JP5752118B2 - ポリブチレンテレフタレート樹脂組成物、金属複合部品、及び金属複合部品の製造方法 - Google Patents
ポリブチレンテレフタレート樹脂組成物、金属複合部品、及び金属複合部品の製造方法 Download PDFInfo
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- JP5752118B2 JP5752118B2 JP2012519315A JP2012519315A JP5752118B2 JP 5752118 B2 JP5752118 B2 JP 5752118B2 JP 2012519315 A JP2012519315 A JP 2012519315A JP 2012519315 A JP2012519315 A JP 2012519315A JP 5752118 B2 JP5752118 B2 JP 5752118B2
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- terephthalate resin
- polybutylene terephthalate
- mass
- parts
- metal composite
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- -1 Polybutylene terephthalate Polymers 0.000 title claims description 296
- 229920001707 polybutylene terephthalate Polymers 0.000 title claims description 168
- 239000002905 metal composite material Substances 0.000 title claims description 117
- 239000011342 resin composition Substances 0.000 title claims description 86
- 238000004519 manufacturing process Methods 0.000 title claims description 28
- 229920005989 resin Polymers 0.000 claims description 182
- 239000011347 resin Substances 0.000 claims description 182
- 229910052751 metal Inorganic materials 0.000 claims description 114
- 239000002184 metal Substances 0.000 claims description 114
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 73
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 73
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 62
- 229920001971 elastomer Polymers 0.000 claims description 62
- 239000003063 flame retardant Substances 0.000 claims description 62
- 239000000806 elastomer Substances 0.000 claims description 58
- 238000000034 method Methods 0.000 claims description 40
- 238000000465 moulding Methods 0.000 claims description 40
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 37
- 239000012778 molding material Substances 0.000 claims description 36
- 229910052698 phosphorus Inorganic materials 0.000 claims description 36
- 239000011574 phosphorus Substances 0.000 claims description 36
- 239000000945 filler Substances 0.000 claims description 26
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 22
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 21
- 150000003839 salts Chemical class 0.000 claims description 20
- 229910052782 aluminium Inorganic materials 0.000 claims description 17
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 11
- 239000011737 fluorine Substances 0.000 claims description 11
- 229910052731 fluorine Inorganic materials 0.000 claims description 11
- 125000003277 amino group Chemical group 0.000 claims description 10
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims description 9
- 239000002131 composite material Substances 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 7
- 238000007788 roughening Methods 0.000 claims description 7
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 6
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims description 6
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- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 5
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 5
- XSAOTYCWGCRGCP-UHFFFAOYSA-K aluminum;diethylphosphinate Chemical group [Al+3].CCP([O-])(=O)CC.CCP([O-])(=O)CC.CCP([O-])(=O)CC XSAOTYCWGCRGCP-UHFFFAOYSA-K 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
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- 150000001340 alkali metals Chemical class 0.000 claims description 4
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- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 4
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 3
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
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- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 9
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- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
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- 238000003486 chemical etching Methods 0.000 description 6
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 6
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 6
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Images
Classifications
