JP5551384B2 - 燃料電池用水素燃料発生システム - Google Patents
燃料電池用水素燃料発生システム Download PDFInfo
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- JP5551384B2 JP5551384B2 JP2009111811A JP2009111811A JP5551384B2 JP 5551384 B2 JP5551384 B2 JP 5551384B2 JP 2009111811 A JP2009111811 A JP 2009111811A JP 2009111811 A JP2009111811 A JP 2009111811A JP 5551384 B2 JP5551384 B2 JP 5551384B2
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- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
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- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
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- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0618—Reforming processes, e.g. autothermal, partial oxidation or steam reforming
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0625—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material in a modular combined reactor/fuel cell structure
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
- H01M8/0668—Removal of carbon monoxide or carbon dioxide
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
- H01M8/0687—Reactant purification by the use of membranes or filters
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0405—Purification by membrane separation
- C01B2203/041—In-situ membrane purification during hydrogen production
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/066—Integration with other chemical processes with fuel cells
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1035—Catalyst coated on equipment surfaces, e.g. reactor walls
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
- H01M2250/20—Fuel cells in motive systems, e.g. vehicle, ship, plane
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02T90/40—Application of hydrogen technology to transportation, e.g. using fuel cells
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Sustainable Energy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Fuel Cell (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Description
H2O + CO (←)→ CO2 + H2 (1)
反応1で示されているように、WGS反応は平衡反応と呼ばれるものであり、このことは、反応が左に向かっても進行することを意味する。究極的に反応が右へ進むか左へ進むかは、温度、関与する物質の濃度などの操作条件に依存する。たとえば、平衡状態にある反応混合物に水またはCOが供給されれば、究極的反応は右へ進むであろう。CO2または水素を反応混合物から除去しても、同じことが起こる。これとの関連で、可能な最大量の水素を生じさせるために、反応をできるだけ右へ推し進めることが原則として望ましいが、反応速度などの他のパラメータも考慮に入れなければならない。スチームリフォーミングおよび部分酸化には適当な比較的高い温度では、反応1の平衡が左へ、すなわち水およびCOが生成する方向へ、移動する。水素の生成を増すために、また、燃料電池では普通望ましくないCOの量を減少させるために、従来のシステムは、第一段階で生成したプロセスガスの冷却後に、WGS反応をより低温で進行させて、平衡を右へ移動させる第二のリフォーミング段階を包含しているのが普通である。
Claims (8)
- 一次燃料を水素に転化するリフォーミングプロセスを実行するための装置ならびにCOからリフォーミングプロセスを去っていく水素燃料の流れをクリーニングする少なくとも1つの装置を包含し、該クリーニング装置が、第一の流路(21)および第二の流路(24)に面するCOに対して選択的透過性を示す膜(22)を包含し、膜(22)から第二の流路(24)にCOを運び去る燃料電池用水素燃料発生システムであって、
前記膜(22)が本質的にCOを膜に吸着させてCOに対して選択的透過性を示すとともに、マイクロポーラス構造を示すセラミック材料によって構成され、細孔のサイズがCOを吸着する膜を通しての水素の輸送を阻害するように形成されていることを特徴とするシステム。 - 前記第一の流路を通って水素燃料の流れが通過するように配置されていること、および、前記膜の二次側(25)が酸化触媒の層(23)によって少なくとも部分的に被覆されていることを特徴とする請求項1に記載のシステム。
- 前記第二の流路(24)を酸素含有フラッシングガスの流れが通過するように配置され、COの酸化が酸素含有フラッシングガスの手段によって膜の二次側で少なくとも部分的に行われることを特徴とする請求項1または2のいずれかに記載のシステム。
- フラッシングガスの流れが、第一流路(21)中の主たる流れの方向とは本質的に逆の方向に通過するように配置されていることを特徴とする請求項3に記載のシステム。
- 膜(22)がCO2に対しても選択的透過性を示すことを特徴とする請求項1〜4のいずれかに記載のシステム。
- 膜(22)がゼオライト構造またはゼオライト様構造を示すことを特徴とする請求項1〜5のいずれかに記載のシステム。
- 前記膜が20Åより小さいサイズの細孔を有することを特徴とする請求項1〜6のいずれかに記載のシステム。
