JP5712123B2 - 複合材料 - Google Patents
複合材料 Download PDFInfo
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- JP5712123B2 JP5712123B2 JP2011282623A JP2011282623A JP5712123B2 JP 5712123 B2 JP5712123 B2 JP 5712123B2 JP 2011282623 A JP2011282623 A JP 2011282623A JP 2011282623 A JP2011282623 A JP 2011282623A JP 5712123 B2 JP5712123 B2 JP 5712123B2
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- Prior art keywords
- resin
- glass
- composite material
- oxide glass
- rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000002131 composite material Substances 0.000 title claims description 36
- 229920005989 resin Polymers 0.000 claims description 75
- 239000011347 resin Substances 0.000 claims description 75
- 239000003365 glass fiber Substances 0.000 claims description 23
- 239000000075 oxide glass Substances 0.000 claims description 18
- 229920001971 elastomer Polymers 0.000 claims description 14
- 239000005060 rubber Substances 0.000 claims description 14
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- -1 polyethylene Polymers 0.000 claims description 8
- 229910052720 vanadium Inorganic materials 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000004696 Poly ether ether ketone Substances 0.000 claims description 4
- 229920002530 polyetherether ketone Polymers 0.000 claims description 4
- 229920001721 polyimide Polymers 0.000 claims description 4
- 229920001955 polyphenylene ether Polymers 0.000 claims description 4
- 238000005979 thermal decomposition reaction Methods 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 3
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229930182556 Polyacetal Natural products 0.000 claims description 2
- 239000004962 Polyamide-imide Substances 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004642 Polyimide Substances 0.000 claims description 2
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 2
- 239000003973 paint Substances 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- 229920002492 poly(sulfone) Polymers 0.000 claims description 2
- 229920002312 polyamide-imide Polymers 0.000 claims description 2
- 229920001230 polyarylate Polymers 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 239000009719 polyimide resin Substances 0.000 claims description 2
- 229920006324 polyoxymethylene Polymers 0.000 claims description 2
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 239000011118 polyvinyl acetate Substances 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 claims description 2
- 229920001290 polyvinyl ester Polymers 0.000 claims description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- 229920001568 phenolic resin Polymers 0.000 claims 1
- 229920001748 polybutylene Polymers 0.000 claims 1
- 238000010248 power generation Methods 0.000 claims 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims 1
- 239000011521 glass Substances 0.000 description 66
- 239000010410 layer Substances 0.000 description 16
- 239000011159 matrix material Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 10
- 239000000843 powder Substances 0.000 description 9
- 229920000049 Carbon (fiber) Polymers 0.000 description 8
