JP6053478B2 - Hair composition - Google Patents
Hair composition Download PDFInfo
- Publication number
- JP6053478B2 JP6053478B2 JP2012260702A JP2012260702A JP6053478B2 JP 6053478 B2 JP6053478 B2 JP 6053478B2 JP 2012260702 A JP2012260702 A JP 2012260702A JP 2012260702 A JP2012260702 A JP 2012260702A JP 6053478 B2 JP6053478 B2 JP 6053478B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- component
- mass
- composition
- polyethylene glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 42
- 229920001223 polyethylene glycol Polymers 0.000 claims description 39
- 239000002202 Polyethylene glycol Substances 0.000 claims description 35
- 238000006116 polymerization reaction Methods 0.000 claims description 27
- 239000000839 emulsion Substances 0.000 claims description 16
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 229960004585 etidronic acid Drugs 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 6
- 239000002563 ionic surfactant Substances 0.000 claims 1
- -1 hydroxyethane diphosphonate tetrapotassium Chemical compound 0.000 description 39
- 238000011156 evaluation Methods 0.000 description 26
- 235000014113 dietary fatty acids Nutrition 0.000 description 19
- 239000000194 fatty acid Substances 0.000 description 19
- 229930195729 fatty acid Natural products 0.000 description 19
- 230000000052 comparative effect Effects 0.000 description 15
- 238000003860 storage Methods 0.000 description 14
- 239000003921 oil Substances 0.000 description 13
- 235000019198 oils Nutrition 0.000 description 13
- 230000000694 effects Effects 0.000 description 12
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 239000001993 wax Substances 0.000 description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
- 150000004665 fatty acids Chemical class 0.000 description 6
- 238000003892 spreading Methods 0.000 description 6
- 239000004166 Lanolin Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000004359 castor oil Substances 0.000 description 5
- 235000019438 castor oil Nutrition 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 229960005150 glycerol Drugs 0.000 description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 5
- 235000019388 lanolin Nutrition 0.000 description 5
- 229940039717 lanolin Drugs 0.000 description 5
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 4
- IZHVBANLECCAGF-UHFFFAOYSA-N 2-hydroxy-3-(octadecanoyloxy)propyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COC(=O)CCCCCCCCCCCCCCCCC IZHVBANLECCAGF-UHFFFAOYSA-N 0.000 description 4
- 239000002738 chelating agent Substances 0.000 description 4
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 230000001953 sensory effect Effects 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 3
- 229920001214 Polysorbate 60 Polymers 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000003925 fat Substances 0.000 description 3
- 235000019197 fats Nutrition 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 2
- YYSFXUWWPNHNAZ-OSDRTFJJSA-N 851536-75-9 Chemical compound C1[C@@H](OC)[C@H](OCCOCC)CC[C@H]1C[C@@H](C)[C@H]1OC(=O)[C@@H]2CCCCN2C(=O)C(=O)[C@](O)(O2)[C@H](C)CCC2C[C@H](OC)/C(C)=C/C=C/C=C/[C@@H](C)C[C@@H](C)C(=O)[C@H](OC)[C@H](O)/C(C)=C/[C@@H](C)C(=O)C1 YYSFXUWWPNHNAZ-OSDRTFJJSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 235000019486 Sunflower oil Nutrition 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- CMPDPBDUZTUXAD-UHFFFAOYSA-N [3-hydroxy-2-(16-methylheptadecanoyloxy)propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(CO)OC(=O)CCCCCCCCCCCCCCC(C)C CMPDPBDUZTUXAD-UHFFFAOYSA-N 0.000 description 2
- YZCLSZPQXZWSCJ-UHFFFAOYSA-L [Na+].[Na+].CCO.[O-]P(=O)OP([O-])=O Chemical compound [Na+].[Na+].CCO.[O-]P(=O)OP([O-])=O YZCLSZPQXZWSCJ-UHFFFAOYSA-L 0.000 description 2
- GFEUHEUTWRQSIR-UHFFFAOYSA-L [Na+].[Na+].[Na+].CCO.[O-]P(=O)OP([O-])=O Chemical compound [Na+].[Na+].[Na+].CCO.[O-]P(=O)OP([O-])=O GFEUHEUTWRQSIR-UHFFFAOYSA-L 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229940074045 glyceryl distearate Drugs 0.000 description 2
- 229940075507 glyceryl monostearate Drugs 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229940119170 jojoba wax Drugs 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 235000019808 microcrystalline wax Nutrition 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- ARIWANIATODDMH-UHFFFAOYSA-N rac-1-monolauroylglycerol Chemical compound CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 description 2
- GHBFNMLVSPCDGN-UHFFFAOYSA-N rac-1-monooctanoylglycerol Chemical compound CCCCCCCC(=O)OCC(O)CO GHBFNMLVSPCDGN-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 239000001587 sorbitan monostearate Substances 0.000 description 2
- 235000011076 sorbitan monostearate Nutrition 0.000 description 2
- 229940035048 sorbitan monostearate Drugs 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 239000002600 sunflower oil Substances 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 1
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- BJDAUCLANVMIOB-UHFFFAOYSA-N (3-decanoyloxy-2,2-dimethylpropyl) decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)(C)COC(=O)CCCCCCCCC BJDAUCLANVMIOB-UHFFFAOYSA-N 0.000 description 1
- PAFJZWHXMSQJKV-UQZRNVAESA-N (3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol;octadecanoic acid Chemical compound OC[C@@H](O)C1OC[C@H](O)[C@H]1O.OC[C@@H](O)C1OC[C@H](O)[C@H]1O.OC[C@@H](O)C1OC[C@H](O)[C@H]1O.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O PAFJZWHXMSQJKV-UQZRNVAESA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
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- OKMWKBLSFKFYGZ-UHFFFAOYSA-N 1-behenoylglycerol Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCC(O)CO OKMWKBLSFKFYGZ-UHFFFAOYSA-N 0.000 description 1
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- QHZLMUACJMDIAE-SFHVURJKSA-N 1-hexadecanoyl-sn-glycerol Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)CO QHZLMUACJMDIAE-SFHVURJKSA-N 0.000 description 1
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- NUHMQHLCUWSBCS-UHFFFAOYSA-N 10-(16-methylheptadecoxy)-10-oxodecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CCCCCCCCC(O)=O NUHMQHLCUWSBCS-UHFFFAOYSA-N 0.000 description 1
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 1
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- DHGBAFGZLVRESL-UHFFFAOYSA-N 14-methylpentadecyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC(C)C DHGBAFGZLVRESL-UHFFFAOYSA-N 0.000 description 1
- LGEZTMRIZWCDLW-UHFFFAOYSA-N 14-methylpentadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC(C)C LGEZTMRIZWCDLW-UHFFFAOYSA-N 0.000 description 1
- FUTGDWNFCMWSJT-UHFFFAOYSA-N 2,3-bis(14-methylpentadecanoyloxy)propyl 14-methylpentadecanoate Chemical compound CC(C)CCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCC(C)C FUTGDWNFCMWSJT-UHFFFAOYSA-N 0.000 description 1
- JNAYPSWVMNJOPQ-UHFFFAOYSA-N 2,3-bis(16-methylheptadecanoyloxy)propyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C JNAYPSWVMNJOPQ-UHFFFAOYSA-N 0.000 description 1
- XFBOJHLYDJZYSP-UHFFFAOYSA-N 2,8-dioxoadenine Chemical compound N1C(=O)N=C2NC(=O)NC2=C1N XFBOJHLYDJZYSP-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- FLPJVCMIKUWSDR-UHFFFAOYSA-N 2-(4-formylphenoxy)acetamide Chemical compound NC(=O)COC1=CC=C(C=O)C=C1 FLPJVCMIKUWSDR-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- ZVUNTIMPQCQCAQ-UHFFFAOYSA-N 2-dodecanoyloxyethyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCC ZVUNTIMPQCQCAQ-UHFFFAOYSA-N 0.000 description 1
- MUHFRORXWCGZGE-KTKRTIGZSA-N 2-hydroxyethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCO MUHFRORXWCGZGE-KTKRTIGZSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 1
- GECRRQVLQHRVNH-MRCUWXFGSA-N 2-octyldodecyl (z)-octadec-9-enoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC GECRRQVLQHRVNH-MRCUWXFGSA-N 0.000 description 1
- QNJOVLAFLJQFBF-UHFFFAOYSA-N 2-octyldodecyl 16-methylheptadecanoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCCCCCCCCCC(C)C QNJOVLAFLJQFBF-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- BQBYBPAPSIWHCE-UHFFFAOYSA-N 5-(dimethylamino)-2-methylpent-2-enoic acid Chemical compound CN(C)CCC=C(C)C(O)=O BQBYBPAPSIWHCE-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
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Description
本発明は、頭髪用組成物に関する。 The present invention relates to a composition for hair.
