JP5690718B2 - 金属水素化物を用いた水素タンクの製造方法 - Google Patents
金属水素化物を用いた水素タンクの製造方法 Download PDFInfo
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- 239000001257 hydrogen Substances 0.000 title claims description 74
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 74
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 70
- 229910052987 metal hydride Inorganic materials 0.000 title claims description 51
- 150000004681 metal hydrides Chemical class 0.000 title claims description 51
- 238000004519 manufacturing process Methods 0.000 title claims description 30
- 238000000034 method Methods 0.000 claims description 73
- 239000000843 powder Substances 0.000 claims description 73
- 239000000463 material Substances 0.000 claims description 63
- 239000002184 metal Substances 0.000 claims description 31
- 229910052751 metal Inorganic materials 0.000 claims description 30
- 238000003860 storage Methods 0.000 claims description 28
- 238000005520 cutting process Methods 0.000 claims description 13
- 230000001681 protective effect Effects 0.000 claims description 12
- 238000003754 machining Methods 0.000 claims description 11
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 11
- 229910052720 vanadium Inorganic materials 0.000 claims description 9
- 229910052748 manganese Inorganic materials 0.000 claims description 6
- 150000002739 metals Chemical class 0.000 claims description 6
- 238000005498 polishing Methods 0.000 claims description 6
- 239000013529 heat transfer fluid Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229910002335 LaNi5 Inorganic materials 0.000 claims description 4
- 238000003801 milling Methods 0.000 claims description 4
- 229910004657 CaNi5 Inorganic materials 0.000 claims description 3
- 229910017060 Fe Cr Inorganic materials 0.000 claims description 3
- 229910002544 Fe-Cr Inorganic materials 0.000 claims description 3
- 229910002551 Fe-Mn Inorganic materials 0.000 claims description 3
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 claims description 3
- 229910000861 Mg alloy Inorganic materials 0.000 claims description 3
- 229910019086 Mg-Cu Inorganic materials 0.000 claims description 3
- 229910019083 Mg-Ni Inorganic materials 0.000 claims description 3
- 229910019403 Mg—Ni Inorganic materials 0.000 claims description 3
- 229910010340 TiFe Inorganic materials 0.000 claims description 3
- 229910011212 Ti—Fe Inorganic materials 0.000 claims description 3
- 229910007727 Zr V Inorganic materials 0.000 claims description 3
- 229910052790 beryllium Inorganic materials 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910000765 intermetallic Inorganic materials 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 239000006104 solid solution Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 claims description 2
- 238000007789 sealing Methods 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- -1 V-Ti-Fe or V-Ti-Cr Chemical compound 0.000 claims 1
- 210000004027 cell Anatomy 0.000 description 87
- 150000004678 hydrides Chemical class 0.000 description 40
- 239000007787 solid Substances 0.000 description 15
- 229910045601 alloy Inorganic materials 0.000 description 14
- 239000000956 alloy Substances 0.000 description 14
- 239000002245 particle Substances 0.000 description 13
- 238000005984 hydrogenation reaction Methods 0.000 description 11
