JP6258020B2 - Solid powder cosmetic - Google Patents
Solid powder cosmetic Download PDFInfo
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- JP6258020B2 JP6258020B2 JP2013242439A JP2013242439A JP6258020B2 JP 6258020 B2 JP6258020 B2 JP 6258020B2 JP 2013242439 A JP2013242439 A JP 2013242439A JP 2013242439 A JP2013242439 A JP 2013242439A JP 6258020 B2 JP6258020 B2 JP 6258020B2
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- 239000000843 powder Substances 0.000 title claims description 86
- 239000002537 cosmetic Substances 0.000 title claims description 41
- 239000007787 solid Substances 0.000 title claims description 34
- 229920001296 polysiloxane Polymers 0.000 claims description 50
- 239000002245 particle Substances 0.000 claims description 13
- 229910052582 BN Inorganic materials 0.000 claims description 12
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 8
- 235000013871 bee wax Nutrition 0.000 claims description 7
- 239000012166 beeswax Substances 0.000 claims description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 26
- 239000003921 oil Substances 0.000 description 20
- 235000019198 oils Nutrition 0.000 description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 18
- 238000011156 evaluation Methods 0.000 description 18
- -1 methyl hydrogen Chemical compound 0.000 description 12
- 239000010445 mica Substances 0.000 description 12
- 229910052618 mica group Inorganic materials 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- 239000000377 silicon dioxide Substances 0.000 description 9
- 239000001993 wax Substances 0.000 description 9
- 239000004677 Nylon Substances 0.000 description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 229920001778 nylon Polymers 0.000 description 8
- 239000010936 titanium Substances 0.000 description 8
- 229910052719 titanium Inorganic materials 0.000 description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 description 6
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 6
- 238000004381 surface treatment Methods 0.000 description 6
- 239000000454 talc Substances 0.000 description 6
- 229910052623 talc Inorganic materials 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000003825 pressing Methods 0.000 description 5
- 238000010298 pulverizing process Methods 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 229940090934 diphenylsiloxy phenyl trimethicone Drugs 0.000 description 3
- 210000004709 eyebrow Anatomy 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910052628 phlogopite Inorganic materials 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241000252100 Conger Species 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000004204 candelilla wax Substances 0.000 description 2
- 235000013868 candelilla wax Nutrition 0.000 description 2
- 229940073532 candelilla wax Drugs 0.000 description 2
- 239000004203 carnauba wax Substances 0.000 description 2
- 235000013869 carnauba wax Nutrition 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- 229940119170 jojoba wax Drugs 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- PHLASVAENYNAOW-UHFFFAOYSA-N methyl-bis[[methyl(diphenyl)silyl]oxy]-phenylsilane Chemical compound C=1C=CC=CC=1[Si](C)(C=1C=CC=CC=1)O[Si](C=1C=CC=CC=1)(C)O[Si](C)(C=1C=CC=CC=1)C1=CC=CC=C1 PHLASVAENYNAOW-UHFFFAOYSA-N 0.000 description 2
- 239000011325 microbead Substances 0.000 description 2
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 description 2
- 239000012860 organic pigment Substances 0.000 description 2
- 239000013500 performance material Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229940057874 phenyl trimethicone Drugs 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 229940117985 trimethyl pentaphenyl trisiloxane Drugs 0.000 description 2
- LINXHFKHZLOLEI-UHFFFAOYSA-N trimethyl-[phenyl-bis(trimethylsilyloxy)silyl]oxysilane Chemical compound C[Si](C)(C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)C1=CC=CC=C1 LINXHFKHZLOLEI-UHFFFAOYSA-N 0.000 description 2
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- WAYINTBTZWQNSN-UHFFFAOYSA-N 11-methyldodecyl 3,5,5-trimethylhexanoate Chemical compound CC(C)CCCCCCCCCCOC(=O)CC(C)CC(C)(C)C WAYINTBTZWQNSN-UHFFFAOYSA-N 0.000 description 1
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 1
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 1
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241001237961 Amanita rubescens Species 0.000 description 1
- 241000972773 Aulopiformes Species 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 235000004035 Cryptotaenia japonica Nutrition 0.000 description 1
- 244000146493 Cryptotaenia japonica Species 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 description 1
- 101100294331 Drosophila melanogaster nod gene Proteins 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 240000002871 Tectona grandis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000012745 brilliant blue FCF Nutrition 0.000 description 1
- 210000001217 buttock Anatomy 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000008406 cosmetic ingredient Substances 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- VPWFPZBFBFHIIL-UHFFFAOYSA-L disodium 4-[(4-methyl-2-sulfophenyl)diazenyl]-3-oxidonaphthalene-2-carboxylate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 VPWFPZBFBFHIIL-UHFFFAOYSA-L 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920003217 poly(methylsilsesquioxane) Polymers 0.000 description 1
- 238000009725 powder blending Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000004170 rice bran wax Substances 0.000 description 1
- 235000019384 rice bran wax Nutrition 0.000 description 1
- 235000019515 salmon Nutrition 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- QPQANCNBWQXGTQ-UHFFFAOYSA-N trihydroxy(trimethylsilylperoxy)silane Chemical compound C[Si](C)(C)OO[Si](O)(O)O QPQANCNBWQXGTQ-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
本願発明は、粉末と油剤を含有した固形粉末化粧料に関するものであり、更に詳しくはとれが良くなめらかな使用感を持ちながら使用時に粉の飛び散りが少なく耐衝撃性に優れ、しかもケーキングを生じない固形粉末化粧料に関するものである。 The present invention relates to a solid powder cosmetic containing a powder and an oil agent, and more specifically, it has excellent smoothness and a good feeling of use, has little powder scattering during use, has excellent impact resistance, and does not cause caking. The present invention relates to a solid powder cosmetic.