従来から、頭髪へ塗布する際に滑らかな曳糸性を有し、頭髪上での延展性を良好にする観点から、曳糸性を発揮させる原料として公知である高重合ポリエチレングリコールを配合した頭髪用の組成物が提案されている（例えば、特許文献１〜４を参照）。 Conventionally, hair that has a smooth spinnability when applied to the hair and blends highly polymerized polyethylene glycol, which is known as a raw material that exhibits the spinnability, from the viewpoint of improving the spreadability on the hair. Have been proposed (see, for example, Patent Documents 1 to 4).
しかしながら、高重合ポリエチレングリコールは、配合することで優れた曳糸性を発揮させることができる一方で、様々な成分が配合された組成物においては、種々の要因により高重合ポリエチレングリコールが劣化し、高温保管時の安定性に劣ってしまうことで高重合ポリエチレングリコール本来の優れた曳糸性を十分に発揮させることができないといった問題がある。高温保管時における曳糸性が低下するという現象は、様々な剤型の中でも、配合成分が多い乳化系において顕著に認められる。 However, highly polymerized polyethylene glycol can exhibit excellent spinnability by blending, while in a composition blended with various components, highly polymerized polyethylene glycol deteriorates due to various factors, There is a problem that the excellent spinnability inherent to the highly polymerized polyethylene glycol cannot be fully exhibited due to poor stability during high-temperature storage. The phenomenon that the spinnability at the time of high temperature storage is lowered is noticeably observed in an emulsified system having many compounding components among various dosage forms.
これまでにも、様々な成分が配合された組成物中における高重合ポリエチレングリコールの劣化を抑制するために、無水亜硫酸ナトリウム、ピロ亜硫酸ナトリウム、アスコルビン酸などの還元剤やエデト酸二ナトリウム、ジエチレントリアミン五酢酸五ナトリウム、クエン酸などのキレート剤が用いられてきたが、高温保管時における曳糸性を十分に発揮できるものはなく、これら課題を解決する手段は、未だ提案されていない。 In the past, in order to suppress deterioration of highly polymerized polyethylene glycol in compositions containing various components, reducing agents such as anhydrous sodium sulfite, sodium pyrosulfite and ascorbic acid, disodium edetate, and diethylenetriamine Chelating agents such as pentasodium acetate and citric acid have been used, but none of them can fully exhibit the spinnability during high-temperature storage, and no means for solving these problems has been proposed.
本発明は、前記従来技術に鑑みてなされたものであり、高重合ポリエチレングリコールが配合された組成物において、常温保管時のみならず、高温保管時であっても曳糸性を十分に発揮させることのできる頭髪用組成物を提供することを課題とする。
尚、本発明において、常温とは、５〜３５℃の範囲を言う。また、高温とは、４０〜５５℃の範囲を言う。
The present invention has been made in view of the above prior art, and in a composition blended with highly polymerized polyethylene glycol, it sufficiently exhibits the spinnability not only at room temperature storage but also at high temperature storage. It is an object to provide a composition for hair that can be used.
In addition, in this invention, normal temperature means the range of 5-35 degreeC. Moreover, high temperature means the range of 40-55 degreeC.
即ち、本発明は、
〔１〕整髪剤であるヘアワックスであり、（Ａ）平均重合度が１０，０００〜２００，０００である高重合ポリエチレングリコール、（Ｂ）ヒドロキシエタンジホスホン酸および／又はその塩、（Ｃ）水、（Ｄ）油剤、並びに（Ｅ）非イオン性界面活性剤を含有し、乳化物であることを特徴とする頭髪用組成物、
〔２〕前記（Ａ）成分の含有量が０．０１〜１．５質量％であり、前記（Ｂ）成分の含有量が０．０１〜０．１５質量％である前記〔１〕に記載の頭髪用組成物
に関する。
That is, the present invention
[1] A hair wax that is a hair styling agent, (A) a highly polymerized polyethylene glycol having an average degree of polymerization of 10,000 to 200,000, (B) hydroxyethanediphosphonic acid and / or a salt thereof, (C) A composition for hair, comprising water, (D) an oil agent, and (E) a nonionic surfactant, which is an emulsion,
[2] The content of the component (A) is 0.01 to 1.5% by mass, and the content of the component (B) is 0.01 to 0.15% by mass. the composition for hair of
About the.
本発明の頭髪用組成物は、常温保管時のみならず、高温保管時であっても、高重合ポリエチレングリコールが本来有する曳糸性を十分に発揮させることができ、のび広がりに優れた効果を奏する。 The hair composition of the present invention can sufficiently exhibit the stringiness inherent in highly polymerized polyethylene glycol, not only at room temperature storage but also at high temperature storage, and has an excellent effect of spreading. Play.
また、油剤と非イオン性界面活性剤をさらに含有し、乳化物とした頭髪用組成物では、本発明の構成を充足しない組成物と対比して、高重合ポリエチレングリコールが本来有する曳糸性をより顕著に発揮させることができ、のび広がりに優れた効果を奏する。 In addition, the hair composition further containing an oil agent and a nonionic surfactant and having an emulsion has a stringiness inherent to the highly polymerized polyethylene glycol as compared with a composition that does not satisfy the constitution of the present invention. It can be exhibited more remarkably and has an excellent effect of spreading.
本発明の頭髪用組成物は、（Ａ）平均重合度が１０，０００〜２００，０００である高重合ポリエチレングリコール、（Ｂ）ヒドロキシエタンジホスホン酸および／又はその塩、並びに（Ｃ）水を含有する。 The hair composition of the present invention comprises (A) a highly polymerized polyethylene glycol having an average degree of polymerization of 10,000 to 200,000, (B) hydroxyethanediphosphonic acid and / or a salt thereof, and (C) water. contains.
（Ａ）成分の高重合ポリエチレングリコールは、平均重合度が１０，０００〜２００，０００であり、水に分散した際に、若しくは水に溶解した際に曳糸性を発揮するものが用いられる。 The highly polymerized polyethylene glycol (A) has an average degree of polymerization of 10,000 to 200,000, and exhibits a spinnability when dispersed in water or dissolved in water.
