪処理方法の具体的なフローについて、一例を挙げながら説明する。
本発明に係る毛髪処理方法では、実際の毛髪処理の前に、毛髪表面に付着した汚れや整髪料等を除去するために、プレシャンプーを行うことができる。このプレシャンプーは、本発明に係る毛髪処理方法においては、必須の工程ではないが、例えば、毛髪にシリコーンオイル等が付着している場合には、行った方が好ましい。プレシャンプーを行うことで、毛髪処理効果をより向上させることができる。
行う毛髪処理の種類に応じて、毛髪処理剤の調製を行う。より具体的には、例えば、本発明のA剤、B剤、及びC剤の全て又は一部を、パーマ剤第1剤及び/又はパーマ剤第2剤に混合して毛髪処理剤(パーマネント処理剤)を調製したり、A剤、B剤、及びC剤の全て又は一部を、染毛剤第1剤及び/又は染毛剤第2剤に混合して毛髪処理剤(染毛剤)を調製したりすることができる。このように、パーマ剤や染毛剤に本発明のA剤、B剤、及びC剤の全て又は一部を混合することにより、パーマネント処理やヘアカラー処理を施しながら、該処理によって生じる活性酸素を毛髪処理剤中の水素によって除去して毛髪や頭皮のダメージを防止すると同時に、水素と活性酸素との結合により、毛髪中の水分量が高まり、髪質の改善を行うことができる。
次に、毛髪処理剤の毛髪への塗布を行う。毛髪処理剤の毛髪への塗布方法は、毛髪処理剤の種類に応じて、常法に従って行うことができる。例えば、パーマネント処理の場合、所望の形状に毛髪を固定した状態で、パーマ剤第1剤を塗布後、必要に応じて放置、リンス等を行い、更にパーマ剤第2剤を塗布する方法を用いることができる。また、ヘアカラー処理の場合、前記の毛髪処理剤の調製で調製された染毛剤第1剤と染毛剤第2剤との混合剤を、そのまま毛髪に塗布する方法を用いることができる。
毛髪処理剤の毛髪への塗布後、そのままの状態で所定時間、放置を行う。放置することで、毛髪の表面や毛髪内部、頭皮において、A剤中の水素化マグネシウムとC剤中の水との加水分解反応が持続的に進行し、水素が発生する。そして、この水素が毛髪の表面や毛髪内部、頭皮における活性酸素と結合して水を発生し、毛髪や頭皮の水分量を向上させることができる。
適宜、放置を行った後、毛髪表面に存在する毛髪処理剤を除去する。毛髪処理剤の除去方法は、特に限定されず、例えば、水、シャンプー剤、リンス剤、などを用いて除去することができる。
毛髪処理剤の除去を行った後、毛髪表面に残った水分を乾燥処理する。乾燥処理の方法は特に限定されず、常法に従って、例えば、タオルドライ後、ヘアドライヤーを用いて乾燥する方法が挙げられる。
毛髪表面に残った水分を乾燥処理した後、本発明に係る毛髪処理方法では、更に毛髪を加熱することが好ましい。前述した通り、前記接触工程(I)〜(III)を経た後に、毛髪を加熱した方が、毛髪中の水分量が向上するからである。
実験例1では、本発明に係る化粧料用キット及び毛髪処理剤用キットから得られる化粧料及び毛髪処理剤について、水素の発生効果及び水素発生の持続効果を検討した。
[実施例1]美容液
下記表1に示す配合で、A剤、B剤及びC剤を調製した後、A剤、B剤、及びC剤を混合することにより美容液を調製した。
下記表2に示す配合で、A剤、B剤及びC剤を調製した後、A剤、B剤、及びC剤を混合することによりクリームを調製した。
下記表3に示す配合で、A剤、B剤及びC剤を調製した後、A剤、B剤、及びC剤を混合することによりローションを調製した。
下記表4に示す配合で、A剤、B剤及びC剤を調製した後、A剤、B剤、及びC剤を混合することによりパーマ剤第1剤を調製した。
下記表5に示す配合で、A剤、B剤及びC剤を調製した後、A剤、B剤、及びC剤を混合することによりパーマ剤第2剤を調製した。
