JP6183927B2 - セキュリティ文書用の保護コーティング - Google Patents
セキュリティ文書用の保護コーティング Download PDFInfo
- Publication number
- JP6183927B2 JP6183927B2 JP2015538351A JP2015538351A JP6183927B2 JP 6183927 B2 JP6183927 B2 JP 6183927B2 JP 2015538351 A JP2015538351 A JP 2015538351A JP 2015538351 A JP2015538351 A JP 2015538351A JP 6183927 B2 JP6183927 B2 JP 6183927B2
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- JP
- Japan
- Prior art keywords
- radiation
- protective varnish
- radiation curable
- curable
- curable protective
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Y10T428/2481—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including layer of mechanically interengaged strands, strand-portions or strand-like strips
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- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
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- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24934—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including paper layer
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Description
[001]本発明は、使用及び時期に際しての早期の汚れ及び/又は湿気の悪影響からの、セキュリティ文書、特に銀行券の保護の分野に関する。
[002]カラーコピー及び印刷物の品質が絶えず改善されている中、銀行券、重要書類又はカード、交通切符又はカード、タックスバンダロール、及び製品ラベルなどのセキュリティ文書を偽造、改ざん又は違法複製から保護する試みから、従来より様々なセキュリティ手段の取り込みがこれらの文書に実施されてきた。セキュリティ手段の典型的な例として、セキュリティスレッド若しくはストライプ、ウィンドウ、繊維、プランシット、ホイル、デカール、ホログラム、透かし、光学的可変顔料、磁気若しくは磁化可能薄膜干渉顔料、干渉コーティング粒子、サーモクロミック顔料、フォトクロミック顔料、発光化合物、赤外線吸収化合物、紫外線吸収化合物又は磁性化合物を含むセキュリティインキが挙げられる。
Tom Buitelaar,De Nederlandsche Bank NV、Amsterdam,the Netherlands、「Effects of Banknote varnishing」、Currency Conference CSI、Sydney 1999;
Hans A.M.de Heij,De Nederlandsche Bank NV,Amsterdam,the Netherlands、「The design methodology of Dutch banknotes」、IS&T/SPIE’s 12th International Symposium on Electronic Imaging,Optical Security and Counterfeit Deterrence Techniques III,San Jose, Calif., USA(2000年1月27〜28日)、Proceedings of SPIE 3973巻、2〜22頁;
Frank Wettstein、Cash Division、Swiss National Bank、Berne and Hubert Lieb、Environmental Unit、Swiss National Bank、Zurich、「Life cycle assessment(LCA) of Swiss banknotes」、Quarterly Bulletin 3/2000 of the Swiss National Bank、2000年9月;
Tom Buitelaar、De Nederlandsche Bank NV、Amsterdam、the Netherlands、「Circulation Fitness Management」、Banknote 2003 Conference、Washington,D.C.、2003年2月3日;
「Bank of England Tests Durability in Circulation Trials」、Currency News、2012年3月、10巻、3号、5頁。
[015]意外にも、上記の課題は、1種以上のカチオン硬化性化合物及び一般式HO−(CH2CH2O)c−CH2−CF2O−(CF2−CF2−O)a−(CF2O)b−CF2−CH2−(OCH2CH2)d−OH(式中、a及びbは、独立に0〜50の範囲の整数であり、a+b≧1であり、c及びdは、同一でも異なっていてもよく、1〜20の範囲である。)の1種以上のジヒドロキシル末端のペルフルオロポリエーテル化合物を含む放射線硬化性保護用ワニスによって解決できることが判明した。
[020]以下の定義は、本明細書で考察され、特許請求の範囲で列挙される用語の意味を解釈するために使用される。
