JP6092977B2 - 架橋エラストマー組成物およびそのような組成物を含む製品 - Google Patents
架橋エラストマー組成物およびそのような組成物を含む製品 Download PDFInfo
- Publication number
- JP6092977B2 JP6092977B2 JP2015200779A JP2015200779A JP6092977B2 JP 6092977 B2 JP6092977 B2 JP 6092977B2 JP 2015200779 A JP2015200779 A JP 2015200779A JP 2015200779 A JP2015200779 A JP 2015200779A JP 6092977 B2 JP6092977 B2 JP 6092977B2
- Authority
- JP
- Japan
- Prior art keywords
- ethylene
- styrene
- alpha
- olefin
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims description 73
- 229920001971 elastomer Polymers 0.000 title claims description 6
- 239000000806 elastomer Substances 0.000 title claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 26
- 239000005977 Ethylene Substances 0.000 claims description 26
- 229920001400 block copolymer Polymers 0.000 claims description 24
- 229920000642 polymer Polymers 0.000 claims description 23
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims description 22
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 22
- 239000004711 α-olefin Substances 0.000 claims description 21
- 125000003118 aryl group Chemical group 0.000 claims description 18
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 claims description 14
- 239000005062 Polybutadiene Substances 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 229920006030 multiblock copolymer Polymers 0.000 claims description 10
- 229920002857 polybutadiene Polymers 0.000 claims description 9
- 229920000428 triblock copolymer Polymers 0.000 claims description 9
- 235000012438 extruded product Nutrition 0.000 claims description 6
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 6
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 4
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 claims description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 2
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 235000018936 Vitellaria paradoxa Nutrition 0.000 claims 1
- 235000010855 food raising agent Nutrition 0.000 claims 1
- 239000000047 product Substances 0.000 description 18
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 13
- 230000005855 radiation Effects 0.000 description 10
- 239000008187 granular material Substances 0.000 description 8
- 229920002633 Kraton (polymer) Polymers 0.000 description 6
- 238000007906 compression Methods 0.000 description 6
- 230000006835 compression Effects 0.000 description 6
- 239000005662 Paraffin oil Substances 0.000 description 5
- 230000032683 aging Effects 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 5
- 230000008961 swelling Effects 0.000 description 5
- UWSMKYBKUPAEJQ-UHFFFAOYSA-N 5-Chloro-2-(3,5-di-tert-butyl-2-hydroxyphenyl)-2H-benzotriazole Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O UWSMKYBKUPAEJQ-UHFFFAOYSA-N 0.000 description 4
