JP5181129B2 - 有機ケイ素化合物を基礎とする架橋可能なコンパウンド - Google Patents
有機ケイ素化合物を基礎とする架橋可能なコンパウンド Download PDFInfo
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- JP5181129B2 JP5181129B2 JP2007204564A JP2007204564A JP5181129B2 JP 5181129 B2 JP5181129 B2 JP 5181129B2 JP 2007204564 A JP2007204564 A JP 2007204564A JP 2007204564 A JP2007204564 A JP 2007204564A JP 5181129 B2 JP5181129 B2 JP 5181129B2
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- 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 1
- 229940053200 antiepileptics fatty acid derivative Drugs 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000006013 carbendazim Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 229940071162 caseinate Drugs 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 150000003983 crown ethers Chemical class 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 229940097362 cyclodextrins Drugs 0.000 description 1
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- QZUFYZAIYPHVTL-UHFFFAOYSA-L diacetyloxy(butyl)tin Chemical compound CCCC[Sn](OC(C)=O)OC(C)=O QZUFYZAIYPHVTL-UHFFFAOYSA-L 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- PQZTVWVYCLIIJY-UHFFFAOYSA-N diethyl(propyl)amine Chemical compound CCCN(CC)CC PQZTVWVYCLIIJY-UHFFFAOYSA-N 0.000 description 1
- LQRUPWUPINJLMU-UHFFFAOYSA-N dioctyl(oxo)tin Chemical compound CCCCCCCC[Sn](=O)CCCCCCCC LQRUPWUPINJLMU-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 239000008393 encapsulating agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 125000005448 ethoxyethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229940014259 gelatin Drugs 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000413 hydrolysate Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 description 1
- 150000002678 macrocyclic compounds Chemical class 0.000 description 1
- 125000005358 mercaptoalkyl group Chemical group 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 1
- XTAZYLNFDRKIHJ-UHFFFAOYSA-N n,n-dioctyloctan-1-amine Chemical compound CCCCCCCCN(CCCCCCCC)CCCCCCCC XTAZYLNFDRKIHJ-UHFFFAOYSA-N 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 125000001190 organyl group Chemical group 0.000 description 1
