JP5566851B2 - 熱発泡性樹脂組成物、熱発泡性樹脂シート、熱発泡性積層体、発泡体およびその製造方法 - Google Patents
熱発泡性樹脂組成物、熱発泡性樹脂シート、熱発泡性積層体、発泡体およびその製造方法 Download PDFInfo
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- JP5566851B2 JP5566851B2 JP2010242014A JP2010242014A JP5566851B2 JP 5566851 B2 JP5566851 B2 JP 5566851B2 JP 2010242014 A JP2010242014 A JP 2010242014A JP 2010242014 A JP2010242014 A JP 2010242014A JP 5566851 B2 JP5566851 B2 JP 5566851B2
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Images
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/32—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/04—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles consisting of at least two parts of chemically or physically different materials, e.g. having different densities
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3415—Heating or cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/36—Feeding the material to be shaped
- B29C44/38—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length
- B29C44/44—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length in solid form
- B29C44/445—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length in solid form in the form of expandable granules, particles or beads
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/228—Forming foamed products
- C08J9/236—Forming foamed products using binding agents
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
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- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/06—Polystyrene
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
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- Polymerisation Methods In General (AREA)
Description
各成分を、表1の配合処方に従って、ミキシングロールにて、50℃で、回転数10min−1、10分間混練して、混練物(熱発泡性樹脂組成物)を調製した。その後、調製した混練物を、50℃、圧力50kg/cm2で、5分間プレスすることにより、厚み5mmの熱発泡性樹脂シートを形成した。なお、実施例1については、厚み2mmの熱発泡性樹脂シートも形成した。
混練温度およびプレス温度を、常温(20℃)に変更した以外は、実施例1と同様に処理することにより、厚み5mmの熱発泡性樹脂シートを形成した。
(1) ムーニー粘度
上記した混練物の調製において、熱膨張カプセル、OBSHおよび発泡性樹脂粒子のいずれをも配合せずに、それら以外の成分を混練して得られた混練物について、ムーニー粘度(ML1+4、100℃)を測定した。その結果を表1に示す。
(2) 密度および発泡倍率
上記により得られた厚み5mmの熱発泡性樹脂シートを、直径19mmの円形状に打ち抜いてサンプルを作製し、その後、作製したサンプルを、100℃のオーブンに投入して、15分間加熱することにより、サンプルを発泡させて、発泡体を得た。
(3) 発泡充填性
