JP5940369B2 - How to control plant diseases - Google Patents
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- JP5940369B2 JP5940369B2 JP2012108334A JP2012108334A JP5940369B2 JP 5940369 B2 JP5940369 B2 JP 5940369B2 JP 2012108334 A JP2012108334 A JP 2012108334A JP 2012108334 A JP2012108334 A JP 2012108334A JP 5940369 B2 JP5940369 B2 JP 5940369B2
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- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N45/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring
- A01N45/02—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring having three carbocyclic rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
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Description
本発明は、植物病害の防除効果を格段に向上させる農園芸用殺菌剤の組合せに関する。 The present invention relates to a combination of an agricultural and horticultural fungicide that significantly improves the effect of controlling plant diseases.
特許文献1には、本発明の有効成分であるベンゾイルピリジン誘導体が殺菌剤として有用であり、必要に応じて他の殺菌剤との混用・併用が可能であるとの記載がある。また、当該ベンゾイルピリジン誘導体と、プロクロラズ等(特許文献2)や、ジフェノコナゾール等(特許文献3)とを各々組み合わせたとき、優れた相乗効果をもつ殺菌剤組成物が得られることが記載されている。
しかしながら、3-(2,3,4-トリメトキシ-6-メチルベンゾイル)-5-クロロ-2-メトキシ-4-メチルピリジンと、プロクロラズと、更に特定の殺菌剤との3種類の殺菌剤を組み合わせて使用することに関する具体的記載はない。
Patent Document 1 describes that the benzoylpyridine derivative, which is an active ingredient of the present invention, is useful as a fungicide and can be used in combination with other fungicides as needed. Further, it is described that a fungicidal composition having an excellent synergistic effect can be obtained when the benzoylpyridine derivative is combined with prochloraz or the like (Patent Document 2) or difenoconazole or the like (Patent Document 3). .
However, combining three types of fungicides: 3- (2,3,4-trimethoxy-6-methylbenzoyl) -5-chloro-2-methoxy-4-methylpyridine, prochloraz, and a specific fungicide There is no specific description regarding use.
本発明の有効成分である、3-(2,3,4-トリメトキシ-6-メチルベンゾイル)-5-クロロ-2-メトキシ-4-メチルピリジン、プロクロラズ及び特定の殺菌剤は、特定の植物病害に対してその効果が十分でなかったり、残効性が比較的短かったり、特定の殺菌剤に対する耐性菌が出現したりして、ある施用場面では、植物病害に対し実用上、不十分な防除効果しか示さないこともある。
本発明の目的は、殺菌剤の組み合わせにより、植物病害防除効果が顕著に改善される植物病害の防除方法を提供することである。
The active ingredient of the present invention, 3- (2,3,4-trimethoxy-6-methylbenzoyl) -5-chloro-2-methoxy-4-methylpyridine, prochloraz and a specific fungicide are specific plant diseases In some applications, there are practically inadequate control of plant diseases, such as when the effect is not sufficient, the residual effect is relatively short, or resistant bacteria to specific fungicides appear. It may only show an effect.
An object of the present invention is to provide a method for controlling plant diseases in which the plant disease control effect is remarkably improved by the combination of fungicides.
本発明者らは、前述の問題点を解決すべく研究した結果、3-(2,3,4-トリメトキシ-6-メチルベンゾイル)-5-クロロ-2-メトキシ-4-メチルピリジンとプロクロラズとに、特定の殺菌剤を更に組み合わせることによって、各化合物を単独で使用した場合に比して、予想できないような優れた殺菌効果が得られることの知見を得、本発明を完成した。 As a result of studies to solve the above-mentioned problems, the present inventors have found that 3- (2,3,4-trimethoxy-6-methylbenzoyl) -5-chloro-2-methoxy-4-methylpyridine, prochloraz, In addition, by further combining specific fungicides, the inventors have obtained the knowledge that an unprecedented excellent bactericidal effect can be obtained as compared with the case where each compound is used alone, and the present invention has been completed.
すなわち、本発明は、
(a)3-(2,3,4-トリメトキシ-6-メチルベンゾイル)-5-クロロ-2-メトキシ-4-メチルピリジン(以下、単に成分(a)ともいう)と、
(b)プロクロラズ(以下、単に成分(b)ともいう)と、
(c)ステロール脱メチル化阻害剤(但し、プロクロラズを除く)、及び電子伝達系複合体II阻害剤からなる群から選択される少なくとも1種の殺菌剤(以下、単に成分(c)ともいう)とを、
組み合わせて、植物に施用することを特徴とする植物病害の防除方法に関する。
That is, the present invention
(A) 3- (2,3,4-trimethoxy-6-methylbenzoyl) -5-chloro-2-methoxy-4-methylpyridine (hereinafter also simply referred to as component (a));
(B) prochloraz (hereinafter also simply referred to as component (b));
(C) At least one fungicide selected from the group consisting of sterol demethylation inhibitors (excluding prochloraz) and electron transport complex II inhibitors (hereinafter also simply referred to as component (c)) And
The present invention relates to a method for controlling plant diseases characterized by being applied to plants in combination.
本発明の殺菌剤の組合せは、植物病害に対して安定した高い防除効果を有するので、本発明の方法は、植物病害の防除方法として有用である。 Since the combination of the fungicides of the present invention has a stable and high control effect against plant diseases, the method of the present invention is useful as a method for controlling plant diseases.
本発明の成分(a)である3-(2,3,4-トリメトキシ-6-メチルベンゾイル)-5-クロロ-2-メトキシ-4-メチルピリジンは、前記特許文献1及び特許文献2に開示された製造方法によって得ることができる。また、このものは、一般名ピリオフェノン(pyriofenone)として知られた化合物である。 The component (a) of the present invention, 3- (2,3,4-trimethoxy-6-methylbenzoyl) -5-chloro-2-methoxy-4-methylpyridine, is disclosed in Patent Document 1 and Patent Document 2 described above. It can be obtained by the manufactured method. This is also a compound known by the general name pyriofenone.
本発明の成分(b)であるプロクロラズ(prochloraz)は、The Pesticide Manual(第15版;BRITISH CROP PROTECTION COUNCIL)第928〜929頁に記載の化合物である。 The component (b), prochloraz, of the present invention is a compound described in The Pesticide Manual (15th edition; BRITISH CROP PROTECTION COUNCIL), pages 928-929.
本発明の成分(c)であるステロール脱メチル化阻害剤(但し、プロクロラズを除く)としては、
アザコナゾール(azaconazole)、ビテルタノール(bitertanol)、ブロムコナゾール(bromuconazole)、シプロコナゾール(cyproconazole)、ジフェノコナゾール(difenoconazole)、ジニコナゾール(diniconazole)、エポキシコナゾール(epoxiconazole)、エタコナゾール(etaconazole)、フェンブコナゾール(fenbuconazole)、フルキンコナゾール(fluquinconazole)、フルシラゾール(flusilazole)、フルトリアホール(flutriafol)、ファーコナゾールシス(furconazole‐cis)、ヘキサコナゾール(hexaconazole)、イミベンコナゾール(imibenconazole)、イプコナゾール(ipconazole)、メトコナゾール(metconazole)、ミクロブタニル(myclobutanil)、ペンコナゾール(penconazole)、プロピコナゾール(propiconazole)、プロチオコナゾール(prothioconazole)、シメコナゾール(simeconazole)、テブコナゾール(tebuconazole)、テトラコナゾール(tetraconazole)、トリアジメホン(triadimefon)、トリアジメノール(triadimenol)、トリチコナゾール(triticonazole)のようなトリアゾール系化合物;
ピリフェノックス(pyrifenox)のようなピリジン系化合物;
トリホリン(triforine)のようなピペラジン系化合物;
ヌアリモール(nuarimol)、フェナリモル(fenarimol)のようなピリミジン系化合物;
オキスポコナゾール(oxpoconazole)、イマザリル(imazalil)、トリフルミゾール(triflumizole)、ペフラゾエート(pefurazoate)のようなイミダゾール系化合物;
等が挙げられる。これらは、いずれも殺菌剤として、The Pesticide Manual(第15版;BRITISH CROP PROTECTION COUNCIL)や、SHIBUYA INDEX 15th edition(SHIBUYA INDEX RESEARCH GROUP)に記載されている化合物である。
これらの中でも、トリアゾール系化合物、イミダゾール系化合物が好ましい。より具体的には、シプロコナゾール、ジフェノコナゾール、エポキシコナゾール、フルキンコナゾール、フルシラゾール、ヘキサコナゾール、イミベンコナゾール、メトコナゾール、ペンコナゾール、プロピコナゾール、プロチオコナゾール、シメコナゾール、テブコナゾール、テトラコナゾール、トリアジメノール、オキスポコナゾール、トリフルミゾールが好ましく、シプロコナゾール、エポキシコナゾール、フルキンコナゾール、ヘキサコナゾール、メトコナゾール、プロピコナゾール、プロチオコナゾール、テブコナゾール、テトラコナゾールがより好ましい。
As the sterol demethylation inhibitor (excluding prochloraz) which is the component (c) of the present invention,
Azaconazole, bitertanol, bromuconazole, cyproconazole, difenoconazole, diiconazole, epiconconazole, etaconazole, fenbuconazole fenbuconazole, fluquinconazole, flusilazole, flutriafol, furconazole-cis, hexaconazole, imibenconazole, ipconazole , Metconazole, microbutanil, penconazole, propiconazole, prothioconazole, simeconazole, tebu Nazoru (Tebuconazole), Tetraconazole tetrazole (tetraconazole), triadimefon (triadimefon), triadimenol (triadimenol), triazole compounds such as triticonazole (triticonazole);
Pyridine compounds such as pyrifenox;
Piperazine compounds such as triforine;
Pyrimidine-based compounds such as nuarimol and fenarimol;
Imidazole compounds such as oxpoconazole, imazalil, triflumizole, pefurazoate;
Etc. These are compounds described in The Pesticide Manual (15th edition; BRITISH CROP PROTECTION COUNCIL) and SHIBUYA INDEX 15th edition (SHIBUYA INDEX RESEARCH GROUP) as fungicides.
