JP6192349B2 - 被覆された金属物品 - Google Patents
被覆された金属物品 Download PDFInfo
- Publication number
- JP6192349B2 JP6192349B2 JP2013093361A JP2013093361A JP6192349B2 JP 6192349 B2 JP6192349 B2 JP 6192349B2 JP 2013093361 A JP2013093361 A JP 2013093361A JP 2013093361 A JP2013093361 A JP 2013093361A JP 6192349 B2 JP6192349 B2 JP 6192349B2
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- JP
- Japan
- Prior art keywords
- metal article
- coated
- article
- coating
- coated metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000002184 metal Substances 0.000 title claims description 80
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- 150000001875 compounds Chemical class 0.000 claims description 41
- 238000000576 coating method Methods 0.000 claims description 33
- 239000011248 coating agent Substances 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 17
- 229910000831 Steel Inorganic materials 0.000 claims description 16
- 239000010959 steel Substances 0.000 claims description 16
- 229920002859 polyalkenylene Polymers 0.000 claims description 11
- 238000009826 distribution Methods 0.000 claims description 5
- 238000000214 vapour pressure osmometry Methods 0.000 claims description 5
- 230000007547 defect Effects 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims 2
- 229920000642 polymer Polymers 0.000 description 37
- -1 for example Chemical class 0.000 description 33
- 230000007797 corrosion Effects 0.000 description 21
- 238000005260 corrosion Methods 0.000 description 21
- 239000010410 layer Substances 0.000 description 19
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- 229920002943 EPDM rubber Polymers 0.000 description 12
- 150000004985 diamines Chemical class 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 11
- 229910052782 aluminium Inorganic materials 0.000 description 9
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 7
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- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 3
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- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 3
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- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- WCASXYBKJHWFMY-NSCUHMNNSA-N 2-Buten-1-ol Chemical compound C\C=C\CO WCASXYBKJHWFMY-NSCUHMNNSA-N 0.000 description 2
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 2
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 229910001335 Galvanized steel Inorganic materials 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
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- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 229920002873 Polyethylenimine Polymers 0.000 description 2
- 101150106148 TOR1 gene Proteins 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
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- 229920000554 ionomer Polymers 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
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- 125000002560 nitrile group Chemical group 0.000 description 2
- 229940055577 oleyl alcohol Drugs 0.000 description 2
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
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- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