- 230000009477 glass transition Effects 0.000 description 4
- 229920001179 medium density polyethylene Polymers 0.000 description 4
- 239000004701 medium-density polyethylene Substances 0.000 description 4
- ORECYURYFJYPKY-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine;2,4,6-trichloro-1,3,5-triazine;2,4,4-trimethylpentan-2-amine Chemical compound CC(C)(C)CC(C)(C)N.ClC1=NC(Cl)=NC(Cl)=N1.C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 ORECYURYFJYPKY-UHFFFAOYSA-N 0.000 description 4
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 description 4
- 229920005629 polypropylene homopolymer Polymers 0.000 description 4
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 3
- 239000004971 Cross linker Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 238000010382 chemical cross-linking Methods 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 238000007580 dry-mixing Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920002943 EPDM rubber Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 2
- -1 treatments Substances 0.000 description 2
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical group C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- MEJAPGGFIJZHEJ-UHFFFAOYSA-N 5-acetamido-1,3,4-thiadiazole-2-sulfonyl chloride Chemical compound CC(=O)NC1=NN=C(S(Cl)(=O)=O)S1 MEJAPGGFIJZHEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004156 Azodicarbonamide Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/246—Intercrosslinking of at least two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16J—PISTONS; CYLINDERS; SEALINGS
- F16J15/00—Sealings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/026—Crosslinking before of after foaming
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/03—Extrusion of the foamable blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2309/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34924—Triazines containing cyanurate groups; Tautomers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Sealing Material Composition (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Description
−例えば、5から50重量%、好ましくは9から25重量%の、エチレンおよびアルファ−オレフィンのポリマー化ユニットを含む、エチレンおよびアルファ−オレフィンのマルチブロックコポリマー、
− 例えば、3から50重量%の、同一でも異なっていてもよく、少なくとも1つの弾力性ブロックで隔離された少なくとも2つの芳香族ブロックを含むエラストマーを有するブロックコポリマー、および
− 架橋性ポリマー、例えば、3から50重量%、好ましくは4から30重量%の、例えば、ジエンエラストマー、
を含む。
Tm > −2002.9 + 4538.5(d)−2422.2(d)2,
好ましくは: Tm > −6288.1 + 13141(d)−6720.3(d)2,
およびより好ましくは: Tm > 858.91 - 1825.3(d)+1112.8(d)2
を満足する。
− 21.8重量%の、エチレンおよびアルファ−オレフィンのマルチブロックコポリマー(DowからのInfuse D9000)、
− 5.9重量%のポリプロピレンホモポリマー、
− 2.9重量%の中密度ポリエチレン、
− 10.6重量%のSBS(30%のスチレンを含有する高分子量、非−油−膨張放射状SBS)、
− 26重量%のパラフィンオイル(高純度白パラフィンオイル)、
− 32.3重量%の5μmチョーク (Durcal 5 (Omya)またはCraie DRB 20 (Imerys Mineraux))、
− 0.35重量%の保護系(Ciba Specialites Chimiques SA (Additifs)のIrganox 1076 FDもしくはChimassorb 944 FDLもしくはTinuvin 327、またはBASFのIrgafos 16)、