固形粉末化粧料は、携帯性、使用時の簡便性に優れるため、白粉、ファンデーション、頬紅、アイカラー等の幅広い化粧料に用いられる化粧料剤型である。固形粉末化粧料は、粉末を主成分とし、これに油剤を分散させ、圧縮成型法等により固形に成型するため、油剤を多量に配合すると、粉末同士の凝集力が強くなり、使用時にチップやブラシ等の化粧用具で表面を擦ったときのとれが悪くなり、表面が固まってしまう現象、いわゆるケーキングを生じる傾向がある。また、肌に塗布したときに化粧料自体がほぐれにくく、ムラのある仕上がりになってしまう。反対に、油剤の配合量を減らした場合には、化粧料の保形成が保てず、十分な耐衝撃性が得られないといった問題点が生じる。 The solid powder cosmetic is a cosmetic dosage form used for a wide variety of cosmetics such as white powder, foundation, blusher, and eye color because it is excellent in portability and convenience during use. Solid powder cosmetics are mainly composed of powder, in which oil is dispersed and molded into a solid by compression molding method, etc., so if a large amount of oil is blended, the cohesive force between the powders becomes stronger, and chips and When the surface is rubbed with a cosmetic tool such as a brush, there is a tendency that the surface becomes harder and the surface is hardened, so-called caking. Further, when applied to the skin, the cosmetics themselves are difficult to loosen, resulting in an uneven finish. On the other hand, when the blending amount of the oil agent is reduced, there is a problem in that the cosmetic cannot be maintained and sufficient impact resistance cannot be obtained.
そこで、粉末状の固形油を用いて、用具へのとれを改善し、十分な耐衝撃性を得るための工夫がなされている（特許文献１〜４）。しかしながら、粉末状の固形油は融点が高く硬質であるため、皮膚への付着力が十分でなかったり、チップやブラシ等の化粧用具で擦った際に粉の飛び散りが多いといった問題点がある。塗布時ののびを良くしたり、使用時のケーキングを抑えるために球状粉末を配合する方法（特許文献５、６）があるが、チップやブラシ等の化粧用具で擦った際に粉の飛び散りが多くなったり、十分な耐衝撃性が得られないといった問題点がある。さらに、優れた耐衝撃性を得るために、特定周波数の振動を付与しながら加圧成型する方法（特許文献７）もあるが、特殊な機械が必要である。 Therefore, a device has been devised to improve the removal of the device by using powdered solid oil and to obtain sufficient impact resistance (Patent Documents 1 to 4). However, since powdered solid oil has a high melting point and is hard, there are problems such as insufficient adhesion to the skin and a lot of powder scattering when rubbed with a cosmetic such as a tip or brush. There is a method of blending spherical powder in order to improve spreading during application and to suppress caking during use (Patent Documents 5 and 6), but powder splattered when rubbed with cosmetic tools such as chips and brushes. There is a problem that it is increased or sufficient impact resistance cannot be obtained. Furthermore, in order to obtain excellent impact resistance, there is a method of pressure molding while applying vibration at a specific frequency (Patent Document 7), but a special machine is required.
このような実状から、とれが良くなめらかな使用感を持ちながら使用時に粉の飛び散りが少なく耐衝撃性に優れ、しかもケーキングを生じない固形粉末化粧料の開発が望まれていた。 From such an actual situation, it has been desired to develop a solid powder cosmetic that has a good and smooth feeling of use, has little powder scattering during use, is excellent in impact resistance, and does not cause caking.
本願発明者は上記実状に鑑みて検討を重ねた結果、固形粉末化粧料において下記（ａ）〜（ｅ）を組合せ、特定量配合することにより、とれが良くなめらかな使用感を持ちながら使用時に粉の飛び散りが少なく耐衝撃性に優れ、しかもケーキングを生じない固形粉末化粧料が得られることを見出した。 As a result of repeated examinations in view of the above circumstances, the inventor of the present application combines the following (a) to (e) in a solid powder cosmetic, and by blending a specific amount, it has a good and smooth feeling during use. It has been found that a solid powder cosmetic is obtained in which powder scattering is small, impact resistance is excellent, and caking does not occur.
すなわち本願発明は、次の成分（ａ）〜（ｅ）；
（ａ）シリコーン処理粉末 ３０質量％以上
（ｂ）窒化ホウ素 １〜２０質量％
（ｃ）球状粉末 １〜２０質量％
（ｄ）２５℃において固形のロウ ０．０５〜５質量％
（ｅ）フェニル変性シリコーン １〜１５質量％
を含有することを特徴とする固形粉末化粧料である。
That is, the present invention provides the following components (a) to (e);
(A) Silicone-treated powder 30% by mass or more (b) Boron nitride 1-20% by mass
(C) Spherical powder 1-20% by mass
(D) 0.05 to 5% by mass of a solid wax at 25 ° C.
(E) Phenyl-modified silicone 1-15% by mass
It is solid powder cosmetics characterized by containing.
本願発明の固形粉末化粧料は、とれが良くなめらかな使用感を持ちながら使用時に粉の飛び散りが少なく耐衝撃性に優れ、しかもケーキングを生じないという特徴を有する。 The solid powder cosmetic of the present invention has the characteristics that it is excellent in impact resistance and does not cause caking, while having good smoothness and a good feeling of use, with little powder scattering during use.
以下本願発明を詳細に説明する。
本願発明に用いられる（ａ）シリコーン処理粉末におけるシリコーン処理は、シリコーンを表面に有することができる処理であれば特に限定されず、化粧品分野で公知の各種方法による処理を適用することができる。例えば、メチルハイドロジェンポリシロキサン、ジメチルポリシロキサン、メチルフェニルポリシロキサン、トリメチルシロキシケイ酸、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン、トリエトキシカプリリルシラン、シリコーン樹脂等による表面処理等が挙げられるが、好ましくはメチルハイドロジェンポリシロキサン、ジメチルポリシロキサン、トリエトキシカプリリルシランによる処理であり、より好ましくはメチルハイドロジェンポリシロキサン、ジメチルポリシロキサンによる処理である。また、異なる処理方法でシリコーン処理した粉末を組み合わせて使用してもよい。
Hereinafter, the present invention will be described in detail.
The silicone treatment in the (a) silicone-treated powder used in the present invention is not particularly limited as long as it can have silicone on the surface, and treatments by various methods known in the cosmetics field can be applied. For example, methyl hydrogen polysiloxane, dimethyl polysiloxane, methylphenyl polysiloxane, trimethylsiloxysilicic acid, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, triethoxycaprylylsilane, silicone resin, etc. Although surface treatment etc. are mentioned, Treatment with methyl hydrogen polysiloxane, dimethyl polysiloxane and triethoxycaprylyl silane is preferred, and treatment with methyl hydrogen polysiloxane and dimethyl polysiloxane is more preferred. Moreover, you may use combining the powder which siliconized by the different processing method.
