JP5017457B2 - 非粘着性塗料組成物およびその製造方法 - Google Patents
非粘着性塗料組成物およびその製造方法 Download PDFInfo
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- 239000008199 coating composition Substances 0.000 title claims description 49
- 239000000853 adhesive Substances 0.000 title claims description 19
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 38
- 229910052582 BN Inorganic materials 0.000 claims description 37
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 37
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 30
- 238000002156 mixing Methods 0.000 claims description 29
- 230000001070 adhesive effect Effects 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 239000003054 catalyst Substances 0.000 claims description 16
- 239000000945 filler Substances 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 14
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 11
- 230000032683 aging Effects 0.000 claims description 10
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims description 9
- 238000010298 pulverizing process Methods 0.000 claims description 9
- 229910044991 metal oxide Inorganic materials 0.000 claims description 8
- 150000004706 metal oxides Chemical class 0.000 claims description 8
- 239000000049 pigment Substances 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 3
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- RSIHJDGMBDPTIM-UHFFFAOYSA-N ethoxy(trimethyl)silane Chemical compound CCO[Si](C)(C)C RSIHJDGMBDPTIM-UHFFFAOYSA-N 0.000 claims description 3
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 18
- 235000019441 ethanol Nutrition 0.000 description 17
- 239000011248 coating agent Substances 0.000 description 15
- 235000013305 food Nutrition 0.000 description 15
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 14
- 239000011247 coating layer Substances 0.000 description 13
- 238000000576 coating method Methods 0.000 description 12
- 229910052782 aluminium Inorganic materials 0.000 description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- 238000010411 cooking Methods 0.000 description 11
- 238000005260 corrosion Methods 0.000 description 11
- 230000007797 corrosion Effects 0.000 description 11
- 239000011230 binding agent Substances 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 7
- 235000019253 formic acid Nutrition 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- 239000011256 inorganic filler Substances 0.000 description 6
- 229910003475 inorganic filler Inorganic materials 0.000 description 6
- 239000003973 paint Substances 0.000 description 6
- 230000000704 physical effect Effects 0.000 description 6
- -1 polytetrafluoroethylene Polymers 0.000 description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 6