- 239000004917 carbon fiber Substances 0.000 description 8
- 230000035699 permeability Effects 0.000 description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 238000005259 measurement Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000004455 differential thermal analysis Methods 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000011152 fibreglass Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000012790 adhesive layer Substances 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229920006038 crystalline resin Polymers 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000013585 weight reducing agent Substances 0.000 description 2
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 229920006127 amorphous resin Polymers 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- WAKZZMMCDILMEF-UHFFFAOYSA-H barium(2+);diphosphate Chemical compound [Ba+2].[Ba+2].[Ba+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O WAKZZMMCDILMEF-UHFFFAOYSA-H 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 229920006241 epoxy vinyl ester resin Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000009661 fatigue test Methods 0.000 description 1
- 238000009730 filament winding Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000007496 glass forming Methods 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000009787 hand lay-up Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000013001 point bending Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000013074 reference sample Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/40—Glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C13/00—Fibre or filament compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
- C03C3/122—Silica-free oxide glass compositions containing oxides of As, Sb, Bi, Mo, W, V, Te as glass formers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
- C03C3/16—Silica-free oxide glass compositions containing phosphorus
- C03C3/21—Silica-free oxide glass compositions containing phosphorus containing titanium, zirconium, vanadium, tungsten or molybdenum
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/10—Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/06—Polystyrene
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F03—MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
- F03D—WIND MOTORS
- F03D1/00—Wind motors with rotation axis substantially parallel to the air flow entering the rotor
- F03D1/06—Rotors
- F03D1/065—Rotors characterised by their construction elements
- F03D1/0675—Rotors characterised by their construction elements of the blades
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/70—Wind energy
- Y02E10/72—Wind turbines with rotation axis in wind direction
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Glass Compositions (AREA)
- Reinforced Plastic Materials (AREA)
- Paints Or Removers (AREA)
Description
本発明は樹脂またはゴム(以下、樹脂等と称する)と酸化物ガラスから構成される複合材料であって、樹脂等がガラス中に分散しているか、ガラスが樹脂等中に分散している。この複合材料を加熱することで、ガラスが、樹脂等の熱分解温度かそれよりも低い温度で軟化流動(溶融)する。一度溶けたガラスと樹脂との界面は滑らかであるため、単に樹脂中にガラス粒子が分散しているものと比較して、樹脂とガラスとの密着性は高くなる。なお、熱分解温度は、加熱により重量減少が始まる温度であり、熱重量測定(TG)する。