Among these, triazole compounds and imidazole compounds are preferable. More specifically, cyproconazole, difenoconazole, epoxiconazole, fluquinconazole, flusilazole, hexaconazole, imibenconazole, metconazole, penconazole, propiconazole, prothioconazole, cimeconazole, tebuconazole, tetraconazole, Triazimenol, oxpoconazole, and triflumizole are preferable, and cyproconazole, epoxyconazole, fluquinconazole, hexaconazole, metconazole, propiconazole, prothioconazole, tebuconazole, and tetraconazole are more preferable.
本発明の成分(c)である電子伝達系複合体II阻害剤としては、
ペンチオピラド(penthiopyrad)、ペンフルフェン(penflufen)、フラメトピル(furametpyr)、ビキサフェン(bixafen)、イソピラザム(isopyrazam)、セダキサン(sedaxane)、フルキサピロキサド(fluxapyroxad)のようなピラゾールカルボキサミド系化合物;
ボスカリド(boscalid)のようなピリジンカルボキサミド系化合物;
チフルザミド(thifluzamide)のようなチアゾールカルボキサミド系化合物;
カルボキシン(carboxin)、オキシカルボキシン(oxycarboxin)のようなオキサチイン系化合物;
フルオピラム(fluopyram)のようなピリジニル−エチルベンズアミド系化合物;
フェンフラム(fenfuram)のようなフランカルボキサミド系化合物;
フルトラニル(flutolanil)、メプロニル(mepronil)、ベノダニル(benodanil)のようなフェニル−ベンズアミド系化合物;
等が挙げられる。これらは、いずれも殺菌剤として、The Pesticide Manual(第15版;BRITISH CROP PROTECTION COUNCIL)やSHIBUYA INDEX 15th edition (SHIBUYA INDEX RESEARCH GROUP)に記載されている化合物である。
これらの中でも、ピラゾールカルボキサミド系化合物、ピリジンカルボキサミド系化合物、ピリジニル−エチルベンズアミド系化合物が好ましい。より具体的には、ペンチオピラド、ペンフルフェン、ビキサフェン、イソピラザム、ボスカリド、セダキサン、フルキサピロキサド、フルオピラムが好ましい。
As the electron transport system complex II inhibitor which is the component (c) of the present invention,
Pyrazole carboxamide compounds such as penthiopyrad, penflufen, furametpyr, bixafen, isopyrazam, sedaxane, fluxapyroxad;
Pyridine carboxamide compounds such as boscalid;
Thiazole carboxamide compounds such as thifluzamide;
Oxathiin compounds such as carboxin and oxycarboxin;
Pyridinyl-ethylbenzamide compounds such as fluopyram;
A furan carboxamide compound such as fenfuram;
Phenyl-benzamide compounds such as flutolanil, mepronil, benodanil;
Etc. These are compounds described in The Pesticide Manual (15th edition; BRITISH CROP PROTECTION COUNCIL) and SHIBUYA INDEX 15th edition (SHIBUYA INDEX RESEARCH GROUP) as fungicides.
Among these, pyrazole carboxamide compounds, pyridine carboxamide compounds, and pyridinyl-ethylbenzamide compounds are preferable. More specifically, penthiopyrad, penflufen, bixaphene, isopyrazam, boscalid, sedaxane, floxapyroxad, and fluopyram are preferred.
成分(a)、成分(b)及び成分(c)は塩の形態であってもよい。塩としては、農業上許容されるものであればいずれのものでもよいが、例えばナトリウム塩、カリウム塩のようなアルカリ金属塩;マグネシウム塩、カルシウム塩のようなアルカリ土類金属塩;モノメチルアンモニウム塩、ジメチルアンモニウム塩、トリエチルアンモニウム塩のようなアンモニウム塩;塩酸塩、過塩素酸塩、硫酸塩、硝酸塩のような無機酸塩;酢酸塩、フマル酸、メタンスルホン酸塩のような有機酸塩などが挙げられる。 Component (a), component (b) and component (c) may be in the form of a salt. Any salt may be used as long as it is agriculturally acceptable. Examples thereof include alkali metal salts such as sodium salt and potassium salt; alkaline earth metal salts such as magnesium salt and calcium salt; monomethylammonium salt. Ammonium salts such as dimethylammonium salt and triethylammonium salt; inorganic acid salts such as hydrochloride, perchlorate, sulfate and nitrate; organic acid salts such as acetate, fumaric acid and methanesulfonate Is mentioned.
本発明の方法は、各種の植物病害の防除に有効であり、例えばイネのいもち病、ごま葉枯病、紋枯病;ムギ類のうどんこ病、赤かび病、さび病、雪腐病、裸黒穂病、眼紋病、葉枯病、ふ枯病;カンキツの黒点病、そうか病;リンゴのモニリア病、うどんこ病、斑点落葉病、黒星病;ナシの黒星病、黒斑病;モモの灰星病、黒星病、フォモプシス腐敗病;ブドウの黒とう病、晩腐病、うどんこ病、べと病;カキの炭そ病、落葉病;ウリ類の炭そ病、うどんこ病、つる枯病、べと病;トマトの輪紋病、葉かび病、疫病;アブラナ科野菜の黒斑病、バレイショの夏疫病、疫病;イチゴのうどんこ病;種々の作物の灰色かび病、菌核病等の植物病害の防除に有効であるが、特にムギ類の病害に優れた防除効果を示す。また、フザリウム菌、ピシウム菌、リゾクトニア菌、バーティシリウム菌、プラズモディオホーラ菌等の植物病原菌によって引き起こされる土壌病害の防除にも有効である。 The method of the present invention is effective for controlling various plant diseases such as rice blast, rice sesame leaf blight, coat blight; wheat powdery mildew, red mold, rust, snow rot, Bare smut, eye rot, leaf blight, dry blight; citrus sunspot disease, scab; apple monilia, powdery mildew, spotted leaf disease, black star disease; pear black star disease, black spot disease; Peach ash scab, black scab, fomoposis rot; Grape black rot, late rot, powdery mildew, mildew; oyster anthracnose, deciduous; cucurbit anthracnose, powdery mildew , Vine blight, downy mildew; tomato ringworm, leaf mold, plague; black crab of cruciferous vegetables, summer plague of potato, plague; strawberry powdery mildew; gray mold of various crops, Although it is effective for controlling plant diseases such as mycorrhizal diseases, it exhibits an excellent control effect especially for wheat diseases. It is also effective for controlling soil diseases caused by phytopathogenic fungi such as Fusarium, Psium, Rhizoctonia, Verticillium, and Plasmodiohora.
本発明の成分(a)、成分(b)及び成分(c)は、従来の農薬製剤と同様に、各種補助剤とを混合して粉剤、粒剤、顆粒水和剤、水和剤、水性懸濁剤、油性懸濁剤、水溶剤、乳剤、液剤、ペースト剤、エアゾール剤、微量散布剤等の種々の形態に製剤して使用されるが、本発明の目的に適合するかぎり、通常の当該分野で用いられているあらゆる製剤形態にすることができる。
製剤調製に際しては、成分(a)、成分(b)及び成分(c)を一緒に混合し製剤調製しても、或はこれらを別々に製剤調製してもよい。
The component (a), component (b) and component (c) of the present invention are mixed with various adjuvants in the same manner as conventional agricultural chemical preparations, and are powdered, granulated, granulated wettable powder, wettable powder, aqueous Used in various forms such as suspensions, oily suspensions, aqueous solvents, emulsions, solutions, pastes, aerosols, microdispersions, etc. Any formulation used in the art can be used.
In preparing the preparation, the component (a), the component (b) and the component (c) may be mixed together to prepare the preparation, or these may be prepared separately.
