JP6317449B2 - 新規なキレート化剤の組合せによる相乗的汚れ除去 - Google Patents
新規なキレート化剤の組合せによる相乗的汚れ除去 Download PDFInfo
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- JP6317449B2 JP6317449B2 JP2016539425A JP2016539425A JP6317449B2 JP 6317449 B2 JP6317449 B2 JP 6317449B2 JP 2016539425 A JP2016539425 A JP 2016539425A JP 2016539425 A JP2016539425 A JP 2016539425A JP 6317449 B2 JP6317449 B2 JP 6317449B2
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- cleaning composition
- alkali metal
- concentrated cleaning
- acid
- diacetic acid
- Prior art date
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- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
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- YDLQSTFHBCVEJV-UHFFFAOYSA-M sodium;2-(3,5,5-trimethylhexanoyloxy)benzenesulfonate Chemical compound [Na+].CC(C)(C)CC(C)CC(=O)OC1=CC=CC=C1S([O-])(=O)=O YDLQSTFHBCVEJV-UHFFFAOYSA-M 0.000 description 1
- OVONNAXAHAIEDF-UHFFFAOYSA-M sodium;4-benzoyloxybenzenesulfonate Chemical compound [Na+].C1=CC(S(=O)(=O)[O-])=CC=C1OC(=O)C1=CC=CC=C1 OVONNAXAHAIEDF-UHFFFAOYSA-M 0.000 description 1
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- 150000003445 sucroses Chemical class 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
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- 239000000271 synthetic detergent Substances 0.000 description 1
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- 108010075550 termamyl Proteins 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 description 1
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- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- 235000011178 triphosphate Nutrition 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- OHOTVSOGTVKXEL-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C(C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-UHFFFAOYSA-K 0.000 description 1
- 239000012588 trypsin Substances 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
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- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/06—Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/16—Phosphates including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3245—Aminoacids
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- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
アルカリ金属水酸化物、
アルカリ金属トリポリホスフェート、並びに
メチルグリシン二酢酸、及びグルタミン酸N,N−二酢酸からなる群から選択される少なくとも1つの錯化剤を含む、濃縮洗浄組成物を提供する。
〔1〕
アルカリ金属水酸化物、
アルカリ金属トリポリホスフェート、並びに
メチルグリシン二酢酸、及びグルタミン酸N,N−二酢酸からなる群から選択される少なくとも1つの錯化剤を含む、濃縮洗浄組成物。
〔2〕
組成物が、前記メチルグリシン二酢酸、及び前記グルタミン酸N,N−二酢酸を含む、項目1に記載の濃縮洗浄組成物。
〔3〕
前記アルカリ金属トリポリホスフェート、前記メチルグリシン二酢酸、及び前記グルタミン酸N,N−二酢酸の合計に対する、前記アルカリ金属トリポリホスフェートのモル比が0.05〜0.95である、項目1又は2に記載の濃縮洗浄組成物。
〔4〕
前記アルカリ金属水酸化物に対する、前記グルタミン酸N,N−二酢酸、前記メチルグリシン二酢酸、及び前記アルカリ金属トリポリホスフェートの合計のモル比が0.01〜1である、項目1〜3のいずれか一項に記載の濃縮洗浄組成物。
〔5〕
組成物が、少なくとも5質量%の前記アルカリ金属水酸化物を含む、項目1〜4のいずれか一項に記載の濃縮洗浄組成物。
〔6〕
前記アルカリ金属水酸化物が水酸化ナトリウムである、項目1〜5のいずれか一項に記載の濃縮洗浄組成物。
〔7〕
前記アルカリ金属トリポリホスフェートがトリポリリン酸ナトリウムである、項目1〜6のいずれか一項に記載の濃縮洗浄組成物。
〔8〕
1g/Lの濃度で蒸留水中に希釈し、温度20℃で測定したときに、組成物が少なくとも9のpHを提供する、項目1〜7のいずれか一項に記載の濃縮洗浄組成物。
〔9〕
組成物は、界面活性剤、漂白剤、活性化剤、キレート剤/封鎖剤、シリケート、洗浄剤フィラー又は結合剤、消泡剤、抗再析剤、酵素、色素、臭気物質、触媒、スレッショルドポリマー、汚れ懸濁剤、抗菌剤、及びその混合物からなる群から選択される化合物の少なくとも1つを更に含む、項目1〜8のいずれか一項に記載の濃縮洗浄組成物。