下記表6に示す配合で、A剤、B剤及びC剤を調製した後、A剤、B剤、及びC剤を混合することにより染毛剤第1剤を調製した。
下記表7に示す配合で、A剤、B剤及びC剤を調製した後、A剤、B剤、及びC剤を混合することにより染毛剤第2剤を調製した。
前記実施例6で調製した染毛剤第1剤と、前記実施例7で調製した染毛剤第2剤と、を混合し、染毛剤を調製した。
前記表1に示す配合中、A剤を配合せずに、実施例1と同様の方法により美容液を調製した。
前記表1に示す配合中、B剤を配合せずに、実施例1と同様の方法により美容液を調製した。
前記表3に示す配合中、A剤を配合せずに、実施例3と同様の方法によりローションを調製した。
前記表4に示す配合中、A剤を配合せずに、実施例4と同様の方法によりパーマ剤第1剤を調製した。
前記表5に示す配合中、A剤及びC剤の代わりに活性水素水5mL(商品名「クリスタル水素水」(株式会社ココシス製)、以下同じ)を配合し、実施例5と同様の方法によりパーマ剤第2剤を調製した。
前記表6に示す配合中、A剤を配合せずに、実施例6と同様の方法により染毛剤第1剤を調製した。
前記表7に示す配合中、A剤及びC剤の代わりに活性水素水5mLを配合し、実施例7と同様の方法により染毛剤第2剤を調製した。
前記比較例6で調製した染毛剤第1剤と、前記比較例7で調製した染毛剤第2剤と、を混合し、染毛剤を調製した。
前記で調製した各化粧料及び毛髪処理剤調製直後に、メチレンブルー試薬(和光純薬株式会社製)を滴下し、その呈色変化を調べた。また、青色に呈色したものに関しては、青色が消失するまでの時間を測定した。
※2:非常に薄い呈色のまま消失せず。
実験例2では、本発明に係る毛髪処理剤用キットから得られる毛髪処理剤をパーマ剤に配合した場合に、毛髪の水分量がどのように変化するかを調べた。
前記実験例1で調製した実施例4と比較例4のパーマ剤第1剤を、同一の被験者の毛髪の左右にそれぞれ塗布し、直径7.0mmのロッドに均一に巻きつけ、15分間放置した。その後、36℃のぬるま湯を用いて中間洗浄し、前記実験例1で調製した実施例5と比較例5のパーマ剤第2剤を、同一の被験者の毛髪の左右にそれぞれ塗布し、15分間放置した。その後、36℃のぬるま湯を用いて洗浄し、タオルドライ後にドライヤーを用いて乾燥した。
第1剤を塗布する前とパーマ処理後の毛髪中の水分量を、赤外線水分計(株式会社ケツト科学研究所製FD-610、以下同じ)を用いて測定した。
結果を下記表9に示す。
実験例3では、本発明に係る毛髪処理剤用キットから得られる毛髪処理剤を染毛剤に配合した場合に、毛髪の水分量がどのように変化するかを調べた。
前記実験例1で調製した実施例6と比較例6の染毛剤第1剤と、実施例7と比較例7の染毛剤第2剤とを混合し、同一の被験者の毛髪の左右にそれぞれ塗布し、15分間放置した。その後、36℃のぬるま湯を用いて洗浄し、タオルドライ後にドライヤーを用いて乾燥した。
染毛剤を塗布する前と染毛処理後の毛髪中の水分量を、赤外線水分計を用いて測定した。
結果を下記表10に示す。
実験例4では、公知の毛髪処理剤を用いた毛髪処理の工程において、本発明に係る毛髪処理を併用した場合に、毛髪の水分量、強度、及び外観がどのように変化するかを調べた。なお、公知の毛髪処理剤としては、染毛剤(ヘアカラー剤)の第1剤としてモルトベーネプロフェッショナル株式会社製のアデイロ(登録商標)カラーを、第2剤として1.8%過酸化水素水(株式会社ソワン製)を用いた。