− 0.09重量%の過酸化物(α,α'−ビス(t−ブチル−ペルオキシ)−ジイソプロピレンベンゼン)、および
− 0.06重量%の助剤 (coagent)シアヌル酸トリアリル (TAC): LehvossからのTAC DL70
を含む組成物 C1である。
− 60 Shore Aの硬度(標準 ISO 868に準拠して測定)、
− 41%の圧縮ひずみ(標準 ISO 815に準拠して、すなわち、70℃にて22時間測定)、および
− 艶消し外観
を有する。
− 13.6重量%の、エチレンおよびアルファ−オレフィンのマルチブロックコポリマー(DowからのInfuse D9000)、
− 11.3重量%のポリプロピレンホモポリマー(100−GB006 (Ineos)またはPP 571P (Sabic)またはPPH3060 (Total))、
− 4.2重量%の中密度ポリエチレン(LydonDellBasellからのLupolen 3721C)、
− 13.6重量%のSEBS(Kraton PolymerからのKraton G6151 ES)、
− 4.7重量%の1,2−ポリブタジエン(JSR CorporationからのRB830)、
− 37重量%のパラフィンオイル(EssoからのPrimol 352)、
− 14.8重量%の5μmチョーク(Durcal 5 (Omya)またはCraie DRB 20 (Imerys Mineraux))、
− 0.72重量%の保護系(Ciba Specialites Chimiques SA (Additifs)からのIrganox 1076 FDもしくは Chimassorb 944 FDLもしくはTinuvin 327、またはBASFからの Irgafos 16)、
− 0.05重量%の過酸化物(Safic AlcanからのLuperox F40)、および
− 0.03重量%の剤TAC(助剤シアヌル酸トリアリル (TAC): LehvossからのTAC FL70)
を含む。
− 60 Shore Aの硬度(標準 ISO 868に準拠して測定)、
− 36%の圧縮ひずみ(標準 ISO 815に準拠して、すなわち、70℃にて22時間測定)、
− サテン外観、
− 紫外線エージングに対するより長期の耐性
を有する
− 14重量%の、エチレンおよびアルファ−オレフィンのマルチブロックコポリマー(DowからのInfuse D9000)、
− 13重量%のポリプロピレンホモポリマー(100−GB0006 (Ineos)またはPP 571P (Sabic)またはPPH3060 (Total))、
− 3重量%の中密度 ポリエチレン(LyonDellBasellからのLupolen 3721C)、
− 5.9重量%の1,2−ポリブタジエン(JSR CorporationからのRB830)、
− 12.5重量%のSEBS(Kraton PolymerからのKraton G6151 ES)、
− 36重量%のパラフィンオイル(EssoからのPrimol 352)、
− 14.8重量%の5 μmチョーク(Durcal 5 (Omya)またはCraie DRB 20 (Imerys Mineraux))、
− 0.62重量%の保護系(Ciba Specialites Chimiques SA (Additifs)からのIrganox 1076 FDもしくはChimassorb 944 FDLもしくはTinuvin 327、またはBASFからのIrgafos 16)、
− 0.12重量%の過酸化物(Safic AlcanからのLuperox F40)、および
− 0.06重量%の剤TAC(助剤シアヌル酸トリアリル (TAC):LehvossからのTAC DL70)
を含む。
− 65 Shore Aの硬度(標準 ISO 868に準拠して測定)、
− 36%の圧縮ひずみ(標準 ISO 815に準拠して、すなわち、70℃にて22時間測定)、
− サテン外観、
− 紫外線エージングに対するより長期の耐性
を有する。
− 13重量%の、エチレンおよびアルファ−オレフィンのマルチブロックコポリマー(DowからのInfuse D9000)、
− 14.6重量%のポリプロピレンホモポリマー(100−GB006 (Ineos)またはPP 571P (Sabic)またはPPH3060 (Total))、
− 4重量%の中密度ポリエチレン(LydonDellBasellからのLupolen 3721C)、
− 4.7重量%の1,2−ポリブタジエン(JSR CorporationからのRB830)、
− 13重量%のSEBS(Kraton PolymerからのKraton G6151 ES)、
− 35重量%のパラフィンオイル(EssoからのPrimol 352)、
− 14.3重量%の5 μmチョーク(Durcal 5 (Omya)またはCraie DRB 20 (Imerys Mineraux))、
− 1.22重量%の保護系(Ciba Specialites Chimiques SA (Additifs)からのIrganox 1076 FDもしくはChimassorb 944 FDLもしくはTinuvin 327、またはBASFからの Irgafos 16)、
− 0.12重量%の過酸化物(Safic AlcanからのLuperox F40)、および
− 0.06重量%の剤TAC(助剤シアヌル酸トリアリル (TAC): LehvossからのTAC FL70)
を含む。
− 70 Shore Aの硬度(標準 ISO 868に準拠して測定)、
− 40%の圧縮ひずみ(標準 ISO 815に準拠して、すなわち、70℃にて22時間測定)、および
− サテン外観、
− 紫外線エージングに対するより長期の耐性
を有する。
Claims (8)
- − エチレンおよびアルファ−オレフィンのポリマー化ユニットを含むエチレンおよびアルファ−オレフィンのマルチブロックコポリマー、
− 同一でも異なっていてもよく、少なくとも1つの弾力性ブロックで隔離された少なくとも2つの芳香族ブロックを有するブロックコポリマーを含むエラストマー、ここに、ブロックコポリマーは、スチレン−エチレン/ブチレン−スチレン(SEBS)トリブロックコポリマーまたはスチレン−ブタジエン−スチレン(SBS)トリブロックコポリマーであり、 − 架橋性ポリマー、ここに、架橋性ポリマーは、ポリブタジエンまたはスチレン−ブタジエン−スチレン(SBS)トリブロックコポリマーである、および