- 239000004810 polytetrafluoroethylene Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 230000009191 jumping Effects 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000009172 bursting Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 235000013601 eggs Nutrition 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- BSYQEPMUPCBSBK-UHFFFAOYSA-N [F].[SiH4] Chemical compound [F].[SiH4] BSYQEPMUPCBSBK-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005524 ceramic coating Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000002431 foraging effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/02—Polysilicates
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/02—Polysilicates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/382—Boron-containing compounds and nitrogen
- C08K2003/385—Binary compounds of nitrogen with boron
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Description
(実施例1)
シリカゾル100重量部を基準として、まず、六方晶窒化ホウ素(hBN)60重量部にイソプロピルアルコール130重量部を混合し、6時間ボールミルで0.5〜10μmの粒子サイズに粉砕した。ここにシリカゾル100重量部と蟻酸0.5重量部を添加し、7分間混合した後、メチルトリメトキシシラン120重量部を添加し、27℃で8時間攪拌および熟成させて塗料組成物を製造した。この塗料組成物を、金剛砂100#でサンドブラストして凸凹を形成させたアルミニウム材質のフライパンの表面にスプレーガンによって30μmの厚さで塗布することにより、コーティング膜を形成した後、200℃の温度で30分間焼結させてコートした。
シリカゾル100重量部を基準として、まず、六方晶窒化ホウ素(hBN)5重量部にイソプロピルアルコール40重量部を混合し、6時間ボールミルで0.5〜10μmの粒子サイズに粉砕した。ここにシリカゾル100重量部と蟻酸3重量部を添加し、7分間混合した後、メチルトリメトキシシラン90重量部を添加し、27℃で8時間攪拌および熟成させて塗料組成物を製造した。この塗料組成物を、実施例1の方法と同様にしてアルミニウム材質のフライパンの表面にコートした。
シリカゾル100重量部を基準として、まず、六方晶窒化ホウ素(hBN)30重量部にイソプロピルアルコール90重量部を混合し、6時間ボールミルで0.5〜10μmの粒子サイズに粉砕した。ここにシリカゾル100重量部と蟻酸2重量部を添加し、7分間混合した後、メチルトリメトキシシラン60重量部を添加し、27℃で8時間攪拌および熟成させて塗料組成物を製造した。この塗料組成物を、実施例1の方法と同様にしてアルミニウム材質のフライパンの表面にコートした。
シリカゾル100重量部を基準として、六方晶窒化ホウ素(hBN)70重量部にイソプロピルアルコール150重量部を混合し、6時間ボールミルで0.5〜10μmの粒子サイズに粉砕した。ここにシリカゾル100重量部と蟻酸0.5重量部を添加し、7分間混合した後、メチルトリメトキシシラン120重量部を添加し、27℃で8時間攪拌および熟成させて塗料組成物を製造した。この塗料組成物を、実施例1の方法と同様にしてアルミニウム材質のフライパンの表面にコートした。
シリカゾル100重量部を基準として、六方晶窒化ホウ素(hBN)3重量部にイソプロピルアルコール50重量部を混合し、6時間ボールミルで0.5〜10μmの粒子サイズに粉砕した。ここにシリカゾル100重量部と蟻酸3重量部を添加し、7分間混合した後、メチルトリメトキシシラン60重量部を添加し、27℃で8時間攪拌および熟成させて塗料組成物を製造した。この塗料組成物を、実施例1の方法と同様にアルミニウム材質のフライパンの表面にコートした。
シリカゾル100重量部にイソプロピルアルコール70重量部および蟻酸2重量部を添加して7分間混合した後、メチルトリメトキシシラン100重量部を添加し、27℃で8時間攪拌および熟成させて塗料組成物を製造した。この塗料組成物を、実施例1の方法と同様にしてアルミニウム材質のフライパンの表面にコートした。
1)塗膜強度は、KS D 8303(アルミニウムおよびアルミニウム合金の陽極酸化塗装複合皮膜の測定方法)の5.9「塗膜の鉛筆硬度抵抗性試験」に基づいて測定した。
前記1.によってコートさせた実施例1〜3と比較例1〜3に対して前記2.の方法によって塗膜強度、耐食性、耐水性および非粘着性を測定し、その測定結果を表1および表2に示した。
Claims (5)
- 非粘着性塗料組成物において、
前記非粘着性塗料組成物は、粒径10〜50nmのシリカ20〜40重量%に水60〜80重量%を混合してなるシリカゾル100重量部に対して、六方晶窒化ホウ素(hBN)40〜60重量%と金属酸化物、非酸化物またはこれらの組み合わせ60〜40重量%とを混合した充填剤5〜60重量部、アルコキシシラン60〜120重量部、メチルアルコールまたはイソプロピルアルコール40〜130重量部、および触媒0.5〜3重量部を含んでなり、
前記金属酸化物はAl2O3またはZrO2であり、前記非酸化物はSi3N4またはB4Cであることを特徴とする、非粘着性塗料組成物。 - 前記アルコキシシランは、メチルトリメトキシシラン[CH3Si(CH3O)3]、テトラメトキシシラン[Si(CH3O)4]、トリメチルエトキシシラン[(CH3)3Si(C2H5O)]、およびテトラエトキシシラン[Si(C2H5O)4]の中から1種またはそれ以上を選択して使用することを特徴とする、請求項1に記載の非粘着性塗料組成物。
