JP5498667B2 - 毛髪化粧料 - Google Patents
毛髪化粧料 Download PDFInfo
- Publication number
- JP5498667B2 JP5498667B2 JP2008105707A JP2008105707A JP5498667B2 JP 5498667 B2 JP5498667 B2 JP 5498667B2 JP 2008105707 A JP2008105707 A JP 2008105707A JP 2008105707 A JP2008105707 A JP 2008105707A JP 5498667 B2 JP5498667 B2 JP 5498667B2
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- Prior art keywords
- hair
- general formula
- fatty acid
- group
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003676 hair preparation Substances 0.000 title claims description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 65
- 239000000194 fatty acid Substances 0.000 claims description 65
- 229930195729 fatty acid Natural products 0.000 claims description 65
- 150000004665 fatty acids Chemical class 0.000 claims description 54
- -1 organic cation salt Chemical class 0.000 claims description 51
- 239000002537 cosmetic Substances 0.000 claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 8
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims description 5
- 239000003093 cationic surfactant Substances 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- NRWCNEBHECBWRJ-UHFFFAOYSA-M trimethyl(propyl)azanium;chloride Chemical compound [Cl-].CCC[N+](C)(C)C NRWCNEBHECBWRJ-UHFFFAOYSA-M 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 description 47
- 125000000217 alkyl group Chemical group 0.000 description 34
- 150000003839 salts Chemical class 0.000 description 23
- 150000001875 compounds Chemical class 0.000 description 20
- 229920001296 polysiloxane Polymers 0.000 description 20
- 125000003342 alkenyl group Chemical group 0.000 description 17
- 150000001768 cations Chemical group 0.000 description 15
- 125000002947 alkylene group Chemical group 0.000 description 13
- 239000000203 mixture Substances 0.000 description 13
- 239000000284 extract Substances 0.000 description 11
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 10
- 238000011282 treatment Methods 0.000 description 10
- 239000004166 Lanolin Substances 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 229940039717 lanolin Drugs 0.000 description 9
- 235000019388 lanolin Nutrition 0.000 description 9
- 125000001453 quaternary ammonium group Chemical group 0.000 description 9
- WSRCOZWDQPJAQT-UHFFFAOYSA-N 18-methylicosanoic acid Chemical compound CCC(C)CCCCCCCCCCCCCCCCC(O)=O WSRCOZWDQPJAQT-UHFFFAOYSA-N 0.000 description 8
- 150000001450 anions Chemical class 0.000 description 8
- 239000004205 dimethyl polysiloxane Substances 0.000 description 8
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 8
- 230000003699 hair surface Effects 0.000 description 8
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
- 150000002892 organic cations Chemical class 0.000 description 8
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- ZRALSGWEFCBTJO-UHFFFAOYSA-O guanidinium Chemical compound NC(N)=[NH2+] ZRALSGWEFCBTJO-UHFFFAOYSA-O 0.000 description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000012190 activator Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 150000002357 guanidines Chemical class 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 235000019486 Sunflower oil Nutrition 0.000 description 4
