JP5727974B2 - 高結晶性物質含有組成物 - Google Patents
高結晶性物質含有組成物 Download PDFInfo
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- JP5727974B2 JP5727974B2 JP2012157348A JP2012157348A JP5727974B2 JP 5727974 B2 JP5727974 B2 JP 5727974B2 JP 2012157348 A JP2012157348 A JP 2012157348A JP 2012157348 A JP2012157348 A JP 2012157348A JP 5727974 B2 JP5727974 B2 JP 5727974B2
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- highly crystalline
- crystalline substance
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Description
一方、強分散性の高圧乳化機を用いる手法は、いかなる生産ラインにも高圧乳化機が設置されているとは限らず汎用性が低く、設置されていたとしても原料の混合釜からラインを通じて高圧乳化機まで混合原料を移送させる必要があり、その間にラインコンタミネーションの可能性が高まることによる品質の劣化、それに伴うクレーム発生の危険性が高い。また高圧で乳化させるため、エネルギーの消費は高く、必ずしも生産性の高い手法であるとはいい難い。
よって、これらの方法では、高結晶性物質の安定な乳化、可溶化状態を長期間保つことができ、安心して飲食品や化粧品に配合できる組成物として十分に満足しうるものは調製することは難しい。
従って、本発明は前記従来技術に鑑みてなされたものであり、本発明の課題は、高結晶性物質を水に容易に均一分散でき、かつ低温・高温の過酷な条件下で長期間保存しても結晶や沈殿を生じない高い安定性を有し、さらに耐酸性、耐塩性、耐熱性、耐アルコール性に優れた高結晶性物質含有組成物、ならびに前記組成物を含有する飲食品、または化粧品を提供することにある。
[1]下記(A)〜(C)を含有する高結晶性物質含有組成物。
(A)高結晶性物質
(B)水酸基価が1200以下、かつ全ての水酸基のうち1級水酸基が50重量%以上であり、さらに環状体含有量が25重量%以下であるポリグリセリンと脂肪酸とがエステル化されたポリグリセリン脂肪酸エステル
(C)IOB(無機/有機バランス)値が0.20〜0.60である液状油であって、ジカプリン酸プロピレングリコール、ドデカ(カプリル・カプリン酸)デカグリセリン及びジイソステアリン酸トリグリセリンの群より選ばれる1種の液状油
[2]組成物が多価アルコール中油型(O/D型)の乳化物である前記[1]記載の高結晶性物質含有組成物。
[3]ポリグリセリン脂肪酸エステルのHLB値が10〜18である前記[1]または[2]記載の高結晶性物質含有組成物。
[4]前記[1]〜[3]いずれか記載の高結晶性物質含有組成物を含む飲食品。
[5]前記[1]〜[3]いずれか記載の高結晶性物質含有組成物を含む化粧品。
本発明に用いるポリグリセリン脂肪酸エステルにおけるポリグリセリンは、分子中の全ての水酸基のうち1級水酸基が50重量%以上であるポリグリセリンであり、得られるポリグリセリン脂肪酸エステルの可溶化性能および乳化安定性をさらに向上する観点から、1級水酸基が好ましくは55重量%以上のポリグリセリン、より好ましくは60重量%以上のポリグリセリンである。さらに上限値は、特に規定するものではないが、その効果を最大限に発揮させるためには90重量%以下であることが望ましい。本願のポリグリセリンにおける全水酸基のうち1級水酸基の占める割合はポリグリセリンの縮合度に応じて変化するため、また一般的に流通しているポリグリセリンの種類がテトラ、ペンタ、ヘキサ、デカであることを考慮してその上限値を例示するならば、テトラグリセリンでは70重量%以下、好ましくは65重量%以下、ペンタグリセリンでは75重量%以下、好ましくは70重量%以下、ヘキサグリセリンでは80重量%以下、好ましくは75重量%以下、デカグリセリンでは85重量%以下、好ましくは80重量%以下といった数値を示すことができる。