- 前記システムが移動/可搬式用途向けに配置されていることを特徴とする請求項1〜7のいずれかに記載のシステム。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE0200589A SE523260C2 (sv) | 2002-02-27 | 2002-02-27 | System för generering av vätgasbränsle till en bränslecell |
SE0200589-0 | 2002-02-27 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2003571205A Division JP5237519B2 (ja) | 2002-02-27 | 2003-02-25 | 燃料電池用水素燃料発生システム |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2009179555A JP2009179555A (ja) | 2009-08-13 |
JP2009179555A5 JP2009179555A5 (ja) | 2011-01-06 |
JP5551384B2 true JP5551384B2 (ja) | 2014-07-16 |
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ID=20287101
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2003571205A Expired - Lifetime JP5237519B2 (ja) | 2002-02-27 | 2003-02-25 | 燃料電池用水素燃料発生システム |
JP2009111811A Expired - Lifetime JP5551384B2 (ja) | 2002-02-27 | 2009-05-01 | 燃料電池用水素燃料発生システム |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
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JP2003571205A Expired - Lifetime JP5237519B2 (ja) | 2002-02-27 | 2003-02-25 | 燃料電池用水素燃料発生システム |
Country Status (10)
Country | Link |
---|---|
US (1) | US20050000161A1 (ja) |
EP (2) | EP1808410B1 (ja) |
JP (2) | JP5237519B2 (ja) |
CN (1) | CN1288072C (ja) |
AT (1) | ATE526283T1 (ja) |
AU (1) | AU2003217097A1 (ja) |
CA (2) | CA2476020C (ja) |
ES (1) | ES2374286T3 (ja) |
SE (1) | SE523260C2 (ja) |
WO (1) | WO2003072493A1 (ja) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
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US20070023210A1 (en) * | 2005-07-28 | 2007-02-01 | Caterpillar Inc. | Electrical system of a mobile machine |
US7291934B2 (en) * | 2005-08-30 | 2007-11-06 | Caterpillar Inc. | Machine with an electrical system |
EP1808327A1 (en) * | 2006-01-13 | 2007-07-18 | Claudio Rossi | Electric energy production through fuel cells fed by hydrogen obtained from ethanol catalytic reforming |
US7484583B2 (en) | 2006-09-29 | 2009-02-03 | Caterpillar Inc. | Auxiliary power unit for moving a vehicle |
DE102010049794A1 (de) * | 2010-05-25 | 2011-12-01 | Diehl Aerospace Gmbh | Verfahren zur Erzeugung von Energie und die Verwendung eines Stoffgemisches zur Erzeugung von Energie |
JP5779397B2 (ja) * | 2011-05-11 | 2015-09-16 | 日立造船株式会社 | 石炭ガス化プロセスにおける二酸化炭素膜分離システム、およびこれを用いた石炭ガス化複合発電設備 |
WO2015171849A2 (en) | 2014-05-07 | 2015-11-12 | Open Water Power, Incorporated | Hydrogen management in electrochemical systems |
KR102341960B1 (ko) * | 2015-04-08 | 2021-12-23 | 할도르 토프쉐 에이/에스 | Co2 막을 포함하는 개질기 디바이스 |
JP2021017380A (ja) * | 2019-07-18 | 2021-02-15 | 株式会社デンソー | 燃料改質システム |
Family Cites Families (17)
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GB1577723A (en) * | 1976-06-11 | 1980-10-29 | Exxon Research Engineering Co | Removal of a gas component present in a gaseous stream |
US5229102A (en) * | 1989-11-13 | 1993-07-20 | Medalert, Inc. | Catalytic ceramic membrane steam-hydrocarbon reformer |
US5019263A (en) * | 1990-06-05 | 1991-05-28 | Mobil Oil Corp. | Membrane composed of a pure molecular sieve |
EP0729196A1 (en) * | 1995-02-27 | 1996-08-28 | FINMECCANICA S.p.A. AZIENDA ANSALDO | Fuel cell integrated with catalytic reactor producing hydrogen |
US6090312A (en) * | 1996-01-31 | 2000-07-18 | Ziaka; Zoe D. | Reactor-membrane permeator process for hydrocarbon reforming and water gas-shift reactions |
US6129861A (en) * | 1996-05-10 | 2000-10-10 | Forschungszentrum Julich Gmbh | Membrane reactor for producing CO- and CO2 -free hydrogen |