- 前記非粘着性塗料組成物は、1〜30重量部の顔料をさらに含むことを特徴とする、請求項1または2に記載の非粘着性塗料組成物。
- 前記顔料は、二酸化チタン(TiO2)、酸化第2鉄(Fe2O3)、酸化クロム(Cr2O3)、炭素(C)、およびコバルト(Co)の中から1種またはそれ以上を選択して使用する、請求項3に記載の非粘着性塗料組成物。
- 塗料組成物の製造方法において、
1)六方晶窒化ホウ素(hBN)40〜60重量%と金属酸化物、非酸化物またはこれらの組み合わせ60〜40重量%とを混合した充填剤と、メチルアルコールまたはイソプロピルアルコールとを混合して2〜10時間粉砕する粉砕段階と、
2)前記1)粉砕段階で粉砕した混合物に、粒径10〜50nmのシリカ20〜40重量%と水60〜80重量%とを混合してなるシリカゾルと触媒を添加し、40〜50rpmの速度で5〜10分間混合する混合段階と、
3)前記2)混合段階で混合した混合物にアルコキシシランを添加して20〜30℃で2〜15時間攪拌しながら熟成させる熟成段階とを含んでなり、
前記金属酸化物はAl2O3またはZrO2であり、前記非酸化物はSi3N4またはB4Cであることを特徴とする、非粘着性塗料組成物の製造方法。
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016033190A (ja) * | 2014-07-31 | 2016-03-10 | 大阪ガスケミカル株式会社 | 塗料組成物 |
KR101813886B1 (ko) * | 2015-10-28 | 2018-01-30 | (주) 삼산Slc | 질화붕소를 이용한 내열 코팅 조성물, 이를 이용한 코팅제 및 이를 이용한 코팅방법 |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
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KR20130039006A (ko) * | 2011-10-11 | 2013-04-19 | 삼성전기주식회사 | 잉크젯 프린트 헤드 조립체 |
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FR2997418B1 (fr) * | 2012-10-31 | 2016-01-01 | Seb Sa | Revetement ceramique aux proprietes de resistance a la rayure et de conduction thermique ameliorees |
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KR101400911B1 (ko) | 2013-11-06 | 2014-06-11 | 주식회사 스폰코리아 | 주방기기용 비점착성 세라믹 코팅제 조성물, 이의 제조방법 및 이를 포함하는 주방기기 |
KR101401222B1 (ko) * | 2013-11-07 | 2014-05-28 | 김태웅 | 가역성 변색 코팅 조성물 및 이의 제조 방법 |
KR102318231B1 (ko) * | 2015-01-29 | 2021-10-27 | 엘지이노텍 주식회사 | 무기충전재, 이를 포함하는 수지 조성물, 그리고 이를 이용한 방열 기판 |
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ES2589478A1 (es) * | 2015-05-11 | 2016-11-14 | Bsh Electrodomésticos España, S.A. | Componente de aparato doméstico que comprende un elemento base con un recubrimiento funcional |
CN104987834B (zh) * | 2015-06-24 | 2017-07-11 | 慧智科技(中国)有限公司 | 耐刮擦玻璃涂层 |
ES2597749B1 (es) * | 2015-07-20 | 2017-12-26 | Bsh Electrodomésticos España, S.A. | Componente de aparato doméstico que comprende un elemento base con un recubrimiento funcional |
KR102227283B1 (ko) * | 2016-04-27 | 2021-03-12 | 주식회사 한국화이어텍 | 비점착성 세라믹도료 조성물 |
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FR3059007B1 (fr) * | 2016-11-21 | 2018-12-07 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Composition de protection pour des substrats a base d'aluminium |
KR20190004927A (ko) * | 2017-07-05 | 2019-01-15 | 전춘식 | 원적외선 방사 코팅제용 조성물 및 그의 제조방법 |
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GB2570733B (en) * | 2018-02-06 | 2022-11-02 | Applied Graphene Mat Uk Ltd | Corrosion protection for metallic substrates |
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KR102478580B1 (ko) * | 2020-10-16 | 2022-12-19 | 배남수 | 기능성 세라믹 도료 조성물 및 이를 이용한 기능성 세라믹 도료 조성물의 혼합방법 |