上記した（Ａ）成分は、市販品を用いることができる。具体的な（Ａ）成分の市販品としては、例えば、Ｐｏｌｙｏｘ ＷＳＲ ２０５，Ｐｏｌｙｏｘ ＷＳＲ Ｎ−３０００（商品名，何れもダウ・ケミカル社製，平均重合度１４，０００，表示名称：ＰＥＧ−１４Ｍ）、アルコックス Ｅ−４５Ｇ（商品名，明成化学工業社製，平均重合度１４，０００，表示名称：ＰＥＧ−１４Ｍ）、アルコックス Ｅ−６０Ｇ（商品名，明成化学工業社製，平均重合度２０，０００，表示名称：ＰＥＧ−２０Ｍ）、Ｐｏｌｙｏｘ ＷＳＲ Ｎ−１２Ｋ（商品名，ダウ・ケミカル社製，平均重合度２３，０００，表示名称：ＰＥＧ−２３Ｍ）、Ｐｏｌｙｏｘ ＷＳＲ Ｎ−６０Ｋ（商品名，ダウ・ケミカル社製，平均重合度４５，０００，表示名称：ＰＥＧ−４５Ｍ）、アルコックス Ｅ−７５Ｇ（商品名，明成化学工業社製，平均重合度４５，０００，表示名称：ＰＥＧ−４５Ｍ）、アルコックス Ｅ−１００（商品名，明成化学工業社製，平均重合度６５，０００，表示名称：ＰＥＧ−６５Ｍ）、Ｐｏｌｙｏｘ ＷＳＲ ３０１（商品名，ダウ・ケミカル社製，平均重合度９０，０００，表示名称：ＰＥＧ−９０Ｍ）、アルコックス Ｅ−１６０Ｇ（商品名，明成化学工業社製，平均重合度９０，０００，表示名称：ＰＥＧ−９０Ｍ）、アルコックス Ｅ−２４０（商品名，明成化学工業社製，平均重合度１１５，０００，表示名称：ＰＥＧ−１１５Ｍ）、Ｐｏｌｙｏｘ ＷＳＲ ３０３（商品名，ダウ・ケミカル社製，平均重合度１６０，０００，表示名称：ＰＥＧ−１６０Ｍ）などが挙げられる。 A commercial item can be used for above-mentioned (A) component. Specific examples of commercially available products of component (A) include Polyox WSR 205, Polyox WSR N-3000 (trade names, all manufactured by Dow Chemical Company, average polymerization degree 14,000, display name: PEG-14M). Alcox E-45G (trade name, manufactured by Meisei Chemical Industry Co., Ltd., average polymerization degree 14,000, display name: PEG-14M), Alcox E-60G (trade name, manufactured by Meisei Chemical Industry Co., Ltd., average polymerization degree 20) , 000, display name: PEG-20M), Polyox WSR N-12K (trade name, manufactured by Dow Chemical Company, average polymerization degree 23,000, display name: PEG-23M), Polyox WSR N-60K (trade name, Dow Chemical Co., Ltd., average polymerization degree 45,000, display name: PEG-45M), Alcox E-75G (trade name, Meisei Chemical) Manufactured by Kogyo Co., Ltd., average polymerization degree 45,000, display name: PEG-45M), Alcox E-100 (trade name, manufactured by Meisei Chemical Industry Co., Ltd., average polymerization degree 65,000, display name: PEG-65M), Polyox WSR 301 (trade name, manufactured by Dow Chemical Company, average polymerization degree 90,000, display name: PEG-90M), Alcox E-160G (trade name, manufactured by Meisei Chemical Industry Co., Ltd., average polymerization degree 90,000, display) Name: PEG-90M), Alcox E-240 (trade name, manufactured by Meisei Chemical Industries, average polymerization degree 115,000, display name: PEG-115M), Polyox WSR 303 (trade name, manufactured by Dow Chemical Company, Average polymerization degree 160,000, display name: PEG-160M) and the like.
上記した（Ａ）成分は、１種を単独で用いてもよく、２種以上を適宜組み合わせて用いることができる。本発明においては、上記した平均重合度が１０，０００〜２００，０００である高重合ポリエチレングリコールの中でも、高温保管時であっても、本来有する曳糸性を十分に発揮させることができる観点から、平均重合度が３０，０００〜２００，０００の高重合ポリエチレングリコールを用いることが好ましく、平均重合度が３０，０００〜１８０，０００の高重合ポリエチレングリコールを用いることがより好ましい。 As the above-described component (A), one type may be used alone, or two or more types may be used in appropriate combination. In the present invention, among the highly polymerized polyethylene glycols having an average degree of polymerization of 10,000 to 200,000 as described above, it is possible to sufficiently exhibit the inherent spinnability even at high temperature storage. It is preferable to use highly polymerized polyethylene glycol having an average degree of polymerization of 30,000 to 200,000, and more preferably using highly polymerized polyethylene glycol having an average degree of polymerization of 30,000 to 180,000.
（Ａ）成分の含有量は、所望の効果が十分に発揮されるのであれば特に限定されないが、通常、十分な曳糸性を付与する観点から、組成物中、０．００５質量％以上であることが好ましく、より好ましくは０．０１質量％以上である。また、均一分散性の観点から、３質量％以下であることが好ましく、より好ましくは１．５質量％以下である。これらの観点から、（Ａ）成分の含有量は、０．００５〜３質量％であることが好ましく、より好ましくは０．０１〜１．５質量％である。 The content of the component (A) is not particularly limited as long as the desired effect is sufficiently exhibited, but is usually 0.005% by mass or more in the composition from the viewpoint of imparting sufficient spinnability. It is preferable that the content is 0.01% by mass or more. Further, from the viewpoint of uniform dispersibility, the content is preferably 3% by mass or less, more preferably 1.5% by mass or less. From these viewpoints, the content of the component (A) is preferably 0.005 to 3% by mass, and more preferably 0.01 to 1.5% by mass.
（Ｂ）成分のヒドロキシエタンジホスホン酸および／又はその塩は、通常、キレート剤として使用される成分である。本発明においては、上記した（Ａ）成分と、（Ｂ）成分であるヒドロキシエタンジホスホン酸および／又はその塩とを併用することで、驚くべきことに、高温保管時であっても、（Ａ）成分が本来有する曳糸性を十分に発揮させることができるようになる。（Ｂ）成分は、１種を単独で用いてもよく、２種以上を適宜組み合わせて用いてもよい。 Component (B), hydroxyethanediphosphonic acid and / or a salt thereof, is a component usually used as a chelating agent. In the present invention, surprisingly, even when stored at a high temperature, (A) component and hydroxyethanediphosphonic acid and / or salt thereof (B) component are used in combination. The spinnability inherent to the component A) can be sufficiently exhibited. (B) A component may be used individually by 1 type and may be used in combination of 2 or more types as appropriate.
ヒドロキシエタンジホスホン酸の塩としては、例えば、ナトリウム塩、カリウム塩などが挙げられる。具体的には、ヒドロキシエタンジホスホン酸四ナトリウム、ヒドロキシエタンジホスホン酸三ナトリウム、ヒドロキシエタンジホスホン酸二ナトリウム、ヒドロキシエタンジホスホン酸ナトリウム、ヒドロキシエタンジホスホン酸四カリウム、ヒドロキシエタンジホスホン酸三カリウム、ヒドロキシエタンジホスホン酸二カリウム、ヒドロキシエタンジホスホン酸カリウムなどを例示することができる。 Examples of the salt of hydroxyethanediphosphonic acid include sodium salt and potassium salt. Specifically, hydroxyethane diphosphonate tetrasodium, hydroxyethane diphosphonate trisodium, hydroxyethane diphosphonate disodium, hydroxyethane diphosphonate sodium, hydroxyethane diphosphonate tetrapotassium, hydroxyethane diphosphonate trisodium Examples include potassium, dipotassium hydroxyethanediphosphonate, potassium hydroxyethanediphosphonate, and the like.
上記した（Ｂ）成分は、市販品を用いることができる。具体的なヒドロキシエタンジホスホン酸の市販品としては、例えば、ターピナルＳＬ（商品名，サーモフォス社製）、ケンロックス２００（商品名，ナガセケムテックス社製）などが挙げられる。また、具体的なヒドロキシエタンジホスホン酸塩の市販品としては、例えば、ターピナル４ＮＬ（商品名，サーモフォス社製）などが挙げられる。 A commercial item can be used for above-mentioned (B) component. Specific commercial products of hydroxyethanediphosphonic acid include, for example, Turpinal SL (trade name, manufactured by Thermophos), Kenlox 200 (trade name, manufactured by Nagase ChemteX). Specific examples of commercially available hydroxyethane diphosphonates include Tarpinal 4NL (trade name, manufactured by Thermophos).