- 230000004913 activation Effects 0.000 description 8
- 230000008901 benefit Effects 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 210000002421 cell wall Anatomy 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 238000003795 desorption Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 238000009434 installation Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000011232 storage material Substances 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000005422 blasting Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910001122 Mischmetal Inorganic materials 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000005056 compaction Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000003670 easy-to-clean Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- 229910000946 Y alloy Inorganic materials 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 208000002352 blister Diseases 0.000 description 1
- 239000013590 bulk material Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000003325 follicular Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000004845 hydriding Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000005382 thermal cycling Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0084—Solid storage mediums characterised by their shape, e.g. pellets, sintered shaped bodies, sheets, porous compacts, spongy metals, hollow particles, solids with cavities, layered solids
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- C—CHEMISTRY; METALLURGY
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0026—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof of one single metal or a rare earth metal; Treatment thereof
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
- C01B3/0036—Intermetallic compounds; Metal alloys; Treatment thereof only containing iron and titanium; Treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
- C01B3/0042—Intermetallic compounds; Metal alloys; Treatment thereof only containing magnesium and nickel; Treatment thereof
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
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- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
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- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
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- C01B3/0068—Intermetallic compounds; Metal alloys; Treatment thereof containing a rare earth metal; Treatment thereof only containing a rare earth metal and only one other metal the other metal being nickel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C11/00—Use of gas-solvents or gas-sorbents in vessels
- F17C11/005—Use of gas-solvents or gas-sorbents in vessels for hydrogen
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Description
化物タンクに関する。
a)前記セル(1)を画定する壁の全てではなく、いくつかの壁によって空洞(open cavity)又は胞状セル(alveolar cell)を形成するように組み立てる工程、
b)金属水素化物を形成可能な材料の1以上の塊状(固体)ピースであって、前記セル中に自由空間を残すような大きさの塊状ピースを、前記空洞又は胞状セル内に配置する工程、
c)前記セルを画定する最後の壁で前記セルを密閉するように組み立てる工程、
d)前記筐体の前記セルの全てを製造するために必要な回数、工程a),b),c)を繰り返し、前記セルに水素を入出させるために各々の壁に1以上のオリフィスが設けられる工程、
e)筐体を密閉する工程、
f)前記筐体に水素を導入することにより、前記セルの各々にある前記材料の塊状ピースを前記金属水素化物粉末に変化させる工程、
g)工程f)を必要に応じて繰り返す工程
を備え、
前記工程a)、b)及びc)を実行することにより各基本セル(1)を順々に製造することと、
前記工程b),c),d)及びe)が前記筐体中の保護雰囲気下で実行されることとを特徴とする貯蔵タンクの製造方法である。
画定する壁(2,3,4,5)の1以上が未だ組み立てられていない。
Claims (14)
