JP5137831B2 - ラテックス促進組成物 - Google Patents
ラテックス促進組成物 Download PDFInfo
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- JP5137831B2 JP5137831B2 JP2008524486A JP2008524486A JP5137831B2 JP 5137831 B2 JP5137831 B2 JP 5137831B2 JP 2008524486 A JP2008524486 A JP 2008524486A JP 2008524486 A JP2008524486 A JP 2008524486A JP 5137831 B2 JP5137831 B2 JP 5137831B2
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- latex
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- rubber latex
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- 239000000203 mixture Substances 0.000 title claims abstract description 69
- 229920000126 latex Polymers 0.000 title claims abstract description 66
- 239000004816 latex Substances 0.000 title claims description 58
- 238000000034 method Methods 0.000 claims abstract description 27
- 238000004519 manufacturing process Methods 0.000 claims abstract description 22
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920006174 synthetic rubber latex Polymers 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 150000001993 dienes Chemical class 0.000 claims abstract description 5
- 229940116901 diethyldithiocarbamate Drugs 0.000 claims abstract description 4
- LMBWSYZSUOEYSN-UHFFFAOYSA-N diethyldithiocarbamic acid Chemical compound CCN(CC)C(S)=S LMBWSYZSUOEYSN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- 229920003051 synthetic elastomer Polymers 0.000 claims description 10
- 239000012190 activator Substances 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 7
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- RKQOSDAEEGPRER-UHFFFAOYSA-L zinc diethyldithiocarbamate Chemical compound [Zn+2].CCN(CC)C([S-])=S.CCN(CC)C([S-])=S RKQOSDAEEGPRER-UHFFFAOYSA-L 0.000 abstract description 11
- -1 e.g. ZDEC) Chemical compound 0.000 abstract description 10
- 230000008569 process Effects 0.000 abstract description 2
- 150000007979 thiazole derivatives Chemical class 0.000 abstract description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 78
- 238000001723 curing Methods 0.000 description 13
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 12
- 239000011593 sulfur Substances 0.000 description 12
- 229910052717 sulfur Inorganic materials 0.000 description 12
- 239000000701 coagulant Substances 0.000 description 10
- 239000012990 dithiocarbamate Substances 0.000 description 9
- 229920001971 elastomer Polymers 0.000 description 9
- 239000003381 stabilizer Substances 0.000 description 9
- 230000032683 aging Effects 0.000 description 8
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- 229920006173 natural rubber latex Polymers 0.000 description 7
- 239000005060 rubber Substances 0.000 description 6
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 5
- GIUBHMDTOCBOPA-UHFFFAOYSA-N 3h-1,3-benzothiazole-2-thione;zinc Chemical compound [Zn].C1=CC=C2SC(S)=NC2=C1 GIUBHMDTOCBOPA-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 4
- 229920002633 Kraton (polymer) Polymers 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 4