（Ｂ）成分の含有量は、所望の効果が十分に発揮されるのであれば特に限定されないが、通常、（Ａ）成分がもたらす曳糸性を安定に発揮させる観点から、組成物中、０．００５質量％以上であることが好ましく、より好ましくは０．０１質量％以上である。また、安定性および刺激性の観点から、０．３質量％以下であることが好ましく、より好ましくは０．１５質量％以下である。これらの観点から、（Ｂ）成分の含有量は、０．００５〜０．３質量％であることが好ましく、より好ましくは０．０１〜０．１５質量％である。 The content of the component (B) is not particularly limited as long as the desired effect is sufficiently exhibited, but usually, 0% in the composition from the viewpoint of stably exhibiting the spinnability provided by the component (A). It is preferably 0.005% by mass or more, and more preferably 0.01% by mass or more. Moreover, it is preferable that it is 0.3 mass% or less from a viewpoint of stability and irritation, More preferably, it is 0.15 mass% or less. From these viewpoints, the content of the component (B) is preferably 0.005 to 0.3% by mass, and more preferably 0.01 to 0.15% by mass.
（Ｃ）成分の水は、化粧料原料として使用できるものであれば特に限定はされないが、例えば、精製水が用いられる。（Ｃ）成分の含有量は、所望の効果が十分に発揮されるのであれば特に限定されないが、通常、（Ａ）成分の分散性の観点から、組成物中、２０質量％以上が好ましく、より好ましくは３０質量％以上である。また、効率的に曳糸性を発揮させる観点から、９５質量％以下が好ましく、より好ましくは９０質量％以下である。これらの観点から、（Ｃ）成分の含有量は、２０〜９５質量％が好ましく、より好ましくは３０〜９０質量％である。 Although the water of (C) component will not be specifically limited if it can be used as a cosmetic raw material, For example, purified water is used. The content of the component (C) is not particularly limited as long as the desired effect is sufficiently exhibited, but usually 20% by mass or more is preferable in the composition from the viewpoint of dispersibility of the component (A). More preferably, it is 30 mass% or more. Moreover, from a viewpoint of exhibiting the spinnability efficiently, 95 mass% or less is preferable, More preferably, it is 90 mass% or less. From these viewpoints, the content of the component (C) is preferably 20 to 95% by mass, more preferably 30 to 90% by mass.
本発明の頭髪用組成物は、上記した（Ａ）成分〜（Ｃ）成分を充足することにより、高温保管時であっても、（Ａ）成分である高重合ポリエチレングリコールが本来有する曳糸性を十分に発揮させることができるようになる。 The composition for hair of the present invention satisfies the above-described components (A) to (C), so that the high-polymerized polyethylene glycol as component (A) originally has a stringiness even when stored at high temperatures. Can be fully exhibited.
また、本発明の頭髪用組成物は、液状、ジェル状、乳液状、クリーム状、ワックス状などの何れの形態であっても所望の効果が十分に発揮されるのであれば特に限定されないが、高温保管時であっても、曳糸性を十分に発揮させることができるという本発明特有の効果は、乳液状、クリーム状、ワックス状などの乳化物である剤型においてより顕著に認められる。 Further, the hair composition of the present invention is not particularly limited as long as the desired effect is sufficiently exerted in any form such as liquid, gel, emulsion, cream, wax, etc. The effect peculiar to the present invention that the spinnability can be sufficiently exhibited even at the time of high-temperature storage is more remarkably observed in a dosage form which is an emulsion such as an emulsion, cream or wax.
本発明の頭髪用組成物を乳液状、クリーム状、ワックス状などの乳化物にするためには、上記した（Ａ）成分〜（Ｃ）成分に加え、さらに、（Ｄ）油剤および（Ｅ）非イオン性界面活性剤が含有される。 In order to make the composition for hair of the present invention into an emulsion such as emulsion, cream, wax, etc., in addition to the above-mentioned components (A) to (C), (D) oil and (E) A nonionic surfactant is contained.
（Ｄ）成分の油剤としては、例えば、油脂、ロウ類、炭化水素油、高級脂肪酸、高級アルコール、脂肪酸エステル油、シリコーン油などが挙げられる。これら（Ｄ）成分は、１種を単独で用いてもよく、２種以上を適宜組み合わせて用いてもよい。 Examples of the component (D) oil include fats and oils, waxes, hydrocarbon oils, higher fatty acids, higher alcohols, fatty acid ester oils, silicone oils, and the like. These (D) components may be used individually by 1 type, and may be used in combination of 2 or more types as appropriate.
具体的な油脂としては、ヒマワリ油、アボガド油、綿実油、大豆油、オリーブ油、マカデミアナッツ油、落花生油、トウモロコシ油、ナタネ油、ゴマ油、サフラワー油、コメヌカ油、ヒマシ油、ホホバ油、椿油、ミンク油などの液体油脂；ヤシ油、パーム油、パーム核油、カカオ脂、硬化油、硬化ヒマシ油などの固体油脂などを例示することができる。 Specific fats and oils include sunflower oil, avocado oil, cottonseed oil, soybean oil, olive oil, macadamia nut oil, peanut oil, corn oil, rapeseed oil, sesame oil, safflower oil, rice bran oil, sunflower oil, jojoba oil, camellia oil, mink Examples thereof include liquid fats and oils such as oil; solid fats and oils such as coconut oil, palm oil, palm kernel oil, cacao butter, hardened oil, and hardened castor oil.
具体的なロウ類としては、カルナウバロウ、キャンデリラロウ、ミツロウ、コメヌカロウ、モンタンロウ、セラックロウ、鯨ロウ、ホホバロウ、ラノリン、液状ラノリン、還元ラノリン、硬質ラノリンなどを例示することができる。 Specific examples of the wax include carnauba wax, candelilla wax, beeswax, rice bran wax, montan wax, shellac wax, whale wax, jojoba wax, lanolin, liquid lanolin, reduced lanolin, and hard lanolin.
具体的な炭化水素油としては、セレシン、パラフィン、流動パラフィン、流動イソパラフィン、固形パラフィン、マイクロクリスタリンワックス、フィッシャー・トロプシュワックス、ポリエチレン末、ポリエチレンワックス、ワセリン、スクワランなどを例示することができる。 Specific examples of the hydrocarbon oil include ceresin, paraffin, liquid paraffin, liquid isoparaffin, solid paraffin, microcrystalline wax, Fischer-Tropsch wax, polyethylene powder, polyethylene wax, petrolatum, squalane and the like.
具体的な高級脂肪酸としては、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、オレイン酸、ベヘニン酸、ウンデシレン酸、イソステアリン酸、リノール酸、リノレン酸、１２−ヒドロキシステアリン酸などを例示することができる。 Specific examples of the higher fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, undecylenic acid, isostearic acid, linoleic acid, linolenic acid, and 12-hydroxystearic acid. .
具体的な高級アルコールとしては、ラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、オレイルアルコール、ラノリンアルコール、ベヘニルアルコール、セトステアリルアルコール、イソステアリルアルコールなどを例示することができる。 Specific examples of the higher alcohol include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, lanolin alcohol, behenyl alcohol, cetostearyl alcohol, and isostearyl alcohol.
