JP6221103B2 - 共結晶の製造方法 - Google Patents
共結晶の製造方法 Download PDFInfo
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- JP6221103B2 JP6221103B2 JP2015553500A JP2015553500A JP6221103B2 JP 6221103 B2 JP6221103 B2 JP 6221103B2 JP 2015553500 A JP2015553500 A JP 2015553500A JP 2015553500 A JP2015553500 A JP 2015553500A JP 6221103 B2 JP6221103 B2 JP 6221103B2
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- Prior art keywords
- suspension
- thiophanate methyl
- liquid
- stirring
- crystal
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- AFJYYKSVHJGXSN-KAJWKRCWSA-N selamectin Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1C(/C)=C/C[C@@H](O[C@]2(O[C@@H]([C@@H](C)CC2)C2CCCCC2)C2)C[C@@H]2OC(=O)[C@@H]([C@]23O)C=C(C)C(=N\O)/[C@H]3OC\C2=C/C=C/[C@@H]1C AFJYYKSVHJGXSN-KAJWKRCWSA-N 0.000 description 1
- 229960002245 selamectin Drugs 0.000 description 1
- MXMXHPPIGKYTAR-UHFFFAOYSA-N silthiofam Chemical compound CC=1SC([Si](C)(C)C)=C(C(=O)NCC=C)C=1C MXMXHPPIGKYTAR-UHFFFAOYSA-N 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229940125794 sodium channel blocker Drugs 0.000 description 1
- 239000003195 sodium channel blocking agent Substances 0.000 description 1
- IYYIUOWKEMQYNV-UHFFFAOYSA-N sodium;ethoxy-oxido-oxophosphanium Chemical compound [Na+].CCO[P+]([O-])=O IYYIUOWKEMQYNV-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-N sodium;hydron;carbonate Chemical compound [Na+].OC(O)=O UIIMBOGNXHQVGW-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000000371 solid-state nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229940014213 spinosad Drugs 0.000 description 1
- DTDSAWVUFPGDMX-UHFFFAOYSA-N spirodiclofen Chemical compound CCC(C)(C)C(=O)OC1=C(C=2C(=CC(Cl)=CC=2)Cl)C(=O)OC11CCCCC1 DTDSAWVUFPGDMX-UHFFFAOYSA-N 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- CLSVJBIHYWPGQY-GGYDESQDSA-N spirotetramat Chemical compound CCOC(=O)OC1=C(C=2C(=CC=C(C)C=2)C)C(=O)N[C@@]11CC[C@H](OC)CC1 CLSVJBIHYWPGQY-GGYDESQDSA-N 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229960005322 streptomycin Drugs 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- QYPNKSZPJQQLRK-UHFFFAOYSA-N tebufenozide Chemical compound C1=CC(CC)=CC=C1C(=O)NN(C(C)(C)C)C(=O)C1=CC(C)=CC(C)=C1 QYPNKSZPJQQLRK-UHFFFAOYSA-N 0.000 description 1