上記により得られた厚み5mmの熱発泡性樹脂シートを、長さ50mm、幅20mmのサイズに切り取ってサンプル(1)を作製し、その後、作製したサンプル(1)を、図5(a)に示すサイズ(長さ50mm、幅25mm)の試験鋼板(2)の間において、下側の試験鋼板(2)の上面の中央に載置した。
○:発泡充填性が良好であった。
(4) 通電およびマイクロ波の照射による発泡性
A.通電による発泡
A−1.ヒーター装置
ニクロムからなる線状の発熱部、発熱部を埋設し、マイカからなるシート状の絶縁体、および、絶縁体を被覆する金属外装板を備える発熱部材(ヒーター装置:商品名「坂口スペースヒーター」、容量60W、坂口電熱社製)を用意した。なお、発熱部材の厚みは4mmであり、サイズが50mm×50mmであった。
ニクロムからなるシート状の発熱部からなる発熱部材(ニクロム箔)を用意した。なお、発熱部材の厚みは2mmであり、サイズが50mm×50mmであった。
PETからなる基材の表面に、アルミニウム蒸着によりマイクロ波吸収層が形成されたマイクロ波吸収体からなる発熱部材を用意した。なお、発熱部材の厚みは6μmであり、サイズが50mm×50mmであった。
ポリイソブチレンゴム*1:Oppanol B50、重量平均分子量(GPC:標準ポリスチレン換算値)340000、密度0.92g/cm3、BASF社製
ポリイソブチレンゴム*2:Oppanol B12、重量平均分子量(GPC:標準ポリスチレン換算値)51000、密度0.92g/cm3、BASF社製
シリコーンゴム*3:KE−550−U、密度1.21g/cm3、信越シリコーン社製
シリコーンゴム*4:KE−951−U、密度1.14g/cm3、信越シリコーン社製
EPDM*5:EPT9090M、ジエン含有量14.2%、三井化学社製
EPDM*6:EPT4045、ジエン含有量8.0%、三井化学社製
EPDM*7:EPT1045、ジエン含有量5.0%、三井化学社製
エポキシ樹脂*8:エピコート♯834、ビスフェノールA型エポキシ樹脂、エポキシ当量230〜270、密度1.18g/cm3、JER社製
エポキシ樹脂*9:PKHM−301、ビスフェノールA型エポキシ樹脂、ガラス転移温度45℃、重量平均分子量39000、InChem社製
マツモトマイクロスフェアーF−36*10:商品名、熱膨張カプセル、発泡開始温度75〜85℃、最大膨張温度120〜130℃、平均粒子径10〜16μm、松本油脂製薬社製
ネオセルボン#1000M*11:商品名、4,4’−オキシビス(ベンゼンスルホニルヒドラジド)、発泡開始温度160℃、平均粒子径4μm、発生ガス量125ml/g(160℃)、永和化成工業社製
発泡性ビーズ*12:発泡性ポリスチレンビーズ(発泡性樹脂粒子)、樹脂のガラス転移温度85℃、熱膨張開始温度70℃、平均粒子径0.46mm、密度(熱膨張前)1.00g/cm3、膨張倍率45倍(100℃)
発泡性ビーズ カネパールK−BS*13:発泡性ポリスチレンビーズ(熱発泡性樹脂粒子)、平均粒子径0.6mm、カネカ社製
発泡性ビーズ カネパールSR*14:発泡性ポリスチレンビーズ(熱発泡性樹脂粒子)、平均粒子径0.19mm、カネカ社製
発泡性ビーズ HCH2*15:商品名、エスレンビーズHCH2、発泡性ポリスチレンビーズ(熱発泡性樹脂粒子)、平均粒子径1.13mm、積水化成品工業社製
発泡性ビーズ HLA3000*16:商品名、ヒートポールGR HLA3000、発泡性アクリロニトリル・スチレン共重合体ビーズ、発泡性(熱発泡性樹脂粒子)、平均粒子径1.13mm、JSP社製
ムーニー粘度*17:100℃のムーニー粘度、自動ムーニー粘度計「AM−1」(東洋精機製作所社製)にて測定
密度*18:JIS Z8807に準拠して測定
発泡倍率*19:体積発泡倍率=発泡前のサンプルの密度/発泡後の発泡体の密度
発泡後*20:発泡後
2 試験鋼板(中空部材)
3 発泡体
4 発熱部材
5 熱発泡性積層体
Claims (22)
- 発泡性樹脂粒子と樹脂組成物とを含有し、
前記発泡性樹脂粒子は、中実の樹脂に熱膨張性物質が含有され、
前記発泡性樹脂粒子の含有割合が、前記樹脂組成物100重量部に対して、0.1〜130重量部であることを特徴とする、熱発泡性樹脂組成物。 - 120℃以下の加熱で発泡することを特徴とする、請求項1に記載の熱発泡性樹脂組成物。
- 前記樹脂組成物が、ゴム、熱可塑性樹脂および熱硬化性樹脂からなる群から選択される少なくとも1種を含有していることを特徴とする、請求項1または2に記載の熱発泡性樹脂組成物。
- 発泡後における密度が、0.02〜1.5g/cm3であることを特徴とする、請求項1〜3のいずれかに記載の熱発泡性樹脂組成物。
- 前記熱膨張性物質の沸点が、−160〜120℃であることを特徴とする、請求項1〜4のいずれかに記載の熱発泡性樹脂組成物。
- 前記発泡性樹脂粒子は、前記樹脂のモノマーを、前記熱膨張性物質の存在下で重合させることにより得られることを特徴とする、請求項1〜5のいずれかに記載の熱発泡性樹脂組成物。
- 前記樹脂が、ポリスチレンおよび/またはポリスチレンコポリマーであることを特徴とする、請求項1〜6のいずれかに記載の熱発泡性樹脂組成物。