具体的な脂肪酸エステル油としては、オレイン酸エチル、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ステアリン酸ブチル、ミリスチン酸ミリスチル、ミリスチン酸セチル、パルミチン酸セチル、ステアリン酸ステアリル、オレイン酸デシル、オレイン酸オレイル、ミリスチン酸オクチルドデシル、オレイン酸オクチルドデシル、イソステアリン酸エチル、ステアリン酸イソセチル、イソステアリン酸イソプロピル、イソステアリン酸イソセチル、２−エチルヘキサン酸セチル、２−エチルヘキサン酸セトステアリル、ジカプリン酸ネオペンチルグリコール、ジオクタン酸ネオペンチルグリコール、トリ２−エチルヘキサン酸グリセリル、トリオクタン酸グリセリル、トリイソパルミチン酸グリセリル、トリイソステアリン酸グリセリル、トリ２−エチルヘキサン酸トリメチロールプロパン、トリイソステアリン酸トリメチロールプロパン、テトラ２−エチルヘキサン酸ペンタエリスリトール、オクタン酸セチル、オクタン酸イソセチル、オクタン酸イソステアリル、セバシン酸イソステアリル、イソステアリン酸オクチルドデシル、ジメチルオクタン酸オクチルドデシルなどを例示することができる。 Specific fatty acid ester oils include ethyl oleate, isopropyl myristate, isopropyl palmitate, butyl stearate, myristyl myristate, cetyl myristate, cetyl palmitate, stearyl stearate, decyl oleate, oleyl oleate, myristic Octyldodecyl acrylate, octyldodecyl oleate, ethyl isostearate, isocetyl stearate, isopropyl isostearate, isocetyl isostearate, cetyl 2-ethylhexanoate, cetostearyl 2-ethylhexanoate, neopentyl glycol dicaprate, neopentyl dioctanoate Glycol, glyceryl tri-2-ethylhexanoate, glyceryl trioctanoate, glyceryl triisopalmitate, triisostearate Seryl, tri-2-ethylhexanoate trimethylolpropane, triisostearate trimethylolpropane, tetra-2-ethylhexanoate pentaerythritol, cetyl octoate, isocetyl octoate, isostearyl octoate, isostearyl sebacate, octyldodecyl isostearate And octyldodecyl dimethyloctanoate.
具体的なシリコーン油としては、メチルポリシロキサン、高重合メチルポリシロキサン、オクタメチルトリシロキサン、デカメチルテトラシロキサン、メチルフェニルポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン、メチルシクロポリシロキサン、アルコール変性シリコーン、アルキル変性シリコーン、アミノ変性シリコーン、ポリエーテル変性シリコーン、フッ素変性シリコーンなどを例示することができる。 Specific silicone oils include methylpolysiloxane, highly polymerized methylpolysiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, methylphenylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane. Examples thereof include methylcyclopolysiloxane, alcohol-modified silicone, alkyl-modified silicone, amino-modified silicone, polyether-modified silicone, and fluorine-modified silicone.
（Ｄ）成分の含有量は、所望の効果が十分に発揮されるのであれば特に限定されないが、通常、使用感の観点から、組成物中、１質量％以上であることが好ましく、より好ましくは２質量％以上である。また、ベタつきや洗い落ちの観点から、７０質量％以下であることが好ましく、より好ましくは６０質量％以下である。これらの観点から、（Ｄ）成分の含有量は、１〜７０質量％であることが好ましく、より好ましくは２〜６０質量％である。 The content of the component (D) is not particularly limited as long as the desired effect is sufficiently exhibited, but it is usually preferably 1% by mass or more in the composition from the viewpoint of feeling of use, and more preferably. Is 2% by mass or more. Moreover, from a viewpoint of stickiness or washing off, it is preferable that it is 70 mass% or less, More preferably, it is 60 mass% or less. From these viewpoints, the content of the component (D) is preferably 1 to 70% by mass, and more preferably 2 to 60% by mass.
（Ｅ）成分の非イオン性界面活性剤としては、例えば、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、グリセリン脂肪酸エステルの酸化エチレン縮合物、ポリエチレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル、ソルビタン脂肪酸エステルの酸化エチレン縮合物、ポリオキシアルキレンアルキルエーテル、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンヒマシ油などが挙げられる。これら（Ｅ）成分は、１種を単独で用いてもよく、２種以上を適宜組み合わせて用いてもよい。 Examples of the nonionic surfactant of component (E) include glycerin fatty acid ester, polyglycerin fatty acid ester, ethylene oxide condensate of glycerin fatty acid ester, polyethylene glycol fatty acid ester, sorbitan fatty acid ester, and ethylene oxide condensation of sorbitan fatty acid ester. Products, polyoxyalkylene alkyl ether, polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, and the like. These (E) components may be used individually by 1 type, and may be used in combination of 2 or more types as appropriate.
具体的なグリセリン脂肪酸エステルとしては、モノカプリル酸グリセリル、モノカプリン酸グリセリル、モノラウリン酸グリセリル、モノミリスチン酸グリセリル、モノパルミチン酸グリセリル、モノステアリン酸グリセリル、モノイソステアリン酸グリセリル、モノベヘン酸グリセリル、モノオレイン酸グリセリル、モノエルカ酸グリセリル、セスキオレイン酸グリセリル、ジステアリン酸グリセリル、ジイソステアリン酸グリセリル、ジアラキン酸グリセリルなどを例示することができる。 Specific glyceryl fatty acid esters include glyceryl monocaprylate, glyceryl monocaprate, glyceryl monolaurate, glyceryl monomyristate, glyceryl monopalmitate, glyceryl monostearate, glyceryl monoisostearate, glyceryl monobehenate, monooleic acid Examples thereof include glyceryl, glyceryl monoerucate, glyceryl sesquioleate, glyceryl distearate, glyceryl diisostearate, and glyceryl diarachiate.
具体的なポリグリセリン脂肪酸エステルとしては、モノカプリル酸ジグリセリル、モノカプリル酸デカグリセリル、モノカプリン酸ヘキサグリセリル、モノラウリン酸テトラグリセリル、モノラウリン酸ヘキサグリセリル、モノラウリン酸デカグリセリル、モノラウリン酸ポリ（４〜１０）グリセリル、モノミリスチン酸デカグリセリル、モノステアリン酸デカグリセリル、モノイソステアリン酸デカグリセリル、モノステアリン酸ポリ（２〜１０）グリセリル、モノオレイン酸ジグリセリル、モノオレイン酸ヘキサグリセリル、セスキオレイン酸ジグリセリル、ジイソステアリン酸ポリ（２〜１０）グリセリル、ジステアリン酸ポリ（６〜１０）グリセリル、トリイソステアリン酸ジグリセリル、トリステアリン酸ポリ（１０）グリセリルなどを例示することができる。尚、前記括弧内の数値は、グリセリン脂肪酸エステルの重合度を表す。 Specific examples of the polyglyceryl fatty acid ester include diglyceryl monocaprylate, decaglyceryl monocaprylate, hexaglyceryl monocaprate, tetraglyceryl monolaurate, hexaglyceryl monolaurate, decaglyceryl monolaurate, poly (4 to 10 polylaurate) ) Glyceryl, decaglyceryl monomyristate, decaglyceryl monostearate, decaglyceryl monoisostearate, poly (2-10) glyceryl monostearate, diglyceryl monooleate, hexaglyceryl monooleate, diglyceryl sesquioleate, Poly (2-10) glyceryl diisostearate, poly (6-10) glyceryl distearate, diglyceryl triisostearate, poly (10) glyceryl tristearate Etc. can be exemplified. In addition, the numerical value in the said parenthesis represents the polymerization degree of glycerol fatty acid ester.
具体的なグリセリン脂肪酸エステルの酸化エチレン縮合物としては、モノステアリン酸ポリオキシエチレングリセリル、モノイソステアリン酸ポリオキシエチレングリセリル、トリイソステアリン酸ポリオキシエチレングリセリル、モノオレイン酸ポリオキシエチレングリセリルなどを例示することができる。尚、酸化エチレンの付加モル数は、特に限定されないが、３〜１００であることが好ましい。 Specific examples of the ethylene oxide condensate of glycerin fatty acid ester include polyoxyethylene glyceryl monostearate, polyoxyethylene glyceryl monoisostearate, polyoxyethylene glyceryl triisostearate, polyoxyethylene glyceryl monooleate, and the like. Can do. The number of added moles of ethylene oxide is not particularly limited, but is preferably 3 to 100.
具体的なポリエチレングリコール脂肪酸エステルとしては、モノラウリン酸ポリエチレングリコール、モノステアリン酸ポリエチレングリコール、モノイソステアリン酸ポリエチレングリコール、モノオレイン酸ポリエチレングリコール、ジラウリン酸ポリエチレングリコール、ジステアリン酸ポリエチレングリコール、ジイソステアリン酸ポリエチレングリコール、ジオレイン酸ポリエチレングリコールなどを例示することができる。尚、酸化エチレンの付加モル数は、特に限定されないが、２〜１００であることが好ましい。 Specific examples of polyethylene glycol fatty acid esters include polyethylene glycol monolaurate, polyethylene glycol monostearate, polyethylene glycol monoisostearate, polyethylene glycol monooleate, polyethylene glycol dilaurate, polyethylene glycol distearate, polyethylene glycol diisostearate, and dioleic acid. Examples thereof include polyethylene glycol. The number of moles of ethylene oxide added is not particularly limited, but is preferably 2 to 100.