〔10〕
組成物が、ポリアクリレート、ポリメタクリレート、及び/又はポリマレアートを更に含む、項目1〜9のいずれか一項に記載の濃縮洗浄組成物。
〔11〕
組成物が、固体、粉末、液体、ゲル、又はペーストの形態で提供される、項目1〜10のいずれか一項に記載の濃縮洗浄組成物。
〔12〕
項目1〜10のいずれか一項に記載の濃縮洗浄組成物を0.1〜10g/L含む、水溶液。
〔13〕
酸化ポリフェノール及びケイ酸カルシウムを含む汚れを除去する物品洗浄用洗浄剤としての、項目1〜10のいずれか一項に記載の濃縮洗浄組成物の使用。
〔14〕
前記濃縮洗浄組成物を希釈して、0.1〜10g/Lの濃度を有する使用溶液を提供する、項目12に記載の使用。
〔15〕
前記物品洗浄用洗浄剤は、お茶及びコーヒー汚れを除去するために用いられる、項目12〜14のいずれか一項に記載の使用。
Claims (13)
- アルカリ金属水酸化物、
アルカリ金属トリポリホスフェート、
グルタミン酸N,N−二酢酸、及び
メチルグリシン二酢酸を含み、
前記アルカリ金属トリポリホスフェート、前記メチルグリシン二酢酸、及び前記グルタミン酸N,N−二酢酸の合計に対する、前記アルカリ金属トリポリホスフェートのモル比が0.8〜0.9であり、前記アルカリ金属トリポリホスフェート、前記メチルグリシン二酢酸、及び前記グルタミン酸N,N−二酢酸の合計に対する、前記グルタミン酸N,N−二酢酸のモル比が0.05〜0.25であり、前記アルカリ金属トリポリホスフェート、前記メチルグリシン二酢酸、及び前記グルタミン酸N,N−二酢酸の合計に対する、前記メチルグリシン二酢酸のモル比が0.05〜0.25である、濃縮洗浄組成物。 - 前記アルカリ金属水酸化物に対する、前記グルタミン酸N,N−二酢酸、前記メチルグリシン二酢酸、及び前記アルカリ金属トリポリホスフェートの合計のモル比が0.01〜1である、請求項1に記載の濃縮洗浄組成物。
- 組成物が、少なくとも5質量%の前記アルカリ金属水酸化物を含む、請求項1又は2に記載の濃縮洗浄組成物。
- 前記アルカリ金属水酸化物が水酸化ナトリウムである、請求項1〜3のいずれか一項に記載の濃縮洗浄組成物。
- 前記アルカリ金属トリポリホスフェートがトリポリリン酸ナトリウムである、請求項1〜4のいずれか一項に記載の濃縮洗浄組成物。
- 1g/Lの濃度で蒸留水中に希釈し、温度20℃で測定したときに、組成物が少なくとも9のpHを提供する、請求項1〜5のいずれか一項に記載の濃縮洗浄組成物。
- 組成物は、界面活性剤、漂白剤、活性化剤、キレート剤/封鎖剤、シリケート、洗浄剤フィラー又は結合剤、消泡剤、抗再析剤、酵素、色素、臭気物質、触媒、スレッショルドポリマー、汚れ懸濁剤、抗菌剤、及びその混合物からなる群から選択される化合物の少なくとも1つを更に含む、請求項1〜6のいずれか一項に記載の濃縮洗浄組成物。
- 組成物が、ポリアクリレート、ポリメタクリレート、及び/又はポリマレアートを更に含む、請求項1〜7のいずれか一項に記載の濃縮洗浄組成物。
- 組成物が、固体、粉末、液体、ゲル、又はペーストの形態で提供される、請求項1〜8のいずれか一項に記載の濃縮洗浄組成物。
- 請求項1〜8のいずれか一項に記載の濃縮洗浄組成物を0.1〜10g/L含む、水溶液。
- 酸化ポリフェノール及びケイ酸カルシウムを含む汚れを除去する物品洗浄用洗浄剤としての、請求項1〜8のいずれか一項に記載の濃縮洗浄組成物の使用。
- 前記濃縮洗浄組成物を希釈して、0.1〜10g/Lの濃度を有する使用溶液を提供する、請求項11に記載の使用。
- 前記物品洗浄用洗浄剤は、お茶及びコーヒー汚れを除去するために用いられる、請求項11又は12に記載の使用。
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ES2654192T3 (es) | 2013-09-09 | 2018-02-12 | Ecolab Usa Inc. | Eliminación sinérgica de manchas mediante una nueva combinación de agentes quelantes |
ES2807630T3 (es) | 2015-03-11 | 2021-02-23 | Basf Se | Mezclas de agentes quelantes y procedimiento de fabricación de dichas mezclas |
US10619125B2 (en) | 2015-03-12 | 2020-04-14 | Basf Se | Process for making mixtures of enantiomers of MGDA and GLDA |
HUE038978T2 (hu) | 2015-10-16 | 2018-12-28 | Hans Georg Hagleitner | Folyékony tisztítószer koncentrátum |
WO2019005940A1 (en) | 2017-06-27 | 2019-01-03 | Ecolab Usa Inc. | ELIMINATION OF NON-PHOSPHOROUS TRANSITION METALS IN LAUNDRY WASHING APPLICATIONS |
JP6514288B2 (ja) * | 2017-09-14 | 2019-05-15 | エコラボ ユーエスエー インコーポレイティド | 新規なキレート化剤の組合せによる相乗的汚れ除去 |
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Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1234445A (ja) | 1967-10-03 | 1971-06-03 | ||
NZ208612A (en) | 1983-06-24 | 1991-09-25 | Genentech Inc | Method of producing "procaryotic carbonyl hydrolases" containing predetermined, site specific mutations |
ATE113070T1 (de) | 1987-05-29 | 1994-11-15 | Genencor Int | Cutinase haltige reinigungsmittelzusammensetzungen. |
DE3727740A1 (de) | 1987-08-20 | 1989-03-02 | Rheinmetall Gmbh | Vorrichtung fuer einen nach vorn gerichteten huelsenauswurf aus einer fremdgetriebenen maschinenkanone |
DK212388D0 (da) | 1988-04-15 | 1988-04-15 | Novo Industri As | Detergent additiv |