- 125000004450 alkenylene group Chemical group 0.000 description 4
- 239000004359 castor oil Substances 0.000 description 4
- 235000019438 castor oil Nutrition 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 4
- 239000002600 sunflower oil Substances 0.000 description 4
- PDSVZUAJOIQXRK-UHFFFAOYSA-N trimethyl(octadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)C PDSVZUAJOIQXRK-UHFFFAOYSA-N 0.000 description 4
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 235000019445 benzyl alcohol Nutrition 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- ZRALSGWEFCBTJO-UHFFFAOYSA-N guanidine group Chemical group NC(=N)N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 3
- 229940083094 guanine derivative acting on arteriolar smooth muscle Drugs 0.000 description 3
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 239000004310 lactic acid Substances 0.000 description 3
- 235000014655 lactic acid Nutrition 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000011049 pearl Substances 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000002453 shampoo Substances 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- NAWXUBYGYWOOIX-SFHVURJKSA-N (2s)-2-[[4-[2-(2,4-diaminoquinazolin-6-yl)ethyl]benzoyl]amino]-4-methylidenepentanedioic acid Chemical compound C1=CC2=NC(N)=NC(N)=C2C=C1CCC1=CC=C(C(=O)N[C@@H](CC(=C)C(O)=O)C(O)=O)C=C1 NAWXUBYGYWOOIX-SFHVURJKSA-N 0.000 description 2
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 2
- HILAYQUKKYWPJW-UHFFFAOYSA-N 1-dodecylguanidine Chemical compound CCCCCCCCCCCCN=C(N)N HILAYQUKKYWPJW-UHFFFAOYSA-N 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- PCGKIWPTIJPQHI-UHFFFAOYSA-N 16-methyloctadecanoic acid Chemical compound CCC(C)CCCCCCCCCCCCCCC(O)=O PCGKIWPTIJPQHI-UHFFFAOYSA-N 0.000 description 2
- YETXGSGCWODRAA-UHFFFAOYSA-N 17-methyloctadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCCC(O)=O YETXGSGCWODRAA-UHFFFAOYSA-N 0.000 description 2
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 2
- GLKRSFJCYTXIOF-UHFFFAOYSA-N 2-octadecylguanidine Chemical compound CCCCCCCCCCCCCCCCCCN=C(N)N GLKRSFJCYTXIOF-UHFFFAOYSA-N 0.000 description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- HEPBMDUSWIMDBM-UHFFFAOYSA-N 2-tetradecylguanidine Chemical compound CCCCCCCCCCCCCCN=C(N)N HEPBMDUSWIMDBM-UHFFFAOYSA-N 0.000 description 2
- QKTZVJSRVGCXCJ-UHFFFAOYSA-N 3-hexadecoxypropyl(trimethyl)azanium Chemical compound CCCCCCCCCCCCCCCCOCCC[N+](C)(C)C QKTZVJSRVGCXCJ-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 230000037308 hair color Effects 0.000 description 2
- 230000003700 hair damage Effects 0.000 description 2
- IRHTZOCLLONTOC-UHFFFAOYSA-N hexacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCO IRHTZOCLLONTOC-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 2
- OQILCOQZDHPEAZ-UHFFFAOYSA-N octyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 description 2
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- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- BJDAUCLANVMIOB-UHFFFAOYSA-N (3-decanoyloxy-2,2-dimethylpropyl) decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)(C)COC(=O)CCCCCCCCC BJDAUCLANVMIOB-UHFFFAOYSA-N 0.000 description 1