- ZZYSLNWGKKDOML-UHFFFAOYSA-N tebufenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(=CC=2)C(C)(C)C)=C1Cl ZZYSLNWGKKDOML-UHFFFAOYSA-N 0.000 description 1
- AWYOMXWDGWUJHS-UHFFFAOYSA-N tebupirimfos Chemical compound CCOP(=S)(OC(C)C)OC1=CN=C(C(C)(C)C)N=C1 AWYOMXWDGWUJHS-UHFFFAOYSA-N 0.000 description 1
- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 1
- UOORRWUZONOOLO-UHFFFAOYSA-N telone II Natural products ClCC=CCl UOORRWUZONOOLO-UHFFFAOYSA-N 0.000 description 1
- WWJZWCUNLNYYAU-UHFFFAOYSA-N temephos Chemical compound C1=CC(OP(=S)(OC)OC)=CC=C1SC1=CC=C(OP(=S)(OC)OC)C=C1 WWJZWCUNLNYYAU-UHFFFAOYSA-N 0.000 description 1
- IWVCMVBTMGNXQD-UHFFFAOYSA-N terramycin dehydrate Natural products C1=CC=C2C(O)(C)C3C(O)C4C(N(C)C)C(O)=C(C(N)=O)C(=O)C4(O)C(O)=C3C(=O)C2=C1O IWVCMVBTMGNXQD-UHFFFAOYSA-N 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 229960002180 tetracycline Drugs 0.000 description 1
- 229930101283 tetracycline Natural products 0.000 description 1
- 235000019364 tetracycline Nutrition 0.000 description 1
- 150000003522 tetracyclines Chemical class 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- IOOGPFMMGKCAGU-UHFFFAOYSA-N tetrasulfur Chemical compound S=S=S=S IOOGPFMMGKCAGU-UHFFFAOYSA-N 0.000 description 1
- 239000004308 thiabendazole Substances 0.000 description 1
- 229960004546 thiabendazole Drugs 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- 235000010296 thiabendazole Nutrition 0.000 description 1
- 125000004305 thiazinyl group Chemical group S1NC(=CC=C1)* 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- DNVLJEWNNDHELH-UHFFFAOYSA-N thiocyclam Chemical compound CN(C)C1CSSSC1 DNVLJEWNNDHELH-UHFFFAOYSA-N 0.000 description 1
- BAKXBZPQTXCKRR-UHFFFAOYSA-N thiodicarb Chemical compound CSC(C)=NOC(=O)NSNC(=O)ON=C(C)SC BAKXBZPQTXCKRR-UHFFFAOYSA-N 0.000 description 1
- OPASCBHCTNRLRM-UHFFFAOYSA-N thiometon Chemical compound CCSCCSP(=S)(OC)OC OPASCBHCTNRLRM-UHFFFAOYSA-N 0.000 description 1
- PYNKFIVDSJSNGL-UHFFFAOYSA-N thiosultap Chemical compound OS(=O)(=O)SCC(N(C)C)CSS(O)(=O)=O PYNKFIVDSJSNGL-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- WPALTCMYPARVNV-UHFFFAOYSA-N tolfenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(OC=3C=CC(C)=CC=3)=CC=2)=C1Cl WPALTCMYPARVNV-UHFFFAOYSA-N 0.000 description 1