- 239000005018 casein Substances 0.000 description 4
- 235000021240 caseins Nutrition 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 239000013022 formulation composition Substances 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000005061 synthetic rubber Substances 0.000 description 3
- 238000004073 vulcanization Methods 0.000 description 3
- AUMBZPPBWALQRO-UHFFFAOYSA-L zinc;n,n-dibenzylcarbamodithioate Chemical compound [Zn+2].C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1.C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1 AUMBZPPBWALQRO-UHFFFAOYSA-L 0.000 description 3
- REBKUVYQFXSVNO-NSCUHMNNSA-N (3E)-1,1-dichloropenta-1,3-diene Chemical compound C\C=C\C=C(Cl)Cl REBKUVYQFXSVNO-NSCUHMNNSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- 206010020751 Hypersensitivity Diseases 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 102000014171 Milk Proteins Human genes 0.000 description 2
- 108010011756 Milk Proteins Proteins 0.000 description 2
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 150000004659 dithiocarbamates Chemical class 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 235000021239 milk protein Nutrition 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- 229920001084 poly(chloroprene) Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229960002447 thiram Drugs 0.000 description 2
- QRJZGVVKGFIGLI-UHFFFAOYSA-N 2-phenylguanidine Chemical compound NC(=N)NC1=CC=CC=C1 QRJZGVVKGFIGLI-UHFFFAOYSA-N 0.000 description 1
- 206010067484 Adverse reaction Diseases 0.000 description 1
- 241001352546 Morrisonia latex Species 0.000 description 1
- KFFQABQEJATQAT-UHFFFAOYSA-N N,N'-dibutylthiourea Chemical compound CCCCNC(=S)NCCCC KFFQABQEJATQAT-UHFFFAOYSA-N 0.000 description 1
- 102000002508 Peptide Elongation Factors Human genes 0.000 description 1
- 108010068204 Peptide Elongation Factors Proteins 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000007059 acute toxicity Effects 0.000 description 1
- 231100000403 acute toxicity Toxicity 0.000 description 1
- 230000006838 adverse reaction Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 239000013566 allergen Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SQEDZTDNVYVPQL-UHFFFAOYSA-N dodecylbenzene;sodium Chemical compound [Na].CCCCCCCCCCCCC1=CC=CC=C1 SQEDZTDNVYVPQL-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 231100000584 environmental toxicity Toxicity 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 210000002445 nipple Anatomy 0.000 description 1
- ZWWQICJTBOCQLA-UHFFFAOYSA-N o-propan-2-yl (propan-2-yloxycarbothioyldisulfanyl)methanethioate Chemical compound CC(C)OC(=S)SSC(=S)OC(C)C ZWWQICJTBOCQLA-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
- 125000004354 sulfur functional group Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
- C08K5/31—Guanidine; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
- Moulding By Coating Moulds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Description
1.促進組成物および安定化剤を含有する水性ラテックス組成物を調製すること。前記促進組成物は、ジチオカルバメート、チアゾールおよびグアニジン化合物を含む。