− 熱可塑性ラバーのオイル
を含む架橋弾力性組成物を含む、押出製品の密閉シールとしての使用。 - 架橋性ポリマーが、シンジオタクティック1,2−ポリ−ブタジエンである、請求項1記載の使用。
- エチレンおよびアルファ−オレフィンのマルチブロックコポリマーが、0.1から0.3の平均ブロックインデックスおよび、1.3を超える分子量分布インデックス、Mw/Mnを有する、請求項1または2に記載の使用。
- エチレンおよびアルファ−オレフィンのマルチブロックコポリマーが、0.91 g/cm3未満の密度を有する、請求項1〜3のいずれか1記載の使用。
- アルファ−オレフィンが、プロピレン、1−ブテン、1−ヘキセン、1−オクテン、4−メチル−1−ペンテン、ノルボルネン、1−デセン、1,5−ヘキサジエン、またはそれらの化合物の組合せを示す、請求項1〜4のいずれか1記載の使用。
- エチレンおよびアルファ−オレフィンのマルチブロックコポリマーは、摂氏で、少なくとも1つの融点 Tm、および1センチメータの3乗あたりグラムで、密度 dを有し、それらの数値は、以下の関係式:
Tm > -2002.9 + 4538.5(d)-2422.2(d) 2
を満足する、請求項1〜5のいずれか1記載の使用。 - 架橋弾力性組成物が、1以上の物理的または化学的膨張剤、または加圧ガスもしくは揮発性液体を含有するマイクロセルラー (microcellular)膨張剤を含む、請求項1〜6のいずれか1記載の使用。
- 製品が膨張している、請求項1〜7のいずれか1記載の使用。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1054860 | 2010-06-18 | ||
FR1054860A FR2961517B1 (fr) | 2010-06-18 | 2010-06-18 | Composition elastomerique reticulee, et produit comprenant une telle composition |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013514741A Division JP2013534552A (ja) | 2010-06-18 | 2011-06-20 | 架橋エラストマー組成物およびそのような組成物を含む製品 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2016029179A JP2016029179A (ja) | 2016-03-03 |
JP6092977B2 true JP6092977B2 (ja) | 2017-03-08 |
Family
ID=43301824
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013514741A Pending JP2013534552A (ja) | 2010-06-18 | 2011-06-20 | 架橋エラストマー組成物およびそのような組成物を含む製品 |
JP2015200779A Active JP6092977B2 (ja) | 2010-06-18 | 2015-10-09 | 架橋エラストマー組成物およびそのような組成物を含む製品 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013514741A Pending JP2013534552A (ja) | 2010-06-18 | 2011-06-20 | 架橋エラストマー組成物およびそのような組成物を含む製品 |
Country Status (12)
Country | Link |
---|---|
US (1) | US20130210945A1 (ja) |
EP (1) | EP2582753B1 (ja) |
JP (2) | JP2013534552A (ja) |
KR (1) | KR20130041908A (ja) |
CN (1) | CN103068911A (ja) |
BR (1) | BR112012032253A2 (ja) |
ES (1) | ES2624281T3 (ja) |
FR (1) | FR2961517B1 (ja) |
MX (1) | MX337680B (ja) |
RU (1) | RU2590555C2 (ja) |
SG (1) | SG186736A1 (ja) |
WO (1) | WO2011157852A1 (ja) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102181768B1 (ko) | 2013-09-13 | 2020-11-25 | 다우 글로벌 테크놀로지스 엘엘씨 | 퍼옥사이드-가교결합성 조성물 및 그의 제조방법 |
TWI659833B (zh) * | 2015-04-01 | 2019-05-21 | 李永騰 | 多層熱塑性彈性體發泡材料及其製造方法 |
CN106147107B (zh) * | 2015-04-01 | 2020-09-04 | 李永腾 | 多层热塑性弹性体发泡材料及其制造方法 |
JP6728646B2 (ja) * | 2015-11-18 | 2020-07-22 | 三菱ケミカルインフラテック株式会社 | パラフィン系組成物及び蓄熱材 |
DE102019110210A1 (de) * | 2019-04-17 | 2020-10-22 | Kraiburg Tpe Gmbh & Co. Kg | Thermoplastische Elastomerzusammensetzung als Verklebesystem für Gummi auf Basis vernetzter Kautschuke |
TWI792752B (zh) * | 2020-12-11 | 2023-02-11 | 南韓商Lg化學股份有限公司 | 包含由用於浸漬成型的乳膠組成物衍生的層之浸漬成型物件 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1230133B (it) * | 1989-04-28 | 1991-10-14 | Himont Inc | Composizioni polipropileniche plasto-elastiche |