製剤に使用する補助剤としては、珪藻土、消石灰、炭酸カルシウム、タルク、ホワイトカーボン、カオリン、ベントナイト、カオリナイト及びセリサイトの混合物、クレー、炭酸ナトリウム、重曹、芒硝、ゼオライト、澱粉等の固型担体;水、トルエン、キシレン、ソルベントナフサ、ジオキサン、アセトン、イソホロン、メチルイソブチルケトン、クロロベンゼン、シクロヘキサン、ジメチルスルホキシド、ジメチルホルムアミド、ジメチルアセトアミド、N−メチル−2−ピロリドン、アルコール等の溶剤;脂肪酸塩、安息香酸塩、アルキルスルホコハク酸塩、ジアルキルスルホコハク酸塩、ポリカルボン酸塩、アルキル硫酸エステル塩、アルキル硫酸塩、アルキルアリール硫酸塩、アルキルジグリコールエーテル硫酸塩、アルコール硫酸エステル塩、アルキルスルホン酸塩、アルキルアリールスルホン酸塩、アリールスルホン酸塩、リグニンスルホン酸塩、アルキルジフェニルエーテルジスルホン酸塩、ポリスチレンスルホン酸塩、アルキルリン酸エステル塩、アルキルアリールリン酸塩、スチリルアリールリン酸塩、ポリオキシエチレンアルキルエーテル硫酸エステル塩、ポリオキシエチレンアルキルアリールエーテル硫酸塩、ポリオキシエチレンアルキルアリールエーテル硫酸エステル塩、ポリオキシエチレンアルキルエーテルリン酸塩、ポリオキシエチレンアルキルアリールリン酸エステル塩、ナフタレンスルホン酸ホルマリン縮合物の塩のような陰イオン系の界面活性剤や展着剤;ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル、脂肪酸ポリグリセライド、脂肪酸アルコールポリグリコールエーテル、アセチレングリコール、アセチレンアルコール、オキシアルキレンブロックポリマー、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルアリールエーテル、ポリオキシエチレンスチリルアリールエーテル、ポリオキシエチレングリコールアルキルエーテル、ポリオキシエチレン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、ポリオキシプロピレン脂肪酸エステルのような非イオン系の界面活性剤や展着剤;オリーブ油、カポック油、ひまし油、シュロ油、椿油、ヤシ油、ごま油、トウモロコシ油、米ぬか油、落花生油、綿実油、大豆油、菜種油、亜麻仁油、きり油、液状パラフィン等の植物油や鉱物油等が挙げられる。これら補助剤は本発明の目的から逸脱しないかぎり、当該分野で知られたものの中から選んで用いることができる。また、増量剤、増粘剤、沈降防止剤、凍結防止剤、分散安定剤、薬害軽減剤、防黴剤等通常使用される各種補助剤も使用することができる。有効成分化合物と各種補助剤との配合割合は、混合重量比が一般に0.005 : 99.995 〜95:5、望ましくは0.2:99.8 〜90:10である。これら製剤の実際の使用に際しては、そのまま使用するか、又は水等の希釈剤で所定濃度に希釈し、必要に応じて各種展着剤を添加して使用することができる。 Adjuvants used in the formulation include solid carriers such as diatomaceous earth, slaked lime, calcium carbonate, talc, white carbon, kaolin, bentonite, kaolinite and sericite, clay, sodium carbonate, sodium bicarbonate, sodium sulfate, zeolite, starch, etc. Solvent such as water, toluene, xylene, solvent naphtha, dioxane, acetone, isophorone, methyl isobutyl ketone, chlorobenzene, cyclohexane, dimethyl sulfoxide, dimethylformamide, dimethylacetamide, N-methyl-2-pyrrolidone, alcohol; fatty acid salt, benzoic acid Acid salt, alkyl sulfosuccinate, dialkyl sulfosuccinate, polycarboxylate, alkyl sulfate ester, alkyl sulfate, alkyl aryl sulfate, alkyl diglycol ether sulfate, alcohol sulfate Ester salt, alkyl sulfonate, alkyl aryl sulfonate, aryl sulfonate, lignin sulfonate, alkyl diphenyl ether disulfonate, polystyrene sulfonate, alkyl phosphate ester salt, alkyl aryl phosphate, styryl aryl phosphorus Acid salt, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl aryl ether sulfate, polyoxyethylene alkyl aryl ether sulfate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkyl aryl phosphate, Anionic surfactants and spreading agents such as naphthalene sulfonic acid formalin condensate salts; sorbitan fatty acid esters, glycerin fatty acid esters, fatty acid polyglycerides, Fatty acid alcohol polyglycol ether, acetylene glycol, acetylene alcohol, oxyalkylene block polymer, polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyoxyethylene styryl aryl ether, polyoxyethylene glycol alkyl ether, polyoxyethylene fatty acid ester , Nonionic surfactants and spreading agents such as polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxypropylene fatty acid ester; olive oil, kapok oil, castor oil, palm Oil, coconut oil, coconut oil, sesame oil, corn oil, rice bran oil, peanut oil, cottonseed oil, soybean oil, rapeseed oil, linseed oil, persimmon oil, liquid paraffin Examples include vegetable oils such as fins and mineral oils. These adjuvants can be selected from those known in the art without departing from the object of the present invention. In addition, various commonly used adjuvants such as extenders, thickeners, anti-settling agents, antifreezing agents, dispersion stabilizers, safeners, and antifungal agents can also be used. The mixing ratio of the active ingredient compound and various adjuvants is generally 0.005: 99.995 to 95: 5, preferably 0.2: 99.8 to 90:10, as a mixing weight ratio. In actual use of these preparations, they can be used as they are, or diluted to a predetermined concentration with a diluent such as water, and various spreaders can be added as necessary.
また、本発明において、他の農薬、例えば殺菌剤、殺虫剤、殺ダニ剤、殺線虫剤、殺土壌害虫剤、抗ウイルス剤、誘引剤、除草剤、植物生長調製剤等をさらに併用することもでき、この場合には一層優れた効果を示すことがある。 In the present invention, other agricultural chemicals such as fungicides, insecticides, acaricides, nematicides, soil insecticides, antiviral agents, attractants, herbicides, plant growth preparations and the like are further used in combination. In this case, a better effect may be exhibited.
上記他の農薬中の、殺菌剤の有効成分化合物(一般名;一部申請中を含む、又は日本植物防疫協会試験コード)としては、例えば、
メパニピリム(mepanipyrim)、ピリメサニル(pyrimethanil)、シプロジニル(cyprodinil)のようなアニリノピリミジン系化合物;
5-クロロ-7-(4-メチルピペリジン-1-イル)-6-(2,4,6-トリフルオロフェニル)[1,2,4]トリアゾロ[1,5-a]ピリミジンのようなトリアゾロピリミジン系化合物;
フルアジナム(fluazinam)のようなピリジナミン系化合物;
トリシクラゾール(tricyclazole)、プロベナゾール(probenazole)のようなアゾール系化合物;
キノメチオネート(quinomethionate)のようなキノキサリン系化合物;
マンネブ(maneb)、ジネブ(zineb)、マンゼブ(mancozeb)、ポリカーバメート(polycarbamate)、メチラム(metiram)、プロピネブ(propineb)、チラム(thiram)のようなジチオカーバメート系化合物;
フサライド(fthalide)、クロロタロニル(chlorothalonil)、キントゼン(quintozene)のような有機塩素系化合物;
ベノミル(benomyl)、チオファネートメチル(thiophanate-methyl)、カーベンダジム(carbendazim)、チアベンダゾール(thiabendazole)、フベリアゾール(fuberiazole)、シアゾファミド(cyazofamid)のようなイミダゾール系化合物;
シモキサニル(cymoxanil)のようなシアノアセトアミド系化合物;
メタラキシル(metalaxyl)、メタラキシル−M(metalaxyl-M;別名メフェノキサム(mefenoxam))、オキサジキシル(oxadixyl)、オフレース(ofurace)、ベナラキシル(benalaxyl)、ベナラキシル−M(benalaxyl-M;別名キララキシル(kiralaxyl、chiralaxyl))、フララキシル(furalaxyl)、シプロフラム(cyprofuram)、
イソチアニル(isotianil)、チアジニル(tiadinil)のようなアニリド系化合物;
ジクロフルアニド(dichlofluanid)のようなスルファミド系化合物;
水酸化第二銅(cupric hydroxide)、有機銅(oxine copper)のような銅系化合物;
ヒメキサゾール(hymexazol)のようなイソキサゾール系化合物;
ホセチルアルミニウム(fosetyl-Al)、トルクロホスメチル(tolclofos-Methyl)、S−ベンジル O,O−ジイソプロピルホスホロチオエート、O−エチル S,S−ジフェニルホスホロジチオエート、アルミニウムエチルハイドロゲンホスホネート、エジフェンホス(edifenphos)、イプロベンホス(iprobenfos)のような有機リン系化合物;
キャプタン、(captan)、キャプタホル(captafol)、フォルペット(folpet)のようなフタルイミド系化合物;
プロシミドン(procymidone)、イプロジオン(iprodione)、ビンクロゾリン(vinclozolin)のようなジカルボキシイミド系化合物;
シルチオファム(silthiopham)、フェノキサニル(fenoxanil)のようなアミド系化合物;
ゾキサミド(zoxamide)のようなベンズアミド系化合物;
フェンプロピディン(fenpropidin)のようなピペリジン系化合物;
フェンプロピモルフ(fenpropimorph)、トリデモルフ(tridemorph)のようなモルフォリン系化合物;
フェンチンヒドロキシド(fentin hydroxide)、フェンチンアセテート(fentin acetate)のような有機スズ系化合物;
ペンシキュロン(pencycuron)のような尿素系化合物;
ジメトモルフ(dimethomorph)、フルモルフ(flumorph)のようなシンナミック酸系化合物;
ジエトフェンカルブ(diethofencarb)のようなフェニルカーバメート系化合物;
フルジオキソニル(fludioxonil)、フェンピクロニル(fenpiclonil)のようなシアノピロール系化合物;
アゾキシストロビン(azoxystrobin)、クレソキシムメチル(kresoxim-methyl)、メトミノストロビン(metominostrobin)、トリフロキシストロビン(trifloxystrobin)、ピコキシストロビン(picoxystrobin)、オリザストロビン(oryzastrobin)、ジモキシストロビン(dimoxystrobin)、ピラクロストロビン(pyraclostrobin)、フルオキサストロビン(fluoxastrobin)、エネストロブリン(Enestroburin)、ピラオキシストロビン(Pyraoxystrobin)、ピラメトストロビン(Pyrametostrobin)のようなストロビルリン系化合物;