本願発明に用いられる（ａ）シリコーン処理粉末におけるシリコーンの処理量は特に限定されないが、好ましくは０．５質量％〜１２質量％処理であり、より好ましくは１質量％〜１０質量％処理である。表面処理量が０．５質量％より低いと、表面処理の効果が発揮できないことがあり、１２質量％より多くなるとべたつきがでて使用感が悪くなることがある。 Although the amount of silicone treatment in the (a) silicone-treated powder used in the present invention is not particularly limited, it is preferably 0.5% by mass to 12% by mass, more preferably 1% by mass to 10% by mass. . When the surface treatment amount is lower than 0.5% by mass, the effect of the surface treatment may not be exhibited. When the surface treatment amount exceeds 12% by mass, the stickiness may occur and the usability may be deteriorated.
（ａ）シリコーン処理粉末の基材となる粉末としては特に限定されず、タルク、マイカ、カオリン、セリサイト、シリカ、硫酸バリウム、アルミナ、酸化チタン、酸化亜鉛等の無機粉末、ナイロン、ポリウレタン、ポリエチレン、ポリスチレン、ポリメタクリル酸メチル、シリコーン粉末等の有機粉末、色調を調整するために、酸化鉄、グンジョウ、コンジョウ等の無機顔料、赤色２０２号、赤色２２６号、黄色５号、青色１号等の有機顔料、雲母チタン、酸化鉄被覆雲母、酸化鉄被覆雲母チタン、コンジョウ被覆雲母チタン、酸化チタン被覆合成金雲母、酸化チタン被覆フレーク状ガラス、酸化鉄被覆フレーク状ガラス等のパール剤等の化粧品において汎用される材料を使用することができる。上記（ａ）シリコーン処理粉末としては、上述したもののうち、２種以上を併用して使用するものであってもよい。好ましくはマイカ、タルク、セリサイト、合成金雲母、二酸化チタン、酸化鉄である。 (A) The powder used as the base material of the silicone-treated powder is not particularly limited, and inorganic powders such as talc, mica, kaolin, sericite, silica, barium sulfate, alumina, titanium oxide, and zinc oxide, nylon, polyurethane, and polyethylene , Organic powders such as polystyrene, polymethyl methacrylate, silicone powder, etc., inorganic pigments such as iron oxide, gunjou, conger, etc., red 202, red 226, yellow 5 and blue 1 For cosmetics such as organic pigments, mica titanium, iron oxide-coated mica, iron oxide-coated mica titanium, koji-coated mica titanium, titanium oxide-coated synthetic phlogopite, titanium oxide-coated flaky glass, iron oxide-coated flaky glass, etc. Commonly used materials can be used. As said (a) silicone processing powder, 2 or more types may be used together among the things mentioned above. Mica, talc, sericite, synthetic phlogopite, titanium dioxide and iron oxide are preferred.
本願発明に用いられる（ａ）シリコーン処理粉末の含有量は全成分中３０質量％以上が好ましく、４０質量％以上がより好ましい。３０質量％を下回ると、使用時のなめらかさがおとり、さらに耐衝撃性が悪くなるという点で好ましくない。 The content of the (a) silicone-treated powder used in the present invention is preferably 30% by mass or more, more preferably 40% by mass or more, based on all components. If it is less than 30% by mass, it is not preferable in that the smoothness during use is reduced and the impact resistance is further deteriorated.
本願発明に用いられる（ｂ）窒化ホウ素は、通常の化粧料に用いられるものであれば特に制限されずに使用することができる。窒化ホウ素の形態としては、六方晶、ウルツ鉱型構造、立方晶、菱面体晶、乱層構造などいずれでも良く、使用性の面から六方晶のものが好ましい。
窒化ホウ素は、塗布時のなめらかさ、適度な光沢感の付与の点から、平均粒子径が２〜１５μｍのものが好ましい。例えば、ＳＨＰ−３、ＳＨＰ−４、ＳＨＰ−７（水島合金鉄株式会社製）等が挙げられる。
(B) Boron nitride used in the present invention can be used without particular limitation as long as it is used in ordinary cosmetics. The form of boron nitride may be any of hexagonal crystal, wurtzite structure, cubic crystal, rhombohedral crystal, and disordered layer structure, and hexagonal crystal is preferable from the viewpoint of usability.
Boron nitride preferably has an average particle diameter of 2 to 15 μm from the viewpoint of smoothness during coating and imparting an appropriate glossiness. For example, SHP-3, SHP-4, SHP-7 (manufactured by Mizushima Alloy Iron Co., Ltd.) and the like can be mentioned.
本願発明に用いられる（ｂ）窒化ホウ素の含有量は全成分中１〜２０質量％が好ましく、３〜１５質量％がより好ましい。１質量％を下回ると、塗布時のなめらかさが低下する点で好ましくなく、また、ケーキングを生じることもある。２０質量％を超えると、使用時に粉の飛び散りが多くなり、また耐衝撃性が悪くなるという点で好ましくない。 The content of (b) boron nitride used in the present invention is preferably 1 to 20% by mass and more preferably 3 to 15% by mass in all components. If it is less than 1% by mass, it is not preferable in that the smoothness at the time of application is lowered, and caking may occur. If it exceeds 20% by mass, powder scattering during use increases, and impact resistance deteriorates.
本願発明に用いられる（ｃ）球状粉末は球状であれば特に限定されないが、アクリル系高分子、ナイロン、シリコーン、セルロースまたはこれら共重合体、シリカ等が挙げられるが、好ましくはアクリル系高分子、ナイロンまたはこれら共重合体、シリカである。尚、これらの粉末は、付着性や分散性を改良するために、シリコーン、フッ素化合物、金属石鹸、油剤等を公知の方法により表面処理して用いても良い。 (C) The spherical powder used in the present invention is not particularly limited as long as it is spherical, and examples thereof include acrylic polymers, nylon, silicone, cellulose or copolymers thereof, silica, etc., preferably acrylic polymers, Nylon or a copolymer thereof, silica. These powders may be used after surface treatment with a known method such as silicone, fluorine compound, metal soap, oil agent, etc. in order to improve adhesion and dispersibility.