2.型を前記ラテックス配合組成物に浸漬する工程。
3.前期型に付着した前記ラテックス配合組成物を硬化させ、エラストマーポリ(イソプレン)物品を作成すること。
(i)ジエチルジチオカルバメートおよび、
(ii)ジフェニルグアニジン(DPG)を含有し、実質的に任意のメルカプトベンゾチアゾールまたはその塩を含有しない成分(i)および(ii)の重量比(i)/(ii)が0.80から2.00の範囲であることを特徴とするラテックスゴム用促進組成物に関する。
本発明の硬化型水性合成ゴムラテックス組成物は、合成ゴムラテックス、加硫化剤、活性化剤および促進剤系を含む。特に、前記ゴムラテックスは、実質的にランダムな構造を有するか、または1つ以上のコモノマーの検出可能なブロックを含有する、ポリ(イソプレン)、ポリ(ブタジエン)、ポリ(クロロプレン)、ポリ(ネオプレン)、スチレン−イソプレンコポリマーから誘導され得る。ポリマーまたはコポリマーの骨格は、直鎖または分枝であってよいが、好ましくは直鎖である。最も好ましいのは、ポリ(イソプレン)ラテックスである。ポリ(イソプレン)は、その化学的性質の天然ゴムとの類似しており、並びに感触、柔軟性を示す係数、破断時の伸びおよび引張強さなどの物理的性質の天然ゴムと類似しているため、好ましいポリマーの1つである。
本発明を種々の特定の好ましい実施形態および技術を参照して記載する。しかし、添付の特許請求の範囲に定義されるような本発明の精神または範囲内にある多くの変形および改変が可能であることを理解すべきである。
本発明の好ましいポリ(イソプレン)ラテックスプレ配合組成物を以下の一般的な手順を用いて調製することができる。
最初に、ポリ(イソプレン)ラテックスプレ配合組成物のpHを約10に調整する。手袋の型をオーブンで約70℃にあらかじめ加熱しておき、あらかじめ調製しておいた凝固剤組成物に約55℃で所定時間浸漬し、取り出す。次に、凝固剤でコーティングされた型を50℃から70℃の乾燥オーブンに凝固剤が十分に乾燥する時間、通常約5分間置く。
ポリ(イソプレン)ラテックス(約65%のTSCを有するKraton IR 401(商標))を周囲温度で攪拌した。連続的に攪拌しながら、酸化亜鉛および硫黄の分散液を該混合物に添加した。促進剤化合物のZDECおよびDPGを配合して分散液を作成し、これを添加した。Aquanox L(商標)を添加し、混合物を約10分間攪拌した。組成物(I)を25℃で24時間維持した。
Claims (4)
- 共役ジエンまたは共役ジエン及びビニル芳香族コモノマーから誘導されたゴムラテックス用の促進組成物であって、
(i)ジエチルジチオカルバメートおよび、
(ii)ジフェニルグアニジン(DPG)を含有し、チアゾールを含有せず、成分(i)および(ii)の重量比(i)/(ii)が0.80から2.00の範囲であることを特徴とする、促進組成物。 - ゴムラテックス、加硫化剤、並びに活性化剤としてのアルカリ土類金属酸化物又は酸化亜鉛を含み、促進剤として請求項1に記載の組成物のみを含む、硬化型水性合成ゴムラテックス組成物。
- 加硫化剤、触媒および請求項1に記載の促進剤の系を含むラテックス分散物またはエマルションを調製すること、前記ラテックス分散物を0.5から1.5日間熟成させること、物品の形状の型をラテックスに浸漬することおよび、前記型上に付着したラテックスを硬化させることを含む、合成エラストマー物品の水ベースの製造のための方法。
- 請求項2に記載の硬化型水性合成ゴムラテックス組成物から調製した、成形した合成エラストマー物品。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05107244.5 | 2005-08-05 | ||
EP05107244 | 2005-08-05 | ||
PCT/EP2006/064653 WO2007017375A1 (en) | 2005-08-05 | 2006-07-26 | Latex accelerator composition |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2009513752A JP2009513752A (ja) | 2009-04-02 |
JP2009513752A5 JP2009513752A5 (ja) | 2012-05-17 |
JP5137831B2 true JP5137831B2 (ja) | 2013-02-06 |
Family
ID=35276983
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008524486A Active JP5137831B2 (ja) | 2005-08-05 | 2006-07-26 | ラテックス促進組成物 |
Country Status (10)
Country | Link |
---|---|
US (1) | US7700705B2 (ja) |
EP (1) | EP1910456B1 (ja) |
JP (1) | JP5137831B2 (ja) |
CN (1) | CN101238172B (ja) |
AT (1) | ATE547462T1 (ja) |
BR (1) | BRPI0615166B1 (ja) |
CA (1) | CA2617283C (ja) |
MY (1) | MY145566A (ja) |
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Families Citing this family (13)
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JP4820412B2 (ja) * | 2005-08-05 | 2011-11-24 | クレイトン・ポリマーズ・リサーチ・ベー・ベー | ラテックス促進剤組成物 |
GB0606536D0 (en) * | 2006-03-31 | 2006-05-10 | Lrc Products | Polyisoprene condom |
EP2227497A1 (en) * | 2008-01-04 | 2010-09-15 | C.R. Bard, INC. | Synthetic polyisoprene foley catheter |
US8087412B2 (en) | 2008-05-01 | 2012-01-03 | Ansell Healthcare Products Llc | Dip-formed synthetic polyisoprene latex articles with improved intraparticle and interparticle crosslinks |