- RSOBJVBYZCMJOS-CYBMUJFWSA-N tolprocarb Chemical compound FC(F)(F)COC(=O)N[C@@H](C(C)C)CNC(=O)C1=CC=C(C)C=C1 RSOBJVBYZCMJOS-CYBMUJFWSA-N 0.000 description 1
- HYVWIQDYBVKITD-UHFFFAOYSA-N tolylfluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=C(C)C=C1 HYVWIQDYBVKITD-UHFFFAOYSA-N 0.000 description 1
- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
- NKNFWVNSBIXGLL-UHFFFAOYSA-N triazamate Chemical compound CCOC(=O)CSC1=NC(C(C)(C)C)=NN1C(=O)N(C)C NKNFWVNSBIXGLL-UHFFFAOYSA-N 0.000 description 1
- IQGKIPDJXCAMSM-UHFFFAOYSA-N triazoxide Chemical compound N=1C2=CC=C(Cl)C=C2[N+]([O-])=NC=1N1C=CN=C1 IQGKIPDJXCAMSM-UHFFFAOYSA-N 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
- 229960000323 triclabendazole Drugs 0.000 description 1
- QFNFRZHOXWNWAQ-UHFFFAOYSA-N triclopyricarb Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NC(Cl)=C(Cl)C=C1Cl QFNFRZHOXWNWAQ-UHFFFAOYSA-N 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 description 1
- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 description 1
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 1
- RVKCCVTVZORVGD-UHFFFAOYSA-N trinexapac-ethyl Chemical group O=C1CC(C(=O)OCC)CC(=O)C1=C(O)C1CC1 RVKCCVTVZORVGD-UHFFFAOYSA-N 0.000 description 1
- YNWVFADWVLCOPU-MAUPQMMJSA-N uniconazole P Chemical compound C1=NC=NN1/C([C@@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MAUPQMMJSA-N 0.000 description 1
- LESVOLZBIFDZGS-UHFFFAOYSA-N vamidothion Chemical compound CNC(=O)C(C)SCCSP(=O)(OC)OC LESVOLZBIFDZGS-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- BCEHBSKCWLPMDN-MGPLVRAMSA-N voriconazole Chemical compound C1([C@H](C)[C@](O)(CN2N=CN=C2)C=2C(=CC(F)=CC=2)F)=NC=NC=C1F BCEHBSKCWLPMDN-MGPLVRAMSA-N 0.000 description 1
- 229960004740 voriconazole Drugs 0.000 description 1
- WCJYTPVNMWIZCG-UHFFFAOYSA-N xylylcarb Chemical compound CNC(=O)OC1=CC=C(C)C(C)=C1 WCJYTPVNMWIZCG-UHFFFAOYSA-N 0.000 description 1
- 239000005943 zeta-Cypermethrin Substances 0.000 description 1