- 125000003110 organyloxy group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 125000005561 phenanthryl group Chemical group 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000003711 photoprotective effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- UQMOLLPKNHFRAC-UHFFFAOYSA-N tetrabutyl silicate Chemical compound CCCCO[Si](OCCCC)(OCCCC)OCCCC UQMOLLPKNHFRAC-UHFFFAOYSA-N 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 239000012974 tin catalyst Substances 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 125000001425 triazolyl group Chemical group 0.000 description 1
- IZRJPHXTEXTLHY-UHFFFAOYSA-N triethoxy(2-triethoxysilylethyl)silane Chemical compound CCO[Si](OCC)(OCC)CC[Si](OCC)(OCC)OCC IZRJPHXTEXTLHY-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 description 1
- GYTROFMCUJZKNA-UHFFFAOYSA-N triethyl triethoxysilyl silicate Chemical compound CCO[Si](OCC)(OCC)O[Si](OCC)(OCC)OCC GYTROFMCUJZKNA-UHFFFAOYSA-N 0.000 description 1
- JCGDCINCKDQXDX-UHFFFAOYSA-N trimethoxy(2-trimethoxysilylethyl)silane Chemical compound CO[Si](OC)(OC)CC[Si](OC)(OC)OC JCGDCINCKDQXDX-UHFFFAOYSA-N 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/544—Silicon-containing compounds containing nitrogen
- C08K5/5465—Silicon-containing compounds containing nitrogen containing at least one C=N bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Toxicology (AREA)
- Medicinal Chemistry (AREA)
- Agronomy & Crop Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Sealing Material Composition (AREA)
Description
(A)少なくとも2個の縮合可能な基を有する有機ケイ素化合物、
(B)カプセル化された殺生物剤、
場合により
(C)架橋剤、及び
場合により
(D)塩基性窒素を含有する化合物
の使用下で製造可能なコンパウンドである。
Ra(OR1)bYcSiO(4-a-b-c)/2 (I)
[式中、Rは、同じか又は異なっていてよく、かつ酸素原子で中断されていてよい置換又は非置換の炭化水素基であり、
R1は、同じか又は異なっていてよく、かつ水素原子、又は酸素原子で中断されていてよい置換又は非置換の1価の炭化水素基であり、
Yは、同じか又は異なっていてよく、かつハロゲン原子、擬ハロゲン基、Si−N結合アミン基、アミド基、オキシム基及びアミノキシ基であり、
aは、0、1、2又は3であり、好ましくは1又は2であり、
bは、0、1、2又は3であり、好ましくは0、1又は2であり、特に好ましくは0であり、かつ
cは、0、1、2又は3であり、好ましくは0又は1であり、特に好ましくは0であり、
但し、a+b+cの合計が4未満であり、かつ1分子当たり少なくとも2個の縮合可能な基(OR1)が存在する]の単位を含有する有機ケイ素化合物である。
(OR1)3-fRfSiO−(SiR2−O)e−SiRf(OR1)3-f (II)
[式中、R及びR1は、上述の意味を有し、
eは、30〜3000であり、かつ
fは、1又は2である]の有機ケイ素化合物(A)である。
(MeO)2MeSiO[SiMe2O]200-2000SiMe(OMe)2、
(HO)Me2SiO[SiMe2O]200-2000SiMe 2 (OH)、
(EtO)2MeSiO[SiMe2O]200-2000SiMe(OEt)2、
(HO)MeViSiO[SiMe2O]200-2000SiMeVi(OH)、
(MeO)2ViSiO[SiMe2O]200-2000SiVi(OMe)2、及び
(EtO)2ViSiO[SiMe2O]200-2000SiVi(OEt)2であり、その式中、Meはメチル基であり、Etはエチル基であり、Viはビニル基である。
(R5O)dZgSiR4 (4-d-g) (III)
[式中、R4は、同じか又は異なっていてよく、かつ酸素原子で中断されていてよい1価の置換又は非置換の炭化水素であり、
R5は、同じか又は異なっていてよく、かつR1について上述した意味を有し、
zは、同じか又は異なっていてよく、かつYについて挙げた意味を有し、
dは、0、1、2、3又は4であり、好ましくは2又は3であり、特に好ましくは3であり、かつ
