JP6298749B2 - 持続型トナー粒子及び現像剤 - Google Patents
持続型トナー粒子及び現像剤 Download PDFInfo
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- JP6298749B2 JP6298749B2 JP2014200601A JP2014200601A JP6298749B2 JP 6298749 B2 JP6298749 B2 JP 6298749B2 JP 2014200601 A JP2014200601 A JP 2014200601A JP 2014200601 A JP2014200601 A JP 2014200601A JP 6298749 B2 JP6298749 B2 JP 6298749B2
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- acid
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- NRTLTGGGUQIRRT-UHFFFAOYSA-N triethylazanium;bromide Chemical compound [Br-].CC[NH+](CC)CC NRTLTGGGUQIRRT-UHFFFAOYSA-N 0.000 description 1
- ILWRPSCZWQJDMK-UHFFFAOYSA-N triethylazanium;chloride Chemical compound Cl.CCN(CC)CC ILWRPSCZWQJDMK-UHFFFAOYSA-N 0.000 description 1
- AISMNBXOJRHCIA-UHFFFAOYSA-N trimethylazanium;bromide Chemical compound Br.CN(C)C AISMNBXOJRHCIA-UHFFFAOYSA-N 0.000 description 1
- CURCMGVZNYCRNY-UHFFFAOYSA-N trimethylazanium;iodide Chemical compound I.CN(C)C CURCMGVZNYCRNY-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08742—Binders for toner particles comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- G03G9/08755—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/0802—Preparation methods
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/0802—Preparation methods
- G03G9/0804—Preparation methods whereby the components are brought together in a liquid dispersing medium
- G03G9/0806—Preparation methods whereby the components are brought together in a liquid dispersing medium whereby chemical synthesis of at least one of the toner components takes place
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/0827—Developers with toner particles characterised by their shape, e.g. degree of sphericity
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
- G03G9/08797—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775 characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/093—Encapsulated toner particles
- G03G9/0935—Encapsulated toner particles specified by the core material
- G03G9/09357—Macromolecular compounds
- G03G9/09371—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/093—Encapsulated toner particles
- G03G9/09392—Preparation thereof
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Developing Agents For Electrophotography (AREA)
- Polyesters Or Polycarbonates (AREA)
Description
1−LのBuchi反応器に、主にデヒドロ−アビエチン酸から構成される不均衡化ロジン酸(258.3g)、グリセリンカーボネート(115.9g)およびヨウ化テトラエチルアンモニウム(1.42g)を添加した。前記混合物を、170℃に加熱し、酸価が1mg/g KOH未満になるまで、9時間維持した。その混合物に、エチルブチレングリコール(169.7g)、テレフタル酸(260.85g)およびFASCAT 4100(1.5g)を添加した。前記混合物を、165℃から220℃に5時間の期間にわたって加熱し、オーバーナイト維持した。ついで、前記混合物を、120.7℃の軟化点が得られるまで、225℃に加熱した。
オーバヘッドミキサーを備える2リットルのガラス反応器内に、307.58gの、標準的なPIEプロセスにより調製した実施例1の生物樹脂(粒径120.6nm)のエマルジョン(19.78重量%)、23.38gのCPE樹脂エマルジョン(35.60重量%)、36.94gのIGIワックス分散液(29.97重量%)および48.09gのシアン顔料PB15:3(14.96重量%)を添加した。別に、1.11gのAl2(SO4)3(27.85重量%)を、均質化下における凝集剤として添加した。前記混合物を、46.4℃に加熱して、300rpmで攪拌しながら、前記粒子を凝集させた。前記コア粒子が、1.25のGSDvを有する4.17μmの体積平均粒径を達するまで、COULTER COUNTERで粒径をモニターした。ついで、169.87gの上記生物樹脂のエマルジョンを、シェル材料として添加して、5.65ミクロンの平均粒径および1.25のGSDvを有するコア−シェル構造化粒子を得た。その後、4重量%のNaOH溶液、続けて、4.62gのEDTA(39重量%)を使用して、反応スラリーのpHを7.8に向上させて、トナーの成長を停止させた。停止後、前記反応混合物を、75℃に加熱し、融着時間(例えば、1時間、2時間および3時間)ならびに記載の円形度(例えば、0.954−0.968)が達成されるように、pHを約8.9から約7.3に調節した。