- FJBGIXKIXPUXBY-UHFFFAOYSA-N {2-[3-(4-chlorophenyl)propyl]-2,4,4-trimethyl-1,3-oxazolidin-3-yl}(imidazol-1-yl)methanone Chemical compound C1=CN=CN1C(=O)N1C(C)(C)COC1(C)CCCC1=CC=C(Cl)C=C1 FJBGIXKIXPUXBY-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C335/00—Thioureas, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C335/04—Derivatives of thiourea
- C07C335/06—Derivatives of thiourea having nitrogen atoms of thiourea groups bound to acyclic carbon atoms
- C07C335/10—Derivatives of thiourea having nitrogen atoms of thiourea groups bound to acyclic carbon atoms of an unsaturated carbon skeleton
- C07C335/12—Derivatives of thiourea having nitrogen atoms of thiourea groups bound to acyclic carbon atoms of an unsaturated carbon skeleton the carbon skeleton containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
本願は、2013年12月19日に、日本に出願された特願2013−262032号に基づき優先権を主張し、その内容をここに援用する。
そこで、本発明の課題は、チオファネートメチルとテブコナゾールなどのトリアゾール系化合物とからなるゾル状態の共結晶を安定的に製造する方法および該共結晶を原材料として用いる農園芸薬組成物の製造方法を提供することである。
混合度0.1〜1.0にて撹拌することを含む
共結晶の製造方法。
〔2〕トリアゾール系化合物がテブコナゾールである〔1〕に記載の製造方法。
〔3〕前記懸濁液は、界面活性剤をさらに含有する〔1〕または〔2〕に記載の製造方法。
〔4〕前記懸濁液は、消泡剤をさらに含有する〔1〕〜〔3〕のいずれかひとつに記載の製造方法。
〔5〕撹拌時の懸濁液温度が0〜100℃である〔1〕〜〔4〕のいずれかひとつに記載の製造方法。
〔7〕前記〔1〕〜〔5〕のいずれかひとつに記載の方法を行って共結晶を含有するゾルを得、
該ゾルに補助成分を加えることを含む、農園芸薬組成物の製造方法。
テブコナゾールは、DMI−殺菌活性成分の一つである。テブコナゾールは式(II)で表わされる化合物である。
懸濁液中のチオファネートメチルとテブコナゾールなどのトリアゾール系化合物の合計含有量は、通常10〜60質量%、好ましくは20〜50質量%である。
懸濁液中の界面活性剤の含有量は、好ましくは0.1〜10質量%、より好ましくは1〜5質量%である。
液採取後、200rpmのアンカー翼による撹拌および5000rpmによるヒスコトロンによる撹拌を同時に15分間行う。撹拌を止め、図1に示す6か所から液を採取する。具体的には容器壁面近傍で円周等分に4か所と、撹拌翼の軸近傍で対角に2か所である。採取は静止液面から深さ約50mmの地点で行う。これら採取した液のチオファネートメチル濃度の標準偏差をσrとした。
(1)有機(チオ)ホスフェート系:アセフェート、アザメチホス、アジンホス・メチル、アジンホス・エチル、ブロモホス・エチル、ブロムフェンビンホス、BRP、クロルピリホス、クロルピリホス・メチル、クロルピリホス・エチル、クロルフェンビンホス、カズサホス、カルボフェノチオン、クロルエトキシホス、クロルメホス、クマホス、シアノフェンホス、シアノホス、CYAP、ジクロルボス、ジクロトホス、ジメトエート、ジスルホトン、ジメトン−S−メチル、ジメチルビンホス、ジメトン−S−メチルスルホン、ジアリホス、ダイアジノン、ジクロフェンチオン、ジオキサベンゾホス、エチオン、エトプロホス、エトリムホス、EPN、フェナミホス、フェニトロチオン、フェンチオン、フェンスルホチオン、フルピラゾホス、ホノホス、ホルモチオン、ホスメチラン、ヘプテノホス、イサゾホス、ヨードフェンホス、イソフェンホス、イソキサチオン、イプロベンホス、マラチオン、メビンホス、メタミドホス、メチダチオン、モノクロトホス、メカルバム、メタクリホス、ナレッド、オメトエート、オキシジメトン・メチル、パラオクソン、パラチオン、パラチオン・メチル、フェントエート、ホサロン、ホスメット、ホスファミドン、ホレート、ホキシム、ピリミホス・メチル、ピリミホス・エチル、プロフェノホス、プロチオホス、ホスチアゼート、ホスホカルブ、プロパホス、プロペタムホス、プロトエート、ピリダフェンチオン、ピラクロホス、キナルホス、サリチオン、スルプロホス、スルホテップ、テトラクロルビンホス、テルブホス、トリアゾホス、トリクロルホン、テブピリムホス、テメホス、チオメトン、バミドチオン;