染毛剤第1剤及び第2剤を混合し、これに水素化マグネシウム0.3gを添加し、混合して毛髪処理剤を調製した。調製した毛髪処理剤を、プレシャンプーを行った被験者3名の毛髪全体に塗布し、そのまま15分放置した。その後、36℃のぬるま湯を用いて洗浄し、タオルドライ後にドライヤーを用いて乾燥した。その後、200℃のアイロンを用いて加熱処理を行った。
染毛処理を行う前と染毛処理後の毛髪中の水分量を、赤外線水分計を用いて測定した。
染毛処理を行う前と染毛処理後の毛髪それぞれについて、デジタルフォースゲージDS2(株式会社イマダ製)を用いて、強度測定を行った。
染毛処理を行う前と染毛処理後の毛髪それぞれについて、肉眼及び電子顕微鏡(株式会社日立ハイテクノロジーズ製miMiniscope TM3000(登録商標))を用いて、毛髪表面の観察を行った。
それぞれの被験者における水分量測定の結果を下記表11に、その平均値を図1に示す。また、それぞれの被験者における強度測定の結果を下記表12に、その平均値を図2に示す。更に、それぞれの被験者の毛髪を写真撮影した結果を図3に、それぞれの被験者の毛髪のキューティクルについて、電子顕微鏡を用いて撮像した結果を図4に示す。なお、図4には、参考のために、理想的なキューティクルの撮像写真を併記した。
実験例5では、加熱工程の有無及びその温度によって、毛髪の水分量がどのように変化するかを調べた。
エアゾール用アルミ容器に、液化石油ガス(LPG)と共に、POE硬化ヒマシ油:2.0質量%、ミリスチン酸イソプロピル:1.0質量%、水素化マグネシウム:2.0質量%、クエン酸:2.0質量%、1,3−ブチレングリコール:5.0質量%、エタノール:10.0質量%、精製水:残余、を充填し、発泡性エアゾール毛髪処理剤を調製した。
(2)染毛処理
実験例4で用いた公知の染毛剤と同一の染毛剤を、プレシャンプーを行った被験者3名の毛髪全体に塗布し、その上から、前記で調製した発泡性エアゾール毛髪処理剤を毛髪全体に塗布し、そのまま15分放置した。その後、36℃のぬるま湯を用いて洗浄し、タオルドライ後に、被験者1は自然乾燥を行った。被験者2はドライヤーを用いて乾燥した。被験者3は、ドライヤーを用いて乾燥した後、200℃のアイロンを用いて加熱処理を行った。
それぞれの被験者について、染毛処理を行う前と染毛処理後の毛髪中の水分量を、赤外線水分計を用いて測定した。
それぞれの被験者における水分量測定の結果を下記表13に示す。
Claims (8)
- 水素化マグネシウムを含有するA剤と、
水溶液が酸性を示す物質を含有するB剤と、
水を含有するC剤と、
からなる毛髪処理剤用キット。 - 前記毛髪処理剤は、パーマ剤又は染毛剤である請求項1記載の毛髪処理剤用キット。
- 前記A剤と、前記B剤と、が予め混合された請求項1又は2に記載の毛髪処理剤用キット。
- 前記B剤と、前記C剤と、が予め混合された請求項1又は2に記載の毛髪処理剤用キット。
- 前記A剤、前記B剤、及び前記C剤を、使用時に混合して毛髪処理剤を得る請求項1から4のいずれか一項に記載の毛髪処理剤用キット。
- 前記水溶液が酸性を示す物質は、クエン酸、塩化マグネシウム、及び過酸化水素から選択される一以上の物質である請求項1から5のいずれか一項に記載の毛髪処理剤用キット。
- 水素化マグネシウムを含有するA剤を毛髪に接触させる接触工程(I)と、
水溶液が酸性を示す物質を含有するB剤を毛髪に接触させる接触工程(II)と、
水を含有するC剤を毛髪に接触させる接触工程(III)と、
を、同時又は順不同で行う毛髪処理方法。 - 前記接触工程(I)〜(III)を経た後に、
毛髪を加熱する加熱工程(IV)、
を、更に行う請求項7記載の毛髪処理方法。
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