本発明の好ましい実施形態によれば、1種以上のジヒドロキシル末端のペルフルオロポリエーテル化合物は、上式の化合物(式中、a+b≧2であり、独立に1〜50の間の範囲の整数であり、c及びdは、同一でも異なっていてもよく、1〜20、好ましくは1〜10、より好ましくは1〜6の範囲である。)の群から選択される。これらのジヒドロキシル末端のペルフルオロポリエーテル化合物は、SOLVAY Solexis(イタリア)から商標Fluorolink(登録商標)E10又はE10−Hで市販されている。本発明で使用されるジヒドロキシル末端のペルフルオロポリエーテル化合物は、例えば、米国特許第3847978号、詳細には第11欄、実施例D及び第17欄、実施例11に記載されている、当技術分野で公知の方法によって得ることができる、ペルフルオロポリエーテルジメチルエステル前駆体から調製してもよい。このペルフルオロポリエーテルジメチルエステル前駆体は、例えば、米国特許第3972856号、第4欄に記載の、当技術分野で公知の方法によって、対応するジメチロール前駆体に還元してもよい。こうして得たジメチロール前駆体は、例えば、米国特許第4775653号及び米国特許第5057628号に記載の、当技術分野で公知の方法によって、アルコキシル化してもよい。例えば、参照により明確に組み込まれるこれらの文献に記載されているスキームに従って、本発明に適した化合物を調製することができる。
a)本明細書に記載されるものなどの、好ましくはビニルエーテル、プロペニルエーテル、環状エーテル及びこれらの混合物からなる群から選択される、好ましくは約70〜約90wt%の量(重量パーセントは、放射線硬化性保護用ワニスの全重量を基準とする)の、1種以上のカチオン硬化性化合物、
b)好ましくは約0.1〜約5wt%、より好ましくは約0.5〜約4wt%の量(重量パーセントは、放射線硬化性保護用ワニスの全重量を基準とする)の、本明細書に記載の1種以上のジヒドロキシル末端のペルフルオロポリエーテル化合物、
c)好ましくはオニウム塩、オキソニウム塩、スルホニウム塩、及びこれらの混合物からなる群から選択される、好ましくは約0.1〜約20wt%、より好ましくは約1〜約15wt%の量(重量パーセントは、放射線硬化性保護用ワニスの全重量を基準とする)の、1種以上のカチオン光開始剤、並びに
d)本明細書に記載されるものなどの、任意選択の1種以上の添加剤。
a)好ましくは約70〜約90wt%の量(重量パーセントは、放射線硬化性保護用ワニスの全重量を基準とする)の、本明細書に記載されるものなどの、好ましくはビニルエーテル、プロペニルエーテル、環状エーテル、及びこれらの混合物からなる群から選択される1種以上のカチオン硬化性化合物と、本明細書に記載されるものなどの1種以上のラジカル硬化性化合物との混合物であって、好ましくは1種以上のカチオン硬化性化合物が、約85〜約95wt%の量で存在し、1種以上のラジカル硬化性化合物が、約5〜約15wt%の量で存在する(重量パーセントは、1種以上のカチオン硬化性化合物と1種以上のラジカル硬化性化合物との混合物の全重量を基準とする)、混合物、
b)好ましくは約0.1〜約5wt%、より好ましくは約0.5〜約4wt%の量(重量パーセントは、放射線硬化性保護用ワニスの全重量を基準とする)の、本明細書に記載の1種以上のジヒドロキシル末端のペルフルオロポリエーテル化合物、
c)好ましくは約0.1〜約20wt%、より好ましくは約1〜約15wt%の量(重量パーセントは、放射線硬化性保護用ワニスの全重量を基準とする)の、好ましくはオニウム塩、オキソニウム塩、スルホニウム塩及びこれらの混合物からなる群から選択される1種以上のカチオン光開始剤と、好ましくはアセトフェノン、ベンゾフェノン、アルファ−アミノケトン、アルファ−ヒドロキシケトン、ホスフィンオキシド、ホスフィンオキシド誘導体、ベンジルジメチルケタール及びこれらの混合物からなる群から選択される1種以上のフリーラジカル光開始剤との混合物、並びに
d)本明細書に記載のものなどの、任意選択の1種以上の添加剤。
a)本明細書に記載の放射線硬化性保護用ワニス、好ましくはUV−Vis放射線硬化性保護用ワニスを、本明細書に記載の基材上に適用して、湿式コーティングを形成するステップ、及び
b)放射線硬化性保護用ワニスを放射線硬化、好ましくはUV−Vis硬化して、放射線硬化型コーティングを形成するステップ。
Claims (16)
- 1種以上のカチオン硬化性化合物、及び、
一般式
HO−(CH2CH2O)c−CH2−CF2O−(CF2−CF2−O)a−(CF2O)b−CF2−CH2−(OCH2CH2)d−OH
(式中、a及びbは、独立に0〜50の範囲の整数であり、a+b≧1であり、c及びdは、同一でも異なっていてもよく、1〜20の範囲である。)
で表される1種以上のジヒドロキシル末端のペルフルオロポリエーテル化合物を含む、放射線硬化性保護用ワニス。 - UV−Vis硬化性保護用ワニスである、請求項1に記載の放射線硬化性保護用ワニス。
- 1種以上の前記カチオン硬化性化合物が、ビニルエーテル、プロペニルエーテル、環状エーテル、及びこれらの混合物からなる群から選択される、請求項1又は2に記載の放射線硬化性保護用ワニス。
- オニウム塩、オキソニウム塩、スルホニウム塩、及びこれらの混合物からなる群から選択される1種以上のカチオン光開始剤をさらに含む、請求項1〜3のいずれか一項に記載の放射線硬化性保護用ワニス。
- 1種以上の前記ジヒドロキシル末端のペルフルオロポリエーテル化合物が、0.1〜5.0wt%の量で存在し、該重量パーセントが放射線硬化性保護用ワニスの全重量を基準とする、請求項1〜4のいずれか一項に記載の放射線硬化性保護用ワニス。
- 1種以上の前記ジヒドロキシル末端のペルフルオロポリエーテル化合物が、500〜3000の重量平均分子量(Mw)を有する、請求項1〜5のいずれか一項に記載の放射線硬化性保護用ワニス。
- 1種以上のラジカル硬化性化合物をさらに含む、請求項1〜6のいずれか一項に記載の放射線硬化性保護用ワニス。
- 1種以上の前記カチオン硬化性化合物が、85〜95wt%の量で存在し、1種以上の前記ラジカル硬化性化合物が、5〜15wt%の量で存在し、該重量パーセントが、1種以上のカチオン硬化性化合物と1種以上のラジカル硬化性化合物との混合物の全重量を基準とする、請求項7に記載の放射線硬化性保護用ワニス。
- 1種以上のフリーラジカル光開始剤をさらに含む、請求項7又は8に記載の放射線硬化性保護用ワニス。
- 基材と、請求項1〜9のいずれか一項に記載の放射線硬化性保護用ワニスを放射線硬化することによって得られる放射線硬化型コーティングとを含む、セキュリティ文書。
- 基材が、紙又は他の繊維性材料、紙含有材料、プラスチック及びポリマー、複合材料、並びにこれらの混合物又は組み合わせからなる群から選択される、請求項10に記載のセキュリティ文書。
- 前記放射線硬化性保護用ワニスから作製される放射線硬化型コーティングが、25mN/m以下の表面エネルギー及び18mN/m以下の分散性表面エネルギーを有する、請求項10又は11に記載のセキュリティ文書。