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- YDFDTKKXMZRNHR-UHFFFAOYSA-N 1-n,3-n-dimethylcyclohexane-1,3-diamine Chemical compound CNC1CCCC(NC)C1 YDFDTKKXMZRNHR-UHFFFAOYSA-N 0.000 description 1
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- DPQHRXRAZHNGRU-UHFFFAOYSA-N 2,4,4-trimethylhexane-1,6-diamine Chemical compound NCC(C)CC(C)(C)CCN DPQHRXRAZHNGRU-UHFFFAOYSA-N 0.000 description 1
- KKKKCPPTESQGQH-UHFFFAOYSA-N 2-(4,5-dihydro-1,3-oxazol-2-yl)-4,5-dihydro-1,3-oxazole Chemical compound O1CCN=C1C1=NCCO1 KKKKCPPTESQGQH-UHFFFAOYSA-N 0.000 description 1
- QEEZSWGDNCHFKC-UHFFFAOYSA-N 2-(4,5-dihydro-1,3-oxazol-2-ylmethyl)-4,5-dihydro-1,3-oxazole Chemical compound N=1CCOC=1CC1=NCCO1 QEEZSWGDNCHFKC-UHFFFAOYSA-N 0.000 description 1
- KFNAHVKJFHDCSK-UHFFFAOYSA-N 2-[2-(4,5-dihydro-1,3-oxazol-2-yl)ethyl]-4,5-dihydro-1,3-oxazole Chemical compound N=1CCOC=1CCC1=NCCO1 KFNAHVKJFHDCSK-UHFFFAOYSA-N 0.000 description 1
- VOGDKZZTBPDRBD-UHFFFAOYSA-N 2-[2-(4,5-dihydro-1,3-oxazol-2-yl)phenyl]-4,5-dihydro-1,3-oxazole Chemical compound O1CCN=C1C1=CC=CC=C1C1=NCCO1 VOGDKZZTBPDRBD-UHFFFAOYSA-N 0.000 description 1
- HMOZDINWBHMBSQ-UHFFFAOYSA-N 2-[3-(4,5-dihydro-1,3-oxazol-2-yl)phenyl]-4,5-dihydro-1,3-oxazole Chemical compound O1CCN=C1C1=CC=CC(C=2OCCN=2)=C1 HMOZDINWBHMBSQ-UHFFFAOYSA-N 0.000 description 1
- GZQKJQLFIGBEIE-UHFFFAOYSA-N 2-[4-(4,5-dihydro-1,3-oxazol-2-yl)butyl]-4,5-dihydro-1,3-oxazole Chemical compound N=1CCOC=1CCCCC1=NCCO1 GZQKJQLFIGBEIE-UHFFFAOYSA-N 0.000 description 1
- ZDNUPMSZKVCETJ-UHFFFAOYSA-N 2-[4-(4,5-dihydro-1,3-oxazol-2-yl)phenyl]-4,5-dihydro-1,3-oxazole Chemical compound O1CCN=C1C1=CC=C(C=2OCCN=2)C=C1 ZDNUPMSZKVCETJ-UHFFFAOYSA-N 0.000 description 1
- LDXQWLJXDIZULP-UHFFFAOYSA-N 2-[6-(4,5-dihydro-1,3-oxazol-2-yl)hexyl]-4,5-dihydro-1,3-oxazole Chemical compound N=1CCOC=1CCCCCCC1=NCCO1 LDXQWLJXDIZULP-UHFFFAOYSA-N 0.000 description 1
- MPPNPBNSYXFIBF-UHFFFAOYSA-N 2-[8-(4,5-dihydro-1,3-oxazol-2-yl)octyl]-4,5-dihydro-1,3-oxazole Chemical compound N=1CCOC=1CCCCCCCCC1=NCCO1 MPPNPBNSYXFIBF-UHFFFAOYSA-N 0.000 description 1
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
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- NYEZZYQZRQDLEH-UHFFFAOYSA-N 2-ethyl-4,5-dihydro-1,3-oxazole Chemical compound CCC1=NCCO1 NYEZZYQZRQDLEH-UHFFFAOYSA-N 0.000 description 1
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- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- LZOPWNDXPBPDER-UHFFFAOYSA-N 3-(2-aminoethyl)pentane-1,5-diamine Chemical compound NCCC(CCN)CCN LZOPWNDXPBPDER-UHFFFAOYSA-N 0.000 description 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- IGSBHTZEJMPDSZ-UHFFFAOYSA-N 4-[(4-amino-3-methylcyclohexyl)methyl]-2-methylcyclohexan-1-amine Chemical compound C1CC(N)C(C)CC1CC1CC(C)C(N)CC1 IGSBHTZEJMPDSZ-UHFFFAOYSA-N 0.000 description 1
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 description 1
- KWCYSQDVFQGKSA-UHFFFAOYSA-N 4-ethyl-2-phenyl-4,5-dihydro-1,3-oxazole Chemical class CCC1COC(C=2C=CC=CC=2)=N1 KWCYSQDVFQGKSA-UHFFFAOYSA-N 0.000 description 1
- RWMKXFCUXJWKBU-UHFFFAOYSA-N 4-ethyl-4,5-dihydro-1,3-oxazole Chemical compound CCC1COC=N1 RWMKXFCUXJWKBU-UHFFFAOYSA-N 0.000 description 1