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C08L67/03—Polyesters derived from dicarboxylic acids and dihydroxy compounds the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
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| JP2012519315A JP5752118B2 (ja) | 2010-06-09 | 2011-05-13 | ポリブチレンテレフタレート樹脂組成物、金属複合部品、及び金属複合部品の製造方法 |
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| JP2010132466 | 2010-06-09 | ||
| JP2010132466 | 2010-06-09 | ||
| JP2012519315A JP5752118B2 (ja) | 2010-06-09 | 2011-05-13 | ポリブチレンテレフタレート樹脂組成物、金属複合部品、及び金属複合部品の製造方法 |
| PCT/JP2011/061060 WO2011155287A1 (ja) | 2010-06-09 | 2011-05-13 | ポリブチレンテレフタレート樹脂組成物、金属複合部品、及び金属複合部品の製造方法 |
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| JPWO2011155287A1 JPWO2011155287A1 (ja) | 2013-08-01 |
| JP5752118B2 true JP5752118B2 (ja) | 2015-07-22 |
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| JP (1) | JP5752118B2 (ko) |
| KR (1) | KR20130133746A (ko) |
| CN (1) | CN102933656B (ko) |
| TW (1) | TW201144381A (ko) |
| WO (1) | WO2011155287A1 (ko) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5925321B2 (ja) * | 2012-08-01 | 2016-05-25 | ウィンテックポリマー株式会社 | 電子機器用筐体 |
| CN104629273A (zh) * | 2015-02-11 | 2015-05-20 | 广州辰东新材料有限公司 | 一种可同时应用于nmt工艺及lds工艺的聚酯复合材料及其制备方法 |
| CN104629274A (zh) * | 2015-02-11 | 2015-05-20 | 广州辰东新材料有限公司 | 一种用于纳米注塑的聚酯复合材料及其制备方法 |
| KR20160107960A (ko) | 2015-03-06 | 2016-09-19 | 에스케이씨 주식회사 | 배터리 하우징 부품용 난연 폴리에스테르 조성물 |
| KR20160107961A (ko) | 2015-03-06 | 2016-09-19 | 에스케이씨 주식회사 | 난연 폴리에스테르 조성물 |
| CN104845297B (zh) * | 2015-05-11 | 2019-06-18 | 深圳华力兴新材料股份有限公司 | 一种用于nmt技术的pbt工程塑料组合物 |
| WO2017115757A1 (ja) * | 2015-12-28 | 2017-07-06 | ウィンテックポリマー株式会社 | ポリブチレンテレフタレート樹脂組成物、及び金属複合部品 |
| US11084915B2 (en) | 2016-01-04 | 2021-08-10 | Sumitomo Seika Chemicals Co., Ltd. | Composition for resin surface roughening |
| JP6902950B2 (ja) * | 2017-07-20 | 2021-07-14 | ポリプラスチックス株式会社 | 金属樹脂複合成形品およびその製造方法 |
| KR102176289B1 (ko) * | 2017-12-08 | 2020-11-09 | 주식회사 엘지화학 | 금속-수지 접합 성형품용 폴리에스테르계 수지 조성물, 이의 제조방법 및 이를 포함하는 금속-수지 접합 성형품 |
| CN109320922B (zh) * | 2018-09-11 | 2021-04-02 | 东莞市雄林新材料科技股份有限公司 | 一种具有夜间反光功能tpu薄膜及其制备方法 |
| JP2020151981A (ja) * | 2019-03-20 | 2020-09-24 | 三井化学株式会社 | 金属樹脂複合体の製造方法および金属樹脂複合体 |
| US20230094235A1 (en) * | 2020-02-19 | 2023-03-30 | Toyobo Co., Ltd. | Flame retardant polyester resin composition and molded article comprising same |
| KR20220043662A (ko) * | 2020-09-29 | 2022-04-05 | 롯데케미칼 주식회사 | 열가소성 수지 조성물 및 이를 이용한 성형품 |
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| JP2005273058A (ja) * | 2004-03-24 | 2005-10-06 | Toray Ind Inc | 吸湿性に優れた芯鞘型ポリエステル繊維及びその製造方法ならびに吸湿性布帛 |
| WO2006016458A1 (ja) * | 2004-08-11 | 2006-02-16 | Toray Industries, Inc. | 光反射体用ポリエステル樹脂組成物 |
| JP2007091865A (ja) * | 2005-09-28 | 2007-04-12 | Wintech Polymer Ltd | 難燃性ポリブチレンテレフタレート樹脂組成物 |
| WO2009011398A1 (ja) * | 2007-07-17 | 2009-01-22 | Taisei Plas Co., Ltd. | 金属と樹脂の複合体とその製造方法 |
| JP2009149018A (ja) * | 2007-12-21 | 2009-07-09 | Wintech Polymer Ltd | 複合成形体 |
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2011
- 2011-05-13 KR KR1020137000425A patent/KR20130133746A/ko not_active Application Discontinuation
- 2011-05-13 CN CN201180028376.8A patent/CN102933656B/zh active Active
- 2011-05-13 JP JP2012519315A patent/JP5752118B2/ja active Active
- 2011-05-13 WO PCT/JP2011/061060 patent/WO2011155287A1/ja active Application Filing
- 2011-05-18 TW TW100117336A patent/TW201144381A/zh unknown
Patent Citations (5)
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|---|---|---|---|---|
| JP2005273058A (ja) * | 2004-03-24 | 2005-10-06 | Toray Ind Inc | 吸湿性に優れた芯鞘型ポリエステル繊維及びその製造方法ならびに吸湿性布帛 |
| WO2006016458A1 (ja) * | 2004-08-11 | 2006-02-16 | Toray Industries, Inc. | 光反射体用ポリエステル樹脂組成物 |
| JP2007091865A (ja) * | 2005-09-28 | 2007-04-12 | Wintech Polymer Ltd | 難燃性ポリブチレンテレフタレート樹脂組成物 |
| WO2009011398A1 (ja) * | 2007-07-17 | 2009-01-22 | Taisei Plas Co., Ltd. | 金属と樹脂の複合体とその製造方法 |
| JP2009149018A (ja) * | 2007-12-21 | 2009-07-09 | Wintech Polymer Ltd | 複合成形体 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2011155287A1 (ja) | 2011-12-15 |
| KR20130133746A (ko) | 2013-12-09 |
| CN102933656A (zh) | 2013-02-13 |
| CN102933656B (zh) | 2014-10-29 |
| TW201144381A (en) | 2011-12-16 |
| JPWO2011155287A1 (ja) | 2013-08-01 |
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