gは、0、1、2、3又は4であり、好ましくは0又は3であり、特に好ましくは0であり、
但し、d+gの合計は3又は4である]の有機ケイ素化合物並びにその部分加水分解物である。
NR6 3 (IV)
[式中、R6は、同じか又は異なっていてよく、かつ水素原子又は炭化水素基であり、該基はヒドロキシ基、ハロゲン原子、アミノ基、エーテル基、エステル基、エポキシ基、メルカプト基、シアノ基又は(ポリ)グリコール基で置換されていてよく、その際、最後の基はオキシエチレン単位及び/又はオキシプロピレン単位から構成されており、
但し、式(IV)中においては多くとも2個のR6が水素原子の意味を有する]の化合物、
脂肪族環式アミン、例えばピペリジン及びモルホリン、
並びに式
R7 kAlSi(OR8)mO(4-k-l-m)/2 (V)
[式中、R7は、同じか又は異なっていてよく、かつ1価のSiC結合した、塩基性窒素を有さない有機基であり、
R8は、同じか又は異なっていてよく、かつ基R1について挙げた意味を有し、
Aは、同じか又は異なっていてよく、かつ1価のSiC結合した、塩基性窒素を有する基であり、
kは、0、1、2又は3であり、
lは、0、1、2、3又は4であり、かつ
mは、0、1、2又は3であり、
但し、k+l+mの合計は4未満であり、かつ1分子当たり少なくとも1個の基Aが存在する]の単位からの少なくとも1個の塩基性窒素を有する有機基を有する有機ケイ素化合物からなる群から選択された化合物である。
H2N(CH2)3−Si(OCH3)2−O−Si(CH3)(OCH3)2、
H2N(CH2)3−Si(OC2H5)2−O−Si(CH3)(OCH3)2、
H2N(CH2)3−Si(OC2H5)2−O−Si(CH3)(OC2H5)2、
H2N(CH2)3−Si(OCH3)(CH3)−O−Si(CH3)(OCH3)2、
H2N(CH2)3−Si(OCH3)(CH3)−O−Si(OCH3)3、
H2N(CH2)3−Si(OC2H5)(CH3)−O−Si(OCH3)3、
H2N(CH2)2NH(CH2)3−Si(OCH3)2−O−Si(CH3)(OCH3)2、
H2N(CH2)2NH(CH2)3−Si(OC2H5)2−O−Si(CH3)(OCH3)2、
H2N(CH2)2NH(CH2)3−Si(OC2H5)2−O−Si(CH3)(OC2H5)2、
H2N(CH2)2NH(CH2)3−Si(OCH3)(CH3)−O−Si(CH3)(OCH3)2、
H2N(CH2)2NH(CH2)3−Si(OCH3)(CH3)−O−Si(OCH3)3、
H2N(CH2)2NH(CH2)3−Si(OC2H5)(CH3)−O−Si(OCH3)3、
シクロ−C6H11NH(CH2)3−Si(OCH3)2−O−Si(CH3)(OCH3)2、
シクロ−C6H11NH(CH2)3−Si(OC2H5)2−O−Si(CH3)(OCH3)2、
シクロ−C6H11NH(CH2)3−Si(OC2H5)2−O−Si(CH3)(OC2H5)2、
シクロ−C6H11NH(CH2)3−Si(OCH3)(CH3)−O−Si(CH3)(OCH3)2、
シクロ−C6H11NH(CH2)3−Si(OCH3)(CH3)−O−Si(OCH3)3、及び
シクロ−C6H11NH(CH2)3−Si(OC2H5)(CH3)−O−Si(OCH3)3、
H2N(CH2)3−Si(OCH3)2−(O−Si(CH3)2)1-100−O−Si(OCH3)2−(CH2)3NH2、
H2N(CH2)3−Si(OCH2CH3)2−(O−Si(OCH2CH3)2)1-100−(O−Si(OCH2CH3)(CH2)3NH2)1-100−O−Si(OCH2CH3)2−(CH2)3NH2、
Si(OCH2CH3)3−(O−Si(OCH2CH3)2)1-100−(O−Si(OCH2CH3)(CH2)3NH2)1-100−O−Si(OCH2CH3)3、
H2N(CH2)2NH(CH2)3−Si(OCH3)2−(O−Si(CH3)2)1-100−O−Si(OCH3)2−(CH2)3NH(CH2)2NH2、
H2N(CH2)2NH(CH2)3−Si(OCH3)2−(O−Si(CH3)2)1-100−(O−Si(OCH3)(CH2)3NH(CH2)2NH2)1-100−O−Si(OCH3)2−(CH2)3NH(CH2)2NH2、
HO−Si(CH3)2−(O−Si(CH3)2)1-100−(O−Si(OCH3)(CH2)3NH(CH2)2NH2)1-100−O−Si(CH3)2−OH
及び
シクロ−C6H11NH(CH2)3−Si(OCH3)2−(O−Si(CH3)2)1-100−O−Si(OCH3)2−(CH2)3NHシクロ−C6H11並びにその部分加水分解物、及びSi−O−Si含有化合物との平衡反応により製造可能な化合物であり、その際、H2N(CH2)3−Si(OC2H5)2−O−Si(CH3)(OC2H5)2、H2N(CH2)3−Si(OCH2CH3)2−(O−Si(OCH2CH3)2)1-100−(O−Si(OCH2CH3)(CH2)3NH2)1-100−O−Si(OCH2CH3)2−(CH2)3NH2、及びH2N(CH2)2NH(CH2)3−Si(OCH3)2−(O−Si(CH3)2)1-100−(O−Si(OCH3)(CH2)3NH(CH2)2NH2)1-100−O−Si(OCH3)2−(CH2)3NH(CH2)2NH2が特に好ましい。
(A)式(I)の単位を含有する有機ケイ素化合物、
(B)カプセル化された殺生物剤、
場合により
(C)式(III)の架橋剤、