- RSCVPGQKACSLBP-UHFFFAOYSA-N 4-methyl-2-[3-(4-methyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl]-4,5-dihydro-1,3-oxazole Chemical compound CC1COC(C=2C=C(C=CC=2)C=2OCC(C)N=2)=N1 RSCVPGQKACSLBP-UHFFFAOYSA-N 0.000 description 1
- FYQUELMPDYVBFY-UHFFFAOYSA-N 4-methyl-2-[4-(4-methyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl]-4,5-dihydro-1,3-oxazole Chemical compound CC1COC(C=2C=CC(=CC=2)C=2OCC(C)N=2)=N1 FYQUELMPDYVBFY-UHFFFAOYSA-N 0.000 description 1
- LDESTFIGYTYDHH-UHFFFAOYSA-N 4-methyl-2-phenyl-4,5-dihydro-1,3-oxazole Chemical compound CC1COC(C=2C=CC=CC=2)=N1 LDESTFIGYTYDHH-UHFFFAOYSA-N 0.000 description 1
- IFIUFEBEPGGBIJ-UHFFFAOYSA-N 4-methyl-4,5-dihydro-1,3-oxazole Chemical compound CC1COC=N1 IFIUFEBEPGGBIJ-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
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- F16L58/109—Coatings characterised by the materials used by rubber or plastics the coating being placed outside the pipe the coating being an extruded layer
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/70—Post-treatment
- C08G2261/76—Post-treatment crosslinking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1355—Elemental metal containing [e.g., substrate, foil, film, coating, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31529—Next to metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31605—Next to free metal
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
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Description
− 金属表面を、以下の成分:
a)ポリマーまたは金属表面への塗布後に反応してポリマーとなる二成分系と、
b)オレフィン性二重結合を含み、蒸気圧浸透圧測定法によって測定して、最高38000g/モルの、好ましくは最高34000g/モルの数平均分子量Mnを有する不飽和化合物と、
を含有する組成物であって、該組成物が70〜2700ミリ当量/kgの、好ましくは140〜1800ミリ当量/kgの、特に好ましくは350〜1350ミリ当量/kgの前記二重結合を含む量で前記不飽和化合物が含まれる組成物で被覆することを特徴とする前記製造方法である。
a)ポリマーまたは金属表面への塗布後に反応してポリマーとなる二成分系と、
b)オレフィン性二重結合を含み、蒸気圧浸透圧測定法によって測定して、最高38000g/モルの、好ましくは最高34000g/モルの数平均分子量Mnを有する不飽和化合物と、
を含有する組成物であって、該組成物が70〜2700ミリ当量/kgの、好ましくは140〜1800ミリ当量/kgの、特に好ましくは350〜1350ミリ当量/kgの前記二重結合を含む量で前記不飽和化合物が含まれる組成物で被覆することによって製造された前記被覆された金属物品である。
25〜46%の第一級アミノ基と、
30〜45%の第二級アミノ基と、
16〜40%の第三級アミノ基と、
を有するものである。
− ポリアルケニレン;
− 不飽和カルボン酸のエステル;
− 不飽和アルコールのエステル;
− モノマー構成単位が少なくとも部分的にジエン由来であるポリマー;
を使用できる。
モノパイル構造は、円筒状の中空の支柱からなる。モノパイルは、沿岸にある多くの欧州の洋上風力発電地帯で使用される。モノパイルは、約20メートルまでの水深の基礎のために適している。モノパイルは、簡単かつ迅速に設置することができるが、建設のために重たい杭打ち装置が必要となる。最近では、ドリルヘッドを用いた穏やかな設置の試みがなされている。
− Fundamente fuer Offshore-Windenergieanlagen, Deutsche Energie-Agentur GmbH, Stand 12/09;
− Florian Biehl, Kollisionssicherheit von Offshore-Windenergieanlagen, Stahlbau, 第78(6)巻, 第402〜409頁 (2009);
− K. Lesny, W. Richwien (編者), Gruendung von Offshore-Windenergieanlagen-Werkzeuge fuer Planung und Bemessung, VGE Verlag Glueckauf 2008, ISBN: 978-3-86797-035-8;
− DE10310708A1
に記載されている。
PA1:VESTAMID(登録商標)L2101、過剰のカルボキシル末端基を有する高粘度のPA12押出成形材料;
PA2:VESTAMID(登録商標)ZA4487、等しい比率のカルボキシル末端基とアミノ末端基を有する調節されていない(ungeregelt)低粘度のPA12;
PA3:VESTAMID(登録商標)ZA7295、過剰のアミノ末端基を有する高粘度のPA12;
PA4:VESTAMID(登録商標)D18、過剰のカルボキシル末端基を有する中粘度のPA612;
PA5:VESTAMID(登録商標)ZA7093、過剰のアミノ末端基を有する中粘度のPA612;
TOR1:VESTENAMER(登録商標)6213、トランス位の二重結合を約60%の割合で有するポリオクテニレン;
TOR2:VESTENAMER(登録商標)8012、トランス位の二重結合を約80%の割合で有するポリオクテニレン。
90質量部のポリアミドPA1〜PA5を、260℃で二軸スクリュー押出機WP ZSK 30, 33D中で10質量部のTOR1と一緒に溶融混合し、25mmのワイヤメッシュを用いた溶融濾過に通し、引き続き押出成形し、水浴中で冷却し、造粒する。