球状粉末配合により、塗布時ののびが良くなり、化粧用具へのとれが良くなり、ケーキングが生じるのを防ぐことができるが、球状粉末の平均粒子径が１μｍより小さくなると、これらの効果が発揮できず、２０μｍを超えると使用時にざらつき感がでてくる傾向があるため、本願発明に用いられる（ｃ）球状粉末の平均粒子径は１〜２０μｍが好ましい。市販品の例としては、ポリアクリル系樹脂であるＭＢ−８Ｃ（積水化成品工業株式会社製）やマイクロスフェアー Ｍ−１００（松本油脂製薬株式会社製）、ナイロンであるナイロンパウダーＳＰ−５００（東レ株式会社製）、シリコーンであるトレフィルＥ−５０５Ｃ（東レ・ダウコーニング・シリコーン株式会社製）やＫＳＰ−１００（信越化学工業株式会社製）、シリカであるサンスフェア Ｈ−１２２（旭硝子株式会社製）やシリカマイクロビードＰ−１５００（日揮触媒化成工業株式会社製）等が挙げられる。また、これらは必要に応じて１種または２種以上を用いることができる。 Spherical powder blending improves spreading at the time of application, improves removal to cosmetics, and prevents caking, but these effects are exhibited when the average particle size of the spherical powder is smaller than 1 μm. If it exceeds 20 μm, a rough feeling tends to appear during use, and therefore the average particle size of the (c) spherical powder used in the present invention is preferably 1 to 20 μm. Examples of commercially available products include MB-8C (manufactured by Sekisui Plastics Co., Ltd.), microsphere M-100 (manufactured by Matsumoto Yushi Seiyaku Co., Ltd.), and nylon powder SP-500 (manufactured by Matsumoto Yushi Seiyaku Co., Ltd.). Toray Industries, Inc.), Silicone Trefil E-505C (Toray Dow Corning Silicone Co., Ltd.) and KSP-100 (Shin-Etsu Chemical Co., Ltd.), Silica Sunsphere H-122 (Asahi Glass Co., Ltd.) And silica microbead P-1500 (manufactured by JGC Catalysts & Chemicals, Inc.). Moreover, these can use 1 type (s) or 2 or more types as needed.
本願発明に用いられる（ｃ）球状粉末の含有量は全成分中１〜２０質量％が好ましく、３〜１５質量％がより好ましい。１質量％を下回ると、化粧用具へのとれが悪くなり、ケーキングを生じることがあり、２０質量％を超えると、使用時に粉の飛び散りが多くなり、また耐衝撃性が悪くなるという点で好ましくない。 The content of the spherical powder (c) used in the present invention is preferably 1 to 20% by mass and more preferably 3 to 15% by mass in all components. When the amount is less than 1% by mass, the cosmetics may not be easily absorbed, and caking may occur. When the amount exceeds 20% by mass, powder scattering during use increases and the impact resistance is deteriorated. Absent.
本願発明に用いられる（ｄ）２５℃において固体のロウとは、高級脂肪酸と高級アルコールのエステルを主成分とし、個体／液体状態に可逆変化するものであり、通常の化粧料に用いられるものであれば特に制限されずに使用することができる。例えば、カルナウバロウ、キャンデリラロウ、コメヌカロウ、モンタンロウ、ミツロウ等が挙げられるが、チップやブラシへのとれと耐衝撃性の点でミツロウがより好ましい。本願発明において（ｄ）２５℃において固体のロウは、他に使用している液状油に加熱溶解して使用する。 (D) The wax that is solid at 25 ° C. used in the present invention is composed mainly of esters of higher fatty acids and higher alcohols, and reversibly changes to a solid / liquid state, and is used for ordinary cosmetics. If there is no particular limitation, it can be used. For example, carnauba wax, candelilla wax, rice bran wax, montan wax, beeswax and the like can be mentioned, but beeswax is more preferable in terms of chipping and brush removal and impact resistance. In the present invention, (d) the wax that is solid at 25 ° C. is used after being dissolved in the liquid oil that is used by heating.
本願発明に用いられる（ｄ）２５℃において固体のロウの含有量は成分中０．０５〜５質量％が好ましく、０．１〜４質量％がより好ましい。０．０５質量％を下回ると、使用時に粉の飛び散りが多くなり、また耐衝撃性が悪くなるという点で好ましくなく、５質量％を超えると、化粧用具へのとれが悪くなり、ケーキングを生じることがある。 (D) The content of solid wax at 25 ° C. used in the present invention is preferably 0.05 to 5% by mass, more preferably 0.1 to 4% by mass in the component. If it is less than 0.05% by mass, it is not preferable in terms of powder scattering during use and impact resistance is deteriorated, and if it exceeds 5% by mass, it will be difficult to remove into a cosmetic tool and cause caking. Sometimes.
本願発明に用いられる（ｅ）フェニル変性シリコーンとは、フェニル基を有する、２５℃で液状のシリコーン油の総称であり、通常化粧料に使用されるものであればいずれのものも使用することができる。例えば、ジフェニルジメチコン、ジフェニルシロキシフェニルトリメチコン、フェニルトリメチコン、トリメチルペンタフェニルトリシロキサン、ビスフェニルプロピルジメチコンなどの名称で知られているものが挙げられるが、好ましくはジフェニルシロキシフェニルトリメチコン、フェニルトリメチコンである。市販品の例としては、ジフェニルシロキシフェニルトリメチコンであるＫＦ−５６Ａ（信越化学工業株式会社製）、フェニルトリメチコンであるＳＨ５５６（東レ・ダウコーニング・シリコーン株式会社製）、トリメチルペンタフェニルトリシロキサンであるＰＨ−１５５５ ＨＲＩ ＣＯＳＭＥＴＩＣ ＦＬＵＩＤ（東レ・ダウコーニング・シリコーン株式会社製）、ビスフェニルプロピルジメチコンであるＳＦ１５５５（モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社製）等が挙げられる。また、これらは必要に応じて１種または２種以上を用いることができる。 (E) Phenyl-modified silicone used in the present invention is a generic term for a silicone oil having a phenyl group and liquid at 25 ° C. Any one can be used as long as it is usually used in cosmetics. it can. Examples thereof include those known by names such as diphenyldimethicone, diphenylsiloxyphenyltrimethicone, phenyltrimethicone, trimethylpentaphenyltrisiloxane, bisphenylpropyldimethicone, and preferably diphenylsiloxyphenyltrimethicone, phenyltrimethicone. It is. Examples of commercially available products are KF-56A (manufactured by Shin-Etsu Chemical Co., Ltd.), which is diphenylsiloxyphenyl trimethicone, SH556 (manufactured by Toray Dow Corning Silicone Co., Ltd.), and trimethylpentaphenyltrisiloxane. A certain PH-1555 HRI COSMETIC FLUID (made by Toray Dow Corning Silicone Co., Ltd.), SF1555 (made by Momentive Performance Materials Japan LLC) which is bisphenylpropyl dimethicone, etc. are mentioned. Moreover, these can use 1 type (s) or 2 or more types as needed.