(a)キチン合成阻害剤:クロルフルアズロン、ジフルベンズロン、フルシクロクスロン、フルフェノクスロン、ヘキサフルムロン、ルフェヌロン、ノバルロン、テフルベンズロン、トリフルムロン、ビストリフルロン、ノビフルムロン、ブプロフェジン、ヘキシチアゾクス、エトキサゾール、クロフェンテジン、フルアズロン、ペンフルロン;
(b)エクジソンアンタゴニスト:ハロフェノジド、メトキシフェノジド、テブフェノジド、クロマフェノジド、アザジラクチン;
(c)幼若ホルモン様物質:ピリプロキシフェン、メトプレン、ジオフェノラン、エポフェノナン、ハイドロプレン、キノプレン、トリプレン;
(d)脂質生合成阻害剤:スピロジクロフェン、スピロメシフェン、スピロテトラマト;
(6)GABAアンタゴニスト化合物:
(a)アセトプロール、エチプロール、フィプロニル、バニリプロール、ピラフルプロール、ピリプロール;
(b)有機塩素系:カンフェクロル、クロルデン、エンドスルファン、HCH、γ−HCH、ヘプタクロル、メトキシクロル;
(8)METI I化合物:フェナザキン、ピリダベン、テブフェンピラド、トルフェンピラド、フルフェネリム、ヒドラメチルノン、フェンピロキシメート、ピリミジフェン、ジコホル;
(9)METI IIおよびIII化合物:アセキノシル、フルアクリピリム、ロテノン;
(11)酸化的リン酸化阻害剤化合物:シヘキサチン、ジアフェンチウロン、フェンブタチン・オキシド、プロパルギット、アゾシクロチン;
(12)脱皮かく乱化合物:シロマジン;
(13)混合機能オキシダーゼ阻害剤化合物:ピペロニルブトキシド;
(14)ナトリウムチャネル遮断剤化合物:インドキサカルブ、メタフルミゾン;
(15)微生物農園芸薬:BT剤、昆虫病原ウイルス剤、昆虫病原糸状菌剤、線虫病原糸状菌剤;バチルス属種、白きょう病菌、黒きょう病菌、ペキロマイセス属種、チューリンギエンシン、バーティシリウム属種;
(17)オクトパミン性作用薬:アミトラズ;
(18)リアノジン誘導体作用薬:フルベンジアミド、クロラントラニリプロール
(19)マグネシウム刺激性ATPアーゼの阻害薬:チオシクラム、チオスルタップ、ネライストキシン;
(20)摂食阻害薬:ピメトロジン;
(21)ダニ成長阻害薬:クロフェンテジン、エトキサゾール;
(a)ベンズイミダゾール系:フェンベンダゾール、アルベンダゾール、トリクラベンダゾール、オキシベンダゾール;
(b)サリチルアニリド系:クロサンテル、オキシクロザニド;
(c)置換フェノール系:ニトロキシニル;
(d)ピリミジン系:ピランテル;
(e)イミダゾチアゾール系:レバミソール;
(f)テトラヒドロピリミジン:プラジカンテル;
(g)その他の駆虫剤:シクロジエン、リアニア、クロルスロン、メトロニダゾール、デミジトラズ。
(1)ベンゾイミダゾール系:ベノミル、カルベンダジム、フベリダゾール、チアベンダゾール、クロルフェナゾール;
(2)ジカルボキシイミド系:クロゾリネート、イプロジオン、プロシミドン、ビンクロゾリン;
(3)DMI−殺菌剤系:イマザリル、オキスポコナゾール、ペフラゾエート、プロクロラズ、トリフルミゾール、トリホリン、ピリフェノックス、フェナリモル、ヌアリモル、アザコナゾール、ビテルタノール、ブロムコナゾール、シプロコナゾール、ジフェノコナゾール、ジニコナゾール、エポキシコナゾール、フェンブコナゾール、フルキンコナゾール、フルシラゾール、フルトリアホル、ヘキサコナゾール、イミベンコナゾール、イプコナゾール、メトコナゾール、ミクロブタニル、ペンコナゾール、プロピコナゾール、プロチオコナゾール、シメコナゾール、テトラコナゾール、トリアジメホン、トリアジメノール、トリチコナゾール、エタコナゾール、ファーコナゾールシス、ジクロブトラゾール、ジニコナゾール−M、ドデモルフ・アセテート、フルコナゾール、イマザリル・サルフェート、ナフチフェン、ユニコナゾールP、ビニコナゾール、ボリコナゾール;
(5)アミン系:アルジモルフ、ドデモルフ、フェンプロピモルフ、トリデモルフ、フェンプロピジン、ピペラリン、スピロキサミン;
(6)ホスホロチオレート系:EDDP、イプロベンホス、ピラゾホス;
(7)ジチオラン系:イソプロチオラン;
(8)カルボキサミド:ベノダニル、ボスカリド、カルボキシン、フェンフラン、フルトラニル、フラメトピル、メプロニル、オキシカルボキシン、ペンチオピラド、チフルザミド、ビキサフェン、イソピラザム、ペンフルフェン、フルキサピロキサド、セダキサン;
(9)ヒドロキシ−(2−アミノ) ピリミジン系:ブピリメート、ジメチリモル、エチリモル;
(11)N−フェニルカーバメート系:ジエトフェンカルブ;
(12)QoI−殺菌剤 (Qo阻害剤)系:アゾキシストロビン、ピコキシストロビン、ピラクロストロビン、クレソキシム−メチル、トリフロキシストロビン、ジモキシストロビン、メトミノストロビン、オリザストロビン、ファモキサドン、フルオキサストロビン、フェンアミドン、メトミノフェン、アメトクトラジン、ピラメトストロビン、ピラオキシストロビン、ピリベンカルブ、クメトキシストロビン、クモキシストロビン、エネストロブリン、フェノキシストロビン、トリクロピリカルブ;
(13)PP殺菌剤 (フェニルピロール)系:フェンピコニル、フルジオキソニル;
(14)キノリン系:キノキシフェン;