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- FTNJQNQLEGKTGD-UHFFFAOYSA-N 1,3-benzodioxole Chemical compound C1=CC=C2OCOC2=C1 FTNJQNQLEGKTGD-UHFFFAOYSA-N 0.000 description 1
- WAYINTBTZWQNSN-UHFFFAOYSA-N 11-methyldodecyl 3,5,5-trimethylhexanoate Chemical compound CC(C)CCCCCCCCCCOC(=O)CC(C)CC(C)(C)C WAYINTBTZWQNSN-UHFFFAOYSA-N 0.000 description 1
- ZONJATNKKGGVSU-UHFFFAOYSA-N 14-methylpentadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCC(O)=O ZONJATNKKGGVSU-UHFFFAOYSA-N 0.000 description 1
- LGEZTMRIZWCDLW-UHFFFAOYSA-N 14-methylpentadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC(C)C LGEZTMRIZWCDLW-UHFFFAOYSA-N 0.000 description 1
- VLJCQMPCVZKWIE-UHFFFAOYSA-N 17-methyl-nonadecanoic acid Chemical compound CCC(C)CCCCCCCCCCCCCCCC(O)=O VLJCQMPCVZKWIE-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- TZHBQKUODQVENR-UHFFFAOYSA-N 2-aminoethyl(triethyl)azanium Chemical compound CC[N+](CC)(CC)CCN TZHBQKUODQVENR-UHFFFAOYSA-N 0.000 description 1
- FZRWLIOCKSFGRG-UHFFFAOYSA-N 2-hexadecylguanidine Chemical compound CCCCCCCCCCCCCCCCN=C(N)N FZRWLIOCKSFGRG-UHFFFAOYSA-N 0.000 description 1
- MYWSBJKVOUZCIA-UHFFFAOYSA-N 2-hydroxy-3,5-diiodobenzaldehyde Chemical compound OC1=C(I)C=C(I)C=C1C=O MYWSBJKVOUZCIA-UHFFFAOYSA-N 0.000 description 1
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- QDMYWSNKJKUIRJ-UHFFFAOYSA-M NCCC[N+](C)(C)CC.S(=O)(=O)(OCC)[O-].NCCC[NH+](C)C.C(C)OS(=O)(=O)[O-] Chemical compound NCCC[N+](C)(C)CC.S(=O)(=O)(OCC)[O-].NCCC[NH+](C)C.C(C)OS(=O)(=O)[O-] QDMYWSNKJKUIRJ-UHFFFAOYSA-M 0.000 description 1
- GWFGDXZQZYMSMJ-UHFFFAOYSA-N Octadecansaeure-heptadecylester Natural products CCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC GWFGDXZQZYMSMJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
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- DRRMRHKHTQRWMB-UHFFFAOYSA-N [3-(2-ethylhexanoyloxy)-2,2-bis(2-ethylhexanoyloxymethyl)propyl] 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC(COC(=O)C(CC)CCCC)(COC(=O)C(CC)CCCC)COC(=O)C(CC)CCCC DRRMRHKHTQRWMB-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
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- 125000003277 amino group Chemical group 0.000 description 1
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- 229940006460 bromide ion Drugs 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
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- 229960004830 cetylpyridinium Drugs 0.000 description 1
- NEUSVAOJNUQRTM-UHFFFAOYSA-N cetylpyridinium Chemical compound CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 NEUSVAOJNUQRTM-UHFFFAOYSA-N 0.000 description 1
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- 239000003240 coconut oil Substances 0.000 description 1
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- 238000011033 desalting Methods 0.000 description 1
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- UCYFZDNMZYZSPN-UHFFFAOYSA-N docosyl(trimethyl)azanium Chemical compound CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C UCYFZDNMZYZSPN-UHFFFAOYSA-N 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