US6048942A (en) * | 1996-09-30 | 2000-04-11 | Montell North America Inc. | Thermoplastic olefin articles having high surface gloss and mar resistance |
ES2397701T3 (es) * | 2004-03-17 | 2013-03-08 | Dow Global Technologies Llc | Composición de catalizador que comprende un agente de transporte para la formación de un copolímero de multi-bloques de olefina superior |
US7582716B2 (en) * | 2004-03-17 | 2009-09-01 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for blown films with high hot tack |
US7671106B2 (en) * | 2004-03-17 | 2010-03-02 | Dow Global Technologies Inc. | Cap liners, closures and gaskets from multi-block polymers |
US7714071B2 (en) * | 2004-03-17 | 2010-05-11 | Dow Global Technologies Inc. | Polymer blends from interpolymers of ethylene/α-olefins and flexible molded articles made therefrom |
EP1716190B1 (en) | 2005-03-17 | 2008-12-31 | Dow Global Technologies Inc. | Ethylene/ alpha-olefins block interpolymers |
US7737215B2 (en) * | 2005-03-17 | 2010-06-15 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
WO2006113000A2 (en) * | 2005-03-17 | 2006-10-26 | Dow Global Technologies Inc. | Cap liners, closures and gaskets from multi-block polymers |
RU2007134379A (ru) | 2005-03-17 | 2009-03-20 | Дау Глобал Текнолоджиз Инк. (Us) | КОМПОЗИЦИИ ПОЛИБЛОЧНОГО ИНТЕРПОЛИМЕРА ЭТИЛЕНА/α-ОЛЕФИНА, ПОДХОДЯЩИЕ ДЛЯ ПЛЕНОК |
EP1871816B1 (en) * | 2005-03-17 | 2014-02-26 | Dow Global Technologies LLC | Polymer blends from interpolymers of ethylene/alpha-olefins and flexible molded articles made therefrom |
JP5248630B2 (ja) * | 2008-03-13 | 2013-07-31 | ビーエーエスエフ ソシエタス・ヨーロピア | ポリオレフィン/スチレンポリマー混合物に基づく弾性成形フォームビーズ |
WO2010098932A1 (en) * | 2009-02-25 | 2010-09-02 | Dow Global Technologies Inc. | PHYLON PROCESSES OF MAKING FOAM ARTICLES COMPRISING ETHYLENE/α-OLEFINS BLOCK INTERPOLYMERS |
-
2010
- 2010-06-18 FR FR1054860A patent/FR2961517B1/fr active Active
-
2011
- 2011-06-20 CN CN2011800301427A patent/CN103068911A/zh active Pending
- 2011-06-20 KR KR1020137001354A patent/KR20130041908A/ko not_active Application Discontinuation
- 2011-06-20 SG SG2012092615A patent/SG186736A1/en unknown
- 2011-06-20 MX MX2012014566A patent/MX337680B/es active IP Right Grant
- 2011-06-20 RU RU2013102291/05A patent/RU2590555C2/ru active
- 2011-06-20 EP EP11727431.6A patent/EP2582753B1/fr active Active
- 2011-06-20 ES ES11727431.6T patent/ES2624281T3/es active Active
- 2011-06-20 JP JP2013514741A patent/JP2013534552A/ja active Pending
- 2011-06-20 US US13/805,330 patent/US20130210945A1/en not_active Abandoned
- 2011-06-20 BR BR112012032253A patent/BR112012032253A2/pt not_active IP Right Cessation
- 2011-06-20 WO PCT/EP2011/060250 patent/WO2011157852A1/fr active Application Filing
-
2015