表1に示す組成を有するガラス(SPL−01〜25)を作製した。表中の組成は、各成分の酸化物換算における質量比率で表示してある。出発原料としては、(株)高純度化学研究所製の酸化物粉末(純度99.9%)を用いた。一部の試料においては、Ba源およびP源としてBa(PO3)2(リン酸バリウム、ラサ工業(株)製)を用いた。
上記で得られた各ガラス粉末に対して、示差熱分析(DTA)により軟化点Tsを測定した。DTA測定は、参照試料(α−アルミナ)および測定試料の質量をそれぞれ650mgとし、大気中5℃/minの昇温速度で行い、第2吸熱ピークのピーク温度を軟化点Tsとして求めた(図1参照)。結果を表1に併記する。
表1に記載のSPL−21ガラス粉末(粒子径:3μm)と、フレーク状のポリスチレン樹脂とを体積比で1:1になるように配合し、2軸混錬機により複合化した。混練機の加熱保持温度を250℃、スクリューの回転速度を40rpm/minとした。
酸素透過度の測定は、温度30℃、湿度90%RHの条件で、米国モコン(MOCON)株式会社製の酸素透過度測定装置(OX−TRAN(R)2/20)を使用し、圧力差0.1MPaの条件で行われた。装置の測定限界は0.01cc/m2/dayである。
22 樹脂
31 前縁部
32 後縁部
33 上スキン
34 下スキン
35 スパー
36、50 フランジ部
37 ウエブ部
42 炭素繊維層
43 接着層
44 複合層
45 ガラス繊維層
46 ガラス繊維
47、48 マトリクス樹脂
49 炭素繊維
Claims (11)
- 樹脂またはゴムと、酸化物ガラスを備えた複合材料において、前記樹脂またはゴムが前記酸化物ガラス中に分散、あるいは、前記酸化物ガラスが前記樹脂またはゴム中に分散し、前記酸化物ガラスが、Te、V、Agを含有することを特徴とする複合材料。
- 請求項1において、加熱により、前記酸化物ガラスが、前記樹脂またはゴムの熱分解温度以下で軟化流動することを特徴とする複合材料。
- 請求項1において、前記酸化物ガラスが、Ag2O、V2O5、TeO2を含有し、Ag2OとV2O5とTeO2との合計含有率が75質量%以上であることを特徴とする複合材料。
- 請求項3において、前記酸化物ガラスが、10〜60質量%のAg2Oと、5〜65質量%のV2O5と、15〜50質量%のTeO2とを含有することを特徴とする複合材料。
- 請求項4において、前記酸化物ガラスのAg2O含有率がV2O5含有率の2.6倍以下であることを特徴とする複合材料。
- 請求項5において、前記酸化物ガラスのAg2O含有率とV2O5含有率との和が40〜80質量%であることを特徴とする複合材料。
- 請求項1又は2において、前記樹脂が、ポリエチレン、ポリ塩化ビニル、ポリプロピレン、ポリスチレン、ポリ酢酸ビニル、ABS樹脂、AS樹脂、アクリル樹脂、ポリアセタール樹脂、ポリイミド、ポリカーボネート、変性ポリフェニレンエーテル(PPE)、ポリブチレンテレフタレート(PBT)、ポリアリレート、ポリサルホン、ポリフェニレンスルフィド、ポリエーテルエーテルケトン、ポリイミド樹脂、フッ素樹脂、ポリアミドイミド、ポリエーテルエーテルケトン、エポキシ樹脂、フェノール樹脂、ポリエステル、ポリビニルエステルのいずれかであることを特徴とする複合材料。
- 請求項1または2の複合材料と有機溶剤とを含むことを特徴とする塗料。
- 請求項1または2の複合材料とガラス繊維とが複合化されたことを特徴とするガラス繊維強化型樹脂。
- 請求項1または2の複合材料から構成されることを特徴とする導電性パッケージ。
- 請求項9のガラス繊維強化型樹脂を備えることを特徴とする風力発電用ブレード。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011282623A JP5712123B2 (ja) | 2011-12-26 | 2011-12-26 | 複合材料 |
PCT/JP2012/078276 WO2013099436A1 (ja) | 2011-12-26 | 2012-11-01 | 複合材料 |
CN201280061149.XA CN103987791B (zh) | 2011-12-26 | 2012-11-01 | 复合材料 |
US14/368,479 US9708460B2 (en) | 2011-12-26 | 2012-11-01 | Composite material |
TW101144463A TWI457376B (zh) | 2011-12-26 | 2012-11-28 | Composites |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011282623A JP5712123B2 (ja) | 2011-12-26 | 2011-12-26 | 複合材料 |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2013133342A JP2013133342A (ja) | 2013-07-08 |
JP2013133342A5 JP2013133342A5 (ja) | 2013-10-17 |
JP5712123B2 true JP5712123B2 (ja) | 2015-05-07 |
Family
ID=48696936
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2011282623A Expired - Fee Related JP5712123B2 (ja) | 2011-12-26 | 2011-12-26 | 複合材料 |
Country Status (5)
Country | Link |
---|---|
US (1) | US9708460B2 (ja) |
JP (1) | JP5712123B2 (ja) |
CN (1) | CN103987791B (ja) |
TW (1) | TWI457376B (ja) |
WO (1) | WO2013099436A1 (ja) |
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JP5726698B2 (ja) | 2011-07-04 | 2015-06-03 | 株式会社日立製作所 | ガラス組成物、それを含むガラスフリット、それを含むガラスペースト、およびそれを利用した電気電子部品 |
JP5667970B2 (ja) | 2011-12-26 | 2015-02-12 | 株式会社日立製作所 | 複合材料 |
JP5816565B2 (ja) | 2012-01-26 | 2015-11-18 | 株式会社日立産機システム | インク、被印字基材、印字装置、印字方法、被印字基材の製造方法 |
JP6350127B2 (ja) * | 2014-08-29 | 2018-07-04 | 日立化成株式会社 | 無鉛低融点ガラス組成物並びにこれを含む低温封止用ガラスフリット、低温封止用ガラスペースト、導電性材料及び導電性ガラスペースト並びにこれらを利用したガラス封止部品及び電気電子部品 |
JP2018109073A (ja) * | 2015-03-31 | 2018-07-12 | 株式会社日立製作所 | 複合材組成物、及びそれを用いたペースト剤 |