- a)請求項1〜9のいずれか一項に記載の放射線硬化性保護用ワニスを基材に適用して、湿式コーティングを形成するステップと、
b)前記放射線硬化性保護用ワニスを放射線硬化して、放射線硬化型コーティングを形成するステップと、を含む、セキュリティ文書を作製するプロセス。 - 保護コーティング又は層をセキュリティ文書上に形成するための、請求項1〜9のいずれか一項に記載の放射線硬化性保護用ワニスの使用。
- 基材を含むセキュリティ文書に汚れに対する抵抗力を付与する方法であって、
請求項1〜9のいずれか一項に記載の放射線硬化性保護用ワニスを前記基材に適用し、前記放射線硬化性保護用ワニスを放射線硬化するステップを含む方法。 - 請求項1〜9のいずれか一項に記載の放射線硬化性保護用ワニスを製造するための、1種以上の前記ジヒドロキシル末端のペルフルオロポリエーテル化合物の使用。
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Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10696917B2 (en) * | 2014-03-14 | 2020-06-30 | Hrl Laboratories, Llc | Low-friction fluorinated coatings |
US10072160B1 (en) | 2014-08-19 | 2018-09-11 | Hrl Laboratories, Llc | High-durability anti-fouling and anti-icing coatings |
WO2016124579A1 (en) * | 2015-02-06 | 2016-08-11 | Solvay Specialty Polymers Italy S.P.A. | (per)fluoropolyether polymers as antifoam agents |
EP3394229B1 (en) * | 2015-12-22 | 2020-11-18 | HRL Laboratories, LLC | Low-friction fluorinated coatings |
KR20180100277A (ko) * | 2017-01-19 | 2018-09-10 | 선전 구딕스 테크놀로지 컴퍼니, 리미티드 | 지문 인식 장치 |
EP3665232A4 (en) | 2017-08-10 | 2021-04-07 | Sun Chemical Corporation | UV CURABLE COMPOSITIONS CONTAINING ACYLPHOSPHINE OXIDE PHOTOINITIATORS |
WO2019190585A1 (en) | 2018-03-27 | 2019-10-03 | Sun Chemical Corporation | Uv-curable compositions comprising cleavage type photoinitiators |
CN110408300B (zh) * | 2018-04-26 | 2021-06-25 | 中钞特种防伪科技有限公司 | 100%固含量的保护性紫外光固化涂料组合物及其涂层和应用 |
CN109259387B (zh) * | 2018-09-03 | 2021-11-12 | 浙江伟星实业发展股份有限公司 | 一种曲面披覆转印效果的钮扣处理工艺 |
TW202104475A (zh) | 2019-05-22 | 2021-02-01 | 瑞士商西克帕控股有限公司 | 安全文件及其製造方法 |
JP2023522117A (ja) | 2020-04-23 | 2023-05-26 | シクパ ホルディング ソシエテ アノニム | 有価文書を保護するための二色性セキュリティ機構を生成するための方法 |
AR124029A1 (es) | 2020-11-10 | 2023-02-08 | Sicpa Holding Sa | Tintas de seguridad endurecibles por radiación uv-vis para producir elementos de seguridad dicroicos |
CN116507686A (zh) * | 2020-11-10 | 2023-07-28 | 锡克拜控股有限公司 | 用于生产二色性安全特征的uv-vis辐射固化性安全墨 |
AR125598A1 (es) * | 2021-04-01 | 2023-08-02 | Sicpa Holding Sa | Barnices protectores catiónicos curables por radiación uv-led para documentos de seguridad |
EP4091832A1 (en) * | 2021-05-19 | 2022-11-23 | Thales DIS France SA | Data carrier with dual-cure coating |
AR126088A1 (es) * | 2021-06-08 | 2023-09-13 | Sicpa Holding Sa | Barnices protectores híbridos curables por radiación uv-led para documentos de seguridad |
WO2023088805A1 (en) | 2021-11-18 | 2023-05-25 | Sicpa Holding Sa | Methods for producing overt security features exhibiting one or more indicia |
FR3136777A1 (fr) | 2022-06-17 | 2023-12-22 | Oberthur Fiduciaire Sas | Utilisation d'un copolymère époxy-silicone, composition fluide réticulable le contenant et billet de banque revêtu de cette composition |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3847978A (en) | 1968-07-01 | 1974-11-12 | Montedison Spa | Perfluorinated linear polyethers having reactive terminal groups at both ends of the chain and process for the preparation thereof |