本願発明に用いられる（ｅ）フェニル変性シリコーンの含有量は成分中１〜１５質量％が好ましく、２〜１０質量％がより好ましい。１質量％を下回ると、（ａ）シリコーン処理粉末と（ｄ）２５℃において固形のロウおよび他に使用している液状油とのなじみが悪くなり、使用時に粉の飛び散りが多くなり、耐衝撃性が悪くなるという点で好ましくなく、１５質量％を超えると、油剤の含有量が多くなりすぎ、化粧用具への取れが悪くなり、ケーキングを生じることがある。 The content of the (e) phenyl-modified silicone used in the present invention is preferably 1 to 15% by mass and more preferably 2 to 10% by mass in the component. Below 1% by mass, the compatibility of (a) silicone-treated powder with (d) solid wax and other liquid oils used at 25 ° C. deteriorates, resulting in increased powder scattering during use and impact resistance. When it exceeds 15% by mass, the content of the oil agent is excessively increased, and the take-up to the cosmetic device may be deteriorated, resulting in caking.
本願発明において、成分（ａ）シリコーン処理粉末、（ｂ）窒化ホウ素、（ｃ）球状粉末以外に、さらに粉末を含有することにより塗布時の感触を調整できる。ここで用いる粉末としては、タルク、シリカ、硫酸バリウム、アルミナ、酸化チタン、酸化亜鉛等の無機粉末、ナイロン、ポリウレタン、ポリエチレン、ポリスチレン、ポリメタクリル酸メチル、シリコーン粉末等の有機粉末、色調を調整するために、酸化鉄、グンジョウ、コンジョウ等の無機顔料、赤色２０２号、赤色２２６号、黄色５号、青色１号等の有機顔料、雲母チタン、酸化鉄被覆雲母、酸化鉄被覆雲母チタン、コンジョウ被覆雲母チタン、酸化チタン被覆合成金雲母、酸化チタン被覆フレーク状ガラス、酸化鉄被覆フレーク状ガラス等のパール剤等を配合することができる。そしてこれらをシリコーン、フッ素化合物、金属石鹸、油剤等を公知の方法により表面処理して用いても良い。 In the present invention, in addition to component (a) silicone-treated powder, (b) boron nitride, and (c) spherical powder, the feel during application can be adjusted by further containing powder. As the powder used here, inorganic powders such as talc, silica, barium sulfate, alumina, titanium oxide, and zinc oxide, organic powders such as nylon, polyurethane, polyethylene, polystyrene, polymethyl methacrylate, and silicone powder, and color tone are adjusted. For this purpose, inorganic pigments such as iron oxide, gunjo, and conger, organic pigments such as red No. 202, red No. 226, yellow No. 5, and blue No. 1, mica titanium, iron oxide-coated mica, iron oxide-coated mica titanium, and salmon coating Pearl agents such as titanium mica, titanium oxide-coated synthetic phlogopite, titanium oxide-coated flaky glass, and iron oxide-coated flaky glass can be blended. These may be used after surface treatment with a known method such as silicone, fluorine compound, metal soap, and oil agent.
また、本願発明において、成分（ｅ）フェニル変性シリコーン以外に、更に油剤を含有することにより、塗布時の感触を調整できる。ここで用いる油剤としては、通常化粧料に用いられる油剤であれば特に制約なく使用することができ、動物油、植物油、合成油等の起源や、半固形油、液体油、揮発性油等の性状を問わず、炭化水素類、油脂類、エステル油類、脂肪酸類、高級アルコール類、シリコーン油類、フッ素系油類、ラノリン誘導体類、油ゲル化剤等を使用することができる。 Moreover, in this invention, the feel at the time of application | coating can be adjusted by containing an oil agent other than component (e) phenyl modified silicone. The oil agent used here can be used without particular limitation as long as it is an oil agent that is usually used in cosmetics. The origin of animal oil, vegetable oil, synthetic oil, etc., and the properties of semi-solid oil, liquid oil, volatile oil, etc. Regardless of, hydrocarbons, fats and oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine-based oils, lanolin derivatives, oil gelling agents, and the like can be used.
本願発明の固形粉末化粧料には、本願発明の効果を損なわない範囲で必要に応じて、前記成分以外の各種成分、例えば紫外線吸収剤、保湿剤、水性成分、界面活性剤、酸化防止剤、美容成分、防腐剤、水溶性高分子、皮膜形成剤、褪色防止剤、消泡剤、香料等を各種の効果を付与するために適宜配合することができる。 In the solid powder cosmetic of the present invention, various components other than the above components, for example, an ultraviolet absorber, a humectant, an aqueous component, a surfactant, an antioxidant, as necessary, as long as the effects of the present invention are not impaired. Cosmetic ingredients, preservatives, water-soluble polymers, film forming agents, anti-fading agents, antifoaming agents, fragrances, and the like can be appropriately blended to impart various effects.
以下に実施例を挙げて、本願発明を更に詳細に説明する。尚、これらは本願発明を何ら限定するものではない。 The present invention will be described in more detail with reference to the following examples. In addition, these do not limit this invention at all.
（実施例１〜２４および比較例１〜９）アイカラー
表１、表２に示す処方および下記に示す方法により、固形粉末化粧料を製造した。得られた各試料について、官能評価により、チップへの取れ、のびのなめらかさ、粉の飛び散りの無さ、ケーキングの無さ、耐衝撃性を評価した。これらの結果も併せて、表１、表２に記載した。
(Examples 1 to 24 and Comparative Examples 1 to 9) Eye color Solid powder cosmetics were produced by the formulations shown in Tables 1 and 2 and the method shown below. Each sample obtained was evaluated by sensory evaluation for removal on a chip, smoothness of spread, no scattering of powder, no caking, and impact resistance. These results are also shown in Tables 1 and 2.
＊１ ジメチルポリシロキサン３％処理
＊２ ＳＨＰ−３（水島合金鉄株式会社製）
＊３ ナイロンパウダーＳＰ−５００（東レ株式会社製）
＊４ ＭＢ−８Ｃ（積水化成品工業株式会社製）
＊５ サンスフェア Ｈ−１２２（旭硝子株式会社製）
＊６ ＢＥＥＳＷＡＸ Ｓ（クローダジャパン株式会社製）
＊７ ＫＦ−５６Ａ（信越化学工業株式会社製）
* 1 3% dimethylpolysiloxane treatment * 2 SHP-3 (manufactured by Mizushima Alloy Iron Co., Ltd.)
* 3 Nylon powder SP-500 (Toray Industries, Inc.)
* 4 MB-8C (manufactured by Sekisui Plastics Co., Ltd.)
* 5 Sunsphere H-122 (Asahi Glass Co., Ltd.)