- 金属水素化物粉末中に水素を吸蔵するための貯蔵タンクであって、壁(2,3,4,5)によって画定された複数の密閉基本セル(1)に分割された密閉筐体を備え、各基本セル(1)に金属水素化物粉末(6)を含有する貯蔵タンクを製造する方法において、
a)前記セル(1)を画定する壁の全てではなく、いくつかの壁によって空洞又は胞状セルを形成するように組み立てる工程、
b)金属水素化物を形成可能な材料の1以上の塊状ピース(7)であって、前記セル(1)中に自由空間(8)を残すような大きさの塊状ピース(7)を、前記空洞又は胞状セル内に配置する工程、
c)前記セル(1)を画定する最後の壁で前記セルを密閉するように組み立てる工程、
d)前記筐体の前記セル(1)の全てを製造するために必要な回数、工程a),b),c)を繰り返し、前記セルに水素を入出させるために各々の壁に1以上のオリフィスが設けられる工程、
e)筐体を密閉する工程、
f)前記筐体に水素を導入することにより、前記セル(1)の各々にある前記材料の塊状ピース(7)を前記金属水素化物粉末(6)に変化させる工程、
g)工程f)を必要に応じて繰り返す工程
を備え、
前記工程a)、b)及びc)を実行することにより各基本セル(1)を順々に製造することと、
前記工程b),c),d)及びe)が前記筐体中の保護雰囲気下で実行されることと、
前記塊状ピース(7)が、前記工程b)の前に、保護雰囲気下で機械加工を受けることとを特徴とする貯蔵タンクの製造方法。 - 請求項1記載の方法であって、
金属水素化物を形成可能な前記塊状ピース(7)が多面体形状を有することを特徴とする方法。 - 請求項2記載の方法であって、
金属水素化物を形成可能な前記塊状ピース(7)が平行六面体形状を有することを特徴とする方法。 - 請求項3記載の方法であって、
金属水素化物を形成可能な前記塊状ピース(7)が直方体形状を有することを特徴とする方法。 - 請求項1〜4のいずれか一項に記載の方法であって、
金属水素化物を形成可能な前記塊状ピース(7)が、各空洞に適合される寸法に大きなサイズの塊状インゴットであるブロックから切り取られることを特徴とする方法。 - 請求項5記載の方法であって、
金属水素化物を形成可能な前記塊状ピース(7)が、各空洞に適合される寸法に大きなサイズの塊状インゴットであるブロックから保護雰囲気下で切り取られることを特徴とする方法。 - 請求項1記載の方法であって、
前記機械加工が、粉砕、切り離し、切り取り、剥離、除去、充填、回転、ミリング、研磨、又はそれらの組合せであることを特徴とする方法。 - 請求項1〜7のいずれか一項に記載の方法であって、
金属水素化物を形成可能な材料が、
TiFe、LaNi5、Mm−Ni、Ti−Cr、CaNi5、Ti−Cr、Ti−Mn、Zr−Mn、Ti−Mn−V、Zr−Fe−Cr、Ti−Zr−V、Ti−Fe−Mn、Ti−Fe−Niのような、金属間化合物AB5、AB2、A2B、AB3、A2B7、A2B17;
V−Ti−Fe又はV−Ti−Cr等のバナジウム等のBCC構造を有する固溶体、Mg、Be、Ti、Zr、V、La、U、Y等の純金属、Mg−Ni、Mg−Cu等のマグネシウム合金等の金属合金;、及び、
上記に挙げられた材料のうち2種類以上の材料の混合物;から選択されることを特徴とする方法。 - 請求項1〜8のいずれか一項に記載の方法であって、
前記セル各々の前記自由空間(8)が、前記セルの体積の少なくとも20%の割合を占めることを特徴とする方法。 - 請求項9記載の方法であって、
前記セル各々の前記自由空間(8)が、前記セルの体積の20〜50%の割合を占めることを特徴とする方法。 - 請求項10記載の方法であって、
前記セル各々の前記自由空間(8)が、前記セルの体積の20〜30%の割合を占めることを特徴とする方法。 - 請求項1〜11のいずれか一項に記載の方法であって、
前記金属水素化物粉末(6)が前記金属水素化物粉末(6)を収容する前記基本セル(1)の壁(2,3,4,5)の全てと接触することを特徴とする方法。 - 請求項1〜12のいずれか一項に記載の方法であって、
前記基本セル(1)の壁のすべてが熱交換器を形成することを特徴とする方法。 - 請求項1〜13のいずれか一項に記載の方法であって、
さらに、水素の送入導管及び排出導管(9)を取り付ける工程と、伝熱流体を移送するための導管(10)を取り付ける工程とを備えることを特徴とする方法。
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FR0853151A FR2931142B1 (fr) | 2008-05-15 | 2008-05-15 | Procede de fabrication d'un reservoir d'hydrogene a hydrures metalliques |
FR0853151 | 2008-05-15 | ||
PCT/EP2009/055728 WO2009138406A1 (fr) | 2008-05-15 | 2009-05-12 | Procede de fabrication d'un reservoir d'hydrogene a hydrures metalliques |
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EP (1) | EP2276965B1 (ja) |
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CA (1) | CA2724227C (ja) |
DK (1) | DK2276965T3 (ja) |
EG (1) | EG26208A (ja) |
FR (1) | FR2931142B1 (ja) |
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FR2952695B1 (fr) | 2009-11-13 | 2012-03-30 | Commissariat Energie Atomique | Reservoir de stockage d'hydrogene a hydrures metalliques |
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JP2011521179A (ja) | 2011-07-21 |
EP2276965B1 (fr) | 2018-11-07 |
DK2276965T3 (en) | 2019-02-25 |
KR20110018310A (ko) | 2011-02-23 |
US20110138748A1 (en) | 2011-06-16 |
FR2931142A1 (fr) | 2009-11-20 |
WO2009138406A1 (fr) | 2009-11-19 |
MA32529B1 (fr) | 2011-08-01 |
BRPI0912712A2 (pt) | 2015-10-13 |
CA2724227A1 (fr) | 2009-11-19 |
US9045334B2 (en) | 2015-06-02 |
CA2724227C (fr) | 2016-05-03 |
FR2931142B1 (fr) | 2010-08-20 |
EG26208A (en) | 2013-04-28 |
CN102027283B (zh) | 2013-03-06 |
EP2276965A1 (fr) | 2011-01-26 |
CN102027283A (zh) | 2011-04-20 |
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