- 請求項1〜7のいずれかに記載の熱発泡性樹脂組成物がシート状に形成されていることを特徴とする、熱発泡性樹脂シート。
- 発熱可能な発熱部材と、
前記発熱部材に接触するように積層される請求項8に記載の熱発泡性樹脂シートと
を備えることを特徴とする、熱発泡性積層体。 - 前記発熱部材は、通電により発熱することを特徴とする、請求項9に記載の熱発泡性積層体。
- 前記発熱部材は、マイクロ波の照射により発熱することを特徴とする、請求項9に記載の熱発泡性積層体。
- 請求項1〜7のいずれかに記載の熱発泡性樹脂組成物を加熱により発泡させることにより得られることを特徴とする、発泡体。
- 請求項8に記載の熱発泡性樹脂シートを加熱により発泡させることにより得られることを特徴とする、発泡体。
- 請求項9に記載の熱発泡性積層体の前記発熱部材を発熱させることにより、前記熱発泡性樹脂シートを加熱して発泡させることにより得られることを特徴とする、発泡体。
- 請求項10に記載の熱発泡性積層体の前記発熱部材に通電して、前記発熱部材を発熱させることによって、前記熱発泡性樹脂シートを加熱して発泡させることにより得られることを特徴とする、発泡体。
- 請求項11に記載の熱発泡性積層体の前記発熱部材にマイクロ波を照射して、前記発熱部材を発熱させることによって、前記熱発泡性樹脂シートを加熱して発泡させることにより得られることを特徴とする、発泡体。
- 請求項1〜7のいずれかに記載の熱発泡性樹脂組成物を、加熱により発泡させることを特徴とする、発泡体の製造方法。
- 請求項8に記載の熱発泡性樹脂シートを、加熱により発泡させることを特徴とする、発泡体の製造方法。
- 請求項9に記載の熱発泡性積層体の前記発熱部材を発熱させることにより、前記熱発泡性樹脂シートを加熱して発泡させることを特徴とする、発泡体の製造方法。
- 請求項10に記載の熱発泡性積層体の前記発熱部材に通電して、前記発熱部材を発熱させることにより、前記熱発泡性樹脂シートを加熱して発泡させることを特徴とする、発泡体の製造方法。
- 請求項11に記載の熱発泡性積層体の前記発熱部材にマイクロ波を照射して、前記発熱部材を発熱させることにより、前記熱発泡性樹脂シートを加熱して発泡させることを特徴とする、発泡体の製造方法。
- 120℃以下の温度に加熱することを特徴とする、請求項17〜21のいずれかに記載の発泡体の製造方法。
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PCT/JP2011/054291 WO2011108453A1 (ja) | 2010-03-04 | 2011-02-25 | 熱発泡性樹脂組成物、熱発泡性樹脂シート、熱発泡性積層体、発泡体およびその製造方法 |
CN2011800124437A CN102791785A (zh) | 2010-03-04 | 2011-02-25 | 热发泡性树脂组合物、热发泡性树脂片、热发泡性层叠体、发泡体及其制造方法 |
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US9272484B2 (en) | 2012-01-25 | 2016-03-01 | Richard W. Roberts, JR. | Structural plastic articles, method of use, and methods of manufacture |
US10207606B2 (en) | 2012-03-28 | 2019-02-19 | Richard W. Roberts | Recyclable plastic structural articles and method of manufacture |
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2011
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- 2011-02-25 WO PCT/JP2011/054291 patent/WO2011108453A1/ja active Application Filing
- 2011-02-25 US US13/582,716 patent/US20120328889A1/en not_active Abandoned
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Publication number | Publication date |
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US20120328889A1 (en) | 2012-12-27 |
JP2011202141A (ja) | 2011-10-13 |
WO2011108453A1 (ja) | 2011-09-09 |
CN102791785A (zh) | 2012-11-21 |
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