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CN114773885A (zh) * | 2022-03-29 | 2022-07-22 | 武汉苏泊尔炊具有限公司 | 改性封闭剂、防腐蚀涂层以及制备防腐蚀涂层的方法 |
CN114790343A (zh) * | 2022-03-29 | 2022-07-26 | 武汉苏泊尔炊具有限公司 | 改性封闭涂料、炊具以及炊具的制造方法 |
KR102532458B1 (ko) * | 2022-08-05 | 2023-05-16 | (주)진영 | 가구 표면 마감용 항균 시트 및 이의 제조방법 |
CN115403942A (zh) * | 2022-08-15 | 2022-11-29 | 广东富多新材料股份有限公司 | 一种疏油疏水的无机双疏陶瓷涂料及其制备方法和应用 |
CN115304940B (zh) * | 2022-08-30 | 2023-06-13 | 上海宜瓷龙新材料股份有限公司 | 一种长效不粘涂料及其制备和施工方法 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62220531A (ja) * | 1986-03-24 | 1987-09-28 | Central Glass Co Ltd | 被覆用組成物 |
JPH0791551B2 (ja) * | 1988-10-19 | 1995-10-04 | 川崎製鉄株式会社 | 高温潤滑・離型剤 |
KR0149731B1 (ko) * | 1994-12-30 | 1998-10-01 | 김충세 | 세라믹 보수제의 제조방법 |
JPH10176277A (ja) * | 1996-12-17 | 1998-06-30 | Ougi Shokai:Kk | 非粘着性セラミック塗料 |
JPH11199880A (ja) * | 1997-11-13 | 1999-07-27 | Stt Kk | 金型鋳造用離型剤 |
KR100374172B1 (ko) * | 1999-12-22 | 2003-03-03 | 김정하 | 착색투명 무기도료 조성물과 제조방법 및 조성물 코팅방법 |
JP2001195770A (ja) | 2000-01-14 | 2001-07-19 | Sharp Corp | 光ピックアップ |
US6645612B2 (en) * | 2001-08-07 | 2003-11-11 | Saint-Gobain Ceramics & Plastics, Inc. | High solids hBN slurry, hBN paste, spherical hBN powder, and methods of making and using them |
JP2003339552A (ja) * | 2002-05-23 | 2003-12-02 | Matsushita Electric Ind Co Ltd | 焼き網およびそれを用いた調理機器 |
ATE269913T1 (de) * | 2002-07-31 | 2004-07-15 | Itn Nanovation Gmbh | Keramische beschichtung für verbrennungskessel |
JP2004359811A (ja) * | 2003-06-04 | 2004-12-24 | Ceramission Kk | 放熱性、遮熱性に優れた組成物及び皮膜 |
CN1690142A (zh) * | 2004-04-19 | 2005-11-02 | 河南大学 | 含氟纳米SiO2复合不粘性涂层材料制备方法 |
JP2006063427A (ja) * | 2004-08-30 | 2006-03-09 | Takasago Tekko Kk | 耐テンパーカラー性の優れたステンレス鋼 |
KR100633177B1 (ko) * | 2005-03-24 | 2006-10-12 | 김정하 | pH 조절을 이용한 상온건조 무기도료 조성물과 그제조방법 및 용도 |
US7524560B2 (en) * | 2005-08-19 | 2009-04-28 | Momentive Performance Materials Inc. | Enhanced boron nitride composition and compositions made therewith |
US7527859B2 (en) * | 2006-10-08 | 2009-05-05 | Momentive Performance Materials Inc. | Enhanced boron nitride composition and compositions made therewith |
CA2701941A1 (en) * | 2007-10-30 | 2009-05-07 | Garlock Sealing Technologies, Llc | Gasket release agent |
-
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JP2016033190A (ja) * | 2014-07-31 | 2016-03-10 | 大阪ガスケミカル株式会社 | 塗料組成物 |
KR101813886B1 (ko) * | 2015-10-28 | 2018-01-30 | (주) 삼산Slc | 질화붕소를 이용한 내열 코팅 조성물, 이를 이용한 코팅제 및 이를 이용한 코팅방법 |
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WO2010044535A1 (ko) | 2010-04-22 |
DE112009000066B4 (de) | 2016-02-04 |
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US7854795B2 (en) | 2010-12-21 |
CN101842445B (zh) | 2012-05-30 |
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