ファモキサドン(famoxadone)のようなオキサゾリジノン系化合物;
エタボキサム(ethaboxam)のようなチアゾールカルボキサミド系化合物;
イプロバリカルブ(iprovalicarb)、ベンチアバリカルブ−イソプロピル(benthiavalicarb-isopropyl)のようなバリンアミド系化合物;
メチル N-(イソプロポキシカルボニル)-L-バリル-(3RS)-3-(4-クロロフェニル)-β-アラニナート(valiphenalate)のようなアシルアミノアシッド系化合物;
フェナミドン(fenamidone)のようなイミダゾリノン系化合物;
フェンヘキサミド(fenhexamid)のようなハイドロキシアニリド系化合物;
フルスルファミド(flusulfamide)のようなベンゼンスルホンアミド系化合物;
シフルフェナミド(cyflufenamid)のようなオキシムエーテル系化合物;
アントラキノン系化合物;
クロトン酸系化合物;
バリダマイシン(validamycin)、カスガマイシン(kasugamycin)、ポリオキシン(polyoxins)のような抗生物質;
イミノクタジン(iminoctadine)、ドディン(dodine)のようなグアニジン系化合物;
テブフロキン(tebufloquin)のようなキノリン系化合物;
フルチアニル(flutianil)のようなチアゾリジン系化合物;
硫黄(Sulfur)のような硫黄系化合物;
その他の化合物として、ピリベンカルブ(pyribencarb)、イソプロチオラン(isoprothiolane)、ピロキロン(pyroquilon)、ジクロメジン(diclomezine)、キノキシフェン(quinoxyfen)、プロパモカルブ塩酸塩(propamocarb hydrochloride)クロルピクリン(chloropicrin)、ダゾメット(dazomet)、メタムナトリウム塩(metam-sodium)、メトラフェノン(metrafenone)、UBF-307、ジクロシメット(diclocymet)、プロキンアジド(proquinazid)、アミスルブロム(amisulbrom;別名アミブロドール(amibromdole))、マンジプロパミド(mandipropamid)、フルオピコリド(fluopicolide)、カルプロパミド(carpropamid)、メプチルジノキャップ(meptyldinocap)、N-[(3', 4'-ジクロロ-1,1-ジメチル)フェナシル]-3-トリフルオロメチル-2-ピリジンカルボキサミド、N-[(3', 4'-ジクロロ-1,1-ジメチル)フェナシル]-3-メチル-2-チオフェンカルボキサミド、N-[(3', 4'-ジクロロ-1,1-ジメチル)フェナシル]−1-メチル-3-トリフルオロメチル-4-ピラゾールカルボキサミド、N-[[2'-メチル-4'-(2-プロピルオキシ)-1,1-ジメチル]フェナシル]-3-トリフルオロメチル-2-ピリジンカルボキサミド、N-[[2'-メチル-4'-(2-プロピルオキシ)-1,1-ジメチル]フェナシル]-3-メチル-2-チオフェンカルボキサミド、N-[[2'-メチル-4'-(2-プロピルオキシ)-1,1-ジメチル]フェナシル]-1-メチル-3-トリフルオロメチル-4-ピラゾールカルボキサミド、N-[[4'-(2-プロピルオキシ)-1,1-ジメチル]フェナシル]-3-トリフルオロメチル-2-ピリジンカルボキサミド、N-[[4'-(2-プロピルオキシ)-1,1-ジメチル]フェナシル]-3-メチル-2-チオフェンカルボキサミド、N-[[4'-(2-プロピルオキシ)-1,1-ジメチル]フェナシル]−1-メチル-3-トリフルオロメチル-4-ピラゾールカルボキサミド、N-[[2'-メチル−4'-(2-ペンチルオキシ)-1,1-ジメチル]フェナシル]-3-トリフルオロメチル-2-ピリジンカルボキサミド、N-[[4'-(2-ペンチルオキシ)-1,1-ジメチル]フェナシル]-3-トリフルオロメチル-2-ピリジンカルボキサミド、フェリムゾン(ferimzone)、スピロキサミン(spiroxamine)、フェンピラザミン(fenpyrazamine)、アメトクトラジン(ametoctradin)、S-2200、ZF-9646、BCM-061、BCM-062等が挙げられる。
In the above-mentioned other agricultural chemicals, as an active ingredient compound of a bactericide (generic name; including some pending applications or Japan Plant Protection Association test code), for example,
Anilinopyrimidine compounds such as mepanipyrim, pyrimethanil, cyprodinil;
Tria such as 5-chloro-7- (4-methylpiperidin-1-yl) -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidine Zolopyrimidine compounds;
Pyridinamine compounds such as fluazinam;
Azole compounds such as tricyclazole and probenazole;
Quinoxaline compounds such as quinomethionate;
Dithiocarbamate compounds such as maneb, zineb, mancozeb, polycarbamate, metiram, propineb, thiram;
Organochlorine compounds such as fthalide, chlorothalonil, quintozene;
Imidazole compounds such as benomyl, thiophanate-methyl, carbendazim, thiabendazole, fuberiazole, cyazofamid;
Cyanoacetamide compounds such as cymoxanil;
Metalaxyl, metalaxyl-M (also known as mefenoxam), oxadixyl, offurace, benalaxyl, benalaxyl-M; also known as kiralaylyl )), Flaxaxyl, cyprofuram,
Anilide compounds such as isotianil, tiadinil;
Sulfamide-type compounds such as dichlofluanid;
Copper-based compounds such as cupric hydroxide and oxine copper;
Isoxazole compounds such as hymexazol;
Fosetyl aluminum (fosetyl-Al), tolclofos-Methyl, S-benzyl O, O-diisopropyl phosphorothioate, O-ethyl S, S-diphenyl phosphorodithioate, aluminum ethyl hydrogen phosphonate, edifenphos, iprobenphos Organophosphorus compounds such as (iprobenfos);
Phthalimide compounds such as captan, captafol, folpet;
Dicarboximide compounds such as procymidone, iprodione, vinclozolin;
Amide compounds such as silthiopham and fenoxanil;
Benzamide compounds such as zoxamide;
Piperidine compounds such as fenpropidin;
Morpholine compounds such as fenpropimorph and tridemorph;
Organotin compounds such as fentin hydroxide and fentin acetate;
Urea-based compounds such as pencycuron;
Synamic acid compounds such as dimethomorph, flumorph;
Phenyl carbamate compounds such as dietofencarb;
Cyanopyrrole compounds such as fludioxonil and fenpiclonil;
Azoxystrobin, kresoxim-methyl, metominostrobin, trifloxystrobin, picoxystrobin, oryzastrobin, dimoxystrobin ( strobilurin-based compounds such as dimoxystrobin, pyraclostrobin, fluoxastrobin, enestroburin, pyroxystrobin, pyrametostrobin;
Oxazolidinone compounds such as famoxadone;
Thiazole carboxamide compounds such as ethaboxam;
Valinamide compounds such as iprovalicarb, benchthiavalicarb-isopropyl;
Acylamino acid compounds such as methyl N- (isopropoxycarbonyl) -L-valyl- (3RS) -3- (4-chlorophenyl) -β-valaniphenate;
Imidazolinone compounds such as fenamidone;
Hydroxyanilide compounds such as fenhexamid;
Benzenesulfonamide compounds such as flusulfamide;
Oxime ether compounds such as cyflufenamid;
Anthraquinone compounds;
Crotonic acid compounds;
Antibiotics such as validamycin, kasugamycin, polyoxins;
Guanidine compounds such as iminoctadine and dodine;
Quinoline compounds such as tebufloquin;
Thiazolidine compounds such as flutianil;
Sulfur-based compounds such as sulfur;
Other compounds include pyribencarb, isoprothiolane, pyroquilon, diclomezine, quinoxyfen, propamocarb hydrochloride, chloropicrin, dazomet, and sodium metam Metam-sodium, metrafenone, UBF-307, diclocymet, proquinazid, amisulbrom (aka amibromdole), mandipropamid, fluopicolide, fluopicolide ), Meptyldinocap, N-[(3 ', 4'-dichloro-1,1-dimethyl) phenacyl] -3-trifluoromethyl-2-pyridinecarboxamide, N-[(3', 4 '-Dichloro-1,1-dimethyl) phenacyl] -3-me Tyl-2-thiophenecarboxamide, N-[(3 ', 4'-dichloro-1,1-dimethyl) phenacyl] -1-methyl-3-trifluoromethyl-4-pyrazolecarboxamide, N-[[2'- Methyl-4 '-(2-propyloxy) -1,1-dimethyl] phenacyl] -3-trifluoromethyl-2-pyridinecarboxamide, N-[[2'-methyl-4'-(2-propyloxy) -1,1-dimethyl] phenacyl] -3-methyl-2-thiophenecarboxamide, N-[[2'-methyl-4 '-(2-propyloxy) -1,1-dimethyl] phenacyl] -1-methyl -3-trifluoromethyl-4-pyrazolecarboxamide, N-[[4 '-(2-propyloxy) -1,1-dimethyl] phenacyl] -3-trifluoromethyl-2-pyridinecarboxamide, N-[[ 4 '-(2-propyloxy) -1,1-dimethyl] phenacyl] -3-methyl-2-thiophenecarboxamide, N-[[4'-(2-propyloxy) -1,1-dimethyl] phenacyl] -1-methyl-3-trifluorome Ru-4-pyrazolecarboxamide, N-[[2'-methyl-4 '-(2-pentyloxy) -1,1-dimethyl] phenacyl] -3-trifluoromethyl-2-pyridinecarboxamide, N-[[ 4 '-(2-pentyloxy) -1,1-dimethyl] phenacyl] -3-trifluoromethyl-2-pyridinecarboxamide, ferimzone, spiroxamine, fenpyrazamine, amethoctrazine (ametoctradin), S-2200, ZF-9646, BCM-061, BCM-062 and the like.