場合により
(D)塩基性窒素を有する化合物、
場合により
(E)触媒、
場合により
(F)可塑剤、
場合により
(G)充填剤、
場合により
(H)定着剤、及び
場合により
(I)添加剤
の使用下で製造可能であり、その際、更なる成分を使用せずに製造可能なコンパウンドである。
マイクロカプセル化された2−n−オクチル−4−イソチアゾリン−3−オン(OIT)(名称「Acticide(R)OTW」(Thor GmbH製)のもとで市販されている)の水性分散液を噴霧乾燥させた。このように得られたカプセル化され、かつ乾燥した65%の作用物質含有率を有するOIT6gを、1000mPa・sの粘度を有するトリメチルシリル末端ブロックポリジメチルシロキサン14g中に分散させた。このために、これらの成分をスパチュラで混合し、次いでハウスチャイルド(Hauschild)ミキサ中で30秒にわたって3000回転/分で均質化した。
80000mPa・sの粘度を有するポリジメチルシロキサン混合物(このシロキサンは、ジメトキシメチルシリル基及び/又はジメトキシビニルシリル基で末端化されており、かつこのジメトキシメチルシリル末端基とジメトキシビニルシリル末端基との比は、約1:1である)330g、1000mPa・sの粘度を有するトリメチルシリル末端ブロックされたポリジメチルシロキサン265g、メチルトリメトキシシラン14g、定着剤(アミノプロピルトリエトキシシラン1部と、エトキシ含有率37%を有するメチルトリエトキシシラン−加水分解物1部との反応により製造された)12.5g、及びアミノプロピルトリメトキシシラン4.5gを遊星ミキサ中で互いに混合し、そして15分間にわたって撹拌した。次いで、このバッチを、150m2/gの比表面積を有する熱分解法シリカ(商標HDK(R)V15(Wacker Chemie AG製)のもとで市販されている)63g、オクチルリン酸1.1g、700mPa・sの粘度を有するポリエチレングリコールポリプロピレングリコール−コポリマー1.4g、スズ触媒(ジ−n−ブチルスズジアセテートとテトラエトキシシランとの反応により製造された)2.5g、及び上述の殺カビ剤調製物1(コンパウンドの全質量に対して1000ppmの作用物質に相当)3.6gを均質に混合することにより完結させた。最後に、約100hPaで5分間にわたって撹拌することにより、撹拌導入された空気を除去した。
実施例1中に記載されたコンパウンドを製造したが、但し、カプセル化されたOIT調製物1000ppmの代わりに、OIT1000ppmをドデシルベンゼン中の10%溶液として添加する変更をした。
ヒドロキシジメチルシリル末端基を有し、かつ80000mPa・sの粘度を有するポリジメチルシロキサン300g、1000mPa・sの粘度を有するトリメチルシリル末端ブロックポリジメチルシロキサン200g、メチルトリス(メチルエチルケトキシモ)シラン38.5g及びビニルトリス(メチルエチルケトキシモ)シラン7.0gを遊星ミキサ中で互いに混合し、そして10分にわたって撹拌し、次いで定着剤(アミノエチルアミノプロピルトリメトキシシラン2部と、約75mPa・sの粘度を有するポリジメチルシロキサン3部との反応により製造された)8.3gを添加し、そして3分にわたって更に撹拌した。次いで、このバッチを、150m2/gの比表面積を有する熱分解法シリカ(商標HDK(R)V15(Wacker Chemie AG)のもとで市販されている)48g、かつ表面被覆された、5.7μmの平均粒径を有する粉砕炭酸カルシウム(Fa.Omya GmbH、D−Koelnにより名称「OMYA BLR3」のもとで市販されている)400g、上述の殺カビ調製物1 5.0g及びジ−n−ブチルスズジアセテート0.9gを均質に混合することにより完結させた。最後に、約100hPaで5分間にわたって撹拌することにより、撹拌導入された空気を除去した。
実施例2中に記載されたコンパウンドを製造したが、但し、カプセル化されたOIT調製物1000ppmの代わりに、OIT1000ppmをドデシルベンゼン中の10%溶液として添加する変更をした。
Claims (5)
- 有機ケイ素化合物を基礎とする、縮合反応により架橋可能なオルガノポリシロキサンコンパウンドであって、
(A)式
Ra(OR1)bYcSiO(4-a-b-c)/2 (I)
[式中、Rは、同じか又は異なっていてよく、かつ酸素原子で中断されていてよい置換又は非置換の炭化水素基であり、
R1は、同じか又は異なっていてよく、かつ水素原子であるか又は酸素原子で中断されていてよい1価の置換又は非置換の炭化水素基であり、
Yは、同じか又は異なっていてよく、かつハロゲン原子、擬ハロゲン基、Si−N−結合アミン基、アミド基、オキシム基及びアミノキシ基であり、
aは、0、1、2又は3であり、
bは、0、1、2又は3であり、かつ
cは、0、1、2又は3であり、
但し、a+b+cの合計は、4未満であり、かつ1分子当たり少なくとも2個の縮合可能な基(OR1)が存在する]の単位を含有する、少なくとも2個の縮合可能な基を有する有機ケイ素化合物、
(B)カプセル化された殺生物剤、その際、殺生物剤は2−n−オクチル−4−イソチアゾリン−3−オン(OIT)及び4,5−ジクロロ−2−n−オクチル−4−イソチアゾリン−3−オン(DCOIT)から選択される、
場合により、
(C)架橋剤、
(D)式
R7 kAlSi(OR8)mO(4-k-l-m)/2 (V)
[式中、R7は、同じか又は異なっていてよく、かつ1価のSiC結合した、塩基性窒素を有さない、置換又は非置換の炭化水素基であり、