アルミニウム管を、ALCOA法(文献:Walter Brockmann, Stefan Emrich, Kleben und Dichten Jahrgang 44, 9/2000, 第40頁)に従って清浄化し、引き続きチタン塩溶液で濡らし(Granodine 1455、Henkel社、ドイツ)、気流中で乾燥させ、少なくとも240℃の温度に誘導加熱し、そして例1〜7のポリアミド成形材料で被覆した。比較のために、相応して、ポリアミドPA1〜PA5での被覆も実施した(比較例1〜5)。
Claims (6)
- 金属物品の被覆方法であって、金属表面を、ポリアミドを含む組成物で被覆する前記方法において、前記組成物が、
以下の成分:
a)ポリアミドと、
b)オレフィン性二重結合を含み、蒸気圧浸透圧測定法によって測定して、最高38000g/モルの数平均分子量M n を有する不飽和化合物と、
を含有し、
該組成物が70〜2700ミリ当量/kgのオレフィン性二重結合を含む量で前記不飽和化合物が含まれ、
前記不飽和化合物が、ポリアルケニレンであることを特徴とする、前記被覆方法。 - 被覆された金属物品が製造されるか、または金属物品の被覆中の欠陥が修復されることを特徴とする、請求項1に記載の方法。
- 被覆された金属物品であって、金属表面を、ポリアミドを含む組成物で被覆することによって製造された前記金属物品において、前記組成物が、
以下の成分:
a)ポリアミドと、
b)オレフィン性二重結合を含み、蒸気圧浸透圧測定法によって測定して、最高38000g/モルの数平均分子量M n を有する不飽和化合物と、
を含有し、
該組成物が70〜2700ミリ当量/kgのオレフィン性二重結合を含む量で前記不飽和化合物が含まれ、
前記不飽和化合物が、ポリアルケニレンであることを特徴とする、前記被覆された金属物品。 - 請求項3に記載の被覆された金属物品もしくは請求項2に記載の方法により得られた被覆された金属物品であって、前記物品が、自動車の部材または機械の部材であることを特徴とする、前記被覆された金属物品。
- 請求項3に記載の被覆された金属物品もしくは請求項2に記載の方法により得られた被覆された金属物品であって、前記物品が、輸送導管、分配導管、屋内配管または供給導管もしくは排出導管であることを特徴とする、前記被覆された金属物品。
- 請求項3に記載の被覆された金属物品もしくは請求項2に記載の方法により得られた被覆された金属物品であって、前記物品が、洋上建造物のための鋼製建築部材または船舶もしくはボートの構造部材であることを特徴とする、前記被覆された金属物品。
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DE201210207173 DE102012207173A1 (de) | 2012-04-30 | 2012-04-30 | Beschichteter Metallgegenstand |
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US (1) | US9556358B2 (ja) |
EP (1) | EP2660295B1 (ja) |
JP (1) | JP6192349B2 (ja) |
KR (1) | KR101965913B1 (ja) |
CN (1) | CN103372534B (ja) |
AR (1) | AR090894A1 (ja) |
BR (1) | BR102013010707B1 (ja) |
CA (1) | CA2814215A1 (ja) |
CL (1) | CL2013001172A1 (ja) |
DE (1) | DE102012207173A1 (ja) |
ES (1) | ES2921529T3 (ja) |
TW (1) | TW201404479A (ja) |
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DE102013205614A1 (de) | 2013-03-28 | 2014-10-02 | Evonik Industries Ag | Verfahren zur Herstellung eines mit einem Inliner ausgekleideten Rohres |
EP2944895A1 (de) * | 2014-05-13 | 2015-11-18 | ThyssenKrupp Steel Europe AG | Verfahren zur Herstellung eines Absorberbauteils für thermosolare Anwendungen und ein solches Absorberbauteil |
EP3296345B1 (de) | 2014-08-26 | 2021-02-24 | Evonik Operations GmbH | Hydrolysestabile polyamidmischung |
MX2017012808A (es) * | 2015-04-06 | 2018-01-30 | Novelis Inc | Composiciones de revestimiento a base de agua y productos y procesos relacionados. |
EP3477176A1 (de) | 2017-10-25 | 2019-05-01 | Evonik Degussa GmbH | Verfahren zur herstellung eines mit einem inliner ausgekleideten rohres |
US10625487B2 (en) | 2018-08-02 | 2020-04-21 | Martinrea International US Inc. | Tubing for brake and fuel systems incorporating graphene impregnated polyamides |
EP3864073A4 (en) * | 2019-12-19 | 2021-08-18 | Evonik Operations GmbH | MOLD COMPOSITION WITH POLYETHER BLOCKAMIDE |
US11796090B2 (en) | 2020-09-04 | 2023-10-24 | Martinrea International US Inc. | Fluid transport tubing incorporating a graphene impregnated outer coating |
US20230184353A1 (en) | 2021-12-15 | 2023-06-15 | Cooper-Standard Automotive Inc. | Abrasion resistant coated tube |
WO2023158790A1 (en) | 2022-02-17 | 2023-08-24 | Martinrea International US Inc. | Automotive fluid tubing with graphene incorporated paint |
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CH642982A5 (de) | 1979-02-26 | 1984-05-15 | Inventa Ag | Polyaetherpolyamide. |