* 6 BEESWAX S (manufactured by Croda Japan Co., Ltd.)
* 7 KF-56A (Shin-Etsu Chemical Co., Ltd.)
（製法）
成分（１）〜（１５）をヘンシェル型ミキサーにて均一に混合し、アトマイザーにて粉砕を行った。さらに、成分（１）〜（１５）の混合粉砕物と、予め加熱混合しておいた成分（１６）〜（１８）をヘンシェル型ミキサーに加えて均一に混合し、アトマイザー粉砕後、ふるいを通し、金皿にプレスしてアイカラーを得た。
(Manufacturing method)
Components (1) to (15) were uniformly mixed with a Henschel mixer, and pulverized with an atomizer. Furthermore, the mixed pulverized product of components (1) to (15) and the components (16) to (18) that have been heated and mixed in advance are added to a Henschel mixer and mixed uniformly. After pulverizing the atomizer, the mixture is passed through a sieve. The eye color was obtained by pressing on a metal plate.
＊８ 精製カルナウバワックスＮｏ．１（株式会社セラリカＮＯＤＡ製）
＊９ 精製キャンデリラワックス スーパーリファイン（ミツバ貿易株式会社製）
＊１０ ＮＩＫＫＯＬ ホホバ油 Ｅ（日光ケミカルズ株式会社製）
＊１１ Ｐａｒａｆｆｉｎ Ｗａｘ １５５（日本精蝋株式会社製）
＊１２ Ｌｉｐｗａｘ Ａ−４（日本ナチュラルプロダクツ社製）
＊１３ ＳＨ２００ Ｃ ＦＬＵＩＤ ３０ＣＳ（東レ・ダウコーニング・シリコーン株式会社製）
* 8 Purified carnauba wax no. 1 (manufactured by Celerica NODA)
* 9 Refined Candelilla Wax Super Refine (Mitsuba Trading Co., Ltd.)
* 10 NIKKOL Jojoba Oil E (Nikko Chemicals)
* 11 Paraffin Wax 155 (Nippon Seiwa Co., Ltd.)
* 12 Lipwax A-4 (Nippon Natural Products)
* 13 SH200 C FLUID 30CS (Toray Dow Corning Silicone Co., Ltd.)
（製法）
成分（１）〜（１１）をヘンシェル型ミキサーにて均一に混合し、アトマイザーにて粉砕を行った。さらに、成分（１）〜（１１）の混合粉砕物と、予め加熱混合しておいた成分（１２）〜（２０）をヘンシェル型ミキサーに加えて均一に混合し、アトマイザー粉砕後、ふるいを通し、金皿にプレスしてアイカラーを得た。
(Manufacturing method)
Components (1) to (11) were uniformly mixed with a Henschel mixer, and pulverized with an atomizer. Furthermore, the mixed pulverized product of components (1) to (11) and the components (12) to (20) that have been heated and mixed in advance are added to a Henschel mixer and mixed uniformly. After pulverizing the atomizer, the mixture is passed through a sieve. The eye color was obtained by pressing on a metal plate.
（評価）
官能評価
（１）チップへの取れ、（２）のびのなめらかさ、（３）粉の飛び散りの無さ、（４）ケーキングの無さについて、専門パネル１０名による使用テストを行い、パネル各人が下記絶対評価にて７段階に評価し評点を付け、試料毎にパネル全員の評点合計から、その平均値を算出し、下記４段階判定基準により判定した。
（評価方法）
１０名の官能検査パネルにより、各試料をチップに取り、瞼部に塗布し、下記評価項目について、パネル各人が絶対評価にて７段階に評価し、各試料のパネル全員の評点の平均値から４段階判定基準により判定した。
（評価項目）
（１）チップへの取れ
（２）のびのなめらかさ
（３）粉の飛び散りの無さ
（４）ケーキングの無さ
（絶対評価）
（評点）：（評価）
６：非常に良い
５：良い
４：やや良い
３：普通
２：やや悪い
１：悪い
０：非常に悪い
（判定基準）
（評点平均値） （判定）
５点を超える ：非常に優れる：◎
３点を超えて５点以下：優れる ：○
１点を超えて３点以下：劣る ：△
１点以下 ：非常に劣る ：×
(Evaluation)
Sensory evaluation (1) Take on chip, (2) Smooth smoothness, (3) No powder scattering, (4) No caking The following absolute evaluation was performed to give 7 grades and given a score. The average value was calculated from the total score of all the panel members for each sample, and judged according to the following 4 grade criteria.
(Evaluation method)
Each sample is taken on a chip by 10 sensory test panels, applied to the buttock, and the following evaluation items are evaluated by each panel in 7 levels by absolute evaluation. The average value of the scores of all the panels of each sample From the 4th criteria, it was judged.
(Evaluation item)
(1) Detachment into chips (2) Smoothness of spread (3) No scattering of powder (4) No caking (absolute evaluation)
(Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad (judgment criteria)
(Average score) (Judgment)
Exceeding 5 points: Excellent: ◎
Over 3 points and under 5 points: Excellent: ○
More than 1 point and 3 points or less: Inferior: △
1 point or less: Very inferior: ×
（評価）
耐衝撃性の評価
（５）耐衝撃性について、各試料を下記の方法で試験し、４段階判定基準により判定した。
（試験方法）
試料を金皿のまま、正立方向で高さ５０ｃｍからベニヤ板上に１〜６回落とし、その状態を観察し、以下に示す４段階判定基準により判定した。
（判定基準）
（状態） （判定）
６回落下しても変化なし ：非常に優れる：◎
４回〜６回落下するとヒビ、割れが生じる：優れる ：○
３回落下してヒビ、割れが生じる ：劣る ：△
２回落下してヒビ、割れが生じる ：非常に劣る ：×
(Evaluation)
Evaluation of impact resistance (5) For impact resistance, each sample was tested by the following method and judged according to a four-step criterion.
(Test method)
The sample was dropped on the plywood plate from the height of 50 cm in the erect direction while being a metal pan, and the state was observed and judged according to the following four-step criteria.