具体的なソルビタン脂肪酸エステルとしては、モノラウリン酸ソルビタン、モノパルミチン酸ソルビタン、モノステアリン酸ソルビタン、モノオレイン酸ソルビタン、モノイソステアリン酸ソルビタン、トリオレイン酸ソルビタン、トリステアリン酸ソルビタン、セスキステアリン酸ソルビタン、セスキイソステアリン酸ソルビタン、セスキオレイン酸ソルビタン、ヤシ油脂肪酸ソルビタンなどを例示することができる。 Specific examples of sorbitan fatty acid esters include sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan monooleate, sorbitan monoisostearate, sorbitan trioleate, sorbitan tristearate, sorbitan sesquistearate, sesquiisostearate Examples include sorbitan acid, sorbitan sesquioleate, and coconut oil fatty acid sorbitan.
具体的なソルビタン脂肪酸エステルの酸化エチレン縮合物としては、モノラウリン酸ポリオキシエチレンソルビタン、モノパルミチン酸ポリオキシエチレンソルビタン、モノステアリン酸ポリオキシエチレンソルビタン、モノオレイン酸ポリオキシエチレンソルビタン、モノイソステアリン酸ポリオキシエチレンソルビタン、モノヤシ油脂肪酸ポリオキシエチレンソルビタン、トリステアリン酸ポリオキシエチレンソルビタン、トリオレイン酸ポリオキシエチレンソルビタンなどを例示することができる。尚、酸化エチレンの付加モル数は、特に限定されないが、２〜１００であることが好ましい。 Specific examples of the ethylene oxide condensate of sorbitan fatty acid esters include polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxymonoisostearate Examples thereof include ethylene sorbitan, monococonut oil fatty acid polyoxyethylene sorbitan, polystearic acid polyoxyethylene sorbitan, and trioleic acid polyoxyethylene sorbitan. The number of moles of ethylene oxide added is not particularly limited, but is preferably 2 to 100.
具体的なポリオキシアルキレンアルキルエーテルとしては、ポリオキシエチレンラウリルエーテル、ポリオキシエチレンセチルエーテル、ポリオキシエチレンステアリルエーテル、ポリオキシエチレンオレイルエーテル、ポリオキシエチレンポリオキシプロピレンラウリルエーテル、ポリオキシプロピレンセチルエーテル、ポリオキシプロピレンイソセチルエーテル、ポリオキシプロピレンステアリルエーテル、ポリオキシプロピレンオレイルエーテルなどを例示することができる。尚、酸化エチレンの付加モル数は、特に限定されないが、２〜１００であることが好ましい。 Specific polyoxyalkylene alkyl ethers include polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene polyoxypropylene lauryl ether, polyoxypropylene cetyl ether, Examples thereof include polyoxypropylene isocetyl ether, polyoxypropylene stearyl ether, polyoxypropylene oleyl ether and the like. The number of moles of ethylene oxide added is not particularly limited, but is preferably 2 to 100.
ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンヒマシ油の酸化エチレンの付加モル数は、特に限定されないが、２〜１５０であることが好ましい。 The number of moles of ethylene oxide added to the polyoxyethylene hydrogenated castor oil and polyoxyethylene castor oil is not particularly limited, but is preferably 2 to 150.
（Ｅ）成分の含有量は、所望の効果が十分に発揮されるのであれば特に限定されないが、通常、乳化安定性の観点から、組成物中、０．１質量％以上であることが好ましく、より好ましくは０．５質量％以上である。また、使用感の観点から、３０質量％以下であることが好ましく、より好ましくは２０質量％以下である。これらの観点から、（Ｅ）成分の含有量は、０．１〜３０質量％であることが好ましく、より好ましくは０．５〜２０質量％である。 The content of the component (E) is not particularly limited as long as the desired effect is sufficiently exhibited, but it is usually preferably 0.1% by mass or more in the composition from the viewpoint of emulsion stability. More preferably, it is 0.5% by mass or more. Moreover, from a viewpoint of a usability | use_condition, it is preferable that it is 30 mass% or less, More preferably, it is 20 mass% or less. From these viewpoints, the content of the component (E) is preferably 0.1 to 30% by mass, and more preferably 0.5 to 20% by mass.
尚、本発明の頭髪用組成物を乳化物とする場合には、前記各構成成分を混合し、公知の方法、例えばホモミキサーを用いた転相乳化法などにより乳化することにより製造することができる。また、混合と乳化は別々に行っても同時に行ってもよい。 In addition, when making the composition for hair of this invention into an emulsion, it can manufacture by mixing each said component and emulsifying by a well-known method, for example, the phase inversion emulsification method using a homomixer. it can. Moreover, mixing and emulsification may be performed separately or simultaneously.
本発明の頭髪用組成物には、本発明の効果を損なわない範囲で、上記した成分の他、通常化粧品に用いられる成分、例えば、アクリル樹脂アルカノールアミン、ポリビニルピロリドン、酢酸ビニル・ビニルピロリドン共重合体、ビニルピロリドン・Ｎ，Ｎ−ジメチルアミノエチルメタクリル酸共重合体ジエチル硫酸塩、ビニルピロリドン・メタクリルアミド・ビニルイミダゾール共重合体、Ｎ−メタクリロイルオキシエチルＮ，Ｎ−ジメチルアンモニウム−α−Ｎ−メチルカル・ボキシベタイン・メタクリル酸アルキルエステル共重合体、ビニルメチルエーテル・マレイン酸ブチル共重合体などの被膜形成剤；グリセリン、１，３−ブチレングリコール、１，２−オクタンジオールなどの（Ａ）成分以外の多価アルコール；ソルビトール、マルチトールなどの糖アルコール；カルボキシビニルポリマー、アクリル酸・メタクリル酸アルキル共重合体、キサンタンガム、ヒドロキシプロピルメチルセルロースなどの増粘性高分子；シリカ、マイカなどの粉体；ベントナイト、ヘクトライト、サポナイトなどの粘土鉱物；水酸化ナトリウム、トリエタノールアミンなどのｐＨ調整剤；低級アルコール、紫外線吸収剤、香料、酸化防止剤、防腐剤、清涼剤、ビタミン類、植物抽出物などを目的に応じて適宜配合することができる。 In the composition for hair of the present invention, within the range not impairing the effects of the present invention, in addition to the above-described components, components commonly used in cosmetics, for example, acrylic resin alkanolamine, polyvinylpyrrolidone, vinyl acetate / vinylpyrrolidone copolymer Polymer, vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate, vinylpyrrolidone / methacrylamide / vinylimidazole copolymer, N-methacryloyloxyethyl N, N-dimethylammonium-α-N-methylcarb -Film forming agents such as boxybetaine / methacrylic acid alkyl ester copolymer, vinyl methyl ether / butyl maleate copolymer; other than component (A) such as glycerin, 1,3-butylene glycol, 1,2-octanediol Polyhydric alcohol; sorbitol, ma Sugar alcohols such as titol; thickening polymers such as carboxyvinyl polymer, acrylic acid / alkyl methacrylate copolymer, xanthan gum and hydroxypropylmethylcellulose; powders such as silica and mica; clay minerals such as bentonite, hectorite and saponite PH adjusting agents such as sodium hydroxide and triethanolamine; lower alcohols, UV absorbers, fragrances, antioxidants, preservatives, refreshing agents, vitamins, plant extracts, etc. may be appropriately blended according to the purpose. it can.