DE112016004340T5 (de) * | 2015-09-25 | 2018-06-07 | Hitachi, Ltd. | Verbindungsmaterial und verbundener körper, der dies verwendet |
CN108463440B (zh) * | 2016-01-18 | 2021-09-21 | 株式会社日立制作所 | 无铅玻璃组合物、玻璃复合材料、玻璃糊剂、密封结构体、电气电子部件和涂装部件 |
CN106746630A (zh) * | 2016-11-25 | 2017-05-31 | 江苏环宇纺织科技有限公司 | 一种合成玻璃纤维防火材料及其制备方法 |
CN110093097A (zh) * | 2019-04-08 | 2019-08-06 | 安徽驭风风电设备有限公司 | 一种风电叶片涂装方法及所用涂料制备方法 |
KR102323875B1 (ko) * | 2021-06-25 | 2021-11-09 | 일성 주식회사 | 교면 방수제 제조방법 및 시공방법 |
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US3798114A (en) * | 1971-05-11 | 1974-03-19 | Owens Illinois Inc | Glasses with high content of silver oxide |
JPH03140337A (ja) * | 1989-10-26 | 1991-06-14 | Toppan Printing Co Ltd | バリヤー性成型品とその製造方法 |
JPH04270140A (ja) * | 1990-06-21 | 1992-09-25 | Johnson Matthey Inc | シーリングガラス組成物および導電性成分を含む同組成物 |
DE4128804A1 (de) * | 1991-08-30 | 1993-03-04 | Demetron | Bleifreies, niedrigschmelzendes glas |
US5334558A (en) | 1992-10-19 | 1994-08-02 | Diemat, Inc. | Low temperature glass with improved thermal stress properties and method of use |
JP3114524B2 (ja) * | 1994-03-24 | 2000-12-04 | 新神戸電機株式会社 | 難燃性樹脂組成物 |
JPH0859295A (ja) * | 1994-08-22 | 1996-03-05 | Nippon Electric Glass Co Ltd | 低融点封着用組成物 |
JP2001064524A (ja) * | 1999-08-27 | 2001-03-13 | Asahi Glass Co Ltd | 難燃化機能を有する耐水性低融点ガラスおよび難燃性樹脂組成物 |
US6734243B2 (en) | 1999-12-15 | 2004-05-11 | Siemens Aktiengesellschaft | Component and method for the production thereof |
JP4465706B2 (ja) | 2003-06-20 | 2010-05-19 | 日本電気硝子株式会社 | ガラス繊維及びガラス繊維強化樹脂 |
EP1561732A4 (en) | 2002-10-15 | 2008-10-08 | Nippon Electric Glass Co | GLASS COMPOSITION AND GLASS FIBER |
CN1753840A (zh) | 2003-02-25 | 2006-03-29 | 肖特股份公司 | 抗菌的硼硅酸盐玻璃 |
DE10308227A1 (de) * | 2003-02-25 | 2004-09-09 | Schott Glas | Antimikrobiell wirkendes Sulfophosphatglas |
WO2004076369A2 (de) * | 2003-02-25 | 2004-09-10 | Schott Ag | Antimikrobiell wirkendes brosilicatglas |
DE10308186B4 (de) * | 2003-02-25 | 2007-01-04 | Schott Ag | Antimikrobiell wirkendes Phosphatglas und dessen Verwendungen |
EP1597211A2 (de) * | 2003-02-25 | 2005-11-23 | Schott AG | Antimikrobiell wirkendes phosphatglas |
KR101457362B1 (ko) * | 2007-09-10 | 2014-11-03 | 주식회사 동진쎄미켐 | 유리 프릿 및 이를 이용한 전기소자의 밀봉방법 |
CN102186786A (zh) * | 2008-10-17 | 2011-09-14 | 旭玻璃纤维股份有限公司 | 低熔点玻璃、使用该玻璃的树脂组合物、树脂成形品 |
KR20130100954A (ko) * | 2010-06-14 | 2013-09-12 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 장기간 옥외 노출 저항성 폴리에스테르 복합 구조체 및 그의 제조 방법 |
JP5726698B2 (ja) | 2011-07-04 | 2015-06-03 | 株式会社日立製作所 | ガラス組成物、それを含むガラスフリット、それを含むガラスペースト、およびそれを利用した電気電子部品 |
JP5667970B2 (ja) | 2011-12-26 | 2015-02-12 | 株式会社日立製作所 | 複合材料 |
JP5487193B2 (ja) | 2011-12-26 | 2014-05-07 | 株式会社日立製作所 | 複合部材 |
JP5732381B2 (ja) | 2011-12-26 | 2015-06-10 | 株式会社日立製作所 | 積層体及びこれを用いた有機el素子、窓、太陽電池モジュール |
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US20140334937A1 (en) | 2014-11-13 |
CN103987791A (zh) | 2014-08-13 |
TW201335250A (zh) | 2013-09-01 |
CN103987791B (zh) | 2016-05-11 |
US9708460B2 (en) | 2017-07-18 |
WO2013099436A1 (ja) | 2013-07-04 |
TWI457376B (zh) | 2014-10-21 |
JP2013133342A (ja) | 2013-07-08 |
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