US4334048A (en) | 1981-05-26 | 1982-06-08 | The United States Of America As Represented By The Secretary Of The Navy | Olefin metathesis |
DE3613527A1 (de) | 1986-04-22 | 1987-10-29 | Huels Chemische Werke Ag | Schlagzaehe polyamid-formmassen |
US4833213A (en) | 1987-06-26 | 1989-05-23 | Minnesota Mining And Manufacturing Company | Method of making purely primary diamines from nitrogen containing nocleophile and terminally electrophilically active polyether |
US5003107A (en) | 1989-12-18 | 1991-03-26 | Texaco Chemical Company | Catalytic method for the reductive amination of poly(oxytetramethyle) glycols |
US5686535A (en) * | 1991-04-29 | 1997-11-11 | Shell Oil Company | Viscous conjugated diene block copolymers |
IT1255234B (it) * | 1992-07-17 | 1995-10-20 | Himont Inc | Procedimento per la riparazione dei rivestimenti in materiali plastici espansi di tubi metallici |
US5520223A (en) | 1994-05-02 | 1996-05-28 | Itt Industries, Inc. | Extruded multiple plastic layer coating bonded to the outer surface of a metal tube having an optical non-reactive inner layer and process for making the same |
DE19908640A1 (de) * | 1999-02-27 | 2000-08-31 | Degussa | Mehrschichtverbund |
DE10010669A1 (de) | 2000-03-04 | 2001-09-06 | Degussa | Verfahren zur Herstellung eines extrusionsbeschichteten Metallgegenstands |
TW587090B (en) * | 2001-07-19 | 2004-05-11 | Ucb Sa | Radiation curable powder coating compositions |
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US20110014443A1 (en) * | 2008-03-10 | 2011-01-20 | The Furukawa Electric Co., Ltd | Adhesive tape for electronic component fabrication |
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-
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- 2012-04-30 DE DE201210207173 patent/DE102012207173A1/de not_active Withdrawn
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- 2013-04-15 ES ES13163753T patent/ES2921529T3/es active Active
- 2013-04-15 EP EP13163753.0A patent/EP2660295B1/de active Active
- 2013-04-26 CN CN201310150078.7A patent/CN103372534B/zh active Active
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- 2013-04-26 TW TW102115032A patent/TW201404479A/zh unknown
- 2013-04-26 CA CA2814215A patent/CA2814215A1/en active Pending
- 2013-04-29 KR KR1020130047221A patent/KR101965913B1/ko active IP Right Grant
- 2013-04-29 CL CL2013001172A patent/CL2013001172A1/es unknown
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Also Published As
Publication number | Publication date |
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KR101965913B1 (ko) | 2019-04-04 |
CN103372534B (zh) | 2017-12-26 |
US20130287981A1 (en) | 2013-10-31 |
ES2921529T3 (es) | 2022-08-29 |
CA2814215A1 (en) | 2013-10-30 |
EP2660295B1 (de) | 2022-06-08 |
EP2660295A1 (de) | 2013-11-06 |
BR102013010707B1 (pt) | 2021-06-08 |
BR102013010707A8 (pt) | 2021-05-25 |
US9556358B2 (en) | 2017-01-31 |
CN103372534A (zh) | 2013-10-30 |
DE102012207173A1 (de) | 2013-10-31 |
CL2013001172A1 (es) | 2014-06-27 |
TW201404479A (zh) | 2014-02-01 |
BR102013010707A2 (pt) | 2015-06-23 |
JP2013230465A (ja) | 2013-11-14 |
AR090894A1 (es) | 2014-12-17 |
KR20130122563A (ko) | 2013-11-07 |
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