R8は、同じか又は異なっていてよく、かつ基R1について挙げた意味を有し、
Aは、同じか又は異なっていてよく、かつ1価のSiC結合した、塩基性窒素を有する基であり、
kは、0、1、2又は3であり、
lは、0、1、2、3又は4であり、かつ
mは、0、1、2又は3であり、
但し、k+l+mの合計は4以下であり、かつ1分子当たり少なくとも1個の基Aが存在する]の単位からの少なくとも1個の塩基性窒素を有する有機ケイ素化合物の使用下で製造可能であるコンパウンドであり、成分(D)が、塩基性窒素の含有量が有機ケイ素化合物(A)100質量部に対して0.01〜5質量部になるような量で存在することを特徴とするコンパウンド。 - 成分(B)が乾燥粉末であることを特徴とする、請求項1に記載の架橋可能なオルガノポリシロキサンコンパウンド。
- 成分(B)を、有機ケイ素化合物(A)100質量部に対して0.01〜3質量部の量で含有することを特徴とする、請求項1又は2に記載の架橋可能なオルガノポリシロキサンコンパウンド。
- 請求項1から3までの何れか1項に記載のコンパウンドの架橋により製造された成形体。
- 請求項1から3までの何れか1項に記載のコンパウンドからなるシーラント。
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DE10359703A1 (de) | 2003-12-18 | 2005-07-14 | Wacker Polymer Systems Gmbh & Co. Kg | Verwendung von Biozide enthaltenden, in Wasser redispergierbaren Polymerpulver-Zusammensetzungen in mineralischen Baustoffmassen |
DE10360469A1 (de) | 2003-12-22 | 2005-07-14 | Wacker-Chemie Gmbh | Vernetzbare Massen auf der Basis von Organosiliciumverbindungen |
ES2297307T3 (es) | 2004-07-10 | 2008-05-01 | Cognis Ip Management Gmbh | Dispersiones. |
KR101483420B1 (ko) * | 2004-09-14 | 2015-01-21 | 마이크로텍 라보라토리즈, 인코포레이티드 | 살생제 및 방오제의 미세캡슐화 |
DE102005009783A1 (de) * | 2005-03-03 | 2006-09-14 | Wacker Chemie Ag | Vernetzbare Massen auf der Basis von Organosiliciumverbindungen |
US9694214B2 (en) † | 2008-04-16 | 2017-07-04 | Dow Corning Corporation | Preparation of silicone microemulsions |
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2006
- 2006-08-04 DE DE102006036556A patent/DE102006036556A1/de not_active Withdrawn
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2007
- 2007-07-25 US US11/782,711 patent/US8183307B2/en active Active
- 2007-07-30 CN CNA2007101371598A patent/CN101117387A/zh active Pending
- 2007-07-31 EP EP07113472.0A patent/EP1884542B2/de active Active
- 2007-07-31 DE DE502007000522T patent/DE502007000522D1/de active Active
- 2007-08-03 KR KR1020070078272A patent/KR101003339B1/ko active IP Right Grant
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KR20080012804A (ko) | 2008-02-12 |
KR101003339B1 (ko) | 2010-12-23 |
EP1884542B1 (de) | 2009-03-18 |
US8183307B2 (en) | 2012-05-22 |
DE502007000522D1 (de) | 2009-04-30 |
EP1884542A1 (de) | 2008-02-06 |
DE102006036556A1 (de) | 2008-02-07 |
US20080033074A1 (en) | 2008-02-07 |
CN101117387A (zh) | 2008-02-06 |
JP2008038154A (ja) | 2008-02-21 |
EP1884542B2 (de) | 2017-12-20 |
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