(15)AH殺菌剤 (芳香族炭化水素)系:ビフェニル、クロロネブ、ジクロラン、キントゼン、テクナゼン;
(17)MBI−D系:カルプロパミド、ジクロシメット、フェノキサニル;
(18)SBI剤:フェンヘキサミド、ピリブチカルブ、タービナフィン;
(19)フェニルウレア:ペンシクロン;
(20)QiI−殺菌剤 (Qi阻害剤):シアゾファミド、アミスルブロム、フルメシクロックス;
(21)ベンズアミド系:ゾキサミド;
(22)エノピランウロン系:ブラストサイジン、ミルディオマイシン;
(23)へキソピラノシル系:カスガマイシン、カスガマイシン塩酸塩;
(24)グルコピラノシル系:ストレプトマイシン、バリダマイシン、バリダマイシンA;
(25)シアノアセトアミド系:シモキサニル;
(27)脱共役剤:ビナパクリル、ジノカップ、フェリムゾン、フルアジナム、メプチルジノカップ;
(28)有機スズ化合物:酢酸トリフェニルスズ、塩化トリフェニルスズ、水酸化トリフェニルスズ;
(29)リン酸エステル:亜リン酸、トルクロホスメチル、ホセチル、トルクトフォスメチル;
(30)フタルアミド酸系:テクロフタラム;
(31)ベンゾトリアジン系:トリアゾキシド;
(32)ベンゼンスルフォナミド系:フルスルファミド;
(33)ピリダジノン:ジクロメジン;
(34)CAA殺菌剤 (カルボン酸アミド)系:ジメトモルフ、フルモルフ、ベンチアバリカルブ−イソプロピル、イプロバリカルブ、マンジプロパミド、バリフェナレート;
(35)テトラサイクリン:オキシテトラサイクリン;
(36)チオカーバメート系:メタスルホカルブ;
(37)抵抗性誘導剤:アシベンゾラルSメチル、プロベナゾール、チアジニル、イソチアニル;
アブシジン酸、インドール酪酸、ウニコナゾール、エチクロゼート、エテホン、クロキシホナック、クロルメコート、クロレラ抽出液、過酸化カルシウム、シアナミド、ジクロルプロップ、ジベレリン、ダミノジッド、デシルアルコール、トリネキサパックエチル、メピコートクロリド、パクロブトラゾール、パラフィンワックス、ピペロニルブトキシド、ピラフルフェンエチル、フルルプリミドール、プロヒドロジャスモン、プロヘキサジオンカルシウム塩、ベンジルアミノプリン、ペンディメタリン、ホルクロルフェニュロン、マレイン酸ヒドラジドカリウム、1−ナフチルアセトアミド、4−CPA、MCPB、コリン、硫酸オキシキノリン、エチクロゼート、ブトルアリン、1−メチルシクロプロペン、アビグリシン塩酸塩。
回分式混合器における混合度は、次のようにして決定する。キサンタンガム(Kelzan S、シーピー・ケルコ社製)12gと水988g混合して、1.2%キサンタンガム溶液 (粘度 約1500mPa・s)を調製した。1.2%キサンタンガムゲル溶液にチオファネートメチルを40%含有する懸濁剤(トップジンMゾル、日本曹達社製)10gを投入して1分間撹拌した。撹拌を止め、図1に示す6か所から液を採取した。具体的には容器壁面近傍で円周等分に4か所と、撹拌翼の軸近傍で対角に2か所である。採取は静止液面から深さ約50mmの地点で行った。これら採取した液の濃度の標準偏差をσ1minとした。
液採取後、200rpmのアンカー翼による撹拌および5000rpmによるヒスコトロンによる撹拌を同時に15分間行った。撹拌を止め、図1に示す6か所から液を採取した。具体的には容器壁面近傍で円周等分に4か所と、撹拌翼の軸近傍で対角に2か所である。採取は静止液面から深さ約50mmの地点で行った。これら採取した液の濃度の標準偏差をσrとした。混合度M1minを式:σr/σ1minで算出した。
表1に、各種の、撹拌装置、撹拌羽根、容器および回転数における混合度を示す。
100ml容量ビーカー(重量W0)に試料液30gを入れた。風袋込みの重量(W1)を測定した。該ビーカーを45度に傾け120秒間保持し試料液を排出させた。次いで100ml容量ビーカーの重量(W2)を測定した。流動性F(%)を式: (W1−W2) / (W1−W0) × 100で算出した。
W0 =100ml容量ビーカーの重量 (g)
W1 =100ml容量ビーカーと排出前の液の合計重量 (g)
W2 =100ml容量ビーカーとビーカー内に残存した液の合計重量 (g)
昇温前の液の流動性(初期流動性)と昇温後20分間経過時の液の流動性(20分後の流動性)を測定した。20分後の流動性が90%以上であれば、液の取扱い性が良好である。
チオファネートメチル360.0g、テブコナゾール105.0g、PO−EOブロックポリマー(Pluronic PE10500;BASF社製)25.0g、シリコーン系消泡剤(SILFORM SE−39;旭化成ワッカーシリコーン社製)6.0g、及び水311.0gを2L容量SUS製カップ(外寸φ138mm×147mm/アズワン社製)に量り取り、スリーワンモーターを用いて200rpmで撹拌した(固形分濃度57.6%)。撹拌羽根としてアンカーパドル(羽根径110mmφ、シャフト8mm×500mm/新光製作所社製)を使用した。この装置Aの混合度は0.256であった。この液を撹拌しながら、液温度が60℃になるまで昇温した。その後、液温度を60℃に保ったまま約20分間撹拌した。このようにしてチオファネートメチルとテブコナゾールの共結晶を含む液を得た。液の流動性を表2に示す。