- 2015-10-09 JP JP2015200779A patent/JP6092977B2/ja active Active
Also Published As
Publication number | Publication date |
---|---|
JP2016029179A (ja) | 2016-03-03 |
EP2582753B1 (fr) | 2017-03-22 |
WO2011157852A1 (fr) | 2011-12-22 |
BR112012032253A2 (pt) | 2019-09-24 |
US20130210945A1 (en) | 2013-08-15 |
SG186736A1 (en) | 2013-02-28 |
FR2961517B1 (fr) | 2014-04-11 |
KR20130041908A (ko) | 2013-04-25 |
RU2013102291A (ru) | 2014-07-27 |
MX337680B (es) | 2016-03-15 |
MX2012014566A (es) | 2013-05-28 |
ES2624281T3 (es) | 2017-07-13 |
FR2961517A1 (fr) | 2011-12-23 |
CN103068911A (zh) | 2013-04-24 |
RU2590555C2 (ru) | 2016-07-10 |
JP2013534552A (ja) | 2013-09-05 |
EP2582753A1 (fr) | 2013-04-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6092977B2 (ja) | 架橋エラストマー組成物およびそのような組成物を含む製品 | |
RU2374278C2 (ru) | Термопластичная эластомерная композиция, имеющая высокую прочность расплава, для изготовления формовых эластичных изделий, способ ее получения, премикс, используемый в качестве гомогенной добавки для деформационного упрочнения расплава, для получения композиции, способ получения премикса, формованное гибкое термопластичное эластомерное изделие и способ его получения | |
EP0845498B1 (en) | Process for the preparation of a thermoplastic elastomeric resin composition | |
ATE555166T1 (de) | Elastomere zusammensetzungen | |
US6476129B2 (en) | Thermoplastic elastomer composition with superior oil resistance | |
KR20110067304A (ko) | 우수한 기계적 물성과 탄성을 가진 고기능성 인조 잔디용 충진제 제조방법 | |
JP4625150B2 (ja) | 難燃性熱可塑性エラストマー樹脂組成物およびその製造方法 | |
WO2000006642A2 (en) | Thermoplastic elastomer | |
US7196137B2 (en) | Polymer compositions | |
JP2008226850A (ja) | 難燃性熱可塑性エラストマー樹脂組成物およびその製造方法 | |
KR101437731B1 (ko) | 성형성 및 인장강도가 우수한 열가소성 고무 조성물 | |
JP2006233085A (ja) | 熱可塑性エラストマー組成物 | |
JP4184206B2 (ja) | 熱可塑性エラストマー組成物 | |
JP2007262424A (ja) | 熱可塑性エラストマー樹脂組成物 | |
JP2003183450A (ja) | 熱可塑性エラストマー組成物 | |
CN114144457A (zh) | 热塑性弹性体组合物,以及接合构件及其制造方法 | |
JP2003012887A (ja) | 熱可塑性エラストマー樹脂組成物 | |
JP2010272531A (ja) | 難燃性熱可塑性エラストマー樹脂組成物およびその製造方法 | |
JP2005307054A (ja) | 樹脂組成物及びその製造方法 | |
JP2005047948A (ja) | スチレン系熱可塑性エラストマー組成物 | |
JP2021161128A (ja) | 熱可塑性エラストマー組成物、成形体及びインストルメントパネル用表皮 | |
JP6838439B2 (ja) | 熱可塑性エラストマー組成物 | |
JP3875551B2 (ja) | 熱可塑性エラストマー組成物 | |
JP2005255775A (ja) | 熱可塑性エラストマー組成物 | |
JP2005307048A (ja) | 樹脂組成物及びその製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20160628 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20160923 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20161124 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20161226 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20170131 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20170209 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6092977 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |