JP5229793B2 - ノミ防除剤 - Google Patents
ノミ防除剤 Download PDFInfo
- Publication number
- JP5229793B2 JP5229793B2 JP2008126917A JP2008126917A JP5229793B2 JP 5229793 B2 JP5229793 B2 JP 5229793B2 JP 2008126917 A JP2008126917 A JP 2008126917A JP 2008126917 A JP2008126917 A JP 2008126917A JP 5229793 B2 JP5229793 B2 JP 5229793B2
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- exo
- control agent
- flea control
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- Prior art date
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- CXBMCYHAMVGWJQ-UHFFFAOYSA-N tetramethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-UHFFFAOYSA-N 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
しかしながら、従来のノミ防除剤は安全性ならびに防除効果の面で必ずしも十分でなく、実用上満足のいく製剤は未だ開発されるに至っていない。
(1)ジョチュウギクエキス(成分(a))と、N−(2−エチルヘキシル)−ビシクロ[2,2,1]−ヘプタ−5−エン−2,3−ジカルボキシイミド(成分(b))とを含有してなり、成分(a)の総ピレトリン:成分(b)の質量比が1:0.5〜1:4で、前記N−(2−エチルヘキシル)−ビシクロ[2,2,1]−ヘプタ−5−エン−2,3−ジカルボキシイミドのExo型/(Exo型+Endo型)比率が0.3〜0.7であるノミ防除剤。
(2)ジョチュウギクエキス、N−(2−エチルヘキシル)−ビシクロ[2,2,1]−ヘプタ−5−エン−2,3−ジカルボキシイミド、及び溶剤を含有するエアゾール原液と、噴射剤とからなるエアゾール形態である(1)記載のノミ防除剤。
ノミ防除剤中に配合されるジョチュウギクエキスは、総ピレトリンとして0.01〜5.0質量%、好ましくは0.1〜2.0質量%である。
すなわち、本発明のノミ防除剤では、ジョチュウギクエキス中の総ピレトリンと効力増強剤Aの質量比は1:0.5〜1:4であり、この範囲を外れると効力増強効果が低下する。
(1)無水ハイミック酸[cis−5−ノルボルネン−2,3−ジカルボン酸無水物]を溶媒中で2−エチル−ヘキシルアミンと反応させて調製でき、通常の製造方法によれば、(Endo型)無水ハイミック酸から(Endo型)効力増強剤A、また、(Exo型)無水ハイミック酸から(Exo型)効力増強剤Aが得られる。
(2)原料の無水ハイミック酸については、Endo型がExo型に較べて格段に安価であり、特段の要請がなければ効力増強剤Aの立体構造はEndo型が主体である。
原料としては安価な(Endo型)の無水ハイミック酸を使用し、工程は大きく、(1)(Endo型)の無水ハイミック酸の(Exo型+Endo型)への異性化反応、(2)生成物の2−エチルヘキシルアミンとの縮合反応、(3)効力増強剤Aの蒸留工程 に分けることができる。
なお、効力増強剤Aを直接210℃以上に加熱して(Exo型+Endo型)への異性化反応を行うことも可能である。
なかでも、上記2成分及び溶剤を含有するエアゾール原液と、噴射剤とからなるエアゾール形態が使いやすく利便性が高い。
また、粉剤や顆粒剤等を調製するにあたり用いられる担体としては、ケイ酸、カオリン、タルク等の各種鉱物性微粉末や、木粉、小麦粉等の各種植物性粉末などを例示できる。
かかるノミ防除成分としては、アレスリン、プラレトリン、フラメトリン、フタルスリン、フェノトリン、ぺルメトリン、シフェノトリン、シペルメトリン、トラロメトリン、レスメトリン、イミプロトリン、エムペントリン、トランスフルトリン、メトフルトリン、プロフルトリン、エトフェンプロックス等のピレスロイド系殺虫成分、シラフルオフェン等の有機ケイ素系殺虫成分、ジクロルボス、フェニトロチオン等の有機リン系殺虫成分、プロポクスル等のカーバメート系殺虫成分、イミダクロプリド、ジノテフラン、クロチアニジン等のネオニコチノイド系殺虫成分などがあげられる。
例えば、広角ノズル付きのトリガースプレータイプを用いれば、一度の操作で広い範囲を処理することが可能となり便利である。
また、本発明のノミ防除剤は人畜に対する安全性に優れるため、エアゾール剤、液剤、粉剤等の散布剤の所定量を犬やネコ等の体表に直接施用することも可能であり、マット、シート材の場合、犬やネコ等が居る場所、あるいはその周辺に設置すればよい。
放冷後、前記の反応液に2−エチルヘキシルアミン4.1gを加え、生成する水を系外に取り出しながら、140℃で1時間反応させた。反応終了後、蒸留を行い、Exo型/(Exo型+Endo型)比率が0.55の効力増強剤A(7.6g)を得た(蒸留温度:160〜170℃/3mmHg、収率:91%)。
室内犬を飼っている部屋でこのエアゾール剤を使用した。すなわち、ネコノミの生息が認められたフローリング板に20cm離れたところから1m2あたり20mL噴霧したところ、ネコノミは直ちにノックダウンし、蘇生することはなかった。このノミ防除効果は処理後3日間以上持続し、室内犬が嫌がる行動も観察されなかった。
このエアゾール剤は、実施例2と同様、ネコノミに対して高いノックダウン効果と致死効果を示した。
[濾紙接触試験]
供試エアゾール剤を噴霧した濾紙を、内径8cm、高さ14cmのプラスチックリング内に置き、これにネコノミ成虫約10匹を接触させた。接触後、時間の経過に伴うノックダウン数を観察した。接触120分後に全供試ノミを清潔なプラスチック製容器に移し、25±2℃の室内に24時間保存後、供試ノミの生死を観察した。対照製剤として、市販のノミ用エアゾール剤(有効成分:アミドフルメト、メトキサジアゾンを含む3成分)を用いた。なお、供試エアゾール剤の噴霧量は、対照製剤を除き1m2あたり20mLとした。
これに対し、比較例4や比較例5の如く、効力増強剤A以外のピレスロイド用共力剤であるピペロニルブトキサイドやオクタクロロジプロピルエーテルは、ノミ類を対象とした場合、ジョチュウギクエキスとの組み合わせにおいてその効力増強効果は乏しかった。
更に、ジョチュウギクエキスの替わりにdl,d−T80−アレスリンを用いた場合(比較例6〜比較例8)、その化学構造がジョチュウギクエキスに含まれるピレトリンIと類似しているにも拘らず、効力増強剤Aの併用によっても速効性はそれほど改善されず、また効力増強剤AのExo型/Endo型比率が効力増強に及ぼす影響も小さかった。
すなわち、ジョチュウギクエキスと効力増強剤Aの組み合わせが、特定の配合比率でノミ類に対し特徴的に有効であることは明らかである。
[チャンバー内噴霧試験]
60cm立方(0.216m3)のガラスチャンバー内にイエバエ(1群約25匹の雌成虫)を放ち、表2に示す供試エアゾール殺虫剤(原液120mL+噴射ガス180mL)を1秒間噴霧した。10分間暴露して時間の経過に伴う仰転虫数を記録しKT50値を求めた。結果を表2に示す。
20cm×20cmのカーペット(ニードルパンチタイプ、アクリル100%)にエアゾール剤を1m2あたり30mL噴霧し、2時間風乾した後、あらかじめ用意しておいたネコノミ10匹を入れた腰高シャーレ(直径9cm、高さ6cm)をカーペット上に移動し薬剤に接触させた。接触時間は2時間とし、その間の経時的なノックダウン虫を記録してKT50値を算出するとともに、所定時間接触後にネコノミ成虫を全て清潔なプラスチック製容器に移し、24時間後の死虫率を求めた。
その結果、本発明のノミ防除剤によれば、KT50値は2分以内、死虫率は100%で、極めて優れたノミ防除剤であることを確認できた。
Claims (2)
- ジョチュウギクエキス(成分(a))と、N−(2−エチルヘキシル)−ビシクロ[2,2,1]−ヘプタ−5−エン−2,3−ジカルボキシイミド(成分(b))とを含有してなり、成分(a)の総ピレトリン:成分(b)の質量比が1:0.5〜1:4で、前記N−(2−エチルヘキシル)−ビシクロ[2,2,1]−ヘプタ−5−エン−2,3−ジカルボキシイミドのExo型/(Exo型+Endo型)比率が0.3〜0.7であることを特徴とするノミ防除剤。
- ジョチュウギクエキス、N−(2−エチルヘキシル)−ビシクロ[2,2,1]−ヘプタ−5−エン−2,3−ジカルボキシイミド、及び溶剤を含有するエアゾール原液と、噴射剤とからなるエアゾール形態であることを特徴とする請求項1記載のノミ防除剤。
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