(Criteria)
(State) (Judgment)
No change after 6 drops: Excellent: ◎
Cracks and cracks occur when dropped 4 to 6 times: Excellent: ○
Drops three times and causes cracks and cracks: Inferior: △
It falls twice and cracks and cracks occur: Very inferior: ×
表１、２において、（ａ）シリコーン処理粉末 ３０質量％以上、（ｂ）窒化ホウ素 １〜２０質量％、（ｃ）球状粉末 １〜２０質量％、（ｄ）２５℃において固形のロウ ０．０５〜５質量％、（ｅ）フェニル変性シリコーン １〜１５質量％の範囲外の固形粉末化粧料は、チップへの取れ、のびのなめらかさ、粉の飛び散りの無さ、ケーキングの無さ、耐衝撃性を評価するといずれかの評価が良くなかった。 In Tables 1 and 2, (a) 30% by mass or more of silicone-treated powder, (b) 1 to 20% by mass of boron nitride, (c) 1 to 20% by mass of spherical powder, (d) solid wax at 25 ° C. Solid powder cosmetics outside the range of 5 to 5% by mass, (e) phenyl-modified silicone 1 to 15% by mass can be taken on a chip, smooth and smooth, no powder scattering, no caking, When the impact property was evaluated, either evaluation was not good.
表２ではさらに（ｄ）２５℃において固形のロウを液状のロウおよび炭化水素ワックスに置き換えて、同様に試験したが、粉の飛び散りの無さ、耐衝撃性の評価が良くなかった。また、（ｅ）フェニル変性シリコーンを他のシリコーンに置き換えて、同様に試験したが、粉の飛び散りの無さ、耐衝撃性の評価が良くなかった。 Further, in Table 2, (d) a solid wax at 25 ° C. was replaced with a liquid wax and a hydrocarbon wax, and the same test was conducted. However, the evaluation of the absence of powder scattering and the impact resistance was not good. Further, (e) phenyl-modified silicone was replaced with another silicone and tested in the same manner. However, evaluation of the absence of powder scattering and impact resistance was not good.
実施例２５：チークカラー
（成分） 配合量（質量％）
１．シリコーン処理タルク ＊１ ３８．０
２．シリコーン処理セリサイト ＊１ ２３．１
３．シリコーン処理酸化チタン ＊１ ２．０
４．シリコーン処理酸化鉄 ＊１ ２．０
５．窒化ホウ素（平均粒子径６μｍ） ＊２ ５．０
６．ナイロン（平均粒子径５μｍ） ＊３ １０．０
７．シリカ（平均粒子径５μｍ） ＊１４ ２．０
８．赤色２０２号 ０．７
９．グンジョウ ０．３
１０．雲母チタン ４．０
１１．酸化鉄被覆雲母チタン １．０
１２．パラベン ０．２
１３．ミツロウ ＊６ １．５
１４．フェニル変性シリコーン ＊１５ ６．０
１５．スクワラン ４．０
１６．香料 ０．２
＊１４ シリカマイクロビードＰ−１５００（日揮触媒化成工業株式会社製）
＊１５ ＳＨ５５６（東レ・ダウコーニング・シリコーン株式会社製）
（製法）
成分（１）〜（１２）をヘンシェル型ミキサーにて均一に混合し、アトマイザーにて粉砕を行った。さらに、成分（１）〜（１２）の混合粉砕物と、予め加熱混合しておいた成分（１３）〜（１６）をヘンシェル型ミキサーに加えて均一に混合し、アトマイザー粉砕後、ふるいを通し、金皿にプレスしてチークカラーを得た。
Example 25: Teak color (component) Compounding amount (mass%)
1. Silicone-treated talc * 1 38.0
2. Silicone-treated sericite * 1 23.1
3. Silicone-treated titanium oxide * 1 2.0
4). Silicone-treated iron oxide * 1 2.0
5. Boron nitride (average particle size 6μm) * 2 5.0
6). Nylon (average particle size 5μm) * 3 10.0
7). Silica (average particle size 5 μm) * 14 2.0
8). Red No. 202 0.7
9. Gunjo 0.3
10. Mica titanium 4.0
11. Iron oxide coated mica titanium 1.0
12 Paraben 0.2
13. Beeslow * 6 1.5
14 Phenyl-modified silicone * 15 6.0
15. Squalane 4.0
16. Fragrance 0.2
* 14 Silica microbead P-1500 (manufactured by JGC Catalysts & Chemicals, Inc.)
* 15 SH556 (Toray Dow Corning Silicone Co., Ltd.)
(Manufacturing method)
Components (1) to (12) were uniformly mixed with a Henschel mixer, and pulverized with an atomizer. Further, the mixed pulverized product of components (1) to (12) and the components (13) to (16) that have been heated and mixed in advance are added to a Henschel mixer and mixed uniformly. After pulverizing the atomizer, the mixture is passed through a sieve. A cheek color was obtained by pressing on a gold plate.
実施例２５について、実施例１〜２４で使用した評価方法と同様に評価を行った結果、ブラシへの取れ、のびのなめらかさ、粉の飛び散りの無さ、ケーキングの無さ、耐衝撃性に優れたチークカラーを得た。 About Example 25, as a result of evaluating in the same manner as in the evaluation methods used in Examples 1 to 24, it was possible to remove the brush, smoothness of the spread, no powder scattering, no caking, and impact resistance. An excellent cheek color was obtained.
実施例２６：パウダーアイブロウ
（成分） 配合量（質量％）
１．シリコーン処理タルク ＊１ １５．０
２．シリコーン処理セリサイト ＊１ ３８．８
３．シリコーン処理酸化チタン ＊１ ５．０
４．シリコーン処理酸化鉄 ＊１ ２０．０
５．窒化ホウ素（平均粒子径８μｍ） ＊１６ ５．０
６．ナイロン（平均粒子径５μｍ） ＊３ ５．０
７．ポリメチルシルセスキオキサン（平均粒子径７μｍ） ＊１７ ２．０
８．パラベン ０．２
９．ミツロウ ＊６ ０．５
１０．ホホバ油 ＊１０ ０．５
１１．フェニル変性シリコーン ＊７ ４．０
１２．イソノナン酸イソトリデシル ４．０
＊１６ ＳＨＰ−７（水島合金鉄株式会社製）
＊１７ トスパール１４５（モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社製）
（製法）
成分（１）〜（８）をヘンシェル型ミキサーにて均一に混合し、アトマイザーにて粉砕を行った。さらに、成分（１）〜（８）の混合粉砕物と、予め加熱混合しておいた成分（９）〜（１２）をヘンシェル型ミキサーに加えて均一に混合し、アトマイザー粉砕後、ふるいを通し、金皿にプレスしてパウダーアイブロウを得た。
Example 26: Powder eyebrow (component) Compounding amount (mass%)
1. Silicone-treated talc * 1 15.0
2. Silicone-treated sericite * 1 38.8
3. Silicone-treated titanium oxide * 1 5.0
4). Silicone-treated iron oxide * 1 20.0
5. Boron nitride (average particle size 8μm) * 16 5.0
6). Nylon (average particle size 5μm) * 3 5.0
7). Polymethylsilsesquioxane (average particle size 7 μm) * 17 2.0
8). Paraben 0.2
9. Beeswax * 6 0.5
10. Jojoba oil * 10 0.5
11. Phenyl-modified silicone * 7 4.0
12 Isotridecyl isononanoate 4.0
* 16 SHP-7 (made by Mizushima Alloy Iron Co., Ltd.)