US3972856A (en) | 1969-03-10 | 1976-08-03 | Minnesota Mining And Manufacturing Company | Polyurethanes containing poly(perfluoroalkylene oxides) units |
CA1243147A (en) | 1983-02-07 | 1988-10-11 | Union Carbide Corporation | Photocopolymerizable compositions based on epoxy and hydroxyl containing organic materials and substituted cycloaliphatic monoepoxide reactive diluents |
DE3668138D1 (de) | 1986-08-19 | 1990-02-15 | Enschede & Zonen Grafisch | Mit tinte bedruckter und mit einer schutzschicht beschichteter papiergegenstand und dessen herstellungsverfahren. |
US4775653A (en) | 1987-04-28 | 1988-10-04 | Vista Chemical Company | Alkoxylation process using calcium based catalysts |
US5057628A (en) | 1987-12-17 | 1991-10-15 | Shell Oil Company | Alkoxylation process catalyzed by compounds of the rare earth elements |
IT1273609B (it) * | 1995-04-28 | 1997-07-08 | Ausimont Spa | Procedimento per la protezione delle superfici lapidee o di rivestimento |
IT1286027B1 (it) * | 1996-06-10 | 1998-07-07 | Ausimont Spa | Rivestimenti protettivi a base di perfluoropolieteri funzionalizzati |
US6020508A (en) * | 1997-05-16 | 2000-02-01 | National Starch And Chemical Investment Holding Corporation | Radiation- or thermally-initiated cationically-curable epoxide compounds and compositions made from those compounds |
PT927749E (pt) | 1997-12-29 | 2003-06-30 | Sicpa Holding Sa | Composicao de revestimento utilizacao das particulas metodo para etiquetar e identificar um documento de seguranca compreendendo a referida composicaode revestimento |
US6028124A (en) * | 1998-11-25 | 2000-02-22 | Dow Corning Corporation | Radiation curable compositions |
DE19935170A1 (de) | 1999-07-28 | 2001-02-01 | Koenig & Bauer Ag | Verfahren zur Veredelung |
DE10124630A1 (de) | 2001-05-18 | 2002-11-21 | Giesecke & Devrient Gmbh | Wertpapier und Verfahren zu seiner Herstellung |
DE10327083A1 (de) * | 2003-02-11 | 2004-08-19 | Giesecke & Devrient Gmbh | Sicherheitspapier und Verfahren zur Herstellung desselben |
CN100432335C (zh) * | 2003-02-11 | 2008-11-12 | 德国捷德有限公司 | 防伪纸及其生产方法 |
EP1629986A1 (fr) | 2004-08-24 | 2006-03-01 | Kba-Giori S.A. | Procédé d'impression de documents de sécurité ainsi qu'un document de sécurité |
CN101395191B (zh) * | 2006-03-02 | 2011-08-17 | 道康宁公司 | 高能射线固化性组合物 |
WO2008040648A1 (en) | 2006-10-04 | 2008-04-10 | Ciba Holding Inc. | Sulphonium salt photoinitiators |
EP3231938B1 (en) | 2006-10-27 | 2021-08-04 | Crane & Co., Inc. | A soil and/or moisture resistant secure document |
DE602006014287D1 (de) | 2006-12-15 | 2010-06-24 | Kba Giori Sa | Schutzbeschichtung für gedruckte Sicherheiten |
DE102008058397A1 (de) * | 2008-11-21 | 2010-05-27 | Giesecke & Devrient Gmbh | Wertdokument mit matten und glänzenden Oberflächenbereichen und Verfahren zu seiner Herstellung |
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