以下、本発明を実施例に基づいて更に詳細に説明するが、本発明はこれら実施例にのみ限定されるものではない。尚、配合量は、特記しない限り「質量％」を表す。 EXAMPLES Hereinafter, although this invention is demonstrated further in detail based on an Example, this invention is not limited only to these Examples. The blending amount represents “% by mass” unless otherwise specified.
（試料の調製１）
表１〜５に記した組成に従い、実施例１〜８および比較例１〜１３（但し、実施例１〜８および比較例１〜１３は参考例である）の各頭髪用組成物を調製し、夫々の試料を２５℃の恒温槽および５０℃の恒温槽に４週間保管後、下記評価に供した。結果を表１〜５に併記する。尚、表中、「高重ＰＥＧ」とは、高重合ポリエチレングリコールを表す。
(Sample preparation 1)
According to the composition described in Tables 1-5, each hair composition of Examples 1-8 and Comparative Examples 1-13 (however, Examples 1-8 and Comparative Examples 1-13 are reference examples) was prepared. Each sample was stored in a constant temperature bath at 25 ° C. and a constant temperature bath at 50 ° C. for 4 weeks, and then subjected to the following evaluation. The results are also shown in Tables 1-5. In the table, “high heavy PEG” represents highly polymerized polyethylene glycol.
（試験例１：曳糸性の評価）
予め石けんで洗浄した手の甲に、上記各恒温槽に保管後、２３℃、湿度６０％の室内で２時間以上静置した実施例および比較例の各試料を１ｇのせた。次いで、試料に指先を押し付けてから離す際の曳糸性を、下記評価基準に従って目視により評価した。
(Test Example 1: Evaluation of spinnability)
1 g of each sample of Examples and Comparative Examples was placed on the back of the hand, which had been washed with soap in advance, after being stored in each of the above thermostats and allowed to stand in a room at 23 ° C. and 60% humidity for 2 hours or more. Next, the spinnability when the fingertip was pressed against the sample and then released was visually evaluated according to the following evaluation criteria.
評価は、１０人の官能評価パネルにより、上記操作を繰り返し３回行った。評価基準は、「曳糸性が強いものを２点」、「曳糸性は強くないが認められるものを１点」、「曳糸性がほとんど認められないものを０点」とし、その合計点を算出した。 The evaluation was repeated three times using a sensory evaluation panel of 10 people. The evaluation criteria were “2 points for strong spinnability”, “1 point for those with no strong spinnability” and “0 points for almost no spinnability” Points were calculated.
＜曳糸性の評価基準＞
◎：合計点が、４６〜６０点
○：合計点が、３１〜４５点
△：合計点が、１６〜３０点
×：合計点が、０〜１５点
<Evaluation criteria for stringiness>
◎: Total score is 46-60 points ○: Total score is 31-45 points Δ: Total score is 16-30 points ×: Total score is 0-15 points
（試験例２：のびの評価）
予め石けんで洗浄した手の甲に、上記各恒温槽に保管後、２３℃、湿度６０％の室内で２時間以上静置した実施例および比較例の各試料を０．３ｇのせた。次いで、試料に指先でのばした際ののびを、下記評価基準に従って目視により評価した。
(Test example 2: Nobori evaluation)
0.3 g of each sample of the example and the comparative example was placed on the back of the hand, which had been washed with soap in advance, after being stored in each of the above-described constant temperature baths and allowed to stand in a room at 23 ° C. and a humidity of 60% for 2 hours or more. Next, the extension of the sample with a fingertip was visually evaluated according to the following evaluation criteria.
評価は、１０人の官能評価パネルにより、上記操作を繰り返し３回行った。評価基準は、「非常にのびのよいものを２点」、「のびのよいものを１点」、「のびの悪いものを０点」とし、その合計点を算出した。 The evaluation was repeated three times using a sensory evaluation panel of 10 people. The evaluation criteria were “2 points with very good spread”, “1 point with good spread”, and “0 points with poor spread”, and the total score was calculated.
＜のびの評価基準＞
◎：合計点が、４６〜６０点
○：合計点が、３１〜４５点
△：合計点が、１６〜３０点
×：合計点が、０〜１５点
<Evaluation criteria for Nobi>
◎: Total score is 46-60 points ○: Total score is 31-45 points Δ: Total score is 16-30 points ×: Total score is 0-15 points
表１〜５に示された結果から、本発明の構成成分を充足する実施例１〜８の頭髪用組成物では、常温保管時のみならず、高温保管時においても、（Ａ）成分である高重合ポリエチレングリコールが本来有する曳糸性を十分に発揮させることができ、のび広がりに優れた効果を奏していることが分かる。 From the results shown in Tables 1 to 5, the hair compositions of Examples 1 to 8 satisfying the constituents of the present invention are the component (A) not only during normal temperature storage but also during high temperature storage. It can be seen that the spinnability inherently possessed by the highly polymerized polyethylene glycol can be sufficiently exerted, and that it has an excellent effect of spreading.
これに対し、（Ｂ）成分を含有しない比較例１〜８の頭髪用組成物、（Ａ）成分を本発明の平均重合度を満たさない高重合ポリエチレングリコールへ置き換えた比較例９の頭髪用組成物、並びに（Ｂ）成分を他の還元剤やキレート剤へ置き換えた比較例１０〜１３の頭髪用組成物では、（Ａ）成分である高重合ポリエチレングリコールが本来有する曳糸性を十分に発揮させることができず、のび広がりにも劣っていることが分かる。 On the other hand, the composition for hair of Comparative Examples 1-8 which does not contain (B) component, and the composition for hair of Comparative Example 9 which replaced (A) component with highly polymerized polyethylene glycol which does not satisfy the average degree of polymerization of the present invention. And the composition for hair of Comparative Examples 10 to 13 in which the component (B) is replaced with another reducing agent or chelating agent, sufficiently exhibits the stringiness inherent in the highly polymerized polyethylene glycol as the component (A) It can be seen that it is inferior in spreading.
特に、比較例９の結果から、本発明の平均重合度を満たさない高重合ポリエチレングリコールへ置き換え、さらに高配合したとしても十分な曳糸性が得られないことが分かる。この結果からも明らかな通り、格段に優れた曳糸性を十分に発揮させ、のび広がりに優れた頭髪用組成物を得るためには、本発明の構成要件を満たすことが必須であると言える。 In particular, it can be seen from the results of Comparative Example 9 that sufficient spinnability cannot be obtained even if the polymerized polyethylene glycol that does not satisfy the average degree of polymerization of the present invention is replaced and further blended. As is clear from these results, it can be said that it is essential to satisfy the constitutional requirements of the present invention in order to sufficiently exhibit the excellent spinnability and to obtain a composition for hair with excellent spread. .
（試料の調製２）
表６〜１０に記した組成に従い、実施例９〜１６および比較例１４〜２６の乳化物である各頭髪用組成物を調製し、夫々の試料を２５℃の恒温槽および５０℃の恒温槽に４週間保管後、下記評価に供した。結果を表６〜１０に併記する。尚、表中、「高重ＰＥＧ」とは、高重合ポリエチレングリコールを表す。
(Sample preparation 2)
According to the composition described in Tables 6-10, each hair composition which is an emulsion of Examples 9-16 and Comparative Examples 14-26 was prepared, and each sample was a 25 degreeC thermostat and a 50 degreeC thermostat. After 4 weeks of storage, it was subjected to the following evaluation. The results are shown in Tables 6-10. In the table, “high heavy PEG” represents highly polymerized polyethylene glycol.
（試験例３：曳糸性の評価）
予め石けんで洗浄した手の甲に、上記各恒温槽に保管後、２３℃、湿度６０％の室内で２時間以上静置した実施例および比較例の各試料を１ｇのせた。次いで、試料に指先を押し付けてから離す際の曳糸性を、下記評価基準に従って目視により評価した。
(Test Example 3: Evaluation of spinnability)
1 g of each sample of Examples and Comparative Examples was placed on the back of the hand, which had been washed with soap in advance, after being stored in each of the above thermostats and allowed to stand in a room at 23 ° C. and 60% humidity for 2 hours or more. Next, the spinnability when the fingertip was pressed against the sample and then released was visually evaluated according to the following evaluation criteria.