DK204290D0 (da) | 1990-08-24 | 1990-08-24 | Novo Nordisk As | Enzymatisk detergentkomposition og fremgangsmaade til enzymstabilisering |
DK28792D0 (da) | 1992-03-04 | 1992-03-04 | Novo Nordisk As | Nyt enzym |
DK52393D0 (ja) | 1993-05-05 | 1993-05-05 | Novo Nordisk As | |
ES2141834T3 (es) | 1993-09-14 | 2000-04-01 | Regofix Ag | Dispositivo de sujecion entre un mango de herramienta y una maquina herramienta. |
US6436690B1 (en) | 1993-09-15 | 2002-08-20 | The Procter & Gamble Company | BPN′ variants having decreased adsorption and increased hydrolysis wherein one or more loop regions are substituted |
CA2173105C (en) | 1993-10-14 | 2003-05-27 | Andre Baeck | Protease-containing cleaning compositions |
MA23346A1 (fr) | 1993-10-14 | 1995-04-01 | Genencor Int | Variantes de la subtilisine |
ZA952220B (en) | 1994-05-02 | 1995-12-14 | Procter & Gamble | Bpn' variants having decreased adsorption and increased hydrolysis wherein one or more loop regions are substituted |
US6599730B1 (en) | 1994-05-02 | 2003-07-29 | Procter & Gamble Company | Subtilisin 309 variants having decreased adsorption and increased hydrolysis |
GB2311538A (en) * | 1996-03-29 | 1997-10-01 | Procter & Gamble | Detergent compositions |
US6165970A (en) * | 1996-03-29 | 2000-12-26 | The Procter & Gamble Company | Detergent composition comprising acrylic acid-based polymer and amino tricarboxylic acid-based compound |
GB2311541A (en) * | 1996-03-29 | 1997-10-01 | Procter & Gamble | Oxygen-releasing bleach composition |
US20040147426A1 (en) * | 1998-07-10 | 2004-07-29 | The Procter & Gamble Company | Laundry and cleaning compositions |
JP5025097B2 (ja) * | 2005-06-02 | 2012-09-12 | ディバーシー・アイピー・インターナショナル・ビー・ヴイ | 自動洗浄機用液体洗浄剤組成物 |
DE102007042857A1 (de) * | 2007-09-10 | 2009-03-12 | Henkel Ag & Co. Kgaa | Verfahren zum maschinellen Reinigen von Geschirr |
US8198228B2 (en) * | 2008-01-04 | 2012-06-12 | Ecolab Usa Inc. | Solidification matrix using an aminocarboxylate |
JP5324207B2 (ja) | 2008-12-19 | 2013-10-23 | ディバーシー株式会社 | 自動食器洗浄機用固形洗浄剤の製法およびそれによって得られる自動食器洗浄機用固形洗浄剤 |
WO2011076897A1 (en) * | 2009-12-22 | 2011-06-30 | Novozymes A/S | Use of amylase variants at low temperature |
KR20120129946A (ko) * | 2010-02-09 | 2012-11-28 | 바스프 에스이 | 세제 조성물 |
DE102010029348A1 (de) * | 2010-05-27 | 2011-12-08 | Henkel Ag & Co. Kgaa | Maschinelles Geschirrspülmittel |
EP2447349B1 (en) * | 2010-10-29 | 2015-07-29 | The Procter & Gamble Company | Thickened liquid hard surface cleaning composition |
CA2874061A1 (en) * | 2012-06-08 | 2014-01-09 | Danisco Us Inc. | Variant alpha amylases with enhanced activity on starch polymers |
ES2654192T3 (es) * | 2013-09-09 | 2018-02-12 | Ecolab Usa Inc. | Eliminación sinérgica de manchas mediante una nueva combinación de agentes quelantes |
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US9796950B2 (en) | 2017-10-24 |
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MX2016002935A (es) | 2016-06-06 |
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EP3272847B1 (en) | 2022-01-19 |
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CN105555930A (zh) | 2016-05-04 |
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AU2013399899B2 (en) | 2016-10-13 |
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