JP4954187B2 - 積層シート - Google Patents
積層シート Download PDFInfo
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- JP4954187B2 JP4954187B2 JP2008307126A JP2008307126A JP4954187B2 JP 4954187 B2 JP4954187 B2 JP 4954187B2 JP 2008307126 A JP2008307126 A JP 2008307126A JP 2008307126 A JP2008307126 A JP 2008307126A JP 4954187 B2 JP4954187 B2 JP 4954187B2
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Description
本発明で使用することのできる透明または半透明シートとしては、光を透過することができ、光を完全に遮断しない用紙であれば、特に限定はなく、例えば、グラシン紙、セロハン紙、模造紙、トレーシングペーパーなどが挙げられる。
上記透明または半透明シートは、その片面、すなわち、擬似接着面とは反対側の面の少なくとも一部分に白色遮蔽層を有する。白色遮蔽層は、光透過の抑制を目的とし、隠蔽積層シートを光にかざした際に隠蔽した情報の判読を難しくすることができる。従って、白色遮蔽層は、上記透明または半透明シートの光透過率の80%以下、好ましくは70%以下、より好ましくは60%以下の光透過率を有することが望ましい。白色遮蔽層の光透過率が、透明または半透明シートの光透過率の80%を超えると、光を透過しすぎて、隠蔽積層シートを光にかざした際に隠蔽した情報の判読が容易になる可能性がある。
文字地紋層は、隠蔽部分の下側に記載された情報、特に文字情報のその上側からの容易な判読および推測を困難にすることを目的として、白色遮蔽層の上側に設けることが好ましい。
本発明において、迷彩地紋層は、通常の印刷によって形成することのできる任意の迷彩地紋を含む層を意味し、文字地紋層の上側または下側あるいはその両方に設けることができる。
感熱方式による隠蔽情報の印字の際に熱の影響によって生じ得るシート表面での化学的および物理的変化を防止することを目的として、隠蔽部分の最上層として樹脂層を設けることが望ましい。樹脂層を設けることによって、感熱方式での印字後では、熱の影響による印字痕が隠蔽部分の表面に残らず、情報の機密性が飛躍的に高まる。さらに、サーマルヘッドを用いて感熱方式で印字する場合、このような樹脂層を設けることによって、サーマルヘッドの走査性(すなわち、ヘッドマッチング)を向上させることができるだけでなく、上述の文字地紋および迷彩地紋を形成するインクがサーマルヘッドに付着して印刷性能が低下するのを防止することができる。
本発明で使用することのできる感熱シートとしては、特に限定はなく、従来公知の感熱シートを使用することができる。
感熱シートの基材の材質は、特に限定されず、紙、各種合成樹脂等の、一般的に多層ハガキに用いられているものが使用できる。
感熱記録層としては、従来提案されているものが利用できる。かかる感熱記録層としては、たとえば、反応性染料(染料前駆体)と顕色剤とを含有する層が挙げられる。かかる層においては、熱により反応性染料と顕色剤とが反応して発色する。
反応性染料として用いられるイミノ化合物としては、たとえば下記一般式(I)で表わされる常温固体の無色または淡色の化合物が挙げられる。
本発明の積層シートは、好ましい実施形態によると、基材、感熱記録層、透明または半透明シート、隠蔽部分の順で積層してなるものであり、より詳細には、上記基材と感熱記録層とからなる感熱シートと、透明または半透明シートとが、擬似接着層を介して、感熱記録層を内側にして、剥離可能な状態で貼り合わせてなるものでる。
擬似接着層におけるシート間の接着強さは、JIS K 6854−3に規定されるT形はく離試験法に準拠して、50〜1000mN/25mm(はく離速度300mm/分)であることが好ましく、更に、80〜600mN/25mm(はく離速度300mm/分)であることがより好ましい。
擬似接着層は、擬似接着剤を含有する塗工液、溶媒を用いないもの、エネルギー線硬化型にしたもの等を用いて形成できる。本発明においては、これらの中でも、擬似接着剤を含有する塗工液(以下、擬似接着層形成用塗工液ということがある。)を用いる方法が好ましい。