上記他の農薬中の、殺虫剤、殺ダニ剤、殺線虫剤或いは殺土壌害虫剤、すなわち殺害虫剤の有効成分化合物(一般名;一部申請中を含む、又は日本植物防疫協会試験コード)としては、例えば、
プロフェノホス(profenofos)、ジクロルボス(dichlorvos)、フェナミホス(fenamiphos)、フェニトロチオン(fenitrothion)、EPN、ダイアジノン(diazinon)、クロルピリホス(chlorpyrifos)、クロルピリホスメチル(chlorpyrifos-methyl)、アセフェート(acephate)、プロチオホス(prothiofos)、ホスチアゼート(fosthiazate)、カズサホス(cadusafos)、ジスルホトン(dislufoton)、イソキサチオン(isoxathion)、イソフェンホス(isofenphos)、エチオン(ethion)、エトリムホス(etrimfos)、キナルホス(quinalphos)、ジメチルビンホス(dimethylvinphos)、ジメトエート(dimethoate)、スルプロホス(sulprofos)、チオメトン(thiometon)、バミドチオン(vamidothion)、ピラクロホス(pyraclofos)、ピリダフェンチオン(pyridaphenthion)、ピリミホスメチル(pirimiphos-methyl)、プロパホス(propaphos)、ホサロン(phosalone)、ホルモチオン(formothion)、マラチオン(malathion)、テトラクロルビンホス(tetrachlorvinphos)、クロルフェンビンホス(chlorfenvinphos)、シアノホス(cyanophos)、トリクロルホン(trichlorfon)、メチダチオン(methidathion)、フェントエート(phenthoate)、ESP、アジンホスメチル(azinphos-methyl)、フェンチオン(fenthion)、ヘプテノホス(heptenophos)、メトキシクロル(methoxychlor)、パラチオン(parathion)、ホスホカルブ(phosphocarb)、デメトン-S-メチル(demeton-S-methyl)、モノクロトホス(monocrotophos)、メタミドホス(methamidophos)、イミシアホス(imicyafos)、パラチオン-メチル(parathion-methyl)、テルブホス(terbufos)、ホスファミドン(phosphamidon)、ホスメット(phosmet)、ホレート(phorate)のような有機リン酸エステル系化合物;
カルバリル(carbaryl)、プロポキスル(propoxur)、アルジカルブ(aldicarb)、カルボフラン(carbofuran)、チオジカルブ(thiodicarb)、メソミル(methomyl)、オキサミル(oxamyl)、エチオフェンカルブ(ethiofencarb)、ピリミカルブ(pirimicarb)、フェノブカルブ(fenobucarb)、カルボスルファン(carbosulfan)、ベンフラカルブ(benfuracarb)、ベンダイオカルブ(bendiocarb)、フラチオカルブ(furathiocab)、イソプロカルブ(isoprocarb)、メトルカルブ(metolcarb)、キシリルカルブ(xylylcarb)、XMC、フェノチオカルブ(fenothiocarb)のようなカーバメート系化合物;
カルタップ(cartap)、チオシクラム(thiocyclam)、ベンスルタップ(bensultap)、チオスルタップナトリウム(thiosultap-sodium)のようなネライストキシン誘導体;
ジコホル(dicofol)、テトラジホン(tetradifon)、エンドスルファン(endosulfan)、ジエノクロル(dienochlor)、ディルドリン(dieldrin)のような有機塩素系化合物;
酸化フェンブタスズ(fenbutatin oxide)、シヘキサチン(cyhexatin)のような有機金属系化合物;
フェンバレレート(fenvalerate)、ペルメトリン(permethrin)、シペルメトリン(cypermethrin)、デルタメトリン(deltamethrin)、シハロトリン(cyhalothrin)、テフルトリン(tefluthrin)、エトフェンプロックス(ethofenprox)、フルフェンプロックス(flufenprox)、シフルトリン(cyfluthrin)、フェンプロパトリン(fenpropathrin)、フルシトリネート(flucythrinate)、フルバリネート(fluvalinate)、シクロプロトリン(cycloprothrin)、ラムダシハロトリン(lambda-cyhalothrin)、ピレスリン(pyrethrins)、エスフェンバレレート(esfenvalerate)、テトラメスリン(tetramethrin)、レスメスリン(resmethrin)、プロトリフェンブト(protrifenbute)、ビフェントリン(bifenthrin)、ゼータシペルメトリン(zeta-cypermethrin)、アクリナトリン(acrinathrin)、アルファシペルメトリン(alpha-cypermethrin)、アレスリン(allethrin)、ガンマシハロトリン(gamma-cyhalothrin)、シータシペルメトリン(theta-cypermethrin)、タウフルバリネート(tau-fluvalinate)、トラロメスリン(tralomethrin)、プロフルスリン(profluthrin)、ベータシペルメトリン(beta-cypermethrin)、ベータシフルトリン(beta-cyfluthrin)、メトフルトリン(metofluthrin)、フェノトリン(phenothrin)、フルメトリン(flumethrin)のようなピレスロイド系化合物;
ジフルベンズロン(diflubenzuron)、クロルフルアズロン(chlorfluazuron)、テフルベンズロン(teflubenzuron)、フルフェノクスロン(flufenoxuron)、トリフルムロン(triflumuron)、ヘキサフルムロン(hexaflumuron)、ルフェヌロン(lufenuron)、ノバルロン(novaluron)、ノビフルムロン(noviflumuron)、ビストリフルロン(bistrifluron)、フルアズロン(fluazuron)のようなベンゾイルウレア系化合物;
メトプレン(methoprene)、ピリプロキシフェン(pyriproxyfen)、フェノキシカルブ(fenoxycarb)、ジオフェノラン(diofenolan)のような幼若ホルモン様化合物;
ピリダベン(pyridaben)のようなピリダジノン系化合物;
フェンピロキシメート(fenpyroximate)、フィプロニル(fipronil)、テブフェンピラド(tebufenpyrad)、エチピロール(ethiprole)、トルフェンピラド(tolfenpyrad)、アセトプロール(acetoprole)、ピラフルプロール(pyrafluprole)、ピリプロール(pyriprole)のようなピラゾール系化合物;
イミダクロプリド(imidacloprid)、ニテンピラム(nitenpyram)、アセタミプリド(acetamiprid)、チアクロプリド(thiacloprid)、チアメトキサム(thiamethoxam)、クロチアニジン(clothianidin)、ニジノテフラン(nidinotefuran)、ジノテフラン(dinotefuran)、ニチアジン(nithiazine)等のようなネオニコチノイド;
テブフェノジド(tebufenozide)、メトキシフェノジド(methoxyfenozide)、クロマフェノジド(chromafenozide)、ハロフェノジド(halofenozide)等のようなヒドラジン系化合物;
フロニカミド(flonicamid)等のようなピリジン系化合物;
スピロディクロフェン(spirodiclofen)等のようなテトロニック酸系化合物;
フルアクリピリム(fluacrypyrim)等のようなストロビルリン系化合物;
フルフェネリム(flufenerim)等のようなピリミジナミン系化合物;
ジニトロ系化合物;
有機硫黄化合物;
尿素系化合物;
トリアジン系化合物;
ヒドラゾン系化合物;
また、その他の化合物として、ブプロフェジン(buprofezin)、ヘキシチアゾクス(hexythiazox)、アミトラズ(amitraz)、クロルジメホルム(chlordimeform)、シラフルオフェン(silafluofen)、トリアザメイト(triazamate)、ピメトロジン(pymetrozine)、ピリミジフェン(pyrimidifen)、クロルフェナピル(chlorfenapyr)、インドキサカルブ(indoxacarb)、アセキノシル(acequinocyl)、エトキサゾール(etoxazole)、シロマジン(cyromazine)、1,3−ジクロロプロペン(1,3-dichloropropene)、ジアフェンチウロン(diafenthiuron)、ベンクロチアズ(benclothiaz)、ビフェナゼート(bifenazate)、スピロメシフェン(spiromesifen)、スピロテトラマット(spirotetramat)、プロパルギット(propargite)、クロフェンテジン(clofentezine)、メタフルミゾン(metaflumizone)、フルベンジアミド(flubendiamide)、シフルメトフェン(cyflumetofen)、クロラントラニリプロール(chlorantraniliprole)、シエノピラフェン(cyenopyrafen)、ピリフルキナゾン(pyrifluquinazone)、フェナザキン(fenazaquin)、アミドフルメット(amidoflumet)、クロロベンゾエート(chlorobenzoate)、スルフルアミド(sulfluramid)、ヒドラメチルノン(hydramethylnon)、メタアルデヒド(metaldehyde)、HGW-86、AKD‐1022、リアノジン(ryanodine)、ピリダリル(pyridalyl)、ベルブチン(verbutin)のような化合物;などが挙げられる。更に、Bacillus thuringiensis aizawai、Bacillus thuringiensis kurstaki、Bacillus thuringiensis israelensis、Bacillus thuringiensis japonensis、Bacillus thuringiensis tenebrionis、Bacillus thuringiensisが生成する結晶タンパク毒素、昆虫病原ウイルス剤、昆虫病原糸状菌剤、線虫病原糸状菌剤などのような微生物農薬;アベルメクチン(avermectin)、エマメクチンベンゾエート(emamectin Benzoate)、ミルベメクチン(milbemectin)、ミルベマイシン(milbemycin)、スピノサッド(spinosad)、イベルメクチン(ivermectin)、レピメクチン(lepimectin)、DE−175、アバメクチン(abamectin)、エマメクチン(emamectin)、スピネトラム(spinetoram)のような抗生物質及び半合成抗生物質;アザディラクチン(azadirachtin)、ロテノン(rotenone)のような天然物;ディート(deet)のような忌避剤;などと混用、併用することもできる。
Insecticides, acaricides, nematicides or soil pesticides in the above-mentioned other pesticides, that is, active ingredient compounds of pesticides (generic name; including some pending applications or Japan Plant Protection Association test code) ), For example,
Profenofos, dichlorvos, fenamiphos, fenitrothion, EPN, diazinon, chlorpyrifos, chlorpyrifos-methyl, acephate, prothiophos, prothiophos Fosthiazate, cadusafos, dislufoton, isoxathion, isofenphos, ethion, etrimfos, quinalphos, dimethylvinphos, dimethoate ), Sulprofos, thiometon, bamidothion, pyraclofos, pyridaphenthion, pirimiphos-methyl, propaphos, phosalone, Lumothione, malathion, tetrachlorvinphos, chlorfenvinphos, cyanophos, trichlorfon, methidathion, phenthoate, ESP, azinephosmethyl ( azinphos-methyl, fenthion, heptenophos, methoxychlor, parathion, phosphocarb, demeton-S-methyl, monocrotophos, methamidophos Organophosphate compounds such as (methamidophos), imimifafos, parathion-methyl, terbufos, phosphamidon, phosmet, phorate;