JP3509427B2 (ja) * | 1996-10-07 | 2004-03-22 | 株式会社ノリタケカンパニーリミテド | ゼオライト膜の製造方法 |
US5997594A (en) * | 1996-10-30 | 1999-12-07 | Northwest Power Systems, Llc | Steam reformer with internal hydrogen purification |
CA2294531A1 (en) * | 1997-08-01 | 1999-02-11 | Win-Sow Ho | Co2-selective membrane process and system for reforming a fuel to hydrogen for a fuel cell |
JP4006107B2 (ja) * | 1998-09-01 | 2007-11-14 | 日本碍子株式会社 | 高純度coの製造方法及び製造装置 |
JP2000143210A (ja) * | 1998-11-09 | 2000-05-23 | Tokyo Gas Co Ltd | 一酸化炭素変成器 |
US6536604B1 (en) * | 1999-06-25 | 2003-03-25 | C. Jeffrey Brinker | Inorganic dual-layer microporous supported membranes |
JP2001015142A (ja) * | 1999-06-30 | 2001-01-19 | Mitsubishi Heavy Ind Ltd | 燃料電池車両の走行方法及び燃料電池車両 |
JP2001139304A (ja) * | 1999-11-09 | 2001-05-22 | Toshiba Corp | 炭酸ガス分離型改質器 |
WO2001089665A1 (en) * | 2000-05-23 | 2001-11-29 | Nedstack Holding B.V. | Purification of gas mixtures |
DE10034401A1 (de) * | 2000-07-14 | 2002-01-24 | Daimler Chrysler Ag | Brennstoffzellen-System mit wenigstens einer mit einem flüssigen Kühlmittel/Brennstoff-Gemisch betriebenen Brennstoffzelle |
JP3871501B2 (ja) * | 2000-08-07 | 2007-01-24 | 株式会社ノリタケカンパニーリミテド | ゼオライト膜とその製造方法と膜リアクター |
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2002
- 2002-02-27 SE SE0200589A patent/SE523260C2/sv not_active IP Right Cessation
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2003
- 2003-02-25 CA CA2476020A patent/CA2476020C/en not_active Expired - Lifetime
- 2003-02-25 WO PCT/SE2003/000314 patent/WO2003072493A1/en active Application Filing
- 2003-02-25 AU AU2003217097A patent/AU2003217097A1/en not_active Abandoned
- 2003-02-25 CN CNB038048337A patent/CN1288072C/zh not_active Expired - Lifetime
- 2003-02-25 EP EP07007482.8A patent/EP1808410B1/en not_active Expired - Lifetime
- 2003-02-25 ES ES03713122T patent/ES2374286T3/es not_active Expired - Lifetime
- 2003-02-25 JP JP2003571205A patent/JP5237519B2/ja not_active Expired - Lifetime
- 2003-02-25 EP EP03713122A patent/EP1480907B1/en not_active Expired - Lifetime
- 2003-02-25 AT AT03713122T patent/ATE526283T1/de not_active IP Right Cessation
- 2003-02-25 CA CA2690210A patent/CA2690210C/en not_active Expired - Lifetime
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2004
- 2004-08-27 US US10/711,152 patent/US20050000161A1/en not_active Abandoned
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- 2009-05-01 JP JP2009111811A patent/JP5551384B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CN1288072C (zh) | 2006-12-06 |
EP1808410A2 (en) | 2007-07-18 |
JP5237519B2 (ja) | 2013-07-17 |
CA2476020C (en) | 2012-09-11 |
ES2374286T3 (es) | 2012-02-15 |
WO2003072493A1 (en) | 2003-09-04 |
AU2003217097A8 (en) | 2003-09-09 |
CA2476020A1 (en) | 2003-09-04 |
CN1639057A (zh) | 2005-07-13 |
ATE526283T1 (de) | 2011-10-15 |
JP2005519012A (ja) | 2005-06-30 |
CA2690210C (en) | 2014-08-05 |
AU2003217097A1 (en) | 2003-09-09 |
EP1480907B1 (en) | 2011-09-28 |
SE0200589L (sv) | 2003-08-28 |
US20050000161A1 (en) | 2005-01-06 |
EP1808410A3 (en) | 2007-08-01 |
WO2003072493A8 (en) | 2004-04-22 |
EP1480907A1 (en) | 2004-12-01 |
JP2009179555A (ja) | 2009-08-13 |
SE0200589D0 (sv) | 2002-02-27 |
EP1808410B1 (en) | 2013-04-10 |
SE523260C2 (sv) | 2004-04-06 |
CA2690210A1 (en) | 2003-09-04 |
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