非溶融画像を、改良したDC12コピー機を使用して生成した。1.00mg/cm2のTMA(単位面積あたりのトナー量)を、Color Xpressions Select(CXS、90gsm、非コート、P/N 3R11540)ペーパー上の配置されたトナー量に使用し、光沢、しわおよびホットオフセットの測定に使用した。光沢/しわのターゲットを、ページの中心に配置された正方形の画像とした。一般的には、現像剤のバイアス電圧を調節しながら、前記DC12による2回の通過を、所望のTMAを達成するのに必要とした。サンプルを、XEROX Fusing Fixtureにより溶融した。前記溶融実験に関する一部のデータを、表2に提供する。
A.元の帯電
市販の添加剤を、製品に見られる量で利用して、帯電を行った。
全てのバイオトナーサンプルは、前記コントロールのそれに匹敵する帯電を示した。
全てのバイオトナーサンプルは、前記コントロールと比較して、匹敵するRH比を示した。
前記バイオトナーサンプルは、コントロールと同様であった。
Claims (7)
- ロジンジオール、2−エチル−2−ブチル−1,3−プロパンジオールおよびテレフタル酸の反応生成物を含むポリエステルポリマーを含有し、前記ロジンジオールがロジン酸とグリセリンカーボネートとの反応生成物である、持続型トナー粒子。
- シェルを有する、請求項1に記載の持続型トナー粒子。
- 請求項1に記載の持続型トナー粒子を含む現像剤。
- キャリア粒子を有する、請求項3に記載の現像剤。
- 前記ポリエステルポリマーの45質量%から75質量%までの含有量で生物由来の材料を含む、請求項1に記載の持続型トナー粒子。
- 非晶質樹脂、結晶性樹脂、着色剤、ワックスまたはそれらの組合せを更に含む、請求項1に記載の持続型トナー粒子。
- 0.955から0.975の円形度を含む、請求項1に記載の持続型トナー粒子。
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US14/059,807 US9377706B2 (en) | 2013-10-22 | 2013-10-22 | Sustainable toner and optimized process |
US14/059,807 | 2013-10-22 |
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JP2015081349A JP2015081349A (ja) | 2015-04-27 |
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JP7083299B2 (ja) | 2018-10-01 | 2022-06-10 | 株式会社ジャパンエンジンコーポレーション | 可動式給油管およびクロスヘッド式内燃機関 |
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US9323167B2 (en) * | 2013-10-22 | 2016-04-26 | Xerox Corporation | Sustainable polyester resin of defined acid value |
US9771487B2 (en) * | 2014-11-10 | 2017-09-26 | Xerox Corporation | Method of three-dimensional printing |
US9791795B2 (en) | 2015-06-01 | 2017-10-17 | Xerox Corporation | Low fixing temperature sustainable toner |
US9971265B1 (en) * | 2017-02-23 | 2018-05-15 | Xerox Corporation | Toner compositions and processes |
Family Cites Families (12)
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JPH01201675A (ja) * | 1988-02-08 | 1989-08-14 | Nippon Synthetic Chem Ind Co Ltd:The | トナー組成物 |
US8076048B2 (en) * | 2009-03-17 | 2011-12-13 | Xerox Corporation | Toner having polyester resin |
JP5397756B2 (ja) * | 2009-06-30 | 2014-01-22 | 株式会社リコー | 静電荷像現像用トナー |
US20110129774A1 (en) * | 2009-12-02 | 2011-06-02 | Xerox Corporation | Incorporation of an oil component into phase inversion emulsion process |
JP5343021B2 (ja) * | 2010-03-02 | 2013-11-13 | シャープ株式会社 | カプセルトナーの製造方法 |
JP5870596B2 (ja) * | 2010-10-20 | 2016-03-01 | 株式会社リコー | トナー、現像剤及び画像形成方法 |
JP5736210B2 (ja) * | 2011-03-29 | 2015-06-17 | 花王株式会社 | 電子写真用トナーの製造方法 |
US8628902B2 (en) * | 2011-04-15 | 2014-01-14 | Fuji Xerox Co., Ltd. | Polyester resin for toner, toner, developer, toner cartridge, process cartridge, and image forming apparatus |
JP5831077B2 (ja) * | 2011-09-16 | 2015-12-09 | 富士ゼロックス株式会社 | 静電荷像現像トナー用ポリエステル樹脂、静電荷像現像トナー、静電荷像現像剤、トナーカートリッジ、プロセスカートリッジ、画像形成装置、及び、画像形成方法 |
JP2013092694A (ja) * | 2011-10-26 | 2013-05-16 | Sharp Corp | トナーおよびその製造方法 |
US8574803B2 (en) * | 2011-12-23 | 2013-11-05 | Xerox Corporation | Toner compositions of biodegradable amorphous polyester resins |
US9328260B2 (en) * | 2014-01-15 | 2016-05-03 | Xerox Corporation | Polyester processes |
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