透明シート(王子製紙株式会社製、商品名:グラシン、縦:152.4mm、横:100mm、厚み:25μm、光透過率:100%)と、感熱シート(王子製紙株式会社製、商品名:PD450、縦:152.4mm、横:100mm、厚み:145μm)とを感熱記録層を内側にしてウェットラミネート法で擬似接着した。
透明シートの一部(縦:8cm、横:9cm)にわたって紫外線硬化型の白色インキ(T&K社製、商品名:改UV161コンク白)を宮腰機械社製の多色オフセット印刷機(商品名:MVF18E)で印刷し、白色遮蔽層(厚さ:1.6μm、光透過率:50%)を形成した。
白色遮蔽層の上に、同じ面積にわたって、図3に示す文字地紋(文字サイズ:10ポイント、色:紺色、文字の角度:ランダム)を宮腰機械社製の多色オフセット印刷機(商品名:MVF18E)で印刷し、文字地紋層を形成した(厚み:0.8μm、文字地紋の割合:文字地紋層の全面積に対して、55%)。
次いで、文字地紋層の上に、同じ面積にわたって、図4に示す迷彩地紋(網目地紋、黒色)を宮腰機械社製の多色オフセット印刷機(商品名:MVF18E)で印刷し、迷彩地紋層を形成した(厚み:0.8μm、迷彩地紋の割合:迷彩地紋層の全面積に対して、55%)。
迷彩地紋層の上に、同じ面積にわたって、OPニス(日本化薬社製、商品名:UFR−11D)を塗布し、透明樹脂層(厚み:0.5μm)を形成した。
実施例1に従って、実施例1で使用した文字地紋の代わりに、図7に示す文字地紋(文字サイズ:12ポイントおよび14ポイント、色:紺藍色、文字の角度:ランダム)を使用して、文字地紋層(厚み:0.8μm、文字地紋の割合:文字地紋層の全面積に対して、65%)を形成し、実施例1で使用した図4に示す迷彩地紋の代わりに、図4の迷彩地紋に図6に示す直線からなる迷彩地紋をさらに含む図5に示す迷彩地紋(黒色)を使用して迷彩地紋層(厚み:0.8μm、迷彩地紋の割合:迷彩地紋層の全面積に対して、67%)を形成し、積層シートを作製した。
実施例1に従って、文字地紋の色を濃紺色に変更して、積層シートを作製した。
実施例1に従って、文字地紋のサイズを10ポイントから11ポイントに変更して、積層シートを作製した。
実施例1に従って、文字地紋を図8に示す文字地紋(文字サイズ:14ポイント、文字の角度:0°(色:群青色)および270°(色:紺藍色)、図3の文字地紋とはフォントが異なる)に変更して、積層シートを作製した。
2 感熱シート
3 白色遮蔽層
4 文字地紋層
5 迷彩地紋層
6 樹脂層
Claims (13)
- 感熱シートと、該感熱シート上に形成された透明または半透明シートとを含む積層シートであって、該透明または半透明シート上の該感熱シートとは反対側の少なくとも一部分に、白色遮蔽層、文字地紋層、迷彩地紋層および樹脂層を含む隠蔽部分を有する、積層シート。
- 上記隠蔽部分が、白色遮蔽層、文字地紋層、迷彩地紋層および樹脂層の順序で重ねて配置してなる請求項1記載の積層シート。
- 上記感熱シートと、上記透明または半透明シートとを擬似接着してなる請求項1または2記載の積層シート。
- 上記白色遮蔽層の光透過率が、上記透明または半透明シートの光透過率の80%以下である請求項1〜3のいずれか1項に記載の積層シート。
- 上記白色遮蔽層の光透過率が、上記透明または半透明シートの光透過率の60%以下である請求項1〜4のいずれか1項に記載の積層シート。
- 上記文字地紋層における文字地紋の割合が、文字地紋層の全面積に対して、30%以上である請求項1〜5のいずれか1項に記載の積層シート。
- 上記迷彩地紋層における迷彩地紋の割合が、迷彩地紋層の全面積に対して、30%以上である請求項1〜6のいずれか1項に記載の積層シート。
- 上記迷彩地紋層における迷彩地紋の割合が、迷彩地紋層の全面積に対して、50〜60%である請求項1〜7のいずれか1項に記載の積層シート。
- 上記迷彩地紋層における迷彩地紋が直線を含む請求項1〜8のいずれか1項に記載の積層シート。
- 上記樹脂層が紫外線硬化性樹脂からなる透明樹脂層である請求項1〜9のいずれか1項に記載の積層シート。
- 上記樹脂層の厚みが1μm以下である請求項1〜10のいずれか1項に記載の積層シート。
- 上記隠蔽部分の上側から感熱方式で感熱シート上に情報を記載する請求項1〜11のいずれか1項に記載の積層シート。
- ハガキとして使用する請求項1〜12のいずれか1項に記載の積層シート。
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