JP6262771B2 - 正電解液においてV+4/V+5レドックス対及び補助Ce+3/Ce+4レドックス対を使用した全バナジウムレドックスフロー電池システム - Google Patents
正電解液においてV+4/V+5レドックス対及び補助Ce+3/Ce+4レドックス対を使用した全バナジウムレドックスフロー電池システム Download PDFInfo
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- JP6262771B2 JP6262771B2 JP2015557528A JP2015557528A JP6262771B2 JP 6262771 B2 JP6262771 B2 JP 6262771B2 JP 2015557528 A JP2015557528 A JP 2015557528A JP 2015557528 A JP2015557528 A JP 2015557528A JP 6262771 B2 JP6262771 B2 JP 6262771B2
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
- H01M8/184—Regeneration by electrochemical means
- H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/20—Indirect fuel cells, e.g. fuel cells with redox couple being irreversible
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
- H01M2250/10—Fuel cells in stationary systems, e.g. emergency power source in plant
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02B90/10—Applications of fuel cells in buildings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Fuel Cell (AREA)
- Inert Electrodes (AREA)
Description
2VO2 ++H2O=V2O5+2H+
に従って起こる。
Claims (8)
- レドックスフロー電池エネルギー貯蔵システムのレドックスフロー電気化学セルの正電解液においてV+4/V+5レドックス対及び負電解液においてV+2/V+3レドックス対を使用した当該レドックスフロー電池エネルギー貯蔵システムであって、補助レドックス対が、前記正電解液中に、前記液中で前記主レドックス対のバナジウムが実質的に完全に酸化する場合に電荷電流を支持するのに十分なモル含有率で存在し、平衡モル量の還元可能なレドックス対が、前記負電解液に存在し、前記正電解液がメタンスルホン酸を含み、前記補助レドックス対がCe+3/Ce+4であることを特徴とする、レドックスフロー電池エネルギー貯蔵システム。
- 前記正電解液が硫酸とメタンスルホン酸溶液の混合物であり、前記補助レドックス対が前記正電解液中に少なくとも100ミリモル/リットルの量で存在する、請求項1に記載のレドックスフロー電池エネルギー貯蔵システム。
- 少なくとも前記正電解液が、アンチモン、ホウ砂又はテルルのいずれかを含み、酸素放出過電圧を増加させる、請求項1に記載のレドックスフロー電池エネルギー貯蔵システム。
- 2つの電解液の前記補助レドックス対及び前記平衡モル量の還元可能なレドックス対が、所定の最大制限時間での完全なバナジウム酸化を超えて電荷電流を支持するように適合されており、前記レドックスフロー電気化学セルの前記正極における不慮の酸素放出を防止する、請求項1又は2に記載のレドックスフロー電池エネルギー貯蔵システム。
- 前記負電解液に添加されている前記平衡モル量の還元可能なレドックス対が、V+2/V+3、Cr+2/Cr+3から構成される群に属する、請求項1又は2に記載のレドックスフロー電池エネルギー貯蔵システム。
- 前記正電解液において抗凝固剤、及び/又は流動する前記正電解液を磁界に供するのに適合した磁気的手段をさらに含む、請求項1に記載のレドックスフロー電池エネルギー貯蔵システム。
- 前記正電解液中の前記抗凝固剤が、前記酸電解液に可溶な電子供与体のルイス塩基化合物である、請求項6に記載のレドックスフロー電池エネルギー貯蔵システム。
- 前記正電解液中の前記抗凝固剤が、ピリジン、ビピリジン及びベンゼンから構成される群に属する、請求項6に記載のレドックスフロー電池エネルギー貯蔵システム。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/IB2013/051199 WO2014125331A1 (en) | 2013-02-14 | 2013-02-14 | ALL-VANADIUM REDOX FLOW BATTERY SYSTEM EMPLOYING A V+4/V+5 REDOX COUPLE AND AN ANCILLARY Ce+3/Ce+4 REDOX COUPLE IN THE POSITIVE ELECTROLYTE SOLUTION |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2016507152A JP2016507152A (ja) | 2016-03-07 |
JP2016507152A5 JP2016507152A5 (ja) | 2017-06-15 |
JP6262771B2 true JP6262771B2 (ja) | 2018-01-17 |
Family
ID=48044967
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015557528A Expired - Fee Related JP6262771B2 (ja) | 2013-02-14 | 2013-02-14 | 正電解液においてV+4/V+5レドックス対及び補助Ce+3/Ce+4レドックス対を使用した全バナジウムレドックスフロー電池システム |
Country Status (7)
Country | Link |
---|---|
US (1) | US10115993B2 (ja) |
EP (1) | EP2973826B1 (ja) |
JP (1) | JP6262771B2 (ja) |
CN (1) | CN105264704A (ja) |
AU (1) | AU2013378525B2 (ja) |
ES (1) | ES2807354T3 (ja) |
WO (1) | WO2014125331A1 (ja) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104319405B (zh) * | 2014-10-15 | 2016-10-05 | 中国科学院金属研究所 | 全钒液流电池用纳米石墨粉/纳米碳纤维复合电极的制备方法 |
CN104409738A (zh) * | 2014-11-05 | 2015-03-11 | 中国科学院金属研究所 | 全钒液流电池用导电炭黑/纳米碳纤维复合电极制备方法 |
CN104332640B (zh) * | 2014-11-06 | 2017-06-20 | 中国科学院金属研究所 | 全钒液流电池用热还原氧化石墨烯/纳米碳纤维复合电极制备方法 |
KR20170099888A (ko) * | 2014-12-22 | 2017-09-01 | 스미토모덴키고교가부시키가이샤 | 레독스 플로우 전지 |