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- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
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- 125000002795 guanidino group Chemical group C(N)(=N)N* 0.000 description 1
- 230000003648 hair appearance Effects 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000005660 hydrophilic surface Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- IIUXHTGBZYEGHI-UHFFFAOYSA-N iso-margaric acid Natural products CC(C)CCCCCCCCCCCCCC(O)=O IIUXHTGBZYEGHI-UHFFFAOYSA-N 0.000 description 1
- 229940078545 isocetyl stearate Drugs 0.000 description 1
- 229940100554 isononyl isononanoate Drugs 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229940074928 isopropyl myristate Drugs 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940075495 isopropyl palmitate Drugs 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 235000021374 legumes Nutrition 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
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- 230000008018 melting Effects 0.000 description 1
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
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- 230000001333 moisturizer Effects 0.000 description 1
- 229940078812 myristyl myristate Drugs 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 229940101267 panthenol Drugs 0.000 description 1
- 235000020957 pantothenol Nutrition 0.000 description 1
- 239000011619 pantothenol Substances 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
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- 229920005989 resin Polymers 0.000 description 1
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- 229940081974 saccharin Drugs 0.000 description 1
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- 235000005713 safflower oil Nutrition 0.000 description 1
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- 235000011803 sesame oil Nutrition 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
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- 229940032094 squalane Drugs 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
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- 239000005720 sucrose Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
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- 239000010936 titanium Substances 0.000 description 1
- FLXZVVQJJIGXRS-UHFFFAOYSA-M trimethyl(octadecyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C FLXZVVQJJIGXRS-UHFFFAOYSA-M 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
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- 238000005406 washing Methods 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Description
有機カチオンとして、具体的には、グアニジニウム、芳香族カチオン、4級アンモニウム等のカチオンが挙げられる。
ラウロイルアミドエチルグアニジニウム、ラウロイルアミドブチルグアニジニウム等のn=1の化合物等が挙げられる。
上記一般式(6)で表される4級アンモニウムとして、具体的には、セチルトリメチルアンモニウム、ステアリルトリメチルアンモニウム、ベヘニルトリメチルアンモニウム、セチロキシプロピルトリメチルアンモニウム、ステアロキシプロピルトリメチルアンモニウムが挙げられる。
また、4級アンモニウムの対アニオンが炭酸イオンや炭酸水素イオンなど、分岐脂肪酸よりも弱酸のアニオンの場合には、溶融あるいは、溶媒に溶解し混合することで分岐脂肪酸の有機カチオン塩を生成させることができる。
ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミルスチン酸ミリスチル、パルミチン酸オクチル、ステアリン酸ステアリル、ステアリン酸イソセチル、イソノナン酸イソノニル、イソノナン酸イソトリデシル、ステアリン酸硬化ヒマシ油、ヒドロキシステアリン酸硬化ヒマシ油、トリ2−エチルヘキサン酸グリセリル、テトラ2−エチルヘキサン酸ペンタエリスリトール、ジカプリン酸ネオペンチルグリコール、ジイソステアリン酸ジグリセリル、ジペンタエリスリトールとヒドロキシステアリン酸/ステアリン酸/ロジン酸等の混合脂肪酸とのエステル等のエステル油が挙げられる。
たとえば下記一般式で表される化合物が挙げられる。
R17−N+(CH3)3 X-
(上記一般式中、R17は炭素数12〜22のアルキル基を示し、X−はハロゲン化物イオン(具体的には塩化物イオンまたは臭化物イオン)または炭素数1〜2のアルキル硫酸イオンを示す。)
たとえば下記一般式で表される化合物が挙げられる。
たとえば下記一般式で表される化合物が挙げられる。
たとえば下記一般式で表される化合物が挙げられる。
(R23)2N+(CH3)2 X-
(上記一般式中、R23は炭素数12〜22のアルキル基またはベンジル基を示し、X−は上記と同じである。)
たとえば下記一般式で表される化合物およびその塩が挙げられる。
R24−N(CH3)2
(上記一般式中、R24は炭素数12〜22のアルキル基を示す。)
たとえば下記一般式で表される化合物およびその塩が挙げられる。
たとえば下記一般式で表される化合物およびその塩が挙げられる。
たとえば下記一般式で表される化合物およびその塩が挙げられる。
グアニジン誘導体とは、分子内にグアニジノ基を有する化合物で、たとえば以下の一般式(8)〜(10)等で表されるものが挙げられる。
ラウロイルアミドエチルグアニジン、ラウロイルアミドブチルグアニジン等のn=1の化合物等が挙げられる。
(i)高重合ジメチルポリシロキサン
高重合ジメチルポリシロキサンは、具体的には重合度が1000以上であるジメチルポリシロキサンであり、たとえば、BY11−026、BY22−19(東レ・ダウコーニング社製)、FZ−3125(日本ユニカー社製)等が挙げられる。
高重合ジメチルポリシロキサンとしては、液状油(たとえば、下記(ii)ジメチルポリシロキサン、(iii)環状シリコーン等の液状シリコーン油、またイソパラフィン等の液状炭化水素油)に溶解または分散したものも使用することができる。
上記以外に、ポリエーテル変性シリコーン、メチルフェニルポリシロキサン、脂肪酸変性シリコーン、アルコール変性シリコーン、アルコキシ変性シリコーン、エポキシ変性シリコーン、フッ素変性シリコーン、アルキル変性シリコーン等が挙げられる。
高級アルコールの具体例としては、セタノール(セチルアルコール)、ステアリルアルコール、アラキルアルコール、ベヘニルアルコール、カラナービルアルコール、セリルアルコール等が挙げられる。これらは1種以上を混合して用いることができる。
ステアリルトリメチルアンモニウムクロライドをメタノールに溶解し、10当量のナトリウムメトキシドを加え、1時間攪拌した。次いで水を加え、クロロホルムで抽出した。その後、水で3回洗浄した。得られたステアリルトリメチルアンモニウム塩を減圧濃縮し、凍結乾燥した。さらに、水−メタノール混合溶媒に溶解後、強塩基性樹脂カラムで精製、減圧濃縮、凍結乾燥した。得られたステアリルトリメチルアンモニウム・ヒドロキシド塩をメタノールに溶解させ、当量の18−メチルエイコサン酸を加えた。それを減圧濃縮、減圧乾燥して、分岐脂肪酸4級アンモニウム塩(ステアリルトリメチルアンモニウムの18−メチルエイコサン酸塩)を得た。
これに準じた手順にて、表1に示す他の種類の分岐脂肪酸4級アンモニウム塩を製造することができる。
上記方法で得られる分岐脂肪酸4級アンモニウム塩を用いて、表1に示す組成のヘアコンディショナーを製造し、下記の方法および基準に従って「毛髪の動摩擦係数」、「シャンプー後の接触角」を評価した。
Bharat Bhushan他2名、「Friction and wear studies of human hair and skin」、Wear、vol.259、p.1012-1021(2005)に記載の方法に従い、毛髪化粧料処理後+シャンプー1回処理後の毛髪(N=10)について動摩擦係数を測定した。
渡部俊輔他1名、「毛髪へのシリコーンの吸着挙動」、粧技誌、第29巻、第1号、p.64-68(1995)に記載の方法に従い、毛髪化粧料処理後+シャンプー1回処理後の毛髪(N=10)について接触角(度)を測定した。
また、塩を形成せず分岐脂肪酸と有機カチオンとを別々に配合した比較例2においても、良好な毛髪の感触が得られなかった。
(質量%)
ステアリルトリメチルアンモニウム、18−メチルエイコサン酸塩 1.0
ステアリルアルコール 5.0
ステアリルトリメチルアンモニウムクロリド 1.0
ジプロピレングリコール 5.0
ベンジルアルコール 0.5
ヒマワリ油 0.5
メチルポリシロキサン混合液 2.5
乳酸 1.0
香料 0.4
水酸化ナトリウム 適量
イオン交換水 残量
(質量%)
ステアロキシプロピルトリメチルアンモニウム、18−メチルエイコサン酸塩
2.0
ステアロキシプロピルトリメチルアンモニウムクロリド 2.0
ステアリルアルコール 5.0
ジプロピレングリコール 5.0
ベンジルアルコール 0.5
フェノキシエタノール 0.1
グリセリン 1.0
ポリプロピレングリコール 2.5
ヒマワリ油 0.5
メチルポリシロキサン混合液 2.5
乳酸 1.0
香料 0.4
水酸化ナトリウム 適量
イオン交換水 残量
(質量%)
ステアリルトリメチルアンモニウム、ラノリン脂肪酸(*1)塩 2.0
ステアリルトリメチルアンモニウムクロリド 2.0
ステアリルアルコール 5.0
ジプロピレングリコール 3.0
ベンジルアルコール 0.5
ポリプロピレングリコール 2.5
ヒマワリ油 0.5
メチルポリシロキサン混合液 2.5
乳酸 1.0
香料 0.4
水酸化ナトリウム 適量
イオン交換水 残量
*1:18−MEA クローダ社製
Claims (4)
- 前記分岐脂肪酸の有機カチオン塩を毛髪化粧料全体に対して0.01質量%以上10質量%以下含有する請求項1に記載の毛髪化粧料。
- 更に、カチオン界面活性剤を毛髪化粧料全体に対して0.01〜10質量%含有する請求項1または2に記載の毛髪化粧料。
- 更に、高級アルコールを含有する請求項1乃至3いずれか一項に記載の毛髪化粧料。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008105707A JP5498667B2 (ja) | 2008-04-15 | 2008-04-15 | 毛髪化粧料 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008105707A JP5498667B2 (ja) | 2008-04-15 | 2008-04-15 | 毛髪化粧料 |
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