評価は、１０人の官能評価パネルにより、上記操作を繰り返し３回行った。評価基準は、「曳糸性が強いものを２点」、「曳糸性は強くないが認められるものを１点」、「曳糸性がほとんど認められないものを０点」とし、その合計点を算出した。 The evaluation was repeated three times using a sensory evaluation panel of 10 people. The evaluation criteria were “2 points for strong spinnability”, “1 point for those with no strong spinnability” and “0 points for almost no spinnability” Points were calculated.
＜曳糸性の評価基準＞
◎：合計点が、４６〜６０点
○：合計点が、３１〜４５点
△：合計点が、１６〜３０点
×：合計点が、０〜１５点
<Evaluation criteria for stringiness>
◎: Total score is 46-60 points ○: Total score is 31-45 points Δ: Total score is 16-30 points ×: Total score is 0-15 points
（試験例４：のびの評価）
予め石けんで洗浄した手の甲に、上記各恒温槽に保管後、２３℃、湿度６０％の室内で３０分間静置した実施例および比較例の各試料を０．３ｇのせた。次いで、試料に指先でのばした際ののびを、下記評価基準に従って目視により評価した。
(Test Example 4: Nobori evaluation)
0.3 g of each sample of the example and the comparative example was placed on the back of the hand, which had been washed with soap in advance, after being stored in each of the above-described thermostatic chambers and then allowed to stand in a room at 23 ° C. and a humidity of 60% for 30 minutes. Next, the extension of the sample with a fingertip was visually evaluated according to the following evaluation criteria.
評価は、１０人の官能評価パネルにより、上記操作を繰り返し３回行った。評価基準は、「非常にのびのよいものを２点」、「のびのよいものを１点」、「のびの悪いものを０点」とし、その合計点を算出した。 The evaluation was repeated three times using a sensory evaluation panel of 10 people. The evaluation criteria were “2 points with very good spread”, “1 point with good spread”, and “0 points with poor spread”, and the total score was calculated.
＜のびの評価基準＞
◎：合計点が、４６〜６０点
○：合計点が、３１〜４５点
△：合計点が、１６〜３０点
×：合計点が、０〜１５点
<Evaluation criteria for Nobi>
◎: Total score is 46-60 points ○: Total score is 31-45 points Δ: Total score is 16-30 points ×: Total score is 0-15 points
表６〜１０に示された結果から、本発明の構成成分を充足する実施例９〜１６の乳化物である頭髪用組成物では、常温保管時のみならず、高温保管時においても、（Ａ）成分である高重合ポリエチレングリコールが本来有する曳糸性を十分に発揮させることができ、のび広がりに優れた効果を奏していることが分かる。 From the results shown in Tables 6 to 10, in the composition for hair which is an emulsion of Examples 9 to 16 satisfying the components of the present invention, not only at room temperature storage but also at high temperature storage (A It can be seen that the high-polymerized polyethylene glycol, which is a component), can sufficiently exhibit the spinnability inherent to it, and has an excellent effect of spreading.
これに対し、（Ｂ）成分を含有しない比較例１４〜２１の乳化物である頭髪用組成物、（Ａ）成分を本発明の平均重合度を満たさない高重合ポリエチレングリコールへ置き換えた比較例２２の乳化物である頭髪用組成物、並びに（Ｂ）成分を他の還元剤やキレート剤へ置き換えた比較例２３〜２６の乳化物である頭髪用組成物では、（Ａ）成分である高重合ポリエチレングリコールが本来有する曳糸性を十分に発揮させることができず、のび広がりにも劣っていることが分かる。 On the other hand, the composition for hair which is an emulsion of Comparative Examples 14-21 which does not contain (B) component, and the comparative example 22 which replaced (A) component with the highly polymerized polyethylene glycol which does not satisfy | fill the average degree of polymerization of this invention. In the composition for hair which is an emulsion of the above, and the composition for hair which is an emulsion of Comparative Examples 23 to 26 in which the component (B) is replaced with other reducing agents and chelating agents, the high polymerization which is the component (A) It can be seen that the inherent spinnability of polyethylene glycol cannot be fully exerted and the spread is inferior.
特に、比較例２２の結果から、本発明の平均重合度を満たさない高重合ポリエチレングリコールへ置き換え、さらに高配合したとしても十分な曳糸性が得られないことが分かる。この結果からも明らかな通り、格段に優れた曳糸性を十分に発揮させ、のび広がりに優れた乳化物である頭髪用組成物を得るためには、本発明の構成要件を満たすことが必須であると言える。 In particular, it can be seen from the results of Comparative Example 22 that sufficient spinnability cannot be obtained even if the polymerized polyethylene glycol which does not satisfy the average degree of polymerization of the present invention is replaced and further blended. As is apparent from these results, it is essential to satisfy the constitutional requirements of the present invention in order to sufficiently exhibit the excellent spinnability and to obtain a composition for hair that is an emulsion excellent in spreading. It can be said that.
以下、本発明に係る頭髪用組成物の処方例を示す。尚、含有量は質量％である。また、ＰＯＥとはポリオキシエチレンの略であり、括弧内の数値は、平均重合度の記載を除き、酸化エチレンの付加モル数を表す。 Hereinafter, the formulation example of the composition for hair based on this invention is shown. In addition, content is mass%. POE is an abbreviation for polyoxyethylene, and the numerical values in parentheses represent the number of moles of ethylene oxide added, except for the description of the average degree of polymerization.
（処方例１：ヘアワックス）
高重合ＰＥＧ（平均重合度９０，０００） ０．０３
プロピレングリコール ２．０
マイクロクリスタリンワックス ５．０
カルナバロウ ５．０
パラフィン ５．０
２−エチルヘキサン酸セチル ５．０
ステアリルアルコール ２．０
ステアリン酸 ２．０
カルボキシビニルポリマー ０．３
トリエタノールアミン ０．８
メチルポリシロキサン ２．０
ポリオキシエチレンセチルエーテル（２０） ４．０
モノステアリン酸ソルビタン ２．０
ヒドロキシエタンジホスホン酸四ナトリウム ０．０３
精製水 ６４．８４
合計 １００．０
(Formulation example 1: hair wax)
High polymerization PEG (average degree of polymerization 90,000) 0.03
Propylene glycol 2.0
Microcrystalline wax 5.0
Carnavalou 5.0
Paraffin 5.0
Cetyl 2-ethylhexanoate 5.0
Stearyl alcohol 2.0
Stearic acid 2.0
Carboxyvinyl polymer 0.3
Triethanolamine 0.8
Methylpolysiloxane 2.0
Polyoxyethylene cetyl ether (20) 4.0
Sorbitan monostearate 2.0
Hydroxyethanediphosphonate tetrasodium 0.03
Purified water 64.84
Total 100.0
Claims (2)
（Ａ）平均重合度が１０，０００〜２００，０００である高重合ポリエチレングリコール、（Ｂ）ヒドロキシエタンジホスホン酸および／又はその塩、（Ｃ）水、（Ｄ）油剤、並びに（Ｅ）非イオン性界面活性剤を含有し、
乳化物であることを特徴とする頭髪用組成物。 Hair wax that is a hair styling agent,
(A) highly polymerized polyethylene glycol having an average degree of polymerization of 10,000 to 200,000, (B) hydroxyethanediphosphonic acid and / or a salt thereof, (C) water, (D) an oil agent, and (E) non Contains an ionic surfactant,
A composition for hair, which is an emulsion.
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| JP2001220334A (en) * | 2001-03-30 | 2001-08-14 | Sanei Kagaku Kk | Composition for formulating hair treatment preparation and hair treatment preparation |
| JP2007126415A (en) * | 2005-11-07 | 2007-05-24 | Shiseido Co Ltd | Hair-dyeing or bleaching agent composition |
| WO2008096497A1 (en) * | 2007-02-08 | 2008-08-14 | Arimino Co., Ltd. | Emulsion composition for preparation for application to hair |
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