CN102131531A (zh) * | 2008-06-30 | 2011-07-20 | Cr巴德公司 | 聚氨酯/聚异戊二烯共混物导管 |
PL2507313T3 (pl) | 2009-12-01 | 2018-09-28 | Kossan Sdn Bhd | Elastomerowa guma i produkty z gumy uzyskiwane bez stosowania przyspieszaczy wulkanizacji i siarki |
BR112012018236B1 (pt) * | 2010-01-22 | 2020-10-27 | Allegiance Corporation | método de embalagem de um artigo elastomérico e embalagem de artigo elastomérico |
CN101824175B (zh) * | 2010-04-15 | 2011-12-28 | 天津市橡胶工业研究所 | 用于制造掌指压力手套的胶层材料及其制备方法 |
EP2771397A4 (en) | 2011-10-24 | 2015-06-10 | Bridgestone Americas Tire | SILICA-CHARGED RUBBER COMPOSITION AND METHOD FOR MANUFACTURING THE SAME |
CN102975321B (zh) * | 2012-10-11 | 2015-03-25 | 上海名邦橡胶制品有限公司 | 一种采用聚异戊二烯胶乳制备避孕套的方法 |
CN105358618B (zh) * | 2013-07-10 | 2017-04-26 | Ttk防护设备有限公司 | 一种用于制备浸渍胶乳制品的二元工艺 |
JP6368621B2 (ja) * | 2014-11-04 | 2018-08-01 | 株式会社レヂテックス | 柔軟性を有する高強度ポリイソプレン及びポリイソプレン組成物とその製造方法 |
US10662269B2 (en) | 2017-08-31 | 2020-05-26 | Lifestyles Healthcare Pte. Ltd. | Ziegler-Natta catalyzed polyisoprene articles |
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GB696678A (en) * | 1950-05-12 | 1953-09-09 | Dunlop Rubber Co | Improvements in the vulcanisation of rubber |
FR1562379A (ja) | 1967-04-12 | 1969-04-04 | ||
FR2039696A5 (ja) | 1969-03-20 | 1971-01-15 | Schildkroet Ag | |
WO2000037267A1 (en) * | 1998-12-22 | 2000-06-29 | Pirelli Pneumatici S.P.A. | Tire for vehicles having a high wear resistance and vulcanizable rubber composition for making the same |
JP2002145965A (ja) * | 2000-08-30 | 2002-05-22 | Jsr Corp | 共役ジエン系ゴム及び油展ゴム並びにこれらを含むゴム組成物 |
JP4774654B2 (ja) * | 2000-08-30 | 2011-09-14 | Jsr株式会社 | 油展ゴム及びゴム組成物 |
WO2002049430A1 (en) | 2000-12-19 | 2002-06-27 | Bio Dreams Co., Ltd | A method for producing the sustained-releasing agricultural chemicals |
CA2408626C (en) * | 2001-03-12 | 2009-02-17 | Allegiance Corporation | Polyisoprene articles and process for making the same |
US20030161975A1 (en) | 2002-02-27 | 2003-08-28 | Lucas David M. | Polyisoprene condom |
JP2005021474A (ja) * | 2003-07-04 | 2005-01-27 | Sumitomo Rubber Ind Ltd | 卓球用ラバーシート |
US7041746B2 (en) | 2003-09-24 | 2006-05-09 | R.T. Vanderbilt Company, Inc. | Accelerator system for synthetic polyisoprene latex |
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2006
- 2006-07-26 EP EP06806730A patent/EP1910456B1/en active Active
- 2006-07-26 CN CN2006800284806A patent/CN101238172B/zh active Active
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RU2008106847A (ru) | 2009-09-10 |
CA2617283A1 (en) | 2007-02-15 |
BRPI0615166A2 (pt) | 2013-01-08 |
MY145566A (en) | 2012-02-27 |
EP1910456A1 (en) | 2008-04-16 |
ATE547462T1 (de) | 2012-03-15 |
US20090118435A1 (en) | 2009-05-07 |
CA2617283C (en) | 2013-01-08 |
BRPI0615166B1 (pt) | 2017-06-13 |
CN101238172B (zh) | 2012-01-18 |
CN101238172A (zh) | 2008-08-06 |
EP1910456B1 (en) | 2012-02-29 |
JP2009513752A (ja) | 2009-04-02 |
US7700705B2 (en) | 2010-04-20 |
RU2415159C2 (ru) | 2011-03-27 |
WO2007017375A1 (en) | 2007-02-15 |
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