Carbaryl, propoxur, aldicarb, carbofuran, thiodicarb, methomyl, oxamyl, ethiofencarb, pirimicarb, fenobucarb, fenobucarb Carbamates such as carbosulfan, benfuracarb, bendiocarb, furathiocab, isoprocarb, metolcarb, xylylcarb, XMC, fenothiocarb Compound;
Nereistoxin derivatives such as cartap, thiocyclam, bensultap, sodium thiosultap-sodium;
Organochlorine compounds such as dicophor, tetradifon, endosulfan, dienochlor, dieldrin;
Organometallic compounds such as fenbutatin oxide and cyhexatin;
Fenvalerate, permethrin, cypermethrin, deltamethrin, cyhalothrin, tefluthrin, etofenprox, flufenprox, cyfluthrin , Fenpropathrin, flucytrinate, fluvalinate, cycloprothrin, lambda-cyhalothrin, pyrethrin, esfenvalerate, Tetramethrin, resmethrin, protrifenbute, bifenthrin, zeta-cypermethrin, acrinathrin, alpha-cypermeline (alpha-cyperme) thrin), allethrin, gamma-cyhalothrin, theta-cypermethrin, tau-fluvalinate, tralomethrin, profluthrin, beta-cypermethrin ( pyrethroid compounds such as beta-cypermethrin), beta-cyfluthrin, mettofluthrin, phenothrin, flumethrin;
Diflubenzuron, chlorfluazuron, teflubenzuron, flufenoxuron, triflumuron, hexaflumuron, lufenuron, novaluron, novaluron, ), Bistrifluron, benzoylurea compounds such as fluazuron;
Juvenile hormone-like compounds such as metoprene, pyriproxyfen, fenoxycarb, diofenolan;
Pyridazinone compounds such as pyridaben;
Pyrazole compounds such as fenpyroximate, fipronil, tebufenpyrad, ethiprole, tolfenpyrad, acetoprole, pyrafluprole, pyriprole;
Imidacloprid, nitenpyram, acetamiprid, thiacloprid, thiamethoxam, clothianidin, nidinotefuran, dinotefuranit, dinotefurannit, dinotefurannit Nicotinoids;
Hydrazine compounds such as tebufenozide, methoxyfenozide, chromafenozide, halofenozide and the like;
Pyridine compounds such as flonicamid;
Tetronic acid compounds such as spirodiclofen;
Strobilurin-based compounds such as fluacrypyrim;
Pyrimidinamine compounds such as flufenerim;
Dinitro compounds;
Organic sulfur compounds;
Urea compounds;
Triazine compounds;
Hydrazone compounds;
Other compounds include buprofezin, hexythiazox, amitraz, chlordimeform, silafluofen, triazamate, pymetrozine, pyrimidifen, and pyrimidifen. ), Indoxacarb, acequinocyl, etoxazole, cyromazine, 1,3-dichloropropene, diafenthiuron, benclothiaz , Bifenazate, spiromesifen, spirotetramat, propargite, clofentezine, metaflumizone, fulvenge Flubendiamide, cyflumetofen, chlorantraniliprole, cyenopyrafen, pyrifluquinazone, phenazaquin, amidoflumet, chlorobenzoate lu, chlorobenzoate lu , Hydramethylnon, metaldehyde, HGW-86, AKD-1022, ryanodine, pyridalyl, and compounds such as verbutin; Furthermore, Bacillus thuringiensis aizawai, Bacillus thuringiensis kurstaki, Bacillus thuringiensis israelensis, Bacillus thuringiensis japonensis, Bacillus thuringiensis tenebrionis, crystalline protein toxins produced by Bacillus thuringiensis, entomopathogenic fungi, nematode pathogenic fungi, etc. Microbial pesticides such as: avermectin, emamectin benzoate, milbemectin, milbemycin, spinosad, ivermectin, lepimectin, DE-175, abamectin ), Antibiotics such as emamectin, spinetoram and semi-synthetic antibiotics; natural products such as azadirachtin and rotenone; repellents such as deet; Mixed with, It is also possible to use.
本発明において、種々の施用方法を採用でき、対象植物、使用方法、製剤形態、施用量等の各種条件に応じて適宜使い分けることができるが、例えば以下のような方法が挙げられる。
(1)成分(a)、成分(b)及び成分(c)を別々に製剤調製したものを、そのまま、若しくは水等で所定濃度に希釈し、必要に応じて各種展着剤(界面活性剤、植物油、鉱物油など)を添加して、対象植物に施用する。
(2−1)成分(a)及び成分(b)を一緒に製剤調製したものと、成分(c)を製剤調製したものとを、そのまま、若しくは水等で所定濃度に希釈し、必要に応じて各種展着剤(界面活性剤、植物油、鉱物油など)を添加して、対象植物に施用する。
(2−2)成分(a)及び成分(c)を一緒に製剤調製したものと、成分(b)を製剤調製したものとを、そのまま、若しくは水等で所定濃度に希釈し、必要に応じて各種展着剤(界面活性剤、植物油、鉱物油など)を添加して、対象植物に施用する。
(2−3)成分(b)及び成分(c)を一緒に製剤調製したものと、成分(a)を製剤調製したものとを、そのまま、若しくは水等で所定濃度に希釈し、必要に応じて各種展着剤(界面活性剤、植物油、鉱物油など)を添加して、対象植物に施用する。
(3)成分(a)、成分(b)及び成分(c)を一緒に製剤調製したものを、そのまま、若しくは水等で所定濃度に希釈し、必要に応じて各種展着剤(界面活性剤、植物油、鉱物油など)を添加して、対象植物に施用する。
上記施用方法(1)及び(2−1)〜(2−3)において、対象植物への施用は、例えば、水等で所定濃度に希釈する時に混合して同時に施用してもよいし、或いは各々を連続して若しくは適切な間隔をあけて施用してもよい。本発明の効果をより効果的に発揮させるには、成分(a)、成分(b)及び成分(c)を同時に施用することが好ましい。
In the present invention, various application methods can be adopted, and can be appropriately selected according to various conditions such as the target plant, method of use, formulation form, application rate, etc. Examples include the following methods.
(1) Components (a), (b) and (c) prepared separately are diluted as they are or with water or the like to a predetermined concentration, and various spreading agents (surfactants) as required , Vegetable oil, mineral oil, etc.) are added to the target plant.
(2-1) The component (a) and the component (b) prepared together and the component (c) prepared are diluted as they are or with water to a predetermined concentration, as necessary. Apply various spreading agents (surfactant, vegetable oil, mineral oil, etc.) and apply to target plants.
(2-2) Components prepared together with component (a) and component (c) and those prepared with component (b) are diluted as they are or with water to a predetermined concentration. Apply various spreading agents (surfactant, vegetable oil, mineral oil, etc.) and apply to target plants.
(2-3) The preparation prepared together with the component (b) and the component (c) and the preparation prepared from the component (a) are diluted as they are or with water to a predetermined concentration. Apply various spreading agents (surfactant, vegetable oil, mineral oil, etc.) and apply to target plants.
(3) Components (a), (b) and (c) prepared together are diluted as they are or with water or the like to a predetermined concentration, and various spreading agents (surfactants as necessary) , Vegetable oil, mineral oil, etc.) are added to the target plant.
In the application methods (1) and (2-1) to (2-3), the application to the target plant may be mixed and applied simultaneously when diluted to a predetermined concentration with water or the like, or Each may be applied continuously or at appropriate intervals. In order to exhibit the effect of the present invention more effectively, it is preferable to apply the component (a), the component (b) and the component (c) at the same time.