全ての水酸基のうちの1級水酸基の割合は、炭素原子に対する核磁気共鳴スペクトル(NMR)を測定する方法を用いて測定される。また、水酸基価は当該分野で公知の方法により測定することができる。
HLB=20×(1−S/A)
(式中、S:エステルのけん化価、A:構成脂肪酸の酸価)
により算出された値のことをいう。
式:IOB=無機性値/有機性値
以下、実施例及び比較例を挙げて本発明を具体的に説明するが、本発明はこれらに限定するものではない。
表2〜4に示す界面活性剤及び液状油をビーカーに入れ、80℃に加温した後、ホモミキサーを用いて6000r/minで攪拌して混合した。得られた混合物に表2〜4に示す高結晶性物質を加えさらに加熱、攪拌して混合した。高結晶性物質が完全に溶解し、溶液が透明になっていることを目視にて確認後、予め別のビーカーにて80℃に加温しておいた多価アルコールを加え、さらに、表2〜4の配合に応じて水またはアルコールを加え、6000rpmにて攪拌混合し、実施例1〜24及び比較例1〜12の組成物を得た。なお、用いたポリグリセリン脂肪酸エステルのHLB、そのポリグリセリンの水酸基価、1級水酸基含量および環状体含量は表1に示すとおりである。
なお、用いたポリグリセリンの環状体含有量は、以下に示す条件で液体クロマトグラフ−質量分析計(LC/MS)を用いて分析した。
イオン化モード;APCI、negativ
測定範囲;90〜2000m/z
カラム;TSKgel α−2500(7.8×300mm)
温度;40℃
溶離液;H2O/アセトニトリル 7/3
流量;0.8ml/min
注入量;10μl、100ppm
分析時間;20分
得られた実施例1〜24及び比較例1〜12の組成物を、100mlの透明瓶に充填後、密栓した。各組成物について、5℃、25℃及び50℃の暗所にて4週間保存後の状態を目視で確認し、以下の評価基準より乳化安定性を評価した。結果を表2〜4に示す。
◎:結晶析出や濁りを認めず、透明である
○:濁りを認める
△:濁りを認め、結晶が少し析出する(数〜十数個程度)
×:濁りを認め、結晶が多く析出する(数十個以上)
××:結晶が多く析出し、完全に分相する
なお、全ての温度帯において◎および○を合格品とする。
実施例1〜24及び比較例1〜12の組成物を高結晶性物質の濃度が0.05重量%となるよう、クエン酸0.24重量%、クエン酸Na0.04重量%および食塩1重量%を加えたpH2.8の水溶液で希釈し、高結晶性物質を含む希釈溶液を調製した。得られた希釈溶液について、100mlの透明ガラス瓶に充填し、55℃、72時間保存の後、3℃、72時間の保存を1つのサイクルとし、このサイクルを5サイクル繰り返し暗所にて保存した。保存後の試料について、状態を目視で確認し、以下の評価基準より外観を評価した。結果を表2〜4に示す。
◎:結晶析出や濁りを認めず、透明である(容器瓶越しに文字が確認可能)
○:濁りを認める
△:結晶が少し析出する(数〜十数個程度)
×:結晶が多く析出する(数十個以上)
なお、◎および○を合格品とする。
表5のスポーツドリンク原料を混合し、pH3.4の飲料ベースを得た。実施例1、5、6、12〜24及び比較例1〜7の組成物を高結晶性物質の濃度が0.01重量%となるよう飲料ベースで希釈し、93℃達温にて加熱殺菌後、無色透明の500mlペットボトルにホットパック充填し、冷却して高結晶性物質を含有する透明〜乳白色のスポーツドリンクを得た。
実施例25〜39及び比較例13〜19のスポーツドリンクについて、37℃、24時間保存の後、−10℃、24時間保存、その後さらに5℃、24時間の保存を1つのサイクルとし、このサイクルを10サイクル繰り返し暗所にて保存した。保存後の飲料について、状態を目視で確認し、以下の評価基準より外観を評価した。なお、評価終了以前に結晶が発生した試料については、結晶発生日を示した。結果を表6に示す。
◎:半透明溶液であり、結晶、沈殿物を認めない(容器越しに文字が認識可能能)