表2に示す配合に変えた以外は実施例1と同じ方法にてチオファネートメチルとテブコナゾールの共結晶を含む液を得た。液の流動性を表2に示す。
チオファネートメチル360.0gとテブコナゾール105.0g、PO−EOブロックポリマー(Pluronic PE10500;BASF社製)25.0g、アニオン性界面活性剤(Tamol DN ;BASF社製)10.0g、シリコーン系消泡剤(SILFORM SE−39;旭化成ワッカーシリコーン社製)6.0g、及び水311.0gを2L容量SUS製カップ(外寸φ138mm×147mm/アズワン社製)に量り取り、スリーワンモーターを用いて200rpmで撹拌した(固形分濃度57.6%)。撹拌羽根としてアンカーパドル(羽根径110mmφ、シャフト8mm×500mm/新光製作所社製)を使用した。この装置Aの混合度は0.256であった。この液を撹拌しながら、液温度が60℃になるまで昇温した。その後、液温度を60℃に保ったまま約20分間撹拌した。このようにしてチオファネートメチルとテブコナゾールの共結晶を含む液を得た。液の流動性を表2に示す。
表2に示す配合に変えた以外は実施例6と同じ方法にてチオファネートメチルとテブコナゾールの共結晶を含む液を得た。液の流動性を表2に示す。
装置Aを装置B(混合度0.174)に変えた以外は実施例6と同じ方法にてチオファネートメチルとテブコナゾールの共結晶を含む液を得た。液の流動性を表2に示す。
装置Aを装置C(混合度0.206)に変えた以外は実施例6と同じ方法にてチオファネートメチルとテブコナゾールの共結晶を含む液を得た。液の流動性を表2に示す。
装置Aを装置D(混合度0.009)に変えた以外は実施例1〜5と同じ方法にてチオファネートメチルとテブコナゾールの共結晶を含む液を得た。液の流動性を表3に示す。
装置Aを装置D(混合度0.009)に変えた以外は実施例6と同じ方法にてチオファネートメチルとテブコナゾールの共結晶を含む液を得た。液の流動性を表3に示す。
装置Aを装置E(混合度0.083)に変えた以外は実施例1と同じ方法にてチオファネートメチルとテブコナゾールの共結晶を含む液を得た。液の流動性を表3に示す。
装置Aを装置F(混合度0.012)に変えた以外は実施例1と同じ方法にてチオファネートメチルとテブコナゾールの共結晶を含む液を得た。液の流動性を表3に示す。
装置Aを装置G(混合度0.011)に変えた以外は実施例1と同じ方法にてチオファネートメチルとテブコナゾールの共結晶を含む液を得た。液の流動性を表3に示す。
丸数字:サンプリングする位置
Claims (6)
- チオファネートメチルとトリアゾール系化合物と液媒体とを含有する懸濁液を、
混合度0.1〜1.0にて撹拌することを含み、
前記懸濁液中のチオファネートメチル/トリアゾール系化合物のモル比は、1/1〜3/1であり、
前記懸濁液中のチオファネートメチルとトリアゾール系化合物の合計含有量は、10〜60質量%であり、
前記液媒体は、水、一価アルコールおよびグリコールからなる群より選ばれる少なくとも一種であり、
前記混合度は、チオファネートメチルを40%含有する懸濁液を1.2%キサンタンガムゲル水溶液に投入して得られる懸濁液を、回分式混合器を用いて1分間撹拌した後に採取した液のチオファネートメチル濃度の標準偏差σ1minに対する、チオファネートメチルを40%含有する懸濁液を1.2%キサンタンガムゲル水溶液に投入して得られる懸濁液を、回分式混合器を用いて完全混合状態になるまで撹拌した後に採取した液のチオファネートメチル濃度の標準偏差σrの割合(σr/σ1min)である
共結晶の製造方法。 - トリアゾール系化合物がテブコナゾールである、請求項1に記載の製造方法。
- 前記懸濁液は、界面活性剤をさらに含有する請求項1または2に記載の製造方法。
- 前記懸濁液は、消泡剤をさらに含有する請求項1〜3のいずれか一項に記載の製造方法。
- 撹拌時の懸濁液温度が0〜100℃である請求項1〜4のいずれか一項に記載の製造方法。
- 請求項1〜5のいずれか一項に記載の方法を行って共結晶を含有するゾルを得、
該ゾルに補助成分を加えることを含む、農園芸薬組成物の製造方法。
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TW201526795A (zh) | 2015-07-16 |
CN105828614B (zh) | 2018-04-03 |
KR20180011359A (ko) | 2018-01-31 |
WO2015093367A1 (ja) | 2015-06-25 |
EP3085232A4 (en) | 2017-05-31 |
KR102091951B1 (ko) | 2020-03-20 |
KR20160082698A (ko) | 2016-07-08 |
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