* 17 Tospearl 145 (Momentive Performance Materials Japan GK)
(Manufacturing method)
Components (1) to (8) were uniformly mixed with a Henschel mixer, and pulverized with an atomizer. Further, the mixed pulverized product of components (1) to (8) and the components (9) to (12) that have been heated and mixed in advance are added to a Henschel mixer and mixed uniformly. After pulverizing the atomizer, the mixture is passed through a sieve. The powder eyebrow was obtained by pressing on a metal plate.
実施例２６について、実施例１〜２４で使用した評価方法と同様に評価を行った結果、ブラシへの取れ、のびのなめらかさ、粉の飛び散りの無さ、ケーキングの無さ、耐衝撃性に優れたパウダーアイブロウを得た。 About Example 26, as a result of evaluating in the same manner as in the evaluation methods used in Examples 1 to 24, it was possible to remove the brush, smoothness of the spread, no powder scattering, no caking, and impact resistance. An excellent powder eyebrow was obtained.
実施例２７：パウダーアイライナー
（成分） 配合量（質量％）
１．シリコーン処理タルク ＊１８ ５．０
２．シリコーン処理セリサイト ＊１８ １４．３
３．シリコーン処理酸化鉄 ＊１８ ５５．０
４．窒化ホウ素（平均粒子径６μｍ） ＊２ １０．０
５．シリカ（平均粒子径５μｍ） ＊１４ ４．０
６．パラベン ０．２
７．ミツロウ ＊６ ０．５
８．フェニル変性シリコーン ＊７ ４．０
９．（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル
２．０
１０．軽質流動イソパラフィン ５．０
＊１８ ジメチルポリシロキサン３％、メチルハイドロジェンポリシロキサン０．５％処理
（製法）
成分（１）〜（６）をヘンシェル型ミキサーにて均一に混合し、アトマイザーにて粉砕を行った。さらに、成分（１）〜（６）の混合粉砕物と、予め加熱混合しておいた成分（７）〜（１０）をヘンシェル型ミキサーに加えて均一に混合し、アトマイザー粉砕後、ふるいを通し、金皿にプレスしてパウダーアイライナーを得た。
Example 27: Powder eyeliner (component) Compounding amount (mass%)
1. Silicone-treated talc * 18 5.0
2. Silicone-treated sericite * 18 14.3
3. Silicone-treated iron oxide * 18 55.0
4). Boron nitride (average particle size 6 μm) * 2 10.0
5. Silica (average particle size 5 μm) * 14 4.0
6). Paraben 0.2
7). Beeswax * 6 0.5
8). Phenyl-modified silicone * 7 4.0
9. (Hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl
2.0
10. Light liquid isoparaffin 5.0
* 18 Treatment with 3% dimethylpolysiloxane and 0.5% methylhydrogenpolysiloxane (production method)
Components (1) to (6) were mixed uniformly with a Henschel mixer and pulverized with an atomizer. Furthermore, the mixed pulverized product of components (1) to (6) and the components (7) to (10) that have been heated and mixed in advance are added to a Henschel mixer and mixed uniformly. After pulverizing the atomizer, the mixture is passed through a sieve. The powder eyeliner was obtained by pressing into a metal pan.
実施例２７について、実施例１〜２４で使用した評価方法と同様に評価を行った結果チップへの取れ、のびのなめらかさ、粉の飛び散りの無さ、ケーキングの無さ、耐衝撃性に優れたパウダーアイライナーを得た。 About Example 27, as a result of evaluating in the same manner as in the evaluation methods used in Examples 1 to 24, it was possible to take chips, smoothness of spread, no scattering of powder, no caking, and excellent impact resistance A powder eyeliner was obtained.
本願発明は、固形粉末化粧料において特定の成分を組合せ、特定量配合することにより、表面をチップやブラシ等の化粧用具で擦ったときに、とれが良くなめらかな使用感を持ちながら、粉の飛び散りが少なく耐衝撃性に優れ、しかもケーキングを生じない固形粉末化粧料が得られることが出来るものである。 The present invention combines a specific component in a solid powder cosmetic and blends a specific amount so that when the surface is rubbed with a cosmetic such as a chip or a brush, the powder has a smooth and comfortable feeling of use. It is possible to obtain a solid powder cosmetic that is less scattered and excellent in impact resistance and that does not cause caking.
Claims (5)
（ａ）シリコーン処理粉末 ３０質量％以上
（ｂ）窒化ホウ素 １〜２０質量％
（ｃ）球状粉末 １〜２０質量％
（ｄ）固形粉末化粧料に含有されている液状油に加熱溶解して使用するミツロウ ０．０５〜５質量％
（ｅ）フェニル変性シリコーン １〜１５質量％
を含有することを特徴とする固形粉末化粧料。 The following components (a) to (e);
(A) Silicone-treated powder 30% by mass or more (b) Boron nitride 1-20% by mass
(C) Spherical powder 1-20% by mass
(D) Beeswax 0.05-5 mass% used by dissolving in liquid oil contained in solid powder cosmetic
(E) Phenyl-modified silicone 1-15% by mass
A solid powder cosmetic characterized by containing.
（ｂ）窒化ホウ素 ３〜１５質量％
（ｃ）球状粉末 ３〜１５質量％
（ｄ）固形粉末化粧料に含有されている液状油に加熱溶解して使用するミツロウ ０．１〜４質量％
（ｅ）フェニル変性シリコーン ２〜１０質量％
を含有することを特徴とする固形粉末化粧料。 (A) Silicone-treated powder 40% by mass or more (b) Boron nitride 3-15% by mass
(C) Spherical powder 3-15 mass%
(D) 0.1 to 4% by mass of beeswax used by dissolving in a liquid oil contained in the solid powder cosmetic
(E) Phenyl-modified silicone 2 to 10% by mass
A solid powder cosmetic characterized by containing.
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| JP7098383B2 (en) * | 2018-03-30 | 2022-07-11 | 株式会社コーセー | Oil-based solid cosmetics |
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