○:白濁溶液であり、結晶、沈殿物を認めない
△:白濁溶液であり、細かい結晶を認める
×:結晶、沈殿物を多数認める
尚、◎および○を合格品とする。
また、試験例3と同条件で保存した実施例25〜39及び比較例13〜19のスポーツドリンクの濁度を、分光光度計を用いて波長650nmにおける吸収光度として測定した。保存後の濁度の変化を、保存前の試料の濁度を基準とし、次式にて変化率を算出した。なお、結晶が発生したものは、測定不能とした。結果を表6に示す。
変化率(%)=(保存後の濁度/保存前の濁度)×100
表7のアルコール飲料原料を混合し、飲料ベースとした。実施例1、4、10及び比較例8、11、12の組成物を高結晶性物質の濃度が0.05重量%となるよう飲料ベースで希釈し、180ml缶に充填後、80℃、10分にて殺菌、冷却して高結晶性物質を含有する透明〜乳白色のアルコール飲料を得た。
実施例40〜42及び比較例20〜22のアルコール飲料について、37℃、24時間保存の後、−10℃、24時間保存、その後さらに5℃、24時間の保存を1つのサイクルとし、このサイクルを10サイクル繰り返し暗所にて保存した。保存後の試料を100mlビーカーに移し、状態を目視で確認し、試験例3と同様の評価基準により外観を評価した。なお、評価終了以前に結晶が発生した試料については、結晶発生日を示した。結果を表8に示す。
また、試験例5と同条件で保存した実施例40〜42及び比較例20〜22のアルコール飲料の平均粒子径を粒度分布測定器(ベックマンコールター社製:LS−230)にて測定した。保存後の濁度の変化を、保存前の試料の粒子径を基準とし、次式にて変化率を算出した。結果を表8に示す。
変化率(%)=(保存後の平均粒子径(μm)/保存前の平均粒子径(μm))×100
表9に示す化粧料成分を攪拌混合し、実施例43及び比較例23の化粧水を得た。なお、比較例23で用いたフェルラ酸は実施例23と同じものである。
実施例43及び比較例23の化粧水について、55℃、1週間保存の後、3℃、1週間の保存を1つのサイクルとし、このサイクルを12サイクル繰り返し暗所にて保存した。保存後の試料について、状態を目視で確認し、試験例3と同様の評価基準により外観を評価した。なお、評価終了以前に結晶が発生した試料については、結晶発生日を示した。結果を表10に示す。
表11に示す割合にしたがって乳液を調製した。精製水にプロピレングリコール、グリセリン、トリエタノールアミンを加え加熱混合し、水相部とした。また、他の成分を70℃にて混合し、この油相部を水相部に加えて予備乳化を行った。ここに実施例2、比較例1の組成物を高結晶性物質の濃度が0.5重量%となるよう配合し、ホモミキサーで均一に乳化し、乳化後30℃まで冷却して乳液を得た。
実施例44及び比較例24の乳液について、55℃、1週間保存の後、3℃、1週間の保存を1つのサイクルとし、このサイクルを12サイクル繰り返し暗所にて保存した。保存後の試料について、使用感を手に塗布して確認し、以下の評価基準より評価した。結果を表12に示す。なお、表12中の評価の点数は、下記の基準で採点した各パネルの平均点である。
滑らかであり伸びがよい :4点
滑らかであるが伸びが悪い:3点
わずかにざらつきを感じる:2点
かなりざらつきを感じる :1点
Claims (4)
- 下記(A)〜(C)を含有する多価アルコール中油型(O/D型)の乳化物であって、高結晶性物質含有組成物。
(A)高結晶性物質
(B)水酸基価が1200以下、かつ全ての水酸基のうち1級水酸基が50重量%以上であり、さらに環状体含有量が25重量%以下であるポリグリセリンと脂肪酸とがエステル化されたポリグリセリン脂肪酸エステル
(C)液状油がIOB(無機/有機バランス)値が0.20〜0.60であるドデカ(カプリル・カプリン酸)デカグリセリン - ポリグリセリン脂肪酸エステルのHLB値が10〜18である請求項1記載の高結晶性物質含有組成物。
- 請求項1又は2記載の高結晶性物質含有組成物を含む飲食品。
- 請求項1又は2記載の高結晶性物質含有組成物を含む化粧品。
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