本発明の成分(a)、成分(b)及び成分(c)の使用濃度は、対象植物、使用方法、製剤形態、施用量等の違いによって異なり、一概に規定できないが、茎葉処理の場合、成分(a)は好ましくは0.1〜2000ppm、より好ましくは0.4〜700ppmであり、成分(b)は好ましくは1〜5000ppm、より好ましくは、3〜3000ppmであり、成分(c)は好ましくは0.5〜2500ppm、より好ましくは0.8〜1500ppmである。土壌処理の場合には、成分(a)は好ましくは10〜500g/ha、より好ましくは30〜200g/haであり、成分(b)は好ましくは50〜2000g/ha、より好ましくは100〜1000g/haであり、成分(c)は好ましくは10〜2000g/ha、より好ましくは40〜1000g/haである。 The concentration of component (a), component (b), and component (c) used in the present invention varies depending on the target plant, method of use, formulation form, application rate, etc., and cannot be specified unconditionally. Component (a) is preferably 0.1 to 2000 ppm, more preferably 0.4 to 700 ppm, Component (b) is preferably 1 to 5000 ppm, more preferably 3 to 3000 ppm, and Component (c) is Preferably it is 0.5-2500 ppm, More preferably, it is 0.8-1500 ppm. In the case of soil treatment, component (a) is preferably 10 to 500 g / ha, more preferably 30 to 200 g / ha, and component (b) is preferably 50 to 2000 g / ha, more preferably 100 to 1000 g. The component (c) is preferably 10 to 2000 g / ha, more preferably 40 to 1000 g / ha.
成分(a)、成分(b)及び成分(c)の適当な混合重量比は、成分(a)1重量部に対して、成分(b)が好ましくは1〜100重量部、より好ましくは1〜50重量部、特に好ましくは1〜20重量部であり、成分(c)が、好ましくは0.1〜100重量部、より好ましくは0.1〜50重量部、特に好ましくは0.1〜20重量部である。 An appropriate mixing weight ratio of the component (a), the component (b) and the component (c) is preferably 1 to 100 parts by weight, more preferably 1 with respect to 1 part by weight of the component (a). To 50 parts by weight, particularly preferably 1 to 20 parts by weight, and the component (c) is preferably 0.1 to 100 parts by weight, more preferably 0.1 to 50 parts by weight, particularly preferably 0.1 to 20 parts by weight.
本発明における種々の製剤、又はその希釈物の施用は、通常一般に行なわれている施用方法、すなわち、散布(例えば散布、噴霧、ミスティング、アトマイジング、散粒、水面施用等)、土壌施用(混入、灌注等)、表面施用(塗布、粉衣、被覆等)等により行うことができる。また、いわゆる超高濃度少量散布法(ultra low volume)により施用することもできる。この方法においては、活性成分を100%含有することが可能である。 Application of various preparations or dilutions thereof according to the present invention is usually performed by commonly used application methods, that is, application (for example, application, spraying, misting, atomizing, dusting, water surface application, etc.), soil application ( Mixing, irrigation, etc.), surface application (application, powder coating, coating, etc.), etc. It can also be applied by the so-called ultra low volume application method (ultra low volume). In this method, it is possible to contain 100% of the active ingredient.
次に、本発明の望ましい態様を例示する。但し、本発明はこれらに限定されるものではない。 Next, preferred embodiments of the present invention will be exemplified. However, the present invention is not limited to these.
[1]成分(a)と、成分(b)と、成分(c)とを、植物に施用することを特徴とする植物病害の防除方法。
[2]成分(a)及び成分(b)を含有する組成物と、成分(c)とを、植物に施用することを特徴とする植物病害の防除方法。
[3]成分(a)及び成分(c)を含有する組成物と、成分(b)とを、植物に施用することを特徴とする植物病害の防除方法。
[4]成分(b)及び成分(c)を含有する組成物と、成分(a)とを、植物に施用することを特徴とする植物病害の防除方法。
[1] A method for controlling plant diseases, comprising applying the component (a), the component (b), and the component (c) to a plant.
[2] A method for controlling plant diseases, comprising applying the composition containing the components (a) and (b) and the component (c) to a plant.
[3] A method for controlling plant diseases, comprising applying the composition containing the components (a) and (c) and the component (b) to a plant.
[4] A method for controlling plant diseases, comprising applying the composition containing the component (b) and the component (c) and the component (a) to a plant.
[5]成分(c)のステロール脱メチル化阻害剤が、トリアゾール系化合物、ピリジン系化合物、ピペラジン系化合物、ピリミジン系化合物又はイミダゾール系化合物であり、電子伝達系複合体II阻害剤が、ピラゾールカルボキサミド系化合物、ピリジンカルボキサミド系化合物、チアゾールカルボキサミド系化合物、オキサチイン系化合物、ピリジニル−エチルベンズアミド系化合物、フランカルボキサミド系化合物又はフェニル−ベンズアミド系化合物である、上記[1]〜[4]のいずれかの防除方法。
[6]成分(c)のステロール脱メチル化阻害剤が、トリアゾール系化合物又はイミダゾール系化合物であり、電子伝達系複合体II阻害剤が、ピラゾールカルボキサミド系化合物、ピリジンカルボキサミド系化合物又はピリジニル−エチルベンズアミド系化合物である、上記[1]〜[4]のいずれかの防除方法。
[7]成分(c)が、シプロコナゾール、ジフェノコナゾール、エポキシコナゾール、フルキンコナゾール、フルシラゾール、ヘキサコナゾール、イミベンコナゾール、メトコナゾール、ペンコナゾール、プロピコナゾール、プロチオコナゾール、シメコナゾール、テブコナゾール、テトラコナゾール、トリアジメノール、オキスポコナゾール、トリフルミゾール、ペンチオピラド、ペンフルフェン、ビキサフェン、イソピラザム、ボスカリド、セダキサン、フルキサピロキサド及びフルオピラムからなる群から選択される少なくとも1種である、上記[1]〜[4]のいずれかの防除方法。
[8]成分(c)が、シプロコナゾール、エポキシコナゾール、フルキンコナゾール、ヘキサコナゾール、メトコナゾール、プロピコナゾール、プロチオコナゾール、テブコナゾール、テトラコナゾール、トリアジメノール、オキスポコナゾール、ペンチオピラド、ボスカリド、セダキサン、フルキサピロキサド及びフルオピラムからなる群から選択される少なくとも1種である、上記[1]〜[4]のいずれかの防除方法。
[5] The sterol demethylation inhibitor of component (c) is a triazole compound, a pyridine compound, a piperazine compound, a pyrimidine compound or an imidazole compound, and the electron transport complex II inhibitor is a pyrazole carboxamide Control of any one of the above-mentioned [1] to [4], which is a benzene compound, a pyridinecarboxamide compound, a thiazolecarboxamide compound, an oxathiin compound, a pyridinyl-ethylbenzamide compound, a furancarboxamide compound, or a phenyl-benzamide compound Method.
[6] The sterol demethylation inhibitor of component (c) is a triazole compound or an imidazole compound, and the electron transport complex II inhibitor is a pyrazole carboxamide compound, a pyridine carboxamide compound, or pyridinyl-ethylbenzamide. The control method in any one of said [1]-[4] which is a system compound.
[7] The component (c) is cyproconazole, difenoconazole, epoxiconazole, fluquinconazole, flusilazole, hexaconazole, imibenconazole, metconazole, penconazole, propiconazole, prothioconazole, cimeconazole, tebuconazole, tetra [1] ] The control method in any one of [4].
[8] The component (c) is cyproconazole, epoxiconazole, fluquinconazole, hexaconazole, metconazole, propiconazole, prothioconazole, tebuconazole, tetraconazole, triazimenol, oxpoconazole, The control method according to any one of the above [1] to [4], which is at least one selected from the group consisting of penthiopyrad, boscalid, sedaxane, floxapyroxad and fluopyram.
[9]成分(a)1重量部に対して、成分(b)を1〜100重量部、成分(c)を0.1〜100重量部の混合重量比で施用する、上記[1]〜[8]のいずれかの防除方法。
[10]成分(a)、成分(b)及び成分(c)を、同時に植物に施用する、上記[1]〜[9]のいずれかの防除方法。
[11]ムギ類の病害の防除方法である、上記[1]〜[10]のいずれかの防除方法。
[9] The above [1] to [1], wherein 1 to 100 parts by weight of component (a) is applied in a mixing weight ratio of 1 to 100 parts by weight of component (b) and 0.1 to 100 parts by weight of component (c). The control method according to any one of [8].
[10] The control method according to any one of the above [1] to [9], wherein the component (a), the component (b) and the component (c) are simultaneously applied to a plant.
[11] The control method according to any one of [1] to [10], which is a method for controlling a disease of wheat.
また、本発明は、殺菌剤組成物や殺菌剤の組み合わせの使用も包含する。このような場合の望ましい態様を例示する。但し、本発明はこれらに限定されるものではない。
[12]成分(a)、成分(b)及び成分(c)を含有する殺菌剤組成物。
[13]成分(c)と組み合わせて使用するための、成分(a)及び成分(b)を含有する殺菌剤組成物。
[14]成分(b)と組み合わせて使用するための、成分(a)及び成分(c)を含有する殺菌剤組成物。
[15]成分(a)と組み合わせて使用するための、成分(b)及び成分(c)を含有する殺菌剤組成物。
The invention also encompasses the use of a fungicide composition or a combination of fungicides. A desirable mode in such a case will be exemplified. However, the present invention is not limited to these.
[12] A bactericidal composition containing component (a), component (b) and component (c).
[13] A fungicidal composition containing component (a) and component (b) for use in combination with component (c).