FR3052924B1 (fr) * | 2016-06-21 | 2019-08-09 | Kemiwatt | Dispositif de protection contre la surcharge electrique pour accumulateur electrochimique |
JP6153100B1 (ja) * | 2016-07-26 | 2017-06-28 | 住友電気工業株式会社 | 電解液流通型電池用電解液、及び電解液流通型電池システム |
US11791488B2 (en) | 2016-07-26 | 2023-10-17 | Sumitomo Electric Industries, Ltd. | Flow battery system |
US10374239B2 (en) | 2016-12-29 | 2019-08-06 | Uchicago Argonne, Llc | Aqueous pyridinium cation-based redox flow batteries |
US10553890B2 (en) | 2017-06-23 | 2020-02-04 | Uchicago Argonne, Llc | Aqueous redox flow batteries |
US10424805B2 (en) | 2017-08-15 | 2019-09-24 | Uchicago Argonne, Llc | Benzothiophene-based redox molecules for flow battery |
CN109768325A (zh) * | 2017-11-09 | 2019-05-17 | 中国科学院大连化学物理研究所 | 一种含添加剂的全钒液流电池正极电解液及其应用 |
CN107804866A (zh) * | 2017-11-27 | 2018-03-16 | 华南师范大学 | 硫酸铈螯合二氧化硫及其制备方法和用途 |
CN108258292A (zh) * | 2018-03-29 | 2018-07-06 | 四川大学 | 一种全钒液流电池正极电解液及其配置方法 |
CN110970645B (zh) * | 2018-09-29 | 2021-11-09 | 中国科学院大连化学物理研究所 | 一种含稳定剂的负极电解液在全钒液流电池中的应用 |
US11271237B2 (en) | 2019-07-29 | 2022-03-08 | Uchicago Argonne, Llc | Organic redox molecules for flow batteries |
FR3102614B1 (fr) * | 2019-10-24 | 2023-05-05 | Arkema France | Composition electrolytique a base d’acide sulfonique comprenant un additif phosphore |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2994210B2 (ja) * | 1994-08-22 | 1999-12-27 | 住友電気工業株式会社 | バナジウム系レドックスフロー型電池の電解液 |
JP2002175831A (ja) | 2000-09-29 | 2002-06-21 | Shinko Kagaku Kogyo Kk | バナジウムレドックスフロー電池用電解液の製造方法 |
US6986966B2 (en) * | 2001-08-10 | 2006-01-17 | Plurion Systems, Inc. | Battery with bifunctional electrolyte |
DE102009009357B4 (de) | 2009-02-18 | 2011-03-03 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Redox-Flow-Batterie zur Speicherung von elektrischer Energie in ionischen Flüssigkeiten |
TW201230482A (en) * | 2010-04-27 | 2012-07-16 | Sumitomo Electric Industries | Redox flow battery |
JP2011233373A (ja) * | 2010-04-27 | 2011-11-17 | Sumitomo Electric Ind Ltd | レドックスフロー電池 |
JP4863172B2 (ja) * | 2010-04-27 | 2012-01-25 | 住友電気工業株式会社 | レドックスフロー電池 |
US20110318644A1 (en) * | 2010-06-29 | 2011-12-29 | Maolin Zhai | Amphoteric ion exchange membranes |
WO2012020277A1 (en) * | 2010-08-13 | 2012-02-16 | Krisada Kampanatsanyakorn | Redox flow battery system employing different charge and discharge cells |
KR101882861B1 (ko) * | 2011-06-28 | 2018-07-27 | 삼성전자주식회사 | 레독스 플로우 전지용 전해액 및 이를 포함하는 레독스 플로우 전지 |
CN102306820A (zh) * | 2011-08-08 | 2012-01-04 | 中南大学 | 一种钒电池用电解液及其制备方法 |
JP5489008B2 (ja) * | 2011-10-20 | 2014-05-14 | 住友電気工業株式会社 | レドックスフロー電池 |
-
2013
- 2013-02-14 AU AU2013378525A patent/AU2013378525B2/en not_active Ceased
- 2013-02-14 EP EP13713539.8A patent/EP2973826B1/en active Active
- 2013-02-14 CN CN201380073095.3A patent/CN105264704A/zh active Pending
- 2013-02-14 ES ES13713539T patent/ES2807354T3/es active Active
- 2013-02-14 WO PCT/IB2013/051199 patent/WO2014125331A1/en active Application Filing
- 2013-02-14 US US14/766,638 patent/US10115993B2/en active Active
- 2013-02-14 JP JP2015557528A patent/JP6262771B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US20150380760A1 (en) | 2015-12-31 |
US10115993B2 (en) | 2018-10-30 |
JP2016507152A (ja) | 2016-03-07 |
EP2973826B1 (en) | 2020-04-22 |
AU2013378525A1 (en) | 2015-08-20 |
EP2973826A1 (en) | 2016-01-20 |
ES2807354T3 (es) | 2021-02-22 |
WO2014125331A1 (en) | 2014-08-21 |
AU2013378525B2 (en) | 2018-08-09 |
CN105264704A (zh) | 2016-01-20 |
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