[14] A bactericidal composition containing component (a) and component (c) for use in combination with component (b).
[15] A fungicidal composition containing component (b) and component (c) for use in combination with component (a).
[16]植物病害を防除するための、成分(a)と、成分(b)と、成分(c)との組み合わせの使用。
[17]植物病害を防除するための、成分(a)及び成分(b)を含有する組成物と、成分(c)との組み合わせの使用。
[18]植物病害を防除するための、成分(a)及び成分(c)を含有する組成物と、成分(b)との組み合わせの使用。
[19]植物病害を防除するための、成分(b)及び成分(c)を含有する組成物と、成分(a)との組み合わせの使用。
[16] Use of a combination of component (a), component (b) and component (c) for controlling plant diseases.
[17] Use of a combination of the composition containing the components (a) and (b) and the component (c) for controlling plant diseases.
[18] Use of a combination of the composition containing the components (a) and (c) and the component (b) for controlling plant diseases.
[19] Use of a combination of the composition containing the component (b) and the component (c) and the component (a) for controlling plant diseases.
次に本発明に係わる試験例を記載するが、これらは本発明を限定するものではない。 Next, although the test example concerning this invention is described, these do not limit this invention.
試験例1:コムギうどんこ病予防効果試験
直径7.5cmのポリ鉢でコムギ(品種:農林61号)を栽培し、1.5葉期に達した時に、各供試化合物を所定濃度に調整した薬液をスプレーガンにて5ml/苗散布した。薬液が乾燥した後、うどんこ病菌の分生胞子を振り掛け接種し、20℃の恒温室内に保った。接種6〜8日後に胞子形成面積を調査し、下記計算により防除価を求め、その結果を第1表〜第6表に示した。なお、無処理区の胞子形成面積は、薬液に代えて水をスプレーガンにて散布したこと以外は処理区と同様の操作を行うことによって求めた。
防除価=(1-a/b)×100
a:処理区の胞子形成面積、b:無処理区の胞子形成面積
下記のコルビーの式により、混用による理論値(防除価)を計算した。実験値が理論値よりも高い場合に、本発明殺菌剤組成物は、コムギうどんこ病に対し相乗効果を有する。こういった場合におけるコルビーの式による理論値を第1表〜第6表の( )内に併せ示した。
コルビーの式=(x+y+z)-(xy+xz+yz)/100+xyz/10000
x:成分(a)単用の防除価
y:成分(b)単用の防除価
z:成分(c)単用の防除価
Test Example 1: Wheat powdery mildew prevention effect test Wheat (variety: Norin 61) was cultivated in a 7.5cm diameter plastic pot, and when the 1.5 leaf stage was reached, each test compound was adjusted to a prescribed concentration. 5 ml / seedling was sprayed with a spray gun. After the chemical solution was dried, conidia of powdery mildew fungus were sprinkled and inoculated and kept in a constant temperature room at 20 ° C. The spore formation area was investigated 6 to 8 days after the inoculation, and the control value was determined by the following calculation. The results are shown in Tables 1 to 6. In addition, the spore formation area of an untreated area was calculated | required by performing operation similar to a treated area except having sprayed water with the spray gun instead of the chemical | medical solution.
Control value = (1-a / b) x 100
a: spore formation area in the treated area, b: spore formation area in the untreated area, the theoretical value (control value) by mixing was calculated according to the following Colby equation. When the experimental value is higher than the theoretical value, the fungicide composition of the present invention has a synergistic effect on wheat powdery mildew. The theoretical values according to the Colby equation in these cases are also shown in parentheses in Tables 1 to 6.
Colby's formula = (x + y + z)-(xy + xz + yz) / 100 + xyz / 10000
x: Control value of component (a) single use
y: Control value of component (b) single use
z: Control value of component (c) single use
試験例2 コムギふ枯病予防効果試験
直径7.5cmのポリ鉢でコムギ(品種:農林61号)を栽培し、1.5葉期に達した時に、各供試化合物を所定濃度に調整した薬液をスプレーガンにて5ml/苗散布した。薬液が乾燥した後、ふ枯病菌の分生胞子懸濁液を噴霧接種し、20℃の接種箱(湿度95%以上)に1日保ち、その後20℃の恒温室内に保った。接種9から11日後に病斑面積を調査し、試験例1と同様にして防除価を求め、その結果を第7表〜第9表に示した。なお、無処理区の病斑面積は、薬液に代えて水をスプレーガンにて散布したこと以外は処理区と同様の操作を行うことによって求めた。
また、コルビーの式による理論値を第7表〜第9表の( )内に併せ示した。
Test Example 2 Wheat Blight Prevention Effect Test Wheat (Cultivar: Norin 61) is cultivated in a 7.5cm diameter plastic pot, and when the 1.5 leaf stage is reached, each chemical compound is adjusted to a prescribed concentration and sprayed. 5ml / seedling was sprayed with a gun. After the chemical solution was dried, a conidial spore suspension of bacterial wilt was spray-inoculated and kept in a 20 ° C. inoculation box (humidity of 95% or more) for 1 day, and then kept in a constant temperature room at 20 ° C. The lesion area was investigated 9 to 11 days after the inoculation, and the control value was determined in the same manner as in Test Example 1, and the results are shown in Tables 7-9. In addition, the lesion area of an untreated area was calculated | required by performing operation similar to a treated area except having sprayed water with the spray gun instead of the chemical | medical solution.
Further, theoretical values according to Colby's formula are shown in parentheses in Tables 7 to 9.
Claims (4)
(b)プロクロラズと、
(c)シプロコナゾール、エポキシコナゾール、フルキンコナゾール、ヘキサコナゾール、メトコナゾール、プロピコナゾール、プロチオコナゾール、テブコナゾール、テトラコナゾール、トリアジメノール、オキスポコナゾール、ペンチオピラド及びボスカリドからなる群から選択される少なくとも1種の殺菌剤とを、
成分(a)1重量部に対して、成分(b)を1〜100重量部、成分(c)を0.1〜100重量部の混合重量比で植物に施用することを特徴とする植物病害の防除方法。 (A) 3- (2,3,4-trimethoxy-6-methylbenzoyl) -5-chloro-2-methoxy-4-methylpyridine;
(B) Prochloraz,
(C) The group consisting of cyproconazole, epoxiconazole, fluquinconazole, hexaconazole, metconazole, propiconazole, prothioconazole, tebuconazole, tetraconazole, triazimenol, oxpoconazole, pentiopyrado and boscalid At least one fungicide selected from
A plant disease characterized by applying 1 to 100 parts by weight of component (a) and 1 to 100 parts by weight of component (b) and 0.1 to 100 parts by weight of component (c) to a plant. Control method.
(b)プロクロラズと、
(c)シプロコナゾール、エポキシコナゾール、フルキンコナゾール、ヘキサコナゾール、メトコナゾール、プロピコナゾール、プロチオコナゾール、テブコナゾール、テトラコナゾール、トリアジメノール、オキスポコナゾール、ペンチオピラド及びボスカリドからなる群から選択される少なくとも1種の殺菌剤を成分(a)1重量部に対して、成分(b)を1〜100重量部、成分(c)を0.1〜100重量部の混合重量比で含有する殺菌剤組成物。 (A) 3- (2,3,4-trimethoxy-6-methylbenzoyl) -5-chloro-2-methoxy-4-methylpyridine;
(B) Prochloraz,
(C) The group consisting of cyproconazole, epoxiconazole, fluquinconazole, hexaconazole, metconazole, propiconazole, prothioconazole, tebuconazole, tetraconazole, triazimenol, oxpoconazole, pentiopyrado and boscalid 1 to 100 parts by weight of component (a) with at least one fungicide selected from 1 to 100 parts by weight of component (b) and 0.1 to 100 parts by weight of component (c) A fungicide composition to contain.
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EA016291B1 (en) * | 2007-04-25 | 2012-03-30 | Басф Се | Fungicide mixtures |
ES2381320T3 (en) * | 2007-09-26 | 2012-05-25 | Basf Se | Ternary fungicidal compositions comprising boscalide and chlorothalonil |
AU2009218585A1 (en) * | 2008-02-28 | 2009-09-03 | Syngenta Participations Ag | Pesticidal combinations |
WO2010002026A2 (en) | 2008-07-03 | 2010-01-07 | Ishihara Sangyo Kaisha, Ltd. | Fungicidal composition and method for controlling plant diseases |
CN101485313B (en) * | 2009-02-18 | 2011-08-10 | 陕西韦尔奇作物保护有限公司 | Compositional bactericidal composition containing thiabendazole and prochloraz |
CN101653139A (en) * | 2009-07-22 | 2010-02-24 | 深圳诺普信农化股份有限公司 | Compound bactericidal composition containing boscalid |
CN101617672A (en) * | 2009-08-12 | 2010-01-06 | 深圳诺普信农化股份有限公司 | Synergistic sterilizing composition |
JP2011118691A (en) | 2009-12-03 | 2011-06-16 | Denso Corp | Onboard etc device |
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TW201309200A (en) | 2013-03-01 |
JP2013010743A (en) | 2013-01-17 |
EP2713753A1 (en) | 2014-04-09 |
BR112013029836A2 (en) | 2016-09-06 |
RU2580681C2 (en) | 2016-04-10 |
RU2013158187A (en) | 2015-07-10 |
UA112544C2 (en) | 2016-09-26 |
WO2012165266A1 (en) | 2012-12-06 |
TWI544871B (en) | 2016-08-11 |
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